TY  - JOUR
AU  - Pavlović, Pavle
AU  - Marković, M.
AU  - Kostić, Olga
AU  - Sakan, Sanja
AU  - Đorđević, Dragana
AU  - Perović, Veljko
AU  - Pavlović, D.
AU  - Pavlović, Marija
AU  - Čakmak, Dragan
AU  - Jarić, S.
AU  - Paunović, M.
AU  - Mitrović, M.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2499
AB  - Contaminated sediments transported onto the river terrace during high water events can contribute significant quantities of potentially toxic elements to riparian soils. Seven trace elements (As, Cd, Cr, Cu, Ni, Pb and Zn) were analysed in the river sediment and riparian soil of the River Sava and their spatial distribution, potential toxicity and ecological risk levels were evaluated. The results showed that levels of all the trace metals were enriched to varying extents in both the sediment (As, Cr, Ni, and Pb) and soil (Ni) when compared to reference levels for sediments and European soils. Mean concentrations of trace metals in sediment and soil, apart from Pb, increased downstream in the River Sava. The similar increasing trend of these elements in sediment and soil may be explained by their increased load due to anthropogenic pressures (As, Cr, Ni, Pb and Zn in sediment and the significant accumulation of Ni in soil) and frequent periodic flooding (As, Cd, Cr, Cu, Ni and Zn in sediment and Cd in soil are influenced by both high water events and natural factors such as the geological substrate), particularly in lowland regions. In this study, soluble As, Cd, Cr, Cu and Ni fractions in sediment and soil  LT 10% indicated their low mobility. The exceptions were readily soluble Pb and Zn in the sediment and soil at some sampling sites. In the lower reaches, levels of Pb in sediment was indicative of a medium environmental hazard, while there was a high environmental hazard in the upper reaches with the average Pb content in sediment higher than the PEL. Pollution factors for Pb in soil indicated a medium environmental hazard in the upper and middle reaches and a high environmental hazard at some sites in the lower stretches of the Sava River, although total Pb content in soil was within the range proposed for European soils.
PB  - Elsevier
T2  - Catena
T1  - Evaluation of potentially toxic element contamination in the riparian zone of the River Sava
VL  - 174
SP  - 399
EP  - 412
DO  - 10.1016/j.catena.2018.11.034
ER  - 

@article{
author = "Pavlović, Pavle and Marković, M. and Kostić, Olga and Sakan, Sanja and Đorđević, Dragana and Perović, Veljko and Pavlović, D. and Pavlović, Marija and Čakmak, Dragan and Jarić, S. and Paunović, M. and Mitrović, M.",
year = "2019",
abstract = "Contaminated sediments transported onto the river terrace during high water events can contribute significant quantities of potentially toxic elements to riparian soils. Seven trace elements (As, Cd, Cr, Cu, Ni, Pb and Zn) were analysed in the river sediment and riparian soil of the River Sava and their spatial distribution, potential toxicity and ecological risk levels were evaluated. The results showed that levels of all the trace metals were enriched to varying extents in both the sediment (As, Cr, Ni, and Pb) and soil (Ni) when compared to reference levels for sediments and European soils. Mean concentrations of trace metals in sediment and soil, apart from Pb, increased downstream in the River Sava. The similar increasing trend of these elements in sediment and soil may be explained by their increased load due to anthropogenic pressures (As, Cr, Ni, Pb and Zn in sediment and the significant accumulation of Ni in soil) and frequent periodic flooding (As, Cd, Cr, Cu, Ni and Zn in sediment and Cd in soil are influenced by both high water events and natural factors such as the geological substrate), particularly in lowland regions. In this study, soluble As, Cd, Cr, Cu and Ni fractions in sediment and soil  LT 10% indicated their low mobility. The exceptions were readily soluble Pb and Zn in the sediment and soil at some sampling sites. In the lower reaches, levels of Pb in sediment was indicative of a medium environmental hazard, while there was a high environmental hazard in the upper reaches with the average Pb content in sediment higher than the PEL. Pollution factors for Pb in soil indicated a medium environmental hazard in the upper and middle reaches and a high environmental hazard at some sites in the lower stretches of the Sava River, although total Pb content in soil was within the range proposed for European soils.",
publisher = "Elsevier",
journal = "Catena",
title = "Evaluation of potentially toxic element contamination in the riparian zone of the River Sava",
volume = "174",
pages = "399-412",
doi = "10.1016/j.catena.2018.11.034"
}

Pavlović, P., Marković, M., Kostić, O., Sakan, S., Đorđević, D., Perović, V., Pavlović, D., Pavlović, M., Čakmak, D., Jarić, S., Paunović, M.,& Mitrović, M.. (2019). Evaluation of potentially toxic element contamination in the riparian zone of the River Sava. in Catena
Elsevier., 174, 399-412.
https://doi.org/10.1016/j.catena.2018.11.034

Pavlović P, Marković M, Kostić O, Sakan S, Đorđević D, Perović V, Pavlović D, Pavlović M, Čakmak D, Jarić S, Paunović M, Mitrović M. Evaluation of potentially toxic element contamination in the riparian zone of the River Sava. in Catena. 2019;174:399-412.
doi:10.1016/j.catena.2018.11.034 .

Pavlović, Pavle, Marković, M., Kostić, Olga, Sakan, Sanja, Đorđević, Dragana, Perović, Veljko, Pavlović, D., Pavlović, Marija, Čakmak, Dragan, Jarić, S., Paunović, M., Mitrović, M., "Evaluation of potentially toxic element contamination in the riparian zone of the River Sava" in Catena, 174 (2019):399-412,
https://doi.org/10.1016/j.catena.2018.11.034 . .

TY  - JOUR
AU  - Egerić, Marija
AU  - Smičiklas, Ivana
AU  - Dojčinović, Biljana
AU  - Sikirić, Biljana
AU  - Jović, Mihajlo
AU  - Šljivić-Ivanović, Marija
AU  - Čakmak, Dragan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3125
AB  - Liming is a common practice in the treatment of acidic and metal contaminated soils, aiming at pH regulation, enhancing of the nutrient availability and attenuation of trace metals mobility. Replacement of natural limestone with alternative soil alkalizers found among waste materials represents a step towards sustainable resource management and reduced waste storage. In this study, waste seashells (SW) and red mud (RM) were applied in different doses to the soil sampled in the vicinity of mining and smelting complex. The soil was characterized by acidic reaction (pH 4.93), increased Cu concentration (219.2 mg/kg) and a very low level of P-supply (3.61 mg P2O5/100 g). The study aimed to quantify and compare additive-induced effects onto soil physicochemical properties, the status of macronutrients and distribution of trace metals. Targeted effect on soil pH was achieved with SW dose of 0.3% and RM dose of 2%. RM was found to be a source of available P and gave rise to the available P concentrations in the soil. Medium level of P-supply (15.60 mg P2O5/100 g) was achieved with RM dose of 5%, however, the increase in soil salinity and total trace elements concentrations have become significant adverse effects at such dose. The decrease in the ion-exchangeable content of Cu and other trace metals was in correlation with the increase in soil pH after the treatments. Redistribution of metal cations was mainly directed to carbonate/acid soluble and Fe, Mn-oxide bonded fraction after SW addition. Even though trace metals concentration has increased in the soil after application of the RM, they were principally found in the residual fraction. The results emphasize low amounts of contained trace elements and lower doses for achieving targeted effects on pH and metal mobility as the main benefits of SW treatments. On the other hand, moderate and controlled use of RM may represent multiple benefits in terms of simultaneous pH regulation, P-supply, and reduced trace metals mobility.
PB  - Elsevier
T2  - Geoderma
T1  - Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives
VL  - 352
SP  - 241
EP  - 250
DO  - 10.1016/j.geoderma.2019.06.015
ER  - 

@article{
author = "Egerić, Marija and Smičiklas, Ivana and Dojčinović, Biljana and Sikirić, Biljana and Jović, Mihajlo and Šljivić-Ivanović, Marija and Čakmak, Dragan",
year = "2019",
abstract = "Liming is a common practice in the treatment of acidic and metal contaminated soils, aiming at pH regulation, enhancing of the nutrient availability and attenuation of trace metals mobility. Replacement of natural limestone with alternative soil alkalizers found among waste materials represents a step towards sustainable resource management and reduced waste storage. In this study, waste seashells (SW) and red mud (RM) were applied in different doses to the soil sampled in the vicinity of mining and smelting complex. The soil was characterized by acidic reaction (pH 4.93), increased Cu concentration (219.2 mg/kg) and a very low level of P-supply (3.61 mg P2O5/100 g). The study aimed to quantify and compare additive-induced effects onto soil physicochemical properties, the status of macronutrients and distribution of trace metals. Targeted effect on soil pH was achieved with SW dose of 0.3% and RM dose of 2%. RM was found to be a source of available P and gave rise to the available P concentrations in the soil. Medium level of P-supply (15.60 mg P2O5/100 g) was achieved with RM dose of 5%, however, the increase in soil salinity and total trace elements concentrations have become significant adverse effects at such dose. The decrease in the ion-exchangeable content of Cu and other trace metals was in correlation with the increase in soil pH after the treatments. Redistribution of metal cations was mainly directed to carbonate/acid soluble and Fe, Mn-oxide bonded fraction after SW addition. Even though trace metals concentration has increased in the soil after application of the RM, they were principally found in the residual fraction. The results emphasize low amounts of contained trace elements and lower doses for achieving targeted effects on pH and metal mobility as the main benefits of SW treatments. On the other hand, moderate and controlled use of RM may represent multiple benefits in terms of simultaneous pH regulation, P-supply, and reduced trace metals mobility.",
publisher = "Elsevier",
journal = "Geoderma",
title = "Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives",
volume = "352",
pages = "241-250",
doi = "10.1016/j.geoderma.2019.06.015"
}

Egerić, M., Smičiklas, I., Dojčinović, B., Sikirić, B., Jović, M., Šljivić-Ivanović, M.,& Čakmak, D.. (2019). Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives. in Geoderma
Elsevier., 352, 241-250.
https://doi.org/10.1016/j.geoderma.2019.06.015

Egerić M, Smičiklas I, Dojčinović B, Sikirić B, Jović M, Šljivić-Ivanović M, Čakmak D. Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives. in Geoderma. 2019;352:241-250.
doi:10.1016/j.geoderma.2019.06.015 .

Egerić, Marija, Smičiklas, Ivana, Dojčinović, Biljana, Sikirić, Biljana, Jović, Mihajlo, Šljivić-Ivanović, Marija, Čakmak, Dragan, "Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives" in Geoderma, 352 (2019):241-250,
https://doi.org/10.1016/j.geoderma.2019.06.015 . .

TY  - JOUR
AU  - Pavlović, Dragana
AU  - Pavlović, Marija
AU  - Čakmak, Dragan
AU  - Kostić, Olga
AU  - Jaric, Snezana
AU  - Sakan, Sanja
AU  - Đorđević, Dragana
AU  - Mitrovic, Miroslava
AU  - Gržetić, Ivan
AU  - Pavlović, Pavle
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2433
AB  - The main soil properties, concentrations of selected elements (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn), and the chemical speciation of each element were determined in urban soil samples taken from urban parks in four Serbian cities (Belgrade, Panevo, Obrenovac, and Smederevo) exposed to different sources of pollution. Pollution indices (PI, PIN) and factors (MF, ICF, GCF) also were evaluated. The study revealed As and Cd concentrations below the detection limit, whereas the content of Cr, Cu, Fe, Mn, Ni, Pb, and Zn at some sites exceeded the limits established by local regulations, as well as the background values, which may represent an environmental threat. Sequential extraction results show that Fe, Cr, Cu, and Ni were predominantly in the residual fraction at most sites; however, Ni from Panevo and Smederevo also was bound to the reducible fraction. The presence of Pb at all sites and Zn in Smederevo and Belgrade was mainly associated with the reducible and residual fractions. The highest Mn content was found in the reducible fraction, followed by the acid soluble/exchangeable and residual fractions. Based on the obtained indices and factors, the overall soil status at the selected sampling sites was found to range from the warning limit to slightly polluted, whereby Smederevo had the highest risk, and Panevo and the control site the lowest risk of contamination by toxic metals.
PB  - Springer, New York
T2  - Archives of Environmental Contamination and Toxicology
T1  - Fractionation, Mobility, and Contamination Assessment of Potentially Toxic Metals in Urban Soils in Four Industrial Serbian Cities
VL  - 75
IS  - 3
SP  - 335
EP  - 350
DO  - 10.1007/s00244-018-0518-x
ER  - 

@article{
author = "Pavlović, Dragana and Pavlović, Marija and Čakmak, Dragan and Kostić, Olga and Jaric, Snezana and Sakan, Sanja and Đorđević, Dragana and Mitrovic, Miroslava and Gržetić, Ivan and Pavlović, Pavle",
year = "2018",
abstract = "The main soil properties, concentrations of selected elements (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn), and the chemical speciation of each element were determined in urban soil samples taken from urban parks in four Serbian cities (Belgrade, Panevo, Obrenovac, and Smederevo) exposed to different sources of pollution. Pollution indices (PI, PIN) and factors (MF, ICF, GCF) also were evaluated. The study revealed As and Cd concentrations below the detection limit, whereas the content of Cr, Cu, Fe, Mn, Ni, Pb, and Zn at some sites exceeded the limits established by local regulations, as well as the background values, which may represent an environmental threat. Sequential extraction results show that Fe, Cr, Cu, and Ni were predominantly in the residual fraction at most sites; however, Ni from Panevo and Smederevo also was bound to the reducible fraction. The presence of Pb at all sites and Zn in Smederevo and Belgrade was mainly associated with the reducible and residual fractions. The highest Mn content was found in the reducible fraction, followed by the acid soluble/exchangeable and residual fractions. Based on the obtained indices and factors, the overall soil status at the selected sampling sites was found to range from the warning limit to slightly polluted, whereby Smederevo had the highest risk, and Panevo and the control site the lowest risk of contamination by toxic metals.",
publisher = "Springer, New York",
journal = "Archives of Environmental Contamination and Toxicology",
title = "Fractionation, Mobility, and Contamination Assessment of Potentially Toxic Metals in Urban Soils in Four Industrial Serbian Cities",
volume = "75",
number = "3",
pages = "335-350",
doi = "10.1007/s00244-018-0518-x"
}

Pavlović, D., Pavlović, M., Čakmak, D., Kostić, O., Jaric, S., Sakan, S., Đorđević, D., Mitrovic, M., Gržetić, I.,& Pavlović, P.. (2018). Fractionation, Mobility, and Contamination Assessment of Potentially Toxic Metals in Urban Soils in Four Industrial Serbian Cities. in Archives of Environmental Contamination and Toxicology
Springer, New York., 75(3), 335-350.
https://doi.org/10.1007/s00244-018-0518-x

Pavlović D, Pavlović M, Čakmak D, Kostić O, Jaric S, Sakan S, Đorđević D, Mitrovic M, Gržetić I, Pavlović P. Fractionation, Mobility, and Contamination Assessment of Potentially Toxic Metals in Urban Soils in Four Industrial Serbian Cities. in Archives of Environmental Contamination and Toxicology. 2018;75(3):335-350.
doi:10.1007/s00244-018-0518-x .

Pavlović, Dragana, Pavlović, Marija, Čakmak, Dragan, Kostić, Olga, Jaric, Snezana, Sakan, Sanja, Đorđević, Dragana, Mitrovic, Miroslava, Gržetić, Ivan, Pavlović, Pavle, "Fractionation, Mobility, and Contamination Assessment of Potentially Toxic Metals in Urban Soils in Four Industrial Serbian Cities" in Archives of Environmental Contamination and Toxicology, 75, no. 3 (2018):335-350,
https://doi.org/10.1007/s00244-018-0518-x . .

TY  - JOUR
AU  - Pavlović, Pavle
AU  - Mitrovic, Miroslava
AU  - Đorđević, Dragana
AU  - Sakan, Sanja
AU  - Slobodnik, J
AU  - Liska, I
AU  - Csanyi, B
AU  - Jaric, S
AU  - Kostić, Olga
AU  - Pavlovic, D
AU  - Marinković, N. S.
AU  - Tubic, B
AU  - Paunović, M.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1999
AB  - The aim of this study was to assess the spatial distribution of arsenic and heavy metals (Cd, Cr, Cu Hg, Ni, Pb and Zn) in a riparian area influenced by periodical flooding along a considerable stretch of the Danube River. This screening was undertaken on soil and plant samples collected from 43 sites along 2386 km of the river, collected during the international Joint Danube Survey 3 expedition (ICPDR, 2015). In addition, data on the concentration of these elements in river sediment was used in order to describe the relationship between sediment, riparian soil and riparian plants. A significant positive correlation (Spearman r, for p  LT  0.05) was found for trace metal concentrations in river sediment and soil (r = 0.817). A significant correlation between soil and plants (r = 0.438) and sediment and plants (r = 0.412) was also found for trace metal concentrations. Elevated levels of Cd, Cr, Cu, and Ni were found at certain sites along the Serbian stretch, while elevated concentrations of Hg were also detected in Hungary, of Pb along the Romanian stretch and of As along the Bulgarian stretch (the Lower Danube). These results point to the presence of naturally-occurring metals derived from ore deposits in the Danube River Basin and anthropogenic metals, released by mining and processing of metal ores and other industrial facilities, which are responsible for the entry of metals such as Cu, Ni and Zn. Our results also indicated toxic Cd and Zn levels in plant samples, measured at the Hercegsznato site (Middle Danube, Hungary), which highlighted these elements as a potential limiting factor for riparian vegetation in that area. The distribution of the analysed elements in plant material also indicates the species-specific accumulation of trace metals. Based on our results, the Lower and Middle Danube were found to be more polluted in terms of the analysed elements.
PB  - Elsevier
T2  - Science of the Total Environment
T1  - Assessment of the contamination of riparian soil and vegetation by trace metals - A Danube River case study
VL  - 540
SP  - 396
EP  - 409
DO  - 10.1016/j.scitotenv.2015.06.125
ER  - 

@article{
author = "Pavlović, Pavle and Mitrovic, Miroslava and Đorđević, Dragana and Sakan, Sanja and Slobodnik, J and Liska, I and Csanyi, B and Jaric, S and Kostić, Olga and Pavlovic, D and Marinković, N. S. and Tubic, B and Paunović, M.",
year = "2016",
abstract = "The aim of this study was to assess the spatial distribution of arsenic and heavy metals (Cd, Cr, Cu Hg, Ni, Pb and Zn) in a riparian area influenced by periodical flooding along a considerable stretch of the Danube River. This screening was undertaken on soil and plant samples collected from 43 sites along 2386 km of the river, collected during the international Joint Danube Survey 3 expedition (ICPDR, 2015). In addition, data on the concentration of these elements in river sediment was used in order to describe the relationship between sediment, riparian soil and riparian plants. A significant positive correlation (Spearman r, for p  LT  0.05) was found for trace metal concentrations in river sediment and soil (r = 0.817). A significant correlation between soil and plants (r = 0.438) and sediment and plants (r = 0.412) was also found for trace metal concentrations. Elevated levels of Cd, Cr, Cu, and Ni were found at certain sites along the Serbian stretch, while elevated concentrations of Hg were also detected in Hungary, of Pb along the Romanian stretch and of As along the Bulgarian stretch (the Lower Danube). These results point to the presence of naturally-occurring metals derived from ore deposits in the Danube River Basin and anthropogenic metals, released by mining and processing of metal ores and other industrial facilities, which are responsible for the entry of metals such as Cu, Ni and Zn. Our results also indicated toxic Cd and Zn levels in plant samples, measured at the Hercegsznato site (Middle Danube, Hungary), which highlighted these elements as a potential limiting factor for riparian vegetation in that area. The distribution of the analysed elements in plant material also indicates the species-specific accumulation of trace metals. Based on our results, the Lower and Middle Danube were found to be more polluted in terms of the analysed elements.",
publisher = "Elsevier",
journal = "Science of the Total Environment",
title = "Assessment of the contamination of riparian soil and vegetation by trace metals - A Danube River case study",
volume = "540",
pages = "396-409",
doi = "10.1016/j.scitotenv.2015.06.125"
}

Pavlović, P., Mitrovic, M., Đorđević, D., Sakan, S., Slobodnik, J., Liska, I., Csanyi, B., Jaric, S., Kostić, O., Pavlovic, D., Marinković, N. S., Tubic, B.,& Paunović, M.. (2016). Assessment of the contamination of riparian soil and vegetation by trace metals - A Danube River case study. in Science of the Total Environment
Elsevier., 540, 396-409.
https://doi.org/10.1016/j.scitotenv.2015.06.125

Pavlović P, Mitrovic M, Đorđević D, Sakan S, Slobodnik J, Liska I, Csanyi B, Jaric S, Kostić O, Pavlovic D, Marinković NS, Tubic B, Paunović M. Assessment of the contamination of riparian soil and vegetation by trace metals - A Danube River case study. in Science of the Total Environment. 2016;540:396-409.
doi:10.1016/j.scitotenv.2015.06.125 .

Pavlović, Pavle, Mitrovic, Miroslava, Đorđević, Dragana, Sakan, Sanja, Slobodnik, J, Liska, I, Csanyi, B, Jaric, S, Kostić, Olga, Pavlovic, D, Marinković, N. S., Tubic, B, Paunović, M., "Assessment of the contamination of riparian soil and vegetation by trace metals - A Danube River case study" in Science of the Total Environment, 540 (2016):396-409,
https://doi.org/10.1016/j.scitotenv.2015.06.125 . .