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Structural effects in electrocatalysis. Oxidation of D-glucose on single crystal platinum electrodes in alkaline solution
(Elsevier, 1991)
Electrochemical oxidation of D-glucose has been studied in 0.1 M NaOH on single crystal platinum electrodes with thirteen different orientations. The reaction rate depends strongly on the crystallographic orientation of ...
Oscillatory phenomena in oxygen and hydrogen peroxide reduction on the Au(100) electrode surface in alkaline solutions
(Elsevier, 1992)
In this work we report preliminary data for oscillatory behavior found in oxygen and hydrogen peroxide reduction on a rotating gold electrode with (100) orientation in alkaline solutions.
Hydrogen adsorption on single-crystal platinum electrodes in alkaline solutions
(Elsevier, 1992)
Hydrogen adsorption on single-crystal platinum low-index and stepped surfaces was studied in 0.1 M and 0.01 M NaOH solutions. A strong dependence on the crystallographic orientation of the electrode surface was found. The ...
The influence of OH- chemisorption on the catalytic properties of gold single crystal surfaces for oxygen reduction in alkaline solutions
(Elsevier, 1996)
Oxygen reduction on gold single crystal electrodes of various orientations, Au(hkl), in 0.1 M NaOH was studied by rotating disk electrode and rotating disk ring electrode techniques, with a goal to correlate the physical ...
Kinetic and mechanistic study of methanol oxidation on a Pt 100/ surface in alkaline media
(Elsevier, 1998)
A comparative study of methanol oxidation on a Pt(100) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. It was shown that Pt(100) adsorbs OH and 'poisoning species'. ...
A New Approach to Metal Electrodeposition at a Periodically Change Rate. Part I. The Reversing Overpotential Method
(Elsevier, 1999)
A method of increasing the apparent deposition exchange current density value in reversing overpotential (RO) copper electrodeposition is described. In pulsating overpotential (PO) metal electrodeposition, the current ...
The roles of the ruthenium concentration profile, the stabilizing component and the substrate on the stability of oxide coatings
(Elsevier, 1992)
Electrocatalytic oxide coatings with variable concentration profiles of RuO2 as the active component were obtained through a combination of separately applied layers of RuO2, TiO2, IrO2, RuO2 + TiO2 and RuO2 + IrO2 on ...
Electrosorption of hydrogen and sulfuric acid anions on single crystal platinum stepped surfaces. Part II. The [110] zone
(Elsevier, 1991)
Hydrogen and bisulphate adsorption at platinum single crystal surfaces from the [ITO] zone is
strongly dependent on the crystallographic orientation of the electrode surface, which is similar to that
found earlier for ...
The electro-oxidation of glycerol on the gold(100)-oriented single-crystal surface and poly crystalline surface in 0.1 M NaOH
(Elsevier, 1991)
Studies of chemical and electrochemical reactions at well-defined surfaces provide additional data on surface reactivity and guidelines for the understanding and design of catalytic materials. In this work, the oxidation ...
Structural effects in electrocatalysis: oxygen reduction on platinum low index single-crystal surfaces in perchloric acid solutions
(Elsevier, 1994)
Oxygen reduction has been studied in 0.1 M HClO4 on the platinum low index surfaces, employing a hanging meniscus rotating-disk technique. A special cleaning procedure has been developed to remove impurities from the surface ...