TY  - JOUR
AU  - Lazarević, Zorica Ž.
AU  - Milutinović, Aleksandra
AU  - Umićević, Ana
AU  - Ivanovski, Valentin N.
AU  - Koteski, Vasil
AU  - Anđelković, Ljubica
AU  - Romčević, Nebojša
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7837
AB  - The powdery cobalt ferrite (CoFe2O4) is prepared by coprecipitation followed by mechanochemical synthesis in a planetary ball mill. Obtained nanomaterial has been studied using a variety of characterization techniques: X-ray diffraction (XRD), Raman spectroscopy, far infrared (FIR) reflectivity and attenuated total reflectance (ATR) in combination with Fourier transform infrared (FTIR) spectroscopy in mid IR spectra. The investigated CoFe2O4 nanomaterial showed a typical XRD pattern of cubic spinel. In the Raman and IR spectra are observed all of first-order Raman and IR active modes. Weak sub bands activated by structure disorder are seen also. Since nano-CoFe2O4 is macroscopically cubic, its main Raman and IR modes are assigned as in normal cubic spinel. Raman spectrum is fitted with 8 Lorentzian peaks. It is observed that the value of x  0.58 obtained from Raman spectrum, is in good agreement with the value obtained by XRD-structural analysis (0.51). To analyze the IR spectra, we used Decoupled Plasmon - Phonon (DPP) model of the complex dielectric function. Measurement of magnetization in the range of magnetic fields H>>Hc enable the calculation of the anisotropy coefficient K1 = 4.02·105 J cm-3 , which is very high in cobalt ferrite. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was measured at room temperature in ± 12 mm s-1 Doppler velocity range. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was fitted with the extended Voigt-based fitting method.
PB  - INOE, Romania
T2  - Optoelectronics and Advanced Materials – Rapid Communications
T1  - Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment
VL  - 18
IS  - 5-6
SP  - 289
EP  - 295
UR  - https://hdl.handle.net/21.15107/rcub_cer_7837
ER  - 

@article{
author = "Lazarević, Zorica Ž. and Milutinović, Aleksandra and Umićević, Ana and Ivanovski, Valentin N. and Koteski, Vasil and Anđelković, Ljubica and Romčević, Nebojša",
year = "2024",
abstract = "The powdery cobalt ferrite (CoFe2O4) is prepared by coprecipitation followed by mechanochemical synthesis in a planetary ball mill. Obtained nanomaterial has been studied using a variety of characterization techniques: X-ray diffraction (XRD), Raman spectroscopy, far infrared (FIR) reflectivity and attenuated total reflectance (ATR) in combination with Fourier transform infrared (FTIR) spectroscopy in mid IR spectra. The investigated CoFe2O4 nanomaterial showed a typical XRD pattern of cubic spinel. In the Raman and IR spectra are observed all of first-order Raman and IR active modes. Weak sub bands activated by structure disorder are seen also. Since nano-CoFe2O4 is macroscopically cubic, its main Raman and IR modes are assigned as in normal cubic spinel. Raman spectrum is fitted with 8 Lorentzian peaks. It is observed that the value of x  0.58 obtained from Raman spectrum, is in good agreement with the value obtained by XRD-structural analysis (0.51). To analyze the IR spectra, we used Decoupled Plasmon - Phonon (DPP) model of the complex dielectric function. Measurement of magnetization in the range of magnetic fields H>>Hc enable the calculation of the anisotropy coefficient K1 = 4.02·105 J cm-3 , which is very high in cobalt ferrite. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was measured at room temperature in ± 12 mm s-1 Doppler velocity range. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was fitted with the extended Voigt-based fitting method.",
publisher = "INOE, Romania",
journal = "Optoelectronics and Advanced Materials – Rapid Communications",
title = "Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment",
volume = "18",
number = "5-6",
pages = "289-295",
url = "https://hdl.handle.net/21.15107/rcub_cer_7837"
}

Lazarević, Z. Ž., Milutinović, A., Umićević, A., Ivanovski, V. N., Koteski, V., Anđelković, L.,& Romčević, N.. (2024). Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment. in Optoelectronics and Advanced Materials – Rapid Communications
INOE, Romania., 18(5-6), 289-295.
https://hdl.handle.net/21.15107/rcub_cer_7837

Lazarević ZŽ, Milutinović A, Umićević A, Ivanovski VN, Koteski V, Anđelković L, Romčević N. Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment. in Optoelectronics and Advanced Materials – Rapid Communications. 2024;18(5-6):289-295.
https://hdl.handle.net/21.15107/rcub_cer_7837 .

Lazarević, Zorica Ž., Milutinović, Aleksandra, Umićević, Ana, Ivanovski, Valentin N., Koteski, Vasil, Anđelković, Ljubica, Romčević, Nebojša, "Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment" in Optoelectronics and Advanced Materials – Rapid Communications, 18, no. 5-6 (2024):289-295,
https://hdl.handle.net/21.15107/rcub_cer_7837 .

TY  - JOUR
AU  - Lazarević, Zorica
AU  - Milutinović, Aleksandra
AU  - Umićević, Ana
AU  - Ivanovski, Valentin
AU  - Koteski, Vasil
AU  - Anđelković, Ljubica
AU  - Romčević, Nebojša
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7659
AB  - The powdery cobalt ferrite (CoFe2O4) is prepared by coprecipitation followed by mechanochemical synthesis in a planetary ball mill. Obtained nanomaterial has been studied using a variety of characterization techniques: X-ray diffraction (XRD), Raman spectroscopy, far infrared (FIR) reflectivity and attenuated total reflectance (ATR) in combination with Fourier-transform infrared (FTIR) spectroscopy in mid IR spectra. The investigated CoFe2O4 nanomaterial showed a typical XRD pattern of cubic spinel. In the Raman and IR spectra are observed all of first-order Raman and IR active modes. Weak sub-bands activated by structure disorder are seen also. Since nano-CoFe2O4 is macroscopically cubic, its main Raman and IR modes are assigned as in normal cubic spinel. Raman spectrum is fitted with 8 Lorentzian peaks. It is observed that the value of x 0.58 obtained from Raman spectrum, is in good agreement with the value obtained by XRD-structural analysis (0.51). To analyze the IR spectra, we used Decoupled Plasmon - Phonon (DPP) model of the complex dielectric function. Measurement of magnetization in the range of magnetic fields H>>Hc enable the calculation of the anisotropy coefficient K1 = 4.02·105 J cm-3, which is very high in cobalt ferrite. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was measured at room temperature in ± 12 mm s-1 Doppler velocity range. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was fitted with the extended Voigt-based fitting method.
PB  - INOE, Romania
T2  - Optoelectronics and Advanced Materials – Rapid Communications
T1  - Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment
VL  - 18
IS  - 5-6
SP  - 289
EP  - 295
UR  - https://hdl.handle.net/21.15107/rcub_cer_7659
ER  - 

@article{
author = "Lazarević, Zorica and Milutinović, Aleksandra and Umićević, Ana and Ivanovski, Valentin and Koteski, Vasil and Anđelković, Ljubica and Romčević, Nebojša",
year = "2024",
abstract = "The powdery cobalt ferrite (CoFe2O4) is prepared by coprecipitation followed by mechanochemical synthesis in a planetary ball mill. Obtained nanomaterial has been studied using a variety of characterization techniques: X-ray diffraction (XRD), Raman spectroscopy, far infrared (FIR) reflectivity and attenuated total reflectance (ATR) in combination with Fourier-transform infrared (FTIR) spectroscopy in mid IR spectra. The investigated CoFe2O4 nanomaterial showed a typical XRD pattern of cubic spinel. In the Raman and IR spectra are observed all of first-order Raman and IR active modes. Weak sub-bands activated by structure disorder are seen also. Since nano-CoFe2O4 is macroscopically cubic, its main Raman and IR modes are assigned as in normal cubic spinel. Raman spectrum is fitted with 8 Lorentzian peaks. It is observed that the value of x 0.58 obtained from Raman spectrum, is in good agreement with the value obtained by XRD-structural analysis (0.51). To analyze the IR spectra, we used Decoupled Plasmon - Phonon (DPP) model of the complex dielectric function. Measurement of magnetization in the range of magnetic fields H>>Hc enable the calculation of the anisotropy coefficient K1 = 4.02·105 J cm-3, which is very high in cobalt ferrite. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was measured at room temperature in ± 12 mm s-1 Doppler velocity range. The 57Fe-Mössbauer spectrum of the CoFe2O4 sample was fitted with the extended Voigt-based fitting method.",
publisher = "INOE, Romania",
journal = "Optoelectronics and Advanced Materials – Rapid Communications",
title = "Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment",
volume = "18",
number = "5-6",
pages = "289-295",
url = "https://hdl.handle.net/21.15107/rcub_cer_7659"
}

Lazarević, Z., Milutinović, A., Umićević, A., Ivanovski, V., Koteski, V., Anđelković, L.,& Romčević, N.. (2024). Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment. in Optoelectronics and Advanced Materials – Rapid Communications
INOE, Romania., 18(5-6), 289-295.
https://hdl.handle.net/21.15107/rcub_cer_7659

Lazarević Z, Milutinović A, Umićević A, Ivanovski V, Koteski V, Anđelković L, Romčević N. Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment. in Optoelectronics and Advanced Materials – Rapid Communications. 2024;18(5-6):289-295.
https://hdl.handle.net/21.15107/rcub_cer_7659 .

Lazarević, Zorica, Milutinović, Aleksandra, Umićević, Ana, Ivanovski, Valentin, Koteski, Vasil, Anđelković, Ljubica, Romčević, Nebojša, "Mössbauer spectroscopy study of nanosized spinel CoFe2O4 ferrite obtained during coprecipitation followed by mechanochemical treatment" in Optoelectronics and Advanced Materials – Rapid Communications, 18, no. 5-6 (2024):289-295,
https://hdl.handle.net/21.15107/rcub_cer_7659 .