Horkans, Jean

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Author's Bibliography

Vapor-Deposited Gold Electrodes: Effects of Undercoatings

Adžić, Radoslav; Horkans, Jean; Cahan, B.D.; Yeager, Ernest

(IOP Publishing, 1973) 

TY  - JOUR
AU  - Adžić, Radoslav
AU  - Horkans, Jean
AU  - Cahan, B.D.
AU  - Yeager, Ernest
PY  - 1973
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4703
AB  - Vapor-deposited metal-film electrodes on smooth glass substrates are attractive for optical reflectance studies of electrochemical systems because of the high optical quality of the surface and a ratio of true to apparent area relatively close to unity. With gold, the double layer capacity of the vapor-deposited films has been found by the authors to be approximately one-half that observed on mechanically polished electrodes of the bulk metal at the same potentials. Metals such as gold, however, do not adhere well when deposited directly on a glass substrate, and some kind of undercoating generally has been used by various authors in order to obtain adherence, e.g., Paik et aI. used glass Ta-Pt-Au. A number of substances yield adherent vapor-deposited gold films. The purpose of this note is to call attention to the fact that these undercoats can seriously interfere with optical and electrochemical measurements.
PB  - IOP Publishing
T2  - Journal of the Electrochemical Society
T1  - Vapor-Deposited Gold Electrodes: Effects of Undercoatings
VL  - 120
IS  - 9
SP  - 1219
EP  - 1220
DO  - 10.1149/1.2403665
ER  - 
@article{
author = "Adžić, Radoslav and Horkans, Jean and Cahan, B.D. and Yeager, Ernest",
year = "1973",
abstract = "Vapor-deposited metal-film electrodes on smooth glass substrates are attractive for optical reflectance studies of electrochemical systems because of the high optical quality of the surface and a ratio of true to apparent area relatively close to unity. With gold, the double layer capacity of the vapor-deposited films has been found by the authors to be approximately one-half that observed on mechanically polished electrodes of the bulk metal at the same potentials. Metals such as gold, however, do not adhere well when deposited directly on a glass substrate, and some kind of undercoating generally has been used by various authors in order to obtain adherence, e.g., Paik et aI. used glass Ta-Pt-Au. A number of substances yield adherent vapor-deposited gold films. The purpose of this note is to call attention to the fact that these undercoats can seriously interfere with optical and electrochemical measurements.",
publisher = "IOP Publishing",
journal = "Journal of the Electrochemical Society",
title = "Vapor-Deposited Gold Electrodes: Effects of Undercoatings",
volume = "120",
number = "9",
pages = "1219-1220",
doi = "10.1149/1.2403665"
}
Adžić, R., Horkans, J., Cahan, B.D.,& Yeager, E.. (1973). Vapor-Deposited Gold Electrodes: Effects of Undercoatings. in Journal of the Electrochemical Society
IOP Publishing., 120(9), 1219-1220.
https://doi.org/10.1149/1.2403665
Adžić R, Horkans J, Cahan B, Yeager E. Vapor-Deposited Gold Electrodes: Effects of Undercoatings. in Journal of the Electrochemical Society. 1973;120(9):1219-1220.
doi:10.1149/1.2403665 .
Adžić, Radoslav, Horkans, Jean, Cahan, B.D., Yeager, Ernest, "Vapor-Deposited Gold Electrodes: Effects of Undercoatings" in Journal of the Electrochemical Society, 120, no. 9 (1973):1219-1220,
https://doi.org/10.1149/1.2403665 . .
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