TY  - JOUR
AU  - Tripković, Dušan
AU  - Milošević, Dragana
AU  - Stevanović, Sanja
AU  - Popović, Ksenija
AU  - Jovanović, Vladislava
AU  - Lopes, Pietro
AU  - Farinazzo Bergamo Dias Martins, Pedro
AU  - Stamenković, Vojislav
AU  - Strmcnik, Dusan
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7701
AB  - Successful development of catalysts for electrochemical formic
acid oxidation (FAO) requires fnding an optimal balance between catalytic
performance (activity, stability, and selectivity) and catalyst cost. While
platinum is one of the most active catalyst materials for FAO, it suffers from
performance loss at low overpotentials due to poisoning with CO, which is
one of the intermediates formed in the so-called indirect path of FAO. In this
work, we explored the synergistic effects of the supporting material and
annealing temperature on the performance of Pt thin flms for FAO in acidic
media. Compared to the as-prepared Pt flms, the annealed flms show up to
5-fold and 15-fold improvement for FAO on Pt@Ni and Pt@Cr, respectively.
While the most active Pt@Ni thin flm shows the lowest stability, the most
active Pt@Cr thin flm is also the most stable, challenging conventional tradeoffs in electrocatalysis and providing a promising candidate for FAO
nanocatalyst synthesis.
PB  - American Chemical Society
T2  - ACS Catalysis
T1  - Design of Advanced Thin-Film Catalysts for Electrooxidation of Formic Acid
VL  - 14
IS  - 4
SP  - 2380
EP  - 2387
DO  - 10.1021/acscatal.3c05520
ER  - 

@article{
author = "Tripković, Dušan and Milošević, Dragana and Stevanović, Sanja and Popović, Ksenija and Jovanović, Vladislava and Lopes, Pietro and Farinazzo Bergamo Dias Martins, Pedro and Stamenković, Vojislav and Strmcnik, Dusan",
year = "2024",
abstract = "Successful development of catalysts for electrochemical formic
acid oxidation (FAO) requires fnding an optimal balance between catalytic
performance (activity, stability, and selectivity) and catalyst cost. While
platinum is one of the most active catalyst materials for FAO, it suffers from
performance loss at low overpotentials due to poisoning with CO, which is
one of the intermediates formed in the so-called indirect path of FAO. In this
work, we explored the synergistic effects of the supporting material and
annealing temperature on the performance of Pt thin flms for FAO in acidic
media. Compared to the as-prepared Pt flms, the annealed flms show up to
5-fold and 15-fold improvement for FAO on Pt@Ni and Pt@Cr, respectively.
While the most active Pt@Ni thin flm shows the lowest stability, the most
active Pt@Cr thin flm is also the most stable, challenging conventional tradeoffs in electrocatalysis and providing a promising candidate for FAO
nanocatalyst synthesis.",
publisher = "American Chemical Society",
journal = "ACS Catalysis",
title = "Design of Advanced Thin-Film Catalysts for Electrooxidation of Formic Acid",
volume = "14",
number = "4",
pages = "2380-2387",
doi = "10.1021/acscatal.3c05520"
}

Tripković, D., Milošević, D., Stevanović, S., Popović, K., Jovanović, V., Lopes, P., Farinazzo Bergamo Dias Martins, P., Stamenković, V.,& Strmcnik, D.. (2024). Design of Advanced Thin-Film Catalysts for Electrooxidation of Formic Acid. in ACS Catalysis
American Chemical Society., 14(4), 2380-2387.
https://doi.org/10.1021/acscatal.3c05520

Tripković D, Milošević D, Stevanović S, Popović K, Jovanović V, Lopes P, Farinazzo Bergamo Dias Martins P, Stamenković V, Strmcnik D. Design of Advanced Thin-Film Catalysts for Electrooxidation of Formic Acid. in ACS Catalysis. 2024;14(4):2380-2387.
doi:10.1021/acscatal.3c05520 .

Tripković, Dušan, Milošević, Dragana, Stevanović, Sanja, Popović, Ksenija, Jovanović, Vladislava, Lopes, Pietro, Farinazzo Bergamo Dias Martins, Pedro, Stamenković, Vojislav, Strmcnik, Dusan, "Design of Advanced Thin-Film Catalysts for Electrooxidation of Formic Acid" in ACS Catalysis, 14, no. 4 (2024):2380-2387,
https://doi.org/10.1021/acscatal.3c05520 . .

TY  - JOUR
AU  - Chung, Dong Young
AU  - Lopes, Pietro Papa
AU  - Farinazzo Bergamo Dias Martins, Pedro
AU  - He, Haiying
AU  - Kawaguchi, Tomoya
AU  - Zapol, Peter
AU  - You, Hoydoo
AU  - Tripković, Dušan
AU  - Strmcnik, Dusan
AU  - Zhu, Yisi
AU  - Seifert, Soenke
AU  - Lee, Sungsik
AU  - Stamenković, Vojislav
AU  - Marković, Nenad M.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3485
AB  - The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the oxygen evolution reaction on conductive M1OxHy, Fe–M1OxHy and Fe–M1M2OxHy hydr(oxy)oxide clusters (M1 = Ni, Co, Fe; M2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe–M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces.
PB  - Springer Science and Business Media LLC
T2  - Nature Energy
T1  - Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
VL  - 5
IS  - 3
SP  - 222
EP  - 230
DO  - 10.1038/s41560-020-0576-y
ER  - 

@article{
author = "Chung, Dong Young and Lopes, Pietro Papa and Farinazzo Bergamo Dias Martins, Pedro and He, Haiying and Kawaguchi, Tomoya and Zapol, Peter and You, Hoydoo and Tripković, Dušan and Strmcnik, Dusan and Zhu, Yisi and Seifert, Soenke and Lee, Sungsik and Stamenković, Vojislav and Marković, Nenad M.",
year = "2020",
abstract = "The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the oxygen evolution reaction on conductive M1OxHy, Fe–M1OxHy and Fe–M1M2OxHy hydr(oxy)oxide clusters (M1 = Ni, Co, Fe; M2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe–M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces.",
publisher = "Springer Science and Business Media LLC",
journal = "Nature Energy",
title = "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction",
volume = "5",
number = "3",
pages = "222-230",
doi = "10.1038/s41560-020-0576-y"
}

Chung, D. Y., Lopes, P. P., Farinazzo Bergamo Dias Martins, P., He, H., Kawaguchi, T., Zapol, P., You, H., Tripković, D., Strmcnik, D., Zhu, Y., Seifert, S., Lee, S., Stamenković, V.,& Marković, N. M.. (2020). Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction. in Nature Energy
Springer Science and Business Media LLC., 5(3), 222-230.
https://doi.org/10.1038/s41560-020-0576-y

Chung DY, Lopes PP, Farinazzo Bergamo Dias Martins P, He H, Kawaguchi T, Zapol P, You H, Tripković D, Strmcnik D, Zhu Y, Seifert S, Lee S, Stamenković V, Marković NM. Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction. in Nature Energy. 2020;5(3):222-230.
doi:10.1038/s41560-020-0576-y .

Chung, Dong Young, Lopes, Pietro Papa, Farinazzo Bergamo Dias Martins, Pedro, He, Haiying, Kawaguchi, Tomoya, Zapol, Peter, You, Hoydoo, Tripković, Dušan, Strmcnik, Dusan, Zhu, Yisi, Seifert, Soenke, Lee, Sungsik, Stamenković, Vojislav, Marković, Nenad M., "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction" in Nature Energy, 5, no. 3 (2020):222-230,
https://doi.org/10.1038/s41560-020-0576-y . .

TY  - JOUR
AU  - Chung, Dong Young
AU  - Lopes, Pietro
AU  - Farinazzo Bergamo Dias Martins, Pedro
AU  - He, Haiying
AU  - Kawaguchi, Tomoya
AU  - Zapol, Peter
AU  - You, Hoydoo
AU  - Tripković, Dušan
AU  - Strmcnik, Dusan
AU  - Zhu, Yisi
AU  - Seifert, Soenke
AU  - Lee, Sungsik
AU  - Stamenković, Vojislav
AU  - Marković, Nenad M.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3700
AB  - The poor activity and stability of electrode materials for the oxygen evolution reaction (OER) are the main bottlenecks in the water splitting reaction for H2 production. Here, by studying activity
stability trends for the OER on conductive M1OxHy, Fe-M1OxHy and Fe-M1M2OxHy
hydr(oxy)oxide clusters (M1= Ni, Co, Fe; M2= Mn, Co, Cu), we show that balancing the rates of
Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites.
Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the
 MOxHy host is the key to control the average number of Fe active sites present at the solid-liquid
 interface. We suggest that the Fe-M adsorption energy can therefore serve as a reaction
 descriptor that unifies OER catalysis on 3d transition metal hydr(oxy)oxides in alkaline media.
 Thus, introduction of dynamically stable active sites extends the design rules for making active
 and stable interfaces.
PB  - Springer Science and Business Media LLC
T2  - Nature Energy
T1  - Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
VL  - 5
VL  - 230
IS  - 3
SP  - 222
EP  - 230
DO  - 10.1038/s41560-020-0576-y
ER  - 

@article{
author = "Chung, Dong Young and Lopes, Pietro and Farinazzo Bergamo Dias Martins, Pedro and He, Haiying and Kawaguchi, Tomoya and Zapol, Peter and You, Hoydoo and Tripković, Dušan and Strmcnik, Dusan and Zhu, Yisi and Seifert, Soenke and Lee, Sungsik and Stamenković, Vojislav and Marković, Nenad M.",
year = "2020",
abstract = "The poor activity and stability of electrode materials for the oxygen evolution reaction (OER) are the main bottlenecks in the water splitting reaction for H2 production. Here, by studying activity
stability trends for the OER on conductive M1OxHy, Fe-M1OxHy and Fe-M1M2OxHy
hydr(oxy)oxide clusters (M1= Ni, Co, Fe; M2= Mn, Co, Cu), we show that balancing the rates of
Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites.
Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the
 MOxHy host is the key to control the average number of Fe active sites present at the solid-liquid
 interface. We suggest that the Fe-M adsorption energy can therefore serve as a reaction
 descriptor that unifies OER catalysis on 3d transition metal hydr(oxy)oxides in alkaline media.
 Thus, introduction of dynamically stable active sites extends the design rules for making active
 and stable interfaces.",
publisher = "Springer Science and Business Media LLC",
journal = "Nature Energy",
title = "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction",
volume = "5, 230",
number = "3",
pages = "222-230",
doi = "10.1038/s41560-020-0576-y"
}

Chung, D. Y., Lopes, P., Farinazzo Bergamo Dias Martins, P., He, H., Kawaguchi, T., Zapol, P., You, H., Tripković, D., Strmcnik, D., Zhu, Y., Seifert, S., Lee, S., Stamenković, V.,& Marković, N. M.. (2020). Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction. in Nature Energy
Springer Science and Business Media LLC., 5(3), 222-230.
https://doi.org/10.1038/s41560-020-0576-y

Chung DY, Lopes P, Farinazzo Bergamo Dias Martins P, He H, Kawaguchi T, Zapol P, You H, Tripković D, Strmcnik D, Zhu Y, Seifert S, Lee S, Stamenković V, Marković NM. Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction. in Nature Energy. 2020;5(3):222-230.
doi:10.1038/s41560-020-0576-y .

Chung, Dong Young, Lopes, Pietro, Farinazzo Bergamo Dias Martins, Pedro, He, Haiying, Kawaguchi, Tomoya, Zapol, Peter, You, Hoydoo, Tripković, Dušan, Strmcnik, Dusan, Zhu, Yisi, Seifert, Soenke, Lee, Sungsik, Stamenković, Vojislav, Marković, Nenad M., "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction" in Nature Energy, 5, no. 3 (2020):222-230,
https://doi.org/10.1038/s41560-020-0576-y . .