Претраживање
Приказ резултата 1-10 од 143
The influence of OH- chemisorption on the catalytic properties of gold single crystal surfaces for oxygen reduction in alkaline solutions
(Elsevier, 1996)
Oxygen reduction on gold single crystal electrodes of various orientations, Au(hkl), in 0.1 M NaOH was studied by rotating disk electrode and rotating disk ring electrode techniques, with a goal to correlate the physical ...
Photodiode quantum efficiency optimization using spherical pits on active surfaces
(Elsevier, 1995)
A numerical model of a photodiode with etched spherical pits on an active surface has been developed. Several geometrical parameters (radius of curvature, depth and arrangement of spherical pits, sample thickness and area, ...
Kinetic and mechanistic study of methanol oxidation on a Pt 100/ surface in alkaline media
(Elsevier, 1998)
A comparative study of methanol oxidation on a Pt(100) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. It was shown that Pt(100) adsorbs OH and 'poisoning species'. ...
A New Approach to Metal Electrodeposition at a Periodically Change Rate. Part I. The Reversing Overpotential Method
(Elsevier, 1999)
A method of increasing the apparent deposition exchange current density value in reversing overpotential (RO) copper electrodeposition is described. In pulsating overpotential (PO) metal electrodeposition, the current ...
Intramolecular Cyclization of Some Unsaturated Alcohols by Means of Thallium Triacetate
(Weinheim : Wiley-VCH Verlag GmbH & Co., 1992)
Reactions of some primary and secondary Δ4‐, Δ5‐ and Δ6‐alkenols with thallium triacetate (TTA) in benzene, acetic acid and chloroform as solvent have been investigated. When terminally unsubstituted Δ4‐alkenols, such as ...
The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential
(Switzerland : Springer Nature, 1991)
It is well known that the deposition conditions such as
bath composition, hydrodynamic regime, temperature,
current density, exhibit a strong effect on the grain size
and the morphology of electrodeposited metal ...
The influence of pH on reaction pathways for O2 reduction on the Au(100) face
(Elsevier, 1996)
Oxygen reduction on the Au(100) face was studied by the rotating disk-ring electrode technique in solutions of anions which adsorb strongly on gold (HSO4-/SO42- and/or OH-) over the entire pH range. The specific adsorption ...
Effect of substituents on the 13 C chemical shifts of the azomethine carbon atom of N-(phenyl substituted) pyridine-4-aldimines
(Elsevier, 1999)
13 C chemical shifts of the azomethine carbon atom for N-(substituted phenyl)pyridine-4-aldimines, 4-Py-CH=N-C 6 H 4 -X, X having a wide range of substituent effects, have been determined in CDCl 3 solution. Exceptionally ...
Properties of activated alumina obtained by flash calcination of gibbsite
(Elsevier, 1992)
On exposing gibbsite, with granulation below 10 μm to flash calcination of 0.5 s in the regime of pneumatic transport and at temperatures above 883 K, a microcrystalline material with a high degree of amorphization was ...
Hydrogen adsorption on single-crystal platinum electrodes in alkaline solutions
(Elsevier, 1992)
Hydrogen adsorption on single-crystal platinum low-index and stepped surfaces was studied in 0.1 M and 0.01 M NaOH solutions. A strong dependence on the crystallographic orientation of the electrode surface was found. The ...