TY  - JOUR
AU  - Mojović, Zorica
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
AU  - Mentus, Slavko
AU  - Jovanović, Dušan M.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/634
AB  - In order to enhance silver effectiveness for oxygen reduction reaction, pillared clay was used as a support for silver nanodispersion. Silver particles incorporation into pillared clay pores was attempted by impregnation/thermal degradation technique. X-ray diffraction as well as adsorption-desorption isotherms confirmed that pillaring procedure was successful. Scanning electron microscopy evidenced that a part of silver appeared outside the pillared clay cavities. Ag-pillared clay composite homogenized with 10 wt.% of nanodispersed carbon black (Vulcan), was applied on a flat glassy carbon surface and used as an electrode material. Oxygen reduction reaction was investigated in an O(2)-saturated aqueous 0.1 M NaOH solution.
PB  - Springer, New York
T2  - Journal of Solid State Electrochemistry
T1  - Electrochemical behavior of silver-impregnated Al-pillared smectite in alkaline solution
VL  - 14
IS  - 9
SP  - 1621
EP  - 1627
DO  - 10.1007/s10008-010-1006-z
ER  - 

@article{
author = "Mojović, Zorica and Milutinović Nikolić, Aleksandra and Banković, Predrag and Mentus, Slavko and Jovanović, Dušan M.",
year = "2010",
abstract = "In order to enhance silver effectiveness for oxygen reduction reaction, pillared clay was used as a support for silver nanodispersion. Silver particles incorporation into pillared clay pores was attempted by impregnation/thermal degradation technique. X-ray diffraction as well as adsorption-desorption isotherms confirmed that pillaring procedure was successful. Scanning electron microscopy evidenced that a part of silver appeared outside the pillared clay cavities. Ag-pillared clay composite homogenized with 10 wt.% of nanodispersed carbon black (Vulcan), was applied on a flat glassy carbon surface and used as an electrode material. Oxygen reduction reaction was investigated in an O(2)-saturated aqueous 0.1 M NaOH solution.",
publisher = "Springer, New York",
journal = "Journal of Solid State Electrochemistry",
title = "Electrochemical behavior of silver-impregnated Al-pillared smectite in alkaline solution",
volume = "14",
number = "9",
pages = "1621-1627",
doi = "10.1007/s10008-010-1006-z"
}

Mojović, Z., Milutinović Nikolić, A., Banković, P., Mentus, S.,& Jovanović, D. M.. (2010). Electrochemical behavior of silver-impregnated Al-pillared smectite in alkaline solution. in Journal of Solid State Electrochemistry
Springer, New York., 14(9), 1621-1627.
https://doi.org/10.1007/s10008-010-1006-z

Mojović Z, Milutinović Nikolić A, Banković P, Mentus S, Jovanović DM. Electrochemical behavior of silver-impregnated Al-pillared smectite in alkaline solution. in Journal of Solid State Electrochemistry. 2010;14(9):1621-1627.
doi:10.1007/s10008-010-1006-z .

Mojović, Zorica, Milutinović Nikolić, Aleksandra, Banković, Predrag, Mentus, Slavko, Jovanović, Dušan M., "Electrochemical behavior of silver-impregnated Al-pillared smectite in alkaline solution" in Journal of Solid State Electrochemistry, 14, no. 9 (2010):1621-1627,
https://doi.org/10.1007/s10008-010-1006-z . .

TY  - JOUR
AU  - Mojović, Zorica
AU  - Iovanovich, L.
AU  - Mentus, Slavko
AU  - Iovanovich, D.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/667
AB  - A composite mixture Ag-NaX zeolite (silver concentration 16.7% w/w) is synthesized usingimpregnation and thermal decomposition. For silver impregnation, a solution of an Ag acetylacetonate complex in acetone was used. Despite the quantity of silver applied was substantially less than it would be necessary to fill the inner pore space in the zeolite completely, some part of silver formed nanocrystallites and nanoparticles giving rise to a novel composite material. The composite powder was uniformed with soot (10% w/w) and applied onto a mirror-smooth graphite surface used as an electrode matrix. The reduction of oxygen on such a surface proceeded with activity comparable to that observed on the most active planes of the silver single crystal, Ag(100).
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Journal of Analytical Chemistry
T1  - Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media
VL  - 65
IS  - 1
SP  - 77
EP  - 81
DO  - 10.1134/S1061934810010144
ER  - 

@article{
author = "Mojović, Zorica and Iovanovich, L. and Mentus, Slavko and Iovanovich, D.",
year = "2010",
abstract = "A composite mixture Ag-NaX zeolite (silver concentration 16.7% w/w) is synthesized usingimpregnation and thermal decomposition. For silver impregnation, a solution of an Ag acetylacetonate complex in acetone was used. Despite the quantity of silver applied was substantially less than it would be necessary to fill the inner pore space in the zeolite completely, some part of silver formed nanocrystallites and nanoparticles giving rise to a novel composite material. The composite powder was uniformed with soot (10% w/w) and applied onto a mirror-smooth graphite surface used as an electrode matrix. The reduction of oxygen on such a surface proceeded with activity comparable to that observed on the most active planes of the silver single crystal, Ag(100).",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Journal of Analytical Chemistry",
title = "Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media",
volume = "65",
number = "1",
pages = "77-81",
doi = "10.1134/S1061934810010144"
}

Mojović, Z., Iovanovich, L., Mentus, S.,& Iovanovich, D.. (2010). Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media. in Journal of Analytical Chemistry
Maik Nauka/Interperiodica/Springer, New York., 65(1), 77-81.
https://doi.org/10.1134/S1061934810010144

Mojović Z, Iovanovich L, Mentus S, Iovanovich D. Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media. in Journal of Analytical Chemistry. 2010;65(1):77-81.
doi:10.1134/S1061934810010144 .

Mojović, Zorica, Iovanovich, L., Mentus, Slavko, Iovanovich, D., "Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media" in Journal of Analytical Chemistry, 65, no. 1 (2010):77-81,
https://doi.org/10.1134/S1061934810010144 . .

TY  - JOUR
AU  - Ciric-Marjanovic, G.
AU  - Dragičević, Ljiljana
AU  - Milojević, M.
AU  - Mojović, Miloš
AU  - Mentus, Slavko
AU  - Dojčinović, Biljana
AU  - Marjanović, B.
AU  - Stejskal, J.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/563
AB  - Self-assembled semiconducting, paramagnetic polyaniline nanotubes have been synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in aqueous medium in the presence of colloidal silica particles of an average diameter ∼12 nm, without added acid. The electrical conductivity of polyaniline nanotubes/silica nanocomposites is in the range (3.3-4.0) × 10-3 S cm-1. The presence of paramagnetic polaronic emeraldine salt form of polyaniline and phenazine units in nanocomposites was proved by FTIR, Raman, and EPR spectroscopies. The influence of the initial silica/aniline weight ratio on the morphology of polyaniline/silica nanocomposites was studied by scanning and transmission electron microscopies. Nano-composites synthesized by using the initial weight ratio silica/aniline ≤0.2 contain polyaniline nanotubes which have a typical outer diameter of 100-250 nm and an inner diameter of 10-80 nm, and nanorods with a diameter of 60-100 nm, accompanied with polyaniline/silica nanogranules, while the nanocomposite synthesized at weight ratio silica/aniline ∼2 contains polyaniline/silica nanogranules with an average diameter of 35-70 nm. The evolution of molecular and supramolecular structure of polyaniline in the presence of colloidal silica is discussed.
PB  - American Chemical Society (ACS)
T2  - Journal of Physical Chemistry B
T1  - Synthesis and characterization of self-assembled polyaniline nanotubes/silica nanocomposites
VL  - 113
IS  - 20
SP  - 7116
EP  - 7127
DO  - 10.1021/jp900096b
ER  - 

@article{
author = "Ciric-Marjanovic, G. and Dragičević, Ljiljana and Milojević, M. and Mojović, Miloš and Mentus, Slavko and Dojčinović, Biljana and Marjanović, B. and Stejskal, J.",
year = "2009",
abstract = "Self-assembled semiconducting, paramagnetic polyaniline nanotubes have been synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in aqueous medium in the presence of colloidal silica particles of an average diameter ∼12 nm, without added acid. The electrical conductivity of polyaniline nanotubes/silica nanocomposites is in the range (3.3-4.0) × 10-3 S cm-1. The presence of paramagnetic polaronic emeraldine salt form of polyaniline and phenazine units in nanocomposites was proved by FTIR, Raman, and EPR spectroscopies. The influence of the initial silica/aniline weight ratio on the morphology of polyaniline/silica nanocomposites was studied by scanning and transmission electron microscopies. Nano-composites synthesized by using the initial weight ratio silica/aniline ≤0.2 contain polyaniline nanotubes which have a typical outer diameter of 100-250 nm and an inner diameter of 10-80 nm, and nanorods with a diameter of 60-100 nm, accompanied with polyaniline/silica nanogranules, while the nanocomposite synthesized at weight ratio silica/aniline ∼2 contains polyaniline/silica nanogranules with an average diameter of 35-70 nm. The evolution of molecular and supramolecular structure of polyaniline in the presence of colloidal silica is discussed.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Physical Chemistry B",
title = "Synthesis and characterization of self-assembled polyaniline nanotubes/silica nanocomposites",
volume = "113",
number = "20",
pages = "7116-7127",
doi = "10.1021/jp900096b"
}

Ciric-Marjanovic, G., Dragičević, L., Milojević, M., Mojović, M., Mentus, S., Dojčinović, B., Marjanović, B.,& Stejskal, J.. (2009). Synthesis and characterization of self-assembled polyaniline nanotubes/silica nanocomposites. in Journal of Physical Chemistry B
American Chemical Society (ACS)., 113(20), 7116-7127.
https://doi.org/10.1021/jp900096b

Ciric-Marjanovic G, Dragičević L, Milojević M, Mojović M, Mentus S, Dojčinović B, Marjanović B, Stejskal J. Synthesis and characterization of self-assembled polyaniline nanotubes/silica nanocomposites. in Journal of Physical Chemistry B. 2009;113(20):7116-7127.
doi:10.1021/jp900096b .

Ciric-Marjanovic, G., Dragičević, Ljiljana, Milojević, M., Mojović, Miloš, Mentus, Slavko, Dojčinović, Biljana, Marjanović, B., Stejskal, J., "Synthesis and characterization of self-assembled polyaniline nanotubes/silica nanocomposites" in Journal of Physical Chemistry B, 113, no. 20 (2009):7116-7127,
https://doi.org/10.1021/jp900096b . .

TY  - JOUR
AU  - Ciric-Marjanovic, G.
AU  - Dondur, Vera
AU  - Milojević, M.
AU  - Mojović, Miloš
AU  - Mentus, Slavko
AU  - Radulović, Aleksandra
AU  - Vuković, Zorica
AU  - Stejskal, J.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/568
AB  - Self-assembled conducting, paramagnetic polyaniline nanotubes have been synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in aqueous medium in the presence of zeolite HZSM-5, without added acid. The influence of initial zeolite/aniline weight ratio on the conductivity, molecular and supramolecular structure, paramagnetic characteristics, thermal stability, and specific surface area of poly aniline/zeolite composites was studied. The conducting (∼10-2S cm-1), semiconducting (3 × 10-5 S cm-1), and nonconducting (5 × 10-9 S cm-1) composites are produced using the zeolite/aniline weight ratios 1, 5, and 10, respectively. The coexistence of polyaniline nanotubes, which have a typical outer diameter of 70-170 nm and an inner diameter of 5-50 nm, accompanied by nanorods with a diameter of 60-100 nm and polyaniline/zeolite mesoporous aggregates, distinct from the morphology of mieroporous zeolite HZSM-5, was proved in the conducting nanocomposite by scanning and transmission electron microscopies. FTIR spectroscopy confirmed the presence of polyaniline in the form of conducting emeraldine salt and suggested significant interaction of polyaniline with zeolite. The evolution of molecular and supramolecular structure of polyaniline in the presence of zeolite was discussed.
T2  - Langmuir
T1  - Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite
VL  - 25
IS  - 5
SP  - 3122
EP  - 3131
DO  - 10.1021/la8030396
ER  - 

@article{
author = "Ciric-Marjanovic, G. and Dondur, Vera and Milojević, M. and Mojović, Miloš and Mentus, Slavko and Radulović, Aleksandra and Vuković, Zorica and Stejskal, J.",
year = "2009",
abstract = "Self-assembled conducting, paramagnetic polyaniline nanotubes have been synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in aqueous medium in the presence of zeolite HZSM-5, without added acid. The influence of initial zeolite/aniline weight ratio on the conductivity, molecular and supramolecular structure, paramagnetic characteristics, thermal stability, and specific surface area of poly aniline/zeolite composites was studied. The conducting (∼10-2S cm-1), semiconducting (3 × 10-5 S cm-1), and nonconducting (5 × 10-9 S cm-1) composites are produced using the zeolite/aniline weight ratios 1, 5, and 10, respectively. The coexistence of polyaniline nanotubes, which have a typical outer diameter of 70-170 nm and an inner diameter of 5-50 nm, accompanied by nanorods with a diameter of 60-100 nm and polyaniline/zeolite mesoporous aggregates, distinct from the morphology of mieroporous zeolite HZSM-5, was proved in the conducting nanocomposite by scanning and transmission electron microscopies. FTIR spectroscopy confirmed the presence of polyaniline in the form of conducting emeraldine salt and suggested significant interaction of polyaniline with zeolite. The evolution of molecular and supramolecular structure of polyaniline in the presence of zeolite was discussed.",
journal = "Langmuir",
title = "Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite",
volume = "25",
number = "5",
pages = "3122-3131",
doi = "10.1021/la8030396"
}

Ciric-Marjanovic, G., Dondur, V., Milojević, M., Mojović, M., Mentus, S., Radulović, A., Vuković, Z.,& Stejskal, J.. (2009). Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite. in Langmuir, 25(5), 3122-3131.
https://doi.org/10.1021/la8030396

Ciric-Marjanovic G, Dondur V, Milojević M, Mojović M, Mentus S, Radulović A, Vuković Z, Stejskal J. Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite. in Langmuir. 2009;25(5):3122-3131.
doi:10.1021/la8030396 .

Ciric-Marjanovic, G., Dondur, Vera, Milojević, M., Mojović, Miloš, Mentus, Slavko, Radulović, Aleksandra, Vuković, Zorica, Stejskal, J., "Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite" in Langmuir, 25, no. 5 (2009):3122-3131,
https://doi.org/10.1021/la8030396 . .

TY  - JOUR
AU  - Mentus, Slavko
AU  - Mojović, Zorica
AU  - Radmilović, Velimir R.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/499
AB  - The incorporation of platinum into the cavities of NaX zeolite was realized by impregnation and thermal decomposition of the organometallic compound Pt(II)-acetylacetonate dissolved in acetone. A high dispersion of platinum to predominantly mono-atomic particles was achieved thanks to the tight fit of the Pt(II)-acetylacetonate molecules in the aperture of the zeolite supercage. Using the high angle annular dark field imaging technique of HRTEM, individual Pt particles situated within the zeolite crystals were, for the first time, clearly visible. This offers new possibilities of studying the distribution of incorporated metal particles along the crystal depth.
AB  - Platina je ugrađena u kaveze zeolita NaX impregnacijom i termalnim razlaganjem organometalnog jedinjenja Pt(II)-acetilacetonata, rastvrenog u acetonu. Visoka disperznost platine pretežno u vidu jednoatomnih čestica, postignuta je zahvaljujući bliskosti dimenzija molekule Pt(II)-acetilacetonata i prečnika ulaznog otvora supekaveza zeolita. Tehnikom širokougaone difrakcije i tamnog polja ultravisokorezolutivne elektronske mikroskopije, prvi put su učinjene vidljivim individualne čestice platine smeštene unutar kristala zeolita, što otvara nove mogućnosti u proučavanju raspodele ugrađenih metalnih čestica po dubini kristala.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution
T1  - Zeolit NaX kao templat za dobijanje monoatomski dispergovane platine impregnacijom sa rastvorom Pt(II)-acetilacetonata u acetonu
VL  - 74
IS  - 10
SP  - 1113
EP  - 1123
DO  - 10.2298/JSC0910113M
ER  - 

@article{
author = "Mentus, Slavko and Mojović, Zorica and Radmilović, Velimir R.",
year = "2009",
abstract = "The incorporation of platinum into the cavities of NaX zeolite was realized by impregnation and thermal decomposition of the organometallic compound Pt(II)-acetylacetonate dissolved in acetone. A high dispersion of platinum to predominantly mono-atomic particles was achieved thanks to the tight fit of the Pt(II)-acetylacetonate molecules in the aperture of the zeolite supercage. Using the high angle annular dark field imaging technique of HRTEM, individual Pt particles situated within the zeolite crystals were, for the first time, clearly visible. This offers new possibilities of studying the distribution of incorporated metal particles along the crystal depth., Platina je ugrađena u kaveze zeolita NaX impregnacijom i termalnim razlaganjem organometalnog jedinjenja Pt(II)-acetilacetonata, rastvrenog u acetonu. Visoka disperznost platine pretežno u vidu jednoatomnih čestica, postignuta je zahvaljujući bliskosti dimenzija molekule Pt(II)-acetilacetonata i prečnika ulaznog otvora supekaveza zeolita. Tehnikom širokougaone difrakcije i tamnog polja ultravisokorezolutivne elektronske mikroskopije, prvi put su učinjene vidljivim individualne čestice platine smeštene unutar kristala zeolita, što otvara nove mogućnosti u proučavanju raspodele ugrađenih metalnih čestica po dubini kristala.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution, Zeolit NaX kao templat za dobijanje monoatomski dispergovane platine impregnacijom sa rastvorom Pt(II)-acetilacetonata u acetonu",
volume = "74",
number = "10",
pages = "1113-1123",
doi = "10.2298/JSC0910113M"
}

Mentus, S., Mojović, Z.,& Radmilović, V. R.. (2009). The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 74(10), 1113-1123.
https://doi.org/10.2298/JSC0910113M

Mentus S, Mojović Z, Radmilović VR. The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution. in Journal of the Serbian Chemical Society. 2009;74(10):1113-1123.
doi:10.2298/JSC0910113M .

Mentus, Slavko, Mojović, Zorica, Radmilović, Velimir R., "The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution" in Journal of the Serbian Chemical Society, 74, no. 10 (2009):1113-1123,
https://doi.org/10.2298/JSC0910113M . .

TY  - JOUR
AU  - Jašin, Danijela M.
AU  - Abu Rabi, Anđela
AU  - Mentus, Slavko
AU  - Jovanović, Dušan M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4253
AB  - From aqueous solutions, gold was deposited on freshly polished titanium surface either by displacement reaction or by potentiodynamic polarization. Both of these procedures resulted in the formation of Au/TiO2 composite layer over the titanium surface, although with quite different Au content. The electrochemical behaviour of these composite layers was examined in 0.1 M NaOH solution, both oxygen free and oxygen saturated, using rotating disc technique. In the potential region of oxygen reduction reaction, the Au/TiO2 layer obtained by potentiodynamic polarization, displayed the voltammetric curve similar to that observed on (1 0 0) plane of Au monocrystal. The Koutecky-Levich analysis evidenced that 4e- route of oxygen reduction dominates on both type of composite layers.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces
VL  - 52
IS  - 13
SP  - 4581
EP  - 4588
DO  - 10.1016/j.electacta.2006.12.071
ER  - 

@article{
author = "Jašin, Danijela M. and Abu Rabi, Anđela and Mentus, Slavko and Jovanović, Dušan M.",
year = "2007",
abstract = "From aqueous solutions, gold was deposited on freshly polished titanium surface either by displacement reaction or by potentiodynamic polarization. Both of these procedures resulted in the formation of Au/TiO2 composite layer over the titanium surface, although with quite different Au content. The electrochemical behaviour of these composite layers was examined in 0.1 M NaOH solution, both oxygen free and oxygen saturated, using rotating disc technique. In the potential region of oxygen reduction reaction, the Au/TiO2 layer obtained by potentiodynamic polarization, displayed the voltammetric curve similar to that observed on (1 0 0) plane of Au monocrystal. The Koutecky-Levich analysis evidenced that 4e- route of oxygen reduction dominates on both type of composite layers.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces",
volume = "52",
number = "13",
pages = "4581-4588",
doi = "10.1016/j.electacta.2006.12.071"
}

Jašin, D. M., Abu Rabi, A., Mentus, S.,& Jovanović, D. M.. (2007). Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces. in Electrochimica Acta
Elsevier., 52(13), 4581-4588.
https://doi.org/10.1016/j.electacta.2006.12.071

Jašin DM, Abu Rabi A, Mentus S, Jovanović DM. Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces. in Electrochimica Acta. 2007;52(13):4581-4588.
doi:10.1016/j.electacta.2006.12.071 .

Jašin, Danijela M., Abu Rabi, Anđela, Mentus, Slavko, Jovanović, Dušan M., "Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces" in Electrochimica Acta, 52, no. 13 (2007):4581-4588,
https://doi.org/10.1016/j.electacta.2006.12.071 . .

TY  - JOUR
AU  - Mojović, Zorica
AU  - Mentus, Slavko
AU  - Krstic, I.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/291
AB  - A new type of an electrode material, zeolite modified by the incorporation of Ni or NiO clusters into its cavities, was synthesized by multiple impregnation of zeolite 13X with a Ni-acetylacetonate solution followed by solvent evaporation and thermal degradation of the nickel compound. Samples with a Ni/13X mass ratio within the range 0.2-1.0 were synthesized. Modification by both Ni and NiO clusters, depending on whether the atmosphere was reducing (H-2) or oxidizing (air), respectively, was used to finish the sample. After modification, the zeolite kept its original crystallographic structure, as proven by X-ray diffractommetry. The dimensions of the incorporated clusters were limited by the diameter of the zeolite cavities (reaching1.3 nm). This material, homogenized with 10 wt% of nanodispersed carbon, was bonded in the form of a thin layer to a glassy carbon disc by means of Nafion and used as an electrode material in an aqueous 0.1 M NaOH solution. The cyclovoltammograms of this thin-layer electrode resemble those of a smooth nickel electrode in alkaline solutions.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Thin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutions
VL  - 81
IS  - 9
SP  - 1452
EP  - 1457
DO  - 10.1134/S0036024407090208
ER  - 

@article{
author = "Mojović, Zorica and Mentus, Slavko and Krstic, I.",
year = "2007",
abstract = "A new type of an electrode material, zeolite modified by the incorporation of Ni or NiO clusters into its cavities, was synthesized by multiple impregnation of zeolite 13X with a Ni-acetylacetonate solution followed by solvent evaporation and thermal degradation of the nickel compound. Samples with a Ni/13X mass ratio within the range 0.2-1.0 were synthesized. Modification by both Ni and NiO clusters, depending on whether the atmosphere was reducing (H-2) or oxidizing (air), respectively, was used to finish the sample. After modification, the zeolite kept its original crystallographic structure, as proven by X-ray diffractommetry. The dimensions of the incorporated clusters were limited by the diameter of the zeolite cavities (reaching1.3 nm). This material, homogenized with 10 wt% of nanodispersed carbon, was bonded in the form of a thin layer to a glassy carbon disc by means of Nafion and used as an electrode material in an aqueous 0.1 M NaOH solution. The cyclovoltammograms of this thin-layer electrode resemble those of a smooth nickel electrode in alkaline solutions.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Thin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutions",
volume = "81",
number = "9",
pages = "1452-1457",
doi = "10.1134/S0036024407090208"
}

Mojović, Z., Mentus, S.,& Krstic, I.. (2007). Thin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutions. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 81(9), 1452-1457.
https://doi.org/10.1134/S0036024407090208

Mojović Z, Mentus S, Krstic I. Thin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutions. in Russian Journal of Physical Chemistry A. 2007;81(9):1452-1457.
doi:10.1134/S0036024407090208 .

Mojović, Zorica, Mentus, Slavko, Krstic, I., "Thin layer of Ni-modified 13X zeolite on glassy carbon support as an electrode material in aqueous solutions" in Russian Journal of Physical Chemistry A, 81, no. 9 (2007):1452-1457,
https://doi.org/10.1134/S0036024407090208 . .