Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites

Link to this page

info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172056/RS//

Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (en)
Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (sr)
Uticaj veličine, oblika i strukture nanočestica na njihova svojstva i svojstva nanokompozita (sr_RS)
Authors

Publications

Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol

Carević, Milica V.; Savić, Tatjana D.; Abazović, Nadica D.; Mojović, Miloš D.; Novaković, Tatjana; Čomor, Mirjana

(Elsevier, 2020)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Savić, Tatjana D.
AU  - Abazović, Nadica D.
AU  - Mojović, Miloš D.
AU  - Novaković, Tatjana
AU  - Čomor, Mirjana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3783
AB  - Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g ~ 4.8 and g ~ 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol.
PB  - Elsevier
T2  - Ceramics International
T1  - Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol
VL  - 46
IS  - 5
SP  - 6820
EP  - 6827
DO  - 10.1016/j.ceramint.2019.11.175
ER  - 
@article{
author = "Carević, Milica V. and Savić, Tatjana D. and Abazović, Nadica D. and Mojović, Miloš D. and Novaković, Tatjana and Čomor, Mirjana",
year = "2020",
abstract = "Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g ~ 4.8 and g ~ 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol",
volume = "46",
number = "5",
pages = "6820-6827",
doi = "10.1016/j.ceramint.2019.11.175"
}
Carević, M. V., Savić, T. D., Abazović, N. D., Mojović, M. D., Novaković, T.,& Čomor, M.. (2020). Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International
Elsevier., 46(5), 6820-6827.
https://doi.org/10.1016/j.ceramint.2019.11.175
Carević MV, Savić TD, Abazović ND, Mojović MD, Novaković T, Čomor M. Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International. 2020;46(5):6820-6827.
doi:10.1016/j.ceramint.2019.11.175 .
Carević, Milica V., Savić, Tatjana D., Abazović, Nadica D., Mojović, Miloš D., Novaković, Tatjana, Čomor, Mirjana, "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol" in Ceramics International, 46, no. 5 (2020):6820-6827,
https://doi.org/10.1016/j.ceramint.2019.11.175 . .
11
4
6

Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol

Carević, Milica V.; Savić, Tatjana D.; Abazović, Nadica D.; Mojović, Miloš D.; Novaković, Tatjana; Čomor, Mirjana

(Elsevier, 2020)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Savić, Tatjana D.
AU  - Abazović, Nadica D.
AU  - Mojović, Miloš D.
AU  - Novaković, Tatjana
AU  - Čomor, Mirjana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3851
AB  - Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g ~ 4.8 and g ~ 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol.
PB  - Elsevier
T2  - Ceramics International
T1  - Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol
VL  - 46
IS  - 5
SP  - 6820
EP  - 6827
DO  - 10.1016/j.ceramint.2019.11.175
ER  - 
@article{
author = "Carević, Milica V. and Savić, Tatjana D. and Abazović, Nadica D. and Mojović, Miloš D. and Novaković, Tatjana and Čomor, Mirjana",
year = "2020",
abstract = "Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g ~ 4.8 and g ~ 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol",
volume = "46",
number = "5",
pages = "6820-6827",
doi = "10.1016/j.ceramint.2019.11.175"
}
Carević, M. V., Savić, T. D., Abazović, N. D., Mojović, M. D., Novaković, T.,& Čomor, M.. (2020). Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International
Elsevier., 46(5), 6820-6827.
https://doi.org/10.1016/j.ceramint.2019.11.175
Carević MV, Savić TD, Abazović ND, Mojović MD, Novaković T, Čomor M. Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International. 2020;46(5):6820-6827.
doi:10.1016/j.ceramint.2019.11.175 .
Carević, Milica V., Savić, Tatjana D., Abazović, Nadica D., Mojović, Miloš D., Novaković, Tatjana, Čomor, Mirjana, "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol" in Ceramics International, 46, no. 5 (2020):6820-6827,
https://doi.org/10.1016/j.ceramint.2019.11.175 . .
11
4
9

Binary oxide ceramics for enhanced phenols degradation under simulated Solar light

Carević, Milica V.; Abazović, Nadica D.; Savić, Tatjana D.; Novaković, Tatjana; Pjevic, Dejan J.; Čomor, Mirjana

(Wiley, Hoboken, 2018)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Abazović, Nadica D.
AU  - Savić, Tatjana D.
AU  - Novaković, Tatjana
AU  - Pjevic, Dejan J.
AU  - Čomor, Mirjana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2466
AB  - Solvothermal synthesis of ZrO2-TiO2 binary oxides and pure counterparts at 150 degrees C in water/isopropanol media is presented. Titanium (IV) isopropoxide and zirconium (IV) propoxide were used as precursors. XRD and TEM techniques were used for structural and morphological characterization of obtained samples. XPS spectra of mixed oxide samples were compared in order to correlate composition of samples with surface properties and presence of defects. Relative positions of defect states within band-gaps of semiconductors were estimated from UCPL spectra. UV-Vis DRS spectra revealed that both pure oxides experienced red shift of absorption thresholds compared to reference data. Photocatalytic activities of all samples were probed under simulated Solar light on three model compounds: phenol, 4-chlorophenol (4-CP) and 2, 4, 6-trichlorphenol (TCP). Pure TiO2 showed the highest photocatalytic activity in the case of phenol. However, pure ZrO2 and binary oxides showed higher photoactivity in degradation of 4-CP and TCP. The activity of wide band-gap semiconductors under simulated Solar light in photodegradation of phenol and its derivatives is most probably the consequence of formation of charge transfer complexes between pollutant molecules and semiconductors surface.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Binary oxide ceramics for enhanced phenols degradation under simulated Solar light
VL  - 101
IS  - 4
SP  - 1420
EP  - 1431
DO  - 10.1111/jace.15324
ER  - 
@article{
author = "Carević, Milica V. and Abazović, Nadica D. and Savić, Tatjana D. and Novaković, Tatjana and Pjevic, Dejan J. and Čomor, Mirjana",
year = "2018",
abstract = "Solvothermal synthesis of ZrO2-TiO2 binary oxides and pure counterparts at 150 degrees C in water/isopropanol media is presented. Titanium (IV) isopropoxide and zirconium (IV) propoxide were used as precursors. XRD and TEM techniques were used for structural and morphological characterization of obtained samples. XPS spectra of mixed oxide samples were compared in order to correlate composition of samples with surface properties and presence of defects. Relative positions of defect states within band-gaps of semiconductors were estimated from UCPL spectra. UV-Vis DRS spectra revealed that both pure oxides experienced red shift of absorption thresholds compared to reference data. Photocatalytic activities of all samples were probed under simulated Solar light on three model compounds: phenol, 4-chlorophenol (4-CP) and 2, 4, 6-trichlorphenol (TCP). Pure TiO2 showed the highest photocatalytic activity in the case of phenol. However, pure ZrO2 and binary oxides showed higher photoactivity in degradation of 4-CP and TCP. The activity of wide band-gap semiconductors under simulated Solar light in photodegradation of phenol and its derivatives is most probably the consequence of formation of charge transfer complexes between pollutant molecules and semiconductors surface.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Binary oxide ceramics for enhanced phenols degradation under simulated Solar light",
volume = "101",
number = "4",
pages = "1420-1431",
doi = "10.1111/jace.15324"
}
Carević, M. V., Abazović, N. D., Savić, T. D., Novaković, T., Pjevic, D. J.,& Čomor, M.. (2018). Binary oxide ceramics for enhanced phenols degradation under simulated Solar light. in Journal of the American Ceramic Society
Wiley, Hoboken., 101(4), 1420-1431.
https://doi.org/10.1111/jace.15324
Carević MV, Abazović ND, Savić TD, Novaković T, Pjevic DJ, Čomor M. Binary oxide ceramics for enhanced phenols degradation under simulated Solar light. in Journal of the American Ceramic Society. 2018;101(4):1420-1431.
doi:10.1111/jace.15324 .
Carević, Milica V., Abazović, Nadica D., Savić, Tatjana D., Novaković, Tatjana, Pjevic, Dejan J., Čomor, Mirjana, "Binary oxide ceramics for enhanced phenols degradation under simulated Solar light" in Journal of the American Ceramic Society, 101, no. 4 (2018):1420-1431,
https://doi.org/10.1111/jace.15324 . .
8
7
8

Binary oxide ceramics for enhanced phenols degradation under simulated Solar light

Carević, Milica V.; Abazović, Nadica D.; Savić, Tatjana D.; Novaković, Tatjana; Pjevic, Dejan J.; Čomor, Mirjana

(Wiley, Hoboken, 2018)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Abazović, Nadica D.
AU  - Savić, Tatjana D.
AU  - Novaković, Tatjana
AU  - Pjevic, Dejan J.
AU  - Čomor, Mirjana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4285
AB  - Solvothermal synthesis of ZrO2-TiO2 binary oxides and pure counterparts at 150 degrees C in water/isopropanol media is presented. Titanium (IV) isopropoxide and zirconium (IV) propoxide were used as precursors. XRD and TEM techniques were used for structural and morphological characterization of obtained samples. XPS spectra of mixed oxide samples were compared in order to correlate composition of samples with surface properties and presence of defects. Relative positions of defect states within band-gaps of semiconductors were estimated from UCPL spectra. UV-Vis DRS spectra revealed that both pure oxides experienced red shift of absorption thresholds compared to reference data. Photocatalytic activities of all samples were probed under simulated Solar light on three model compounds: phenol, 4-chlorophenol (4-CP) and 2, 4, 6-trichlorphenol (TCP). Pure TiO2 showed the highest photocatalytic activity in the case of phenol. However, pure ZrO2 and binary oxides showed higher photoactivity in degradation of 4-CP and TCP. The activity of wide band-gap semiconductors under simulated Solar light in photodegradation of phenol and its derivatives is most probably the consequence of formation of charge transfer complexes between pollutant molecules and semiconductors surface.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Binary oxide ceramics for enhanced phenols degradation under simulated Solar light
VL  - 101
IS  - 4
SP  - 1420
EP  - 1431
DO  - 10.1111/jace.15324
ER  - 
@article{
author = "Carević, Milica V. and Abazović, Nadica D. and Savić, Tatjana D. and Novaković, Tatjana and Pjevic, Dejan J. and Čomor, Mirjana",
year = "2018",
abstract = "Solvothermal synthesis of ZrO2-TiO2 binary oxides and pure counterparts at 150 degrees C in water/isopropanol media is presented. Titanium (IV) isopropoxide and zirconium (IV) propoxide were used as precursors. XRD and TEM techniques were used for structural and morphological characterization of obtained samples. XPS spectra of mixed oxide samples were compared in order to correlate composition of samples with surface properties and presence of defects. Relative positions of defect states within band-gaps of semiconductors were estimated from UCPL spectra. UV-Vis DRS spectra revealed that both pure oxides experienced red shift of absorption thresholds compared to reference data. Photocatalytic activities of all samples were probed under simulated Solar light on three model compounds: phenol, 4-chlorophenol (4-CP) and 2, 4, 6-trichlorphenol (TCP). Pure TiO2 showed the highest photocatalytic activity in the case of phenol. However, pure ZrO2 and binary oxides showed higher photoactivity in degradation of 4-CP and TCP. The activity of wide band-gap semiconductors under simulated Solar light in photodegradation of phenol and its derivatives is most probably the consequence of formation of charge transfer complexes between pollutant molecules and semiconductors surface.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Binary oxide ceramics for enhanced phenols degradation under simulated Solar light",
volume = "101",
number = "4",
pages = "1420-1431",
doi = "10.1111/jace.15324"
}
Carević, M. V., Abazović, N. D., Savić, T. D., Novaković, T., Pjevic, D. J.,& Čomor, M.. (2018). Binary oxide ceramics for enhanced phenols degradation under simulated Solar light. in Journal of the American Ceramic Society
Wiley, Hoboken., 101(4), 1420-1431.
https://doi.org/10.1111/jace.15324
Carević MV, Abazović ND, Savić TD, Novaković T, Pjevic DJ, Čomor M. Binary oxide ceramics for enhanced phenols degradation under simulated Solar light. in Journal of the American Ceramic Society. 2018;101(4):1420-1431.
doi:10.1111/jace.15324 .
Carević, Milica V., Abazović, Nadica D., Savić, Tatjana D., Novaković, Tatjana, Pjevic, Dejan J., Čomor, Mirjana, "Binary oxide ceramics for enhanced phenols degradation under simulated Solar light" in Journal of the American Ceramic Society, 101, no. 4 (2018):1420-1431,
https://doi.org/10.1111/jace.15324 . .
8
7
7

Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites

Radoicic, Marija; Ciric-Marjanovic, Gordana; Spasojevic, Vuk; Ahrenkiel, Scott Phillip; Mitrić, Miodrag; Novaković, Tatjana; Šaponjić, Zoran

(Elsevier, 2017)

TY  - JOUR
AU  - Radoicic, Marija
AU  - Ciric-Marjanovic, Gordana
AU  - Spasojevic, Vuk
AU  - Ahrenkiel, Scott Phillip
AU  - Mitrić, Miodrag
AU  - Novaković, Tatjana
AU  - Šaponjić, Zoran
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2238
AB  - A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites
VL  - 213
SP  - 155
EP  - 166
DO  - 10.1016/j.apcatb.2017.05.023
ER  - 
@article{
author = "Radoicic, Marija and Ciric-Marjanovic, Gordana and Spasojevic, Vuk and Ahrenkiel, Scott Phillip and Mitrić, Miodrag and Novaković, Tatjana and Šaponjić, Zoran",
year = "2017",
abstract = "A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites",
volume = "213",
pages = "155-166",
doi = "10.1016/j.apcatb.2017.05.023"
}
Radoicic, M., Ciric-Marjanovic, G., Spasojevic, V., Ahrenkiel, S. P., Mitrić, M., Novaković, T.,& Šaponjić, Z.. (2017). Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental
Elsevier., 213, 155-166.
https://doi.org/10.1016/j.apcatb.2017.05.023
Radoicic M, Ciric-Marjanovic G, Spasojevic V, Ahrenkiel SP, Mitrić M, Novaković T, Šaponjić Z. Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental. 2017;213:155-166.
doi:10.1016/j.apcatb.2017.05.023 .
Radoicic, Marija, Ciric-Marjanovic, Gordana, Spasojevic, Vuk, Ahrenkiel, Scott Phillip, Mitrić, Miodrag, Novaković, Tatjana, Šaponjić, Zoran, "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites" in Applied Catalysis B-Environmental, 213 (2017):155-166,
https://doi.org/10.1016/j.apcatb.2017.05.023 . .
64
35
61

Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites

Radoicic, Marija; Ciric-Marjanovic, Gordana; Spasojevic, Vuk; Ahrenkiel, Scott Phillip; Mitrić, Miodrag; Novaković, Tatjana; Šaponjić, Zoran

(Elsevier, 2017)

TY  - JOUR
AU  - Radoicic, Marija
AU  - Ciric-Marjanovic, Gordana
AU  - Spasojevic, Vuk
AU  - Ahrenkiel, Scott Phillip
AU  - Mitrić, Miodrag
AU  - Novaković, Tatjana
AU  - Šaponjić, Zoran
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3018
AB  - A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites
VL  - 213
SP  - 155
EP  - 166
DO  - 10.1016/j.apcatb.2017.05.023
ER  - 
@article{
author = "Radoicic, Marija and Ciric-Marjanovic, Gordana and Spasojevic, Vuk and Ahrenkiel, Scott Phillip and Mitrić, Miodrag and Novaković, Tatjana and Šaponjić, Zoran",
year = "2017",
abstract = "A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites",
volume = "213",
pages = "155-166",
doi = "10.1016/j.apcatb.2017.05.023"
}
Radoicic, M., Ciric-Marjanovic, G., Spasojevic, V., Ahrenkiel, S. P., Mitrić, M., Novaković, T.,& Šaponjić, Z.. (2017). Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental
Elsevier., 213, 155-166.
https://doi.org/10.1016/j.apcatb.2017.05.023
Radoicic M, Ciric-Marjanovic G, Spasojevic V, Ahrenkiel SP, Mitrić M, Novaković T, Šaponjić Z. Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental. 2017;213:155-166.
doi:10.1016/j.apcatb.2017.05.023 .
Radoicic, Marija, Ciric-Marjanovic, Gordana, Spasojevic, Vuk, Ahrenkiel, Scott Phillip, Mitrić, Miodrag, Novaković, Tatjana, Šaponjić, Zoran, "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites" in Applied Catalysis B-Environmental, 213 (2017):155-166,
https://doi.org/10.1016/j.apcatb.2017.05.023 . .
64
35
62

Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.

Carević, Milica V.; Abazović, Nadica D.; Novaković, Tatjana; Pavlović, Vladimir B.; Čomor, Mirjana

(Amsterdam : Elsevier Science BV, 2016)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Abazović, Nadica D.
AU  - Novaković, Tatjana
AU  - Pavlović, Vladimir B.
AU  - Čomor, Mirjana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4295
AB  - We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.
PB  - Amsterdam : Elsevier Science BV
T2  - Applied Catalysis B-Environmental
T1  - Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.
VL  - 195
SP  - 112
EP  - 120
DO  - 10.1016/j.apcatb.2016.05.005
ER  - 
@article{
author = "Carević, Milica V. and Abazović, Nadica D. and Novaković, Tatjana and Pavlović, Vladimir B. and Čomor, Mirjana",
year = "2016",
abstract = "We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.",
publisher = "Amsterdam : Elsevier Science BV",
journal = "Applied Catalysis B-Environmental",
title = "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.",
volume = "195",
pages = "112-120",
doi = "10.1016/j.apcatb.2016.05.005"
}
Carević, M. V., Abazović, N. D., Novaković, T., Pavlović, V. B.,& Čomor, M.. (2016). Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental
Amsterdam : Elsevier Science BV., 195, 112-120.
https://doi.org/10.1016/j.apcatb.2016.05.005
Carević MV, Abazović ND, Novaković T, Pavlović VB, Čomor M. Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental. 2016;195:112-120.
doi:10.1016/j.apcatb.2016.05.005 .
Carević, Milica V., Abazović, Nadica D., Novaković, Tatjana, Pavlović, Vladimir B., Čomor, Mirjana, "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light." in Applied Catalysis B-Environmental, 195 (2016):112-120,
https://doi.org/10.1016/j.apcatb.2016.05.005 . .
1
41
27
35

Characterization of hydrothermaly synthesized zirconia nanopowders

Carević, Milica; Abazović, Nadica; Savić, Tatjana D.; Novaković, Tatjana; Čomor, Mirjana

(Society of Physical Chemists of Serbia, 2016)

TY  - CONF
AU  - Carević, Milica
AU  - Abazović, Nadica
AU  - Savić, Tatjana D.
AU  - Novaković, Tatjana
AU  - Čomor, Mirjana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7458
AB  - In this paper,a hydrothermal method for synthesis of zirconia nanopowders: pure  and  with  incorporated  Si4+ions  is  presented.  Zirconyl  chloride  and tetraethyl  orthosilicate  were  used  as  precursors.  As  prepared  powders  were annealed  at  600  °C  and  their  structural  (XRD),  morphological  (TEM)  and textural  (BET  method)  properties  were  obtained.It  has  been  shown  that  by using   hydrothermal   synthesis   method   pure   monoclinic   ZrO2highly crystalline    powder    can    be    obtainedwithcrystallites    of    about    25nm. Incorporation  of  Si4+ions  induced  stabilization  of  tetragonal  crystalline phase  at  room  temperature,  decreasing  particle  sizes  to  about  3-6  nm  and increasing specific surface area of nanopowders.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry
T1  - Characterization of hydrothermaly synthesized zirconia nanopowders
SP  - 553
EP  - 556
UR  - https://hdl.handle.net/21.15107/rcub_cer_7458
ER  - 
@conference{
author = "Carević, Milica and Abazović, Nadica and Savić, Tatjana D. and Novaković, Tatjana and Čomor, Mirjana",
year = "2016",
abstract = "In this paper,a hydrothermal method for synthesis of zirconia nanopowders: pure  and  with  incorporated  Si4+ions  is  presented.  Zirconyl  chloride  and tetraethyl  orthosilicate  were  used  as  precursors.  As  prepared  powders  were annealed  at  600  °C  and  their  structural  (XRD),  morphological  (TEM)  and textural  (BET  method)  properties  were  obtained.It  has  been  shown  that  by using   hydrothermal   synthesis   method   pure   monoclinic   ZrO2highly crystalline    powder    can    be    obtainedwithcrystallites    of    about    25nm. Incorporation  of  Si4+ions  induced  stabilization  of  tetragonal  crystalline phase  at  room  temperature,  decreasing  particle  sizes  to  about  3-6  nm  and increasing specific surface area of nanopowders.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry",
title = "Characterization of hydrothermaly synthesized zirconia nanopowders",
pages = "553-556",
url = "https://hdl.handle.net/21.15107/rcub_cer_7458"
}
Carević, M., Abazović, N., Savić, T. D., Novaković, T.,& Čomor, M.. (2016). Characterization of hydrothermaly synthesized zirconia nanopowders. in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., 553-556.
https://hdl.handle.net/21.15107/rcub_cer_7458
Carević M, Abazović N, Savić TD, Novaković T, Čomor M. Characterization of hydrothermaly synthesized zirconia nanopowders. in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry. 2016;:553-556.
https://hdl.handle.net/21.15107/rcub_cer_7458 .
Carević, Milica, Abazović, Nadica, Savić, Tatjana D., Novaković, Tatjana, Čomor, Mirjana, "Characterization of hydrothermaly synthesized zirconia nanopowders" in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry (2016):553-556,
https://hdl.handle.net/21.15107/rcub_cer_7458 .

Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.

Carević, Milica V.; Abazović, Nadica D.; Novaković, Tatjana; Pavlović, Vladimir B.; Čomor, Mirjana

(Amsterdam : Elsevier Science BV, 2016)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Abazović, Nadica D.
AU  - Novaković, Tatjana
AU  - Pavlović, Vladimir B.
AU  - Čomor, Mirjana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1859
AB  - We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.
PB  - Amsterdam : Elsevier Science BV
T2  - Applied Catalysis B-Environmental
T1  - Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.
VL  - 195
SP  - 112
EP  - 120
DO  - 10.1016/j.apcatb.2016.05.005
ER  - 
@article{
author = "Carević, Milica V. and Abazović, Nadica D. and Novaković, Tatjana and Pavlović, Vladimir B. and Čomor, Mirjana",
year = "2016",
abstract = "We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.",
publisher = "Amsterdam : Elsevier Science BV",
journal = "Applied Catalysis B-Environmental",
title = "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.",
volume = "195",
pages = "112-120",
doi = "10.1016/j.apcatb.2016.05.005"
}
Carević, M. V., Abazović, N. D., Novaković, T., Pavlović, V. B.,& Čomor, M.. (2016). Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental
Amsterdam : Elsevier Science BV., 195, 112-120.
https://doi.org/10.1016/j.apcatb.2016.05.005
Carević MV, Abazović ND, Novaković T, Pavlović VB, Čomor M. Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental. 2016;195:112-120.
doi:10.1016/j.apcatb.2016.05.005 .
Carević, Milica V., Abazović, Nadica D., Novaković, Tatjana, Pavlović, Vladimir B., Čomor, Mirjana, "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light." in Applied Catalysis B-Environmental, 195 (2016):112-120,
https://doi.org/10.1016/j.apcatb.2016.05.005 . .
1
41
27
38

Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light

Carević, Milica; Abazović, Nadica D.; Savić, Tatjana D.; Novaković, Tatjana; Mojović, Miloš; Čomor, Mirjana

(Elsevier Sci Ltd, Oxford, 2016)

TY  - JOUR
AU  - Carević, Milica
AU  - Abazović, Nadica D.
AU  - Savić, Tatjana D.
AU  - Novaković, Tatjana
AU  - Mojović, Miloš
AU  - Čomor, Mirjana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1982
AB  - We report the successful, low temperature synthesis of pure and Fe-doped titania nanoparticle (NP) powders, using organic Ti- and Fe-precursors. The properties of the synthesized titania based materials were obtained using XRD, UV/vis and EPR spectroscopy and BET measurements. The doping of TiO2 induced a shift in the absorption threshold towards the visible spectral range, compared to pure titania. The process of annealing induced an increase in crystallinity and particle sizes in the obtained materials. The photocatalytic activity, using simulated Solar light (Vitalux lamp), of our samples was checked by following the photodegradation reaction of Rhodamine B and trichlorophenole as model compounds.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light
VL  - 42
IS  - 1
SP  - 1521
EP  - 1529
DO  - 10.1016/j.ceramint.2015.09.100
ER  - 
@article{
author = "Carević, Milica and Abazović, Nadica D. and Savić, Tatjana D. and Novaković, Tatjana and Mojović, Miloš and Čomor, Mirjana",
year = "2016",
abstract = "We report the successful, low temperature synthesis of pure and Fe-doped titania nanoparticle (NP) powders, using organic Ti- and Fe-precursors. The properties of the synthesized titania based materials were obtained using XRD, UV/vis and EPR spectroscopy and BET measurements. The doping of TiO2 induced a shift in the absorption threshold towards the visible spectral range, compared to pure titania. The process of annealing induced an increase in crystallinity and particle sizes in the obtained materials. The photocatalytic activity, using simulated Solar light (Vitalux lamp), of our samples was checked by following the photodegradation reaction of Rhodamine B and trichlorophenole as model compounds.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light",
volume = "42",
number = "1",
pages = "1521-1529",
doi = "10.1016/j.ceramint.2015.09.100"
}
Carević, M., Abazović, N. D., Savić, T. D., Novaković, T., Mojović, M.,& Čomor, M.. (2016). Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light. in Ceramics International
Elsevier Sci Ltd, Oxford., 42(1), 1521-1529.
https://doi.org/10.1016/j.ceramint.2015.09.100
Carević M, Abazović ND, Savić TD, Novaković T, Mojović M, Čomor M. Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light. in Ceramics International. 2016;42(1):1521-1529.
doi:10.1016/j.ceramint.2015.09.100 .
Carević, Milica, Abazović, Nadica D., Savić, Tatjana D., Novaković, Tatjana, Mojović, Miloš, Čomor, Mirjana, "Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light" in Ceramics International, 42, no. 1 (2016):1521-1529,
https://doi.org/10.1016/j.ceramint.2015.09.100 . .
12
9
11

Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light

Carević, Milica; Abazović, Nadica D.; Savić, Tatjana D.; Novaković, Tatjana; Mojović, Miloš; Čomor, Mirjana

(Elsevier, 2016)

TY  - JOUR
AU  - Carević, Milica
AU  - Abazović, Nadica D.
AU  - Savić, Tatjana D.
AU  - Novaković, Tatjana
AU  - Mojović, Miloš
AU  - Čomor, Mirjana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4296
AB  - We report the successful, low temperature synthesis of pure and Fe-doped titania nanoparticle (NP) powders, using organic Ti- and Fe-precursors. The properties of the synthesized titania based materials were obtained using XRD, UV/vis and EPR spectroscopy and BET measurements. The doping of TiO2 induced a shift in the absorption threshold towards the visible spectral range, compared to pure titania. The process of annealing induced an increase in crystallinity and particle sizes in the obtained materials. The photocatalytic activity, using simulated Solar light (Vitalux lamp), of our samples was checked by following the photodegradation reaction of Rhodamine B and trichlorophenole as model compounds.
PB  - Elsevier
T2  - Ceramics International
T1  - Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light
VL  - 42
IS  - 1
SP  - 1521
EP  - 1529
DO  - 10.1016/j.ceramint.2015.09.100
ER  - 
@article{
author = "Carević, Milica and Abazović, Nadica D. and Savić, Tatjana D. and Novaković, Tatjana and Mojović, Miloš and Čomor, Mirjana",
year = "2016",
abstract = "We report the successful, low temperature synthesis of pure and Fe-doped titania nanoparticle (NP) powders, using organic Ti- and Fe-precursors. The properties of the synthesized titania based materials were obtained using XRD, UV/vis and EPR spectroscopy and BET measurements. The doping of TiO2 induced a shift in the absorption threshold towards the visible spectral range, compared to pure titania. The process of annealing induced an increase in crystallinity and particle sizes in the obtained materials. The photocatalytic activity, using simulated Solar light (Vitalux lamp), of our samples was checked by following the photodegradation reaction of Rhodamine B and trichlorophenole as model compounds.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light",
volume = "42",
number = "1",
pages = "1521-1529",
doi = "10.1016/j.ceramint.2015.09.100"
}
Carević, M., Abazović, N. D., Savić, T. D., Novaković, T., Mojović, M.,& Čomor, M.. (2016). Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light. in Ceramics International
Elsevier., 42(1), 1521-1529.
https://doi.org/10.1016/j.ceramint.2015.09.100
Carević M, Abazović ND, Savić TD, Novaković T, Mojović M, Čomor M. Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light. in Ceramics International. 2016;42(1):1521-1529.
doi:10.1016/j.ceramint.2015.09.100 .
Carević, Milica, Abazović, Nadica D., Savić, Tatjana D., Novaković, Tatjana, Mojović, Miloš, Čomor, Mirjana, "Structural, optical and photodegradation properties of pure and Fe-doped titania nanoparticles probed using simulated Solar light" in Ceramics International, 42, no. 1 (2016):1521-1529,
https://doi.org/10.1016/j.ceramint.2015.09.100 . .
12
9
11

Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric

Marković, Darka; Šaponjić, Zoran; Radoičić, Marija B.; Radetić, Tamara; Vodnik, Vesna; Potkonjak, Branislav; Radetić, Maja

(Elsevier, 2015)

TY  - JOUR
AU  - Marković, Darka
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija B.
AU  - Radetić, Tamara
AU  - Vodnik, Vesna
AU  - Potkonjak, Branislav
AU  - Radetić, Maja
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2687
AB  - This study discusses the possibility of using corona pre-treated polypropylene (PP) non-woven fabric as a support for immobilization of colloidal TiO2 and Ag nanoparticles in order to remove dye C.I. Acid Orange 7 from aqueous solution. Dye removal efficiency by sonocatalysis, photocatalysis and sonophotocatalysis was evaluated on corona pre-treated fabric loaded with TiO2 nanoparticles, corona pre-treated fabric double loaded with TiO2 nanoparticles and corona pre-treated fabrics loaded with TiO2 nanoparticles before and after deposition of Ag nanoparticles. In addition, the stability of PP non-woven fabric during these processes was investigated. The substrates were characterized by SEM, EDX and AAS analyses. The change of the dye concentration was evaluated by UV-VIS spectrophotometry. Unlike sonocatalysis and photocatalysis, complete dye removal from both solution and non-woven fabric was obtained already after 240-270 min of sonophotocatalysis. Corona pre-treated PP non-woven fabric loaded with Ag nanoparticles prior to deposition of TiO2 nanoparticles provided excellent degradation efficiency and superior reusability. Sonophotocatalytic degradation of dye in the presence of all investigated samples was the most prominent in acidic conditions. Although this nanocomposite system ensured fast discoloration of dye solution, TOC values of water measured after sonophotocatalysis were not satisfactory because of PP degradation. Therefore, it is suggested to include TOC evaluation in each case study where different supports for TiO2 nanoparticles are used since these nanoparticles may guarantee the dye removal from solution but the stability of support could be problematic causing even more serious environmental impact. (C) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Ultrasonics Sonochemistry
T1  - Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric
VL  - 24
SP  - 221
EP  - 229
DO  - 10.1016/j.ultsonch.2014.11.017
ER  - 
@article{
author = "Marković, Darka and Šaponjić, Zoran and Radoičić, Marija B. and Radetić, Tamara and Vodnik, Vesna and Potkonjak, Branislav and Radetić, Maja",
year = "2015",
abstract = "This study discusses the possibility of using corona pre-treated polypropylene (PP) non-woven fabric as a support for immobilization of colloidal TiO2 and Ag nanoparticles in order to remove dye C.I. Acid Orange 7 from aqueous solution. Dye removal efficiency by sonocatalysis, photocatalysis and sonophotocatalysis was evaluated on corona pre-treated fabric loaded with TiO2 nanoparticles, corona pre-treated fabric double loaded with TiO2 nanoparticles and corona pre-treated fabrics loaded with TiO2 nanoparticles before and after deposition of Ag nanoparticles. In addition, the stability of PP non-woven fabric during these processes was investigated. The substrates were characterized by SEM, EDX and AAS analyses. The change of the dye concentration was evaluated by UV-VIS spectrophotometry. Unlike sonocatalysis and photocatalysis, complete dye removal from both solution and non-woven fabric was obtained already after 240-270 min of sonophotocatalysis. Corona pre-treated PP non-woven fabric loaded with Ag nanoparticles prior to deposition of TiO2 nanoparticles provided excellent degradation efficiency and superior reusability. Sonophotocatalytic degradation of dye in the presence of all investigated samples was the most prominent in acidic conditions. Although this nanocomposite system ensured fast discoloration of dye solution, TOC values of water measured after sonophotocatalysis were not satisfactory because of PP degradation. Therefore, it is suggested to include TOC evaluation in each case study where different supports for TiO2 nanoparticles are used since these nanoparticles may guarantee the dye removal from solution but the stability of support could be problematic causing even more serious environmental impact. (C) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Ultrasonics Sonochemistry",
title = "Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric",
volume = "24",
pages = "221-229",
doi = "10.1016/j.ultsonch.2014.11.017"
}
Marković, D., Šaponjić, Z., Radoičić, M. B., Radetić, T., Vodnik, V., Potkonjak, B.,& Radetić, M.. (2015). Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric. in Ultrasonics Sonochemistry
Elsevier., 24, 221-229.
https://doi.org/10.1016/j.ultsonch.2014.11.017
Marković D, Šaponjić Z, Radoičić MB, Radetić T, Vodnik V, Potkonjak B, Radetić M. Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric. in Ultrasonics Sonochemistry. 2015;24:221-229.
doi:10.1016/j.ultsonch.2014.11.017 .
Marković, Darka, Šaponjić, Zoran, Radoičić, Marija B., Radetić, Tamara, Vodnik, Vesna, Potkonjak, Branislav, Radetić, Maja, "Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric" in Ultrasonics Sonochemistry, 24 (2015):221-229,
https://doi.org/10.1016/j.ultsonch.2014.11.017 . .
42
29
42

Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization

Vukoje, Ivana D.; Vodnik, Vesna; Džunuzović, Jasna; Džunuzović, Enis S.; Marinović-Cincović, Milena; Jeremić, Katarina B.; Nedeljković, Jovan M.

(Oxford : Pergamon-Elsevier Science Ltd, 2014)

TY  - JOUR
AU  - Vukoje, Ivana D.
AU  - Vodnik, Vesna
AU  - Džunuzović, Jasna
AU  - Džunuzović, Enis S.
AU  - Marinović-Cincović, Milena
AU  - Jeremić, Katarina B.
AU  - Nedeljković, Jovan M.
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1531
AB  - Nanocomposites (NCs) with different content of silver nanoparticles (Ag NPs) embeded in polystyrene (PS) matrix were prepared by in situ bulk radical polymerization. The nearly monodisperse Ag NPs protected with oleylamine were synthesized via organic solvo-thermal method and further used as a filler. The as-prepared spherical Ag NPs with diameter of 7.0 +/- 1.5 nm were well dispersed in the PS matrix. The structural properties of the resulting Ag/PS NCs were characterized by transmission electron microscope (TEM) and Fourier transform infrared (FTIR) spectroscopy, while optical properties were characterized using optical absorption measurements. The gel permeation chromatography (GPC) measurements showed that the presence of Ag NPs stabilized with oleylamine has no influence on the molecular weight and polydispersity of the PS matrix. The influence of silver content on the thermal properties of Ag/PS NCs was investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that resistance of PS to thermal degradation was improved upon incorporation of Ag NPs. The Ag/PS NCs have lower glass transition temperatures than net PS because loosely packed oleylamine molecules at the interface caused the increase of free volume and chain segments mobility near the surface of Ag NPs.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Materials Research Bulletin
T1  - Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization
VL  - 49
SP  - 434
EP  - 439
DO  - 10.1016/j.materresbull.2013.09.029
ER  - 
@article{
author = "Vukoje, Ivana D. and Vodnik, Vesna and Džunuzović, Jasna and Džunuzović, Enis S. and Marinović-Cincović, Milena and Jeremić, Katarina B. and Nedeljković, Jovan M.",
year = "2014",
abstract = "Nanocomposites (NCs) with different content of silver nanoparticles (Ag NPs) embeded in polystyrene (PS) matrix were prepared by in situ bulk radical polymerization. The nearly monodisperse Ag NPs protected with oleylamine were synthesized via organic solvo-thermal method and further used as a filler. The as-prepared spherical Ag NPs with diameter of 7.0 +/- 1.5 nm were well dispersed in the PS matrix. The structural properties of the resulting Ag/PS NCs were characterized by transmission electron microscope (TEM) and Fourier transform infrared (FTIR) spectroscopy, while optical properties were characterized using optical absorption measurements. The gel permeation chromatography (GPC) measurements showed that the presence of Ag NPs stabilized with oleylamine has no influence on the molecular weight and polydispersity of the PS matrix. The influence of silver content on the thermal properties of Ag/PS NCs was investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that resistance of PS to thermal degradation was improved upon incorporation of Ag NPs. The Ag/PS NCs have lower glass transition temperatures than net PS because loosely packed oleylamine molecules at the interface caused the increase of free volume and chain segments mobility near the surface of Ag NPs.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Materials Research Bulletin",
title = "Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization",
volume = "49",
pages = "434-439",
doi = "10.1016/j.materresbull.2013.09.029"
}
Vukoje, I. D., Vodnik, V., Džunuzović, J., Džunuzović, E. S., Marinović-Cincović, M., Jeremić, K. B.,& Nedeljković, J. M.. (2014). Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization. in Materials Research Bulletin
Oxford : Pergamon-Elsevier Science Ltd., 49, 434-439.
https://doi.org/10.1016/j.materresbull.2013.09.029
Vukoje ID, Vodnik V, Džunuzović J, Džunuzović ES, Marinović-Cincović M, Jeremić KB, Nedeljković JM. Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization. in Materials Research Bulletin. 2014;49:434-439.
doi:10.1016/j.materresbull.2013.09.029 .
Vukoje, Ivana D., Vodnik, Vesna, Džunuzović, Jasna, Džunuzović, Enis S., Marinović-Cincović, Milena, Jeremić, Katarina B., Nedeljković, Jovan M., "Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization" in Materials Research Bulletin, 49 (2014):434-439,
https://doi.org/10.1016/j.materresbull.2013.09.029 . .
22
16
20

Synthesis and characterization of polystyrene based nanocomposites

Vodnik, Vesna; Džunuzović, Enis S.; Džunuzović, Jasna

(Nova Science Publishers, Inc., 2014)

TY  - CHAP
AU  - Vodnik, Vesna
AU  - Džunuzović, Enis S.
AU  - Džunuzović, Jasna
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1611
AB  - Polystyrene, one of the most important material in the modern plastic industry and one of the major synthetic polymer in use today, offers an extremely broad range of applications, due to its good physical properties and low-cost. Significant change of mechanical, rheological, thermal, optical, fire retardancy and barrier properties of polystyrene has been obtained by its combination with different nanoparticles. Due to the extremely high interface area between nanoparticles and polystyrene, some new properties could also be generated, which are often necessary to provide in order to meet current and future demands for various significant applications in different fields. In this review, recent advances on nanocomposites based on polystyrene and different kinds of nanoparticles will be presented through the results obtained by authors of this chapter and results given in other literature reports. This chapter reviews the current understanding of polystyrene based nanocomposites with three particular topics: (i) the preparation conditions of nanoparticles for their efficient, homogeneous incorporation in polystyrene matrix, (ii) different approaches for the synthesis of nanocomposites based on polystyrene and (iii) the influence of the type, size and shape of incorporated nanoparticles on the properties of the polystyrene based nanocomposites. The potential applications of these nanocomposites are also highlighted.
PB  - Nova Science Publishers, Inc.
T2  - Polystyrene: Synthesis, Characteristics and Applications
T1  - Synthesis and characterization of polystyrene based nanocomposites
SP  - 201
EP  - 240
UR  - https://hdl.handle.net/21.15107/rcub_cer_1611
ER  - 
@inbook{
author = "Vodnik, Vesna and Džunuzović, Enis S. and Džunuzović, Jasna",
year = "2014",
abstract = "Polystyrene, one of the most important material in the modern plastic industry and one of the major synthetic polymer in use today, offers an extremely broad range of applications, due to its good physical properties and low-cost. Significant change of mechanical, rheological, thermal, optical, fire retardancy and barrier properties of polystyrene has been obtained by its combination with different nanoparticles. Due to the extremely high interface area between nanoparticles and polystyrene, some new properties could also be generated, which are often necessary to provide in order to meet current and future demands for various significant applications in different fields. In this review, recent advances on nanocomposites based on polystyrene and different kinds of nanoparticles will be presented through the results obtained by authors of this chapter and results given in other literature reports. This chapter reviews the current understanding of polystyrene based nanocomposites with three particular topics: (i) the preparation conditions of nanoparticles for their efficient, homogeneous incorporation in polystyrene matrix, (ii) different approaches for the synthesis of nanocomposites based on polystyrene and (iii) the influence of the type, size and shape of incorporated nanoparticles on the properties of the polystyrene based nanocomposites. The potential applications of these nanocomposites are also highlighted.",
publisher = "Nova Science Publishers, Inc.",
journal = "Polystyrene: Synthesis, Characteristics and Applications",
booktitle = "Synthesis and characterization of polystyrene based nanocomposites",
pages = "201-240",
url = "https://hdl.handle.net/21.15107/rcub_cer_1611"
}
Vodnik, V., Džunuzović, E. S.,& Džunuzović, J.. (2014). Synthesis and characterization of polystyrene based nanocomposites. in Polystyrene: Synthesis, Characteristics and Applications
Nova Science Publishers, Inc.., 201-240.
https://hdl.handle.net/21.15107/rcub_cer_1611
Vodnik V, Džunuzović ES, Džunuzović J. Synthesis and characterization of polystyrene based nanocomposites. in Polystyrene: Synthesis, Characteristics and Applications. 2014;:201-240.
https://hdl.handle.net/21.15107/rcub_cer_1611 .
Vodnik, Vesna, Džunuzović, Enis S., Džunuzović, Jasna, "Synthesis and characterization of polystyrene based nanocomposites" in Polystyrene: Synthesis, Characteristics and Applications (2014):201-240,
https://hdl.handle.net/21.15107/rcub_cer_1611 .
1

Antibacterial activity of copper nanoparticles

Bogdanović, Una; Lazić, Vesna; Vodnik, Vesna; Budimir, Milica; Marković, Z.; Dimitrijević, S.; Džunuzović, Jasna

(Society of Physical Chemists of Serbia, 2014)

TY  - CONF
AU  - Bogdanović, Una
AU  - Lazić, Vesna
AU  - Vodnik, Vesna
AU  - Budimir, Milica
AU  - Marković, Z.
AU  - Dimitrijević, S.
AU  - Džunuzović, Jasna
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6648
AB  - Copper nanoparticles (CuNPs), with an average particle size of about 5 nm,
was prepared by the simple chemical reduction procedure. TEM and UV–
Vis spectroscopy contributed to the analysis of size and optical properties of
CuNPs, and their antibacterial activity was evaluated toward human
pathogenic bacteria Escherichia coli and Staphylococcus aureus, in a
concentration dependent manner. The changes in the cell membrane
morphology of tested strains were investigated by atomic force microscope
(AFM), after 2 h of their contact with CuNPs. It was found that CuNPs
cause different types of cell membrane disruptions, as well as that S. aureus
bacteria were slightly resistant to the cell membrane damage than E. coli.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry „Physical Chemistry 2014“,  September 22-26, Belgrade
T1  - Antibacterial activity of copper nanoparticles
VL  - 2
SP  - 526
EP  - 529
UR  - https://hdl.handle.net/21.15107/rcub_cer_6648
ER  - 
@conference{
author = "Bogdanović, Una and Lazić, Vesna and Vodnik, Vesna and Budimir, Milica and Marković, Z. and Dimitrijević, S. and Džunuzović, Jasna",
year = "2014",
abstract = "Copper nanoparticles (CuNPs), with an average particle size of about 5 nm,
was prepared by the simple chemical reduction procedure. TEM and UV–
Vis spectroscopy contributed to the analysis of size and optical properties of
CuNPs, and their antibacterial activity was evaluated toward human
pathogenic bacteria Escherichia coli and Staphylococcus aureus, in a
concentration dependent manner. The changes in the cell membrane
morphology of tested strains were investigated by atomic force microscope
(AFM), after 2 h of their contact with CuNPs. It was found that CuNPs
cause different types of cell membrane disruptions, as well as that S. aureus
bacteria were slightly resistant to the cell membrane damage than E. coli.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry „Physical Chemistry 2014“,  September 22-26, Belgrade",
title = "Antibacterial activity of copper nanoparticles",
volume = "2",
pages = "526-529",
url = "https://hdl.handle.net/21.15107/rcub_cer_6648"
}
Bogdanović, U., Lazić, V., Vodnik, V., Budimir, M., Marković, Z., Dimitrijević, S.,& Džunuzović, J.. (2014). Antibacterial activity of copper nanoparticles. in Proceedings - 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry „Physical Chemistry 2014“,  September 22-26, Belgrade
Society of Physical Chemists of Serbia., 2, 526-529.
https://hdl.handle.net/21.15107/rcub_cer_6648
Bogdanović U, Lazić V, Vodnik V, Budimir M, Marković Z, Dimitrijević S, Džunuzović J. Antibacterial activity of copper nanoparticles. in Proceedings - 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry „Physical Chemistry 2014“,  September 22-26, Belgrade. 2014;2:526-529.
https://hdl.handle.net/21.15107/rcub_cer_6648 .
Bogdanović, Una, Lazić, Vesna, Vodnik, Vesna, Budimir, Milica, Marković, Z., Dimitrijević, S., Džunuzović, Jasna, "Antibacterial activity of copper nanoparticles" in Proceedings - 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry „Physical Chemistry 2014“,  September 22-26, Belgrade, 2 (2014):526-529,
https://hdl.handle.net/21.15107/rcub_cer_6648 .

Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites

Vodnik, Vesna; Šaponjić, Zoran; Džunuzović, Jasna; Bogdanovic, Una; Mitrić, Miodrag; Nedeljković, Jovan M.

(Oxford : Pergamon-Elsevier Science Ltd, 2013)

TY  - JOUR
AU  - Vodnik, Vesna
AU  - Šaponjić, Zoran
AU  - Džunuzović, Jasna
AU  - Bogdanovic, Una
AU  - Mitrić, Miodrag
AU  - Nedeljković, Jovan M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1316
AB  - Prismatic and plate-like silver nanoparticles (Ag NPs) were synthesized according to the seed-mediated method. These particles were used as precursors for preparation of homogenous, transparent and colored Ag/poly(vinyl alcohol) (PVA) nanocomposite films with different concentrations of Ag by solution-casting technique. Optical and structural characterization of these nanocomposites includes UV-visible spectroscopy, X-ray diffraction (XRD), FTIR spectroscopy and SEM measurements. Further, the effect of embedded nanoparticles on the thermal properties of the PVA matrix was studied. The value of the glass transition temperature of polymer is found to increase after embedding Ag NPs. Comparison of thermal properties of pure PVA and nanocomposite films showed that the thermo-oxidative stability of polymer slightly increased in the presence of Ag NPs. Furthermore, the effect of the Ag NPs on the crystallinity of polymer was also observed.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Materials Research Bulletin
T1  - Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites
VL  - 48
IS  - 1
SP  - 52
EP  - 57
DO  - 10.1016/j.materresbull.2012.09.059
ER  - 
@article{
author = "Vodnik, Vesna and Šaponjić, Zoran and Džunuzović, Jasna and Bogdanovic, Una and Mitrić, Miodrag and Nedeljković, Jovan M.",
year = "2013",
abstract = "Prismatic and plate-like silver nanoparticles (Ag NPs) were synthesized according to the seed-mediated method. These particles were used as precursors for preparation of homogenous, transparent and colored Ag/poly(vinyl alcohol) (PVA) nanocomposite films with different concentrations of Ag by solution-casting technique. Optical and structural characterization of these nanocomposites includes UV-visible spectroscopy, X-ray diffraction (XRD), FTIR spectroscopy and SEM measurements. Further, the effect of embedded nanoparticles on the thermal properties of the PVA matrix was studied. The value of the glass transition temperature of polymer is found to increase after embedding Ag NPs. Comparison of thermal properties of pure PVA and nanocomposite films showed that the thermo-oxidative stability of polymer slightly increased in the presence of Ag NPs. Furthermore, the effect of the Ag NPs on the crystallinity of polymer was also observed.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Materials Research Bulletin",
title = "Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites",
volume = "48",
number = "1",
pages = "52-57",
doi = "10.1016/j.materresbull.2012.09.059"
}
Vodnik, V., Šaponjić, Z., Džunuzović, J., Bogdanovic, U., Mitrić, M.,& Nedeljković, J. M.. (2013). Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites. in Materials Research Bulletin
Oxford : Pergamon-Elsevier Science Ltd., 48(1), 52-57.
https://doi.org/10.1016/j.materresbull.2012.09.059
Vodnik V, Šaponjić Z, Džunuzović J, Bogdanovic U, Mitrić M, Nedeljković JM. Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites. in Materials Research Bulletin. 2013;48(1):52-57.
doi:10.1016/j.materresbull.2012.09.059 .
Vodnik, Vesna, Šaponjić, Zoran, Džunuzović, Jasna, Bogdanovic, Una, Mitrić, Miodrag, Nedeljković, Jovan M., "Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites" in Materials Research Bulletin, 48, no. 1 (2013):52-57,
https://doi.org/10.1016/j.materresbull.2012.09.059 . .
25
19
25

A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis

Savić, Tatjana D.; Validzic, Ivana Lj; Novaković, Tatjana; Vuković, Zorica; Čomor, Mirjana

(Springer/Plenum Publishers, New York, 2013)

TY  - JOUR
AU  - Savić, Tatjana D.
AU  - Validzic, Ivana Lj
AU  - Novaković, Tatjana
AU  - Vuković, Zorica
AU  - Čomor, Mirjana
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1219
AB  - ZnO/ZnWO4 composite rod-like nanoparticles were synthesized by low-temperature soft solution method at 95 A degrees C with different reaction times (1-120 h), in the presence of non-ionic copolymer surfactant Pluronic F68. Obtained nanoparticles had diameters in the range around 10 nm and length of 30 nm. Optical properties such as reflection and room temperature photoluminescence of obtained samples showed strong dependence on their crystallinity and composition. Photocatalytic activity of ZnO/ZnWO4 nanopowders was checked using photodegradation of selected dyes as model system. Obtained results were correlated with specific surface area, particle sizes, crystallinity and ZnO/ZnWO4 ratio of the samples. As crystallinity of ZnWO4 component in the ZnO/ZnWO4 increase, photocatalytic activity also increases. The main findings can be explained by charge transfer reactions that follow light absorption by ZnO and ZnWO4 in nanocomposite.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Cluster Science
T1  - A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis
VL  - 24
IS  - 3
SP  - 679
EP  - 688
DO  - 10.1007/s10876-013-0562-7
ER  - 
@article{
author = "Savić, Tatjana D. and Validzic, Ivana Lj and Novaković, Tatjana and Vuković, Zorica and Čomor, Mirjana",
year = "2013",
abstract = "ZnO/ZnWO4 composite rod-like nanoparticles were synthesized by low-temperature soft solution method at 95 A degrees C with different reaction times (1-120 h), in the presence of non-ionic copolymer surfactant Pluronic F68. Obtained nanoparticles had diameters in the range around 10 nm and length of 30 nm. Optical properties such as reflection and room temperature photoluminescence of obtained samples showed strong dependence on their crystallinity and composition. Photocatalytic activity of ZnO/ZnWO4 nanopowders was checked using photodegradation of selected dyes as model system. Obtained results were correlated with specific surface area, particle sizes, crystallinity and ZnO/ZnWO4 ratio of the samples. As crystallinity of ZnWO4 component in the ZnO/ZnWO4 increase, photocatalytic activity also increases. The main findings can be explained by charge transfer reactions that follow light absorption by ZnO and ZnWO4 in nanocomposite.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Cluster Science",
title = "A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis",
volume = "24",
number = "3",
pages = "679-688",
doi = "10.1007/s10876-013-0562-7"
}
Savić, T. D., Validzic, I. L., Novaković, T., Vuković, Z.,& Čomor, M.. (2013). A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis. in Journal of Cluster Science
Springer/Plenum Publishers, New York., 24(3), 679-688.
https://doi.org/10.1007/s10876-013-0562-7
Savić TD, Validzic IL, Novaković T, Vuković Z, Čomor M. A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis. in Journal of Cluster Science. 2013;24(3):679-688.
doi:10.1007/s10876-013-0562-7 .
Savić, Tatjana D., Validzic, Ivana Lj, Novaković, Tatjana, Vuković, Zorica, Čomor, Mirjana, "A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis" in Journal of Cluster Science, 24, no. 3 (2013):679-688,
https://doi.org/10.1007/s10876-013-0562-7 . .
12
8
13

Silver/polystyrene nanocomposites: Optical and thermal properties

Vodnik, Vesna; Bozanic, Dusan K.; Džunuzović, Jasna; Vukoje, Ivana; Nedeljković, Jovan M.

(Wiley-Blackwell, Hoboken, 2012)

TY  - JOUR
AU  - Vodnik, Vesna
AU  - Bozanic, Dusan K.
AU  - Džunuzović, Jasna
AU  - Vukoje, Ivana
AU  - Nedeljković, Jovan M.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1018
AB  - Nanocomposites consisted of different quantities of silver (Ag) nanoparticles incorporated in a polystyrene (PS) matrix have been prepared by solution mixing method. Transmission electron microscopy was applied to determine the size distribution of the Ag nanoparticles, while the morphology of fractured surfaces of pure PS and Ag/PS nanocomposites was examined by scanning electron microscopy. Absorption spectra of nanocomposites were compared with theoretically calculated spectra based on the Maxwell-Garnett effective medium theory. The influence of Ag content on thermal properties of Ag/PS nanocomposites was investigated by thermogravimetric analysis and differential scanning calorimetry. Thermal and thermo-oxidative stability of the host polymer were improved by introduction of silver nanoparticles. The glass transition temperature of the prepared Ag/PS nanocomposites was lower in comparison with the neat PS and decreased with the increase of the Ag content due to the very weak interfacial interaction between Ag nanoparticles and polymer matrix. POLYM. COMPOS., 2012.
PB  - Wiley-Blackwell, Hoboken
T2  - Polymer Composites
T1  - Silver/polystyrene nanocomposites: Optical and thermal properties
VL  - 33
IS  - 5
SP  - 782
EP  - 788
DO  - 10.1002/pc.22207
ER  - 
@article{
author = "Vodnik, Vesna and Bozanic, Dusan K. and Džunuzović, Jasna and Vukoje, Ivana and Nedeljković, Jovan M.",
year = "2012",
abstract = "Nanocomposites consisted of different quantities of silver (Ag) nanoparticles incorporated in a polystyrene (PS) matrix have been prepared by solution mixing method. Transmission electron microscopy was applied to determine the size distribution of the Ag nanoparticles, while the morphology of fractured surfaces of pure PS and Ag/PS nanocomposites was examined by scanning electron microscopy. Absorption spectra of nanocomposites were compared with theoretically calculated spectra based on the Maxwell-Garnett effective medium theory. The influence of Ag content on thermal properties of Ag/PS nanocomposites was investigated by thermogravimetric analysis and differential scanning calorimetry. Thermal and thermo-oxidative stability of the host polymer were improved by introduction of silver nanoparticles. The glass transition temperature of the prepared Ag/PS nanocomposites was lower in comparison with the neat PS and decreased with the increase of the Ag content due to the very weak interfacial interaction between Ag nanoparticles and polymer matrix. POLYM. COMPOS., 2012.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "Polymer Composites",
title = "Silver/polystyrene nanocomposites: Optical and thermal properties",
volume = "33",
number = "5",
pages = "782-788",
doi = "10.1002/pc.22207"
}
Vodnik, V., Bozanic, D. K., Džunuzović, J., Vukoje, I.,& Nedeljković, J. M.. (2012). Silver/polystyrene nanocomposites: Optical and thermal properties. in Polymer Composites
Wiley-Blackwell, Hoboken., 33(5), 782-788.
https://doi.org/10.1002/pc.22207
Vodnik V, Bozanic DK, Džunuzović J, Vukoje I, Nedeljković JM. Silver/polystyrene nanocomposites: Optical and thermal properties. in Polymer Composites. 2012;33(5):782-788.
doi:10.1002/pc.22207 .
Vodnik, Vesna, Bozanic, Dusan K., Džunuzović, Jasna, Vukoje, Ivana, Nedeljković, Jovan M., "Silver/polystyrene nanocomposites: Optical and thermal properties" in Polymer Composites, 33, no. 5 (2012):782-788,
https://doi.org/10.1002/pc.22207 . .
1
28
19
28

Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations

Vukoje, Ivana; Božanić, Dušan; Džunuzović, Jasna; Bogdanović, Una; Vodnik, Vesna

(Association of Chemical Engineers of Serbia, 2012)

TY  - JOUR
AU  - Vukoje, Ivana
AU  - Božanić, Dušan
AU  - Džunuzović, Jasna
AU  - Bogdanović, Una
AU  - Vodnik, Vesna
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1045
AB  - The aim of this study was to investigate and compare the changes in surface plasmon resonance (SPR) of silver (Ag) hydrosol and organosols obtained by experimental and theoretical approaches. Silver nanoparticles (Ag NPs) of 5±1.5 nm in diameter were prepared in water by reduction of silver nitrate with sodium borohydride. Nanoparticles were subsequently transferred into different organic solvents (chloroform, hexane, toluene, 1,2-di- chlorobenzene) using oleylamine as a transfer agent. These solvents were chosen because of the differences in their refractive indices. Using UV-Vis absorption spectrophotometry and transmission electron microscopy (TEM), we confirmed that there were no shape and size changes of the nanoparticles upon the transfer to the organic phase. The absorption spectra of the obtained Ag organosols showed changes only in the position of the SPR band depending on the dielectric property of the used solvent. To analyze these changes, absorption spectra were modelled using Mie theory for small spherical particles. The experimental and theoretical resonance values were compared with those predicted by the Drude model and its limitations in the analysis of absorption behavior of Ag NPs in organic solvents were briefly discussed.
AB  - Cilj ovog rada je eksperimentalno i teorijsko ispitivanje i upoređivanje pro- mena površinskih plazmona nanočestica srebra u vodi i organskim rastvaračima. Nanočestice srebra prečnika 5±1,5 nm sintetisane su u vodi redukcijom srebro nitrata pomoću natrijum borhidrida. Nakon toga, nanočestice su prebačene u različite organske rastvarače (hloroform, heksan, toluen i 1,2-dihlorbenzen) pomoću oleilamina. Upotrebljeni rastvarači izabrani su na osnovu razlike u indeksima pre- lamanja. Na osnovu UV-Vis apsorpcione spektrofotometrije i transmisione elektronske mikroskopije (TEM) potvrđeno je da nema promena u obliku i veličini čes- tica nakon transfera u organske rastvarače. Apsorpcioni spektri nanočestica srebra u različitim rastvaračima pokazuju promene u položaju površinskih plazmona na osnovu razlike u dielektričnim karakteristikama upotrebljenih rastvarača. Za analizu ovih promena eksperimentalni apsorpcioni spektri su modelovani pomoću Mie teorije za male sferne čestice. Eksperimentalne i teorijske vrednosti položaja površinskih plazmona nanočestica srebra upoređivane su sa Drude teorijom i diskutovana su ograničenja primene same teorije na ponašanja nanočestica srebra u organskim rastvaračima.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations
T1  - Rezonance površinskih plazmona organosola srebra - eksperimentalna i teorijska ispitivanja
VL  - 66
IS  - 6
SP  - 805
EP  - 812
DO  - 10.2298/HEMIND120112028V
ER  - 
@article{
author = "Vukoje, Ivana and Božanić, Dušan and Džunuzović, Jasna and Bogdanović, Una and Vodnik, Vesna",
year = "2012",
abstract = "The aim of this study was to investigate and compare the changes in surface plasmon resonance (SPR) of silver (Ag) hydrosol and organosols obtained by experimental and theoretical approaches. Silver nanoparticles (Ag NPs) of 5±1.5 nm in diameter were prepared in water by reduction of silver nitrate with sodium borohydride. Nanoparticles were subsequently transferred into different organic solvents (chloroform, hexane, toluene, 1,2-di- chlorobenzene) using oleylamine as a transfer agent. These solvents were chosen because of the differences in their refractive indices. Using UV-Vis absorption spectrophotometry and transmission electron microscopy (TEM), we confirmed that there were no shape and size changes of the nanoparticles upon the transfer to the organic phase. The absorption spectra of the obtained Ag organosols showed changes only in the position of the SPR band depending on the dielectric property of the used solvent. To analyze these changes, absorption spectra were modelled using Mie theory for small spherical particles. The experimental and theoretical resonance values were compared with those predicted by the Drude model and its limitations in the analysis of absorption behavior of Ag NPs in organic solvents were briefly discussed., Cilj ovog rada je eksperimentalno i teorijsko ispitivanje i upoređivanje pro- mena površinskih plazmona nanočestica srebra u vodi i organskim rastvaračima. Nanočestice srebra prečnika 5±1,5 nm sintetisane su u vodi redukcijom srebro nitrata pomoću natrijum borhidrida. Nakon toga, nanočestice su prebačene u različite organske rastvarače (hloroform, heksan, toluen i 1,2-dihlorbenzen) pomoću oleilamina. Upotrebljeni rastvarači izabrani su na osnovu razlike u indeksima pre- lamanja. Na osnovu UV-Vis apsorpcione spektrofotometrije i transmisione elektronske mikroskopije (TEM) potvrđeno je da nema promena u obliku i veličini čes- tica nakon transfera u organske rastvarače. Apsorpcioni spektri nanočestica srebra u različitim rastvaračima pokazuju promene u položaju površinskih plazmona na osnovu razlike u dielektričnim karakteristikama upotrebljenih rastvarača. Za analizu ovih promena eksperimentalni apsorpcioni spektri su modelovani pomoću Mie teorije za male sferne čestice. Eksperimentalne i teorijske vrednosti položaja površinskih plazmona nanočestica srebra upoređivane su sa Drude teorijom i diskutovana su ograničenja primene same teorije na ponašanja nanočestica srebra u organskim rastvaračima.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations, Rezonance površinskih plazmona organosola srebra - eksperimentalna i teorijska ispitivanja",
volume = "66",
number = "6",
pages = "805-812",
doi = "10.2298/HEMIND120112028V"
}
Vukoje, I., Božanić, D., Džunuzović, J., Bogdanović, U.,& Vodnik, V.. (2012). Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations. in Hemijska industrija
Association of Chemical Engineers of Serbia., 66(6), 805-812.
https://doi.org/10.2298/HEMIND120112028V
Vukoje I, Božanić D, Džunuzović J, Bogdanović U, Vodnik V. Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations. in Hemijska industrija. 2012;66(6):805-812.
doi:10.2298/HEMIND120112028V .
Vukoje, Ivana, Božanić, Dušan, Džunuzović, Jasna, Bogdanović, Una, Vodnik, Vesna, "Surface plasmon resonance of Ag organosols: Experimental and theoretical investigations" in Hemijska industrija, 66, no. 6 (2012):805-812,
https://doi.org/10.2298/HEMIND120112028V . .
2
2
2