TY  - JOUR
AU  - Mališić, Vanja
AU  - Pezo, Milada L.
AU  - Jelić, Aleksandra
AU  - Patarić, Aleksandra
AU  - Putić, Slaviša
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7214
AB  - Poly(methyl methacrylate) (PMMA) has a broad spectrum of uses, especially in medical applications. The role of fine-grained alumina particles of PMMA composites was investigated in this study. The composites were based on PMMA modified with dimethyl itaconate (DMI) as a matrix and alumina particles (Al2O3) and alumina doped with iron (Al2O3-Fe) modified with
3-aminopropyl-trimethoxysilane (AM) and flax oil fatty acid methyl esters (biodiesel) as reinforcements. Three particle sizes were measured (~0.4, ~0.6 and ~1.2 μm). The highest thermal conductivity values were measured for the composite 5 wt.% Al2O3-Fe-AM. With the addition of 3 wt.% Al2O3-AM to the PMMA/DMI matrix, mechanical properties were improved (tensile strength, strain, and modulus of elasticity). An artificial neural network model based on the Broyden-Fletcher-Goldfarb-Shanno iterative algorithm was investigated for prediction of thermal conductivity and mechanical properties of the composites showing satisfactory results. This is relevant for applications for optimization of dental materials to produce dentures, which were exposed to variations in temperature during the application.
AB  - Poli (metil metakrilata) (PMMA) ima široku upotrebu, posebno u stomatologiji i medicini. Kompoziti su napravljeni od PMMA modifikovanog dimetil itakonatom (DMI) kao matrice. Kao pojačanje korišćene su čestice glinice (Al2O3) i glinice dopirane oksidom gvožđa (Al2O3-Fe) modifikovanim sa 3-aminopropiltrimetoksilanom (AM) i metil estrima masnih kiselina lanenog ulja (biodizel – BD). Prema merenjima toplotne provodljivosti, najveće vrednosti toplotne provodljivosti imao je kompozit sa česticama glinice 5 wt.% Al2O3-Fe-AM. Dodatkom modifikovanih čestica glinice u PMMA/DMI matricu, poboljšane su mehaničke osobine (zatezna čvrstoća, deformacija i modul elastičnosti). Razvijen je model veštačke neuronske mreže zasnovan na iterativnom algoritmu predloženom u literaturi (Broiden-Fletcher-Goldfarb-Shanno), za predviđanje toplotne provodljivosti i mehaničkih svojstava kompozita na bazi akrilata u kombinaciji sa česticama na bazi glinice, u zavisnosti od masenog udela čestica, i dodatka oksida gvožđa i modifikatora. Pokazano je da ovi matematički modeli mogu predvideti mehanička i termička svojstva kompozitnih materijala. Ovo je posebno relevantno za predviđanje toplotne provodljivosti materijala koji se koriste u stomatologiji za izradu proteza i koji su izloženi temperaturnim promenama tokom primene.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling
T1  - Predviđanje termičkih i mehaničkih svojstava kompozita na bazi akrilata  korišćenjem modela veštačke neuronske mreže
VL  - 77
IS  - 4
SP  - 293
EP  - 302
DO  - 10.2298/HEMIND230119029M
ER  - 

@article{
author = "Mališić, Vanja and Pezo, Milada L. and Jelić, Aleksandra and Patarić, Aleksandra and Putić, Slaviša",
year = "2023",
abstract = "Poly(methyl methacrylate) (PMMA) has a broad spectrum of uses, especially in medical applications. The role of fine-grained alumina particles of PMMA composites was investigated in this study. The composites were based on PMMA modified with dimethyl itaconate (DMI) as a matrix and alumina particles (Al2O3) and alumina doped with iron (Al2O3-Fe) modified with
3-aminopropyl-trimethoxysilane (AM) and flax oil fatty acid methyl esters (biodiesel) as reinforcements. Three particle sizes were measured (~0.4, ~0.6 and ~1.2 μm). The highest thermal conductivity values were measured for the composite 5 wt.% Al2O3-Fe-AM. With the addition of 3 wt.% Al2O3-AM to the PMMA/DMI matrix, mechanical properties were improved (tensile strength, strain, and modulus of elasticity). An artificial neural network model based on the Broyden-Fletcher-Goldfarb-Shanno iterative algorithm was investigated for prediction of thermal conductivity and mechanical properties of the composites showing satisfactory results. This is relevant for applications for optimization of dental materials to produce dentures, which were exposed to variations in temperature during the application., Poli (metil metakrilata) (PMMA) ima široku upotrebu, posebno u stomatologiji i medicini. Kompoziti su napravljeni od PMMA modifikovanog dimetil itakonatom (DMI) kao matrice. Kao pojačanje korišćene su čestice glinice (Al2O3) i glinice dopirane oksidom gvožđa (Al2O3-Fe) modifikovanim sa 3-aminopropiltrimetoksilanom (AM) i metil estrima masnih kiselina lanenog ulja (biodizel – BD). Prema merenjima toplotne provodljivosti, najveće vrednosti toplotne provodljivosti imao je kompozit sa česticama glinice 5 wt.% Al2O3-Fe-AM. Dodatkom modifikovanih čestica glinice u PMMA/DMI matricu, poboljšane su mehaničke osobine (zatezna čvrstoća, deformacija i modul elastičnosti). Razvijen je model veštačke neuronske mreže zasnovan na iterativnom algoritmu predloženom u literaturi (Broiden-Fletcher-Goldfarb-Shanno), za predviđanje toplotne provodljivosti i mehaničkih svojstava kompozita na bazi akrilata u kombinaciji sa česticama na bazi glinice, u zavisnosti od masenog udela čestica, i dodatka oksida gvožđa i modifikatora. Pokazano je da ovi matematički modeli mogu predvideti mehanička i termička svojstva kompozitnih materijala. Ovo je posebno relevantno za predviđanje toplotne provodljivosti materijala koji se koriste u stomatologiji za izradu proteza i koji su izloženi temperaturnim promenama tokom primene.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling, Predviđanje termičkih i mehaničkih svojstava kompozita na bazi akrilata  korišćenjem modela veštačke neuronske mreže",
volume = "77",
number = "4",
pages = "293-302",
doi = "10.2298/HEMIND230119029M"
}

Mališić, V., Pezo, M. L., Jelić, A., Patarić, A.,& Putić, S.. (2023). Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling. in Hemijska industrija
Association of Chemical Engineers of Serbia., 77(4), 293-302.
https://doi.org/10.2298/HEMIND230119029M

Mališić V, Pezo ML, Jelić A, Patarić A, Putić S. Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling. in Hemijska industrija. 2023;77(4):293-302.
doi:10.2298/HEMIND230119029M .

Mališić, Vanja, Pezo, Milada L., Jelić, Aleksandra, Patarić, Aleksandra, Putić, Slaviša, "Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling" in Hemijska industrija, 77, no. 4 (2023):293-302,
https://doi.org/10.2298/HEMIND230119029M . .

TY  - JOUR
AU  - Mališić, Vanja
AU  - Gajić, Vuk
AU  - Porobić, Slavica
AU  - Patarić, Aleksandra
AU  - Putić, Slaviša
AU  - Vujčić, Ivica
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10683
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7168
AB  - Polymethyl methacrylate (PMMA) is a polymer material widely used in dental applications due to its excellent biocompatibility, stable physicochemical properties, easy manipulation, and low cost. The combination of biocompatible polymers and ceramics has great potential for the development of materials in the dental industry with improved mechanical properties. The addition of Al2O3 nanoparticles to PMMA can significantly improve its compressive and flexural strengths and wear resistance. Since this material is used in dental applications, it requires a high degree of product sterility. This can easily be achieved with gamma radiation treatment. Gamma radiation not only ensures the sterility of the product but can also affects changes in numerous material properties. The aim of this paper is to determine the influence of different doses of gamma radiation on the microbiological purity and changes in the mechanical and thermal properties of the PMMA/Al2O3 composite as well as the microstructural and color changes. It was found that the dose of radiation of 25 kGy is sufficient for complete sterilization of the product. This radiation dose improves the mechanical properties of the material and thermal stability. On the other hand, the dose of 25 kGy does not affect the morphology of the exposed sample and has small effect on the color change.
T2  - Radiation Physics and Chemistry
T1  - The effect of gamma irradiation on the synthesis, microbiological sterility, and improvement of properties of PMMA-Al2O3 composite used in dental prosthesis manufacturing
VL  - 207
SP  - 110846
DO  - 10.1016/j.radphyschem.2023.110846
ER  - 

@article{
author = "Mališić, Vanja and Gajić, Vuk and Porobić, Slavica and Patarić, Aleksandra and Putić, Slaviša and Vujčić, Ivica",
year = "2023",
abstract = "Polymethyl methacrylate (PMMA) is a polymer material widely used in dental applications due to its excellent biocompatibility, stable physicochemical properties, easy manipulation, and low cost. The combination of biocompatible polymers and ceramics has great potential for the development of materials in the dental industry with improved mechanical properties. The addition of Al2O3 nanoparticles to PMMA can significantly improve its compressive and flexural strengths and wear resistance. Since this material is used in dental applications, it requires a high degree of product sterility. This can easily be achieved with gamma radiation treatment. Gamma radiation not only ensures the sterility of the product but can also affects changes in numerous material properties. The aim of this paper is to determine the influence of different doses of gamma radiation on the microbiological purity and changes in the mechanical and thermal properties of the PMMA/Al2O3 composite as well as the microstructural and color changes. It was found that the dose of radiation of 25 kGy is sufficient for complete sterilization of the product. This radiation dose improves the mechanical properties of the material and thermal stability. On the other hand, the dose of 25 kGy does not affect the morphology of the exposed sample and has small effect on the color change.",
journal = "Radiation Physics and Chemistry",
title = "The effect of gamma irradiation on the synthesis, microbiological sterility, and improvement of properties of PMMA-Al2O3 composite used in dental prosthesis manufacturing",
volume = "207",
pages = "110846",
doi = "10.1016/j.radphyschem.2023.110846"
}

Mališić, V., Gajić, V., Porobić, S., Patarić, A., Putić, S.,& Vujčić, I.. (2023). The effect of gamma irradiation on the synthesis, microbiological sterility, and improvement of properties of PMMA-Al2O3 composite used in dental prosthesis manufacturing. in Radiation Physics and Chemistry, 207, 110846.
https://doi.org/10.1016/j.radphyschem.2023.110846

Mališić V, Gajić V, Porobić S, Patarić A, Putić S, Vujčić I. The effect of gamma irradiation on the synthesis, microbiological sterility, and improvement of properties of PMMA-Al2O3 composite used in dental prosthesis manufacturing. in Radiation Physics and Chemistry. 2023;207:110846.
doi:10.1016/j.radphyschem.2023.110846 .

Mališić, Vanja, Gajić, Vuk, Porobić, Slavica, Patarić, Aleksandra, Putić, Slaviša, Vujčić, Ivica, "The effect of gamma irradiation on the synthesis, microbiological sterility, and improvement of properties of PMMA-Al2O3 composite used in dental prosthesis manufacturing" in Radiation Physics and Chemistry, 207 (2023):110846,
https://doi.org/10.1016/j.radphyschem.2023.110846 . .

TY  - JOUR
AU  - Jegdić, Bore
AU  - Bobić, Biljana
AU  - Pavlović, Miloš K.
AU  - Alil, Ana
AU  - Putić, Slaviša S.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1734
AB  - The effect of one-step and a new (short) two-step aging process on the resistance to stress corrosion cracking of an aluminum alloy 7000 series was investigated, using slow strain rate test and fracture mechanics method. The aging level in the tested alloy was evaluated by means of scanning electron microscopy and measurements of electrical resistivity. It was shown that the alloy after the new two-step aging is significantly more resistant to stress corrosion cracking. Values of tensile properties and fracture toughness are similar for both thermal states. Processes that take place at the crack tip have been considered. The effect of the testing solution temperature on the crack growth rate on the plateau was determined. Two values of the apparent activation energy were obtained. These values correspond to different processes that control crack growth rate on the plateau at higher and lower temperatures.
AB  - Ispitivan je uticaj jednostepenog i novog (kratkotrajnog) dvostepenog termičkog taloženja na otpornost prema naponskoj koroziji aluminijumske legure serije 7000, primenom metode male brzine deformacije i metode mehanike loma. Stepen starenja ispitivane legure je procenjen primenom skening elektronske mikroskopije i na osnovu merenja električne otpornosti. Pokazano je da je legura posle novog dvostepenog termičkog starenja znatno otpornija prema naponskoj koroziji. Vrednosti zateznih karakteristika i žilavosti loma su slične za oba termička stanja legure. Razmatrani su procesi koji se odvijaju na vrhu naponsko-korozione prsline. Određen je uticaj temperature rastvora za ispitivanje na brzinu rasta prsline na platou. Određene su dve vrednosti prividne energije aktivacije. Ove vrednosti odgovaraju različitim procesima koji kontrolišu brzinu rasta prsline na platou, na visokim i niskim temperaturama.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging
T1  - Otpornost aluminijumske legure serije 7000 prema naponskoj koroziji posle dvostepenog termičkog taloženja
VL  - 21
IS  - 2
SP  - 261
EP  - 268
DO  - 10.2298/CICEQ140324024J
ER  - 

@article{
author = "Jegdić, Bore and Bobić, Biljana and Pavlović, Miloš K. and Alil, Ana and Putić, Slaviša S.",
year = "2015",
abstract = "The effect of one-step and a new (short) two-step aging process on the resistance to stress corrosion cracking of an aluminum alloy 7000 series was investigated, using slow strain rate test and fracture mechanics method. The aging level in the tested alloy was evaluated by means of scanning electron microscopy and measurements of electrical resistivity. It was shown that the alloy after the new two-step aging is significantly more resistant to stress corrosion cracking. Values of tensile properties and fracture toughness are similar for both thermal states. Processes that take place at the crack tip have been considered. The effect of the testing solution temperature on the crack growth rate on the plateau was determined. Two values of the apparent activation energy were obtained. These values correspond to different processes that control crack growth rate on the plateau at higher and lower temperatures., Ispitivan je uticaj jednostepenog i novog (kratkotrajnog) dvostepenog termičkog taloženja na otpornost prema naponskoj koroziji aluminijumske legure serije 7000, primenom metode male brzine deformacije i metode mehanike loma. Stepen starenja ispitivane legure je procenjen primenom skening elektronske mikroskopije i na osnovu merenja električne otpornosti. Pokazano je da je legura posle novog dvostepenog termičkog starenja znatno otpornija prema naponskoj koroziji. Vrednosti zateznih karakteristika i žilavosti loma su slične za oba termička stanja legure. Razmatrani su procesi koji se odvijaju na vrhu naponsko-korozione prsline. Određen je uticaj temperature rastvora za ispitivanje na brzinu rasta prsline na platou. Određene su dve vrednosti prividne energije aktivacije. Ove vrednosti odgovaraju različitim procesima koji kontrolišu brzinu rasta prsline na platou, na visokim i niskim temperaturama.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging, Otpornost aluminijumske legure serije 7000 prema naponskoj koroziji posle dvostepenog termičkog taloženja",
volume = "21",
number = "2",
pages = "261-268",
doi = "10.2298/CICEQ140324024J"
}

Jegdić, B., Bobić, B., Pavlović, M. K., Alil, A.,& Putić, S. S.. (2015). Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Association of the Chemical Engineers of Serbia., 21(2), 261-268.
https://doi.org/10.2298/CICEQ140324024J

Jegdić B, Bobić B, Pavlović MK, Alil A, Putić SS. Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2015;21(2):261-268.
doi:10.2298/CICEQ140324024J .

Jegdić, Bore, Bobić, Biljana, Pavlović, Miloš K., Alil, Ana, Putić, Slaviša S., "Stress corrosion cracking resistance of aluminum alloy 7000 series after two-step aging" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 21, no. 2 (2015):261-268,
https://doi.org/10.2298/CICEQ140324024J . .