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Toward enhanced hydrogen production in a catalytic naphtha reforming process

Stijepović, Vladimir; Linke, Patrick; Alnouri, Sabla; Kijevčanin, Mirjana; Grujić, Aleksandar; Stijepović, Mirko Z.

(Oxford : Pergamon-Elsevier Science Ltd, 2012)

TY  - JOUR
AU  - Stijepović, Vladimir
AU  - Linke, Patrick
AU  - Alnouri, Sabla
AU  - Kijevčanin, Mirjana
AU  - Grujić, Aleksandar
AU  - Stijepović, Mirko Z.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/960
AB  - Environmental regulations imposed on transport fuels, especially specifications on sulfur and nitrogen content, generally boost hydrogen requirements in refining industries. The catalytic naphtha reformer (CNR) process is one of the major sources of hydrogen in naphtha refinery, thus improving its hydrogen production would be of great importance for refining industries. Close examination of the reaction kinetics of CNR processes has identified temperature, hydrogen concentration and catalyst activity as key variables affecting the process's performance. In this paper, a new reactor concept is developed that better exploits these process variables. The proposed membrane moving-bed reactor promises to significantly outperform the conventional continuous catalyst regenerative (CCR) design. A case study identifies improvements of 23.6 mol% in hydrogen production, 18.8 mol% in aromatics production. Moreover, the reformate yield was found to increase by 10.6 wt%, while the production of light gases decreases to a value of 18.6 wt%. Copyright
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - International Journal of Hydrogen Energy
T1  - Toward enhanced hydrogen production in a catalytic naphtha reforming process
VL  - 37
IS  - 16
SP  - 11772
EP  - 11784
DO  - 10.1016/j.ijhydene.2012.05.103
ER  - 
@article{
author = "Stijepović, Vladimir and Linke, Patrick and Alnouri, Sabla and Kijevčanin, Mirjana and Grujić, Aleksandar and Stijepović, Mirko Z.",
year = "2012",
abstract = "Environmental regulations imposed on transport fuels, especially specifications on sulfur and nitrogen content, generally boost hydrogen requirements in refining industries. The catalytic naphtha reformer (CNR) process is one of the major sources of hydrogen in naphtha refinery, thus improving its hydrogen production would be of great importance for refining industries. Close examination of the reaction kinetics of CNR processes has identified temperature, hydrogen concentration and catalyst activity as key variables affecting the process's performance. In this paper, a new reactor concept is developed that better exploits these process variables. The proposed membrane moving-bed reactor promises to significantly outperform the conventional continuous catalyst regenerative (CCR) design. A case study identifies improvements of 23.6 mol% in hydrogen production, 18.8 mol% in aromatics production. Moreover, the reformate yield was found to increase by 10.6 wt%, while the production of light gases decreases to a value of 18.6 wt%. Copyright",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "International Journal of Hydrogen Energy",
title = "Toward enhanced hydrogen production in a catalytic naphtha reforming process",
volume = "37",
number = "16",
pages = "11772-11784",
doi = "10.1016/j.ijhydene.2012.05.103"
}
Stijepović, V., Linke, P., Alnouri, S., Kijevčanin, M., Grujić, A.,& Stijepović, M. Z.. (2012). Toward enhanced hydrogen production in a catalytic naphtha reforming process. in International Journal of Hydrogen Energy
Oxford : Pergamon-Elsevier Science Ltd., 37(16), 11772-11784.
https://doi.org/10.1016/j.ijhydene.2012.05.103
Stijepović V, Linke P, Alnouri S, Kijevčanin M, Grujić A, Stijepović MZ. Toward enhanced hydrogen production in a catalytic naphtha reforming process. in International Journal of Hydrogen Energy. 2012;37(16):11772-11784.
doi:10.1016/j.ijhydene.2012.05.103 .
Stijepović, Vladimir, Linke, Patrick, Alnouri, Sabla, Kijevčanin, Mirjana, Grujić, Aleksandar, Stijepović, Mirko Z., "Toward enhanced hydrogen production in a catalytic naphtha reforming process" in International Journal of Hydrogen Energy, 37, no. 16 (2012):11772-11784,
https://doi.org/10.1016/j.ijhydene.2012.05.103 . .
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