Fizička hemija dinamičkih stanja i struktura neravnotežnih sistema - od monotone do oscilatorne evolucije i haosa

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Fizička hemija dinamičkih stanja i struktura neravnotežnih sistema - od monotone do oscilatorne evolucije i haosa (en)
Физичка хемија динамичких стања и структура неравнотежних система - од монотоне до осцилаторне еволуције и хаоса (sr)
Fizička hemija dinamičkih stanja i struktura neravnotežnih sistema - od monotone do oscilatorne evolucije i haosa (sr_RS)
Authors

Publications

The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution

Milenković, Maja; Stanisavljev, Dragomir; Mudrinić, Tihana; Vuković, Milica

(Society of Physical Chemists of Serbia, 2010)

TY  - CONF
AU  - Milenković, Maja
AU  - Stanisavljev, Dragomir
AU  - Mudrinić, Tihana
AU  - Vuković, Milica
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6810
AB  - The kinetics of the complex reaction between I– and H2O2 in acid media is investigated. The particular attention is focused on the determination of the rate
constant of the reaction between HIO and H2O2 involved in investigated complex
process. The examination of the whole kinetics was performed by monitoring
evolution of O2 pressure, I3– and I– concentrations. We modeled behavior of
experimentally followed components based on Liebhafsky research. Our
preliminary results suggest a significantly higher rate constant of the reaction
between HIO and H2O2 from those proposed in the literature.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia
T1  - The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution
SP  - 242
EP  - 244
UR  - https://hdl.handle.net/21.15107/rcub_cer_6810
ER  - 
@conference{
author = "Milenković, Maja and Stanisavljev, Dragomir and Mudrinić, Tihana and Vuković, Milica",
year = "2010",
abstract = "The kinetics of the complex reaction between I– and H2O2 in acid media is investigated. The particular attention is focused on the determination of the rate
constant of the reaction between HIO and H2O2 involved in investigated complex
process. The examination of the whole kinetics was performed by monitoring
evolution of O2 pressure, I3– and I– concentrations. We modeled behavior of
experimentally followed components based on Liebhafsky research. Our
preliminary results suggest a significantly higher rate constant of the reaction
between HIO and H2O2 from those proposed in the literature.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia",
title = "The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution",
pages = "242-244",
url = "https://hdl.handle.net/21.15107/rcub_cer_6810"
}
Milenković, M., Stanisavljev, D., Mudrinić, T.,& Vuković, M.. (2010). The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution. in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia
Society of Physical Chemists of Serbia., 242-244.
https://hdl.handle.net/21.15107/rcub_cer_6810
Milenković M, Stanisavljev D, Mudrinić T, Vuković M. The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution. in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia. 2010;:242-244.
https://hdl.handle.net/21.15107/rcub_cer_6810 .
Milenković, Maja, Stanisavljev, Dragomir, Mudrinić, Tihana, Vuković, Milica, "The Kinetics of Reaction between Iodide and Hydrogen Peroxide in Acid Solution" in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia (2010):242-244,
https://hdl.handle.net/21.15107/rcub_cer_6810 .

Critical manifold of the model for Bray-Liebhafsky oscillatory reaction

Ivanović, Ana; Čupić, Željko; Marinović, Sanja; Schmitz, Guy; Kolar-Anić, Ljiljana

(Society of Physical Chemists of Serbia, 2010)

TY  - CONF
AU  - Ivanović, Ana
AU  - Čupić, Željko
AU  - Marinović, Sanja
AU  - Schmitz, Guy
AU  - Kolar-Anić, Ljiljana
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6317
AB  - Mixed mode oscillations are obtained in numerical simulations of the Bray-
Liebhafsky oscillatory reaction in CSTR, for appropriate choice of the parameter
set. In this paper, we analyze critical manifold of the slow-fast system in three
dimensional phase subspace. We found that small amplitude oscillations obtained
as a part of mixed mode dynamics are governed by canard solutions.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia
T1  - Critical manifold of the model for Bray-Liebhafsky oscillatory reaction
SP  - 236
EP  - 238
UR  - https://hdl.handle.net/21.15107/rcub_cer_6317
ER  - 
@conference{
author = "Ivanović, Ana and Čupić, Željko and Marinović, Sanja and Schmitz, Guy and Kolar-Anić, Ljiljana",
year = "2010",
abstract = "Mixed mode oscillations are obtained in numerical simulations of the Bray-
Liebhafsky oscillatory reaction in CSTR, for appropriate choice of the parameter
set. In this paper, we analyze critical manifold of the slow-fast system in three
dimensional phase subspace. We found that small amplitude oscillations obtained
as a part of mixed mode dynamics are governed by canard solutions.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia",
title = "Critical manifold of the model for Bray-Liebhafsky oscillatory reaction",
pages = "236-238",
url = "https://hdl.handle.net/21.15107/rcub_cer_6317"
}
Ivanović, A., Čupić, Ž., Marinović, S., Schmitz, G.,& Kolar-Anić, L.. (2010). Critical manifold of the model for Bray-Liebhafsky oscillatory reaction. in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia
Society of Physical Chemists of Serbia., 236-238.
https://hdl.handle.net/21.15107/rcub_cer_6317
Ivanović A, Čupić Ž, Marinović S, Schmitz G, Kolar-Anić L. Critical manifold of the model for Bray-Liebhafsky oscillatory reaction. in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia. 2010;:236-238.
https://hdl.handle.net/21.15107/rcub_cer_6317 .
Ivanović, Ana, Čupić, Željko, Marinović, Sanja, Schmitz, Guy, Kolar-Anić, Ljiljana, "Critical manifold of the model for Bray-Liebhafsky oscillatory reaction" in Proceedings - 10th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2010, 21-24 September 2010, Belgrade, Serbia (2010):236-238,
https://hdl.handle.net/21.15107/rcub_cer_6317 .

Current oscillations during the anodic dissolution of copper in trifluoroacetic acid

Potkonjak, Nebojsa I.; Potkonjak, Tanja. N.; Blagojević, Stevan; Dudic, Boris; Randjelović, Danijela

(Oxford : Pergamon-Elsevier Science Ltd, 2010)

TY  - JOUR
AU  - Potkonjak, Nebojsa I.
AU  - Potkonjak, Tanja. N.
AU  - Blagojević, Stevan
AU  - Dudic, Boris
AU  - Randjelović, Danijela
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/660
AB  - A phenomenon of current oscillators was characterized crosswise active-passive potential region during the electrodissolution of copper electrode in trifluoroacetic acid (TFA). The current density-potential curves show two transition points. A potential region of current oscillations was found as a part of limiting current region. The Cu vertical bar TFA electrochemical oscillator was found to displaying rich dynamical response on varying the temperature and the applied potential. The Cu vertical bar TFA system display current oscillation behaviour from the mono-periodic to the mixed-mode (relaxation type). Changes of the electrode surface structure and morphology were investigated by X-ray diffraction spectroscopy, atomic forced microscopy and optical microscopy.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Corrosion Science
T1  - Current oscillations during the anodic dissolution of copper in trifluoroacetic acid
VL  - 52
IS  - 5
SP  - 1618
EP  - 1624
DO  - 10.1016/j.corsci.2010.02.021
ER  - 
@article{
author = "Potkonjak, Nebojsa I. and Potkonjak, Tanja. N. and Blagojević, Stevan and Dudic, Boris and Randjelović, Danijela",
year = "2010",
abstract = "A phenomenon of current oscillators was characterized crosswise active-passive potential region during the electrodissolution of copper electrode in trifluoroacetic acid (TFA). The current density-potential curves show two transition points. A potential region of current oscillations was found as a part of limiting current region. The Cu vertical bar TFA electrochemical oscillator was found to displaying rich dynamical response on varying the temperature and the applied potential. The Cu vertical bar TFA system display current oscillation behaviour from the mono-periodic to the mixed-mode (relaxation type). Changes of the electrode surface structure and morphology were investigated by X-ray diffraction spectroscopy, atomic forced microscopy and optical microscopy.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Corrosion Science",
title = "Current oscillations during the anodic dissolution of copper in trifluoroacetic acid",
volume = "52",
number = "5",
pages = "1618-1624",
doi = "10.1016/j.corsci.2010.02.021"
}
Potkonjak, N. I., Potkonjak, Tanja. N., Blagojević, S., Dudic, B.,& Randjelović, D.. (2010). Current oscillations during the anodic dissolution of copper in trifluoroacetic acid. in Corrosion Science
Oxford : Pergamon-Elsevier Science Ltd., 52(5), 1618-1624.
https://doi.org/10.1016/j.corsci.2010.02.021
Potkonjak NI, Potkonjak TN, Blagojević S, Dudic B, Randjelović D. Current oscillations during the anodic dissolution of copper in trifluoroacetic acid. in Corrosion Science. 2010;52(5):1618-1624.
doi:10.1016/j.corsci.2010.02.021 .
Potkonjak, Nebojsa I., Potkonjak, Tanja. N., Blagojević, Stevan, Dudic, Boris, Randjelović, Danijela, "Current oscillations during the anodic dissolution of copper in trifluoroacetic acid" in Corrosion Science, 52, no. 5 (2010):1618-1624,
https://doi.org/10.1016/j.corsci.2010.02.021 . .
11
10
11

Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems

Kolar-Anić, Ljiljana; Čupić, Željko; Schmitz, Guy; Anić, Slobodan

(Oxford : Pergamon-Elsevier Science Ltd, 2010)

TY  - JOUR
AU  - Kolar-Anić, Ljiljana
AU  - Čupić, Željko
AU  - Schmitz, Guy
AU  - Anić, Slobodan
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/633
AB  - Stoichiometric network analysis (SNA), a known method for analyzing complex reaction systems including biochemical ones, is improved and applied to a nonlinear process studied far from equilibrium in a continuously fed, well stirred tank reactor (CSTR). A particular attention is focused on the determination of the narrow range of the control parameter values where the main steady state is unstable and where different dynamic states can be simulated numerically. The instability region, the most important feature of nonlinear reaction systems, is calculated as a function of the SNA parameters (current rates and reciprocal concentrations of intermediate species in the steady state) and simplified by retaining only the dominant terms. Since the number of the current rates is usually larger than the number of linearly independent equations to be used for their calculation, it is shown here that the current rates can be replaced with a smaller number of reaction rates at the steady state. These rates are related to the experimental data in a simple manner. The instability conditions is also written as a function of dimensionless parameters derived from the SNA. This general approach is applied to a model of the Bray-Liebhafsky (BL) reaction having seven reactions without direct autocatalysis or autoinhibition, studied under CSTR conditions. Since the model has six intermediate species, it would be very difficult to analyze its instability condition by the conventional procedure, where a sixth order characteristics equation would have to be solved. On the other hand, the instability condition, obtained easily by the improved SNA, locates correctly the oscillatory region using numerical integration. Other dynamic states found earlier with a larger model of the BL reaction, such as mixed-mode oscillations, period doubling and chaos, are also obtained within the theoretically predicted oscillatory region. Thus, besides the general advantages of the improved stoichiometric network analysis as a method appropriate for the examination of complex nonlinear reactions, we show that the various mentioned dynamic states can be obtained by a very simple variant of the model of the BL reaction realized under CSTR conditions.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Chemical Engineering Science
T1  - Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems
VL  - 65
IS  - 12
SP  - 3718
EP  - 3728
DO  - 10.1016/j.ces.2010.03.008
ER  - 
@article{
author = "Kolar-Anić, Ljiljana and Čupić, Željko and Schmitz, Guy and Anić, Slobodan",
year = "2010",
abstract = "Stoichiometric network analysis (SNA), a known method for analyzing complex reaction systems including biochemical ones, is improved and applied to a nonlinear process studied far from equilibrium in a continuously fed, well stirred tank reactor (CSTR). A particular attention is focused on the determination of the narrow range of the control parameter values where the main steady state is unstable and where different dynamic states can be simulated numerically. The instability region, the most important feature of nonlinear reaction systems, is calculated as a function of the SNA parameters (current rates and reciprocal concentrations of intermediate species in the steady state) and simplified by retaining only the dominant terms. Since the number of the current rates is usually larger than the number of linearly independent equations to be used for their calculation, it is shown here that the current rates can be replaced with a smaller number of reaction rates at the steady state. These rates are related to the experimental data in a simple manner. The instability conditions is also written as a function of dimensionless parameters derived from the SNA. This general approach is applied to a model of the Bray-Liebhafsky (BL) reaction having seven reactions without direct autocatalysis or autoinhibition, studied under CSTR conditions. Since the model has six intermediate species, it would be very difficult to analyze its instability condition by the conventional procedure, where a sixth order characteristics equation would have to be solved. On the other hand, the instability condition, obtained easily by the improved SNA, locates correctly the oscillatory region using numerical integration. Other dynamic states found earlier with a larger model of the BL reaction, such as mixed-mode oscillations, period doubling and chaos, are also obtained within the theoretically predicted oscillatory region. Thus, besides the general advantages of the improved stoichiometric network analysis as a method appropriate for the examination of complex nonlinear reactions, we show that the various mentioned dynamic states can be obtained by a very simple variant of the model of the BL reaction realized under CSTR conditions.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Chemical Engineering Science",
title = "Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems",
volume = "65",
number = "12",
pages = "3718-3728",
doi = "10.1016/j.ces.2010.03.008"
}
Kolar-Anić, L., Čupić, Ž., Schmitz, G.,& Anić, S.. (2010). Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems. in Chemical Engineering Science
Oxford : Pergamon-Elsevier Science Ltd., 65(12), 3718-3728.
https://doi.org/10.1016/j.ces.2010.03.008
Kolar-Anić L, Čupić Ž, Schmitz G, Anić S. Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems. in Chemical Engineering Science. 2010;65(12):3718-3728.
doi:10.1016/j.ces.2010.03.008 .
Kolar-Anić, Ljiljana, Čupić, Željko, Schmitz, Guy, Anić, Slobodan, "Improvement of the stoichiometric network analysis for determination of instability conditions of complex nonlinear reaction systems" in Chemical Engineering Science, 65, no. 12 (2010):3718-3728,
https://doi.org/10.1016/j.ces.2010.03.008 . .
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31

Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge

Gorjanović, Stanislava Ž.; Novaković, Miroslav; Potkonjak, Nebojsa I.; Suznjevic, Desanka Z.

(American Chemical Society (ACS), 2010)

TY  - JOUR
AU  - Gorjanović, Stanislava Ž.
AU  - Novaković, Miroslav
AU  - Potkonjak, Nebojsa I.
AU  - Suznjevic, Desanka Z.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/645
AB  - Antioxidant (AO) activity of various red and white wines of different origin as well as some individual phenolic compounds present in wine has been assessed using a polarographic assay. Direct current polarography has been used to survey hydrogen peroxide scavenge (HPS) upon gradual addition of tested samples. Results expressed as reciprocal value of wine volume required for 50% decrease of anodic limiting current of hydrogen peroxide have been validated through correlation with Folin Ciocalteau and DPPH assays. All wines exhibit HPS activity analogous with total phenolic content and DPPH scavenge. Reliability and accuracy, low cost, and rapid and direct experimental procedure open a wide area for application of this assay, making it a good alternative to standard, widely accepted AO assays.
PB  - American Chemical Society (ACS)
T2  - Journal of Agricultural and Food Chemistry
T1  - Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge
VL  - 58
IS  - 8
SP  - 4626
EP  - 4631
DO  - 10.1021/jf100022e
ER  - 
@article{
author = "Gorjanović, Stanislava Ž. and Novaković, Miroslav and Potkonjak, Nebojsa I. and Suznjevic, Desanka Z.",
year = "2010",
abstract = "Antioxidant (AO) activity of various red and white wines of different origin as well as some individual phenolic compounds present in wine has been assessed using a polarographic assay. Direct current polarography has been used to survey hydrogen peroxide scavenge (HPS) upon gradual addition of tested samples. Results expressed as reciprocal value of wine volume required for 50% decrease of anodic limiting current of hydrogen peroxide have been validated through correlation with Folin Ciocalteau and DPPH assays. All wines exhibit HPS activity analogous with total phenolic content and DPPH scavenge. Reliability and accuracy, low cost, and rapid and direct experimental procedure open a wide area for application of this assay, making it a good alternative to standard, widely accepted AO assays.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Agricultural and Food Chemistry",
title = "Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge",
volume = "58",
number = "8",
pages = "4626-4631",
doi = "10.1021/jf100022e"
}
Gorjanović, S. Ž., Novaković, M., Potkonjak, N. I.,& Suznjevic, D. Z.. (2010). Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge. in Journal of Agricultural and Food Chemistry
American Chemical Society (ACS)., 58(8), 4626-4631.
https://doi.org/10.1021/jf100022e
Gorjanović SŽ, Novaković M, Potkonjak NI, Suznjevic DZ. Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge. in Journal of Agricultural and Food Chemistry. 2010;58(8):4626-4631.
doi:10.1021/jf100022e .
Gorjanović, Stanislava Ž., Novaković, Miroslav, Potkonjak, Nebojsa I., Suznjevic, Desanka Z., "Antioxidant Activity of Wines Determined by a Polarographic Assay Based on Hydrogen Peroxide Scavenge" in Journal of Agricultural and Food Chemistry, 58, no. 8 (2010):4626-4631,
https://doi.org/10.1021/jf100022e . .
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Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction

Ivanović-Šašić, Ana; Čupić, Željko; Kolar-Anić, Ljiljana; Janković, Marija M.; Anić, Slobodan

(Maik Nauka/Interperiodica/Springer, New York, 2009)

TY  - JOUR
AU  - Ivanović-Šašić, Ana
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
AU  - Janković, Marija M.
AU  - Anić, Slobodan
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/535
AB  - We applied multifractal analysis on time series obtained by deterministic simulation of the Bray-Liebhafsky oscillatory reaction. Large deviation spectrum was used to represent multifractal properties of the attractor. We obtained spectrums with two peaks, one in region of low and the other in region of high values of Holder exponent. Their intensity depends on flow rate. The method developed on the results from numerical simulations is tested on the experimental record from the same reaction system and multifractality of the time series is confirmed.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction
VL  - 83
IS  - 9
SP  - 1526
EP  - 1530
DO  - 10.1134/S0036024409090192
ER  - 
@article{
author = "Ivanović-Šašić, Ana and Čupić, Željko and Kolar-Anić, Ljiljana and Janković, Marija M. and Anić, Slobodan",
year = "2009",
abstract = "We applied multifractal analysis on time series obtained by deterministic simulation of the Bray-Liebhafsky oscillatory reaction. Large deviation spectrum was used to represent multifractal properties of the attractor. We obtained spectrums with two peaks, one in region of low and the other in region of high values of Holder exponent. Their intensity depends on flow rate. The method developed on the results from numerical simulations is tested on the experimental record from the same reaction system and multifractality of the time series is confirmed.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction",
volume = "83",
number = "9",
pages = "1526-1530",
doi = "10.1134/S0036024409090192"
}
Ivanović-Šašić, A., Čupić, Ž., Kolar-Anić, L., Janković, M. M.,& Anić, S.. (2009). Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1526-1530.
https://doi.org/10.1134/S0036024409090192
Ivanović-Šašić A, Čupić Ž, Kolar-Anić L, Janković MM, Anić S. Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction. in Russian Journal of Physical Chemistry A. 2009;83(9):1526-1530.
doi:10.1134/S0036024409090192 .
Ivanović-Šašić, Ana, Čupić, Željko, Kolar-Anić, Ljiljana, Janković, Marija M., Anić, Slobodan, "Large deviation spectra of chaotic time series from Bray-Liebhafsky reaction" in Russian Journal of Physical Chemistry A, 83, no. 9 (2009):1526-1530,
https://doi.org/10.1134/S0036024409090192 . .
4
5
7

Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator

Anić, Slobodan; Maksimović, Jelena; Lončarević, Davor; Pejić, Nataša; Čupić, Željko

(Maik Nauka/Interperiodica/Springer, New York, 2009)

TY  - JOUR
AU  - Anić, Slobodan
AU  - Maksimović, Jelena
AU  - Lončarević, Davor
AU  - Pejić, Nataša
AU  - Čupić, Željko
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/544
AB  - The infuence of poly-4-vinylpyridine-co-divinylbenzene-Co2+ catalyst on the Bray-Liebhafsky (BL) oscillator used as the matrix for establishing catalyst's activity was analyzed. The addition of the catalyst do not change the dynamics of the reaction in the BL matrix, but the periods of the oscillatory evolution as well as the preoscillatory period (tau(1)) and the duration from the beginning of the reaction to the end of the oscillatory state (tau(end)). All experimental results are simulated satisfactory.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator
VL  - 83
IS  - 9
SP  - 1468
EP  - 1472
DO  - 10.1134/S003602440909009X
ER  - 
@article{
author = "Anić, Slobodan and Maksimović, Jelena and Lončarević, Davor and Pejić, Nataša and Čupić, Željko",
year = "2009",
abstract = "The infuence of poly-4-vinylpyridine-co-divinylbenzene-Co2+ catalyst on the Bray-Liebhafsky (BL) oscillator used as the matrix for establishing catalyst's activity was analyzed. The addition of the catalyst do not change the dynamics of the reaction in the BL matrix, but the periods of the oscillatory evolution as well as the preoscillatory period (tau(1)) and the duration from the beginning of the reaction to the end of the oscillatory state (tau(end)). All experimental results are simulated satisfactory.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator",
volume = "83",
number = "9",
pages = "1468-1472",
doi = "10.1134/S003602440909009X"
}
Anić, S., Maksimović, J., Lončarević, D., Pejić, N.,& Čupić, Ž.. (2009). Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1468-1472.
https://doi.org/10.1134/S003602440909009X
Anić S, Maksimović J, Lončarević D, Pejić N, Čupić Ž. Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator. in Russian Journal of Physical Chemistry A. 2009;83(9):1468-1472.
doi:10.1134/S003602440909009X .
Anić, Slobodan, Maksimović, Jelena, Lončarević, Davor, Pejić, Nataša, Čupić, Željko, "Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator" in Russian Journal of Physical Chemistry A, 83, no. 9 (2009):1468-1472,
https://doi.org/10.1134/S003602440909009X . .
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10

Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations

Jelić, S.; Čupić, Željko; Kolar-Anić, Ljiljana; Vukojević, V.

(2009)

TY  - JOUR
AU  - Jelić, S.
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
AU  - Vukojević, V.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/626
AB  - Two methods for dynamic systems analysis, Stoichiometric Network Analysis (SNA) and Quenching of Small Amplitude Oscillations (QA), are used to study the behaviour of a vital biological system. Both methods use geometric approaches for the study of complex reaction systems. In SNA, methods based on convex polytopes geometry are applied for stability analysis and optimization of reaction networks. QA relies on a geometric representation of the concentration phase space, introduces the concept of manifolds and the singular perturbation theory to study the dynamics of complex processes. The analyzed system, the Hypothalamic-Pituitary-Adrenal (HPA) axis, as a major constituent of the neuroendocrine system has a critical role in integrating biological responses in basal conditions and during stress. Self-regulation in the HPA system was modeled through a positive and negative feedback effect of Cortisol. A systematically reduced low-dimensional model of HPA activity in humans was fine-tuned by SNA, until quantitative agreement with experimental findings was achieved. By QA, we revealed an important dynamic regulatory mechanism that is a natural consequence of the intrinsic rhythmicity of the considered system.
T2  - International Journal of Nonlinear Sciences and Numerical Simulation
T1  - Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations
VL  - 10
IS  - 11-12
SP  - 1451
EP  - 1472
UR  - https://hdl.handle.net/21.15107/rcub_cer_626
ER  - 
@article{
author = "Jelić, S. and Čupić, Željko and Kolar-Anić, Ljiljana and Vukojević, V.",
year = "2009",
abstract = "Two methods for dynamic systems analysis, Stoichiometric Network Analysis (SNA) and Quenching of Small Amplitude Oscillations (QA), are used to study the behaviour of a vital biological system. Both methods use geometric approaches for the study of complex reaction systems. In SNA, methods based on convex polytopes geometry are applied for stability analysis and optimization of reaction networks. QA relies on a geometric representation of the concentration phase space, introduces the concept of manifolds and the singular perturbation theory to study the dynamics of complex processes. The analyzed system, the Hypothalamic-Pituitary-Adrenal (HPA) axis, as a major constituent of the neuroendocrine system has a critical role in integrating biological responses in basal conditions and during stress. Self-regulation in the HPA system was modeled through a positive and negative feedback effect of Cortisol. A systematically reduced low-dimensional model of HPA activity in humans was fine-tuned by SNA, until quantitative agreement with experimental findings was achieved. By QA, we revealed an important dynamic regulatory mechanism that is a natural consequence of the intrinsic rhythmicity of the considered system.",
journal = "International Journal of Nonlinear Sciences and Numerical Simulation",
title = "Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations",
volume = "10",
number = "11-12",
pages = "1451-1472",
url = "https://hdl.handle.net/21.15107/rcub_cer_626"
}
Jelić, S., Čupić, Ž., Kolar-Anić, L.,& Vukojević, V.. (2009). Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations. in International Journal of Nonlinear Sciences and Numerical Simulation, 10(11-12), 1451-1472.
https://hdl.handle.net/21.15107/rcub_cer_626
Jelić S, Čupić Ž, Kolar-Anić L, Vukojević V. Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations. in International Journal of Nonlinear Sciences and Numerical Simulation. 2009;10(11-12):1451-1472.
https://hdl.handle.net/21.15107/rcub_cer_626 .
Jelić, S., Čupić, Željko, Kolar-Anić, Ljiljana, Vukojević, V., "Predictive modeling of the hypothalamic-pituitary-adrenal (HPA) function. dynamic systems theory approach by stoichiometric network analysis and quenching small amplitude oscillations" in International Journal of Nonlinear Sciences and Numerical Simulation, 10, no. 11-12 (2009):1451-1472,
https://hdl.handle.net/21.15107/rcub_cer_626 .
19

Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction

Blagojević, Slavica; Anić, Slobodan; Čupić, Željko; Pejić, Nataša; Kolar-Anić, Ljiljana

(Maik Nauka/Interperiodica/Springer, New York, 2009)

TY  - JOUR
AU  - Blagojević, Slavica
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Pejić, Nataša
AU  - Kolar-Anić, Ljiljana
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/537
AB  - The kinetic investigations of the malonic acid decomposition (8.00 x 10(-3) mol dm(-3) a parts per thousand currency sign [CH(2)(COOH)(2)](0) a parts per thousand currency sign 4.30 x 10(-2) mol dm(-3)) in the Belousov-Zhabotinsky (BZ) system in the presence of bromate, bromide, sulfuric acid and cerium sulfate, were performed in the isothermal closed well stirred reactor at different temperatures (25.0A degrees C a parts per thousand currency sign T a parts per thousand currency sign 45.0A degrees C). The formal kinetics of the overall BZ reaction, and particularly kinetics in characteristic periods of BZ reaction, based on the analyses of the bromide oscillograms, was accomplished. The evolution as well as the rate constants and the apparent activation energies of the reactions, which exist in the preoscillatory and oscillatory periods, are also successfully calculated by numerical simulations. Simulations are based on the model including the Br(2)O species.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction
VL  - 83
IS  - 9
SP  - 1496
EP  - 1501
DO  - 10.1134/S0036024409090143
ER  - 
@article{
author = "Blagojević, Slavica and Anić, Slobodan and Čupić, Željko and Pejić, Nataša and Kolar-Anić, Ljiljana",
year = "2009",
abstract = "The kinetic investigations of the malonic acid decomposition (8.00 x 10(-3) mol dm(-3) a parts per thousand currency sign [CH(2)(COOH)(2)](0) a parts per thousand currency sign 4.30 x 10(-2) mol dm(-3)) in the Belousov-Zhabotinsky (BZ) system in the presence of bromate, bromide, sulfuric acid and cerium sulfate, were performed in the isothermal closed well stirred reactor at different temperatures (25.0A degrees C a parts per thousand currency sign T a parts per thousand currency sign 45.0A degrees C). The formal kinetics of the overall BZ reaction, and particularly kinetics in characteristic periods of BZ reaction, based on the analyses of the bromide oscillograms, was accomplished. The evolution as well as the rate constants and the apparent activation energies of the reactions, which exist in the preoscillatory and oscillatory periods, are also successfully calculated by numerical simulations. Simulations are based on the model including the Br(2)O species.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction",
volume = "83",
number = "9",
pages = "1496-1501",
doi = "10.1134/S0036024409090143"
}
Blagojević, S., Anić, S., Čupić, Ž., Pejić, N.,& Kolar-Anić, L.. (2009). Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1496-1501.
https://doi.org/10.1134/S0036024409090143
Blagojević S, Anić S, Čupić Ž, Pejić N, Kolar-Anić L. Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction. in Russian Journal of Physical Chemistry A. 2009;83(9):1496-1501.
doi:10.1134/S0036024409090143 .
Blagojević, Slavica, Anić, Slobodan, Čupić, Željko, Pejić, Nataša, Kolar-Anić, Ljiljana, "Temperature influence on the malonic acid decomposition in the Belousov-Zhabotinsky reaction" in Russian Journal of Physical Chemistry A, 83, no. 9 (2009):1496-1501,
https://doi.org/10.1134/S0036024409090143 . .
4
6
6

The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor

Ivanović-Šašić, Ana; Čupić, Željko; Janković, Marija M.; Kolar-Anić, Ljiljana; Anić, Slobodan

(Royal Soc Chemistry, Cambridge, 2008)

TY  - JOUR
AU  - Ivanović-Šašić, Ana
AU  - Čupić, Željko
AU  - Janković, Marija M.
AU  - Kolar-Anić, Ljiljana
AU  - Anić, Slobodan
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/382
AB  - Attractor reconstruction is done from the time series obtained by experimental investigation and by deterministic and stochastic simulation of the Bray-Liebhafsky oscillatory reaction. The appearance of deterministic chaos is confirmed and proven by both simulation and experiment, determining Lyapunov exponents for the sequences of flow rate values, as the control parameter. Moreover, unusual chaotic series were additionally recorded in the experiments, which cannot be found in deterministic numerical simulations. Therefore, an explanation of the difference between the dynamic behavior in the experiment and the deterministic simulation was sought and stochastic simulations based on the same reaction model were particularly useful. The. ne structure of the chaotic windows, derived from the analysis of deterministic simulations in the range of flow rate values, made the system highly susceptible to noise induced effects, in general.
PB  - Royal Soc Chemistry, Cambridge
T2  - Physical Chemistry Chemical Physics
T1  - The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor
VL  - 10
IS  - 38
SP  - 5848
EP  - 5858
DO  - 10.1039/b804580a
ER  - 
@article{
author = "Ivanović-Šašić, Ana and Čupić, Željko and Janković, Marija M. and Kolar-Anić, Ljiljana and Anić, Slobodan",
year = "2008",
abstract = "Attractor reconstruction is done from the time series obtained by experimental investigation and by deterministic and stochastic simulation of the Bray-Liebhafsky oscillatory reaction. The appearance of deterministic chaos is confirmed and proven by both simulation and experiment, determining Lyapunov exponents for the sequences of flow rate values, as the control parameter. Moreover, unusual chaotic series were additionally recorded in the experiments, which cannot be found in deterministic numerical simulations. Therefore, an explanation of the difference between the dynamic behavior in the experiment and the deterministic simulation was sought and stochastic simulations based on the same reaction model were particularly useful. The. ne structure of the chaotic windows, derived from the analysis of deterministic simulations in the range of flow rate values, made the system highly susceptible to noise induced effects, in general.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Physical Chemistry Chemical Physics",
title = "The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor",
volume = "10",
number = "38",
pages = "5848-5858",
doi = "10.1039/b804580a"
}
Ivanović-Šašić, A., Čupić, Ž., Janković, M. M., Kolar-Anić, L.,& Anić, S.. (2008). The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor. in Physical Chemistry Chemical Physics
Royal Soc Chemistry, Cambridge., 10(38), 5848-5858.
https://doi.org/10.1039/b804580a
Ivanović-Šašić A, Čupić Ž, Janković MM, Kolar-Anić L, Anić S. The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor. in Physical Chemistry Chemical Physics. 2008;10(38):5848-5858.
doi:10.1039/b804580a .
Ivanović-Šašić, Ana, Čupić, Željko, Janković, Marija M., Kolar-Anić, Ljiljana, Anić, Slobodan, "The chaotic sequences in the Bray-Liebhafsky reaction in an open reactor" in Physical Chemistry Chemical Physics, 10, no. 38 (2008):5848-5858,
https://doi.org/10.1039/b804580a . .
22
23
27

Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction

Schmitz, Guy; Kolar-Anić, Ljiljana; Anić, Slobodan; Čupić, Željko

(American Chemical Society (ACS), 2008)

TY  - JOUR
AU  - Schmitz, Guy
AU  - Kolar-Anić, Ljiljana
AU  - Anić, Slobodan
AU  - Čupić, Željko
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/385
AB  - The stoichiometric network analysis (SNA) introduced by B. L. Clarke is applied to a simplified model of the complex oscillating Bray-Liebhafsky reaction under batch conditions, which was not examined by this method earlier. This powerful method for the analysis of steady-states stability is also used to transform the classical differential equations into dimensionless equations. This transformation is easy and leads to a form of the equations combining the advantages of classical dimensionless equations with the advantages of the SNA. The used dimensionless parameters have orders of magnitude given by the experimental information about concentrations and currents. This simplifies greatly the study of the slow manifold and shows which parameters are essential for controlling its shape and consequently have an important influence oil the trajectories. The effectiveness of these equations is illustrated on two examples: the study of the bifurcations points and a simple sensitivity analysis, different from the classical one, more based on the chemistry of the studied system.
PB  - American Chemical Society (ACS)
T2  - Journal of Physical Chemistry A
T1  - Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction
VL  - 112
IS  - 51
SP  - 13452
EP  - 13457
DO  - 10.1021/jp8056674
ER  - 
@article{
author = "Schmitz, Guy and Kolar-Anić, Ljiljana and Anić, Slobodan and Čupić, Željko",
year = "2008",
abstract = "The stoichiometric network analysis (SNA) introduced by B. L. Clarke is applied to a simplified model of the complex oscillating Bray-Liebhafsky reaction under batch conditions, which was not examined by this method earlier. This powerful method for the analysis of steady-states stability is also used to transform the classical differential equations into dimensionless equations. This transformation is easy and leads to a form of the equations combining the advantages of classical dimensionless equations with the advantages of the SNA. The used dimensionless parameters have orders of magnitude given by the experimental information about concentrations and currents. This simplifies greatly the study of the slow manifold and shows which parameters are essential for controlling its shape and consequently have an important influence oil the trajectories. The effectiveness of these equations is illustrated on two examples: the study of the bifurcations points and a simple sensitivity analysis, different from the classical one, more based on the chemistry of the studied system.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Physical Chemistry A",
title = "Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction",
volume = "112",
number = "51",
pages = "13452-13457",
doi = "10.1021/jp8056674"
}
Schmitz, G., Kolar-Anić, L., Anić, S.,& Čupić, Ž.. (2008). Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction. in Journal of Physical Chemistry A
American Chemical Society (ACS)., 112(51), 13452-13457.
https://doi.org/10.1021/jp8056674
Schmitz G, Kolar-Anić L, Anić S, Čupić Ž. Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction. in Journal of Physical Chemistry A. 2008;112(51):13452-13457.
doi:10.1021/jp8056674 .
Schmitz, Guy, Kolar-Anić, Ljiljana, Anić, Slobodan, Čupić, Željko, "Stoichiometric Network Analysis and Associated Dimensionless Kinetic Equations. Application to a Model of the Bray-Liebhafsky Reaction" in Journal of Physical Chemistry A, 112, no. 51 (2008):13452-13457,
https://doi.org/10.1021/jp8056674 . .
28
26
32

Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions

Blagojević, Slavica; Anić, Slobodan; Čupić, Željko; Pejić, Nataša; Kolar-Anić, Ljiljana

(Royal Soc Chemistry, Cambridge, 2008)

TY  - JOUR
AU  - Blagojević, Slavica
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Pejić, Nataša
AU  - Kolar-Anić, Ljiljana
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/396
AB  - The influence of the initial malonic acid concentration [MA](0) (8.00 x 10(-3)  LT = [MA](0)  LT = 4.30 x 10(-2) mol dm(-3)) in the presence of bromate (6.20 x 10(-2) mol dm(-3)), bromide (1.50 x 10(-5) mol dm(-3)), sulfuric acid (1.00 mol dm(-3)) and cerium sulfate (2.50 x 10(-3) mol dm(-3)) on the dynamics and the kinetics of the Belousov-Zhabotinsky (BZ) reactions was examined under batch conditions at 30.0 degrees C. The kinetics of the BZ reaction was analyzed by the earlier proposed method convenient for the examinations of the oscillatory reactions. In the defined region of parameters where oscillograms with only large-amplitude relaxation oscillations appeared, the pseudo-first order of the overall malonic acid decomposition with a corresponding rate constant of 2.14 x 10(-2) min(-1) was established. The numerical results on the dynamics and kinetics of the BZ reaction, carried out by the known skeleton model including the Br2O species, were in good agreement with the experimental ones. The already found saddle node infinite period (SNIPER) bifurcation point in transition from a stable quasi-steady state to periodic orbits and vice versa is confirmed by both experimental and numerical investigations of the system under consideration. Namely, the large-amplitude relaxation oscillations with increasing periods between oscillations in approaching the bifurcation points at the beginning and the end of the oscillatory domain, together with excitability of the stable quasi-steady states in their vicinity are obtained.
PB  - Royal Soc Chemistry, Cambridge
T2  - Physical Chemistry Chemical Physics
T1  - Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions
VL  - 10
IS  - 44
SP  - 6658
EP  - 6664
DO  - 10.1039/b804919j
ER  - 
@article{
author = "Blagojević, Slavica and Anić, Slobodan and Čupić, Željko and Pejić, Nataša and Kolar-Anić, Ljiljana",
year = "2008",
abstract = "The influence of the initial malonic acid concentration [MA](0) (8.00 x 10(-3)  LT = [MA](0)  LT = 4.30 x 10(-2) mol dm(-3)) in the presence of bromate (6.20 x 10(-2) mol dm(-3)), bromide (1.50 x 10(-5) mol dm(-3)), sulfuric acid (1.00 mol dm(-3)) and cerium sulfate (2.50 x 10(-3) mol dm(-3)) on the dynamics and the kinetics of the Belousov-Zhabotinsky (BZ) reactions was examined under batch conditions at 30.0 degrees C. The kinetics of the BZ reaction was analyzed by the earlier proposed method convenient for the examinations of the oscillatory reactions. In the defined region of parameters where oscillograms with only large-amplitude relaxation oscillations appeared, the pseudo-first order of the overall malonic acid decomposition with a corresponding rate constant of 2.14 x 10(-2) min(-1) was established. The numerical results on the dynamics and kinetics of the BZ reaction, carried out by the known skeleton model including the Br2O species, were in good agreement with the experimental ones. The already found saddle node infinite period (SNIPER) bifurcation point in transition from a stable quasi-steady state to periodic orbits and vice versa is confirmed by both experimental and numerical investigations of the system under consideration. Namely, the large-amplitude relaxation oscillations with increasing periods between oscillations in approaching the bifurcation points at the beginning and the end of the oscillatory domain, together with excitability of the stable quasi-steady states in their vicinity are obtained.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Physical Chemistry Chemical Physics",
title = "Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions",
volume = "10",
number = "44",
pages = "6658-6664",
doi = "10.1039/b804919j"
}
Blagojević, S., Anić, S., Čupić, Ž., Pejić, N.,& Kolar-Anić, L.. (2008). Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions. in Physical Chemistry Chemical Physics
Royal Soc Chemistry, Cambridge., 10(44), 6658-6664.
https://doi.org/10.1039/b804919j
Blagojević S, Anić S, Čupić Ž, Pejić N, Kolar-Anić L. Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions. in Physical Chemistry Chemical Physics. 2008;10(44):6658-6664.
doi:10.1039/b804919j .
Blagojević, Slavica, Anić, Slobodan, Čupić, Željko, Pejić, Nataša, Kolar-Anić, Ljiljana, "Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov-Zhabotinsky reaction under batch conditions" in Physical Chemistry Chemical Physics, 10, no. 44 (2008):6658-6664,
https://doi.org/10.1039/b804919j . .
26
26
30

Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel

Adnađević, Borivoj; Jovanović, Jelena; Drakulić, Branko

(Elsevier, 2007)

TY  - JOUR
AU  - Adnađević, Borivoj
AU  - Jovanović, Jelena
AU  - Drakulić, Branko
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3191
AB  - The isothermal kinetics of the release of the drug (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid (MEPBA) from poly(acrylic acid) hydrogel were studied. The isothermal kinetic curves of MEPBA release from the poly(acrylic acid) hydrogel in bidistilled water at different temperatures ranging from 22 °C to 42 °C were determined. The reaction rate constants of the investigated process were determined using the initial rate, saturation rate and power law. Also, to quickly determine the kinetic model of drug release, the so-called method of reduced time was applied. The influence of the degree of the MEPBA released (α) at the values of the kinetic parameters as well as the presence of a compensation effect was established. The procedure for determining the distribution function of activation energies was developed. This procedure was based on the experimentally determined relationship between the activation energy and the degree of drug released. The process of MEPBA release from PAA hydrogel, almost in entire range, can be described with the model of the drug desorption from the active centers with different specific energies.
PB  - Elsevier
T2  - Thermochimica Acta
T1  - Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel
VL  - 466
IS  - 1-2
SP  - 38
EP  - 48
DO  - 10.1016/j.tca.2007.10.009
ER  - 
@article{
author = "Adnađević, Borivoj and Jovanović, Jelena and Drakulić, Branko",
year = "2007",
abstract = "The isothermal kinetics of the release of the drug (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid (MEPBA) from poly(acrylic acid) hydrogel were studied. The isothermal kinetic curves of MEPBA release from the poly(acrylic acid) hydrogel in bidistilled water at different temperatures ranging from 22 °C to 42 °C were determined. The reaction rate constants of the investigated process were determined using the initial rate, saturation rate and power law. Also, to quickly determine the kinetic model of drug release, the so-called method of reduced time was applied. The influence of the degree of the MEPBA released (α) at the values of the kinetic parameters as well as the presence of a compensation effect was established. The procedure for determining the distribution function of activation energies was developed. This procedure was based on the experimentally determined relationship between the activation energy and the degree of drug released. The process of MEPBA release from PAA hydrogel, almost in entire range, can be described with the model of the drug desorption from the active centers with different specific energies.",
publisher = "Elsevier",
journal = "Thermochimica Acta",
title = "Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel",
volume = "466",
number = "1-2",
pages = "38-48",
doi = "10.1016/j.tca.2007.10.009"
}
Adnađević, B., Jovanović, J.,& Drakulić, B.. (2007). Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel. in Thermochimica Acta
Elsevier., 466(1-2), 38-48.
https://doi.org/10.1016/j.tca.2007.10.009
Adnađević B, Jovanović J, Drakulić B. Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel. in Thermochimica Acta. 2007;466(1-2):38-48.
doi:10.1016/j.tca.2007.10.009 .
Adnađević, Borivoj, Jovanović, Jelena, Drakulić, Branko, "Isothermal kinetics of (E)-4-(4-metoxyphenyl)-4-oxo-2-butenoic acid release from poly(acrylic acid) hydrogel" in Thermochimica Acta, 466, no. 1-2 (2007):38-48,
https://doi.org/10.1016/j.tca.2007.10.009 . .
19
24
25

Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States

Anić, Slobodan; Kostić, M.; Ninić, Marko; Blagojević, Stevan; Kolar-Anić, Ljiljana

(Belgrade: ETRAN – Society for electronics, telecommunication, computing, automatics and nuclear engineering, 2007)

TY  - JOUR
AU  - Anić, Slobodan
AU  - Kostić, M.
AU  - Ninić, Marko
AU  - Blagojević, Stevan
AU  - Kolar-Anić, Ljiljana
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4258
AB  - Modeling of any complex reaction system is a difficult task. If the system under examination can be in various oscillatory dynamic states, the apparent activation energies corresponding to different pathways may be of crucial importance for this purpose. In that case the activation energies can be determined by means of the main characteristics of an oscillatory process such as pre-oscillatory period, duration of the oscillatory period, the period from the beginning of the process to the end of the last oscillation, number of oscillations and others. All is illustrated on the Bray-Liebhafsky oscillatory reaction.
AB  - Моделирање ма ког комплексног рекакционог система је тежак задатак. Ако испитивани систем може да постоји у различитим осцилаторним динамичким стањима, привидне енергије активације, које одговарају различитим реакционим путевима, могу бити од битне важности за моделирање. У том случају енергије активације могу бити одређене помоћу основних особина осцилаторног процеса као што су предосцилаторни период, трајање осцилаторног периода, период од почетка процеса до заршетка задње осцилације, број осцилација и других. Све ово је објашњено на Bray-Liebhfasky осцилаторној реакцији.
PB  - Belgrade: ETRAN – Society for electronics, telecommunication, computing, automatics and nuclear engineering
T2  - Science of Sintering
T1  - Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States
VL  - 39
IS  - 1
SP  - 77
EP  - 83
DO  - 10.2298/SOS0701077A
ER  - 
@article{
author = "Anić, Slobodan and Kostić, M. and Ninić, Marko and Blagojević, Stevan and Kolar-Anić, Ljiljana",
year = "2007",
abstract = "Modeling of any complex reaction system is a difficult task. If the system under examination can be in various oscillatory dynamic states, the apparent activation energies corresponding to different pathways may be of crucial importance for this purpose. In that case the activation energies can be determined by means of the main characteristics of an oscillatory process such as pre-oscillatory period, duration of the oscillatory period, the period from the beginning of the process to the end of the last oscillation, number of oscillations and others. All is illustrated on the Bray-Liebhafsky oscillatory reaction., Моделирање ма ког комплексног рекакционог система је тежак задатак. Ако испитивани систем може да постоји у различитим осцилаторним динамичким стањима, привидне енергије активације, које одговарају различитим реакционим путевима, могу бити од битне важности за моделирање. У том случају енергије активације могу бити одређене помоћу основних особина осцилаторног процеса као што су предосцилаторни период, трајање осцилаторног периода, период од почетка процеса до заршетка задње осцилације, број осцилација и других. Све ово је објашњено на Bray-Liebhfasky осцилаторној реакцији.",
publisher = "Belgrade: ETRAN – Society for electronics, telecommunication, computing, automatics and nuclear engineering",
journal = "Science of Sintering",
title = "Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States",
volume = "39",
number = "1",
pages = "77-83",
doi = "10.2298/SOS0701077A"
}
Anić, S., Kostić, M., Ninić, M., Blagojević, S.,& Kolar-Anić, L.. (2007). Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States. in Science of Sintering
Belgrade: ETRAN – Society for electronics, telecommunication, computing, automatics and nuclear engineering., 39(1), 77-83.
https://doi.org/10.2298/SOS0701077A
Anić S, Kostić M, Ninić M, Blagojević S, Kolar-Anić L. Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States. in Science of Sintering. 2007;39(1):77-83.
doi:10.2298/SOS0701077A .
Anić, Slobodan, Kostić, M., Ninić, Marko, Blagojević, Stevan, Kolar-Anić, Ljiljana, "Activation Energies as the Validity Criterion of a Model for Complex Reactions that can be in Oscillatory States" in Science of Sintering, 39, no. 1 (2007):77-83,
https://doi.org/10.2298/SOS0701077A . .
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Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor

Lončarević, Davor; Krstić, Jugoslav; Banković, Predrag; Anić, Slobodan; Čupić, Željko

(Maik Nauka/Interperiodica/Springer, New York, 2007)

TY  - JOUR
AU  - Lončarević, Davor
AU  - Krstić, Jugoslav
AU  - Banković, Predrag
AU  - Anić, Slobodan
AU  - Čupić, Željko
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/295
AB  - Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was characterized by means of SEM-EDX, FTIR, diffuse reflectance UV-Vis, N-2 sorption, and mercury porosimetry. Activation energies were determined under steady state conditions for the net production of cyclohexanone and cyclohexanol and for cyclohexane and oxygen net consumption. Some activation energies were lower than the ones reported for the uncatalyzed process, indicating that the catalyst played an important role in the initiation of the free-radical reaction.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor
VL  - 81
IS  - 9
SP  - 1398
EP  - 1401
DO  - 10.1134/S0036024407090099
ER  - 
@article{
author = "Lončarević, Davor and Krstić, Jugoslav and Banković, Predrag and Anić, Slobodan and Čupić, Željko",
year = "2007",
abstract = "Polymer-supported Co(II) catalyst was prepared and its activity and selectivity in the partial oxidation of cyclohexane was determined at several temperatures in a polytetrafluoroethylene reactor ( PTFE). The catalyst was characterized by means of SEM-EDX, FTIR, diffuse reflectance UV-Vis, N-2 sorption, and mercury porosimetry. Activation energies were determined under steady state conditions for the net production of cyclohexanone and cyclohexanol and for cyclohexane and oxygen net consumption. Some activation energies were lower than the ones reported for the uncatalyzed process, indicating that the catalyst played an important role in the initiation of the free-radical reaction.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor",
volume = "81",
number = "9",
pages = "1398-1401",
doi = "10.1134/S0036024407090099"
}
Lončarević, D., Krstić, J., Banković, P., Anić, S.,& Čupić, Ž.. (2007). Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 81(9), 1398-1401.
https://doi.org/10.1134/S0036024407090099
Lončarević D, Krstić J, Banković P, Anić S, Čupić Ž. Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor. in Russian Journal of Physical Chemistry A. 2007;81(9):1398-1401.
doi:10.1134/S0036024407090099 .
Lončarević, Davor, Krstić, Jugoslav, Banković, Predrag, Anić, Slobodan, Čupić, Željko, "Temperature dependence of catalytic cyclohexane partial oxidation in a polytetrafluoroethylene reactor" in Russian Journal of Physical Chemistry A, 81, no. 9 (2007):1398-1401,
https://doi.org/10.1134/S0036024407090099 . .
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