Matović, Luka

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orcid::0000-0003-4945-7776
  • Matović, Luka (6)
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Author's Bibliography

Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora

Milošević, Dragana; Matović, Luka; Ljubić, Verica; Perendija, Jovana; Cvetković, Slobodan

(Beograd : Savez inženjera i tehničara Srbije, 2023)

TY  - CONF
AU  - Milošević, Dragana
AU  - Matović, Luka
AU  - Ljubić, Verica
AU  - Perendija, Jovana
AU  - Cvetković, Slobodan
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6789
AB  - У овом раду, отпадна биомаса Аrundo donax (АД) је коришћена за адсорпцију Ni2+ из водених раствора. Површина АД је карактерисана СЕМ и ФТИР методама анализе. Адсорпциони експерименти су изведени у шаржним условима, при почетној pH вредности раствора pHi = 7 и различитим почетним концентрацијама Ni2+. Процес адсорпције је боље описан Фројндлиховим него Лангмировим моделом, односно адсорпција је вишеслојна са хетерогеном расподелом активних центара на површини материјала. Кинетика адсорпције Ni2+ на АД јe боље описана моделом псеудо–другог реда него моделом псеудо–првог реда, што указује на успостављање хемијских интеракција између адсорбата и слободних места на површини адсорбената. Добијени резултати су указали да АД има потенцијал за пречишћавање вода загађених никлом.
AB  - In this paper, Arundo donax (AD) waste biomass was used for the adsorption of Ni2+ from aqueous solutions. The AD surface was characterized by SEM and FT-IR analysis. Adsorption experiments were carried out in the batch adsorption system, at an initial pH value of pHi = 7 and different initial Ni2+ concentrations. The adsorption process was better described by Freundlich’s than by Langmuir’s model, i.e. adsorption is multilayered with a heterogeneous distribution of active sites on the material surface. The kinetic study of Ni2+ adsorption showed that pseudo–second order was the model that better described the experimental adsorption data compared to pseudo first order model, indicating the formation of chemical interactions between adsorbate and free sites on the adsorbent surface. The obtained results indicated that AD has the potential for the remediation of nickel-polluted waters.
PB  - Beograd : Savez inženjera i tehničara Srbije
C3  - Zbornik radova sa 44. Međunarodne konferencije Vodovod i kanalizacija '23, 10-13- oktobar 2023, Zlatibor
T1  - Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora
T1  - The possibility of using waste biomass (Arundo donax) for adsorption of Ni2+ from aqueous solutions
SP  - 243
EP  - 248
UR  - https://hdl.handle.net/21.15107/rcub_cer_6789
ER  - 
@conference{
author = "Milošević, Dragana and Matović, Luka and Ljubić, Verica and Perendija, Jovana and Cvetković, Slobodan",
year = "2023",
abstract = "У овом раду, отпадна биомаса Аrundo donax (АД) је коришћена за адсорпцију Ni2+ из водених раствора. Површина АД је карактерисана СЕМ и ФТИР методама анализе. Адсорпциони експерименти су изведени у шаржним условима, при почетној pH вредности раствора pHi = 7 и различитим почетним концентрацијама Ni2+. Процес адсорпције је боље описан Фројндлиховим него Лангмировим моделом, односно адсорпција је вишеслојна са хетерогеном расподелом активних центара на површини материјала. Кинетика адсорпције Ni2+ на АД јe боље описана моделом псеудо–другог реда него моделом псеудо–првог реда, што указује на успостављање хемијских интеракција између адсорбата и слободних места на површини адсорбената. Добијени резултати су указали да АД има потенцијал за пречишћавање вода загађених никлом., In this paper, Arundo donax (AD) waste biomass was used for the adsorption of Ni2+ from aqueous solutions. The AD surface was characterized by SEM and FT-IR analysis. Adsorption experiments were carried out in the batch adsorption system, at an initial pH value of pHi = 7 and different initial Ni2+ concentrations. The adsorption process was better described by Freundlich’s than by Langmuir’s model, i.e. adsorption is multilayered with a heterogeneous distribution of active sites on the material surface. The kinetic study of Ni2+ adsorption showed that pseudo–second order was the model that better described the experimental adsorption data compared to pseudo first order model, indicating the formation of chemical interactions between adsorbate and free sites on the adsorbent surface. The obtained results indicated that AD has the potential for the remediation of nickel-polluted waters.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Zbornik radova sa 44. Međunarodne konferencije Vodovod i kanalizacija '23, 10-13- oktobar 2023, Zlatibor",
title = "Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora, The possibility of using waste biomass (Arundo donax) for adsorption of Ni2+ from aqueous solutions",
pages = "243-248",
url = "https://hdl.handle.net/21.15107/rcub_cer_6789"
}
Milošević, D., Matović, L., Ljubić, V., Perendija, J.,& Cvetković, S.. (2023). Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora. in Zbornik radova sa 44. Međunarodne konferencije Vodovod i kanalizacija '23, 10-13- oktobar 2023, Zlatibor
Beograd : Savez inženjera i tehničara Srbije., 243-248.
https://hdl.handle.net/21.15107/rcub_cer_6789
Milošević D, Matović L, Ljubić V, Perendija J, Cvetković S. Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora. in Zbornik radova sa 44. Međunarodne konferencije Vodovod i kanalizacija '23, 10-13- oktobar 2023, Zlatibor. 2023;:243-248.
https://hdl.handle.net/21.15107/rcub_cer_6789 .
Milošević, Dragana, Matović, Luka, Ljubić, Verica, Perendija, Jovana, Cvetković, Slobodan, "Mogućnost primene otpadne biomase (Arundo donax) za adsorpciju Ni2+ iz vodenih rastvora" in Zbornik radova sa 44. Međunarodne konferencije Vodovod i kanalizacija '23, 10-13- oktobar 2023, Zlatibor (2023):243-248,
https://hdl.handle.net/21.15107/rcub_cer_6789 .

Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone

Lazić, Anita; Lađarević, Jelena; Mašulović, Aleksandra; Gak Simić, Kristina; Matović, Luka; Đorđević, Ivana; Trišović, Nemanja

(Szeged : University of Szeged, 2023)

TY  - CONF
AU  - Lazić, Anita
AU  - Lađarević, Jelena
AU  - Mašulović, Aleksandra
AU  - Gak Simić, Kristina
AU  - Matović, Luka
AU  - Đorđević, Ivana
AU  - Trišović, Nemanja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7402
AB  - A convenient and efficient approach toward the synthesis of six 3-(4-substituted benzyl)-6,7-benzo-1,3-diazaspiro[4.5]decane-2,4-diones (1‒6) by Bucherer-Bergs reaction and further alkylation at position 3 of the hydantoin ring is reported. Further, their chemical structure was confirmed by melting points, elemental analysis, FT-IR, NMR and UV–Vis spectroscopic methods. To gain an insight into interactions which the investigated spirohydantoins establish with their environment, their absorption spectra were recorded in selected solvents of different polarity and the solvent effects on the UV-Vis absorption band positions, intensity and shape, were discussed. Substiuent effects on the solvatochromism of compounds 1−6 were analyzed using the Hammett's equation. Considering the broad applications of hydantoin derivatives, as well as the fact that their relative importance may increase in the future, results obtained in this study serve as a basis for further investigations.
PB  - Szeged : University of Szeged
C3  - Proceedings of the 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November 13-14, 2023
T1  - Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone
SP  - 202
EP  - 206
UR  - https://hdl.handle.net/21.15107/rcub_cer_7402
ER  - 
@conference{
author = "Lazić, Anita and Lađarević, Jelena and Mašulović, Aleksandra and Gak Simić, Kristina and Matović, Luka and Đorđević, Ivana and Trišović, Nemanja",
year = "2023",
abstract = "A convenient and efficient approach toward the synthesis of six 3-(4-substituted benzyl)-6,7-benzo-1,3-diazaspiro[4.5]decane-2,4-diones (1‒6) by Bucherer-Bergs reaction and further alkylation at position 3 of the hydantoin ring is reported. Further, their chemical structure was confirmed by melting points, elemental analysis, FT-IR, NMR and UV–Vis spectroscopic methods. To gain an insight into interactions which the investigated spirohydantoins establish with their environment, their absorption spectra were recorded in selected solvents of different polarity and the solvent effects on the UV-Vis absorption band positions, intensity and shape, were discussed. Substiuent effects on the solvatochromism of compounds 1−6 were analyzed using the Hammett's equation. Considering the broad applications of hydantoin derivatives, as well as the fact that their relative importance may increase in the future, results obtained in this study serve as a basis for further investigations.",
publisher = "Szeged : University of Szeged",
journal = "Proceedings of the 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November 13-14, 2023",
title = "Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone",
pages = "202-206",
url = "https://hdl.handle.net/21.15107/rcub_cer_7402"
}
Lazić, A., Lađarević, J., Mašulović, A., Gak Simić, K., Matović, L., Đorđević, I.,& Trišović, N.. (2023). Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone. in Proceedings of the 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November 13-14, 2023
Szeged : University of Szeged., 202-206.
https://hdl.handle.net/21.15107/rcub_cer_7402
Lazić A, Lađarević J, Mašulović A, Gak Simić K, Matović L, Đorđević I, Trišović N. Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone. in Proceedings of the 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November 13-14, 2023. 2023;:202-206.
https://hdl.handle.net/21.15107/rcub_cer_7402 .
Lazić, Anita, Lađarević, Jelena, Mašulović, Aleksandra, Gak Simić, Kristina, Matović, Luka, Đorđević, Ivana, Trišović, Nemanja, "Evaluation of solvent and substituent effects on absorption spectra of spirohydantoins derived from alfa-tetralone" in Proceedings of the 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November 13-14, 2023 (2023):202-206,
https://hdl.handle.net/21.15107/rcub_cer_7402 .

Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells

Matović, Luka; Trišović, Nemanja; Lađarević, Jelena; Vitnik, Vesna; Vitnik, Željko; Yavuz, Cagdas; Sen, Burak; Yasir, Albashir; Ela, Sule Erten; Mijin, Dušan

(Elsevier, 2023)

TY  - JOUR
AU  - Matović, Luka
AU  - Trišović, Nemanja
AU  - Lađarević, Jelena
AU  - Vitnik, Vesna
AU  - Vitnik, Željko
AU  - Yavuz, Cagdas
AU  - Sen, Burak
AU  - Yasir, Albashir
AU  - Ela, Sule Erten
AU  - Mijin, Dušan
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5385
AB  - Five novel D-π-A structured pyridinium based compounds, bearing different electron-donating units were synthesized, minutely characterized, and their solvatochromic and electronic properties were investigated. Subsequently, these compounds were added to a liquid electrolyte in order to enhance the photovoltaic performance of the N719-sensitized solar cell. It was demonstrated that the utilization of all compounds improved the conversion efficiency, compared to the reference solar cell comprised of plain liquid electrolyte. The photovoltaic performance of the fabricated DSSC depended of the electron-donating moiety of the synthesized compound. The highest photovoltaic conversion efficiency of 4.11% was obtained for DSSC with the compound bearing the 4-(N,N-dimethylamino)phenyl group.
PB  - Elsevier
T2  - Journal of Molecular Structure
T1  - Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells
VL  - 1274
SP  - 134433
DO  - 10.1016/j.molstruc.2022.134433
ER  - 
@article{
author = "Matović, Luka and Trišović, Nemanja and Lađarević, Jelena and Vitnik, Vesna and Vitnik, Željko and Yavuz, Cagdas and Sen, Burak and Yasir, Albashir and Ela, Sule Erten and Mijin, Dušan",
year = "2023",
abstract = "Five novel D-π-A structured pyridinium based compounds, bearing different electron-donating units were synthesized, minutely characterized, and their solvatochromic and electronic properties were investigated. Subsequently, these compounds were added to a liquid electrolyte in order to enhance the photovoltaic performance of the N719-sensitized solar cell. It was demonstrated that the utilization of all compounds improved the conversion efficiency, compared to the reference solar cell comprised of plain liquid electrolyte. The photovoltaic performance of the fabricated DSSC depended of the electron-donating moiety of the synthesized compound. The highest photovoltaic conversion efficiency of 4.11% was obtained for DSSC with the compound bearing the 4-(N,N-dimethylamino)phenyl group.",
publisher = "Elsevier",
journal = "Journal of Molecular Structure",
title = "Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells",
volume = "1274",
pages = "134433",
doi = "10.1016/j.molstruc.2022.134433"
}
Matović, L., Trišović, N., Lađarević, J., Vitnik, V., Vitnik, Ž., Yavuz, C., Sen, B., Yasir, A., Ela, S. E.,& Mijin, D.. (2023). Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells. in Journal of Molecular Structure
Elsevier., 1274, 134433.
https://doi.org/10.1016/j.molstruc.2022.134433
Matović L, Trišović N, Lađarević J, Vitnik V, Vitnik Ž, Yavuz C, Sen B, Yasir A, Ela SE, Mijin D. Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells. in Journal of Molecular Structure. 2023;1274:134433.
doi:10.1016/j.molstruc.2022.134433 .
Matović, Luka, Trišović, Nemanja, Lađarević, Jelena, Vitnik, Vesna, Vitnik, Željko, Yavuz, Cagdas, Sen, Burak, Yasir, Albashir, Ela, Sule Erten, Mijin, Dušan, "Synthesis of novel pyridinium based compounds and their possible application in dye-sensitized solar cells" in Journal of Molecular Structure, 1274 (2023):134433,
https://doi.org/10.1016/j.molstruc.2022.134433 . .
2
2

Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones

Lađarević, Jelena; Božić, Bojan; Vitnik, Vesna; Matović, Luka; Mijin, Dušan; Vitnik, Željko

(Elsevier, 2022)

TY  - JOUR
AU  - Lađarević, Jelena
AU  - Božić, Bojan
AU  - Vitnik, Vesna
AU  - Matović, Luka
AU  - Mijin, Dušan
AU  - Vitnik, Željko
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5277
AB  - In order to improve the performance of theoretical UV–Vis spectra predictions, a theoretical and experimental study of solvatochromic properties of ten azo pyridone dyes has been performed. For quantitative estimation of intermolecular solvent–solute interactions, a concept of the linear solvation energy relationships has been applied using Kamlet-Taft and Catalán models. Theoretical UV–Vis spectra for all dyes have been calculated using four TD-DFT methods in nine different solvents with the aim to define the most reliable model. Finally, new polylinear equations for more accurate theoretical prediction of UV–Vis maxima are developed using empirical Kamlet-Taft and Catalán solvent parameters as additive corrections for specific and nonspecific solvent–solute interactions.
PB  - Elsevier
T2  - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
T1  - Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones
VL  - 272
SP  - 120978
DO  - 10.1016/j.saa.2022.120978
ER  - 
@article{
author = "Lađarević, Jelena and Božić, Bojan and Vitnik, Vesna and Matović, Luka and Mijin, Dušan and Vitnik, Željko",
year = "2022",
abstract = "In order to improve the performance of theoretical UV–Vis spectra predictions, a theoretical and experimental study of solvatochromic properties of ten azo pyridone dyes has been performed. For quantitative estimation of intermolecular solvent–solute interactions, a concept of the linear solvation energy relationships has been applied using Kamlet-Taft and Catalán models. Theoretical UV–Vis spectra for all dyes have been calculated using four TD-DFT methods in nine different solvents with the aim to define the most reliable model. Finally, new polylinear equations for more accurate theoretical prediction of UV–Vis maxima are developed using empirical Kamlet-Taft and Catalán solvent parameters as additive corrections for specific and nonspecific solvent–solute interactions.",
publisher = "Elsevier",
journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",
title = "Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones",
volume = "272",
pages = "120978",
doi = "10.1016/j.saa.2022.120978"
}
Lađarević, J., Božić, B., Vitnik, V., Matović, L., Mijin, D.,& Vitnik, Ž.. (2022). Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones. in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Elsevier., 272, 120978.
https://doi.org/10.1016/j.saa.2022.120978
Lađarević J, Božić B, Vitnik V, Matović L, Mijin D, Vitnik Ž. Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones. in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022;272:120978.
doi:10.1016/j.saa.2022.120978 .
Lađarević, Jelena, Božić, Bojan, Vitnik, Vesna, Matović, Luka, Mijin, Dušan, Vitnik, Željko, "Improvement of theoretical UV–Vis spectra calculations by empirical solvatochromic parameters: Case study of 5-arylazo-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyridones" in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 272 (2022):120978,
https://doi.org/10.1016/j.saa.2022.120978 . .
2
2

On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells

Matović, Luka; Tasić, Nikola; Trišović, Nemanja; Lađarević, Jelena; Vitnik, Vesna; Vitnik, Željko; Grgur, Branimir N.; Mijin, Dušan

(The Scientific and Technological Research Council of Turkey (TÜBİTAK), 2019)

TY  - JOUR
AU  - Matović, Luka
AU  - Tasić, Nikola
AU  - Trišović, Nemanja
AU  - Lađarević, Jelena
AU  - Vitnik, Vesna
AU  - Vitnik, Željko
AU  - Grgur, Branimir N.
AU  - Mijin, Dušan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3242
PB  - The Scientific and Technological Research Council of Turkey  (TÜBİTAK)
T2  - Turkish Journal of Chemistry
T1  - On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells
VL  - 43
IS  - 4
SP  - 1183
EP  - 1203
DO  - 10.3906/kim-1903-76
ER  - 
@article{
author = "Matović, Luka and Tasić, Nikola and Trišović, Nemanja and Lađarević, Jelena and Vitnik, Vesna and Vitnik, Željko and Grgur, Branimir N. and Mijin, Dušan",
year = "2019",
publisher = "The Scientific and Technological Research Council of Turkey  (TÜBİTAK)",
journal = "Turkish Journal of Chemistry",
title = "On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells",
volume = "43",
number = "4",
pages = "1183-1203",
doi = "10.3906/kim-1903-76"
}
Matović, L., Tasić, N., Trišović, N., Lađarević, J., Vitnik, V., Vitnik, Ž., Grgur, B. N.,& Mijin, D.. (2019). On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells. in Turkish Journal of Chemistry
The Scientific and Technological Research Council of Turkey  (TÜBİTAK)., 43(4), 1183-1203.
https://doi.org/10.3906/kim-1903-76
Matović L, Tasić N, Trišović N, Lađarević J, Vitnik V, Vitnik Ž, Grgur BN, Mijin D. On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells. in Turkish Journal of Chemistry. 2019;43(4):1183-1203.
doi:10.3906/kim-1903-76 .
Matović, Luka, Tasić, Nikola, Trišović, Nemanja, Lađarević, Jelena, Vitnik, Vesna, Vitnik, Željko, Grgur, Branimir N., Mijin, Dušan, "On the azo dyes derived from benzoic and cinnamic acids used as photosensitizersin dye-sensitized solar cells" in Turkish Journal of Chemistry, 43, no. 4 (2019):1183-1203,
https://doi.org/10.3906/kim-1903-76 . .
13
5
12

Solvatochromism and quantum mechanical investigation of disazo pyridone dye

Mijin, Dušan; Božić, Bojan; Lađarević, Jelena; Matović, Luka; Ušćumlić, Gordana; Vitnik, Vesna; Vitnik, Željko

(Blackwell Publishing Ltd, 2018)

TY  - JOUR
AU  - Mijin, Dušan
AU  - Božić, Bojan
AU  - Lađarević, Jelena
AU  - Matović, Luka
AU  - Ušćumlić, Gordana
AU  - Vitnik, Vesna
AU  - Vitnik, Željko
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2412
AB  - Disazo pyridone dye, 4-methyl-2,6-dioxo-5-(2-(4-(phenyldiazenyl)phenyl)hydrazono)-1,2,5,6-tetrahydropyridine-3-carbonitrile, is synthesised and thoroughly characterised by a combination of experimental and computational approaches. Fourier Transform-infrared and nuclear magnetic resonance (NMR) spectra prove the existence of the hydrazone form in the solid state and in dimethyl sulphoxide, which is also supported by vibrational and NMR theoretical studies. Ultraviolet (UV) spectral properties, as well as solvatochromism in 19 solvents of different polarity, are investigated. In most of the solvents, the dye is solely present in the hydrazone form, whereas in certain solvents, an acid–base equilibrium exists. Excellent agreement between computational and experimental UV–visible data was established. Frontier Molecular Orbital analysis was performed and proved the existence of intramolecular charge transfer through the dye molecule. A molecular electrostatic potential surface was plotted over the optimised geometry to lighten the reactivity of the investigated molecule.
PB  - Blackwell Publishing Ltd
T2  - Coloration Technology
T1  - Solvatochromism and quantum mechanical investigation of disazo pyridone dye
VL  - 134
IS  - 6
SP  - 478
EP  - 490
DO  - 10.1111/cote.12369
ER  - 
@article{
author = "Mijin, Dušan and Božić, Bojan and Lađarević, Jelena and Matović, Luka and Ušćumlić, Gordana and Vitnik, Vesna and Vitnik, Željko",
year = "2018",
abstract = "Disazo pyridone dye, 4-methyl-2,6-dioxo-5-(2-(4-(phenyldiazenyl)phenyl)hydrazono)-1,2,5,6-tetrahydropyridine-3-carbonitrile, is synthesised and thoroughly characterised by a combination of experimental and computational approaches. Fourier Transform-infrared and nuclear magnetic resonance (NMR) spectra prove the existence of the hydrazone form in the solid state and in dimethyl sulphoxide, which is also supported by vibrational and NMR theoretical studies. Ultraviolet (UV) spectral properties, as well as solvatochromism in 19 solvents of different polarity, are investigated. In most of the solvents, the dye is solely present in the hydrazone form, whereas in certain solvents, an acid–base equilibrium exists. Excellent agreement between computational and experimental UV–visible data was established. Frontier Molecular Orbital analysis was performed and proved the existence of intramolecular charge transfer through the dye molecule. A molecular electrostatic potential surface was plotted over the optimised geometry to lighten the reactivity of the investigated molecule.",
publisher = "Blackwell Publishing Ltd",
journal = "Coloration Technology",
title = "Solvatochromism and quantum mechanical investigation of disazo pyridone dye",
volume = "134",
number = "6",
pages = "478-490",
doi = "10.1111/cote.12369"
}
Mijin, D., Božić, B., Lađarević, J., Matović, L., Ušćumlić, G., Vitnik, V.,& Vitnik, Ž.. (2018). Solvatochromism and quantum mechanical investigation of disazo pyridone dye. in Coloration Technology
Blackwell Publishing Ltd., 134(6), 478-490.
https://doi.org/10.1111/cote.12369
Mijin D, Božić B, Lađarević J, Matović L, Ušćumlić G, Vitnik V, Vitnik Ž. Solvatochromism and quantum mechanical investigation of disazo pyridone dye. in Coloration Technology. 2018;134(6):478-490.
doi:10.1111/cote.12369 .
Mijin, Dušan, Božić, Bojan, Lađarević, Jelena, Matović, Luka, Ušćumlić, Gordana, Vitnik, Vesna, Vitnik, Željko, "Solvatochromism and quantum mechanical investigation of disazo pyridone dye" in Coloration Technology, 134, no. 6 (2018):478-490,
https://doi.org/10.1111/cote.12369 . .
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