TY  - JOUR
AU  - Kokanović, Andrija
AU  - Ajdačić, Vladimir
AU  - Terzić Jovanović, Nataša
AU  - Stankić, Slavica
AU  - Opsenica, Igor
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7165
AB  - Herein, we report the synthesis and application of a highly active andversatile Pd/chemical vapor synthesis-ZnO (Pd/CVS-ZnO) catalytic system. The twosteppreparation of the catalyst includes chemical vapor synthesis (CVS) of ultrapureZnO nanotetrapods, followed by the liquid-phase in situ reduction of a Pd precursorand deposition of polycrystalline Pd nanoparticles (∼6 nm). The as-synthesized catalystwas characterized using standard instrumental techniques. The catalyst was successfullyapplied in four chemical reactions: Suzuki−Miyaura cross-coupling, reduction ofnitroarenes, decarbonylation, and hydrodebromination of aromatic compounds, ofwhich, the latter two are reported for the first time for the Pd/ZnO catalytic system.The catalyst showed excellent activity within a wide range of substrates, delivering the products in high yields (70−99%). Therecyclability of the Pd/CVS-ZnO catalyst was tested through two different approaches. First, the catalyst recyclability was examinedin all four reactions, reusing the catalyst up to four times in the Suzuki−Miyaura cross-coupling reaction, as well as the reduction of4-nitrobenzonitrile, without a significant loss of yield. Furthermore, the catalyst was successively used in three different reactions,showing a high degree of stability and delivering excellent product yields in all cases. In addition to its excellent activity, versatility,and stability, the Pd/CVS-ZnO catalytic system also exhibits excellent recyclability over consecutive runs, which makes it apromising candidate for future application in complex industrial processes.
PB  - American Chemical Society (ACS)
T2  - ACS Applied Nano Materials
T1  - Pd Nanoparticles Supported on Ultrapure ZnO Nanopowders as Reusable Multipurpose Catalysts
VL  - 6
IS  - 17
SP  - 15820
EP  - 15828
DO  - 10.1021/acsanm.3c02743
ER  - 

@article{
author = "Kokanović, Andrija and Ajdačić, Vladimir and Terzić Jovanović, Nataša and Stankić, Slavica and Opsenica, Igor",
year = "2023",
abstract = "Herein, we report the synthesis and application of a highly active andversatile Pd/chemical vapor synthesis-ZnO (Pd/CVS-ZnO) catalytic system. The twosteppreparation of the catalyst includes chemical vapor synthesis (CVS) of ultrapureZnO nanotetrapods, followed by the liquid-phase in situ reduction of a Pd precursorand deposition of polycrystalline Pd nanoparticles (∼6 nm). The as-synthesized catalystwas characterized using standard instrumental techniques. The catalyst was successfullyapplied in four chemical reactions: Suzuki−Miyaura cross-coupling, reduction ofnitroarenes, decarbonylation, and hydrodebromination of aromatic compounds, ofwhich, the latter two are reported for the first time for the Pd/ZnO catalytic system.The catalyst showed excellent activity within a wide range of substrates, delivering the products in high yields (70−99%). Therecyclability of the Pd/CVS-ZnO catalyst was tested through two different approaches. First, the catalyst recyclability was examinedin all four reactions, reusing the catalyst up to four times in the Suzuki−Miyaura cross-coupling reaction, as well as the reduction of4-nitrobenzonitrile, without a significant loss of yield. Furthermore, the catalyst was successively used in three different reactions,showing a high degree of stability and delivering excellent product yields in all cases. In addition to its excellent activity, versatility,and stability, the Pd/CVS-ZnO catalytic system also exhibits excellent recyclability over consecutive runs, which makes it apromising candidate for future application in complex industrial processes.",
publisher = "American Chemical Society (ACS)",
journal = "ACS Applied Nano Materials",
title = "Pd Nanoparticles Supported on Ultrapure ZnO Nanopowders as Reusable Multipurpose Catalysts",
volume = "6",
number = "17",
pages = "15820-15828",
doi = "10.1021/acsanm.3c02743"
}

Kokanović, A., Ajdačić, V., Terzić Jovanović, N., Stankić, S.,& Opsenica, I.. (2023). Pd Nanoparticles Supported on Ultrapure ZnO Nanopowders as Reusable Multipurpose Catalysts. in ACS Applied Nano Materials
American Chemical Society (ACS)., 6(17), 15820-15828.
https://doi.org/10.1021/acsanm.3c02743

Kokanović A, Ajdačić V, Terzić Jovanović N, Stankić S, Opsenica I. Pd Nanoparticles Supported on Ultrapure ZnO Nanopowders as Reusable Multipurpose Catalysts. in ACS Applied Nano Materials. 2023;6(17):15820-15828.
doi:10.1021/acsanm.3c02743 .

Kokanović, Andrija, Ajdačić, Vladimir, Terzić Jovanović, Nataša, Stankić, Slavica, Opsenica, Igor, "Pd Nanoparticles Supported on Ultrapure ZnO Nanopowders as Reusable Multipurpose Catalysts" in ACS Applied Nano Materials, 6, no. 17 (2023):15820-15828,
https://doi.org/10.1021/acsanm.3c02743 . .