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Oxygen reduction on a ruthenium electrode in acid electrolytes
(Elsevier, 1986)
The kinetics and mechanism of O2 reduction on an Ru electrode in acid electrolytes have been measured by using a disc—ring method. The reaction proceeds through a “parallel” mechanism with the exchange of approximately ...
Photoelectrochemical microscopy of oxide films on metals: Ti/TiO2 interface
(Elsevier, 1988)
Thin electrochemically grown oxide films on polycrystalline titanium substrates were examined by photoelectrochemical and electron diffraction techniques. Photoelectrochemical microscopy, based on illumination by a focused ...
Surface properties of RuO2 + IrO2 mixed oxide electrodes
(Elsevier, 1986)
The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV ...
Structural effects in electrocatalysis: oxidation of formic acid and hydrogen adsorption on platinum single-crystal stepped surfaces
(Elsevier, 1986)
The oxidation of formic acid and hydrogen adsorption have been measured on platinum single-crystal stepped surfaces with five orientations. A pronounced structural sensitivity of both reactions has been found. They show a ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
Structural effects in electrocatalysis
(Springer Science and Business Media LLC, 1982)
Studies of chemical reactions on well-defined surfaces provide fundamental data on surface reactivity and guidelines for the understanding and design of catalytic materials but few such studies have been done in electrocatalysis. ...
Structural effects in electrocatalysis: Oxygen and hydrogen peroxide reduction on single crystal gold electrodes and the effects of lead ad-atoms
(Elsevier, 1982)
Structural effects in electrocatalysis have been clearly and definitely demonstrated for example in the oxidation of HCOOH, CH3OH and CH2O on platinum single crystal electrodes. In this note, we report considerable structural ...
Fundamental aspects of pulsating current metal electrodeposition IX: The prevention of spongy deposit formation on inert substrates
(Elsevier, 1984)
It is shown that spongy deposits are obtained under d.c. conditions and that compact deposits are obtained in pulsating current (PC) deposition with high pause-to-pulse ratios at the same average current density and ...
Electrosorption of hydrogen and sulphuric acid anions on single-crystal platinum stepped surfaces. Part I. The [110] zone
(Elsevier, 1988)
The adsorption of hydrogen and sulphuric acid anions has been studied on single-crystal platinum stepped surfaces from the [110] zone. Both processes depend on the orientation of the electrode surface. The multiple states ...
Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
(Elsevier, 1987)
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the ...