Manojlović, Dragan

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Authority KeyName Variants
orcid::0000-0003-1388-6245
  • Manojlović, Dragan (111)
  • Manojlović, Dragan D. (1)
Projects
Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Simultaneous Bioremediation and Soilification of Degraded Areas to Preserve Natural Resources of Biologically Active Substances, and Development and Production of Biomaterials and Dietetic Products
Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes Ministry of Science of the Republic of Serbia
Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences
Structure-properties relationships of natural and synthetic molecules and their metal complexes Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology
Molecular determinants of innate immunity in autoimmunity and tumorogenesis Spektroskopska dijagnostika plazme u izvorima značajnim za primene
Sinteza, karakterizacija i testiranje katalitičkih svojstava specijalno dizajniranih materijala Mezoporozni i nanomaterijali u katalitičkim i sorpcionim procesima
Improvement of production capacities of the carp (Cyprinus carpio L) using feeding and selective breeding programs Brazilian agency CNPq
Brazilian agency FACEPE Brazilian agency FAPESP
Physics of nanostructured oxide materials and strongly correlated systems Diagnostics and Optimization of Plasma Sources Important for Applications
Developing infrastructure for priority research fields Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200007 (University of Belgrade, Institute for Biological Research 'Siniša Stanković')
Nanostructured multifunctional materials and nanocomposites Multiscale structuring of polymer nanocomposites and functional materials based on different precursors
Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine Bilateral Franco-Serbian PHC-Pavle Savic
CEEPUS network CIII-CZ-0212-13-1920-M-131892 COST Action [Grantnumber: 18234]
Czech Science Foundation (18-03932S) Czech Science Foundation (No: 18-03932S).

Author's Bibliography

Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure

Mutić, Tijana; Stanković, Dalibor; Manojlović, Dragan; Petrić, Djordje; Pastor, Ferenc; Avdin, Vyacheslav V.; Ognjanović, Miloš; Stanković, Vesna

(MDPI AG, 2024)

TY  - JOUR
AU  - Mutić, Tijana
AU  - Stanković, Dalibor
AU  - Manojlović, Dragan
AU  - Petrić, Djordje
AU  - Pastor, Ferenc
AU  - Avdin, Vyacheslav V.
AU  - Ognjanović, Miloš
AU  - Stanković, Vesna
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7422
AB  - In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.
PB  - MDPI AG
T2  - Electrochem
T1  - Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure
VL  - 5
IS  - 1
SP  - 45
EP  - 56
DO  - 10.3390/electrochem5010003
ER  - 
@article{
author = "Mutić, Tijana and Stanković, Dalibor and Manojlović, Dragan and Petrić, Djordje and Pastor, Ferenc and Avdin, Vyacheslav V. and Ognjanović, Miloš and Stanković, Vesna",
year = "2024",
abstract = "In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.",
publisher = "MDPI AG",
journal = "Electrochem",
title = "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure",
volume = "5",
number = "1",
pages = "45-56",
doi = "10.3390/electrochem5010003"
}
Mutić, T., Stanković, D., Manojlović, D., Petrić, D., Pastor, F., Avdin, V. V., Ognjanović, M.,& Stanković, V.. (2024). Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem
MDPI AG., 5(1), 45-56.
https://doi.org/10.3390/electrochem5010003
Mutić T, Stanković D, Manojlović D, Petrić D, Pastor F, Avdin VV, Ognjanović M, Stanković V. Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem. 2024;5(1):45-56.
doi:10.3390/electrochem5010003 .
Mutić, Tijana, Stanković, Dalibor, Manojlović, Dragan, Petrić, Djordje, Pastor, Ferenc, Avdin, Vyacheslav V., Ognjanović, Miloš, Stanković, Vesna, "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure" in Electrochem, 5, no. 1 (2024):45-56,
https://doi.org/10.3390/electrochem5010003 . .
1

Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants

Sentić, Milica; Trajković, Ivana; Manojlović, Dragan; Stanković, Dalibor; Nikolić, Maria Vesna; Šojić, Nešo; Vidić, Jasmina

(MDPI, 2023)

TY  - JOUR
AU  - Sentić, Milica
AU  - Trajković, Ivana
AU  - Manojlović, Dragan
AU  - Stanković, Dalibor
AU  - Nikolić, Maria Vesna
AU  - Šojić, Nešo
AU  - Vidić, Jasmina
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7109
AB  - Modern lifestyle has increased our utilization of pollutants such as heavy metals, aromatic 17 compounds, and contaminants of rising concern involving pharmaceutical and personal products 18 and other materials that may have an important environmental impact. Especially, the ultimate re-19 sults of intense use of highly stable materials, such as heavy metals and chemical restudies are that 20 they turn into waste materials which, when discharged, accumulate in the environment water bod-21 ies. In this context, the present review presents application of metal-organic frameworks (MOFs) in 22 electrochemiluminescent (ECL) sensing for water pollutant detection. MOF composites applied as 23 innovative luminophore or luminophore carriers, materials for electrode modification and enhance-24 ment of co-reaction in ECL sensors have enabled sensitive monitoring of some most common con-25 taminants of emerging concern such as heavy metals, volatile organic compounds, pharmaceuticals, 26 industrial chemicals and cyanotoxins. Moreover, we provide future trends and prospects associated 27 with ECL MOF-composites for environmental sensing.
PB  - MDPI
T2  - Materials
T1  - Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants
VL  - 16
IS  - 23
SP  - 7502
DO  - 10.3390/ma16237502
ER  - 
@article{
author = "Sentić, Milica and Trajković, Ivana and Manojlović, Dragan and Stanković, Dalibor and Nikolić, Maria Vesna and Šojić, Nešo and Vidić, Jasmina",
year = "2023",
abstract = "Modern lifestyle has increased our utilization of pollutants such as heavy metals, aromatic 17 compounds, and contaminants of rising concern involving pharmaceutical and personal products 18 and other materials that may have an important environmental impact. Especially, the ultimate re-19 sults of intense use of highly stable materials, such as heavy metals and chemical restudies are that 20 they turn into waste materials which, when discharged, accumulate in the environment water bod-21 ies. In this context, the present review presents application of metal-organic frameworks (MOFs) in 22 electrochemiluminescent (ECL) sensing for water pollutant detection. MOF composites applied as 23 innovative luminophore or luminophore carriers, materials for electrode modification and enhance-24 ment of co-reaction in ECL sensors have enabled sensitive monitoring of some most common con-25 taminants of emerging concern such as heavy metals, volatile organic compounds, pharmaceuticals, 26 industrial chemicals and cyanotoxins. Moreover, we provide future trends and prospects associated 27 with ECL MOF-composites for environmental sensing.",
publisher = "MDPI",
journal = "Materials",
title = "Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants",
volume = "16",
number = "23",
pages = "7502",
doi = "10.3390/ma16237502"
}
Sentić, M., Trajković, I., Manojlović, D., Stanković, D., Nikolić, M. V., Šojić, N.,& Vidić, J.. (2023). Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants. in Materials
MDPI., 16(23), 7502.
https://doi.org/10.3390/ma16237502
Sentić M, Trajković I, Manojlović D, Stanković D, Nikolić MV, Šojić N, Vidić J. Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants. in Materials. 2023;16(23):7502.
doi:10.3390/ma16237502 .
Sentić, Milica, Trajković, Ivana, Manojlović, Dragan, Stanković, Dalibor, Nikolić, Maria Vesna, Šojić, Nešo, Vidić, Jasmina, "Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants" in Materials, 16, no. 23 (2023):7502,
https://doi.org/10.3390/ma16237502 . .

A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples

Mijajlović, Aleksandar; Stanković, Vesna; Đurđić, Slađana; Manojlović, Dragan; Stanković, Dalibor

(University of Belgrade : Faculty of Chemistry, 2023)

TY  - CONF
AU  - Mijajlović, Aleksandar
AU  - Stanković, Vesna
AU  - Đurđić, Slađana
AU  - Manojlović, Dragan
AU  - Stanković, Dalibor
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7357
AB  - Pesticides have a significant role in the world food chain in the setting of rising agricultural output demand and rising climate change impacts on agricultural productivity. Pesticide contamination across the world is not just a pressing issue; it also has the potential to get worse, for instance, because of movements in global production to nations with laxer environmental regulations [1]. In this work, we have designed a new electrochemical sensor for detecting bentazone (BZT) by using NP-Y2O3/g-C3N4 modified carbon paste electrode (CP). For the first time, the Pechini method was employed to synthesize the Y2O3 nanocomposite. The nanomaterial was characterized by Xray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). In order to create an analytical technique for identifying and measuring BZT, the electrocatalytic characteristics of the suggested Y2O3/g-C3N4 modified CP electrode were examined. Using the CV and DPV approaches, the electrochemical behavior of BZT at the Y2O3/gC3N4 sensor was investigated. The proposed electrochemical sensor exhibited excellent electrochemical response toward BZT with a wide linear range of 1 to 100 µM, with a detection limit of 0.68 µM. The effect of possible interfering agents is negligible, confirming the good selectivity of the method. The sensor also displayed excellent sensitivity, reproducibility, and stability. Additionally, the Y2O3/g-C3N4 sensor was utilized for the detection of BZT in water and soil samples, and also in red and green pepper samples, and it exhibited good recovery results.
PB  - University of Belgrade : Faculty of Chemistry
C3  - 28th Young Investigators' Seminar  on Analytical Chemistry YISAC 2023, Book of Abstracts, June 25th - 28th, 2023, Belgrade, Serbia
T1  - A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples
SP  - 26
EP  - 26
UR  - https://hdl.handle.net/21.15107/rcub_cer_7357
ER  - 
@conference{
author = "Mijajlović, Aleksandar and Stanković, Vesna and Đurđić, Slađana and Manojlović, Dragan and Stanković, Dalibor",
year = "2023",
abstract = "Pesticides have a significant role in the world food chain in the setting of rising agricultural output demand and rising climate change impacts on agricultural productivity. Pesticide contamination across the world is not just a pressing issue; it also has the potential to get worse, for instance, because of movements in global production to nations with laxer environmental regulations [1]. In this work, we have designed a new electrochemical sensor for detecting bentazone (BZT) by using NP-Y2O3/g-C3N4 modified carbon paste electrode (CP). For the first time, the Pechini method was employed to synthesize the Y2O3 nanocomposite. The nanomaterial was characterized by Xray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). In order to create an analytical technique for identifying and measuring BZT, the electrocatalytic characteristics of the suggested Y2O3/g-C3N4 modified CP electrode were examined. Using the CV and DPV approaches, the electrochemical behavior of BZT at the Y2O3/gC3N4 sensor was investigated. The proposed electrochemical sensor exhibited excellent electrochemical response toward BZT with a wide linear range of 1 to 100 µM, with a detection limit of 0.68 µM. The effect of possible interfering agents is negligible, confirming the good selectivity of the method. The sensor also displayed excellent sensitivity, reproducibility, and stability. Additionally, the Y2O3/g-C3N4 sensor was utilized for the detection of BZT in water and soil samples, and also in red and green pepper samples, and it exhibited good recovery results.",
publisher = "University of Belgrade : Faculty of Chemistry",
journal = "28th Young Investigators' Seminar  on Analytical Chemistry YISAC 2023, Book of Abstracts, June 25th - 28th, 2023, Belgrade, Serbia",
title = "A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples",
pages = "26-26",
url = "https://hdl.handle.net/21.15107/rcub_cer_7357"
}
Mijajlović, A., Stanković, V., Đurđić, S., Manojlović, D.,& Stanković, D.. (2023). A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples. in 28th Young Investigators' Seminar  on Analytical Chemistry YISAC 2023, Book of Abstracts, June 25th - 28th, 2023, Belgrade, Serbia
University of Belgrade : Faculty of Chemistry., 26-26.
https://hdl.handle.net/21.15107/rcub_cer_7357
Mijajlović A, Stanković V, Đurđić S, Manojlović D, Stanković D. A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples. in 28th Young Investigators' Seminar  on Analytical Chemistry YISAC 2023, Book of Abstracts, June 25th - 28th, 2023, Belgrade, Serbia. 2023;:26-26.
https://hdl.handle.net/21.15107/rcub_cer_7357 .
Mijajlović, Aleksandar, Stanković, Vesna, Đurđić, Slađana, Manojlović, Dragan, Stanković, Dalibor, "A novel carbon paste electrode modified by NP-Y2O3 doped with the g-C3N4 for sensitive electrochemical detection of herbicide bentazone in river, soil, and vegetable samples" in 28th Young Investigators' Seminar  on Analytical Chemistry YISAC 2023, Book of Abstracts, June 25th - 28th, 2023, Belgrade, Serbia (2023):26-26,
https://hdl.handle.net/21.15107/rcub_cer_7357 .

The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan

Knežević, Sara; Ostojić, Jelena; Ognjanović, Miloš; Savić, Slađana; Kovačević, Aleksandra; Manojlović, Dragan; Stanković, Vesna; Stanković, Dalibor

(Elsevier, 2023)

TY  - JOUR
AU  - Knežević, Sara
AU  - Ostojić, Jelena
AU  - Ognjanović, Miloš
AU  - Savić, Slađana
AU  - Kovačević, Aleksandra
AU  - Manojlović, Dragan
AU  - Stanković, Vesna
AU  - Stanković, Dalibor
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5389
AB  - Triclosan (TCS) is a polychlorinated phenoxy phenol (PCPPs) used as a disinfectant and a broad-spectrum antibacterial and antifungal agent in personal hygiene products. TCS easily forms diphenyl ethers and dioxins, which are persistent organic pollutants. This work used a double approach for the TSC sensing: a) screen-printed (SPE) electrochemical platform for on-site application, modified with lanthanum iron oxide and graphitic carbon nitride composite (LaFeO3/Fe2O3@g-C3N4/SPE); and b) carbon paste electrode (CPE), modified with the same material and used in laboratory conditions. Linear range from 0.1 μM to 10 μM, the limit of detection (LOD) of 29 nM and the limit of quantification (LOQ) of 91 nM were obtained for CP electrode in BRBS pH 8. SPE showed the best analytical parameters in BRBS at pH 3, with a linear range from 0.3 μM to 7 μM, LOD of 0.09 μM and LOQ of 0.28 μM. Furthermore, the influence of potential interferents was investigated and proven to be negligible. Determination of TSC was performed to estimate the environmental impact of this compound as well as the practical usefulness of the proposed sensor in the real sample analysis, confirmed with a HPLC analysis.
PB  - Elsevier
T2  - Science of the Total Environment
T1  - The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan
VL  - 857
SP  - 159250
DO  - 10.1016/j.scitotenv.2022.159250
ER  - 
@article{
author = "Knežević, Sara and Ostojić, Jelena and Ognjanović, Miloš and Savić, Slađana and Kovačević, Aleksandra and Manojlović, Dragan and Stanković, Vesna and Stanković, Dalibor",
year = "2023",
abstract = "Triclosan (TCS) is a polychlorinated phenoxy phenol (PCPPs) used as a disinfectant and a broad-spectrum antibacterial and antifungal agent in personal hygiene products. TCS easily forms diphenyl ethers and dioxins, which are persistent organic pollutants. This work used a double approach for the TSC sensing: a) screen-printed (SPE) electrochemical platform for on-site application, modified with lanthanum iron oxide and graphitic carbon nitride composite (LaFeO3/Fe2O3@g-C3N4/SPE); and b) carbon paste electrode (CPE), modified with the same material and used in laboratory conditions. Linear range from 0.1 μM to 10 μM, the limit of detection (LOD) of 29 nM and the limit of quantification (LOQ) of 91 nM were obtained for CP electrode in BRBS pH 8. SPE showed the best analytical parameters in BRBS at pH 3, with a linear range from 0.3 μM to 7 μM, LOD of 0.09 μM and LOQ of 0.28 μM. Furthermore, the influence of potential interferents was investigated and proven to be negligible. Determination of TSC was performed to estimate the environmental impact of this compound as well as the practical usefulness of the proposed sensor in the real sample analysis, confirmed with a HPLC analysis.",
publisher = "Elsevier",
journal = "Science of the Total Environment",
title = "The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan",
volume = "857",
pages = "159250",
doi = "10.1016/j.scitotenv.2022.159250"
}
Knežević, S., Ostojić, J., Ognjanović, M., Savić, S., Kovačević, A., Manojlović, D., Stanković, V.,& Stanković, D.. (2023). The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan. in Science of the Total Environment
Elsevier., 857, 159250.
https://doi.org/10.1016/j.scitotenv.2022.159250
Knežević S, Ostojić J, Ognjanović M, Savić S, Kovačević A, Manojlović D, Stanković V, Stanković D. The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan. in Science of the Total Environment. 2023;857:159250.
doi:10.1016/j.scitotenv.2022.159250 .
Knežević, Sara, Ostojić, Jelena, Ognjanović, Miloš, Savić, Slađana, Kovačević, Aleksandra, Manojlović, Dragan, Stanković, Vesna, Stanković, Dalibor, "The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan" in Science of the Total Environment, 857 (2023):159250,
https://doi.org/10.1016/j.scitotenv.2022.159250 . .
9
9

Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications

Korina, Elena; Abramyan, Anton; Bol’shakov, Oleg; Avdin, Vyacheslav V.; Savić, Sladjana; Manojlović, Dragan; Stanković, Vesna; Stanković, Dalibor M.

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Korina, Elena
AU  - Abramyan, Anton
AU  - Bol’shakov, Oleg
AU  - Avdin, Vyacheslav V.
AU  - Savić, Sladjana
AU  - Manojlović, Dragan
AU  - Stanković, Vesna
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5657
AB  - Stable, water-soluble titanium complexed with mandelic acid was used as a precursor for titanium phosphorus double oxide obtained in hydrothermal conditions in the presence of phosphoric acid. Surprisingly, hydrolysis of organic complexes provided a microstructured sphere with narrow size distribution, low aggregation and a small fraction of morphological irregularities. Obtained microspheres had a complex structure comprised of flakes, whose size could be manipulated with temperature conditions. Samples were found to be electrochemically active against sulcotrione, a well-recognized herbicide. Electrochemical sensors based on the synthesized microspheres were successfully adapted for natural water reservoir analysis and exhibited low levels of detection of 0.61 µM, limit of quantification of 1.86 µM, wide dynamic linear range from 2 to 200 µM, good selectivity, excellent reproducibility and in-time stability.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Sensors
T1  - Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications
VL  - 23
IS  - 2
SP  - 933
DO  - 10.3390/s23020933
ER  - 
@article{
author = "Korina, Elena and Abramyan, Anton and Bol’shakov, Oleg and Avdin, Vyacheslav V. and Savić, Sladjana and Manojlović, Dragan and Stanković, Vesna and Stanković, Dalibor M.",
year = "2023",
abstract = "Stable, water-soluble titanium complexed with mandelic acid was used as a precursor for titanium phosphorus double oxide obtained in hydrothermal conditions in the presence of phosphoric acid. Surprisingly, hydrolysis of organic complexes provided a microstructured sphere with narrow size distribution, low aggregation and a small fraction of morphological irregularities. Obtained microspheres had a complex structure comprised of flakes, whose size could be manipulated with temperature conditions. Samples were found to be electrochemically active against sulcotrione, a well-recognized herbicide. Electrochemical sensors based on the synthesized microspheres were successfully adapted for natural water reservoir analysis and exhibited low levels of detection of 0.61 µM, limit of quantification of 1.86 µM, wide dynamic linear range from 2 to 200 µM, good selectivity, excellent reproducibility and in-time stability.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Sensors",
title = "Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications",
volume = "23",
number = "2",
pages = "933",
doi = "10.3390/s23020933"
}
Korina, E., Abramyan, A., Bol’shakov, O., Avdin, V. V., Savić, S., Manojlović, D., Stanković, V.,& Stanković, D. M.. (2023). Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications. in Sensors
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 23(2), 933.
https://doi.org/10.3390/s23020933
Korina E, Abramyan A, Bol’shakov O, Avdin VV, Savić S, Manojlović D, Stanković V, Stanković DM. Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications. in Sensors. 2023;23(2):933.
doi:10.3390/s23020933 .
Korina, Elena, Abramyan, Anton, Bol’shakov, Oleg, Avdin, Vyacheslav V., Savić, Sladjana, Manojlović, Dragan, Stanković, Vesna, Stanković, Dalibor M., "Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications" in Sensors, 23, no. 2 (2023):933,
https://doi.org/10.3390/s23020933 . .

Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA

Mijajlović, Aleksandar; Ognjanović, Miloš; Manojlović, Dragan; Vlahović, Filip; Ðurđić, Slađana; Stanković, Vesna; Stanković, Dalibor

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Mijajlović, Aleksandar
AU  - Ognjanović, Miloš
AU  - Manojlović, Dragan
AU  - Vlahović, Filip
AU  - Ðurđić, Slađana
AU  - Stanković, Vesna
AU  - Stanković, Dalibor
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5694
AB  - There are ten million people in the world who have Parkinson’s disease. The most potent medicine for Parkinson’s disease is levodopa (L-DOPA). However, long-term consumption of L-DOPA leads to the appearance of side effects, as a result of which the control and monitoring of its concentrations are of great importance. In this work, we have designed a new electrochemical sensor for detecting L-DOPA using a carbon paste electrode (CPE) modified with Eu2O3@Cr2O3 composite nanoparticles. Rare earth elements, including Eu, are increasingly used to design new electrode nanocomposites with enhanced electrocatalytic properties. Europium has been considered a significant lanthanide element with greater redox reaction behavior. We conducted a hydrothermal synthesis of Eu2O3@Cr2O3 and, for the first time, the acquired nanoparticles were used to modify CPE. The proposed Eu2O3@Cr2O3/CPE electrode was investigated in terms of its electrocatalytic properties and then used to develop an analytical method for detecting and quantifying L-DOPA. The proposed sensor offers a wide linear range (1–100 µM), high sensitivity (1.38 µA µM−1 cm−2) and a low detection limit (0.72 µM). The practical application of the proposed sensor was investigated by analyzing commercially available pharmaceutical tablets of L-DOPA. The corresponding results indicate the excellent potential of the Eu2O3@Cr2O3/CPE sensor for application in real-time L-DOPA detection.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Biosensors
T1  - Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA
VL  - 13
IS  - 2
SP  - 201
DO  - 10.3390/bios13020201
ER  - 
@article{
author = "Mijajlović, Aleksandar and Ognjanović, Miloš and Manojlović, Dragan and Vlahović, Filip and Ðurđić, Slađana and Stanković, Vesna and Stanković, Dalibor",
year = "2023",
abstract = "There are ten million people in the world who have Parkinson’s disease. The most potent medicine for Parkinson’s disease is levodopa (L-DOPA). However, long-term consumption of L-DOPA leads to the appearance of side effects, as a result of which the control and monitoring of its concentrations are of great importance. In this work, we have designed a new electrochemical sensor for detecting L-DOPA using a carbon paste electrode (CPE) modified with Eu2O3@Cr2O3 composite nanoparticles. Rare earth elements, including Eu, are increasingly used to design new electrode nanocomposites with enhanced electrocatalytic properties. Europium has been considered a significant lanthanide element with greater redox reaction behavior. We conducted a hydrothermal synthesis of Eu2O3@Cr2O3 and, for the first time, the acquired nanoparticles were used to modify CPE. The proposed Eu2O3@Cr2O3/CPE electrode was investigated in terms of its electrocatalytic properties and then used to develop an analytical method for detecting and quantifying L-DOPA. The proposed sensor offers a wide linear range (1–100 µM), high sensitivity (1.38 µA µM−1 cm−2) and a low detection limit (0.72 µM). The practical application of the proposed sensor was investigated by analyzing commercially available pharmaceutical tablets of L-DOPA. The corresponding results indicate the excellent potential of the Eu2O3@Cr2O3/CPE sensor for application in real-time L-DOPA detection.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Biosensors",
title = "Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA",
volume = "13",
number = "2",
pages = "201",
doi = "10.3390/bios13020201"
}
Mijajlović, A., Ognjanović, M., Manojlović, D., Vlahović, F., Ðurđić, S., Stanković, V.,& Stanković, D.. (2023). Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA. in Biosensors
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 13(2), 201.
https://doi.org/10.3390/bios13020201
Mijajlović A, Ognjanović M, Manojlović D, Vlahović F, Ðurđić S, Stanković V, Stanković D. Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA. in Biosensors. 2023;13(2):201.
doi:10.3390/bios13020201 .
Mijajlović, Aleksandar, Ognjanović, Miloš, Manojlović, Dragan, Vlahović, Filip, Ðurđić, Slađana, Stanković, Vesna, Stanković, Dalibor, "Eu2O3@Cr2O3 Nanoparticles-Modified Carbon Paste Electrode for Efficient Electrochemical Sensing of Neurotransmitters Precursor L-DOPA" in Biosensors, 13, no. 2 (2023):201,
https://doi.org/10.3390/bios13020201 . .
1
4

Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory

Đurđić, Slađana; Vlahović, Filip; Markićević, Milan; Mutić, Jelena; Manojlović, Dragan; Stanković, Vesna; Švorc, Ľubomír; Stanković, Dalibor

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Đurđić, Slađana
AU  - Vlahović, Filip
AU  - Markićević, Milan
AU  - Mutić, Jelena
AU  - Manojlović, Dragan
AU  - Stanković, Vesna
AU  - Švorc, Ľubomír
AU  - Stanković, Dalibor
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5774
AB  - Herein, a screen–printed diamond electrode (SPDE) coupled with a “point-of-care” platform (30 µL-drop concepts, single-drop-detection approach) was successfully applied for the electrochemical determination of pterostilbene (PTS). Cyclic voltammetry identified irreversible oxidation of PTS, where oxidation peak was shown to be strongly dependent on the pH of the working environmental. Although the proposition of the detailed electrochemical oxidation mechanism of PTS goes out of the scope of the present research, we have determined the most probable reactive site of our analyte, by utilizing DFT-based reactivity descriptors (Fukui functions). For electrochemical quantification of PTS, oxidation peak at 0.32 V (vs. Ag/AgCl) was followed in presence of 0.5 mol L−1 of Briton–Robinson buffer solution (pH = 9). Coupled with the optimized parameters of differential pulse voltammetry (DPV), SPDE detected PTS in two linear ranges (first range was from 0.011 to 0.912 µmol L−1; second range was from 0.912 to 4.420 µmol L−1), providing the LOD and LOQ on a nanomolar level (3.1 nmol L−1 and 10.0 nmol L−1, respectively). The selectivity of the optimized DPV method was found to be excellent, with the current changes of less than 7%, in the presence of ten times higher concentrations of the certain interferences. The practical applicability of the SPDE and single-drop-detection approach in dietary supplements (with a declared PTS content of 50 mg/tablet), with the recovery values ranging from 95 to 102%, shows that the developed method has high potential for precise and accurate PTS detection, as well as exceptional miniaturization possibilities of relevant equipment for on-site sensing.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Chemosensors
T1  - Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory
VL  - 11
IS  - 1
SP  - 15
DO  - 10.3390/chemosensors11010015
ER  - 
@article{
author = "Đurđić, Slađana and Vlahović, Filip and Markićević, Milan and Mutić, Jelena and Manojlović, Dragan and Stanković, Vesna and Švorc, Ľubomír and Stanković, Dalibor",
year = "2023",
abstract = "Herein, a screen–printed diamond electrode (SPDE) coupled with a “point-of-care” platform (30 µL-drop concepts, single-drop-detection approach) was successfully applied for the electrochemical determination of pterostilbene (PTS). Cyclic voltammetry identified irreversible oxidation of PTS, where oxidation peak was shown to be strongly dependent on the pH of the working environmental. Although the proposition of the detailed electrochemical oxidation mechanism of PTS goes out of the scope of the present research, we have determined the most probable reactive site of our analyte, by utilizing DFT-based reactivity descriptors (Fukui functions). For electrochemical quantification of PTS, oxidation peak at 0.32 V (vs. Ag/AgCl) was followed in presence of 0.5 mol L−1 of Briton–Robinson buffer solution (pH = 9). Coupled with the optimized parameters of differential pulse voltammetry (DPV), SPDE detected PTS in two linear ranges (first range was from 0.011 to 0.912 µmol L−1; second range was from 0.912 to 4.420 µmol L−1), providing the LOD and LOQ on a nanomolar level (3.1 nmol L−1 and 10.0 nmol L−1, respectively). The selectivity of the optimized DPV method was found to be excellent, with the current changes of less than 7%, in the presence of ten times higher concentrations of the certain interferences. The practical applicability of the SPDE and single-drop-detection approach in dietary supplements (with a declared PTS content of 50 mg/tablet), with the recovery values ranging from 95 to 102%, shows that the developed method has high potential for precise and accurate PTS detection, as well as exceptional miniaturization possibilities of relevant equipment for on-site sensing.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Chemosensors",
title = "Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory",
volume = "11",
number = "1",
pages = "15",
doi = "10.3390/chemosensors11010015"
}
Đurđić, S., Vlahović, F., Markićević, M., Mutić, J., Manojlović, D., Stanković, V., Švorc, Ľ.,& Stanković, D.. (2023). Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory. in Chemosensors
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 11(1), 15.
https://doi.org/10.3390/chemosensors11010015
Đurđić S, Vlahović F, Markićević M, Mutić J, Manojlović D, Stanković V, Švorc Ľ, Stanković D. Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory. in Chemosensors. 2023;11(1):15.
doi:10.3390/chemosensors11010015 .
Đurđić, Slađana, Vlahović, Filip, Markićević, Milan, Mutić, Jelena, Manojlović, Dragan, Stanković, Vesna, Švorc, Ľubomír, Stanković, Dalibor, "Application of Screen Printed Diamond Electrode, Coupled with “Point-of-Care” Platform, for Nanomolar Quantification of Phytonutrient Pterostilbene in Dietary Supplements: An Experimental Study Supported by Theory" in Chemosensors, 11, no. 1 (2023):15,
https://doi.org/10.3390/chemosensors11010015 . .
1
1

Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments

Randjelović, Danijela; Joksimović, Kristina; Kodranov, Igor; Žerađanin, Aleksandra; Popović, Bogdan; Poljak, Predrag; Manojlović, Dragan; Beškoski, Vladimir

(Institute of Electrical and Electronics Engineers Inc (IEEE), 2022)

TY  - CONF
AU  - Randjelović, Danijela
AU  - Joksimović, Kristina
AU  - Kodranov, Igor
AU  - Žerađanin, Aleksandra
AU  - Popović, Bogdan
AU  - Poljak, Predrag
AU  - Manojlović, Dragan
AU  - Beškoski, Vladimir
PY  - 2022
UR  - https://ieeexplore.ieee.org/document/9934706
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5857
AB  - This paper gives overview of research activities, performed by our team, in the field of Microbial Fuel Cells (MFCs). Evolution of construction, performance and application of MFCs is presented. The path towards optimization of the performance led through design and construction of the cell and was followed by investigation of impact of different sediments containing different microbial communities. The sediment samples were collected from two locations in Serbia, confluence of rivers Sava and Danube in Belgrade and the acid mine drainage lake "Robule" in the copper mine Bor. Results of verified application in wastewater treatment are discussed.
PB  - Institute of Electrical and Electronics Engineers Inc (IEEE)
C3  - Proceedings - 45th IEEE International Semiconductor Conference CAS 2022, Poiana Brasov, October 12-14, 2022, Romania
T1  - Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments
SP  - 30
EP  - 37
DO  - 10.1109/CAS56377.2022.9934706
ER  - 
@conference{
author = "Randjelović, Danijela and Joksimović, Kristina and Kodranov, Igor and Žerađanin, Aleksandra and Popović, Bogdan and Poljak, Predrag and Manojlović, Dragan and Beškoski, Vladimir",
year = "2022",
abstract = "This paper gives overview of research activities, performed by our team, in the field of Microbial Fuel Cells (MFCs). Evolution of construction, performance and application of MFCs is presented. The path towards optimization of the performance led through design and construction of the cell and was followed by investigation of impact of different sediments containing different microbial communities. The sediment samples were collected from two locations in Serbia, confluence of rivers Sava and Danube in Belgrade and the acid mine drainage lake "Robule" in the copper mine Bor. Results of verified application in wastewater treatment are discussed.",
publisher = "Institute of Electrical and Electronics Engineers Inc (IEEE)",
journal = "Proceedings - 45th IEEE International Semiconductor Conference CAS 2022, Poiana Brasov, October 12-14, 2022, Romania",
title = "Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments",
pages = "30-37",
doi = "10.1109/CAS56377.2022.9934706"
}
Randjelović, D., Joksimović, K., Kodranov, I., Žerađanin, A., Popović, B., Poljak, P., Manojlović, D.,& Beškoski, V.. (2022). Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments. in Proceedings - 45th IEEE International Semiconductor Conference CAS 2022, Poiana Brasov, October 12-14, 2022, Romania
Institute of Electrical and Electronics Engineers Inc (IEEE)., 30-37.
https://doi.org/10.1109/CAS56377.2022.9934706
Randjelović D, Joksimović K, Kodranov I, Žerađanin A, Popović B, Poljak P, Manojlović D, Beškoski V. Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments. in Proceedings - 45th IEEE International Semiconductor Conference CAS 2022, Poiana Brasov, October 12-14, 2022, Romania. 2022;:30-37.
doi:10.1109/CAS56377.2022.9934706 .
Randjelović, Danijela, Joksimović, Kristina, Kodranov, Igor, Žerađanin, Aleksandra, Popović, Bogdan, Poljak, Predrag, Manojlović, Dragan, Beškoski, Vladimir, "Evolution of Construction, Performance and Application of Microbial Fuel Cells Based on River and Acid Mine Drainage Sediments" in Proceedings - 45th IEEE International Semiconductor Conference CAS 2022, Poiana Brasov, October 12-14, 2022, Romania (2022):30-37,
https://doi.org/10.1109/CAS56377.2022.9934706 . .

The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials

Pergal, Marija; Kodranov, Igor; Vasiljević-Radović, Dana; Steinhart, Milos; Gojgić-Cvijović, Gordana; Manojlović, Dragan; Špirkova, Milena

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Pergal, Marija
AU  - Kodranov, Igor
AU  - Vasiljević-Radović, Dana
AU  - Steinhart, Milos
AU  - Gojgić-Cvijović, Gordana
AU  - Manojlović, Dragan
AU  - Špirkova, Milena
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5801
AB  - in this study, in situ polymerization procedure in solvent mixture was used for the preparation of thermosetting PU nanocomposites (PUNCs) with different content of soft segment (from 30 to 60 wt%), and with the addition of organomodified montmorillonite clay (Cloisite 30B®) as the nanofiller, in an amount of 0.5 wt.%. The PUNCs were based on poly(dimethylsiloxane) macrodiol (PDMS) that represents soft segment and 4,4′-diphenylmethane diisocyanate (MDI) and hyperbranched polyester (BH-30) which were selected as the hard segment. The PUNCs are marked.
so that the last two numbers in title indicate wt.% of soft segment in materials. Namely, the main 
objective of this study is to analyze the effect of the soft segment content on the morphology of the 
prepared PU nanocomposite films using atomic force microscopy (AFM), scanning electron 
microscopy (SEM), and small- and near wide-angle X-Ray scattering (SWAXS) analyses. SEM 
images of the fractured surfaces were obtained on JEOL JSM-6610LV. AFM analysis was carried 
out by atomic force microscope (Dimension Icon, Bruker, USA). SWAXS measurements of the 
PUNCs were performed using SAXS instrument (originally Molecular Metrology, USA, recently 
considerably upgraded by SAXSLAB, now Xenocs).
PB  - Belgrade : Serbian Academy of Sciences and Arts
PB  - Belgrade : Faculty of Technology and Metallurgy, University of Belgrade
C3  - Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022, August 22nd-26th, 2022, Belgrade, Serbia
T1  - The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials
SP  - 140
EP  - 141
UR  - https://hdl.handle.net/21.15107/rcub_cer_5801
ER  - 
@conference{
author = "Pergal, Marija and Kodranov, Igor and Vasiljević-Radović, Dana and Steinhart, Milos and Gojgić-Cvijović, Gordana and Manojlović, Dragan and Špirkova, Milena",
year = "2022",
abstract = "in this study, in situ polymerization procedure in solvent mixture was used for the preparation of thermosetting PU nanocomposites (PUNCs) with different content of soft segment (from 30 to 60 wt%), and with the addition of organomodified montmorillonite clay (Cloisite 30B®) as the nanofiller, in an amount of 0.5 wt.%. The PUNCs were based on poly(dimethylsiloxane) macrodiol (PDMS) that represents soft segment and 4,4′-diphenylmethane diisocyanate (MDI) and hyperbranched polyester (BH-30) which were selected as the hard segment. The PUNCs are marked.
so that the last two numbers in title indicate wt.% of soft segment in materials. Namely, the main 
objective of this study is to analyze the effect of the soft segment content on the morphology of the 
prepared PU nanocomposite films using atomic force microscopy (AFM), scanning electron 
microscopy (SEM), and small- and near wide-angle X-Ray scattering (SWAXS) analyses. SEM 
images of the fractured surfaces were obtained on JEOL JSM-6610LV. AFM analysis was carried 
out by atomic force microscope (Dimension Icon, Bruker, USA). SWAXS measurements of the 
PUNCs were performed using SAXS instrument (originally Molecular Metrology, USA, recently 
considerably upgraded by SAXSLAB, now Xenocs).",
publisher = "Belgrade : Serbian Academy of Sciences and Arts, Belgrade : Faculty of Technology and Metallurgy, University of Belgrade",
journal = "Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022, August 22nd-26th, 2022, Belgrade, Serbia",
title = "The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials",
pages = "140-141",
url = "https://hdl.handle.net/21.15107/rcub_cer_5801"
}
Pergal, M., Kodranov, I., Vasiljević-Radović, D., Steinhart, M., Gojgić-Cvijović, G., Manojlović, D.,& Špirkova, M.. (2022). The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials. in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022, August 22nd-26th, 2022, Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 140-141.
https://hdl.handle.net/21.15107/rcub_cer_5801
Pergal M, Kodranov I, Vasiljević-Radović D, Steinhart M, Gojgić-Cvijović G, Manojlović D, Špirkova M. The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials. in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022, August 22nd-26th, 2022, Belgrade, Serbia. 2022;:140-141.
https://hdl.handle.net/21.15107/rcub_cer_5801 .
Pergal, Marija, Kodranov, Igor, Vasiljević-Radović, Dana, Steinhart, Milos, Gojgić-Cvijović, Gordana, Manojlović, Dragan, Špirkova, Milena, "The effect of poly(dimethylsiloxane) segment content on the morphology of polyurethane composite materials" in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022, August 22nd-26th, 2022, Belgrade, Serbia (2022):140-141,
https://hdl.handle.net/21.15107/rcub_cer_5801 .

Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances

Savić, Slađana; Roglić, Goran; Dojčinović, Biljana; Manojlović, Dragan; Stanković, Dalibor

(Elsevier, 2022)

TY  - CHAP
AU  - Savić, Slađana
AU  - Roglić, Goran
AU  - Dojčinović, Biljana
AU  - Manojlović, Dragan
AU  - Stanković, Dalibor
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5644
AB  - Environmental pollution requires a facile, sustainable, and adjustable approach for the processing. Most of the standard treatment procedures include high temperature and pressure, accompanied by expensive catalysts. Visible light improves decomposing systems of various contaminants from the hydrosphere and atmosphere. Graphitic carbon nitride (g-C3N4) dragged research interest in the degradation of diverse environmental contaminants, due to its photoactivity under the visible electromagnetic spectrum, production of oxidative species, and a range of relatively simple ways of synthesis. Nowadays, catalytic properties of g-C3N4 are enhanced by expanding surface area, widening of the bandgap, and by the development of doped or copolymer materials. Mechanisms of catalysis using different nanocomposites are given in detail, followed by the extent of degradation of dangerous chemicals. Considering all valuable evolutions of g-C3N4 as an important ingredient in the degeneration of diverse pollutants, here we provide a systematic overview of the nanostructured g-C3N4 used in solving environmental problems.
PB  - Elsevier
T2  - Advanced Materials for Sustainable Environmental Remediation: Terrestrial and Aquatic Environments
T1  - Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances
SP  - 533
EP  - 549
DO  - 10.1016/B978-0-323-90485-8.00007-2
ER  - 
@inbook{
author = "Savić, Slađana and Roglić, Goran and Dojčinović, Biljana and Manojlović, Dragan and Stanković, Dalibor",
year = "2022",
abstract = "Environmental pollution requires a facile, sustainable, and adjustable approach for the processing. Most of the standard treatment procedures include high temperature and pressure, accompanied by expensive catalysts. Visible light improves decomposing systems of various contaminants from the hydrosphere and atmosphere. Graphitic carbon nitride (g-C3N4) dragged research interest in the degradation of diverse environmental contaminants, due to its photoactivity under the visible electromagnetic spectrum, production of oxidative species, and a range of relatively simple ways of synthesis. Nowadays, catalytic properties of g-C3N4 are enhanced by expanding surface area, widening of the bandgap, and by the development of doped or copolymer materials. Mechanisms of catalysis using different nanocomposites are given in detail, followed by the extent of degradation of dangerous chemicals. Considering all valuable evolutions of g-C3N4 as an important ingredient in the degeneration of diverse pollutants, here we provide a systematic overview of the nanostructured g-C3N4 used in solving environmental problems.",
publisher = "Elsevier",
journal = "Advanced Materials for Sustainable Environmental Remediation: Terrestrial and Aquatic Environments",
booktitle = "Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances",
pages = "533-549",
doi = "10.1016/B978-0-323-90485-8.00007-2"
}
Savić, S., Roglić, G., Dojčinović, B., Manojlović, D.,& Stanković, D.. (2022). Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances. in Advanced Materials for Sustainable Environmental Remediation: Terrestrial and Aquatic Environments
Elsevier., 533-549.
https://doi.org/10.1016/B978-0-323-90485-8.00007-2
Savić S, Roglić G, Dojčinović B, Manojlović D, Stanković D. Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances. in Advanced Materials for Sustainable Environmental Remediation: Terrestrial and Aquatic Environments. 2022;:533-549.
doi:10.1016/B978-0-323-90485-8.00007-2 .
Savić, Slađana, Roglić, Goran, Dojčinović, Biljana, Manojlović, Dragan, Stanković, Dalibor, "Chapter 20 - Graphitic carbon nitride: Triggering the solar light–assisted decomposition of hazardous substances" in Advanced Materials for Sustainable Environmental Remediation: Terrestrial and Aquatic Environments (2022):533-549,
https://doi.org/10.1016/B978-0-323-90485-8.00007-2 . .

Polyurethane/ferrites composite materials: A study on antimicrobial activity

Pergal, Marija; Kodranov, Igor; Vasiljević-Radović, Dana; Nikodinović-Runić, Jasmina; Dojčinović, Biljana; Manojlović, Dragan; Antić, Bratislav

(Srbija,Niš : RAD Centre, 2022)

TY  - CONF
AU  - Pergal, Marija
AU  - Kodranov, Igor
AU  - Vasiljević-Radović, Dana
AU  - Nikodinović-Runić, Jasmina
AU  - Dojčinović, Biljana
AU  - Manojlović, Dragan
AU  - Antić, Bratislav
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6363
AB  - Polyurethane (PU) nanocomposites are highly utilized in biomedical devices/implants due to their excellent mechanical properties, good biocompatibility, and low cytotoxicity. These PU nanocomposites with silver nanoparticles are well known potent antimicrobial agents. Biocompatible magnetic nanoparticles such as ferrites has also gained attention especially in various fields of drug delivery, biosensing and magnetic resonance imaging which requires highly specific magnetic nanoparticle (MNP) properties such as uniform size distribution, less agglomeration and stability in the biological medium. Among MNP, copper and zinc ferrites have been broadly applicable in biomedical, optoelectronic, catalysis and drug delivery. With a view to design PU/ferrites nanocomposites and to explore their antimicrobial potential, the present preliminary study reports the preparation of PU nanocomposites with copper ferrite and zinc ferrite (1 wt.%) and with the same composition. The nanocomposites were characterized using water absorption and swelling measurements. The antimicrobial activity of these composites was investigated against four bacterial strains: Staphylococcus aureus, Enterococcus faecium, Pseudomonas aeruginosa, and Klebsiella pneumoniae, and one Candida strain, C. albicans and compared with those of PU nanocomposites with silver ferrite nanoparticles. PU nanocomposites based on zinc and copper ferrites did not show antimicrobial activity, on the contrary they supported microbial attachment and growth. However, PU nanocomposites with silver ferrite did not show significant antibacterial activity but show antifungal activity and it is related with hydrophilicity of the prepared materials.
PB  - Srbija,Niš : RAD  Centre
C3  - RAD 2022 : 10th Jubilee International Conference on Radiation in Various Fields of Research : the book of abstracts; July 25-29; Herceg Novi, Montenegro
T1  - Polyurethane/ferrites composite materials: A study on antimicrobial activity
SP  - 38
EP  - 38
DO  - 10.21175/rad.sum.abstr.book.2022.11.14
ER  - 
@conference{
author = "Pergal, Marija and Kodranov, Igor and Vasiljević-Radović, Dana and Nikodinović-Runić, Jasmina and Dojčinović, Biljana and Manojlović, Dragan and Antić, Bratislav",
year = "2022",
abstract = "Polyurethane (PU) nanocomposites are highly utilized in biomedical devices/implants due to their excellent mechanical properties, good biocompatibility, and low cytotoxicity. These PU nanocomposites with silver nanoparticles are well known potent antimicrobial agents. Biocompatible magnetic nanoparticles such as ferrites has also gained attention especially in various fields of drug delivery, biosensing and magnetic resonance imaging which requires highly specific magnetic nanoparticle (MNP) properties such as uniform size distribution, less agglomeration and stability in the biological medium. Among MNP, copper and zinc ferrites have been broadly applicable in biomedical, optoelectronic, catalysis and drug delivery. With a view to design PU/ferrites nanocomposites and to explore their antimicrobial potential, the present preliminary study reports the preparation of PU nanocomposites with copper ferrite and zinc ferrite (1 wt.%) and with the same composition. The nanocomposites were characterized using water absorption and swelling measurements. The antimicrobial activity of these composites was investigated against four bacterial strains: Staphylococcus aureus, Enterococcus faecium, Pseudomonas aeruginosa, and Klebsiella pneumoniae, and one Candida strain, C. albicans and compared with those of PU nanocomposites with silver ferrite nanoparticles. PU nanocomposites based on zinc and copper ferrites did not show antimicrobial activity, on the contrary they supported microbial attachment and growth. However, PU nanocomposites with silver ferrite did not show significant antibacterial activity but show antifungal activity and it is related with hydrophilicity of the prepared materials.",
publisher = "Srbija,Niš : RAD  Centre",
journal = "RAD 2022 : 10th Jubilee International Conference on Radiation in Various Fields of Research : the book of abstracts; July 25-29; Herceg Novi, Montenegro",
title = "Polyurethane/ferrites composite materials: A study on antimicrobial activity",
pages = "38-38",
doi = "10.21175/rad.sum.abstr.book.2022.11.14"
}
Pergal, M., Kodranov, I., Vasiljević-Radović, D., Nikodinović-Runić, J., Dojčinović, B., Manojlović, D.,& Antić, B.. (2022). Polyurethane/ferrites composite materials: A study on antimicrobial activity. in RAD 2022 : 10th Jubilee International Conference on Radiation in Various Fields of Research : the book of abstracts; July 25-29; Herceg Novi, Montenegro
Srbija,Niš : RAD  Centre., 38-38.
https://doi.org/10.21175/rad.sum.abstr.book.2022.11.14
Pergal M, Kodranov I, Vasiljević-Radović D, Nikodinović-Runić J, Dojčinović B, Manojlović D, Antić B. Polyurethane/ferrites composite materials: A study on antimicrobial activity. in RAD 2022 : 10th Jubilee International Conference on Radiation in Various Fields of Research : the book of abstracts; July 25-29; Herceg Novi, Montenegro. 2022;:38-38.
doi:10.21175/rad.sum.abstr.book.2022.11.14 .
Pergal, Marija, Kodranov, Igor, Vasiljević-Radović, Dana, Nikodinović-Runić, Jasmina, Dojčinović, Biljana, Manojlović, Dragan, Antić, Bratislav, "Polyurethane/ferrites composite materials: A study on antimicrobial activity" in RAD 2022 : 10th Jubilee International Conference on Radiation in Various Fields of Research : the book of abstracts; July 25-29; Herceg Novi, Montenegro (2022):38-38,
https://doi.org/10.21175/rad.sum.abstr.book.2022.11.14 . .

Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties

Pergal, Marija; Gojgić-Cvijović, Gordana; Steinhart, Miloš; Manojlović, Dragan; Ostojić, Sanja; Pezo, Lato; Špírková, Milena

(Elsevier, 2022)

TY  - JOUR
AU  - Pergal, Marija
AU  - Gojgić-Cvijović, Gordana
AU  - Steinhart, Miloš
AU  - Manojlović, Dragan
AU  - Ostojić, Sanja
AU  - Pezo, Lato
AU  - Špírková, Milena
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5237
AB  - A series of novel polyurethane network/organoclay nanocomposites (PUN-NCs) with different soft segment contents (30–60 wt%) was prepared by in situ polymerization in solution and characterized. PU network (PUN) was made from poly(dimethylsiloxane)-based macrodiol as the soft segment and 4,4′-methylenediphenyldiisocyanate and hyperbranched polyester of the third pseudo generation as the hard segment. Nanocomposites were obtained by dispersion of organically modified montmorillonite (Cloisite 30B) nanofiller (0.5 wt%). The influence of the soft segment content on the functional properties of PUN-NCs was studied by Fourier transform infrared (FTIR), small-angle and near wide-angle X-ray scattering (SWAXS), thermogravimetric analysis (TGA), dynamic mechanical thermal analyses (DMTA), differential scanning calorimetry (DSC), nanoindentation, atomic force microscopy (AFM), scanning electron microscopy (SEM), and swelling behavior, water absorption and contact angle measurements. The biodegradation process was evaluated using mixed cultures of microorganisms that originated from soil. Mechanically strong PUN-NC materials in the form of films were obtained, pointing to good dispersion and the existence of exfoliated morphology of Cloisite 30B within the PUN matrix, and the nanocomposites with the abovementioned characteristics were obtained as a function of the soft segment content. The decrease of the soft segment content induced a higher degree of phase separated microstructure, increase of Young's modulus, hardness, plasticity, storage modulus, glass transition temperature, surface free energy and swelling ability in tetrahydrofuran, but at the same time, it is responsible for the decrease of crosslinking density and hydrophobicity of PUN-NCs. By choosing adequate soft segment content, the prepared materials can potentially be designed for coating applications, such as top coating materials in environmental conditions.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties
VL  - 163
IS  - 106664
DO  - 10.1016/j.porgcoat.2021.106664
ER  - 
@article{
author = "Pergal, Marija and Gojgić-Cvijović, Gordana and Steinhart, Miloš and Manojlović, Dragan and Ostojić, Sanja and Pezo, Lato and Špírková, Milena",
year = "2022",
abstract = "A series of novel polyurethane network/organoclay nanocomposites (PUN-NCs) with different soft segment contents (30–60 wt%) was prepared by in situ polymerization in solution and characterized. PU network (PUN) was made from poly(dimethylsiloxane)-based macrodiol as the soft segment and 4,4′-methylenediphenyldiisocyanate and hyperbranched polyester of the third pseudo generation as the hard segment. Nanocomposites were obtained by dispersion of organically modified montmorillonite (Cloisite 30B) nanofiller (0.5 wt%). The influence of the soft segment content on the functional properties of PUN-NCs was studied by Fourier transform infrared (FTIR), small-angle and near wide-angle X-ray scattering (SWAXS), thermogravimetric analysis (TGA), dynamic mechanical thermal analyses (DMTA), differential scanning calorimetry (DSC), nanoindentation, atomic force microscopy (AFM), scanning electron microscopy (SEM), and swelling behavior, water absorption and contact angle measurements. The biodegradation process was evaluated using mixed cultures of microorganisms that originated from soil. Mechanically strong PUN-NC materials in the form of films were obtained, pointing to good dispersion and the existence of exfoliated morphology of Cloisite 30B within the PUN matrix, and the nanocomposites with the abovementioned characteristics were obtained as a function of the soft segment content. The decrease of the soft segment content induced a higher degree of phase separated microstructure, increase of Young's modulus, hardness, plasticity, storage modulus, glass transition temperature, surface free energy and swelling ability in tetrahydrofuran, but at the same time, it is responsible for the decrease of crosslinking density and hydrophobicity of PUN-NCs. By choosing adequate soft segment content, the prepared materials can potentially be designed for coating applications, such as top coating materials in environmental conditions.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties",
volume = "163",
number = "106664",
doi = "10.1016/j.porgcoat.2021.106664"
}
Pergal, M., Gojgić-Cvijović, G., Steinhart, M., Manojlović, D., Ostojić, S., Pezo, L.,& Špírková, M.. (2022). Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties. in Progress in Organic Coatings
Elsevier., 163(106664).
https://doi.org/10.1016/j.porgcoat.2021.106664
Pergal M, Gojgić-Cvijović G, Steinhart M, Manojlović D, Ostojić S, Pezo L, Špírková M. Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties. in Progress in Organic Coatings. 2022;163(106664).
doi:10.1016/j.porgcoat.2021.106664 .
Pergal, Marija, Gojgić-Cvijović, Gordana, Steinhart, Miloš, Manojlović, Dragan, Ostojić, Sanja, Pezo, Lato, Špírková, Milena, "Novel polyurethane network/organoclay nanocomposites: Microstructure and physicochemical properties" in Progress in Organic Coatings, 163, no. 106664 (2022),
https://doi.org/10.1016/j.porgcoat.2021.106664 . .
1
6
6

Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye

Joksimović, Kristina; Kodranov, Igor; Randjelović, Danijela; Slavković Beškoski, Latinka; Radulović, Jelena; Lješević, Marija; Manojlović, Dragan; Beškoski, Vladimir

(Elsevier, 2022)

TY  - JOUR
AU  - Joksimović, Kristina
AU  - Kodranov, Igor
AU  - Randjelović, Danijela
AU  - Slavković Beškoski, Latinka
AU  - Radulović, Jelena
AU  - Lješević, Marija
AU  - Manojlović, Dragan
AU  - Beškoski, Vladimir
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4942
AB  - The problem of wastewater has long been ubiquitous and has great consequences for the environment and its
inhabitants. Microbial fuel cells (MFCs) have enormous potential for the treatment of wastewaters polluted with
azo dyes. The amount of energy that can be produced from a single-chamber MFC is sufficient to perform
decolorization and degradation of such dyes, which are widely used in the textile industry. This study on the azo
dye, reactive black 5 (RB5), provides an alternative method through three parallel-connected MFCs to obtain
electricity that directly serves for the dye’s electrochemical degradation. We examined degradation followed by
decolorization of RB5 using Fe and Pt electrodes, together with H2O2, to achieve the electro-Fenton process. The
amount of voltage produced (295 mV), the current density (276 mA m− 3
) and the power density (50 mW m− 3
)
were sufficient to degrade 25 mg L-1 RB5 dye with 0.5 mM H2O2 in just 2 h. The dye degradation mechanism was
investigated using UV–VIS, FT-IR and HPLC-MS/MS. The ecotoxicity of the degradation products was assessed
using a bacterial model, Aliivibrio fischeri. These tests showed that there was successful degradation of the dye to
products whose toxicity is less than that of RB5.
PB  - Elsevier
T2  - Bioelectrochemistry
T1  - Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye
VL  - 145
SP  - 108088
DO  - 10.1016/j.bioelechem.2022.108088
ER  - 
@article{
author = "Joksimović, Kristina and Kodranov, Igor and Randjelović, Danijela and Slavković Beškoski, Latinka and Radulović, Jelena and Lješević, Marija and Manojlović, Dragan and Beškoski, Vladimir",
year = "2022",
abstract = "The problem of wastewater has long been ubiquitous and has great consequences for the environment and its
inhabitants. Microbial fuel cells (MFCs) have enormous potential for the treatment of wastewaters polluted with
azo dyes. The amount of energy that can be produced from a single-chamber MFC is sufficient to perform
decolorization and degradation of such dyes, which are widely used in the textile industry. This study on the azo
dye, reactive black 5 (RB5), provides an alternative method through three parallel-connected MFCs to obtain
electricity that directly serves for the dye’s electrochemical degradation. We examined degradation followed by
decolorization of RB5 using Fe and Pt electrodes, together with H2O2, to achieve the electro-Fenton process. The
amount of voltage produced (295 mV), the current density (276 mA m− 3
) and the power density (50 mW m− 3
)
were sufficient to degrade 25 mg L-1 RB5 dye with 0.5 mM H2O2 in just 2 h. The dye degradation mechanism was
investigated using UV–VIS, FT-IR and HPLC-MS/MS. The ecotoxicity of the degradation products was assessed
using a bacterial model, Aliivibrio fischeri. These tests showed that there was successful degradation of the dye to
products whose toxicity is less than that of RB5.",
publisher = "Elsevier",
journal = "Bioelectrochemistry",
title = "Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye",
volume = "145",
pages = "108088",
doi = "10.1016/j.bioelechem.2022.108088"
}
Joksimović, K., Kodranov, I., Randjelović, D., Slavković Beškoski, L., Radulović, J., Lješević, M., Manojlović, D.,& Beškoski, V.. (2022). Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye. in Bioelectrochemistry
Elsevier., 145, 108088.
https://doi.org/10.1016/j.bioelechem.2022.108088
Joksimović K, Kodranov I, Randjelović D, Slavković Beškoski L, Radulović J, Lješević M, Manojlović D, Beškoski V. Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye. in Bioelectrochemistry. 2022;145:108088.
doi:10.1016/j.bioelechem.2022.108088 .
Joksimović, Kristina, Kodranov, Igor, Randjelović, Danijela, Slavković Beškoski, Latinka, Radulović, Jelena, Lješević, Marija, Manojlović, Dragan, Beškoski, Vladimir, "Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye" in Bioelectrochemistry, 145 (2022):108088,
https://doi.org/10.1016/j.bioelechem.2022.108088 . .
14
13

Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation

Šalipur, Hristina; Lončarević, Davor; Dostanić, Jasmina; Likozar, Blaž; Prašnikar, Anže; Manojlović, Dragan

(Elsevier, 2022)

TY  - JOUR
AU  - Šalipur, Hristina
AU  - Lončarević, Davor
AU  - Dostanić, Jasmina
AU  - Likozar, Blaž
AU  - Prašnikar, Anže
AU  - Manojlović, Dragan
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0360319922006036
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5228
AB  - In this work hydrogen production activity of a series of the nickel-loaded, nitrogen-doped titanate-based photocatalysts was tested by water splitting reaction in isopropanol-water mixture. The utilization of ammonium ions during catalyst synthesis and subsequent calcination led to successful formation of nitrogen-doped nanotubular titanates with lower sodium content, favored titanate-to-anatase transformation and enhanced textural, morphological and interface properties. The photocatalytic tests revealed that hydrogen production activity of nitrogen-doped titanates is ten times higher compared to nitrogen-free titanates. The presence of highly photoactive anatase phase, improved anatase crystallinity and lower amount of sodium ions are found to be decisive factors for increased hydrogen production activity. The optimal nickel loading was determined and the variation in photocatalytic activity with reduction temperature was explained. Stability tests gave quantitative analysis of the effects of reaction products accumulation and photocorrosion on the catalyst deactivation.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation
VL  - 47
IS  - 26
SP  - 12937
EP  - 12952
DO  - 10.1016/j.ijhydene.2022.02.054
ER  - 
@article{
author = "Šalipur, Hristina and Lončarević, Davor and Dostanić, Jasmina and Likozar, Blaž and Prašnikar, Anže and Manojlović, Dragan",
year = "2022",
abstract = "In this work hydrogen production activity of a series of the nickel-loaded, nitrogen-doped titanate-based photocatalysts was tested by water splitting reaction in isopropanol-water mixture. The utilization of ammonium ions during catalyst synthesis and subsequent calcination led to successful formation of nitrogen-doped nanotubular titanates with lower sodium content, favored titanate-to-anatase transformation and enhanced textural, morphological and interface properties. The photocatalytic tests revealed that hydrogen production activity of nitrogen-doped titanates is ten times higher compared to nitrogen-free titanates. The presence of highly photoactive anatase phase, improved anatase crystallinity and lower amount of sodium ions are found to be decisive factors for increased hydrogen production activity. The optimal nickel loading was determined and the variation in photocatalytic activity with reduction temperature was explained. Stability tests gave quantitative analysis of the effects of reaction products accumulation and photocorrosion on the catalyst deactivation.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation",
volume = "47",
number = "26",
pages = "12937-12952",
doi = "10.1016/j.ijhydene.2022.02.054"
}
Šalipur, H., Lončarević, D., Dostanić, J., Likozar, B., Prašnikar, A.,& Manojlović, D.. (2022). Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation. in International Journal of Hydrogen Energy
Elsevier., 47(26), 12937-12952.
https://doi.org/10.1016/j.ijhydene.2022.02.054
Šalipur H, Lončarević D, Dostanić J, Likozar B, Prašnikar A, Manojlović D. Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation. in International Journal of Hydrogen Energy. 2022;47(26):12937-12952.
doi:10.1016/j.ijhydene.2022.02.054 .
Šalipur, Hristina, Lončarević, Davor, Dostanić, Jasmina, Likozar, Blaž, Prašnikar, Anže, Manojlović, Dragan, "Nickel-loaded nitrogen-doped titanate nanostructured catalysts for solar-light driven hydrogen evolution and environmental remediation" in International Journal of Hydrogen Energy, 47, no. 26 (2022):12937-12952,
https://doi.org/10.1016/j.ijhydene.2022.02.054 . .
1
1

Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection

Stanković, Vesna; Manojlović, Dragan; Roglić, Goran; Tolstoguzov, Dmitry S.; Zherebtsov, Dmitry A.; Uchaev, Daniel A.; Avdin, Viacheslav V.; Stanković, Dalibor

(MDPI AG, 2022)

TY  - JOUR
AU  - Stanković, Vesna
AU  - Manojlović, Dragan
AU  - Roglić, Goran
AU  - Tolstoguzov, Dmitry S.
AU  - Zherebtsov, Dmitry A.
AU  - Uchaev, Daniel A.
AU  - Avdin, Viacheslav V.
AU  - Stanković, Dalibor
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5567
AB  - Nanoparticles of TiO2 are suitable for many catalytic and photocatalytic applications due to their extraordinary properties such as superhydrophobicity, semiconductivity, electron-rich, and environmental compatibility. The main crystalline phases of TiO2, anatase, and rutile possess different crystal structures, crystallinity, crystalline sizes, and specific surface areas, and these characteristics directly affect the catalytic performance of TiO2. In the present study, domestic carbon material enhanced with TiO2 nanoparticles was synthesized and used for the construction of a modified carbon paste electrode. The electrocatalytic activity of the modified electrodes was investigated depending on the TiO2 crystalline phases in the electrode material. Furthermore, the obtained working electrode was utilized for triclosan detection. Under optimized experimental conditions, the developed electrode showed a submicromolar triclosan detection limit of 0.07 µM and a wide linear range of 0.1 to 15 µM. The relative standard deviations for repeatability and reproducibility were lower than 4.1%, and with satisfactory selectivity, the proposed system was successfully applied to triclosan monitoring in groundwater. All these results confirm that the sustainable production of new and domestically prepared materials is of great benefit in the field of electrocatalysis and that the morphology of such produced materials is strongly related to their catalytic properties.
PB  - MDPI AG
T2  - Catalysts
T1  - Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection
VL  - 12
IS  - 12
SP  - 1571
DO  - 10.3390/catal12121571
ER  - 
@article{
author = "Stanković, Vesna and Manojlović, Dragan and Roglić, Goran and Tolstoguzov, Dmitry S. and Zherebtsov, Dmitry A. and Uchaev, Daniel A. and Avdin, Viacheslav V. and Stanković, Dalibor",
year = "2022",
abstract = "Nanoparticles of TiO2 are suitable for many catalytic and photocatalytic applications due to their extraordinary properties such as superhydrophobicity, semiconductivity, electron-rich, and environmental compatibility. The main crystalline phases of TiO2, anatase, and rutile possess different crystal structures, crystallinity, crystalline sizes, and specific surface areas, and these characteristics directly affect the catalytic performance of TiO2. In the present study, domestic carbon material enhanced with TiO2 nanoparticles was synthesized and used for the construction of a modified carbon paste electrode. The electrocatalytic activity of the modified electrodes was investigated depending on the TiO2 crystalline phases in the electrode material. Furthermore, the obtained working electrode was utilized for triclosan detection. Under optimized experimental conditions, the developed electrode showed a submicromolar triclosan detection limit of 0.07 µM and a wide linear range of 0.1 to 15 µM. The relative standard deviations for repeatability and reproducibility were lower than 4.1%, and with satisfactory selectivity, the proposed system was successfully applied to triclosan monitoring in groundwater. All these results confirm that the sustainable production of new and domestically prepared materials is of great benefit in the field of electrocatalysis and that the morphology of such produced materials is strongly related to their catalytic properties.",
publisher = "MDPI AG",
journal = "Catalysts",
title = "Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection",
volume = "12",
number = "12",
pages = "1571",
doi = "10.3390/catal12121571"
}
Stanković, V., Manojlović, D., Roglić, G., Tolstoguzov, D. S., Zherebtsov, D. A., Uchaev, D. A., Avdin, V. V.,& Stanković, D.. (2022). Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection. in Catalysts
MDPI AG., 12(12), 1571.
https://doi.org/10.3390/catal12121571
Stanković V, Manojlović D, Roglić G, Tolstoguzov DS, Zherebtsov DA, Uchaev DA, Avdin VV, Stanković D. Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection. in Catalysts. 2022;12(12):1571.
doi:10.3390/catal12121571 .
Stanković, Vesna, Manojlović, Dragan, Roglić, Goran, Tolstoguzov, Dmitry S., Zherebtsov, Dmitry A., Uchaev, Daniel A., Avdin, Viacheslav V., Stanković, Dalibor, "Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection" in Catalysts, 12, no. 12 (2022):1571,
https://doi.org/10.3390/catal12121571 . .
1

Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses

Nićetin, Milica; Pezo, Lato; Pergal, Marija; Lončar, Biljana; Filipović, Vladimir; Knežević, Violeta; Demir, Hande; Filipović, Jelena; Manojlović, Dragan

(MDPI, 2022)

TY  - JOUR
AU  - Nićetin, Milica
AU  - Pezo, Lato
AU  - Pergal, Marija
AU  - Lončar, Biljana
AU  - Filipović, Vladimir
AU  - Knežević, Violeta
AU  - Demir, Hande
AU  - Filipović, Jelena
AU  - Manojlović, Dragan
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5582
AB  - The osmotic dehydration (OD) of celery root in sugar beet molasses was studied at three temperatures (20, 35, and 50 °C) and three immersion periods (1, 3, and 5 h) in order to examine the changes in antioxidant potential and phenolic profile of celery root throughout the process. The antioxidant capacity (AOC) of dehydrated samples was evaluated by spectrophotometric and polarographic assays, the total phenolic content by the Folin-Ciocalteu method, and the individual phenolic compounds by HPLC-DAD. As a result of OD in molasses, the AOC and phenols content in samples increased proportionally to the augmentation of temperature and the immersion time. Vanillic acid, syringic acid, and catechin were detected in dehydrated samples as a result of transfer from molasses. Compared to fresh celery root, the content of identified phenols in osmodehydrated samples was improved from 1.5 to 6.2 times. Strong correlations between applied assays were obtained, except for the DPPH. Based on the correlation analysis chlorogenic acid, gallic acid, chrysin, catechin, and kaempferol showed the greatest contribution to the overall AOC of osmodehydrated celery root. Molasses, an agro-industrial waste from sugar production, could be valorized as a valuable osmotic solution.
PB  - MDPI
T2  - Foods
T1  - Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses
VL  - 11
IS  - 13
SP  - 1945
DO  - 10.3390/foods11131945
ER  - 
@article{
author = "Nićetin, Milica and Pezo, Lato and Pergal, Marija and Lončar, Biljana and Filipović, Vladimir and Knežević, Violeta and Demir, Hande and Filipović, Jelena and Manojlović, Dragan",
year = "2022",
abstract = "The osmotic dehydration (OD) of celery root in sugar beet molasses was studied at three temperatures (20, 35, and 50 °C) and three immersion periods (1, 3, and 5 h) in order to examine the changes in antioxidant potential and phenolic profile of celery root throughout the process. The antioxidant capacity (AOC) of dehydrated samples was evaluated by spectrophotometric and polarographic assays, the total phenolic content by the Folin-Ciocalteu method, and the individual phenolic compounds by HPLC-DAD. As a result of OD in molasses, the AOC and phenols content in samples increased proportionally to the augmentation of temperature and the immersion time. Vanillic acid, syringic acid, and catechin were detected in dehydrated samples as a result of transfer from molasses. Compared to fresh celery root, the content of identified phenols in osmodehydrated samples was improved from 1.5 to 6.2 times. Strong correlations between applied assays were obtained, except for the DPPH. Based on the correlation analysis chlorogenic acid, gallic acid, chrysin, catechin, and kaempferol showed the greatest contribution to the overall AOC of osmodehydrated celery root. Molasses, an agro-industrial waste from sugar production, could be valorized as a valuable osmotic solution.",
publisher = "MDPI",
journal = "Foods",
title = "Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses",
volume = "11",
number = "13",
pages = "1945",
doi = "10.3390/foods11131945"
}
Nićetin, M., Pezo, L., Pergal, M., Lončar, B., Filipović, V., Knežević, V., Demir, H., Filipović, J.,& Manojlović, D.. (2022). Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses. in Foods
MDPI., 11(13), 1945.
https://doi.org/10.3390/foods11131945
Nićetin M, Pezo L, Pergal M, Lončar B, Filipović V, Knežević V, Demir H, Filipović J, Manojlović D. Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses. in Foods. 2022;11(13):1945.
doi:10.3390/foods11131945 .
Nićetin, Milica, Pezo, Lato, Pergal, Marija, Lončar, Biljana, Filipović, Vladimir, Knežević, Violeta, Demir, Hande, Filipović, Jelena, Manojlović, Dragan, "Celery Root Phenols Content, Antioxidant Capacities and Their Correlations after Osmotic Dehydration in Molasses" in Foods, 11, no. 13 (2022):1945,
https://doi.org/10.3390/foods11131945 . .
5
3

Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol

Knežević, Sara; Ognjanović, Miloš; Dojčinović, Biljana; Antić, Bratislav; Vraneš‑Đurić, Sanja; Manojlović, Dragan; Stanković, Dalibor M.

(Springer, 2022)

TY  - JOUR
AU  - Knežević, Sara
AU  - Ognjanović, Miloš
AU  - Dojčinović, Biljana
AU  - Antić, Bratislav
AU  - Vraneš‑Đurić, Sanja
AU  - Manojlović, Dragan
AU  - Stanković, Dalibor M.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4873
AB  - Honokiol is neolignan present in the magnolia bark. It displays versatile pharmacological properties—neuroprotective and anxiolytic effect, anti-cancer activity and antimicrobial effect being the most important. This paper aims to develop a voltammetric non-enzymatic biosensor for honokiol detection, quantification and monitoring in drugs and cosmetic products. The materials used in this study were synthesized and characterized by HR-XRPD, SEM, ATR-FTIR and electrochemical methods. Bi2O3, being a p-type semiconductor, was used as an electrode material. Both its semiconductivity and electrocatalytic properties result from lattice structure defects, which differ on the surface and in the bulk of the bismuth oxide crystal, and therefore are crystal size dependent. The influence of the particle size of Bi2O3 on its electrocatalytic properties was studied, and it was confirmed that Bi2O3 nanoparticles have better overall conductive/resistive and catalytic characteristics than microribbons and that the optimal electrode modification for sensing application was obtained by Bi2O3@SWCNT composite material preparation. Here, we established a sensitive electrochemical sensing platform for honokiol detection based on CP electrode modified with bismuth oxide nanoparticles and SWCNT with the 0.17 μM limit of detection, and linear operating range from 0.1 to 50 μM. The effect of potential interferents on honokiol detection was explored. Obtained results in the interference tests and the real sample analysis suggest that the developed approach is selective, accurate and reproducible. Due to the low detection limit and a wide working range, the proposed sensing platform opens great opportunities for further construction of sensors for honokiol detection and monitoring in the pharmaceutical industry and medicinal chemistry.
PB  - Springer
T2  - Food Analytical Methods
T1  - Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol
VL  - 15
IS  - 4
SP  - 856
EP  - 867
DO  - 10.1007/s12161-021-02174-2
ER  - 
@article{
author = "Knežević, Sara and Ognjanović, Miloš and Dojčinović, Biljana and Antić, Bratislav and Vraneš‑Đurić, Sanja and Manojlović, Dragan and Stanković, Dalibor M.",
year = "2022",
abstract = "Honokiol is neolignan present in the magnolia bark. It displays versatile pharmacological properties—neuroprotective and anxiolytic effect, anti-cancer activity and antimicrobial effect being the most important. This paper aims to develop a voltammetric non-enzymatic biosensor for honokiol detection, quantification and monitoring in drugs and cosmetic products. The materials used in this study were synthesized and characterized by HR-XRPD, SEM, ATR-FTIR and electrochemical methods. Bi2O3, being a p-type semiconductor, was used as an electrode material. Both its semiconductivity and electrocatalytic properties result from lattice structure defects, which differ on the surface and in the bulk of the bismuth oxide crystal, and therefore are crystal size dependent. The influence of the particle size of Bi2O3 on its electrocatalytic properties was studied, and it was confirmed that Bi2O3 nanoparticles have better overall conductive/resistive and catalytic characteristics than microribbons and that the optimal electrode modification for sensing application was obtained by Bi2O3@SWCNT composite material preparation. Here, we established a sensitive electrochemical sensing platform for honokiol detection based on CP electrode modified with bismuth oxide nanoparticles and SWCNT with the 0.17 μM limit of detection, and linear operating range from 0.1 to 50 μM. The effect of potential interferents on honokiol detection was explored. Obtained results in the interference tests and the real sample analysis suggest that the developed approach is selective, accurate and reproducible. Due to the low detection limit and a wide working range, the proposed sensing platform opens great opportunities for further construction of sensors for honokiol detection and monitoring in the pharmaceutical industry and medicinal chemistry.",
publisher = "Springer",
journal = "Food Analytical Methods",
title = "Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol",
volume = "15",
number = "4",
pages = "856-867",
doi = "10.1007/s12161-021-02174-2"
}
Knežević, S., Ognjanović, M., Dojčinović, B., Antić, B., Vraneš‑Đurić, S., Manojlović, D.,& Stanković, D. M.. (2022). Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol. in Food Analytical Methods
Springer., 15(4), 856-867.
https://doi.org/10.1007/s12161-021-02174-2
Knežević S, Ognjanović M, Dojčinović B, Antić B, Vraneš‑Đurić S, Manojlović D, Stanković DM. Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol. in Food Analytical Methods. 2022;15(4):856-867.
doi:10.1007/s12161-021-02174-2 .
Knežević, Sara, Ognjanović, Miloš, Dojčinović, Biljana, Antić, Bratislav, Vraneš‑Đurić, Sanja, Manojlović, Dragan, Stanković, Dalibor M., "Sensing Platform Based on Carbon Paste Electrode Modified with Bismuth Oxide Nanoparticles and SWCNT for Submicromolar Quantification of Honokiol" in Food Analytical Methods, 15, no. 4 (2022):856-867,
https://doi.org/10.1007/s12161-021-02174-2 . .
7
5

Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation

Stanković, Dalibor M.; Kukuruzar, Andrej; Savić, Slađana; Ognjanović, Miloš; Janković-Častvan, Ivona M.; Roglić, Goran; Antić, Bratislav; Manojlović, Dragan; Dojčinović, Biljana

(Elsevier, 2021)

TY  - JOUR
AU  - Stanković, Dalibor M.
AU  - Kukuruzar, Andrej
AU  - Savić, Slađana
AU  - Ognjanović, Miloš
AU  - Janković-Častvan, Ivona M.
AU  - Roglić, Goran
AU  - Antić, Bratislav
AU  - Manojlović, Dragan
AU  - Dojčinović, Biljana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4788
AB  - The textile industry is one of the major pollutants of waterbodies with effluents high in biochemical and chemical oxygen demand values, high values of total dissolved solids, total suspended solids, and low dissolved oxygen values along with strong color. The existence of a successful method for its decontamination would be beneficial. In this work, we synthesized sponge-like europium oxide (Eu2O3) using a template-directed route from carbon hollow spheres, obtained from glucose as a carbon source. The material synthesis method was done in an aqueous environment, without using any organic solvents. Electrochemical properties of the synthesized material were investigated using cyclic voltammetry and electrical impedance spectroscopy, while morphological characterization was done using scanning electron microscopy and X-ray powder diffraction analysis. Eu2O3 were successfully immobilized at the surface of a screen-printed carbon electrode (Eu2O3/SPCE) using the drop-casting method. Finally, the prepared electrodes were tested toward the removal of Reactive Blue 52 (RB52) using electrochemical advanced oxidation processes (EAOPs). Important parameters, that is, the supporting electrolyte, its concentration, pH value, and the applied voltage, were optimized for RB52 degradation. The rate of removal was monitored spectrophotometrically and by high-performance liquid chromatography with a diode array detector (HPLC-DAD). It was found that the proposed approach reaches complete decolorization of the RB52 solution after a 60-min treatment, at pH 5.6 of KCl supporting electrolyte at a concentration of 0.05 M. Under optimal parameters, after 3 h of treatment, total organic carbon (TOC) was lowered by ~40%. The obtained results indicate that the proposed method may find potential application in EAOPs, considering electrode stability, durability, and efficiency and simplicity of the method.
PB  - Elsevier
T2  - Materials Chemistry and Physics
T1  - Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation
VL  - 273
SP  - 125154
DO  - 10.1016/j.matchemphys.2021.125154
ER  - 
@article{
author = "Stanković, Dalibor M. and Kukuruzar, Andrej and Savić, Slađana and Ognjanović, Miloš and Janković-Častvan, Ivona M. and Roglić, Goran and Antić, Bratislav and Manojlović, Dragan and Dojčinović, Biljana",
year = "2021",
abstract = "The textile industry is one of the major pollutants of waterbodies with effluents high in biochemical and chemical oxygen demand values, high values of total dissolved solids, total suspended solids, and low dissolved oxygen values along with strong color. The existence of a successful method for its decontamination would be beneficial. In this work, we synthesized sponge-like europium oxide (Eu2O3) using a template-directed route from carbon hollow spheres, obtained from glucose as a carbon source. The material synthesis method was done in an aqueous environment, without using any organic solvents. Electrochemical properties of the synthesized material were investigated using cyclic voltammetry and electrical impedance spectroscopy, while morphological characterization was done using scanning electron microscopy and X-ray powder diffraction analysis. Eu2O3 were successfully immobilized at the surface of a screen-printed carbon electrode (Eu2O3/SPCE) using the drop-casting method. Finally, the prepared electrodes were tested toward the removal of Reactive Blue 52 (RB52) using electrochemical advanced oxidation processes (EAOPs). Important parameters, that is, the supporting electrolyte, its concentration, pH value, and the applied voltage, were optimized for RB52 degradation. The rate of removal was monitored spectrophotometrically and by high-performance liquid chromatography with a diode array detector (HPLC-DAD). It was found that the proposed approach reaches complete decolorization of the RB52 solution after a 60-min treatment, at pH 5.6 of KCl supporting electrolyte at a concentration of 0.05 M. Under optimal parameters, after 3 h of treatment, total organic carbon (TOC) was lowered by ~40%. The obtained results indicate that the proposed method may find potential application in EAOPs, considering electrode stability, durability, and efficiency and simplicity of the method.",
publisher = "Elsevier",
journal = "Materials Chemistry and Physics",
title = "Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation",
volume = "273",
pages = "125154",
doi = "10.1016/j.matchemphys.2021.125154"
}
Stanković, D. M., Kukuruzar, A., Savić, S., Ognjanović, M., Janković-Častvan, I. M., Roglić, G., Antić, B., Manojlović, D.,& Dojčinović, B.. (2021). Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation. in Materials Chemistry and Physics
Elsevier., 273, 125154.
https://doi.org/10.1016/j.matchemphys.2021.125154
Stanković DM, Kukuruzar A, Savić S, Ognjanović M, Janković-Častvan IM, Roglić G, Antić B, Manojlović D, Dojčinović B. Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation. in Materials Chemistry and Physics. 2021;273:125154.
doi:10.1016/j.matchemphys.2021.125154 .
Stanković, Dalibor M., Kukuruzar, Andrej, Savić, Slađana, Ognjanović, Miloš, Janković-Častvan, Ivona M., Roglić, Goran, Antić, Bratislav, Manojlović, Dragan, Dojčinović, Biljana, "Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation" in Materials Chemistry and Physics, 273 (2021):125154,
https://doi.org/10.1016/j.matchemphys.2021.125154 . .
1
3
2
3

Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water

Pergal, Marija; Avdin, Viacheslav V.; Manojlović, Dragan

(New York : Nova Science Publishers, Inc., 2021)

TY  - CHAP
AU  - Pergal, Marija
AU  - Avdin, Viacheslav V.
AU  - Manojlović, Dragan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5803
AB  - This chapter summarizes the reactivity, mechanism and toxicity assessment of pesticides and pharmaceuticals by chlorine dioxide (ClO2). ClO2 has been successfully employed as disinfectant in water treatment systems due to its antibacterial and antiviral characteristics. Also, ClO2
can be used as an alternative to chlorine, compared with which, it effectively reduces the amount of chlorinated products. As a powerful oxidant, ClO2 can remove effectively many organic and inorganic pollutants from water. Anthropogenic influences on groundwater (mining, industrial, agricultural and urbanization activities, and/or climate change) can affect water quality by production of different contaminants. The quality of surface water is critical because of the importance of raw water quality for all forms of life. Considering the increasing application
of ClO2 in water treatment, it is very important to investigate the reactions of ClO2 with the most extensively consumed pharmaceutical drugs and pesticides, which are regularly detected in surface water. Oxidative degradation via ClO2 of pharmaceutical contaminants and pesticides from water solutions is presented. Pollutants on which ClO2 has high or low degradation efficiency are highlighted. The recent developments on the effects of organic substances on pollutant degradation in surface water are addressed. Future trends in pollution degradation using ClO2 are also discussed.
PB  - New York : Nova Science Publishers, Inc.
T2  - Advances in Environmental Research
T1  - Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water
VL  - 81
SP  - 1
EP  - 87
UR  - https://hdl.handle.net/21.15107/rcub_cer_5803
ER  - 
@inbook{
author = "Pergal, Marija and Avdin, Viacheslav V. and Manojlović, Dragan",
year = "2021",
abstract = "This chapter summarizes the reactivity, mechanism and toxicity assessment of pesticides and pharmaceuticals by chlorine dioxide (ClO2). ClO2 has been successfully employed as disinfectant in water treatment systems due to its antibacterial and antiviral characteristics. Also, ClO2
can be used as an alternative to chlorine, compared with which, it effectively reduces the amount of chlorinated products. As a powerful oxidant, ClO2 can remove effectively many organic and inorganic pollutants from water. Anthropogenic influences on groundwater (mining, industrial, agricultural and urbanization activities, and/or climate change) can affect water quality by production of different contaminants. The quality of surface water is critical because of the importance of raw water quality for all forms of life. Considering the increasing application
of ClO2 in water treatment, it is very important to investigate the reactions of ClO2 with the most extensively consumed pharmaceutical drugs and pesticides, which are regularly detected in surface water. Oxidative degradation via ClO2 of pharmaceutical contaminants and pesticides from water solutions is presented. Pollutants on which ClO2 has high or low degradation efficiency are highlighted. The recent developments on the effects of organic substances on pollutant degradation in surface water are addressed. Future trends in pollution degradation using ClO2 are also discussed.",
publisher = "New York : Nova Science Publishers, Inc.",
journal = "Advances in Environmental Research",
booktitle = "Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water",
volume = "81",
pages = "1-87",
url = "https://hdl.handle.net/21.15107/rcub_cer_5803"
}
Pergal, M., Avdin, V. V.,& Manojlović, D.. (2021). Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water. in Advances in Environmental Research
New York : Nova Science Publishers, Inc.., 81, 1-87.
https://hdl.handle.net/21.15107/rcub_cer_5803
Pergal M, Avdin VV, Manojlović D. Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water. in Advances in Environmental Research. 2021;81:1-87.
https://hdl.handle.net/21.15107/rcub_cer_5803 .
Pergal, Marija, Avdin, Viacheslav V., Manojlović, Dragan, "Chlorine dioxide use to oxidate and remove pesticides and pharmaceuticals from water" in Advances in Environmental Research, 81 (2021):1-87,
https://hdl.handle.net/21.15107/rcub_cer_5803 .

Decolorisation of the textile dye using microbial fuel cells as an electricity source

Joksimović, Kristina; Kodranov, Igor; Žerađanin, Aleksandra; Randjelović, Danijela; Popović, Bogdan; Manojlović, Dragan; Nakano, Takeshi; Beškoski, Vladimir

(Japan Society for Environmental Chemistry, 2021)

TY  - CONF
AU  - Joksimović, Kristina
AU  - Kodranov, Igor
AU  - Žerađanin, Aleksandra
AU  - Randjelović, Danijela
AU  - Popović, Bogdan
AU  - Manojlović, Dragan
AU  - Nakano, Takeshi
AU  - Beškoski, Vladimir
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5071
AB  - Microbial fuel cells are increasingly used as alternative energy sources. The amount of electricity produced by MFC systems is sufficient to run systems that do not require high energy consumption, such as electrochemical decomposition of wastewater from the textile dye industry. The aim of this study was to analyze the voltage and current of two parallelly-connected MFC cells used for decolorisation of the wastewater that contained Reactive Black 5 (RB5) dye.
PB  - Japan Society for Environmental Chemistry
C3  - 29th Symposium on Environmental Chemistry, June 1.-3., 2021 (virtual), Osaca (Japan)
T1  - Decolorisation of the textile dye using microbial fuel cells as an electricity source
SP  - 275
UR  - https://hdl.handle.net/21.15107/rcub_cer_5071
ER  - 
@conference{
author = "Joksimović, Kristina and Kodranov, Igor and Žerađanin, Aleksandra and Randjelović, Danijela and Popović, Bogdan and Manojlović, Dragan and Nakano, Takeshi and Beškoski, Vladimir",
year = "2021",
abstract = "Microbial fuel cells are increasingly used as alternative energy sources. The amount of electricity produced by MFC systems is sufficient to run systems that do not require high energy consumption, such as electrochemical decomposition of wastewater from the textile dye industry. The aim of this study was to analyze the voltage and current of two parallelly-connected MFC cells used for decolorisation of the wastewater that contained Reactive Black 5 (RB5) dye.",
publisher = "Japan Society for Environmental Chemistry",
journal = "29th Symposium on Environmental Chemistry, June 1.-3., 2021 (virtual), Osaca (Japan)",
title = "Decolorisation of the textile dye using microbial fuel cells as an electricity source",
pages = "275",
url = "https://hdl.handle.net/21.15107/rcub_cer_5071"
}
Joksimović, K., Kodranov, I., Žerađanin, A., Randjelović, D., Popović, B., Manojlović, D., Nakano, T.,& Beškoski, V.. (2021). Decolorisation of the textile dye using microbial fuel cells as an electricity source. in 29th Symposium on Environmental Chemistry, June 1.-3., 2021 (virtual), Osaca (Japan)
Japan Society for Environmental Chemistry., 275.
https://hdl.handle.net/21.15107/rcub_cer_5071
Joksimović K, Kodranov I, Žerađanin A, Randjelović D, Popović B, Manojlović D, Nakano T, Beškoski V. Decolorisation of the textile dye using microbial fuel cells as an electricity source. in 29th Symposium on Environmental Chemistry, June 1.-3., 2021 (virtual), Osaca (Japan). 2021;:275.
https://hdl.handle.net/21.15107/rcub_cer_5071 .
Joksimović, Kristina, Kodranov, Igor, Žerađanin, Aleksandra, Randjelović, Danijela, Popović, Bogdan, Manojlović, Dragan, Nakano, Takeshi, Beškoski, Vladimir, "Decolorisation of the textile dye using microbial fuel cells as an electricity source" in 29th Symposium on Environmental Chemistry, June 1.-3., 2021 (virtual), Osaca (Japan) (2021):275,
https://hdl.handle.net/21.15107/rcub_cer_5071 .

Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida

Kodranov, Igor; Pergal, Marija; Krpić, Marko; Manojlović, Dragan

(Serbian Chemical Society, 2021)

TY  - CONF
AU  - Kodranov, Igor
AU  - Pergal, Marija
AU  - Krpić, Marko
AU  - Manojlović, Dragan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5824
AB  - Ibuprofen (IBP) zbog svoje giroke primene, velike konzumacije, relativno brzog metabolizma i eliminacije iz organizma, predstavlja potencionalni rizik po 2ivotnu sredinu. Hlor - dioksid, kao jako oksidaciono sredstvo, pokazao se kao dobar reagens za uklanjanje odredenih grupa pesticida iz hrane i vode, kao i za degradaciju odredenih lekova. Cilj ovog rada bio je da se ispita pod kojim uslovima i u kojoj meri hlor - dioksid mote da ukloni IBP u vodi. Ispitivana je degradacija IBP razlibitih koncentracija (10, 20, 35 i 60 mg/L) sa razli6itim koncentracijama hlor - dioksida (5, 10 i 15 mg/L) na pH vrednostima 3,00, 7,00 i 10,00 i pri razliditim rekcionim vremenima (0,5 h, 1 h, 2 h, 3 h, 6 h, 24 h). Rezultati HPLC - DAD analize su pokazali da je IBP mogude efikasno ukloniti iz vode. Najveda efikasnost degradacije od 99% postignuta je kada je koncentracija IBP u vodi bila 10 mg/L, a rastvor je bio tretiran sa 15 mg/L hlor - dioksida na pH 10,00 posle 24 h tretiranja hlor - dioksidom.
AB  - Due to ibuprofen (IBP) wide application, high consumption, relatively fast metabolism and elimination from the organism, it represents a potential risk for our environment. Chlorine dioxide, as a strong oxidizing agent, has been shown to be a good reagent for removing certain groups of pesticides from food and water, as well as for degradation of certain drugs. The aim of this study was to find optimal conditions for IBP removal from water using chlorine dioxide. Degradation of IBP of different concentrations (10, 20, 35 and 60 mg/L) with different concentrations of chlorine dioxide (5, 10 and 15 mg/L) at pH values of 3.00, 7.00 and 10.00 and at different reaction times (0.5 h, 1 h, 2 h, 3 h, 6 h, 24 h), was investigated. The results of HPLC - DAD analysis showed that IBP can be effectively removed from water. The highest degradation efficiency of 99% was achieved when the concentration of IBP in water was 10 mg/L, and the solution was treated with 15 mg/L of chlorine dioxide at pH 10.00 after 24 h of chlorine dioxide treatment.
PB  - Serbian Chemical Society
C3  - Kratki izvodi radova/ Knjiga radova - 57. Savetovanje Srpskog hemijskog društva, 18. i 19. juni 2021, Kragujevac / Book of Abstracts/Proceedings - 57th Meeting of  the Serbian Chemical Society, June 18-19, 2021, Kragujevac, Serbia
T1  - Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida
T1  - Optimization of conditions for degradation of ibuprofen using chlorine dioxide
SP  - 102
EP  - 106
UR  - https://hdl.handle.net/21.15107/rcub_cer_5824
ER  - 
@conference{
author = "Kodranov, Igor and Pergal, Marija and Krpić, Marko and Manojlović, Dragan",
year = "2021",
abstract = "Ibuprofen (IBP) zbog svoje giroke primene, velike konzumacije, relativno brzog metabolizma i eliminacije iz organizma, predstavlja potencionalni rizik po 2ivotnu sredinu. Hlor - dioksid, kao jako oksidaciono sredstvo, pokazao se kao dobar reagens za uklanjanje odredenih grupa pesticida iz hrane i vode, kao i za degradaciju odredenih lekova. Cilj ovog rada bio je da se ispita pod kojim uslovima i u kojoj meri hlor - dioksid mote da ukloni IBP u vodi. Ispitivana je degradacija IBP razlibitih koncentracija (10, 20, 35 i 60 mg/L) sa razli6itim koncentracijama hlor - dioksida (5, 10 i 15 mg/L) na pH vrednostima 3,00, 7,00 i 10,00 i pri razliditim rekcionim vremenima (0,5 h, 1 h, 2 h, 3 h, 6 h, 24 h). Rezultati HPLC - DAD analize su pokazali da je IBP mogude efikasno ukloniti iz vode. Najveda efikasnost degradacije od 99% postignuta je kada je koncentracija IBP u vodi bila 10 mg/L, a rastvor je bio tretiran sa 15 mg/L hlor - dioksida na pH 10,00 posle 24 h tretiranja hlor - dioksidom., Due to ibuprofen (IBP) wide application, high consumption, relatively fast metabolism and elimination from the organism, it represents a potential risk for our environment. Chlorine dioxide, as a strong oxidizing agent, has been shown to be a good reagent for removing certain groups of pesticides from food and water, as well as for degradation of certain drugs. The aim of this study was to find optimal conditions for IBP removal from water using chlorine dioxide. Degradation of IBP of different concentrations (10, 20, 35 and 60 mg/L) with different concentrations of chlorine dioxide (5, 10 and 15 mg/L) at pH values of 3.00, 7.00 and 10.00 and at different reaction times (0.5 h, 1 h, 2 h, 3 h, 6 h, 24 h), was investigated. The results of HPLC - DAD analysis showed that IBP can be effectively removed from water. The highest degradation efficiency of 99% was achieved when the concentration of IBP in water was 10 mg/L, and the solution was treated with 15 mg/L of chlorine dioxide at pH 10.00 after 24 h of chlorine dioxide treatment.",
publisher = "Serbian Chemical Society",
journal = "Kratki izvodi radova/ Knjiga radova - 57. Savetovanje Srpskog hemijskog društva, 18. i 19. juni 2021, Kragujevac / Book of Abstracts/Proceedings - 57th Meeting of  the Serbian Chemical Society, June 18-19, 2021, Kragujevac, Serbia",
title = "Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida, Optimization of conditions for degradation of ibuprofen using chlorine dioxide",
pages = "102-106",
url = "https://hdl.handle.net/21.15107/rcub_cer_5824"
}
Kodranov, I., Pergal, M., Krpić, M.,& Manojlović, D.. (2021). Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida. in Kratki izvodi radova/ Knjiga radova - 57. Savetovanje Srpskog hemijskog društva, 18. i 19. juni 2021, Kragujevac / Book of Abstracts/Proceedings - 57th Meeting of  the Serbian Chemical Society, June 18-19, 2021, Kragujevac, Serbia
Serbian Chemical Society., 102-106.
https://hdl.handle.net/21.15107/rcub_cer_5824
Kodranov I, Pergal M, Krpić M, Manojlović D. Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida. in Kratki izvodi radova/ Knjiga radova - 57. Savetovanje Srpskog hemijskog društva, 18. i 19. juni 2021, Kragujevac / Book of Abstracts/Proceedings - 57th Meeting of  the Serbian Chemical Society, June 18-19, 2021, Kragujevac, Serbia. 2021;:102-106.
https://hdl.handle.net/21.15107/rcub_cer_5824 .
Kodranov, Igor, Pergal, Marija, Krpić, Marko, Manojlović, Dragan, "Optimizacija uslova za degradaciju ibuprofena pomoću hlor-dioksida" in Kratki izvodi radova/ Knjiga radova - 57. Savetovanje Srpskog hemijskog društva, 18. i 19. juni 2021, Kragujevac / Book of Abstracts/Proceedings - 57th Meeting of  the Serbian Chemical Society, June 18-19, 2021, Kragujevac, Serbia (2021):102-106,
https://hdl.handle.net/21.15107/rcub_cer_5824 .

Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection

Đurđić, Slađana; Stanković, Vesna; Vlahović, Filip; Ognjanović, Miloš; Kalcher, Kurt; Manojlović, Dragan; Mutić, Jelena; Stanković, Dalibor M.

(Elsevier, 2021)

TY  - JOUR
AU  - Đurđić, Slađana
AU  - Stanković, Vesna
AU  - Vlahović, Filip
AU  - Ognjanović, Miloš
AU  - Kalcher, Kurt
AU  - Manojlović, Dragan
AU  - Mutić, Jelena
AU  - Stanković, Dalibor M.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4683
AB  - L-DOPA (L-3,4-dihydroxyphenylalanine), the precursor of dopamine, is widely used in the treatment of Parkinson’s disease, thus determining and monitoring the concentration of L-DOPA is of utmost importance for both medical and scientific purposes. Although many analytical approaches, designed for drug detection and quantification, already exist, there is a constant need for modification of old and tailoring of new, faster, and selective methods. Redox active chemical species, such as L-DOPA, can be measured directly by electrochemical means, whereas electrochemical sensors combine sensitivity and selectivity within a small analytical device. This work demonstrates the development of such electrochemical sensor, based on carboxylated single-wall carbon nanotubes (SWCNT-COOH) decorated with SiO2 coated-Nd2O3 nanoparticles, and further application for the detection of L-DOPA. Developed SWCNT-COOH@Nd2O3-SiO2 sensor shows linear response in the range from 2 µmol L−1 to 52 µmol L−1 analyte concentration, and beside the low detection limit, it is characterized by a fast response time, as well as good life-time, reproducibility and repeatability.
PB  - Elsevier
T2  - Microchemical Journal
T1  - Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection
VL  - 168
SP  - 106416
DO  - 10.1016/j.microc.2021.106416
ER  - 
@article{
author = "Đurđić, Slađana and Stanković, Vesna and Vlahović, Filip and Ognjanović, Miloš and Kalcher, Kurt and Manojlović, Dragan and Mutić, Jelena and Stanković, Dalibor M.",
year = "2021",
abstract = "L-DOPA (L-3,4-dihydroxyphenylalanine), the precursor of dopamine, is widely used in the treatment of Parkinson’s disease, thus determining and monitoring the concentration of L-DOPA is of utmost importance for both medical and scientific purposes. Although many analytical approaches, designed for drug detection and quantification, already exist, there is a constant need for modification of old and tailoring of new, faster, and selective methods. Redox active chemical species, such as L-DOPA, can be measured directly by electrochemical means, whereas electrochemical sensors combine sensitivity and selectivity within a small analytical device. This work demonstrates the development of such electrochemical sensor, based on carboxylated single-wall carbon nanotubes (SWCNT-COOH) decorated with SiO2 coated-Nd2O3 nanoparticles, and further application for the detection of L-DOPA. Developed SWCNT-COOH@Nd2O3-SiO2 sensor shows linear response in the range from 2 µmol L−1 to 52 µmol L−1 analyte concentration, and beside the low detection limit, it is characterized by a fast response time, as well as good life-time, reproducibility and repeatability.",
publisher = "Elsevier",
journal = "Microchemical Journal",
title = "Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection",
volume = "168",
pages = "106416",
doi = "10.1016/j.microc.2021.106416"
}
Đurđić, S., Stanković, V., Vlahović, F., Ognjanović, M., Kalcher, K., Manojlović, D., Mutić, J.,& Stanković, D. M.. (2021). Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection. in Microchemical Journal
Elsevier., 168, 106416.
https://doi.org/10.1016/j.microc.2021.106416
Đurđić S, Stanković V, Vlahović F, Ognjanović M, Kalcher K, Manojlović D, Mutić J, Stanković DM. Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection. in Microchemical Journal. 2021;168:106416.
doi:10.1016/j.microc.2021.106416 .
Đurđić, Slađana, Stanković, Vesna, Vlahović, Filip, Ognjanović, Miloš, Kalcher, Kurt, Manojlović, Dragan, Mutić, Jelena, Stanković, Dalibor M., "Carboxylated single-wall carbon nanotubes decorated with SiO2 coated-Nd2O3 nanoparticles as an electrochemical sensor for L-DOPA detection" in Microchemical Journal, 168 (2021):106416,
https://doi.org/10.1016/j.microc.2021.106416 . .
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Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites

Pergal, Marija; Brkljačić, Jelena; Tovilović-Kovačević, Gordana; Špírková, Milena; Kodranov, Igor; Manojlović, Dragan; Ostojić, Sanja; Knežević, Nikola Ž.

(Elsevier, 2021)

TY  - JOUR
AU  - Pergal, Marija
AU  - Brkljačić, Jelena
AU  - Tovilović-Kovačević, Gordana
AU  - Špírková, Milena
AU  - Kodranov, Igor
AU  - Manojlović, Dragan
AU  - Ostojić, Sanja
AU  - Knežević, Nikola Ž.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4016
AB  - Novel polyurethane nanocomposite (PUN) materials containing different surface-functionalized mesoporous silica nanoparticles (MSNs) were prepared by in situ polymerization methodology. Polyurethane network was formed from poly(dimethylsiloxane)-based macrodiol (PDMS), 4,4′-methylenediphenyldiisocyanate (MDI), and hyperbranched polyester of the second pseudo-generation (BH-20; used as crosslinking agent). PU and PU/MSN nanocomposites contained equal ratios of soft PDMS and hard MDI-BH-20 segments. Non-functionalized and surface-functionalized (with 3-(trihydroxysilyl)propyl methylphosphonate (FOMSN) and 2-[methoxy(polyethyleneoxy)6−9propyl]trimethoxysilane (PEGMSN)) MSNs were used as the nanofillers at a concentration of 1 wt%. Prepared materials were characterized by Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical thermal analyses (DMTA), nanoindentation, equilibrium swelling and water absorption measurements. Characteristics of the prepared PUNs when in contact with a biological environment were assessed through testing their biocompatibility, protein adsorption and adhesion of endothelial cells. The favourable influence of MSNs on the physico-chemical and biological characteristics of these novel PUN materials was identified, which evidences their vast applicability potential as coatings for medical devices and implants.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites
VL  - 151
SP  - 106049
DO  - 10.1016/j.porgcoat.2020.106049
ER  - 
@article{
author = "Pergal, Marija and Brkljačić, Jelena and Tovilović-Kovačević, Gordana and Špírková, Milena and Kodranov, Igor and Manojlović, Dragan and Ostojić, Sanja and Knežević, Nikola Ž.",
year = "2021",
abstract = "Novel polyurethane nanocomposite (PUN) materials containing different surface-functionalized mesoporous silica nanoparticles (MSNs) were prepared by in situ polymerization methodology. Polyurethane network was formed from poly(dimethylsiloxane)-based macrodiol (PDMS), 4,4′-methylenediphenyldiisocyanate (MDI), and hyperbranched polyester of the second pseudo-generation (BH-20; used as crosslinking agent). PU and PU/MSN nanocomposites contained equal ratios of soft PDMS and hard MDI-BH-20 segments. Non-functionalized and surface-functionalized (with 3-(trihydroxysilyl)propyl methylphosphonate (FOMSN) and 2-[methoxy(polyethyleneoxy)6−9propyl]trimethoxysilane (PEGMSN)) MSNs were used as the nanofillers at a concentration of 1 wt%. Prepared materials were characterized by Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical thermal analyses (DMTA), nanoindentation, equilibrium swelling and water absorption measurements. Characteristics of the prepared PUNs when in contact with a biological environment were assessed through testing their biocompatibility, protein adsorption and adhesion of endothelial cells. The favourable influence of MSNs on the physico-chemical and biological characteristics of these novel PUN materials was identified, which evidences their vast applicability potential as coatings for medical devices and implants.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites",
volume = "151",
pages = "106049",
doi = "10.1016/j.porgcoat.2020.106049"
}
Pergal, M., Brkljačić, J., Tovilović-Kovačević, G., Špírková, M., Kodranov, I., Manojlović, D., Ostojić, S.,& Knežević, N. Ž.. (2021). Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites. in Progress in Organic Coatings
Elsevier., 151, 106049.
https://doi.org/10.1016/j.porgcoat.2020.106049
Pergal M, Brkljačić J, Tovilović-Kovačević G, Špírková M, Kodranov I, Manojlović D, Ostojić S, Knežević NŽ. Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites. in Progress in Organic Coatings. 2021;151:106049.
doi:10.1016/j.porgcoat.2020.106049 .
Pergal, Marija, Brkljačić, Jelena, Tovilović-Kovačević, Gordana, Špírková, Milena, Kodranov, Igor, Manojlović, Dragan, Ostojić, Sanja, Knežević, Nikola Ž., "Effect of mesoporous silica nanoparticles on the properties of polyurethane network composites" in Progress in Organic Coatings, 151 (2021):106049,
https://doi.org/10.1016/j.porgcoat.2020.106049 . .
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Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis

Arsenijević, Dragana; Stojanović, Bojana; Milovanović, Jelena; Arsenijević, Aleksandar; Simić, Miloš; Pergal, Marija; Kodranov, Igor; Cvetković, Olga; Vojvodić, Danilo; Ristanović, Elizabeta; Manojlović, Dragan; Milovanović, Marija; Arsenijević, Nebojša

(MDPI, 2021)

TY  - JOUR
AU  - Arsenijević, Dragana
AU  - Stojanović, Bojana
AU  - Milovanović, Jelena
AU  - Arsenijević, Aleksandar
AU  - Simić, Miloš
AU  - Pergal, Marija
AU  - Kodranov, Igor
AU  - Cvetković, Olga
AU  - Vojvodić, Danilo
AU  - Ristanović, Elizabeta
AU  - Manojlović, Dragan
AU  - Milovanović, Marija
AU  - Arsenijević, Nebojša
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4835
AB  - The main biologically active components of plants belonging to the genus Allium, responsible for their biological activities, including anti-inflammatory, antioxidant and immunomodulatory, are organosulfur compounds. The aim of this study was to synthetize the mixture of dipropyl polysul-fides (DPPS) and to test their biological activity in acute hepatitis. C57BL/6 mice were administered orally with DPPS 6 h before intravenous injection of Concanavalin A (ConA). Liver inflammation, necrosis and hepatocytes apoptosis were determined by histological analyses. Cytokines in liver tissue were determined by ELISA, expression of adhesive molecules and enzymes by RT PCR, while liver mononuclear cells were analyzed by flow cytometry. DPPS pretreatment significantly attenuated liver inflammation and injury, as evidenced by biochemical and histopathological observations. In DPPS-pretreated mice, messenger RNA levels of adhesion molecules and NADPH oxidase complex were significantly reduced, while the expression of SOD enzymes was enhanced. DPPS pretreatment decreased protein level of inflammatory cytokines and increased percentage of T regulatory cells in the livers of ConA mice. DPPS showed hepatoprotective effects in ConA-induced hepatitis, charac-terized by attenuation of inflammation and affection of Th17/Treg balance in favor of T regulatory cells and implicating potential therapeutic usage of DPPS mixture in inflammatory liver diseases.
PB  - MDPI
T2  - Nutrients
T1  - Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis
VL  - 13
IS  - 3
SP  - 1
EP  - 15
DO  - 10.3390/nu13031022
ER  - 
@article{
author = "Arsenijević, Dragana and Stojanović, Bojana and Milovanović, Jelena and Arsenijević, Aleksandar and Simić, Miloš and Pergal, Marija and Kodranov, Igor and Cvetković, Olga and Vojvodić, Danilo and Ristanović, Elizabeta and Manojlović, Dragan and Milovanović, Marija and Arsenijević, Nebojša",
year = "2021",
abstract = "The main biologically active components of plants belonging to the genus Allium, responsible for their biological activities, including anti-inflammatory, antioxidant and immunomodulatory, are organosulfur compounds. The aim of this study was to synthetize the mixture of dipropyl polysul-fides (DPPS) and to test their biological activity in acute hepatitis. C57BL/6 mice were administered orally with DPPS 6 h before intravenous injection of Concanavalin A (ConA). Liver inflammation, necrosis and hepatocytes apoptosis were determined by histological analyses. Cytokines in liver tissue were determined by ELISA, expression of adhesive molecules and enzymes by RT PCR, while liver mononuclear cells were analyzed by flow cytometry. DPPS pretreatment significantly attenuated liver inflammation and injury, as evidenced by biochemical and histopathological observations. In DPPS-pretreated mice, messenger RNA levels of adhesion molecules and NADPH oxidase complex were significantly reduced, while the expression of SOD enzymes was enhanced. DPPS pretreatment decreased protein level of inflammatory cytokines and increased percentage of T regulatory cells in the livers of ConA mice. DPPS showed hepatoprotective effects in ConA-induced hepatitis, charac-terized by attenuation of inflammation and affection of Th17/Treg balance in favor of T regulatory cells and implicating potential therapeutic usage of DPPS mixture in inflammatory liver diseases.",
publisher = "MDPI",
journal = "Nutrients",
title = "Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis",
volume = "13",
number = "3",
pages = "1-15",
doi = "10.3390/nu13031022"
}
Arsenijević, D., Stojanović, B., Milovanović, J., Arsenijević, A., Simić, M., Pergal, M., Kodranov, I., Cvetković, O., Vojvodić, D., Ristanović, E., Manojlović, D., Milovanović, M.,& Arsenijević, N.. (2021). Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis. in Nutrients
MDPI., 13(3), 1-15.
https://doi.org/10.3390/nu13031022
Arsenijević D, Stojanović B, Milovanović J, Arsenijević A, Simić M, Pergal M, Kodranov I, Cvetković O, Vojvodić D, Ristanović E, Manojlović D, Milovanović M, Arsenijević N. Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis. in Nutrients. 2021;13(3):1-15.
doi:10.3390/nu13031022 .
Arsenijević, Dragana, Stojanović, Bojana, Milovanović, Jelena, Arsenijević, Aleksandar, Simić, Miloš, Pergal, Marija, Kodranov, Igor, Cvetković, Olga, Vojvodić, Danilo, Ristanović, Elizabeta, Manojlović, Dragan, Milovanović, Marija, Arsenijević, Nebojša, "Hepatoprotective effect of mixture of dipropyl polysulfides in concanavalin a-induced hepatitis" in Nutrients, 13, no. 3 (2021):1-15,
https://doi.org/10.3390/nu13031022 . .
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Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles

Anđelković, Ljubica; Jeremić, Dejan; Milenković, Milica R.; Radosavljević, Jelena; Vulić, Predrag; Pavlović, Vladimir B.; Manojlović, Dragan; Nikolić, Aleksandar S.

(Elsevier, 2020)

TY  - JOUR
AU  - Anđelković, Ljubica
AU  - Jeremić, Dejan
AU  - Milenković, Milica R.
AU  - Radosavljević, Jelena
AU  - Vulić, Predrag
AU  - Pavlović, Vladimir B.
AU  - Manojlović, Dragan
AU  - Nikolić, Aleksandar S.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3145
AB  - A simple organic-phase synthesis process was used to produce bare NiFe2O4 and ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 ferrite nanoparticles. X-ray powder diffractograms for all investigated powders show characteristic peaks of a spinel cubic structure without a secondary phase. Transmission electron microscopy (TEM) indicated the presence of nanoparticles that are smaller than 20 nm. The release of divalent ions (Ni2+ and Zn2+) from synthesized nanoparticles that were dispersed in saline solution, phosphate-buffered saline (PBS) and human serum, as determined by the inductively coupled plasma mass spectrometry (ICP-MS) method, was lower than 2 wt %. These results demonstrate the stability of the investigated nanoparticles in biologically relevant media and exclude the toxicity of Ni2+ and Zn2+ due to metal ion release, thereby opening a broad range of (bio)medical applications.
PB  - Elsevier
T2  - Ceramics International
T1  - Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles
VL  - 46
IS  - 3
SP  - 3528
EP  - 3533
DO  - 10.1016/j.ceramint.2019.10.068
ER  - 
@article{
author = "Anđelković, Ljubica and Jeremić, Dejan and Milenković, Milica R. and Radosavljević, Jelena and Vulić, Predrag and Pavlović, Vladimir B. and Manojlović, Dragan and Nikolić, Aleksandar S.",
year = "2020",
abstract = "A simple organic-phase synthesis process was used to produce bare NiFe2O4 and ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 ferrite nanoparticles. X-ray powder diffractograms for all investigated powders show characteristic peaks of a spinel cubic structure without a secondary phase. Transmission electron microscopy (TEM) indicated the presence of nanoparticles that are smaller than 20 nm. The release of divalent ions (Ni2+ and Zn2+) from synthesized nanoparticles that were dispersed in saline solution, phosphate-buffered saline (PBS) and human serum, as determined by the inductively coupled plasma mass spectrometry (ICP-MS) method, was lower than 2 wt %. These results demonstrate the stability of the investigated nanoparticles in biologically relevant media and exclude the toxicity of Ni2+ and Zn2+ due to metal ion release, thereby opening a broad range of (bio)medical applications.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles",
volume = "46",
number = "3",
pages = "3528-3533",
doi = "10.1016/j.ceramint.2019.10.068"
}
Anđelković, L., Jeremić, D., Milenković, M. R., Radosavljević, J., Vulić, P., Pavlović, V. B., Manojlović, D.,& Nikolić, A. S.. (2020). Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles. in Ceramics International
Elsevier., 46(3), 3528-3533.
https://doi.org/10.1016/j.ceramint.2019.10.068
Anđelković L, Jeremić D, Milenković MR, Radosavljević J, Vulić P, Pavlović VB, Manojlović D, Nikolić AS. Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles. in Ceramics International. 2020;46(3):3528-3533.
doi:10.1016/j.ceramint.2019.10.068 .
Anđelković, Ljubica, Jeremić, Dejan, Milenković, Milica R., Radosavljević, Jelena, Vulić, Predrag, Pavlović, Vladimir B., Manojlović, Dragan, Nikolić, Aleksandar S., "Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles" in Ceramics International, 46, no. 3 (2020):3528-3533,
https://doi.org/10.1016/j.ceramint.2019.10.068 . .
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