Filipovic, Jovanka M.

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Authority KeyName Variants
29ed1ede-567d-4368-ab41-2185c2ba5328
  • Filipovic, Jovanka M. (3)
  • Filipović, Jovanka M. (2)
  • Filipovic, Jovanka M (1)
  • Vukajlović-Filipović, Jovanka (1)
Projects

Author's Bibliography

Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution

Antić, Katarina M.; Babić, Marija M.; Jovašević Vuković, Jovana J.; Vasiljević-Radović, Dana; Onjia, Antonije E.; Filipović, Jovanka M.; Tomić, Simonida Lj.

(Amsterdam : Elsevier Science Bv, 2015)

TY  - JOUR
AU  - Antić, Katarina M.
AU  - Babić, Marija M.
AU  - Jovašević Vuković, Jovana J.
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije E.
AU  - Filipović, Jovanka M.
AU  - Tomić, Simonida Lj.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2898
AB  - Series of novel hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA), P(HEA/IA) copolymers, were prepared by free radical cross-linking copolymerization and investigated as potential adsorbents for Cd2+ removal from aqueous solution. The hydrogels before and after Cd2+ adsorption were characterized using FTIR, temperature sensitive. In order to evaluate adsorption behavior of samples various factors affecting the Cd2+ uptake behavior, such as: contact time, temperature, pH, ionic strength, adsorbent weight, competitive ions and initial concentration of the metal ions were investigated. Five adsorption isotherms and two kinetic models were studied. The adsorption behavior can be very well described by the pseudo-second order kinetic model and Langmuir isotherm. Multicomponent adsorption studies revealed that adsorption of cadmium depends on the type of metal ions present in the system. Desorption studies showed that hydrogel can be reused three times with only 15% loss of adsorption capacity. All results indicate that the sample with the highest IA content is the most promising adsorbent for Cd2+ removal.
PB  - Amsterdam : Elsevier Science Bv
T2  - Applied Surface Science
T1  - Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution
VL  - 338
SP  - 178
EP  - 189
DO  - 10.1016/j.apsusc.2015.02.133
ER  - 
@article{
author = "Antić, Katarina M. and Babić, Marija M. and Jovašević Vuković, Jovana J. and Vasiljević-Radović, Dana and Onjia, Antonije E. and Filipović, Jovanka M. and Tomić, Simonida Lj.",
year = "2015",
abstract = "Series of novel hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA), P(HEA/IA) copolymers, were prepared by free radical cross-linking copolymerization and investigated as potential adsorbents for Cd2+ removal from aqueous solution. The hydrogels before and after Cd2+ adsorption were characterized using FTIR, temperature sensitive. In order to evaluate adsorption behavior of samples various factors affecting the Cd2+ uptake behavior, such as: contact time, temperature, pH, ionic strength, adsorbent weight, competitive ions and initial concentration of the metal ions were investigated. Five adsorption isotherms and two kinetic models were studied. The adsorption behavior can be very well described by the pseudo-second order kinetic model and Langmuir isotherm. Multicomponent adsorption studies revealed that adsorption of cadmium depends on the type of metal ions present in the system. Desorption studies showed that hydrogel can be reused three times with only 15% loss of adsorption capacity. All results indicate that the sample with the highest IA content is the most promising adsorbent for Cd2+ removal.",
publisher = "Amsterdam : Elsevier Science Bv",
journal = "Applied Surface Science",
title = "Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution",
volume = "338",
pages = "178-189",
doi = "10.1016/j.apsusc.2015.02.133"
}
Antić, K. M., Babić, M. M., Jovašević Vuković, J. J., Vasiljević-Radović, D., Onjia, A. E., Filipović, J. M.,& Tomić, S. Lj.. (2015). Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution. in Applied Surface Science
Amsterdam : Elsevier Science Bv., 338, 178-189.
https://doi.org/10.1016/j.apsusc.2015.02.133
Antić KM, Babić MM, Jovašević Vuković JJ, Vasiljević-Radović D, Onjia AE, Filipović JM, Tomić SL. Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution. in Applied Surface Science. 2015;338:178-189.
doi:10.1016/j.apsusc.2015.02.133 .
Antić, Katarina M., Babić, Marija M., Jovašević Vuković, Jovana J., Vasiljević-Radović, Dana, Onjia, Antonije E., Filipović, Jovanka M., Tomić, Simonida Lj., "Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution" in Applied Surface Science, 338 (2015):178-189,
https://doi.org/10.1016/j.apsusc.2015.02.133 . .
20
13
20

Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution

Antić, Katarina M.; Babić, Marija M.; Jovašević Vuković, Jovana J.; Vasiljević-Radović, Dana; Onjia, Antonije E.; Filipovic, Jovanka M; Tomić, Simonida Lj.

(Elsevier, 2015)

TY  - JOUR
AU  - Antić, Katarina M.
AU  - Babić, Marija M.
AU  - Jovašević Vuković, Jovana J.
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije E.
AU  - Filipovic, Jovanka M
AU  - Tomić, Simonida Lj.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1764
AB  - Series of novel hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA), P(HEA/IA) copolymers, were prepared by free radical cross-linking copolymerization and investigated as potential adsorbents for Cd2+ removal from aqueous solution. The hydrogels before and after Cd2+ adsorption were characterized using FTIR, temperature sensitive. In order to evaluate adsorption behavior of samples various factors affecting the Cd2+ uptake behavior, such as: contact time, temperature, pH, ionic strength, adsorbent weight, competitive ions and initial concentration of the metal ions were investigated. Five adsorption isotherms and two kinetic models were studied. The adsorption behavior can be very well described by the pseudo-second order kinetic model and Langmuir isotherm. Multicomponent adsorption studies revealed that adsorption of cadmium depends on the type of metal ions present in the system. Desorption studies showed that hydrogel can be reused three times with only 15% loss of adsorption capacity. All results indicate that the sample with the highest IA content is the most promising adsorbent for Cd2+ removal.
PB  - Elsevier
T2  - Applied Surface Science
T1  - Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution
VL  - 338
SP  - 178
EP  - 189
DO  - 10.1016/j.apsusc.2015.02.133
ER  - 
@article{
author = "Antić, Katarina M. and Babić, Marija M. and Jovašević Vuković, Jovana J. and Vasiljević-Radović, Dana and Onjia, Antonije E. and Filipovic, Jovanka M and Tomić, Simonida Lj.",
year = "2015",
abstract = "Series of novel hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA), P(HEA/IA) copolymers, were prepared by free radical cross-linking copolymerization and investigated as potential adsorbents for Cd2+ removal from aqueous solution. The hydrogels before and after Cd2+ adsorption were characterized using FTIR, temperature sensitive. In order to evaluate adsorption behavior of samples various factors affecting the Cd2+ uptake behavior, such as: contact time, temperature, pH, ionic strength, adsorbent weight, competitive ions and initial concentration of the metal ions were investigated. Five adsorption isotherms and two kinetic models were studied. The adsorption behavior can be very well described by the pseudo-second order kinetic model and Langmuir isotherm. Multicomponent adsorption studies revealed that adsorption of cadmium depends on the type of metal ions present in the system. Desorption studies showed that hydrogel can be reused three times with only 15% loss of adsorption capacity. All results indicate that the sample with the highest IA content is the most promising adsorbent for Cd2+ removal.",
publisher = "Elsevier",
journal = "Applied Surface Science",
title = "Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution",
volume = "338",
pages = "178-189",
doi = "10.1016/j.apsusc.2015.02.133"
}
Antić, K. M., Babić, M. M., Jovašević Vuković, J. J., Vasiljević-Radović, D., Onjia, A. E., Filipovic, J. M.,& Tomić, S. Lj.. (2015). Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution. in Applied Surface Science
Elsevier., 338, 178-189.
https://doi.org/10.1016/j.apsusc.2015.02.133
Antić KM, Babić MM, Jovašević Vuković JJ, Vasiljević-Radović D, Onjia AE, Filipovic JM, Tomić SL. Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution. in Applied Surface Science. 2015;338:178-189.
doi:10.1016/j.apsusc.2015.02.133 .
Antić, Katarina M., Babić, Marija M., Jovašević Vuković, Jovana J., Vasiljević-Radović, Dana, Onjia, Antonije E., Filipovic, Jovanka M, Tomić, Simonida Lj., "Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution" in Applied Surface Science, 338 (2015):178-189,
https://doi.org/10.1016/j.apsusc.2015.02.133 . .
20
13
20

Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study

Milosavljevic, Nedeljko B.; Ristic, Mirjana D.; Peric-Grujic, Aleksandra A.; Filipovic, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier, 2011)

TY  - JOUR
AU  - Milosavljevic, Nedeljko B.
AU  - Ristic, Mirjana D.
AU  - Peric-Grujic, Aleksandra A.
AU  - Filipovic, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/800
AB  - A removal of Cu2+ ions from aqueous solutions onto hydrogels of chitosan. itaconic and methacrylic acid has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, initial metal ion concentration, contact time and temperature. The FIR spectra showed that -NH2, -OH and -COOH groups are involved in the Cu2+ ions adsorption. The surface topography changes were observed by AFM, where the phase images indicated that sorption takes place on the surface of the hydrogel and in the bulk. Pseudo-first order, pseudo-second order and intraparticle diffusion models were analyzed and showed that the Cu2+ ions adsorption followed pseudo-second order kinetics. The equilibrium data were analyzed using Langmuir, Freundlich and Redlich-Peterson isotherms and the best interpretation was given by Redlich-Peterson. The adsorption capacity was found to be 122.59 mg/g, based on the non-linear Langmuir isotherm. Based on the separation factor. R-L, the Cu2+ ion adsorption is favorable, while the low activation energies indicate physisorption. Desorption experiments, done with a nitric acid, showed that the investigated hydrogels could be reused without significant losses of the initial properties even after three adsorption-sorption cycles.
PB  - Elsevier
T2  - Colloids and Surfaces A-Physicochemical and Engineering Aspects
T1  - Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study
VL  - 388
IS  - 1-3
SP  - 59
EP  - 69
DO  - 10.1016/j.colsurfa.2011.08.011
ER  - 
@article{
author = "Milosavljevic, Nedeljko B. and Ristic, Mirjana D. and Peric-Grujic, Aleksandra A. and Filipovic, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2011",
abstract = "A removal of Cu2+ ions from aqueous solutions onto hydrogels of chitosan. itaconic and methacrylic acid has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, initial metal ion concentration, contact time and temperature. The FIR spectra showed that -NH2, -OH and -COOH groups are involved in the Cu2+ ions adsorption. The surface topography changes were observed by AFM, where the phase images indicated that sorption takes place on the surface of the hydrogel and in the bulk. Pseudo-first order, pseudo-second order and intraparticle diffusion models were analyzed and showed that the Cu2+ ions adsorption followed pseudo-second order kinetics. The equilibrium data were analyzed using Langmuir, Freundlich and Redlich-Peterson isotherms and the best interpretation was given by Redlich-Peterson. The adsorption capacity was found to be 122.59 mg/g, based on the non-linear Langmuir isotherm. Based on the separation factor. R-L, the Cu2+ ion adsorption is favorable, while the low activation energies indicate physisorption. Desorption experiments, done with a nitric acid, showed that the investigated hydrogels could be reused without significant losses of the initial properties even after three adsorption-sorption cycles.",
publisher = "Elsevier",
journal = "Colloids and Surfaces A-Physicochemical and Engineering Aspects",
title = "Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study",
volume = "388",
number = "1-3",
pages = "59-69",
doi = "10.1016/j.colsurfa.2011.08.011"
}
Milosavljevic, N. B., Ristic, M. D., Peric-Grujic, A. A., Filipovic, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2011). Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study. in Colloids and Surfaces A-Physicochemical and Engineering Aspects
Elsevier., 388(1-3), 59-69.
https://doi.org/10.1016/j.colsurfa.2011.08.011
Milosavljevic NB, Ristic MD, Peric-Grujic AA, Filipovic JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study. in Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2011;388(1-3):59-69.
doi:10.1016/j.colsurfa.2011.08.011 .
Milosavljevic, Nedeljko B., Ristic, Mirjana D., Peric-Grujic, Aleksandra A., Filipovic, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study" in Colloids and Surfaces A-Physicochemical and Engineering Aspects, 388, no. 1-3 (2011):59-69,
https://doi.org/10.1016/j.colsurfa.2011.08.011 . .
84
68
93

Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid

Milosavljevic, Nedeljko B.; Ristic, Mirjana D.; Peric-Grujic, Aleksandra A.; Filipovic, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier, 2011)

TY  - JOUR
AU  - Milosavljevic, Nedeljko B.
AU  - Ristic, Mirjana D.
AU  - Peric-Grujic, Aleksandra A.
AU  - Filipovic, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/805
AB  - Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn(2+) ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.
PB  - Elsevier
T2  - Journal of Hazardous Materials
T1  - Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid
VL  - 192
IS  - 2
SP  - 846
EP  - 854
DO  - 10.1016/j.jhazmat.2011.05.093
ER  - 
@article{
author = "Milosavljevic, Nedeljko B. and Ristic, Mirjana D. and Peric-Grujic, Aleksandra A. and Filipovic, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2011",
abstract = "Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn(2+) ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.",
publisher = "Elsevier",
journal = "Journal of Hazardous Materials",
title = "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid",
volume = "192",
number = "2",
pages = "846-854",
doi = "10.1016/j.jhazmat.2011.05.093"
}
Milosavljevic, N. B., Ristic, M. D., Peric-Grujic, A. A., Filipovic, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2011). Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid. in Journal of Hazardous Materials
Elsevier., 192(2), 846-854.
https://doi.org/10.1016/j.jhazmat.2011.05.093
Milosavljevic NB, Ristic MD, Peric-Grujic AA, Filipovic JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid. in Journal of Hazardous Materials. 2011;192(2):846-854.
doi:10.1016/j.jhazmat.2011.05.093 .
Milosavljevic, Nedeljko B., Ristic, Mirjana D., Peric-Grujic, Aleksandra A., Filipovic, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid" in Journal of Hazardous Materials, 192, no. 2 (2011):846-854,
https://doi.org/10.1016/j.jhazmat.2011.05.093 . .
58
43
56

Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution

Milosavljevic, Nedeljko B.; Ristic, Mirjana D.; Peric-Grujic, Aleksandra A.; Filipovic, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier Science Sa, Lausanne, 2010)

TY  - JOUR
AU  - Milosavljevic, Nedeljko B.
AU  - Ristic, Mirjana D.
AU  - Peric-Grujic, Aleksandra A.
AU  - Filipovic, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/687
AB  - A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution
VL  - 165
IS  - 2
SP  - 554
EP  - 562
DO  - 10.1016/j.cej.2010.09.072
ER  - 
@article{
author = "Milosavljevic, Nedeljko B. and Ristic, Mirjana D. and Peric-Grujic, Aleksandra A. and Filipovic, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2010",
abstract = "A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution",
volume = "165",
number = "2",
pages = "554-562",
doi = "10.1016/j.cej.2010.09.072"
}
Milosavljevic, N. B., Ristic, M. D., Peric-Grujic, A. A., Filipovic, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2010). Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 165(2), 554-562.
https://doi.org/10.1016/j.cej.2010.09.072
Milosavljevic NB, Ristic MD, Peric-Grujic AA, Filipovic JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal. 2010;165(2):554-562.
doi:10.1016/j.cej.2010.09.072 .
Milosavljevic, Nedeljko B., Ristic, Mirjana D., Peric-Grujic, Aleksandra A., Filipovic, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution" in Chemical Engineering Journal, 165, no. 2 (2010):554-562,
https://doi.org/10.1016/j.cej.2010.09.072 . .
46
44
46

Cohesive energy densities of poly(di‐n‐alkyl itaconates)

Veličković, Jovan S.; Filipović, Jovanka M.

(Wiley, 1977)

TY  - JOUR
AU  - Veličković, Jovan S.
AU  - Filipović, Jovanka M.
PY  - 1977
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4705
AB  - The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and hydrogen bonding capacity. Numerical values from 9.58 to 8.10 (cal/cm3)1/2 were obtained independently from measurements in hydrocarbon and oxygen containing solvents, close to solubility parameters calculated from polymer densities and molar attraction constants. The values obtained reflects the increasing paraffinic character within the series and can be correlated to solubility parameters published in the literature for structurally similar poly(alkyl acrylates) and poly(alkyl methacrylates).
PB  - Wiley
T2  - Die Angewandte Makromolekulare Chemie
T1  - Cohesive energy densities of poly(di‐n‐alkyl itaconates)
VL  - 57
IS  - 1
SP  - 139
EP  - 152
DO  - 10.1002/apmc.1977.050570111
ER  - 
@article{
author = "Veličković, Jovan S. and Filipović, Jovanka M.",
year = "1977",
abstract = "The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and hydrogen bonding capacity. Numerical values from 9.58 to 8.10 (cal/cm3)1/2 were obtained independently from measurements in hydrocarbon and oxygen containing solvents, close to solubility parameters calculated from polymer densities and molar attraction constants. The values obtained reflects the increasing paraffinic character within the series and can be correlated to solubility parameters published in the literature for structurally similar poly(alkyl acrylates) and poly(alkyl methacrylates).",
publisher = "Wiley",
journal = "Die Angewandte Makromolekulare Chemie",
title = "Cohesive energy densities of poly(di‐n‐alkyl itaconates)",
volume = "57",
number = "1",
pages = "139-152",
doi = "10.1002/apmc.1977.050570111"
}
Veličković, J. S.,& Filipović, J. M.. (1977). Cohesive energy densities of poly(di‐n‐alkyl itaconates). in Die Angewandte Makromolekulare Chemie
Wiley., 57(1), 139-152.
https://doi.org/10.1002/apmc.1977.050570111
Veličković JS, Filipović JM. Cohesive energy densities of poly(di‐n‐alkyl itaconates). in Die Angewandte Makromolekulare Chemie. 1977;57(1):139-152.
doi:10.1002/apmc.1977.050570111 .
Veličković, Jovan S., Filipović, Jovanka M., "Cohesive energy densities of poly(di‐n‐alkyl itaconates)" in Die Angewandte Makromolekulare Chemie, 57, no. 1 (1977):139-152,
https://doi.org/10.1002/apmc.1977.050570111 . .
3
4

Refractive index increments of di‐n‐alkylitaconate polymers and copolymers

Veličković, Jovan S.; Vukajlović-Filipović, Jovanka

(Wiley, 1970)

TY  - JOUR
AU  - Veličković, Jovan S.
AU  - Vukajlović-Filipović, Jovanka
PY  - 1970
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4688
AB  - Refractive index increments of 11 poly(di‐n‐alkylitaconate) polymers were determined systematically in seven organic solvents, expected to be suitable for light scattering and other solution property measurements. Of 13 solvents tried, poly(dimethylitaconate) was soluble only in 6, however higher members of the polymer series exhibit better solubility. The measured dn/dc values in butanone and ethyl‐and amylacetate are practically independent of an increase of the number of carbon atoms in the ester substituents of the monomer, however a decrease of the values for solvents with higher refractive indices can be observed. For statistical poly(styrene‐co‐di‐n‐alkylitaconate) samples the additive character of dn/dc in butanone and toluene was observed and verified from copolymer compositions determined by UV and elemental analysis.
AB  - Brechungsinkremente von elf verschiedenen Di-n-alkylitakonat-Polymerewn urden systematisch in sieben organischen Losungsmitteln bestimmt, um eine giinstige Auswahl fiir Lichtstreuungs- und andere Losung~igenschaftsmessungeznu ermoglichen. Polydimethylitakonat war nur in sechs von 13 untersuchten Losungsmitteln loslich, wiihrend hohere Glieder der Polymerenreihe bedeutend bessere Loslichkeiten
aufwiesen. Die ermittelten dn/dc Werte in Butanon, Athyl- und Amylacetat hangen praktisch von einer Zunahme der Zahl der Kohlenstoffatome in den Estersubstituenten nicht ab; bei Losungsmitteln mit hoheren Brechungsindizes ist aber eine sinkende Tendenz der Werte bemerkbar. Bei statistischen Copolymeren aus Styrol und Di-n-alkylitakonat wird der additive Charakter von dn/dc in Butanon und Toluol bemerkbar, welcher durch Bestimmung der chemischen Zusammensetzung mittels UV und Kohlenstoffgehalt bestiitigt werden konnte.
PB  - Wiley
T2  - Die Angewandte Makromolekulare Chemie
T1  - Refractive index increments of di‐n‐alkylitaconate polymers and copolymers
VL  - 13
IS  - 1
SP  - 79
EP  - 88
DO  - 10.1002/apmc.1970.050130106
ER  - 
@article{
author = "Veličković, Jovan S. and Vukajlović-Filipović, Jovanka",
year = "1970",
abstract = "Refractive index increments of 11 poly(di‐n‐alkylitaconate) polymers were determined systematically in seven organic solvents, expected to be suitable for light scattering and other solution property measurements. Of 13 solvents tried, poly(dimethylitaconate) was soluble only in 6, however higher members of the polymer series exhibit better solubility. The measured dn/dc values in butanone and ethyl‐and amylacetate are practically independent of an increase of the number of carbon atoms in the ester substituents of the monomer, however a decrease of the values for solvents with higher refractive indices can be observed. For statistical poly(styrene‐co‐di‐n‐alkylitaconate) samples the additive character of dn/dc in butanone and toluene was observed and verified from copolymer compositions determined by UV and elemental analysis., Brechungsinkremente von elf verschiedenen Di-n-alkylitakonat-Polymerewn urden systematisch in sieben organischen Losungsmitteln bestimmt, um eine giinstige Auswahl fiir Lichtstreuungs- und andere Losung~igenschaftsmessungeznu ermoglichen. Polydimethylitakonat war nur in sechs von 13 untersuchten Losungsmitteln loslich, wiihrend hohere Glieder der Polymerenreihe bedeutend bessere Loslichkeiten
aufwiesen. Die ermittelten dn/dc Werte in Butanon, Athyl- und Amylacetat hangen praktisch von einer Zunahme der Zahl der Kohlenstoffatome in den Estersubstituenten nicht ab; bei Losungsmitteln mit hoheren Brechungsindizes ist aber eine sinkende Tendenz der Werte bemerkbar. Bei statistischen Copolymeren aus Styrol und Di-n-alkylitakonat wird der additive Charakter von dn/dc in Butanon und Toluol bemerkbar, welcher durch Bestimmung der chemischen Zusammensetzung mittels UV und Kohlenstoffgehalt bestiitigt werden konnte.",
publisher = "Wiley",
journal = "Die Angewandte Makromolekulare Chemie",
title = "Refractive index increments of di‐n‐alkylitaconate polymers and copolymers",
volume = "13",
number = "1",
pages = "79-88",
doi = "10.1002/apmc.1970.050130106"
}
Veličković, J. S.,& Vukajlović-Filipović, J.. (1970). Refractive index increments of di‐n‐alkylitaconate polymers and copolymers. in Die Angewandte Makromolekulare Chemie
Wiley., 13(1), 79-88.
https://doi.org/10.1002/apmc.1970.050130106
Veličković JS, Vukajlović-Filipović J. Refractive index increments of di‐n‐alkylitaconate polymers and copolymers. in Die Angewandte Makromolekulare Chemie. 1970;13(1):79-88.
doi:10.1002/apmc.1970.050130106 .
Veličković, Jovan S., Vukajlović-Filipović, Jovanka, "Refractive index increments of di‐n‐alkylitaconate polymers and copolymers" in Die Angewandte Makromolekulare Chemie, 13, no. 1 (1970):79-88,
https://doi.org/10.1002/apmc.1970.050130106 . .
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