Ministry of Science, Technology and Development of Republic of Serbia, Contracts No. 1230

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Ministry of Science, Technology and Development of Republic of Serbia, Contracts No. 1230

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The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol

Panić, Vladimir; Vidaković, Tanja; Gojković, Suzana; Dekanski, Aleksandar; Milonjić, Slobodan; Nikolić, Branislav

(Elsevier, 2003)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković, Tanja
AU  - Gojković, Suzana
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan
AU  - Nikolić, Branislav
PY  - 2003
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4091
AB  - Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000® (BP) and Vulcan® XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 °C. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 °C, while the low-intensity peak at 2θ position that corresponds to the most intensive peak of the rutile structure was registered at 450 °C. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g−1 of composite was registered for RuOxHy supported on BP and calcined at 300 °C while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOxHy composite is highly porous while BP-supported one is more compact.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
VL  - 48
SP  - 3805
EP  - 3813
DO  - 10.1016/S0013-4686(03)00514-0
ER  - 
@article{
author = "Panić, Vladimir and Vidaković, Tanja and Gojković, Suzana and Dekanski, Aleksandar and Milonjić, Slobodan and Nikolić, Branislav",
year = "2003",
abstract = "Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000® (BP) and Vulcan® XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 °C. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 °C, while the low-intensity peak at 2θ position that corresponds to the most intensive peak of the rutile structure was registered at 450 °C. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g−1 of composite was registered for RuOxHy supported on BP and calcined at 300 °C while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOxHy composite is highly porous while BP-supported one is more compact.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol",
volume = "48",
pages = "3805-3813",
doi = "10.1016/S0013-4686(03)00514-0"
}
Panić, V., Vidaković, T., Gojković, S., Dekanski, A., Milonjić, S.,& Nikolić, B.. (2003). The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta
Elsevier., 48, 3805-3813.
https://doi.org/10.1016/S0013-4686(03)00514-0
Panić V, Vidaković T, Gojković S, Dekanski A, Milonjić S, Nikolić B. The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta. 2003;48:3805-3813.
doi:10.1016/S0013-4686(03)00514-0 .
Panić, Vladimir, Vidaković, Tanja, Gojković, Suzana, Dekanski, Aleksandar, Milonjić, Slobodan, Nikolić, Branislav, "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol" in Electrochimica Acta, 48 (2003):3805-3813,
https://doi.org/10.1016/S0013-4686(03)00514-0 . .
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