TY  - JOUR
AU  - Popović, Mina
AU  - Veličković, Zlate S.
AU  - Bogdanov, Jovica
AU  - Marinković, Aleksandar D.
AU  - Luna, Mariano Casas
AU  - Trajković, Isaak
AU  - Obradović, Nina
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5238
AB  - In this study, the structure, morphology and composition of the synthesized magnetite/3D-printed wollastonite (3D_W/M) composite were characterized, and its adsorption performance with respect to As(V) and Cr(VI) were studied. Magnetite (MG) modified 3D printed wollastonite was obtained by two step procedure: modification of 3D_W with 3-aminoproylsilane (APTES) followed by controlled magnetite (MG) deposition to obtain 3D_W/M adsorbent. The structure/properties of 3D_W/M were confirmed by applying FTIR, XRD, TGD/DTA, and SEM analysis. The adsorption properties of hybrid adsorbents were carried out for As(V) and Cr(VI) removal-one relative to the initial pH value, the adsorbent mass, the temperature, and the adsorption time. Time-dependent adsorption study was best described by pseudo-second order equation, while Weber Morris analysis showed that intraparticle diffusion controled diffusional transport. Similar activation energy, 17.44 and 14.49 kJ•mol-1 for adsorption As(V) and Cr(VI) on 3D_W/M, respectively, indicated main contribution of physical adsorption. Determination of adsorption parameters was performed by applying different adsorption isotherm models, and the best fit was obtained using Freundlich model. The adsorption capacity of 24.16 and 29.6 mg g-1 for As(V) and Cr(VI) at 2o C, Co = 5.5 and 5.3 mg L-1, respectively, were obtained. Thermodynamic study indicated favourable process at a higher temperature. Preliminary fixed-bed column study and results fitting with Bohart-Adams, Yoon-Nelson, Thomas, and Modified dose-response model showed good agreement with results from the batch study.
PB  - International Institute for the Science of Sintering (IISS)
T2  - Science of Sintering
T1  - Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent
VL  - 54
IS  - 1
SP  - 105
EP  - 124
DO  - 10.2298/SOS2201105P
ER  - 

@article{
author = "Popović, Mina and Veličković, Zlate S. and Bogdanov, Jovica and Marinković, Aleksandar D. and Luna, Mariano Casas and Trajković, Isaak and Obradović, Nina and Pavlović, Vladimir B.",
year = "2022",
abstract = "In this study, the structure, morphology and composition of the synthesized magnetite/3D-printed wollastonite (3D_W/M) composite were characterized, and its adsorption performance with respect to As(V) and Cr(VI) were studied. Magnetite (MG) modified 3D printed wollastonite was obtained by two step procedure: modification of 3D_W with 3-aminoproylsilane (APTES) followed by controlled magnetite (MG) deposition to obtain 3D_W/M adsorbent. The structure/properties of 3D_W/M were confirmed by applying FTIR, XRD, TGD/DTA, and SEM analysis. The adsorption properties of hybrid adsorbents were carried out for As(V) and Cr(VI) removal-one relative to the initial pH value, the adsorbent mass, the temperature, and the adsorption time. Time-dependent adsorption study was best described by pseudo-second order equation, while Weber Morris analysis showed that intraparticle diffusion controled diffusional transport. Similar activation energy, 17.44 and 14.49 kJ•mol-1 for adsorption As(V) and Cr(VI) on 3D_W/M, respectively, indicated main contribution of physical adsorption. Determination of adsorption parameters was performed by applying different adsorption isotherm models, and the best fit was obtained using Freundlich model. The adsorption capacity of 24.16 and 29.6 mg g-1 for As(V) and Cr(VI) at 2o C, Co = 5.5 and 5.3 mg L-1, respectively, were obtained. Thermodynamic study indicated favourable process at a higher temperature. Preliminary fixed-bed column study and results fitting with Bohart-Adams, Yoon-Nelson, Thomas, and Modified dose-response model showed good agreement with results from the batch study.",
publisher = "International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent",
volume = "54",
number = "1",
pages = "105-124",
doi = "10.2298/SOS2201105P"
}

Popović, M., Veličković, Z. S., Bogdanov, J., Marinković, A. D., Luna, M. C., Trajković, I., Obradović, N.,& Pavlović, V. B.. (2022). Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent. in Science of Sintering
International Institute for the Science of Sintering (IISS)., 54(1), 105-124.
https://doi.org/10.2298/SOS2201105P

Popović M, Veličković ZS, Bogdanov J, Marinković AD, Luna MC, Trajković I, Obradović N, Pavlović VB. Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent. in Science of Sintering. 2022;54(1):105-124.
doi:10.2298/SOS2201105P .

Popović, Mina, Veličković, Zlate S., Bogdanov, Jovica, Marinković, Aleksandar D., Luna, Mariano Casas, Trajković, Isaak, Obradović, Nina, Pavlović, Vladimir B., "Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent" in Science of Sintering, 54, no. 1 (2022):105-124,
https://doi.org/10.2298/SOS2201105P . .

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4356
AB  - Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction
VL  - 53
SP  - 1
EP  - 8
DO  - 10.2298/SOS2101001F
ER  - 

@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana and Mirković, Miljana and Pavlović, Vladimir and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction",
volume = "53",
pages = "1-8",
doi = "10.2298/SOS2101001F"
}

Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J., Mirković, M., Pavlović, V., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 53, 1-8.
https://doi.org/10.2298/SOS2101001F

Filipović S, Obradović N, Anđelković L, Olćan D, Petrović J, Mirković M, Pavlović V, Jeremić D, Vlahović B, Đorđević A. Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering. 2021;53:1-8.
doi:10.2298/SOS2101001F .

Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana, Mirković, Miljana, Pavlović, Vladimir, Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction" in Science of Sintering, 53 (2021):1-8,
https://doi.org/10.2298/SOS2101001F . .

TY  - CONF
AU  - Đorđević, Nataša G.
AU  - Peleš, Adriana
AU  - Obradović, Nina
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
AU  - Martinović, Sanja
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4917
AB  - The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.
AB  - Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS
C3  - Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
T1  - Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics
T1  - Uticaj vremena sinterovanja na gustinu i SEM analiza kordijeritne keramike
SP  - 265
EP  - 268
UR  - https://hdl.handle.net/21.15107/rcub_dais_12354
ER  - 

@conference{
author = "Đorđević, Nataša G. and Peleš, Adriana and Obradović, Nina and Vlahović, Milica and Mihajlović, Slavica and Martinović, Sanja",
year = "2021",
abstract = "The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties., Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS",
journal = "Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021",
title = "Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics, Uticaj vremena sinterovanja na gustinu i SEM analiza kordijeritne keramike",
pages = "265-268",
url = "https://hdl.handle.net/21.15107/rcub_dais_12354"
}

Đorđević, N. G., Peleš, A., Obradović, N., Vlahović, M., Mihajlović, S.,& Martinović, S.. (2021). Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS., 265-268.
https://hdl.handle.net/21.15107/rcub_dais_12354

Đorđević NG, Peleš A, Obradović N, Vlahović M, Mihajlović S, Martinović S. Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021. 2021;:265-268.
https://hdl.handle.net/21.15107/rcub_dais_12354 .

Đorđević, Nataša G., Peleš, Adriana, Obradović, Nina, Vlahović, Milica, Mihajlović, Slavica, Martinović, Sanja, "Influence of sintering time on density properties and SEM analysis of cordierite-based ceramics" in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021 (2021):265-268,
https://hdl.handle.net/21.15107/rcub_dais_12354 .

TY  - CONF
AU  - Đorđević, Nataša G.
AU  - Peleš, Adriana
AU  - Obradović, Nina
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
AU  - Martinović, Sanja
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4918
AB  - The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.
AB  - Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS
C3  - Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
T1  - Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time
T1  - Električna svojstva izotermski sinterovane keramike na bazi kordierita kao funkcija vremena sinterovanja i aktivacije
SP  - 269
EP  - 272
UR  - https://hdl.handle.net/21.15107/rcub_dais_12355
ER  - 

@conference{
author = "Đorđević, Nataša G. and Peleš, Adriana and Obradović, Nina and Vlahović, Milica and Mihajlović, Slavica and Martinović, Sanja",
year = "2021",
abstract = "The mechanical activation of the starting mixtures of cordierite (2MgO*2Al2O3*5SiO2) with 5.00 mass % TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties., Mehanička aktivacija početnih smeša kordierita (2MgO*2Al2O3*5SiO2) sa 5.00 mas. % TiO2 izvršena je u visokoenergetskom mlinu sa kuglama tokom 10-80 min. Primenjeni pritisak presovanja pre procesa sinterovanja bio je 2 t/cm2. Proces sinterovanja je izveden na 1350 °C tokom 2h i 4h u vazdušnoj atmosferi. Skenirajuća elektronska mikroskopija je izvršena u cilju analize mikrostrukture presovanih i sinterovanih uzoraka. Za ispitivanje površine sinterovanih uzoraka korišćen je mikroskop atomskih sila. Ovaj rad istražuje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka zajedno sa električnim svojstvima.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS",
journal = "Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021",
title = "Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time, Električna svojstva izotermski sinterovane keramike na bazi kordierita kao funkcija vremena sinterovanja i aktivacije",
pages = "269-272",
url = "https://hdl.handle.net/21.15107/rcub_dais_12355"
}

Đorđević, N. G., Peleš, A., Obradović, N., Vlahović, M., Mihajlović, S.,& Martinović, S.. (2021). Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS., 269-272.
https://hdl.handle.net/21.15107/rcub_dais_12355

Đorđević NG, Peleš A, Obradović N, Vlahović M, Mihajlović S, Martinović S. Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time. in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021. 2021;:269-272.
https://hdl.handle.net/21.15107/rcub_dais_12355 .

Đorđević, Nataša G., Peleš, Adriana, Obradović, Nina, Vlahović, Milica, Mihajlović, Slavica, Martinović, Sanja, "Electrical properties of isothermally sintered cordierite-based ceramics as function of sintering and activation time" in Zbornik radova / 9. Međunarodna konferencija o obnovljivim izvorima električne energije, Beograd, 15. oktobar 2021 = Proceedings / 9th International Conference on Renewable Electrical Power Sources, Belgrade, October 15, 2021 (2021):269-272,
https://hdl.handle.net/21.15107/rcub_dais_12355 .

TY  - JOUR
AU  - Rusmirović, Jelena
AU  - Obradović, Nina
AU  - Perendija, Jovana
AU  - Umićević, Ana
AU  - Kapidžić, Ana
AU  - Vlahović, Branislav
AU  - Pavlović, Vera
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://doi.org/10.1007/s11356-019-04625-0
UR  - http://dais.sanu.ac.rs/123456789/5273
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3334
AB  - Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal
VL  - 26
IS  - 12
SP  - 12379
EP  - 12398
DO  - 10.1007/s11356-019-04625-0
ER  - 

@article{
author = "Rusmirović, Jelena and Obradović, Nina and Perendija, Jovana and Umićević, Ana and Kapidžić, Ana and Vlahović, Branislav and Pavlović, Vera and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal",
volume = "26",
number = "12",
pages = "12379-12398",
doi = "10.1007/s11356-019-04625-0"
}

Rusmirović, J., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V., Marinković, A. D.,& Pavlović, V. B.. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research
Springer., 26(12), 12379-12398.
https://doi.org/10.1007/s11356-019-04625-0

Rusmirović J, Obradović N, Perendija J, Umićević A, Kapidžić A, Vlahović B, Pavlović V, Marinković AD, Pavlović VB. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research. 2019;26(12):12379-12398.
doi:10.1007/s11356-019-04625-0 .

Rusmirović, Jelena, Obradović, Nina, Perendija, Jovana, Umićević, Ana, Kapidžić, Ana, Vlahović, Branislav, Pavlović, Vera, Marinković, Aleksandar D., Pavlović, Vladimir B., "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal" in Environmental Science and Pollution Research, 26, no. 12 (2019):12379-12398,
https://doi.org/10.1007/s11356-019-04625-0 . .

TY  - JOUR
AU  - Rusmirović, Jelena
AU  - Obradović, Nina
AU  - Perendija, Jovana
AU  - Umićević, Ana
AU  - Kapidžić, Ana
AU  - Vlahović, Branislav
AU  - Pavlović, Vera P.
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2845
AB  - Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal
VL  - 26
IS  - 12
SP  - 12379
EP  - 12398
DO  - 10.1007/s11356-019-04625-0
ER  - 

@article{
author = "Rusmirović, Jelena and Obradović, Nina and Perendija, Jovana and Umićević, Ana and Kapidžić, Ana and Vlahović, Branislav and Pavlović, Vera P. and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2019",
abstract = "Iron oxide, in the form of magnetite (MG)–functionalized porous wollastonite (WL), was used as an adsorbent for heavy metal ions (cadmium and nickel) and oxyanions (chromate and phosphate) removal from water. The porous WL was synthesized from calcium carbonate and siloxane by controlled sintering process using low molecular weight submicrosized poly(methyl methacrylate) as a pore-forming agent. The precipitation of MG nanoparticles was carried out directly by a polyol-medium solvothermal method or via branched amino/carboxylic acid cross-linker by solvent/nonsolvent method producing WL/MG and WL-γ-APS/MG adsorbents, respectively. The structure/properties of MG functionalized WL was confirmed by applying FTIR, Raman, XRD, Mössbauer, and SEM analysis. Higher adsorption capacities of 73.126, 66.144, 64.168, and 63.456 mg g−1 for WL-γ-APS/MG in relation to WL/MG of 55.450, 52.019, 48.132, and 47.382 mg g−1 for Cd2+, Ni2+, phosphate, and chromate, respectively, were obtained using nonlinear Langmuir model fitting. Adsorption phenomena were analyzed using monolayer statistical physics model for single adsorption with one energy. Kinetic study showed exceptionally higher pseudo-second-order rate constants for WL-γ-APS/MG, e.g., 1.17–13.4 times, with respect to WL/MG indicating importance of both WL surface modification and controllable precipitation of MG on WL-γ-APS.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal",
volume = "26",
number = "12",
pages = "12379-12398",
doi = "10.1007/s11356-019-04625-0"
}

Rusmirović, J., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V. P., Marinković, A. D.,& Pavlović, V. B.. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research
Springer., 26(12), 12379-12398.
https://doi.org/10.1007/s11356-019-04625-0

Rusmirović J, Obradović N, Perendija J, Umićević A, Kapidžić A, Vlahović B, Pavlović VP, Marinković AD, Pavlović VB. Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. in Environmental Science and Pollution Research. 2019;26(12):12379-12398.
doi:10.1007/s11356-019-04625-0 .

Rusmirović, Jelena, Obradović, Nina, Perendija, Jovana, Umićević, Ana, Kapidžić, Ana, Vlahović, Branislav, Pavlović, Vera P., Marinković, Aleksandar D., Pavlović, Vladimir B., "Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal" in Environmental Science and Pollution Research, 26, no. 12 (2019):12379-12398,
https://doi.org/10.1007/s11356-019-04625-0 . .

TY  - JOUR
AU  - Brkovic, Danijela V.
AU  - Pavlović, Vladimir B.
AU  - Pavlović, Vera P.
AU  - Obradovic, Nina
AU  - Mitrić, Miodrag
AU  - Stevanović, Sanja
AU  - Vlahovic, Branislav
AU  - Uskoković, Petar S.
AU  - Marinković, Aleksandar D.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2152
AB  - The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60 degrees C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30 degrees C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37 degrees C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.
PB  - Wiley, Hoboken
T2  - Polymer Composites
T1  - Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization
VL  - 38
DO  - 10.1002/pc.23996
ER  - 

@article{
author = "Brkovic, Danijela V. and Pavlović, Vladimir B. and Pavlović, Vera P. and Obradovic, Nina and Mitrić, Miodrag and Stevanović, Sanja and Vlahovic, Branislav and Uskoković, Petar S. and Marinković, Aleksandar D.",
year = "2017",
abstract = "The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60 degrees C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30 degrees C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37 degrees C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.",
publisher = "Wiley, Hoboken",
journal = "Polymer Composites",
title = "Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization",
volume = "38",
doi = "10.1002/pc.23996"
}

Brkovic, D. V., Pavlović, V. B., Pavlović, V. P., Obradovic, N., Mitrić, M., Stevanović, S., Vlahovic, B., Uskoković, P. S.,& Marinković, A. D.. (2017). Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization. in Polymer Composites
Wiley, Hoboken., 38.
https://doi.org/10.1002/pc.23996

Brkovic DV, Pavlović VB, Pavlović VP, Obradovic N, Mitrić M, Stevanović S, Vlahovic B, Uskoković PS, Marinković AD. Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization. in Polymer Composites. 2017;38.
doi:10.1002/pc.23996 .

Brkovic, Danijela V., Pavlović, Vladimir B., Pavlović, Vera P., Obradovic, Nina, Mitrić, Miodrag, Stevanović, Sanja, Vlahovic, Branislav, Uskoković, Petar S., Marinković, Aleksandar D., "Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization" in Polymer Composites, 38 (2017),
https://doi.org/10.1002/pc.23996 . .

TY  - JOUR
AU  - Peleš, Adriana
AU  - Pavlović, Vera P.
AU  - Filipović, Suzana
AU  - Obradovic, Nina
AU  - Mančić, Lidija
AU  - Krstić, Jugoslav
AU  - Mitrić, Miodrag
AU  - Vlahović, Branislav
AU  - Rašić, Goran
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1715
AB  - Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural investigation of mechanically activated ZnO powder
VL  - 648
SP  - 971
EP  - 979
DO  - 10.1016/j.jallcom.2015.06.247
ER  - 

@article{
author = "Peleš, Adriana and Pavlović, Vera P. and Filipović, Suzana and Obradovic, Nina and Mančić, Lidija and Krstić, Jugoslav and Mitrić, Miodrag and Vlahović, Branislav and Rašić, Goran and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2015",
abstract = "Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural investigation of mechanically activated ZnO powder",
volume = "648",
pages = "971-979",
doi = "10.1016/j.jallcom.2015.06.247"
}

Peleš, A., Pavlović, V. P., Filipović, S., Obradovic, N., Mančić, L., Krstić, J., Mitrić, M., Vlahović, B., Rašić, G., Kosanović, D.,& Pavlović, V. B.. (2015). Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds
Elsevier., 648, 971-979.
https://doi.org/10.1016/j.jallcom.2015.06.247

Peleš A, Pavlović VP, Filipović S, Obradovic N, Mančić L, Krstić J, Mitrić M, Vlahović B, Rašić G, Kosanović D, Pavlović VB. Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds. 2015;648:971-979.
doi:10.1016/j.jallcom.2015.06.247 .

Peleš, Adriana, Pavlović, Vera P., Filipović, Suzana, Obradovic, Nina, Mančić, Lidija, Krstić, Jugoslav, Mitrić, Miodrag, Vlahović, Branislav, Rašić, Goran, Kosanović, Darko, Pavlović, Vladimir B., "Structural investigation of mechanically activated ZnO powder" in Journal of Alloys and Compounds, 648 (2015):971-979,
https://doi.org/10.1016/j.jallcom.2015.06.247 . .

TY  - CONF
AU  - Peleš, Adriana
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Krstić, Jugoslav
AU  - Pavlović, Vladimir B.
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/606
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2863
AB  - The authors investigated the morphological characteristics of mechanically activated ZnO powder. ZnO powder was mechanically activated for 2, 5, 10 and 30 minutes in a planetary ball mill. Mechanical activation introduces lattice disorder and defects into ZnO hexagonal wurtzite structure. In order to determine specific surface area and pore volume, we performed N2 porosimetry and SEM in order to investigate the microstructure of non-activated and mechanically activated ZnO powders. Using Kubelka-Munk function, UV-Vis spectra showed the reducing in band gap with activation time. ZnO powder activated for 5 minutes has the narrowest band gap.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts / III Serbian Ceramic Society Conference, 29th September - 1st October, Belgrade, 2014
T1  - The Morphological Characterization of Mechanically Activated ZnO Powder
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_dais_606
ER  - 

@conference{
author = "Peleš, Adriana and Filipović, Suzana and Obradović, Nina and Krstić, Jugoslav and Pavlović, Vladimir B.",
year = "2014",
abstract = "The authors investigated the morphological characteristics of mechanically activated ZnO powder. ZnO powder was mechanically activated for 2, 5, 10 and 30 minutes in a planetary ball mill. Mechanical activation introduces lattice disorder and defects into ZnO hexagonal wurtzite structure. In order to determine specific surface area and pore volume, we performed N2 porosimetry and SEM in order to investigate the microstructure of non-activated and mechanically activated ZnO powders. Using Kubelka-Munk function, UV-Vis spectra showed the reducing in band gap with activation time. ZnO powder activated for 5 minutes has the narrowest band gap.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts / III Serbian Ceramic Society Conference, 29th September - 1st October, Belgrade, 2014",
title = "The Morphological Characterization of Mechanically Activated ZnO Powder",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_dais_606"
}

Peleš, A., Filipović, S., Obradović, N., Krstić, J.,& Pavlović, V. B.. (2014). The Morphological Characterization of Mechanically Activated ZnO Powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts / III Serbian Ceramic Society Conference, 29th September - 1st October, Belgrade, 2014
Belgrade : Serbian Ceramic Society., 92-92.
https://hdl.handle.net/21.15107/rcub_dais_606

Peleš A, Filipović S, Obradović N, Krstić J, Pavlović VB. The Morphological Characterization of Mechanically Activated ZnO Powder. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts / III Serbian Ceramic Society Conference, 29th September - 1st October, Belgrade, 2014. 2014;:92-92.
https://hdl.handle.net/21.15107/rcub_dais_606 .

Peleš, Adriana, Filipović, Suzana, Obradović, Nina, Krstić, Jugoslav, Pavlović, Vladimir B., "The Morphological Characterization of Mechanically Activated ZnO Powder" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts / III Serbian Ceramic Society Conference, 29th September - 1st October, Belgrade, 2014 (2014):92-92,
https://hdl.handle.net/21.15107/rcub_dais_606 .

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradovic, Nina
AU  - Krstić, Jugoslav
AU  - Scepanovic, M.
AU  - Pavlović, Vladimir B.
AU  - Paunović, Vesna
AU  - Ristic, M. M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1274
AB  - In this article the influence of ball miling process on structure of MgO-TiO2 system, as well as the electrical properties of samples after sintering, was investigated. The mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for the time period from 0 to 120 min. The influence of mechanical activation and sintering on the lattice vibrational spectra was studied by Raman spectroscopy at room temperature. Structural investigations have been performed on produced powders. Nitrogen adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results have been obtained: specific surface area continuosly decreased up to 40 min of activation and increased after that, reaching its minimun value of 5.5 m(2)/g. The Raman spectra of activated powders have shown that anatase modes have been decreasing in intensity and broadening as the time of activation extended. Also, the additional modes attributed to TiO2 II, srilankite and rutile phases started to appear as a consequence of activation. The small differences noticed in the Raman spectra of sintered samples have been explained by structural modification of MgTiO3 phase due to the presence of defects. The effects of activation and sintering process on microstructure were investigated by scanning electron microscopy (SEM). The electrical measurements showed difference in dielectric constant (epsilon(r)), loss tangent (tg delta) and specific resistance (rho) as a function of time of mechanical treatment.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural characterization and electrical properties of sintered magnesium-titanate ceramics
VL  - 555
SP  - 39
EP  - 44
DO  - 10.1016/j.jallcom.2012.12.040
ER  - 

@article{
author = "Filipović, Suzana and Obradovic, Nina and Krstić, Jugoslav and Scepanovic, M. and Pavlović, Vladimir B. and Paunović, Vesna and Ristic, M. M.",
year = "2013",
abstract = "In this article the influence of ball miling process on structure of MgO-TiO2 system, as well as the electrical properties of samples after sintering, was investigated. The mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for the time period from 0 to 120 min. The influence of mechanical activation and sintering on the lattice vibrational spectra was studied by Raman spectroscopy at room temperature. Structural investigations have been performed on produced powders. Nitrogen adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results have been obtained: specific surface area continuosly decreased up to 40 min of activation and increased after that, reaching its minimun value of 5.5 m(2)/g. The Raman spectra of activated powders have shown that anatase modes have been decreasing in intensity and broadening as the time of activation extended. Also, the additional modes attributed to TiO2 II, srilankite and rutile phases started to appear as a consequence of activation. The small differences noticed in the Raman spectra of sintered samples have been explained by structural modification of MgTiO3 phase due to the presence of defects. The effects of activation and sintering process on microstructure were investigated by scanning electron microscopy (SEM). The electrical measurements showed difference in dielectric constant (epsilon(r)), loss tangent (tg delta) and specific resistance (rho) as a function of time of mechanical treatment.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural characterization and electrical properties of sintered magnesium-titanate ceramics",
volume = "555",
pages = "39-44",
doi = "10.1016/j.jallcom.2012.12.040"
}

Filipović, S., Obradovic, N., Krstić, J., Scepanovic, M., Pavlović, V. B., Paunović, V.,& Ristic, M. M.. (2013). Structural characterization and electrical properties of sintered magnesium-titanate ceramics. in Journal of Alloys and Compounds
Elsevier., 555, 39-44.
https://doi.org/10.1016/j.jallcom.2012.12.040

Filipović S, Obradovic N, Krstić J, Scepanovic M, Pavlović VB, Paunović V, Ristic MM. Structural characterization and electrical properties of sintered magnesium-titanate ceramics. in Journal of Alloys and Compounds. 2013;555:39-44.
doi:10.1016/j.jallcom.2012.12.040 .

Filipović, Suzana, Obradovic, Nina, Krstić, Jugoslav, Scepanovic, M., Pavlović, Vladimir B., Paunović, Vesna, Ristic, M. M., "Structural characterization and electrical properties of sintered magnesium-titanate ceramics" in Journal of Alloys and Compounds, 555 (2013):39-44,
https://doi.org/10.1016/j.jallcom.2012.12.040 . .

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Krstić, Jugoslav
AU  - Šćepanović, M.
AU  - Pavlović, Vladimir B.
AU  - Paunović, Vesna
AU  - Ristić, Momčilo M.
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/442
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2861
AB  - In this article the influence of ball milling process on structure of MgO-TiO2 system, along with its influence on electrical properties of post-sintering samples, were investigated. Mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for time interval from 0 to 120 minutes. On thus obtained powders, structural investigations have been performed. N2 adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results were obtained: specific surface area continuously decreases up to 40 minutes of activation and after that increases, reaching its minimum value of 5.5 m2/g. The influence of mechanical activation on lattice vibration spectra was examined by Raman spectroscopy at room temperature. For sintered samples characterization, Raman scattering spectroscopy has been used. Very similar spectra for all samples were observed. Raman spectroscopy of sintered samples indicates a presence of two phases, while varieties in spectra were explained with different ratio of present phases. Effect of activation and sintering process on microstructure was investigated by scanning electron microscopy (SEM). Electrical measurements showed difference in dielectric constant (εr), loss tangent (tgδ) and specific resistance (ρ) as a function of time of mechanical treatment.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
T1  - Structural characterization and electrical properties of sintered magnesium-titanate ceramics
SP  - 80
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_dais_442
ER  - 

@conference{
author = "Filipović, Suzana and Obradović, Nina and Krstić, Jugoslav and Šćepanović, M. and Pavlović, Vladimir B. and Paunović, Vesna and Ristić, Momčilo M.",
year = "2012",
abstract = "In this article the influence of ball milling process on structure of MgO-TiO2 system, along with its influence on electrical properties of post-sintering samples, were investigated. Mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for time interval from 0 to 120 minutes. On thus obtained powders, structural investigations have been performed. N2 adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results were obtained: specific surface area continuously decreases up to 40 minutes of activation and after that increases, reaching its minimum value of 5.5 m2/g. The influence of mechanical activation on lattice vibration spectra was examined by Raman spectroscopy at room temperature. For sintered samples characterization, Raman scattering spectroscopy has been used. Very similar spectra for all samples were observed. Raman spectroscopy of sintered samples indicates a presence of two phases, while varieties in spectra were explained with different ratio of present phases. Effect of activation and sintering process on microstructure was investigated by scanning electron microscopy (SEM). Electrical measurements showed difference in dielectric constant (εr), loss tangent (tgδ) and specific resistance (ρ) as a function of time of mechanical treatment.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts",
title = "Structural characterization and electrical properties of sintered magnesium-titanate ceramics",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_dais_442"
}

Filipović, S., Obradović, N., Krstić, J., Šćepanović, M., Pavlović, V. B., Paunović, V.,& Ristić, M. M.. (2012). Structural characterization and electrical properties of sintered magnesium-titanate ceramics. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 80-80.
https://hdl.handle.net/21.15107/rcub_dais_442

Filipović S, Obradović N, Krstić J, Šćepanović M, Pavlović VB, Paunović V, Ristić MM. Structural characterization and electrical properties of sintered magnesium-titanate ceramics. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts. 2012;:80-80.
https://hdl.handle.net/21.15107/rcub_dais_442 .

Filipović, Suzana, Obradović, Nina, Krstić, Jugoslav, Šćepanović, M., Pavlović, Vladimir B., Paunović, Vesna, Ristić, Momčilo M., "Structural characterization and electrical properties of sintered magnesium-titanate ceramics" in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts (2012):80-80,
https://hdl.handle.net/21.15107/rcub_dais_442 .

TY  - CONF
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Krstić, Jugoslav
AU  - Kosanović, Darko
AU  - Šćepanović, M.
AU  - Pavlović, Vladimir B.
AU  - Maričić, Aleksa
AU  - Ristić, Momčilo M.
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/629
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2611
AB  - Mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for time interval from 0 to 120 minutes. On thus obtained powders, structural investigations have been performed. N2 adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results are obtained: specific surface area continuously decreases up to 40 minutes of activation and after that increases, reaching its minimum value of 4.4 m2/g. The influence of mechanical activation on lattice vibrational spectra was examined by Raman spectroscopy at room temperatures. The differential thermal analysis has been performed in order to investigate thermal behavior of the mixtures, indicating at several endothermal peaks in range of RT to 1100oC. SEM gave information about changes in microstructures, showing the clear decrease in particle size.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts
T1  - Structural characterization of mechanically activated MgO-TiO2 system
SP  - 101
EP  - 101
UR  - https://hdl.handle.net/21.15107/rcub_dais_629
ER  - 

@conference{
author = "Filipović, Suzana and Obradović, Nina and Krstić, Jugoslav and Kosanović, Darko and Šćepanović, M. and Pavlović, Vladimir B. and Maričić, Aleksa and Ristić, Momčilo M.",
year = "2011",
abstract = "Mixtures of MgO-TiO2 powders were mechanically activated in a planetary ball mill for time interval from 0 to 120 minutes. On thus obtained powders, structural investigations have been performed. N2 adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results are obtained: specific surface area continuously decreases up to 40 minutes of activation and after that increases, reaching its minimum value of 4.4 m2/g. The influence of mechanical activation on lattice vibrational spectra was examined by Raman spectroscopy at room temperatures. The differential thermal analysis has been performed in order to investigate thermal behavior of the mixtures, indicating at several endothermal peaks in range of RT to 1100oC. SEM gave information about changes in microstructures, showing the clear decrease in particle size.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts",
title = "Structural characterization of mechanically activated MgO-TiO2 system",
pages = "101-101",
url = "https://hdl.handle.net/21.15107/rcub_dais_629"
}

Filipović, S., Obradović, N., Krstić, J., Kosanović, D., Šćepanović, M., Pavlović, V. B., Maričić, A.,& Ristić, M. M.. (2011). Structural characterization of mechanically activated MgO-TiO2 system. in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 101-101.
https://hdl.handle.net/21.15107/rcub_dais_629

Filipović S, Obradović N, Krstić J, Kosanović D, Šćepanović M, Pavlović VB, Maričić A, Ristić MM. Structural characterization of mechanically activated MgO-TiO2 system. in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts. 2011;:101-101.
https://hdl.handle.net/21.15107/rcub_dais_629 .

Filipović, Suzana, Obradović, Nina, Krstić, Jugoslav, Kosanović, Darko, Šćepanović, M., Pavlović, Vladimir B., Maričić, Aleksa, Ristić, Momčilo M., "Structural characterization of mechanically activated MgO-TiO2 system" in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts (2011):101-101,
https://hdl.handle.net/21.15107/rcub_dais_629 .