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cooperative catalysis
cyclization
dihydropyrane
organopalladium reagents
2016
Bojan Vulovi{\'{c}}
Ivana Mari{\'{c}}
Radomir Matovi{\'{c}}
Radomir N. Sai{\v{c}}i{\'{c}}
D5-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)4. This type of transformation was also accomplished with an aryl ketone.
{Synthesis of vinyldihydropyrane by cooperative catalysis}
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Ivana Mari{\'{c}}
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Radomir N. Sai{\v{c}}i{\'{c}}
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