Fidanovski, Bojana Z.

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  • Fidanovski, Bojana Z. (2)
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Author's Bibliography

Combustion of waste thermobaric explosive under controlled conditions as a source of energy

Bajić, Danica; Krstović, Mirjana; Timotijević, Mladen; Fidanovski, Bojana Z.; Alil, Ana

(Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), 2023)

TY  - CONF
AU  - Bajić, Danica
AU  - Krstović, Mirjana
AU  - Timotijević, Mladen
AU  - Fidanovski, Bojana Z.
AU  - Alil, Ana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6862
AB  - Thermobaric explosive mixtures are recently widely studied due to their specific energetic effects, 
especially regarding thermal output during the post-detonation combustion phase. Most of these 
mixtures contain as a very important component some metal powder fuel, which burns in contact 
with atmosphere oxygen or the oxidant component of the mixture after the initiation. This 
combustion process releases a large amount of thermal energy, which is recognized as a potential 
source of other types of energy if it were released and further transformed under controlled 
conditions. In this research, the possibility of controlled combustion of waste thermobaric 
explosives as a source of energy was considered. Thermobaric compositions containing aluminium, 
magnesium and boron powder were analysed. EXPLO5 software was used to calculate parameters 
of their isochoric and adiabatic combustion, to predict the potential thermal output of these 
mixtures. The selected compositions were experimentally examined in small samples by the method 
of calorimetry to determine their energetic potential during combustion in atmosphere of inert gas 
in a calorimetric bomb. The obtained results encourage further research into the possible 
applications of this thermal energy, which can be released not only in the reaction of a destructive 
explosion, but also by combustion under controlled conditions, as a quaternary recycling of waste 
explosives - a potential source of heat and electric energy.
AB  - Termobarične eksplozivne smeše su u poslednje vreme dosta proučavane zbog specifičnih 
energetskih efekata, posebno u pogledu toplotnog dejstva tokom faze post-detonacionog 
sagorevanja. Većina ovih smeša sadrži kao veoma važnu gorivnu komponentu neki metalni prah 
koji nakon iniciranja sagoreva u kontaktu sa atmosferskim kiseonikom ili oksidatorskom 
komponentom smeše. Ovaj proces sagorevanja oslobađa veliku količinu toplotne energije, koja je 
prepoznata kao potencijalni izvor drugih vidova energij ukoliko bi se oslobađala i dalje 
transformisala pod kontrolisanim uslovima. U ovom istraživanju razmotrena je mogućnost 
kontrolisanog sagorevanja otpadnog termobaričnog eksploziva kao izvora energije. Analizirane su 
termobarične smeše koje sadrže prah aluminijuma, magnezijuma i bora. Za izračunavanje 
parametara njihovog izohorskog i adijabatskog sagorevanja korišćen je softver EXPLO5, za 
predviđanje potencijalnog toplotnog efekta ovih smeša. Odabrani sastavi su eksperimentalno 
ispitani metodom kalorimetrije na malim uzorcima kako bi se utvrdio njihov energetski potencijal 
pri sagorevanju u atmosferi inertnog gasa u kalorimetrijskoj bombi. Dobijeni rezultati podstiču 
dalje istraživanje mogućih primena ove toplotne energije koja se može osloboditi ne samo u reakciji 
destruktivne eksplozije, već i kroy sagorevanje u kontrolisanim uslovima, kao kvaternernu reciklažu 
otpadnih eksploziva - potencijalni izvor toplotne odnosno električne energije.
PB  - Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)
C3  - Proceedings - 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia
T1  - Combustion of waste thermobaric explosive under controlled conditions as a source of energy
T1  - Sagorevanje otpadnog termobaričnog eksploziva pod kontrolisanim uslovima kao izvor energije
SP  - 351
EP  - 357
UR  - https://hdl.handle.net/21.15107/rcub_cer_6862
ER  - 
@conference{
author = "Bajić, Danica and Krstović, Mirjana and Timotijević, Mladen and Fidanovski, Bojana Z. and Alil, Ana",
year = "2023",
abstract = "Thermobaric explosive mixtures are recently widely studied due to their specific energetic effects, 
especially regarding thermal output during the post-detonation combustion phase. Most of these 
mixtures contain as a very important component some metal powder fuel, which burns in contact 
with atmosphere oxygen or the oxidant component of the mixture after the initiation. This 
combustion process releases a large amount of thermal energy, which is recognized as a potential 
source of other types of energy if it were released and further transformed under controlled 
conditions. In this research, the possibility of controlled combustion of waste thermobaric 
explosives as a source of energy was considered. Thermobaric compositions containing aluminium, 
magnesium and boron powder were analysed. EXPLO5 software was used to calculate parameters 
of their isochoric and adiabatic combustion, to predict the potential thermal output of these 
mixtures. The selected compositions were experimentally examined in small samples by the method 
of calorimetry to determine their energetic potential during combustion in atmosphere of inert gas 
in a calorimetric bomb. The obtained results encourage further research into the possible 
applications of this thermal energy, which can be released not only in the reaction of a destructive 
explosion, but also by combustion under controlled conditions, as a quaternary recycling of waste 
explosives - a potential source of heat and electric energy., Termobarične eksplozivne smeše su u poslednje vreme dosta proučavane zbog specifičnih 
energetskih efekata, posebno u pogledu toplotnog dejstva tokom faze post-detonacionog 
sagorevanja. Većina ovih smeša sadrži kao veoma važnu gorivnu komponentu neki metalni prah 
koji nakon iniciranja sagoreva u kontaktu sa atmosferskim kiseonikom ili oksidatorskom 
komponentom smeše. Ovaj proces sagorevanja oslobađa veliku količinu toplotne energije, koja je 
prepoznata kao potencijalni izvor drugih vidova energij ukoliko bi se oslobađala i dalje 
transformisala pod kontrolisanim uslovima. U ovom istraživanju razmotrena je mogućnost 
kontrolisanog sagorevanja otpadnog termobaričnog eksploziva kao izvora energije. Analizirane su 
termobarične smeše koje sadrže prah aluminijuma, magnezijuma i bora. Za izračunavanje 
parametara njihovog izohorskog i adijabatskog sagorevanja korišćen je softver EXPLO5, za 
predviđanje potencijalnog toplotnog efekta ovih smeša. Odabrani sastavi su eksperimentalno 
ispitani metodom kalorimetrije na malim uzorcima kako bi se utvrdio njihov energetski potencijal 
pri sagorevanju u atmosferi inertnog gasa u kalorimetrijskoj bombi. Dobijeni rezultati podstiču 
dalje istraživanje mogućih primena ove toplotne energije koja se može osloboditi ne samo u reakciji 
destruktivne eksplozije, već i kroy sagorevanje u kontrolisanim uslovima, kao kvaternernu reciklažu 
otpadnih eksploziva - potencijalni izvor toplotne odnosno električne energije.",
publisher = "Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)",
journal = "Proceedings - 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia",
title = "Combustion of waste thermobaric explosive under controlled conditions as a source of energy, Sagorevanje otpadnog termobaričnog eksploziva pod kontrolisanim uslovima kao izvor energije",
pages = "351-357",
url = "https://hdl.handle.net/21.15107/rcub_cer_6862"
}
Bajić, D., Krstović, M., Timotijević, M., Fidanovski, B. Z.,& Alil, A.. (2023). Combustion of waste thermobaric explosive under controlled conditions as a source of energy. in Proceedings - 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia
Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)., 351-357.
https://hdl.handle.net/21.15107/rcub_cer_6862
Bajić D, Krstović M, Timotijević M, Fidanovski BZ, Alil A. Combustion of waste thermobaric explosive under controlled conditions as a source of energy. in Proceedings - 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia. 2023;:351-357.
https://hdl.handle.net/21.15107/rcub_cer_6862 .
Bajić, Danica, Krstović, Mirjana, Timotijević, Mladen, Fidanovski, Bojana Z., Alil, Ana, "Combustion of waste thermobaric explosive under controlled conditions as a source of energy" in Proceedings - 11th International Conference on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia (2023):351-357,
https://hdl.handle.net/21.15107/rcub_cer_6862 .

Synthesis and characterization of fully bio-based unsaturated polyester resins

Fidanovski, Bojana Z.; Spasojević, Pavle; Panić, Vesna; Šešlija, Sanja; Spasojevic, Jelena P.; Popović, Ivanka G.

(Springer, 2018)

TY  - JOUR
AU  - Fidanovski, Bojana Z.
AU  - Spasojević, Pavle
AU  - Panić, Vesna
AU  - Šešlija, Sanja
AU  - Spasojevic, Jelena P.
AU  - Popović, Ivanka G.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2458
AB  - The sustainable tomorrow for future generations lies with the present industrial development toward the proper utilization of various bio-based products. For a transition to a higher level of sustainability, it is necessary to form a new platform for advanced technology products. This paper reports the development of new fully bio-based unsaturated polyesters resins (UPRs). A series of prepolymers were synthesized by varying saturated diacids (oxalic, succinic and adipic acid), itaconic acid and 1,2-propandiol. Dimethyl itaconate was used as a reactive diluent (RD) in amounts of 30, 35 and 40 wt%. Rheological measurements showed that the obtained resins possessed viscosities (234-2226 mPa s) amenable to a variety of liquid molding techniques. The impact of composition variables-prepolymer structure and amount of RD-on the chemical, mechanical and thermal properties of the thermosets was examined by DMA, TA and tensile measurements and was discussed in detail. The tensile properties (37-52 MPa), glass transition temperature (60-97 A degrees C) and coefficient of thermal expansion (71-168 10(-6) A degrees C-1) of the cured resins were in the desired range for UPRs. This investigation showed that UPRs based on itaconic acid can be tailored during synthesis of the prepolymer to meet the needs of different property profiles.
PB  - Springer
T2  - Journal of Materials Science
T1  - Synthesis and characterization of fully bio-based unsaturated polyester resins
VL  - 53
IS  - 6
SP  - 4635
EP  - 4644
DO  - 10.1007/s10853-017-1822-y
ER  - 
@article{
author = "Fidanovski, Bojana Z. and Spasojević, Pavle and Panić, Vesna and Šešlija, Sanja and Spasojevic, Jelena P. and Popović, Ivanka G.",
year = "2018",
abstract = "The sustainable tomorrow for future generations lies with the present industrial development toward the proper utilization of various bio-based products. For a transition to a higher level of sustainability, it is necessary to form a new platform for advanced technology products. This paper reports the development of new fully bio-based unsaturated polyesters resins (UPRs). A series of prepolymers were synthesized by varying saturated diacids (oxalic, succinic and adipic acid), itaconic acid and 1,2-propandiol. Dimethyl itaconate was used as a reactive diluent (RD) in amounts of 30, 35 and 40 wt%. Rheological measurements showed that the obtained resins possessed viscosities (234-2226 mPa s) amenable to a variety of liquid molding techniques. The impact of composition variables-prepolymer structure and amount of RD-on the chemical, mechanical and thermal properties of the thermosets was examined by DMA, TA and tensile measurements and was discussed in detail. The tensile properties (37-52 MPa), glass transition temperature (60-97 A degrees C) and coefficient of thermal expansion (71-168 10(-6) A degrees C-1) of the cured resins were in the desired range for UPRs. This investigation showed that UPRs based on itaconic acid can be tailored during synthesis of the prepolymer to meet the needs of different property profiles.",
publisher = "Springer",
journal = "Journal of Materials Science",
title = "Synthesis and characterization of fully bio-based unsaturated polyester resins",
volume = "53",
number = "6",
pages = "4635-4644",
doi = "10.1007/s10853-017-1822-y"
}
Fidanovski, B. Z., Spasojević, P., Panić, V., Šešlija, S., Spasojevic, J. P.,& Popović, I. G.. (2018). Synthesis and characterization of fully bio-based unsaturated polyester resins. in Journal of Materials Science
Springer., 53(6), 4635-4644.
https://doi.org/10.1007/s10853-017-1822-y
Fidanovski BZ, Spasojević P, Panić V, Šešlija S, Spasojevic JP, Popović IG. Synthesis and characterization of fully bio-based unsaturated polyester resins. in Journal of Materials Science. 2018;53(6):4635-4644.
doi:10.1007/s10853-017-1822-y .
Fidanovski, Bojana Z., Spasojević, Pavle, Panić, Vesna, Šešlija, Sanja, Spasojevic, Jelena P., Popović, Ivanka G., "Synthesis and characterization of fully bio-based unsaturated polyester resins" in Journal of Materials Science, 53, no. 6 (2018):4635-4644,
https://doi.org/10.1007/s10853-017-1822-y . .
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