TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Jovicevic, Niko
AU  - Stevanović, Jasmina
AU  - Pavlović, Miomir
AU  - Vukićević, Nataša
AU  - Stevanović, Zoran
AU  - Jovićević, Jovan N.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2181
AB  - Magnesium underpotential deposition on gold electrodes from magnesium nitrate-ammonium nitrate melts has been investigated. Linear sweep voltammetry and potential step were used as electrochemical techniques. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD) were used for characterization of obtained electrode surfaces. It was observed that reduction processes of nitrate, nitrite and traces of water (when present), in the Mg underpotential range studied, proceeded simultaneously with magnesium underpotential deposition. There was no clear evidence of Mg/Au alloy formation induced by Mg UPD from the melt made from eutectic mixture [Mg(NO3)(2).6H(2)O + NH4NO3.XH2O]. However, EDS and XRD analysis showed magnesium present in the gold substrate and four different Mg/Au alloys being formed as a result of magnesium underpotential deposition and interdiffusion between Mg deposit and Au substrate from the melt made of a nonaqueous [Mg(NO3)(2) + NH4NO3] eutectic mixture at 460 K.
PB  - MDPI
T2  - Metals
T1  - Magnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts
VL  - 7
IS  - 3
DO  - 10.3390/met7030095
ER  - 

@article{
author = "Cvetković, Vesna S. and Jovicevic, Niko and Stevanović, Jasmina and Pavlović, Miomir and Vukićević, Nataša and Stevanović, Zoran and Jovićević, Jovan N.",
year = "2017",
abstract = "Magnesium underpotential deposition on gold electrodes from magnesium nitrate-ammonium nitrate melts has been investigated. Linear sweep voltammetry and potential step were used as electrochemical techniques. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD) were used for characterization of obtained electrode surfaces. It was observed that reduction processes of nitrate, nitrite and traces of water (when present), in the Mg underpotential range studied, proceeded simultaneously with magnesium underpotential deposition. There was no clear evidence of Mg/Au alloy formation induced by Mg UPD from the melt made from eutectic mixture [Mg(NO3)(2).6H(2)O + NH4NO3.XH2O]. However, EDS and XRD analysis showed magnesium present in the gold substrate and four different Mg/Au alloys being formed as a result of magnesium underpotential deposition and interdiffusion between Mg deposit and Au substrate from the melt made of a nonaqueous [Mg(NO3)(2) + NH4NO3] eutectic mixture at 460 K.",
publisher = "MDPI",
journal = "Metals",
title = "Magnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts",
volume = "7",
number = "3",
doi = "10.3390/met7030095"
}

Cvetković, V. S., Jovicevic, N., Stevanović, J., Pavlović, M., Vukićević, N., Stevanović, Z.,& Jovićević, J. N.. (2017). Magnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts. in Metals
MDPI., 7(3).
https://doi.org/10.3390/met7030095

Cvetković VS, Jovicevic N, Stevanović J, Pavlović M, Vukićević N, Stevanović Z, Jovićević JN. Magnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts. in Metals. 2017;7(3).
doi:10.3390/met7030095 .

Cvetković, Vesna S., Jovicevic, Niko, Stevanović, Jasmina, Pavlović, Miomir, Vukićević, Nataša, Stevanović, Zoran, Jovićević, Jovan N., "Magnesium-Gold Alloy Formation by Underpotential Deposition of Magnesium onto Gold from Nitrate Melts" in Metals, 7, no. 3 (2017),
https://doi.org/10.3390/met7030095 . .

TY  - JOUR
AU  - Jovicevic, Niko
AU  - Cvetković, Vesna S.
AU  - Kamberovic, Zeljko
AU  - Barudžija, Tanja S.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1789
AB  - Aim of this work was to study underpotential deposition of aluminium onto polycrystalline vanadium electrode from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. It was found that aluminium was deposited and incorporated into polycrystalline vanadium electrode at potentials more positive than the Al reverse potential. Applied electrochemical techniques: linear sweep voltammetry and potentiostatic deposition/ galvanostatic striping, showed clear evidence of formation of three intermetallic compounds whose presence depends on temperature and applied deposition time. Deposits were studied via scanning electron microscopy (SEM), energy dispersive spectrometry and X-ray spectroscopy (EDS and EDX), atomic force microscopy (AFM) and X-ray diffraction (XRD).
PB  - Electrochemical Science Group
T2  - International Journal of Electrochemical Science
T1  - Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate
VL  - 10
IS  - 11
SP  - 8959
EP  - 8972
UR  - https://hdl.handle.net/21.15107/rcub_cer_1789
ER  - 

@article{
author = "Jovicevic, Niko and Cvetković, Vesna S. and Kamberovic, Zeljko and Barudžija, Tanja S.",
year = "2015",
abstract = "Aim of this work was to study underpotential deposition of aluminium onto polycrystalline vanadium electrode from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. It was found that aluminium was deposited and incorporated into polycrystalline vanadium electrode at potentials more positive than the Al reverse potential. Applied electrochemical techniques: linear sweep voltammetry and potentiostatic deposition/ galvanostatic striping, showed clear evidence of formation of three intermetallic compounds whose presence depends on temperature and applied deposition time. Deposits were studied via scanning electron microscopy (SEM), energy dispersive spectrometry and X-ray spectroscopy (EDS and EDX), atomic force microscopy (AFM) and X-ray diffraction (XRD).",
publisher = "Electrochemical Science Group",
journal = "International Journal of Electrochemical Science",
title = "Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate",
volume = "10",
number = "11",
pages = "8959-8972",
url = "https://hdl.handle.net/21.15107/rcub_cer_1789"
}

Jovicevic, N., Cvetković, V. S., Kamberovic, Z.,& Barudžija, T. S.. (2015). Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate. in International Journal of Electrochemical Science
Electrochemical Science Group., 10(11), 8959-8972.
https://hdl.handle.net/21.15107/rcub_cer_1789

Jovicevic N, Cvetković VS, Kamberovic Z, Barudžija TS. Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate. in International Journal of Electrochemical Science. 2015;10(11):8959-8972.
https://hdl.handle.net/21.15107/rcub_cer_1789 .

Jovicevic, Niko, Cvetković, Vesna S., Kamberovic, Zeljko, Barudžija, Tanja S., "Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate" in International Journal of Electrochemical Science, 10, no. 11 (2015):8959-8972,
https://hdl.handle.net/21.15107/rcub_cer_1789 .