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Effect of malondialdehyde on the ovalbumin structure and its interactions with T84 epithelial cells
(Elsevier, 2017)
Background: Protein oxidation can occur as a consequence of lipid peroxidation during food processing. The aim of this work was to explore the effect of malondialdehyde (MDA) modification of ovalbumin (OVA) on its interaction ...
Conformational mobility of active and E-64-inhibited actinidin
(Elsevier, 2013)
Background: Actinidin, a protease from kiwifruit, belongs to the C1 family of cysteine proteases. Cysteine proteases were found to be involved in many disease states and are valid therapeutic targets. Actinidin has a wide ...
A density functional study of the spin state energetics of polypyrazolylborato complexes of first-row transition metals
(Royal Soc Chemistry, Cambridge, 2014)
Density Functional Theory (DFT) was used to analyse and explain spin state energetics of first-row transition metals (Mn-II, Fe-II, Co-II; Cr-III, Mn-III, Fe-III, Co-III; Mn-IV) in polypyrazolylborato complexes. We explored ...
Active actinidin retains function upon gastro-intestinal digestion and is more thermostable than the E-64-inhibited counterpart
(Wiley-Blackwell, Hoboken, 2014)
BACKGROUND: Actinidin is a cysteine protease and major allergen from kiwi fruit. When purified under specific native conditions, actinidin preparations from fresh kiwi fruit contain both an active and inactive form of this ...
Challenges in assignment of orbital populations in a high spin manganese(III) complex
(Royal Soc Chemistry, Cambridge, 2016)
Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation ...
Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C
(Royal Soc Chemistry, Cambridge, 2014)
The total synthesis of desmethylabyssomicin C analogue 1 was accomplished using diastereotopos-selective ring closing metathesis and Nozaki-Hiyama-Kishi cyclization as the key steps. The synthetic analogue retained its ...
Comparison of cavitation erosion behavior of cordierite and zircon based samples using image and morphological analyses
(Elsevier, 2018)
In this study the resistance of cordierite and zircon to the cavitation erosion was investigated with the aim of possible spreading their application. Cavitation erosion test was applied using standard ultrasonic vibratory ...
4-Oxothiazolidines with Exocyclic C=C Double Bond(s): Synthesis, Structure, Reactions and Biological Activity
(Bentham Science Publ Ltd, Sharjah, 2014)
4-Oxothiazolidine core, owing to the wide range of pharmacological activities exhibited by its derivatives, has been recognized as an important structural motif in biologically active compounds. A subclass constitutes ...
Substituent effects on cyclic electron delocalization in symmetric B- and N- trisubstituted borazine derivatives
(Royal Soc Chemistry, Cambridge, 2013)
Aromaticity is an important concept in chemistry, useful to rationalize structure, physical properties and chemical behaviour of molecules. Aromaticity of an inorganic relative of benzene, borazine, has been the topic of ...