@article{
author = "Wang, Lianke and Zlatar, Matija and Vlahović, Filip and Demeshko, Serhiy and Philouze, Christian and Molton, Florian and Gennari, Marcello and Meyer, Franc and Duboc, Carole and Gruden, Maja",
year = "2018",
abstract = "The complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square pyramidal coordinated Fe-III ion. Unusually, all three complexes have intermediate spin ground states. Susceptibility measurements, powder cw X- and Q-band EPR spectra, and zero-field powder Mossbauer spectra show that all complexes display distinct magnetic anisotropy, which has been rationalized by DFT calculations.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Chemistry-A European Journal",
title = "Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes",
volume = "24",
number = "20",
pages = "5091-5094",
doi = "10.1002/chem.201705989"
}