@article{
author = "Tanaka, Auro A. and Adžić, Radoslav R. and Nikolić, Branislav Ž.",
year = "1999",
abstract = "Oxygen reduction reaction has been studied on Pt low index planes in 0.1 M and 85% H3PO4 using hanging meniscus rotating disc electrode technique. The first-order kinetics of O2 reduction reaction was found for all three surfaces in a four-electron process with the first electron transfer rate determining in both 0.1 M and 85% H2PO4 solutions. Catalytic activity for O2 reduction follows the sequence Pt (110)>Pt (100)>Pt (111). Structural dependence is predominantly determined by the adsorption of phosphoric acid anions, which is strongly structure-dependent on Pt surfaces., Ispitivana je reakcija redukcije kiseonika na niskoindeksnim monokristalima
platine u 85%i0.1 M rastvoru H3PO4 tehnikom rotirajućeg meniska. Utvrđeno je da je
u oba rastvora reakcija prvog reda i da se odigrava 4-elektronskim putem u kome je
prenos prvog elektrona spori stupanj. Katalitička aktivnost za redukciju kiseonika
sledi niz Pt(110) > Pt(100) > Pt(111). Strukturna zavisnost aktivnosti dominantno je
određena strukturno zavisnom adsorpcijom anjona fosforne kiseline na Pt(hkl)
ravnima.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions, Redukcija kiseonika na monokristalnim platinskim elektrodama u rastvorima fosforne kiseline",
volume = "64",
number = "11",
pages = "695-705",
doi = "10.2298/jsc9911695t"
}