TY  - JOUR
AU  - Spasojević, Miroslav D.
AU  - Krstajić, Nedeljko V.
AU  - Despotov, P.
AU  - Atanasoski, Radoslav T.
AU  - Popov, Konstantin I.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4452
AB  - It is shown that good quality deposits of cobalt-molybdenum alloys may be produced using pulse plating and it is demonstrated that such coatings on titanium have a low overpotential for hydrogen evolution under typical brine electrolysis conditions.
PB  - Switzerland : Springer Nature
T2  - Journal of Applied Electrochemistry
T1  - The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics
VL  - 14
IS  - 2
SP  - 265
EP  - 266
DO  - 10.1007/BF00618745
ER  - 

@article{
author = "Spasojević, Miroslav D. and Krstajić, Nedeljko V. and Despotov, P. and Atanasoski, Radoslav T. and Popov, Konstantin I.",
year = "1984",
abstract = "It is shown that good quality deposits of cobalt-molybdenum alloys may be produced using pulse plating and it is demonstrated that such coatings on titanium have a low overpotential for hydrogen evolution under typical brine electrolysis conditions.",
publisher = "Switzerland : Springer Nature",
journal = "Journal of Applied Electrochemistry",
title = "The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics",
volume = "14",
number = "2",
pages = "265-266",
doi = "10.1007/BF00618745"
}

Spasojević, M. D., Krstajić, N. V., Despotov, P., Atanasoski, R. T.,& Popov, K. I.. (1984). The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics. in Journal of Applied Electrochemistry
Switzerland : Springer Nature., 14(2), 265-266.
https://doi.org/10.1007/BF00618745

Spasojević MD, Krstajić NV, Despotov P, Atanasoski RT, Popov KI. The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics. in Journal of Applied Electrochemistry. 1984;14(2):265-266.
doi:10.1007/BF00618745 .

Spasojević, Miroslav D., Krstajić, Nedeljko V., Despotov, P., Atanasoski, Radoslav T., Popov, Konstantin I., "The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics" in Journal of Applied Electrochemistry, 14, no. 2 (1984):265-266,
https://doi.org/10.1007/BF00618745 . .

TY  - JOUR
AU  - Krstajić, Nedeljko V.
AU  - Spasojević, Miroslav D.
AU  - Atanasoski, Radoslav T.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4451
AB  - There is practical interest in the use of titanium as a cathode material in brine electrolysis processes. The overvoltage of hydrogen evolution on titanium is, however, very high and, at the same time, hydrogen penetrates the bulk of the metal. Here, a new type of catalytically active coating has been applied on the surface of titanium in order to overcome these problems. The coating consists of a mixture of the thermal decomposition products of lanthanum chloride and sodium molybdate. The coating has been tested for 18 months of continuous operation. No change in the overvoltage gain (of 0.4 V at 3 kA m-2, as compared with pure titanium) nor change in the properties of the bulk metal have been noticed during this period.
PB  - Switzerland : Springer Nature
T2  - Journal of Applied Electrochemistry
T1  - Lanthanum-molybdenum coating for hydrogen evolution on titanium
VL  - 19
VL  - 14
IS  - 11
IS  - 1
DO  - 10.1007/BF00611270
ER  - 

@article{
author = "Krstajić, Nedeljko V. and Spasojević, Miroslav D. and Atanasoski, Radoslav T.",
year = "1984",
abstract = "There is practical interest in the use of titanium as a cathode material in brine electrolysis processes. The overvoltage of hydrogen evolution on titanium is, however, very high and, at the same time, hydrogen penetrates the bulk of the metal. Here, a new type of catalytically active coating has been applied on the surface of titanium in order to overcome these problems. The coating consists of a mixture of the thermal decomposition products of lanthanum chloride and sodium molybdate. The coating has been tested for 18 months of continuous operation. No change in the overvoltage gain (of 0.4 V at 3 kA m-2, as compared with pure titanium) nor change in the properties of the bulk metal have been noticed during this period.",
publisher = "Switzerland : Springer Nature",
journal = "Journal of Applied Electrochemistry",
title = "Lanthanum-molybdenum coating for hydrogen evolution on titanium",
volume = "19, 14",
number = "11, 1",
doi = "10.1007/BF00611270"
}

Krstajić, N. V., Spasojević, M. D.,& Atanasoski, R. T.. (1984). Lanthanum-molybdenum coating for hydrogen evolution on titanium. in Journal of Applied Electrochemistry
Switzerland : Springer Nature., 19(11).
https://doi.org/10.1007/BF00611270

Krstajić NV, Spasojević MD, Atanasoski RT. Lanthanum-molybdenum coating for hydrogen evolution on titanium. in Journal of Applied Electrochemistry. 1984;19(11).
doi:10.1007/BF00611270 .

Krstajić, Nedeljko V., Spasojević, Miroslav D., Atanasoski, Radoslav T., "Lanthanum-molybdenum coating for hydrogen evolution on titanium" in Journal of Applied Electrochemistry, 19, no. 11 (1984),
https://doi.org/10.1007/BF00611270 . .

TY  - JOUR
AU  - Spasojević, Miroslav D.
AU  - Krstajić, Nedeljko V.
AU  - Jakšić, Milan M.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4434
AB  - It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well as the former catalyst exhibits almost equal electrocatalytic activity and a high corrosion stability in both dichromate and phosphate buffering systems. Electrocatalytic optimization of faradaic yields over a much wider pH range for the chlorate cell process has been achieved by the mixed ruthenium, palladium, tin and titanium oxide catalysts and in the presence of a phosphate buffer. The effect is tentatively ascribed to the phosphate adsorption associated with further activation polarization (inhibition effect) of the available chlorine oxidation reaction at the anode. Two benefits result therefrom: (a) the pH value can be kept at around pH 7, providing better elemental chlorine absorption, and (b) dichromate buffer can be at least partially replaced by the more convinient phosphate buffering system.
PB  - Elsevier
T2  - Surface Technology
T1  - Electrocatalytic optimization of faradaic yields in the chlorate cell process
VL  - 21
IS  - 1
SP  - 19
EP  - 26
DO  - 10.1016/0376-4583(84)90144-4
ER  - 

@article{
author = "Spasojević, Miroslav D. and Krstajić, Nedeljko V. and Jakšić, Milan M.",
year = "1984",
abstract = "It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well as the former catalyst exhibits almost equal electrocatalytic activity and a high corrosion stability in both dichromate and phosphate buffering systems. Electrocatalytic optimization of faradaic yields over a much wider pH range for the chlorate cell process has been achieved by the mixed ruthenium, palladium, tin and titanium oxide catalysts and in the presence of a phosphate buffer. The effect is tentatively ascribed to the phosphate adsorption associated with further activation polarization (inhibition effect) of the available chlorine oxidation reaction at the anode. Two benefits result therefrom: (a) the pH value can be kept at around pH 7, providing better elemental chlorine absorption, and (b) dichromate buffer can be at least partially replaced by the more convinient phosphate buffering system.",
publisher = "Elsevier",
journal = "Surface Technology",
title = "Electrocatalytic optimization of faradaic yields in the chlorate cell process",
volume = "21",
number = "1",
pages = "19-26",
doi = "10.1016/0376-4583(84)90144-4"
}

Spasojević, M. D., Krstajić, N. V.,& Jakšić, M. M.. (1984). Electrocatalytic optimization of faradaic yields in the chlorate cell process. in Surface Technology
Elsevier., 21(1), 19-26.
https://doi.org/10.1016/0376-4583(84)90144-4

Spasojević MD, Krstajić NV, Jakšić MM. Electrocatalytic optimization of faradaic yields in the chlorate cell process. in Surface Technology. 1984;21(1):19-26.
doi:10.1016/0376-4583(84)90144-4 .

Spasojević, Miroslav D., Krstajić, Nedeljko V., Jakšić, Milan M., "Electrocatalytic optimization of faradaic yields in the chlorate cell process" in Surface Technology, 21, no. 1 (1984):19-26,
https://doi.org/10.1016/0376-4583(84)90144-4 . .