Tanaka, Auro A.

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Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions

Tanaka, Auro A.; Adžić, Radoslav R.; Nikolić, Branislav Ž.

(Belgrade : Serbian Chemical Society, 1999)

TY  - JOUR
AU  - Tanaka, Auro A.
AU  - Adžić, Radoslav R.
AU  - Nikolić, Branislav Ž.
PY  - 1999
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4400
AB  - Oxygen reduction reaction has been studied on Pt low index planes in 0.1 M and 85% H3PO4 using hanging meniscus rotating disc electrode technique. The first-order kinetics of O2 reduction reaction was found for all three surfaces in a four-electron process with the first electron transfer rate determining in both 0.1 M and 85% H2PO4 solutions. Catalytic activity for O2 reduction follows the sequence Pt (110)>Pt (100)>Pt (111). Structural dependence is predominantly determined by the adsorption of phosphoric acid anions, which is strongly structure-dependent on Pt surfaces.
AB  - Ispitivana je reakcija redukcije kiseonika na niskoindeksnim monokristalima
platine u 85%i0.1 M rastvoru H3PO4 tehnikom rotirajućeg meniska. Utvrđeno je da je
u oba rastvora reakcija prvog reda i da se odigrava 4-elektronskim putem u kome je
prenos prvog elektrona spori stupanj. Katalitička aktivnost za redukciju kiseonika
sledi niz Pt(110) > Pt(100) > Pt(111). Strukturna zavisnost aktivnosti dominantno je
određena strukturno zavisnom adsorpcijom anjona fosforne kiseline na Pt(hkl)
ravnima.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions
T1  - Redukcija kiseonika na monokristalnim platinskim elektrodama u rastvorima fosforne kiseline
VL  - 64
IS  - 11
SP  - 695
EP  - 705
DO  - 10.2298/jsc9911695t
ER  - 
@article{
author = "Tanaka, Auro A. and Adžić, Radoslav R. and Nikolić, Branislav Ž.",
year = "1999",
abstract = "Oxygen reduction reaction has been studied on Pt low index planes in 0.1 M and 85% H3PO4 using hanging meniscus rotating disc electrode technique. The first-order kinetics of O2 reduction reaction was found for all three surfaces in a four-electron process with the first electron transfer rate determining in both 0.1 M and 85% H2PO4 solutions. Catalytic activity for O2 reduction follows the sequence Pt (110)>Pt (100)>Pt (111). Structural dependence is predominantly determined by the adsorption of phosphoric acid anions, which is strongly structure-dependent on Pt surfaces., Ispitivana je reakcija redukcije kiseonika na niskoindeksnim monokristalima
platine u 85%i0.1 M rastvoru H3PO4 tehnikom rotirajućeg meniska. Utvrđeno je da je
u oba rastvora reakcija prvog reda i da se odigrava 4-elektronskim putem u kome je
prenos prvog elektrona spori stupanj. Katalitička aktivnost za redukciju kiseonika
sledi niz Pt(110) > Pt(100) > Pt(111). Strukturna zavisnost aktivnosti dominantno je
određena strukturno zavisnom adsorpcijom anjona fosforne kiseline na Pt(hkl)
ravnima.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions, Redukcija kiseonika na monokristalnim platinskim elektrodama u rastvorima fosforne kiseline",
volume = "64",
number = "11",
pages = "695-705",
doi = "10.2298/jsc9911695t"
}
Tanaka, A. A., Adžić, R. R.,& Nikolić, B. Ž.. (1999). Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 64(11), 695-705.
https://doi.org/10.2298/jsc9911695t
Tanaka AA, Adžić RR, Nikolić BŽ. Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions. in Journal of the Serbian Chemical Society. 1999;64(11):695-705.
doi:10.2298/jsc9911695t .
Tanaka, Auro A., Adžić, Radoslav R., Nikolić, Branislav Ž., "Oxygen reduction on single crystal platinum electrodes in phosphoric acid solutions" in Journal of the Serbian Chemical Society, 64, no. 11 (1999):695-705,
https://doi.org/10.2298/jsc9911695t . .
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