TY  - JOUR
AU  - Džambaski, Zdravko
AU  - Tzaras, Dimitrios‐Ioannis
AU  - Lee, Sunggi
AU  - Kokotos, Christoforos G.
AU  - Bondžić, Bojan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2953
AB  - α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks.
PB  - Wiley
T2  - Advanced Synthesis & Catalysis
T1  - Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
VL  - 361
IS  - 8
SP  - 1792
EP  - 1797
DO  - 10.1002/adsc.201900061
ER  - 

@article{
author = "Džambaski, Zdravko and Tzaras, Dimitrios‐Ioannis and Lee, Sunggi and Kokotos, Christoforos G. and Bondžić, Bojan",
year = "2019",
abstract = "α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks.",
publisher = "Wiley",
journal = "Advanced Synthesis & Catalysis",
title = "Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction",
volume = "361",
number = "8",
pages = "1792-1797",
doi = "10.1002/adsc.201900061"
}

Džambaski, Z., Tzaras, D., Lee, S., Kokotos, C. G.,& Bondžić, B.. (2019). Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction. in Advanced Synthesis & Catalysis
Wiley., 361(8), 1792-1797.
https://doi.org/10.1002/adsc.201900061

Džambaski Z, Tzaras D, Lee S, Kokotos CG, Bondžić B. Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction. in Advanced Synthesis & Catalysis. 2019;361(8):1792-1797.
doi:10.1002/adsc.201900061 .

Džambaski, Zdravko, Tzaras, Dimitrios‐Ioannis, Lee, Sunggi, Kokotos, Christoforos G., Bondžić, Bojan, "Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction" in Advanced Synthesis & Catalysis, 361, no. 8 (2019):1792-1797,
https://doi.org/10.1002/adsc.201900061 . .

TY  - JOUR
AU  - Džambaski, Zdravko
AU  - Tzaras, Dimitrios‐Ioannis
AU  - Lee, Sunggi
AU  - Kokotos, Christoforos G.
AU  - Bondžić, Bojan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2954
AB  - α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks.
PB  - Wiley
T2  - Advanced Synthesis & Catalysis
T1  - Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
VL  - 361
IS  - 8
SP  - 1792
EP  - 1797
DO  - 10.1002/adsc.201900061
ER  - 

@article{
author = "Džambaski, Zdravko and Tzaras, Dimitrios‐Ioannis and Lee, Sunggi and Kokotos, Christoforos G. and Bondžić, Bojan",
year = "2019",
abstract = "α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks.",
publisher = "Wiley",
journal = "Advanced Synthesis & Catalysis",
title = "Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction",
volume = "361",
number = "8",
pages = "1792-1797",
doi = "10.1002/adsc.201900061"
}

Džambaski, Z., Tzaras, D., Lee, S., Kokotos, C. G.,& Bondžić, B.. (2019). Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction. in Advanced Synthesis & Catalysis
Wiley., 361(8), 1792-1797.
https://doi.org/10.1002/adsc.201900061

Džambaski Z, Tzaras D, Lee S, Kokotos CG, Bondžić B. Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction. in Advanced Synthesis & Catalysis. 2019;361(8):1792-1797.
doi:10.1002/adsc.201900061 .

Džambaski, Zdravko, Tzaras, Dimitrios‐Ioannis, Lee, Sunggi, Kokotos, Christoforos G., Bondžić, Bojan, "Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction" in Advanced Synthesis & Catalysis, 361, no. 8 (2019):1792-1797,
https://doi.org/10.1002/adsc.201900061 . .