Ministry of Education, Science and Technological Development of the Republic of Serbia - Grant 92166/3-19

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Ministry of Education, Science and Technological Development of the Republic of Serbia - Grant 92166/3-19

Authors

Publications

Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete

Savić, Aleksandar R.; Vlahović, Milica; Martinović, Sanja; Đorđević, Nataša G.; Broćeta, Gordana; Volkov Husović, Tatjana

(International Institute for the Science of Sintering, Beograd, 2020)

TY  - JOUR
AU  - Savić, Aleksandar R.
AU  - Vlahović, Milica
AU  - Martinović, Sanja
AU  - Đorđević, Nataša G.
AU  - Broćeta, Gordana
AU  - Volkov Husović, Tatjana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3764
AB  - This study analyzes the feasibility of valorizing industrial by-product, fly ash from a
thermal power plant as a partial replacement of mineral filler-limestone for the production of
self-compacting concrete (SCC). Three types of SCC mixtures with different portions of fly
ash and the reference mixture with limestone were designed. The synthesized SCCs in the
fresh state were examined for density, entrained air content, flowability (Slump flow, Slump
flow time (t500), V-funnel time (tv)), passing ability (L-box), and segregation resistance,
while hardened state testing included: density, compressive and flexural strength, static
modulus of elasticity, water permeability, resistance against freezing in the presence of deicing salt, and SEM analysis. Taking into account the obtained results it can be concluded
that the addition of fly ash has a positive impact on the concrete properties and that the
optimal content of fly ash is 20 % with respect to the total filler mass
PB  - International Institute for the Science of Sintering, Beograd
T2  - Science of Sintering
T1  - Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete
VL  - 52
IS  - 3
SP  - 307
EP  - 327
DO  - 10.2298/SOS2003307S
ER  - 
@article{
author = "Savić, Aleksandar R. and Vlahović, Milica and Martinović, Sanja and Đorđević, Nataša G. and Broćeta, Gordana and Volkov Husović, Tatjana",
year = "2020",
abstract = "This study analyzes the feasibility of valorizing industrial by-product, fly ash from a
thermal power plant as a partial replacement of mineral filler-limestone for the production of
self-compacting concrete (SCC). Three types of SCC mixtures with different portions of fly
ash and the reference mixture with limestone were designed. The synthesized SCCs in the
fresh state were examined for density, entrained air content, flowability (Slump flow, Slump
flow time (t500), V-funnel time (tv)), passing ability (L-box), and segregation resistance,
while hardened state testing included: density, compressive and flexural strength, static
modulus of elasticity, water permeability, resistance against freezing in the presence of deicing salt, and SEM analysis. Taking into account the obtained results it can be concluded
that the addition of fly ash has a positive impact on the concrete properties and that the
optimal content of fly ash is 20 % with respect to the total filler mass",
publisher = "International Institute for the Science of Sintering, Beograd",
journal = "Science of Sintering",
title = "Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete",
volume = "52",
number = "3",
pages = "307-327",
doi = "10.2298/SOS2003307S"
}
Savić, A. R., Vlahović, M., Martinović, S., Đorđević, N. G., Broćeta, G.,& Volkov Husović, T.. (2020). Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete. in Science of Sintering
International Institute for the Science of Sintering, Beograd., 52(3), 307-327.
https://doi.org/10.2298/SOS2003307S
Savić AR, Vlahović M, Martinović S, Đorđević NG, Broćeta G, Volkov Husović T. Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete. in Science of Sintering. 2020;52(3):307-327.
doi:10.2298/SOS2003307S .
Savić, Aleksandar R., Vlahović, Milica, Martinović, Sanja, Đorđević, Nataša G., Broćeta, Gordana, Volkov Husović, Tatjana, "Valorization of fly ash from a thermal power plant for producing high-performance self-compacting concrete" in Science of Sintering, 52, no. 3 (2020):307-327,
https://doi.org/10.2298/SOS2003307S . .
3
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High temperature materials: properties, demands and applications

Simić, Marko; Alil, Ana; Martinović, Sanja; Vlahović, Milica; Savić, Aleksandar R.; Volkov Husović, Tatjana

(Association of the Chemical Engineers of Serbia, 2020)

TY  - JOUR
AU  - Simić, Marko
AU  - Alil, Ana
AU  - Martinović, Sanja
AU  - Vlahović, Milica
AU  - Savić, Aleksandar R.
AU  - Volkov Husović, Tatjana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3765
AB  - High-temperature materials are used in a wide range of industries and applications such as gas
turbine engines for aircrafts, power and nuclear power plants, different types of furnaces,
including blast furnaces, some fuel cells, industrial gas turbines, different types of reactors,
engines, electronic and lighting devices, and many others. Demands for high-temperature
materials are becoming more and more challenging every year. To perform efficiently,
effectively and at the same time to be economically viable, the materials used at high
temperatures must have certain characteristics that are particularly expected for applying
under such extreme conditions, for example, the strength and thermal resistance. In the
present review, some important requirements that should be satisfied by high temperature
materials will be discussed. Furthermore, the focus is put on refractory concretes, ceramics,
intermetallic alloys, and composites as four different categories of these materials, which are
also considered in respect to possibilities to overcome some of the current challenges.
AB  - U visokotemperaturske materijale spada široki spektar materijala koji se koriste u industriji, za primenu poput turbina za motore i avione, termo i nuklearne elektrane, različite tipove peći uključujući visoku peć, gorivne ćelije, turbine za različiite namene u industriji, razne vrste reaktora, motora, uređaja u elektronici i osvetljenju, kao i mnoge druge. Svake godine zahtevi za visokotemperaturske materijale postaju sve izazovniji. Da bi se ostvarila efikasnost i efektivnost, i da bi se istovremeno postigla ekonomska održivost, materijali koji se koriste na visokim temperaturama moraju zadovoljiti određene zahteve i imati svojstva koja se očekuju u tako ekspremnim uslovima, kao što su, na primer čvrstoća i otpornost na povišene temperature. U ovom preglednom radu razmatrani su neki od značajnih zahteva koji moraju biti zadovoljeni
za visokotemperaturske materijale. Rad se odnosi na vatrostalne betone, keramiku, intermetalne legure i kompozite, kao četiri različite kategorije ove vrste materijala. Navedeni materijali su razmatrani u pogledu mogućnosti prevazilaženja nekih trenutnih izazova.
PB  - Association of the Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - High temperature materials: properties, demands and applications
T1  - Visokotemperaturski materijali: svojstva, zahtevi i primena
VL  - 74
IS  - 4
SP  - 273
EP  - 284
DO  - 10.2298/HEMIND200421019S
ER  - 
@article{
author = "Simić, Marko and Alil, Ana and Martinović, Sanja and Vlahović, Milica and Savić, Aleksandar R. and Volkov Husović, Tatjana",
year = "2020",
abstract = "High-temperature materials are used in a wide range of industries and applications such as gas
turbine engines for aircrafts, power and nuclear power plants, different types of furnaces,
including blast furnaces, some fuel cells, industrial gas turbines, different types of reactors,
engines, electronic and lighting devices, and many others. Demands for high-temperature
materials are becoming more and more challenging every year. To perform efficiently,
effectively and at the same time to be economically viable, the materials used at high
temperatures must have certain characteristics that are particularly expected for applying
under such extreme conditions, for example, the strength and thermal resistance. In the
present review, some important requirements that should be satisfied by high temperature
materials will be discussed. Furthermore, the focus is put on refractory concretes, ceramics,
intermetallic alloys, and composites as four different categories of these materials, which are
also considered in respect to possibilities to overcome some of the current challenges., U visokotemperaturske materijale spada široki spektar materijala koji se koriste u industriji, za primenu poput turbina za motore i avione, termo i nuklearne elektrane, različite tipove peći uključujući visoku peć, gorivne ćelije, turbine za različiite namene u industriji, razne vrste reaktora, motora, uređaja u elektronici i osvetljenju, kao i mnoge druge. Svake godine zahtevi za visokotemperaturske materijale postaju sve izazovniji. Da bi se ostvarila efikasnost i efektivnost, i da bi se istovremeno postigla ekonomska održivost, materijali koji se koriste na visokim temperaturama moraju zadovoljiti određene zahteve i imati svojstva koja se očekuju u tako ekspremnim uslovima, kao što su, na primer čvrstoća i otpornost na povišene temperature. U ovom preglednom radu razmatrani su neki od značajnih zahteva koji moraju biti zadovoljeni
za visokotemperaturske materijale. Rad se odnosi na vatrostalne betone, keramiku, intermetalne legure i kompozite, kao četiri različite kategorije ove vrste materijala. Navedeni materijali su razmatrani u pogledu mogućnosti prevazilaženja nekih trenutnih izazova.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "High temperature materials: properties, demands and applications, Visokotemperaturski materijali: svojstva, zahtevi i primena",
volume = "74",
number = "4",
pages = "273-284",
doi = "10.2298/HEMIND200421019S"
}
Simić, M., Alil, A., Martinović, S., Vlahović, M., Savić, A. R.,& Volkov Husović, T.. (2020). High temperature materials: properties, demands and applications. in Hemijska industrija
Association of the Chemical Engineers of Serbia., 74(4), 273-284.
https://doi.org/10.2298/HEMIND200421019S
Simić M, Alil A, Martinović S, Vlahović M, Savić AR, Volkov Husović T. High temperature materials: properties, demands and applications. in Hemijska industrija. 2020;74(4):273-284.
doi:10.2298/HEMIND200421019S .
Simić, Marko, Alil, Ana, Martinović, Sanja, Vlahović, Milica, Savić, Aleksandar R., Volkov Husović, Tatjana, "High temperature materials: properties, demands and applications" in Hemijska industrija, 74, no. 4 (2020):273-284,
https://doi.org/10.2298/HEMIND200421019S . .
6
1
5

Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela

Martinović, Sanja; Vlahović, Milica; Volkov Husović, Tatjana; Savić, Aleksandar; Milićević, Sonja; Jovanović, Vladimir; Đorđević, Nataša G.

(Zavod za intelektualnu svojinu Republike Srbije, 2020)

TY  - PAT
AU  - Martinović, Sanja
AU  - Vlahović, Milica
AU  - Volkov Husović, Tatjana
AU  - Savić, Aleksandar
AU  - Milićević, Sonja
AU  - Jovanović, Vladimir
AU  - Đorđević, Nataša G.
PY  - 2020
UR  - http://www.zis.gov.rs/informacione-usluge.48.html
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3766
AB  - Stabilizacija teških metala, posebno bakra, iz kiselih otpadnih rudničkih voda izvodi se njihovom solidifikacijom u sumpor polimerni beton kao ekološki prihvatljiv građevinski materijal. Postupak se izvodi tako što se u reakcionom sudu agregat u količini od 56 mas. % zagreva na 160 °C. Zatim se dodaje 5 mas. % letećegpepela iz termoelektrane kao filera i 6 mas. % peleta letećeg pepela sa adsorbovanim teškim metalima iz rudničkih voda. Homogenizovanoj čvrstoj mešavini dodaje se 33 mas. % rastopa elementarnog i modifikovanog sumpora, tzv. sumpor modifikovanog veziva u masenom odnosu 98,2 % elementarnog sumpora i 1,8 % modifikovanog sumpora. Modifikovani sumpor dobijen je mešanjem elementarnog sumpora kao nus-proizvoda iz rafinacije nafte sa diciklopentadienom, na temperaturi od 132-141 °C. Nakon homogenizacije u trajanju od 2 do 5 minuta, dobijena mešavina izliva se u kalupe prethodno zagrejane na 120 °C i vibrira 10 sekundi. Površina ovako dobijene sumpor polimerne betonske mešavine se izravna i ostavi da očvrsne u kalupu na sobnoj temperaturi. Nakon 3 časa očvršćavanja uzorci se vade iz kalupa i neguju na sobnoj temperaturi tokom 24 časa. Dobijeni materijal je nakon ispitivanja pokazao zadovoljavajuće karakteristike potrebne za sve oblasti primene konvencionalnih betona. Ovim postupkom eliminisani su teški metali iz otpadnih rudničkih voda, korišćeni su industrijski nus-proizvodi (leteći pepeo i sumpor), čime su smanjene njihove deponije dok dobijeni materijal ne dovodi do sekundarnog zagađenja životne i stoga se smatra ekološki prihvatljivim.
AB  - Stabilization of heavy metals, especially copper, from acidic mine wastewater is performed by their solidification into sulfur polymer concrete as an environmentally acceptable building material. The procedure is carried out by heating the aggregate in an amount of 56 mass % in a reaction vessel with continuous mixing up to a temperature of 160 °C. Subsequently 5 mass % of fly ash from the thermal power plant is added as a filler and 6 mass % of fly ash pellets with absorbed heavy metals from mine waters. Finally, 33 mass % of the sulfur modified binder, that is mixed melted elemental and modified sulfur in the mass ratio of 98.2 % : 1.8 % is added to the homogenized solid mixture. Modified sulfur is prepared by mixing the elemental sulfur that is by-product of oil refining with dicyclopentadiene at a temperature of 132-141 °C. After the homogenization of the sulfur polymer concrete mixture for 2-5 minutes, the resulting melted mixture is poured into the molds pre-heated to 120 °C and vibrated for 10 seconds. Thus obtained surface of the sulfur polymer concrete mixture is flattened and leave to harden in the mold at room temperature. The samples were removed from the mold after 3 hours of hardening and then cured at room temperature for another 24 hours. After characterization, obtained building material showed satisfactory properties required for all application areas of conventional concrete. By this process, heavy metals from mine wastewater were eliminated, industrial by-products (fly ash and sulfur) were used thus reducing their landfills, while the obtained material does not lead to secondary environmental pollution and therefore is considered as environmentally friendly.
PB  - Zavod za intelektualnu svojinu Republike Srbije
T2  - Glasnik intelektualne svojine
T1  - Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela
T1  - Procedure of solidification and stabilization of heavy metals from mine waste waters adsorbed on fly ash pellets into enviromentally acceptable building material
VL  - 10
SP  - 8
EP  - 9
UR  - https://hdl.handle.net/21.15107/rcub_cer_3766
ER  - 
@misc{
author = "Martinović, Sanja and Vlahović, Milica and Volkov Husović, Tatjana and Savić, Aleksandar and Milićević, Sonja and Jovanović, Vladimir and Đorđević, Nataša G.",
year = "2020",
abstract = "Stabilizacija teških metala, posebno bakra, iz kiselih otpadnih rudničkih voda izvodi se njihovom solidifikacijom u sumpor polimerni beton kao ekološki prihvatljiv građevinski materijal. Postupak se izvodi tako što se u reakcionom sudu agregat u količini od 56 mas. % zagreva na 160 °C. Zatim se dodaje 5 mas. % letećegpepela iz termoelektrane kao filera i 6 mas. % peleta letećeg pepela sa adsorbovanim teškim metalima iz rudničkih voda. Homogenizovanoj čvrstoj mešavini dodaje se 33 mas. % rastopa elementarnog i modifikovanog sumpora, tzv. sumpor modifikovanog veziva u masenom odnosu 98,2 % elementarnog sumpora i 1,8 % modifikovanog sumpora. Modifikovani sumpor dobijen je mešanjem elementarnog sumpora kao nus-proizvoda iz rafinacije nafte sa diciklopentadienom, na temperaturi od 132-141 °C. Nakon homogenizacije u trajanju od 2 do 5 minuta, dobijena mešavina izliva se u kalupe prethodno zagrejane na 120 °C i vibrira 10 sekundi. Površina ovako dobijene sumpor polimerne betonske mešavine se izravna i ostavi da očvrsne u kalupu na sobnoj temperaturi. Nakon 3 časa očvršćavanja uzorci se vade iz kalupa i neguju na sobnoj temperaturi tokom 24 časa. Dobijeni materijal je nakon ispitivanja pokazao zadovoljavajuće karakteristike potrebne za sve oblasti primene konvencionalnih betona. Ovim postupkom eliminisani su teški metali iz otpadnih rudničkih voda, korišćeni su industrijski nus-proizvodi (leteći pepeo i sumpor), čime su smanjene njihove deponije dok dobijeni materijal ne dovodi do sekundarnog zagađenja životne i stoga se smatra ekološki prihvatljivim., Stabilization of heavy metals, especially copper, from acidic mine wastewater is performed by their solidification into sulfur polymer concrete as an environmentally acceptable building material. The procedure is carried out by heating the aggregate in an amount of 56 mass % in a reaction vessel with continuous mixing up to a temperature of 160 °C. Subsequently 5 mass % of fly ash from the thermal power plant is added as a filler and 6 mass % of fly ash pellets with absorbed heavy metals from mine waters. Finally, 33 mass % of the sulfur modified binder, that is mixed melted elemental and modified sulfur in the mass ratio of 98.2 % : 1.8 % is added to the homogenized solid mixture. Modified sulfur is prepared by mixing the elemental sulfur that is by-product of oil refining with dicyclopentadiene at a temperature of 132-141 °C. After the homogenization of the sulfur polymer concrete mixture for 2-5 minutes, the resulting melted mixture is poured into the molds pre-heated to 120 °C and vibrated for 10 seconds. Thus obtained surface of the sulfur polymer concrete mixture is flattened and leave to harden in the mold at room temperature. The samples were removed from the mold after 3 hours of hardening and then cured at room temperature for another 24 hours. After characterization, obtained building material showed satisfactory properties required for all application areas of conventional concrete. By this process, heavy metals from mine wastewater were eliminated, industrial by-products (fly ash and sulfur) were used thus reducing their landfills, while the obtained material does not lead to secondary environmental pollution and therefore is considered as environmentally friendly.",
publisher = "Zavod za intelektualnu svojinu Republike Srbije",
journal = "Glasnik intelektualne svojine",
title = "Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela, Procedure of solidification and stabilization of heavy metals from mine waste waters adsorbed on fly ash pellets into enviromentally acceptable building material",
volume = "10",
pages = "8-9",
url = "https://hdl.handle.net/21.15107/rcub_cer_3766"
}
Martinović, S., Vlahović, M., Volkov Husović, T., Savić, A., Milićević, S., Jovanović, V.,& Đorđević, N. G.. (2020). Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela. in Glasnik intelektualne svojine
Zavod za intelektualnu svojinu Republike Srbije., 10, 8-9.
https://hdl.handle.net/21.15107/rcub_cer_3766
Martinović S, Vlahović M, Volkov Husović T, Savić A, Milićević S, Jovanović V, Đorđević NG. Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela. in Glasnik intelektualne svojine. 2020;10:8-9.
https://hdl.handle.net/21.15107/rcub_cer_3766 .
Martinović, Sanja, Vlahović, Milica, Volkov Husović, Tatjana, Savić, Aleksandar, Milićević, Sonja, Jovanović, Vladimir, Đorđević, Nataša G., "Postupak solidifkacije i stabilizacije teških metala iz otpadnih rudničkih voda adsorbovanih na peletama u ekološki prihvatljiv građevinski materijal pepela" in Glasnik intelektualne svojine, 10 (2020):8-9,
https://hdl.handle.net/21.15107/rcub_cer_3766 .