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Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides

Antonović, D G; Vajs, Vlatka; Stojanović, N D; Nikolić, A D; Petrović, S D

(Elsevier Science Publishers B.V, 1992)

TY  - JOUR
AU  - Antonović, D G
AU  - Vajs, Vlatka
AU  - Stojanović, N D
AU  - Nikolić, A D
AU  - Petrović, S D
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2790
AB  - As a part of a study on the structural characteristics of some new various N-alkyl-N-substituted 2-phenylacetamides the infrared and 1 H N.M.R. spectra were obtained and interpreted. The synthesis of a various N-n-propyl-N-alkyl 2-phenylacetamides of the general formula PhCH 2 CON(nPr)R, wherein R is ethyl, isopropyl, n-butyl, t-butyl and cyclohexyl, were performed. The corresponding mixed secondary amines of the type HNnPrR were obtained by catalytic hydrogenation of the synthetized propylidenealkylamines. The 1 H N.M.R. spectra of these unsymmetrically N,N-disubstituted amides have been studied and the peaks have been assigned in each cases to two possible conformational isomers, arising from the lack of free rotation about the C(O)N bond. These results are in accordance with our previous investigation of the structure of N-substituted 2-phenylacetamides. © 1992.
PB  - Elsevier Science Publishers B.V
T2  - Journal of Molecular Structure
T1  - Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides
VL  - 266
IS  - C
SP  - 255
EP  - 258
DO  - 10.1016/0022-2860(92)80075-S
ER  - 
@article{
author = "Antonović, D G and Vajs, Vlatka and Stojanović, N D and Nikolić, A D and Petrović, S D",
year = "1992",
abstract = "As a part of a study on the structural characteristics of some new various N-alkyl-N-substituted 2-phenylacetamides the infrared and 1 H N.M.R. spectra were obtained and interpreted. The synthesis of a various N-n-propyl-N-alkyl 2-phenylacetamides of the general formula PhCH 2 CON(nPr)R, wherein R is ethyl, isopropyl, n-butyl, t-butyl and cyclohexyl, were performed. The corresponding mixed secondary amines of the type HNnPrR were obtained by catalytic hydrogenation of the synthetized propylidenealkylamines. The 1 H N.M.R. spectra of these unsymmetrically N,N-disubstituted amides have been studied and the peaks have been assigned in each cases to two possible conformational isomers, arising from the lack of free rotation about the C(O)N bond. These results are in accordance with our previous investigation of the structure of N-substituted 2-phenylacetamides. © 1992.",
publisher = "Elsevier Science Publishers B.V",
journal = "Journal of Molecular Structure",
title = "Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides",
volume = "266",
number = "C",
pages = "255-258",
doi = "10.1016/0022-2860(92)80075-S"
}
Antonović, D. G., Vajs, V., Stojanović, N. D., Nikolić, A. D.,& Petrović, S. D.. (1992). Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides. in Journal of Molecular Structure
Elsevier Science Publishers B.V., 266(C), 255-258.
https://doi.org/10.1016/0022-2860(92)80075-S
Antonović DG, Vajs V, Stojanović ND, Nikolić AD, Petrović SD. Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides. in Journal of Molecular Structure. 1992;266(C):255-258.
doi:10.1016/0022-2860(92)80075-S .
Antonović, D G, Vajs, Vlatka, Stojanović, N D, Nikolić, A D, Petrović, S D, "Conformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamides" in Journal of Molecular Structure, 266, no. C (1992):255-258,
https://doi.org/10.1016/0022-2860(92)80075-S . .
2
5

Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms

Adžić, Radoslav R.; Spasojević, M. D.; Despić, Aleksandar R.

(Pergamon Press, 1979)

TY  - JOUR
AU  - Adžić, Radoslav R.
AU  - Spasojević, M. D.
AU  - Despić, Aleksandar R.
PY  - 1979
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2751
AB  - Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving rise to the Tafel slope of 30 mV with recombination of H adatoms as a rate controlling step. However, H2 evolution decreases with θM to the fourth power, due to a simple blocking of Pt surface and a decrease of number of pairs of Pt atoms necessary for a recombination reaction. At higher coverages of foreign metal adatoms (θM ≥ 0.5), when the activation energy for the recombination of H adatoms becomes too high, the ion-plus atom reaction begins to control the rate of reaction. The Tafel slope acquires a value of 120 mV. Now, a decrease of H2 evolution has been found proportional to the coverage of metal adatoms. A quantitative analysis based on above model agrees very well with the experiment. Some information on underpotential deposition of above metal on Pt has also been obtained. © 1979.
PB  - Pergamon Press
T2  - Electrochimica Acta
T2  - Electrochimica Acta
T1  - Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms
VL  - 24
IS  - 5
SP  - 569
EP  - 576
DO  - 10.1016/0013-4686(79)85034-3
ER  - 
@article{
author = "Adžić, Radoslav R. and Spasojević, M. D. and Despić, Aleksandar R.",
year = "1979",
abstract = "Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving rise to the Tafel slope of 30 mV with recombination of H adatoms as a rate controlling step. However, H2 evolution decreases with θM to the fourth power, due to a simple blocking of Pt surface and a decrease of number of pairs of Pt atoms necessary for a recombination reaction. At higher coverages of foreign metal adatoms (θM ≥ 0.5), when the activation energy for the recombination of H adatoms becomes too high, the ion-plus atom reaction begins to control the rate of reaction. The Tafel slope acquires a value of 120 mV. Now, a decrease of H2 evolution has been found proportional to the coverage of metal adatoms. A quantitative analysis based on above model agrees very well with the experiment. Some information on underpotential deposition of above metal on Pt has also been obtained. © 1979.",
publisher = "Pergamon Press",
journal = "Electrochimica Acta, Electrochimica Acta",
title = "Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms",
volume = "24",
number = "5",
pages = "569-576",
doi = "10.1016/0013-4686(79)85034-3"
}
Adžić, R. R., Spasojević, M. D.,& Despić, A. R.. (1979). Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms. in Electrochimica Acta
Pergamon Press., 24(5), 569-576.
https://doi.org/10.1016/0013-4686(79)85034-3
Adžić RR, Spasojević MD, Despić AR. Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms. in Electrochimica Acta. 1979;24(5):569-576.
doi:10.1016/0013-4686(79)85034-3 .
Adžić, Radoslav R., Spasojević, M. D., Despić, Aleksandar R., "Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms" in Electrochimica Acta, 24, no. 5 (1979):569-576,
https://doi.org/10.1016/0013-4686(79)85034-3 . .
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Effect of codeposition of polymer on the morphology of electrodeposited copper

Despić, Aleksandar R.; Maglić, G S; Jaćović, M

(Kluwer Academic Publishers, 1979)

TY  - JOUR
AU  - Despić, Aleksandar R.
AU  - Maglić, G S
AU  - Jaćović, M
PY  - 1979
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2749
AB  - Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep investigations have shown that the copolymer affects the electrocrystallization of copper on graphite by delaying nucleation even before conditions for codeposition of the polymer are reached. At overpotentials at which the diffusion limiting current of copper is reached and hydrogen evolution starts, alkalinity at the electrode surface causes precipitation of the polymer. This is found to affect the resistivity of the deposit. Electron microscopy revealed that under such conditions copper is deposited in the form of globular particles, the size of the globules being in the micron range and decreasing with increasing overpotential. © 1979 Chapman and Hall Ltd.
PB  - Kluwer Academic Publishers
T2  - Journal of Applied Electrochemistry
T1  - Effect of codeposition of polymer on the morphology of electrodeposited copper
VL  - 9
IS  - 2
SP  - 147
EP  - 153
DO  - 10.1007/BF00616084
ER  - 
@article{
author = "Despić, Aleksandar R. and Maglić, G S and Jaćović, M",
year = "1979",
abstract = "Poly(4-vinyl pyridine-co-methyl methacrylate), which is soluble in water in its protonated form and insoluble as a neutral molecule, has been synthesized and introduced into an acid bath for copper deposition. Potential-sweep investigations have shown that the copolymer affects the electrocrystallization of copper on graphite by delaying nucleation even before conditions for codeposition of the polymer are reached. At overpotentials at which the diffusion limiting current of copper is reached and hydrogen evolution starts, alkalinity at the electrode surface causes precipitation of the polymer. This is found to affect the resistivity of the deposit. Electron microscopy revealed that under such conditions copper is deposited in the form of globular particles, the size of the globules being in the micron range and decreasing with increasing overpotential. © 1979 Chapman and Hall Ltd.",
publisher = "Kluwer Academic Publishers",
journal = "Journal of Applied Electrochemistry",
title = "Effect of codeposition of polymer on the morphology of electrodeposited copper",
volume = "9",
number = "2",
pages = "147-153",
doi = "10.1007/BF00616084"
}
Despić, A. R., Maglić, G. S.,& Jaćović, M.. (1979). Effect of codeposition of polymer on the morphology of electrodeposited copper. in Journal of Applied Electrochemistry
Kluwer Academic Publishers., 9(2), 147-153.
https://doi.org/10.1007/BF00616084
Despić AR, Maglić GS, Jaćović M. Effect of codeposition of polymer on the morphology of electrodeposited copper. in Journal of Applied Electrochemistry. 1979;9(2):147-153.
doi:10.1007/BF00616084 .
Despić, Aleksandar R., Maglić, G S, Jaćović, M, "Effect of codeposition of polymer on the morphology of electrodeposited copper" in Journal of Applied Electrochemistry, 9, no. 2 (1979):147-153,
https://doi.org/10.1007/BF00616084 . .
2
3

Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions

Dražić, Dragutin M.; Vorkapić, L. Ž.

(Pergamon Press, 1978)

TY  - JOUR
AU  - Dražić, Dragutin M.
AU  - Vorkapić, L. Ž.
PY  - 1978
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2758
AB  - The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion of iron. This effect has been explained as the under-potential deposition of the adatoms of these metals on iron. © 1978.
PB  - Pergamon Press
T2  - Corrosion Science
T1  - Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions
VL  - 18
IS  - 10
SP  - 907
EP  - 910
DO  - 10.1016/0010-938X(78)90011-2
ER  - 
@article{
author = "Dražić, Dragutin M. and Vorkapić, L. Ž.",
year = "1978",
abstract = "The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion of iron. This effect has been explained as the under-potential deposition of the adatoms of these metals on iron. © 1978.",
publisher = "Pergamon Press",
journal = "Corrosion Science",
title = "Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions",
volume = "18",
number = "10",
pages = "907-910",
doi = "10.1016/0010-938X(78)90011-2"
}
Dražić, D. M.,& Vorkapić, L. Ž.. (1978). Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions. in Corrosion Science
Pergamon Press., 18(10), 907-910.
https://doi.org/10.1016/0010-938X(78)90011-2
Dražić DM, Vorkapić LŽ. Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions. in Corrosion Science. 1978;18(10):907-910.
doi:10.1016/0010-938X(78)90011-2 .
Dražić, Dragutin M., Vorkapić, L. Ž., "Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions" in Corrosion Science, 18, no. 10 (1978):907-910,
https://doi.org/10.1016/0010-938X(78)90011-2 . .
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