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Kinetic and mechanistic study of methanol oxidation on a Pt(110) surface in alkaline media
(Elsevier, 1998)
The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH- electrosorption precedes the oxide layer formation in sodium ...
Oxygen reduction on polycrystalline palladium in acid and alkaline solutions: topographical and chemical Pd surface changes
(Oxford : Pergamon-Elsevier Science Ltd, 2015)
Oxygen reduction reaction (ORR) was investigated on polycrystalline palladium, Pd(poly), in acid and alkaline solutions using rotating-disc electrode technique. Pd(poly) was prepared in non-aqueous media which provided ...
HCOOH oxidation on thin Pd layers on Au: Self-poisoning by the subsequent reaction of the reaction product
(Oxford : Pergamon-Elsevier Science Ltd, 2013)
The oxidation of HCOOH has been investigated on thin Pd layers ranging from 1 to 17 ML equivalents electrodeposited on polycrystalline Au substrate (Pd"Au). The results are compared to those on Pd black. Potentiodynamic ...
The influence of pH on reaction pathways for O2 reduction on the Au(100) face
(Elsevier, 1996)
Oxygen reduction on the Au(100) face was studied by the rotating disk-ring electrode technique in solutions of anions which adsorb strongly on gold (HSO4-/SO42- and/or OH-) over the entire pH range. The specific adsorption ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Oxford : Pergamon-Elsevier Science Ltd, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms
(Pergamon Press, 1979)
Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving ...
Polarization curves in the ohmic controlled electrodeposition of metals
(Oxford : Pergamon-Elsevier Science Ltd, 2009)
The conditions under which ohmic controlled metal electrodeposition occurs are discussed using a simple mathematical model. it is shown that ohmic controlled electrodeposition can be operative if the value of the exchange ...
Studies of the deposition of cadmium on foreign substrates
(Elsevier, 1977)
Cadmium deposition on nickel, lead, silver, gold and copper has been studied by the potential sweep and potentiostatic method with a simultaneous observation of the surface by optical microscopy. It was found that the ...
A new technique for measuring adsorption on non-noble metals
(Elsevier, 1974)
A new technique for measuring adsorption on non-noble metals is presented here on the basis of former experimental results and experience.
On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
(Elsevier, 1977)
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange ...