Baláž, Matej

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  • Baláž, Matej (2)
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Author's Bibliography

Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor

Baláž, Matej; Džunda, Róbert; Daneu, Nina; Shalabayev, Zhandos; Khan, Natalya; Tatykayev, Batukhan; Mudrinić, Tihana; Casas-Luna, Mariano; Čelko, Ladislav

(Ostrava : TANGER Ltd, 2021)

TY  - CONF
AU  - Baláž, Matej
AU  - Džunda, Róbert
AU  - Daneu, Nina
AU  - Shalabayev, Zhandos
AU  - Khan, Natalya
AU  - Tatykayev, Batukhan
AU  - Mudrinić, Tihana
AU  - Casas-Luna, Mariano
AU  - Čelko, Ladislav
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7022
AB  - Nature is an inexhaustible source of idea and materials. This time, chicken eggshell membrane, a nature product and waste material, has been discovered as a potential sulfur source for the production of sulfide. This is possible because of the presence of sulfur-containing amino acids in the proteins forming its fibers. In the present research eggshell membrane was high-energy ball milled with lead precursor to yield lead sulfide PbS, a semiconductor material suitable for the application in solar cells. Thus, a completely solid-state methodology (mechanochemical synthesis) without the need to use toxic precursors and solvents and evaluated temperatures has been successfully applied. The effect of rotation speed and the type of lead precursor (acetate and nitrate) on the reaction course was investigated. The as-received powders were washed with distilled water, filtered and the content of lead in the filtrate reaction was measured by means of atomic absorption spectrometry. This provided a direct information about the reaction progress (reactants are water-soluble whereas the produced PbS is not). The conversion reached 100 % after 120 min of treatment at 750 rpm, whereas only around 60 %conversion was achieved when milling at 500 rpm. The products were characterized by a vast number of characterization techniques, including XRD, low temperature N2 physisorption, SEM, TEM, XPS and electrochemical impedance spectroscopy using Mott-Schottky analysis.  The nanocrystalline character of the products was confirmed by XRD and TEM. At the end, the photocatalytic activity to degrade selected organic dye of the products was tested.
PB  - Ostrava : TANGER Ltd
C3  - Abstracts - Nanocon 2021, 13th International Conference on Nanomaterial-Research & Application, October 20-22 2021, Brno, Czech Republic
T1  - Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor
SP  - 50
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_cer_7022
ER  - 
@conference{
author = "Baláž, Matej and Džunda, Róbert and Daneu, Nina and Shalabayev, Zhandos and Khan, Natalya and Tatykayev, Batukhan and Mudrinić, Tihana and Casas-Luna, Mariano and Čelko, Ladislav",
year = "2021",
abstract = "Nature is an inexhaustible source of idea and materials. This time, chicken eggshell membrane, a nature product and waste material, has been discovered as a potential sulfur source for the production of sulfide. This is possible because of the presence of sulfur-containing amino acids in the proteins forming its fibers. In the present research eggshell membrane was high-energy ball milled with lead precursor to yield lead sulfide PbS, a semiconductor material suitable for the application in solar cells. Thus, a completely solid-state methodology (mechanochemical synthesis) without the need to use toxic precursors and solvents and evaluated temperatures has been successfully applied. The effect of rotation speed and the type of lead precursor (acetate and nitrate) on the reaction course was investigated. The as-received powders were washed with distilled water, filtered and the content of lead in the filtrate reaction was measured by means of atomic absorption spectrometry. This provided a direct information about the reaction progress (reactants are water-soluble whereas the produced PbS is not). The conversion reached 100 % after 120 min of treatment at 750 rpm, whereas only around 60 %conversion was achieved when milling at 500 rpm. The products were characterized by a vast number of characterization techniques, including XRD, low temperature N2 physisorption, SEM, TEM, XPS and electrochemical impedance spectroscopy using Mott-Schottky analysis.  The nanocrystalline character of the products was confirmed by XRD and TEM. At the end, the photocatalytic activity to degrade selected organic dye of the products was tested.",
publisher = "Ostrava : TANGER Ltd",
journal = "Abstracts - Nanocon 2021, 13th International Conference on Nanomaterial-Research & Application, October 20-22 2021, Brno, Czech Republic",
title = "Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor",
pages = "50-50",
url = "https://hdl.handle.net/21.15107/rcub_cer_7022"
}
Baláž, M., Džunda, R., Daneu, N., Shalabayev, Z., Khan, N., Tatykayev, B., Mudrinić, T., Casas-Luna, M.,& Čelko, L.. (2021). Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor. in Abstracts - Nanocon 2021, 13th International Conference on Nanomaterial-Research & Application, October 20-22 2021, Brno, Czech Republic
Ostrava : TANGER Ltd., 50-50.
https://hdl.handle.net/21.15107/rcub_cer_7022
Baláž M, Džunda R, Daneu N, Shalabayev Z, Khan N, Tatykayev B, Mudrinić T, Casas-Luna M, Čelko L. Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor. in Abstracts - Nanocon 2021, 13th International Conference on Nanomaterial-Research & Application, October 20-22 2021, Brno, Czech Republic. 2021;:50-50.
https://hdl.handle.net/21.15107/rcub_cer_7022 .
Baláž, Matej, Džunda, Róbert, Daneu, Nina, Shalabayev, Zhandos, Khan, Natalya, Tatykayev, Batukhan, Mudrinić, Tihana, Casas-Luna, Mariano, Čelko, Ladislav, "Sustainable mechanochemical synthesis of nanocrystalline lead sulfide using eggshell membrane as a sulfur precursor" in Abstracts - Nanocon 2021, 13th International Conference on Nanomaterial-Research & Application, October 20-22 2021, Brno, Czech Republic (2021):50-50,
https://hdl.handle.net/21.15107/rcub_cer_7022 .

State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry

Baláž, Matej; Boldyreva, Elena; Rybin, Dmitry; Pavlović, Stefan; Rodríguez-Padrón, Daily; Mudrinić, Tihana; Luque, Rafael

(Frontiers Media S.A., 2021)

TY  - JOUR
AU  - Baláž, Matej
AU  - Boldyreva, Elena
AU  - Rybin, Dmitry
AU  - Pavlović, Stefan
AU  - Rodríguez-Padrón, Daily
AU  - Mudrinić, Tihana
AU  - Luque, Rafael
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4157
AB  - Eggshell waste is among the most abundant waste materials coming from food processing technologies. Despite the unique properties that both its components (eggshell, ES, and eggshell membrane, ESM) possess, it is very often discarded without further use. This review article aims to summarize the recent reports utilizing eggshell waste for very diverse purposes, stressing the need to use a mechanochemical approach to broaden its applications. The most studied field with regards to the potential use of eggshell waste is catalysis. Upon proper treatment, it can be used for turning waste oils into biodiesel and moreover, the catalytic effect of eggshell-based material in organic synthesis is also very beneficial. In inorganic chemistry, the eggshell membrane is very often used as a templating agent for nanoparticles production. Such composites are suitable for application in photocatalysis. These bionanocomposites are also capable of heavy metal ions reduction and can be also used for the ozonation process. The eggshell and its membrane are applicable in electrochemistry as well. Due to the high protein content and the presence of functional groups on the surface, ESM can be easily converted to a high-performance electrode material. Finally, both ES and ESM are suitable for medical applications, as the former can be used as an inexpensive Ca2+ source for the development of medications, particles for drug delivery, organic matrix/mineral nanocomposites as potential tissue scaffolds, food supplements and the latter for the treatment of joint diseases, in reparative medicine and vascular graft producing. For the majority of the above-mentioned applications, the pretreatment of the eggshell waste is necessary. Among other options, the mechanochemical pretreatment has found an inevitable place. Since the publication of the last review paper devoted to the mechanochemical treatment of eggshell waste, a few new works have appeared, which are reviewed here to underline the sustainable character of the proposed methodology. The mechanochemical treatment of eggshell is capable of producing the nanoscale material which can be further used for bioceramics synthesis, dehalogenation processes, wastewater treatment, preparation of hydrophobic filters, lithium-ion batteries, dental materials, and in the building industry as cement.
PB  - Frontiers Media S.A.
T2  - Frontiers in Bioengineering and Biotechnology
T1  - State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry
VL  - 8
SP  - 612567
DO  - 10.3389/fbioe.2020.612567
ER  - 
@article{
author = "Baláž, Matej and Boldyreva, Elena and Rybin, Dmitry and Pavlović, Stefan and Rodríguez-Padrón, Daily and Mudrinić, Tihana and Luque, Rafael",
year = "2021",
abstract = "Eggshell waste is among the most abundant waste materials coming from food processing technologies. Despite the unique properties that both its components (eggshell, ES, and eggshell membrane, ESM) possess, it is very often discarded without further use. This review article aims to summarize the recent reports utilizing eggshell waste for very diverse purposes, stressing the need to use a mechanochemical approach to broaden its applications. The most studied field with regards to the potential use of eggshell waste is catalysis. Upon proper treatment, it can be used for turning waste oils into biodiesel and moreover, the catalytic effect of eggshell-based material in organic synthesis is also very beneficial. In inorganic chemistry, the eggshell membrane is very often used as a templating agent for nanoparticles production. Such composites are suitable for application in photocatalysis. These bionanocomposites are also capable of heavy metal ions reduction and can be also used for the ozonation process. The eggshell and its membrane are applicable in electrochemistry as well. Due to the high protein content and the presence of functional groups on the surface, ESM can be easily converted to a high-performance electrode material. Finally, both ES and ESM are suitable for medical applications, as the former can be used as an inexpensive Ca2+ source for the development of medications, particles for drug delivery, organic matrix/mineral nanocomposites as potential tissue scaffolds, food supplements and the latter for the treatment of joint diseases, in reparative medicine and vascular graft producing. For the majority of the above-mentioned applications, the pretreatment of the eggshell waste is necessary. Among other options, the mechanochemical pretreatment has found an inevitable place. Since the publication of the last review paper devoted to the mechanochemical treatment of eggshell waste, a few new works have appeared, which are reviewed here to underline the sustainable character of the proposed methodology. The mechanochemical treatment of eggshell is capable of producing the nanoscale material which can be further used for bioceramics synthesis, dehalogenation processes, wastewater treatment, preparation of hydrophobic filters, lithium-ion batteries, dental materials, and in the building industry as cement.",
publisher = "Frontiers Media S.A.",
journal = "Frontiers in Bioengineering and Biotechnology",
title = "State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry",
volume = "8",
pages = "612567",
doi = "10.3389/fbioe.2020.612567"
}
Baláž, M., Boldyreva, E., Rybin, D., Pavlović, S., Rodríguez-Padrón, D., Mudrinić, T.,& Luque, R.. (2021). State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry. in Frontiers in Bioengineering and Biotechnology
Frontiers Media S.A.., 8, 612567.
https://doi.org/10.3389/fbioe.2020.612567
Baláž M, Boldyreva E, Rybin D, Pavlović S, Rodríguez-Padrón D, Mudrinić T, Luque R. State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry. in Frontiers in Bioengineering and Biotechnology. 2021;8:612567.
doi:10.3389/fbioe.2020.612567 .
Baláž, Matej, Boldyreva, Elena, Rybin, Dmitry, Pavlović, Stefan, Rodríguez-Padrón, Daily, Mudrinić, Tihana, Luque, Rafael, "State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry" in Frontiers in Bioengineering and Biotechnology, 8 (2021):612567,
https://doi.org/10.3389/fbioe.2020.612567 . .
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