TY  - JOUR
AU  - Pavlović, Stefan
AU  - Marinković, Dalibor
AU  - Kostić, Milan
AU  - Janković-Častvan, Ivona
AU  - Mojović, Ljiljana
AU  - Stanković, Miroslav
AU  - Veljković, Vlada B.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3423
AB  - The present paper is focused on the development of a new environment-friendly methanolysis catalyst completely
based on waste materials: lignite coal fly ash and chicken eggshells. A novel catalyst based on CaO
supported on a fly ash-based zeolitic material (CaO/FA-ZM) was obtained from a cancrinite-sodalite group
zeolite-like material (vishnevite type) and active CaO by alkali activation in a new miniature autoclave reactor
system and hydration-dehydration. Agitation by rotation of the entire reaction mixture led to a more homogeneous
zeolitic product and saved both time and energy. The obtained catalyst structure corresponds to gismondine
and the crystallographic modification of calcium silicate (α’-dicalcium silicate) with deposited CaO.
The characteristics of the synthesized catalyst were determined using ED-XRF, XRD, FT-IR, SEM, Hg-porosimetry,
N2-physisorption, LDPSA, and Hammett indicators. The CaO/FA-ZM catalyst exhibited a high activity
(97.8% of FAME for only 30 min) and stability (a negligible drop in activity in five consecutive cycles) in the
methanolysis reaction under the optimal reaction conditions (temperature of 60 °C, methanol/oil molar ratio of
6:1, and catalyst concentration of 6 wt%). A kinetic study was performed using two different mechanisms: the
irreversible pseudo-first-order reaction mechanism in two regimes (heterogeneous and homogeneous) and the
changing mechanism combined with the triacylglycerol mass transfer limitation. Both models showed a satisfactory
agreement between the experimental and predicted values of conversion degree (R2 > 0.93), confirming
their validity for the CaO-based heterogeneously catalyzed methanolysis. The values of the activation
energy calculated for both mechanisms were 67.17 and 58.03 kJ mol−1, respectively.
PB  - Elsevier
T2  - Fuel
T1  - A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production
VL  - 267
SP  - 117171
DO  - 10.1016/j.fuel.2020.117171
ER  - 

@article{
author = "Pavlović, Stefan and Marinković, Dalibor and Kostić, Milan and Janković-Častvan, Ivona and Mojović, Ljiljana and Stanković, Miroslav and Veljković, Vlada B.",
year = "2020",
abstract = "The present paper is focused on the development of a new environment-friendly methanolysis catalyst completely
based on waste materials: lignite coal fly ash and chicken eggshells. A novel catalyst based on CaO
supported on a fly ash-based zeolitic material (CaO/FA-ZM) was obtained from a cancrinite-sodalite group
zeolite-like material (vishnevite type) and active CaO by alkali activation in a new miniature autoclave reactor
system and hydration-dehydration. Agitation by rotation of the entire reaction mixture led to a more homogeneous
zeolitic product and saved both time and energy. The obtained catalyst structure corresponds to gismondine
and the crystallographic modification of calcium silicate (α’-dicalcium silicate) with deposited CaO.
The characteristics of the synthesized catalyst were determined using ED-XRF, XRD, FT-IR, SEM, Hg-porosimetry,
N2-physisorption, LDPSA, and Hammett indicators. The CaO/FA-ZM catalyst exhibited a high activity
(97.8% of FAME for only 30 min) and stability (a negligible drop in activity in five consecutive cycles) in the
methanolysis reaction under the optimal reaction conditions (temperature of 60 °C, methanol/oil molar ratio of
6:1, and catalyst concentration of 6 wt%). A kinetic study was performed using two different mechanisms: the
irreversible pseudo-first-order reaction mechanism in two regimes (heterogeneous and homogeneous) and the
changing mechanism combined with the triacylglycerol mass transfer limitation. Both models showed a satisfactory
agreement between the experimental and predicted values of conversion degree (R2 > 0.93), confirming
their validity for the CaO-based heterogeneously catalyzed methanolysis. The values of the activation
energy calculated for both mechanisms were 67.17 and 58.03 kJ mol−1, respectively.",
publisher = "Elsevier",
journal = "Fuel",
title = "A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production",
volume = "267",
pages = "117171",
doi = "10.1016/j.fuel.2020.117171"
}

Pavlović, S., Marinković, D., Kostić, M., Janković-Častvan, I., Mojović, L., Stanković, M.,& Veljković, V. B.. (2020). A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production. in Fuel
Elsevier., 267, 117171.
https://doi.org/10.1016/j.fuel.2020.117171

Pavlović S, Marinković D, Kostić M, Janković-Častvan I, Mojović L, Stanković M, Veljković VB. A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production. in Fuel. 2020;267:117171.
doi:10.1016/j.fuel.2020.117171 .

Pavlović, Stefan, Marinković, Dalibor, Kostić, Milan, Janković-Častvan, Ivona, Mojović, Ljiljana, Stanković, Miroslav, Veljković, Vlada B., "A CaO/zeolite-based catalyst obtained from waste chicken eggshell and coal fly ash for biodiesel production" in Fuel, 267 (2020):117171,
https://doi.org/10.1016/j.fuel.2020.117171 . .