Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy - DE-AC02-05CH11231

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Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy - DE-AC02-05CH11231

Authors

Publications

Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy

Radetić, Tamara; Popović, M.; Jegdić, Bore; Romhanji, E.

(Wiley, 2016)

TY  - JOUR
AU  - Radetić, Tamara
AU  - Popović, M.
AU  - Jegdić, Bore
AU  - Romhanji, E.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4382
AB  - Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.
PB  - Wiley
T2  - Materials and Corrosion-Werkstoffe Und Korrosion
T1  - Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy
VL  - 67
IS  - 8
SP  - 867
EP  - 875
DO  - 10.1002/maco.201508709
ER  - 
@article{
author = "Radetić, Tamara and Popović, M. and Jegdić, Bore and Romhanji, E.",
year = "2016",
abstract = "Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.",
publisher = "Wiley",
journal = "Materials and Corrosion-Werkstoffe Und Korrosion",
title = "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy",
volume = "67",
number = "8",
pages = "867-875",
doi = "10.1002/maco.201508709"
}
Radetić, T., Popović, M., Jegdić, B.,& Romhanji, E.. (2016). Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion
Wiley., 67(8), 867-875.
https://doi.org/10.1002/maco.201508709
Radetić T, Popović M, Jegdić B, Romhanji E. Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion. 2016;67(8):867-875.
doi:10.1002/maco.201508709 .
Radetić, Tamara, Popović, M., Jegdić, Bore, Romhanji, E., "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy" in Materials and Corrosion-Werkstoffe Und Korrosion, 67, no. 8 (2016):867-875,
https://doi.org/10.1002/maco.201508709 . .
6
4
6

Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy

Radetić, Tamara; Popović, M.; Jegdić, Bore; Romhanji, E.

(Wiley, 2016)

TY  - JOUR
AU  - Radetić, Tamara
AU  - Popović, M.
AU  - Jegdić, Bore
AU  - Romhanji, E.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1919
AB  - Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.
PB  - Wiley
T2  - Materials and Corrosion-Werkstoffe Und Korrosion
T1  - Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy
VL  - 67
IS  - 8
SP  - 867
EP  - 875
DO  - 10.1002/maco.201508709
ER  - 
@article{
author = "Radetić, Tamara and Popović, M. and Jegdić, Bore and Romhanji, E.",
year = "2016",
abstract = "Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC susceptibility. Microstructural characterization shows fine precipitation of Mg-rich phase forming nearly continuous film at grain boundaries, despite small precipitated fraction (0.5%), and grain boundary faceting. Sensitised specimens annealed at 265 degrees C are IGC susceptible, but SCC resistant. Precipitation at grain boundaries is discrete, although the precipitated fraction is greater (3%) than in specimens annealed at 320 degrees C. Potentiodynamic measurements show that of all measured parameters, charge density is in the strongest correlation with the NAMLT and SSRT results.",
publisher = "Wiley",
journal = "Materials and Corrosion-Werkstoffe Und Korrosion",
title = "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy",
volume = "67",
number = "8",
pages = "867-875",
doi = "10.1002/maco.201508709"
}
Radetić, T., Popović, M., Jegdić, B.,& Romhanji, E.. (2016). Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion
Wiley., 67(8), 867-875.
https://doi.org/10.1002/maco.201508709
Radetić T, Popović M, Jegdić B, Romhanji E. Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy. in Materials and Corrosion-Werkstoffe Und Korrosion. 2016;67(8):867-875.
doi:10.1002/maco.201508709 .
Radetić, Tamara, Popović, M., Jegdić, Bore, Romhanji, E., "Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy" in Materials and Corrosion-Werkstoffe Und Korrosion, 67, no. 8 (2016):867-875,
https://doi.org/10.1002/maco.201508709 . .
6
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6

RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation

Obradović, Maja; Lačnjevac, Uroš; Babic, B M; Ercius, P; Radmilović, Velimir R.; Krstajić, Nedeljko V.; Gojković, Snežana Lj.

(Elsevier, 2015)

TY  - JOUR
AU  - Obradović, Maja
AU  - Lačnjevac, Uroš
AU  - Babic, B M
AU  - Ercius, P
AU  - Radmilović, Velimir R.
AU  - Krstajić, Nedeljko V.
AU  - Gojković, Snežana Lj.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1763
AB  - Two binary Ru-Ti oxides, Rum Ti0.9O2 and Ru0.7Ti0.3O2, were synthesized by the sol-gel method and used as an electrocatalyst support. The system was characterized by XRD, EDS, TEM and cyclic voltammetry. The Rum Ti0.9O2 and Ru0.7Ti0.3O2 consist of two phases of anatase and rutile structure. An average size of the Pt nanoparticles supported on them is similar to 3.5 nm and they are deposited on both Ru and Ti-rich domains. The supports exhibited good conductivity and electrochemical stability. The onset potentials of COads oxidation on the synthesized catalysts and on commercial PtRu/C are similar to each other and lower than that on Pt/C. This suggests that in Pt/Rum Ti0.9O2 and Pt/Ru0(.7)Ti(0.3)O(2) the Pt nanoparticles are in close contact with Ru atoms from the support, which enables the bifunctional mechanism. The activity and stability of the catalysts for methanol oxidation were examined under potentiodynamic and potentiostatic conditions. While the activity of Pt/Rum Ti0.9O2 is unsatisfactory, the performance of Pt/Ru0.7Ti0.3O2 is comparable to PtRu/C. For example, in the potentiostatic test at 0.5 V the activities after 25 min are 0.035 mA cm(-2) and 0.022 mA cm(-2) for Pt/Ru0.7Ti0.3O2 and PtRu/C, respectively. In potentiodynamic test the activities at 0.5V after 250 cycles are around 0.02 mA cm(-2) for both catalysts.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation
VL  - 170
SP  - 144
EP  - 152
DO  - 10.1016/j.apcatb.2015.01.038
ER  - 
@article{
author = "Obradović, Maja and Lačnjevac, Uroš and Babic, B M and Ercius, P and Radmilović, Velimir R. and Krstajić, Nedeljko V. and Gojković, Snežana Lj.",
year = "2015",
abstract = "Two binary Ru-Ti oxides, Rum Ti0.9O2 and Ru0.7Ti0.3O2, were synthesized by the sol-gel method and used as an electrocatalyst support. The system was characterized by XRD, EDS, TEM and cyclic voltammetry. The Rum Ti0.9O2 and Ru0.7Ti0.3O2 consist of two phases of anatase and rutile structure. An average size of the Pt nanoparticles supported on them is similar to 3.5 nm and they are deposited on both Ru and Ti-rich domains. The supports exhibited good conductivity and electrochemical stability. The onset potentials of COads oxidation on the synthesized catalysts and on commercial PtRu/C are similar to each other and lower than that on Pt/C. This suggests that in Pt/Rum Ti0.9O2 and Pt/Ru0(.7)Ti(0.3)O(2) the Pt nanoparticles are in close contact with Ru atoms from the support, which enables the bifunctional mechanism. The activity and stability of the catalysts for methanol oxidation were examined under potentiodynamic and potentiostatic conditions. While the activity of Pt/Rum Ti0.9O2 is unsatisfactory, the performance of Pt/Ru0.7Ti0.3O2 is comparable to PtRu/C. For example, in the potentiostatic test at 0.5 V the activities after 25 min are 0.035 mA cm(-2) and 0.022 mA cm(-2) for Pt/Ru0.7Ti0.3O2 and PtRu/C, respectively. In potentiodynamic test the activities at 0.5V after 250 cycles are around 0.02 mA cm(-2) for both catalysts.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation",
volume = "170",
pages = "144-152",
doi = "10.1016/j.apcatb.2015.01.038"
}
Obradović, M., Lačnjevac, U., Babic, B. M., Ercius, P., Radmilović, V. R., Krstajić, N. V.,& Gojković, S. Lj.. (2015). RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation. in Applied Catalysis B-Environmental
Elsevier., 170, 144-152.
https://doi.org/10.1016/j.apcatb.2015.01.038
Obradović M, Lačnjevac U, Babic BM, Ercius P, Radmilović VR, Krstajić NV, Gojković SL. RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation. in Applied Catalysis B-Environmental. 2015;170:144-152.
doi:10.1016/j.apcatb.2015.01.038 .
Obradović, Maja, Lačnjevac, Uroš, Babic, B M, Ercius, P, Radmilović, Velimir R., Krstajić, Nedeljko V., Gojković, Snežana Lj., "RuxTi1-xO2 as the support for Pt nanoparticles: Electrocatalysis of methanol oxidation" in Applied Catalysis B-Environmental, 170 (2015):144-152,
https://doi.org/10.1016/j.apcatb.2015.01.038 . .
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20
23

Randomly oriented twin domains in electrodeposited silver dendrites

Ivanović, Evica; Nikolić, Nebojša D.; Radmilović, Velimir R.

(Serbian Chemical Society, 2015)

TY  - JOUR
AU  - Ivanović, Evica
AU  - Nikolić, Nebojša D.
AU  - Radmilović, Velimir R.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1738
AB  - Silver dendrites were prepared by electrochemical deposition. The structures of the Ag dendrites, the type of twins and their distribution were investigated by scanning electron microscopy (SEM), Z-contrast high angle annular dark field transmission electron microscopy (HAADF), and crystallographically sensitive orientation imaging microscopy (OIM). The results revealed that the silver dendrites were characterized by the presence of randomly distributed 180 degrees rotational twin domains. The broad surface of dendrites was of the {111} type. The directions of growth of the main dendrite stem and all branches were of the  LT 112> type.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Randomly oriented twin domains in electrodeposited silver dendrites
VL  - 80
IS  - 1
SP  - 107
EP  - 113
DO  - 10.2298/JSC140306045I
ER  - 
@article{
author = "Ivanović, Evica and Nikolić, Nebojša D. and Radmilović, Velimir R.",
year = "2015",
abstract = "Silver dendrites were prepared by electrochemical deposition. The structures of the Ag dendrites, the type of twins and their distribution were investigated by scanning electron microscopy (SEM), Z-contrast high angle annular dark field transmission electron microscopy (HAADF), and crystallographically sensitive orientation imaging microscopy (OIM). The results revealed that the silver dendrites were characterized by the presence of randomly distributed 180 degrees rotational twin domains. The broad surface of dendrites was of the {111} type. The directions of growth of the main dendrite stem and all branches were of the  LT 112> type.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Randomly oriented twin domains in electrodeposited silver dendrites",
volume = "80",
number = "1",
pages = "107-113",
doi = "10.2298/JSC140306045I"
}
Ivanović, E., Nikolić, N. D.,& Radmilović, V. R.. (2015). Randomly oriented twin domains in electrodeposited silver dendrites. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 80(1), 107-113.
https://doi.org/10.2298/JSC140306045I
Ivanović E, Nikolić ND, Radmilović VR. Randomly oriented twin domains in electrodeposited silver dendrites. in Journal of the Serbian Chemical Society. 2015;80(1):107-113.
doi:10.2298/JSC140306045I .
Ivanović, Evica, Nikolić, Nebojša D., Radmilović, Velimir R., "Randomly oriented twin domains in electrodeposited silver dendrites" in Journal of the Serbian Chemical Society, 80, no. 1 (2015):107-113,
https://doi.org/10.2298/JSC140306045I . .
1
8
5
2

Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation

Obradović, Maja; Babić, Biljana M.; Radmilović, Velimir R.; Krstajić, Nedeljko V.; Gojković, Snežana Lj.

(Oxford : Pergamon-Elsevier Science Ltd, 2012)

TY  - JOUR
AU  - Obradović, Maja
AU  - Babić, Biljana M.
AU  - Radmilović, Velimir R.
AU  - Krstajić, Nedeljko V.
AU  - Gojković, Snežana Lj.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/977
AB  - Tungsten carbide was synthesized by calcination of carbon cryogel containing tungsten in a form of metatungstate. Characterization by X-ray diffraction and transmission electron microscopy indicated core-shell structure of the particles with tungsten core and tungsten carbide shell, attached to graphitized carbon. Pt nanoparticles were deposited on this material and most of them were nucleated on tungsten carbide. Cyclic voltammetry of W-C support and Pt/W-C catalyst indicated hydrogen intercalation in surface hydrous tungsten oxide. Oxidation of COads on Pt/W-C commences earlier than on Pt/C for about 100 mV. The onset potentials of MOR on Pt/W-C and Pt/C are the same, but at more positive potentials Pt/W-C catalyst is more active. It was proposed that promotion of MOR is based on bifunctional mechanism that facilitates COads removal. Stability test was performed by potential cycling of Pt/W-C and Pt/C in the supporting electrolyte and in the presence of methanol. Pt surface area loss observed in the supporting electrolyte of both catalysts after 250 cycles was about 20%. Decrease in the activity for methanol oxidation was 30% for Pt/W-C, but even 48% for Pt/C. The difference was explained by the presence of hydrous tungsten oxide on Pt in Pt/W-C catalyst, which reduces accumulation of poisoning COads. Copyright
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - International Journal of Hydrogen Energy
T1  - Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation
VL  - 37
IS  - 14
SP  - 10671
EP  - 10679
DO  - 10.1016/j.ijhydene.2012.04.114
ER  - 
@article{
author = "Obradović, Maja and Babić, Biljana M. and Radmilović, Velimir R. and Krstajić, Nedeljko V. and Gojković, Snežana Lj.",
year = "2012",
abstract = "Tungsten carbide was synthesized by calcination of carbon cryogel containing tungsten in a form of metatungstate. Characterization by X-ray diffraction and transmission electron microscopy indicated core-shell structure of the particles with tungsten core and tungsten carbide shell, attached to graphitized carbon. Pt nanoparticles were deposited on this material and most of them were nucleated on tungsten carbide. Cyclic voltammetry of W-C support and Pt/W-C catalyst indicated hydrogen intercalation in surface hydrous tungsten oxide. Oxidation of COads on Pt/W-C commences earlier than on Pt/C for about 100 mV. The onset potentials of MOR on Pt/W-C and Pt/C are the same, but at more positive potentials Pt/W-C catalyst is more active. It was proposed that promotion of MOR is based on bifunctional mechanism that facilitates COads removal. Stability test was performed by potential cycling of Pt/W-C and Pt/C in the supporting electrolyte and in the presence of methanol. Pt surface area loss observed in the supporting electrolyte of both catalysts after 250 cycles was about 20%. Decrease in the activity for methanol oxidation was 30% for Pt/W-C, but even 48% for Pt/C. The difference was explained by the presence of hydrous tungsten oxide on Pt in Pt/W-C catalyst, which reduces accumulation of poisoning COads. Copyright",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "International Journal of Hydrogen Energy",
title = "Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation",
volume = "37",
number = "14",
pages = "10671-10679",
doi = "10.1016/j.ijhydene.2012.04.114"
}
Obradović, M., Babić, B. M., Radmilović, V. R., Krstajić, N. V.,& Gojković, S. Lj.. (2012). Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation. in International Journal of Hydrogen Energy
Oxford : Pergamon-Elsevier Science Ltd., 37(14), 10671-10679.
https://doi.org/10.1016/j.ijhydene.2012.04.114
Obradović M, Babić BM, Radmilović VR, Krstajić NV, Gojković SL. Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation. in International Journal of Hydrogen Energy. 2012;37(14):10671-10679.
doi:10.1016/j.ijhydene.2012.04.114 .
Obradović, Maja, Babić, Biljana M., Radmilović, Velimir R., Krstajić, Nedeljko V., Gojković, Snežana Lj., "Core-shell structured tungsten-tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation" in International Journal of Hydrogen Energy, 37, no. 14 (2012):10671-10679,
https://doi.org/10.1016/j.ijhydene.2012.04.114 . .
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Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate

Obradović, Maja; Rogan, Jelena R.; Babić, Biljana M.; Tripković, Amalija; Gautam, A. R. S.; Radmilović, Velimir R.; Gojković, Snežana Lj.

(Elsevier, 2012)

TY  - JOUR
AU  - Obradović, Maja
AU  - Rogan, Jelena R.
AU  - Babić, Biljana M.
AU  - Tripković, Amalija
AU  - Gautam, A. R. S.
AU  - Radmilović, Velimir R.
AU  - Gojković, Snežana Lj.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1086
AB  - Pt-Au nanoparticles supported on high area carbon were prepared by simultaneous reduction of Au and Pt precursors and by reduction of Pt precursor on already prepared Au nanoparticles. The first method produced a solid solution of Pt in Au containing similar to 5% Pt with the remaining Pt on the nanoparticles' surface. For the Pt:Au precursor ratio of 1:4 and 1:9, the surface ratio was found to be 0.70:0.30 and 0.55:0.45, respectively. By the second method with the Pt:Au precursors ratio of 1:12, the surface ratio was 0.30:0.70. The voltammetric peaks of Pt-oxide reduction and CO(ads) oxidation demonstrated electronic modification of Pt by Au in all catalysts. With decreasing Pt:Au surface ratio the activity for HCOOH oxidation increases and surface coverage by CO(ads) decreases. The highest activity under potentiodynamic and quasi steady-state conditions without poisoning by CO(ads) was observed for the catalyst with the lowest Pt:Au surface ratio. Chronoamperometic test showed that its high catalytic activity is associated with a high deactivation rate. It was postulated that too strong adsorption of a reactive or non-reactive intermediate caused by electron modification of Pt by underlying Au, is responsible for the deactivation. This result stresses that high Pt dispersion, necessary for promotion of the dehydrogenation path in HCOOH oxidation, can produce too strong adsorption of intermediates causing deactivation of the catalyst.
PB  - Elsevier
T2  - Journal of Power Sources
T1  - Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate
VL  - 197
SP  - 72
EP  - 79
DO  - 10.1016/j.jpowsour.2011.09.043
ER  - 
@article{
author = "Obradović, Maja and Rogan, Jelena R. and Babić, Biljana M. and Tripković, Amalija and Gautam, A. R. S. and Radmilović, Velimir R. and Gojković, Snežana Lj.",
year = "2012",
abstract = "Pt-Au nanoparticles supported on high area carbon were prepared by simultaneous reduction of Au and Pt precursors and by reduction of Pt precursor on already prepared Au nanoparticles. The first method produced a solid solution of Pt in Au containing similar to 5% Pt with the remaining Pt on the nanoparticles' surface. For the Pt:Au precursor ratio of 1:4 and 1:9, the surface ratio was found to be 0.70:0.30 and 0.55:0.45, respectively. By the second method with the Pt:Au precursors ratio of 1:12, the surface ratio was 0.30:0.70. The voltammetric peaks of Pt-oxide reduction and CO(ads) oxidation demonstrated electronic modification of Pt by Au in all catalysts. With decreasing Pt:Au surface ratio the activity for HCOOH oxidation increases and surface coverage by CO(ads) decreases. The highest activity under potentiodynamic and quasi steady-state conditions without poisoning by CO(ads) was observed for the catalyst with the lowest Pt:Au surface ratio. Chronoamperometic test showed that its high catalytic activity is associated with a high deactivation rate. It was postulated that too strong adsorption of a reactive or non-reactive intermediate caused by electron modification of Pt by underlying Au, is responsible for the deactivation. This result stresses that high Pt dispersion, necessary for promotion of the dehydrogenation path in HCOOH oxidation, can produce too strong adsorption of intermediates causing deactivation of the catalyst.",
publisher = "Elsevier",
journal = "Journal of Power Sources",
title = "Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate",
volume = "197",
pages = "72-79",
doi = "10.1016/j.jpowsour.2011.09.043"
}
Obradović, M., Rogan, J. R., Babić, B. M., Tripković, A., Gautam, A. R. S., Radmilović, V. R.,& Gojković, S. Lj.. (2012). Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate. in Journal of Power Sources
Elsevier., 197, 72-79.
https://doi.org/10.1016/j.jpowsour.2011.09.043
Obradović M, Rogan JR, Babić BM, Tripković A, Gautam ARS, Radmilović VR, Gojković SL. Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate. in Journal of Power Sources. 2012;197:72-79.
doi:10.1016/j.jpowsour.2011.09.043 .
Obradović, Maja, Rogan, Jelena R., Babić, Biljana M., Tripković, Amalija, Gautam, A. R. S., Radmilović, Velimir R., Gojković, Snežana Lj., "Formic acid oxidation on Pt-Au nanoparticles: Relation between the catalyst activity and the poisoning rate" in Journal of Power Sources, 197 (2012):72-79,
https://doi.org/10.1016/j.jpowsour.2011.09.043 . .
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48

Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method

Jokić, Bojan; Drmanić, Saša Ž.; Radetić, Tamara; Krstić, Jugoslav; Petrovic, R.; Orlovic, A.; Janaćković, Đorđe

(Elsevier, 2010)

TY  - JOUR
AU  - Jokić, Bojan
AU  - Drmanić, Saša Ž.
AU  - Radetić, Tamara
AU  - Krstić, Jugoslav
AU  - Petrovic, R.
AU  - Orlovic, A.
AU  - Janaćković, Đorđe
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/715
AB  - Submicron carbon spherical particles were obtained by polycondensation of resorcinol and formaldehyde in a solution and subsequent ultrasonic spray pyrolysis of the prepared sol. Microscopic characterization indicates the regular spherical shape of the obtained particles and sphere diameters in 200-700 nm range. The carbon spheres are amorphous as confirmed by electron diffraction, EELS, XRD and HREM characterization. Activation procedure was performed with H2O in a nitrogen flow for 15 and 30 min at 800 degrees C. The activation procedure preserved the initial spherical shapes of the particles while the particle porosity and specific surface area were increased. The amount of surface oxygen functionalities was also increased by activation procedure as indicated by FTIR analysis.
PB  - Elsevier
T2  - Materials Letters
T1  - Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method
VL  - 64
IS  - 20
SP  - 2173
EP  - 2176
DO  - 10.1016/j.matlet.2010.06.066
ER  - 
@article{
author = "Jokić, Bojan and Drmanić, Saša Ž. and Radetić, Tamara and Krstić, Jugoslav and Petrovic, R. and Orlovic, A. and Janaćković, Đorđe",
year = "2010",
abstract = "Submicron carbon spherical particles were obtained by polycondensation of resorcinol and formaldehyde in a solution and subsequent ultrasonic spray pyrolysis of the prepared sol. Microscopic characterization indicates the regular spherical shape of the obtained particles and sphere diameters in 200-700 nm range. The carbon spheres are amorphous as confirmed by electron diffraction, EELS, XRD and HREM characterization. Activation procedure was performed with H2O in a nitrogen flow for 15 and 30 min at 800 degrees C. The activation procedure preserved the initial spherical shapes of the particles while the particle porosity and specific surface area were increased. The amount of surface oxygen functionalities was also increased by activation procedure as indicated by FTIR analysis.",
publisher = "Elsevier",
journal = "Materials Letters",
title = "Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method",
volume = "64",
number = "20",
pages = "2173-2176",
doi = "10.1016/j.matlet.2010.06.066"
}
Jokić, B., Drmanić, S. Ž., Radetić, T., Krstić, J., Petrovic, R., Orlovic, A.,& Janaćković, Đ.. (2010). Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method. in Materials Letters
Elsevier., 64(20), 2173-2176.
https://doi.org/10.1016/j.matlet.2010.06.066
Jokić B, Drmanić SŽ, Radetić T, Krstić J, Petrovic R, Orlovic A, Janaćković Đ. Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method. in Materials Letters. 2010;64(20):2173-2176.
doi:10.1016/j.matlet.2010.06.066 .
Jokić, Bojan, Drmanić, Saša Ž., Radetić, Tamara, Krstić, Jugoslav, Petrovic, R., Orlovic, A., Janaćković, Đorđe, "Synthesis of submicron carbon spheres by the ultrasonic spray pyrolysis method" in Materials Letters, 64, no. 20 (2010):2173-2176,
https://doi.org/10.1016/j.matlet.2010.06.066 . .
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