Dinić, Zoran

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orcid::0000-0003-4109-4106
  • Dinić, Zoran (2)
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Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal

Malnar, Maja; Radojičić, Vesna; Kulić, Gordana; Dinić, Zoran; Cvetković, Olga

(Walter de Gruyter GmbH, 2023)

TY  - JOUR
AU  - Malnar, Maja
AU  - Radojičić, Vesna
AU  - Kulić, Gordana
AU  - Dinić, Zoran
AU  - Cvetković, Olga
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7224
AB  - As a tobacco producer, Serbia has to deal with large amounts of leftover tobacco stalks after harvesting. One option for this type of  biomass is to burn it, but burning is not encouraged in Serbia, since the levels of its combustion products have not been investigated yet.  The aim of this study was therefore to determine the elemental composition, ash and nicotine content, heat values, and composition of  gaseous combustion products of tobacco stalk briquettes and to see if their mixing with other types of biomass available in Serbia could  improve their ecological profile. We made 11 different types of briquettes: six of pure raw materials, including burley tobacco stalks,  sunflower head remains, wheat straw, corncob, soy straw, and beech sawdust and five by mixing tobacco stalks with these other raw materials  in a 50:50 mass ratio. All briquettes meet the ecological criteria regarding the emission limits for nitrogen oxides (NOx ), sulphur dioxide,  carbon monoxide, and carbon dioxide. Nicotine content in flue gases (<10 mg/kg) is far below the maximum level allowed by the European  Union. Heat values of all biomass samples are acceptable, although lower than those specified for solid biofuels (≥16.0 MJ/kg), save for  corncob and beech sawdust and their mixtures with tobacco stalks. Our findings therefore encourage the use of tobacco stalks as a viable  biofuel.
AB  - Kao proizvođač duhana, Srbija raspolaže velikim količinama stabljika duhana koje ostaju nakon berbe listova. Jedna je od opcija za ovu  vrstu biomase njezino izgaranje, ali se ono ne promiče u Srbiji jer još uvijek nisu istraženi njezini produkti izgaranja. Stoga je cilj ovog  istraživanja bio utvrditi elementarni sastav, sadržaj pepela i nikotina, ogrjevnu vrijednost i sastav plinovitih produkata pri izgaranju briketa  od duhanskih stabljika i ustanoviti može li njihovo miješanje s drugim vrstama biomase, koje su dostupne u Srbiji, poboljšati njihov ekološki  profil. Proizveli smo 11 različitih vrsta briketa: šest od čistih sirovina, uključujući stabljike berlej duhana, ostatke glava suncokreta, pšeničnu  slamu, kukuruzni oklasak, sojinu slamu i bukovu piljevinu, a pet od mješavina stabljike duhana s ostalim navedenim sirovinama u odnosu  50:50. Utvrđeno je da svi briketi ispunjavaju ekološke kriterije u pogledu ograničenja emisije dušikova oksida (NOx ), sumporova dioksida,  ugljikova monoksida i ugljikova dioksida. Sadržaj nikotina u dimnim plinovima (<10 mg/kg) znatno je ispod maksimalne vrijednosti koju  dopušta Europska unija. Prihvatljive su ogrjevne vrijednosti svih uzoraka biomase iako su ispod kriterija za specifikacije i klase čvrstih  biogoriva (≥16,0 MJ/kg), osim za kukuruzni oklasak i bukovu piljevinu, kao i njihove mješavine sa stabljikama duhana. Naši nalazi stoga  idu u prilog uporabi stabljika duhana kao održivoga biogoriva.
PB  - Walter de Gruyter GmbH
T2  - Archives of Industrial Hygiene and Toxicology
T1  - Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal
T1  - Energetska i emisijska svojstva briketa od stabljika berlej duhana i njihovih kombinacija sa drugom biomasom kao obećavajuća  zamjena za ugljen
VL  - 74
IS  - 1
SP  - 61
EP  - 68
DO  - 10.2478/aiht-2023-74-3630
ER  - 
@article{
author = "Malnar, Maja and Radojičić, Vesna and Kulić, Gordana and Dinić, Zoran and Cvetković, Olga",
year = "2023",
abstract = "As a tobacco producer, Serbia has to deal with large amounts of leftover tobacco stalks after harvesting. One option for this type of  biomass is to burn it, but burning is not encouraged in Serbia, since the levels of its combustion products have not been investigated yet.  The aim of this study was therefore to determine the elemental composition, ash and nicotine content, heat values, and composition of  gaseous combustion products of tobacco stalk briquettes and to see if their mixing with other types of biomass available in Serbia could  improve their ecological profile. We made 11 different types of briquettes: six of pure raw materials, including burley tobacco stalks,  sunflower head remains, wheat straw, corncob, soy straw, and beech sawdust and five by mixing tobacco stalks with these other raw materials  in a 50:50 mass ratio. All briquettes meet the ecological criteria regarding the emission limits for nitrogen oxides (NOx ), sulphur dioxide,  carbon monoxide, and carbon dioxide. Nicotine content in flue gases (<10 mg/kg) is far below the maximum level allowed by the European  Union. Heat values of all biomass samples are acceptable, although lower than those specified for solid biofuels (≥16.0 MJ/kg), save for  corncob and beech sawdust and their mixtures with tobacco stalks. Our findings therefore encourage the use of tobacco stalks as a viable  biofuel., Kao proizvođač duhana, Srbija raspolaže velikim količinama stabljika duhana koje ostaju nakon berbe listova. Jedna je od opcija za ovu  vrstu biomase njezino izgaranje, ali se ono ne promiče u Srbiji jer još uvijek nisu istraženi njezini produkti izgaranja. Stoga je cilj ovog  istraživanja bio utvrditi elementarni sastav, sadržaj pepela i nikotina, ogrjevnu vrijednost i sastav plinovitih produkata pri izgaranju briketa  od duhanskih stabljika i ustanoviti može li njihovo miješanje s drugim vrstama biomase, koje su dostupne u Srbiji, poboljšati njihov ekološki  profil. Proizveli smo 11 različitih vrsta briketa: šest od čistih sirovina, uključujući stabljike berlej duhana, ostatke glava suncokreta, pšeničnu  slamu, kukuruzni oklasak, sojinu slamu i bukovu piljevinu, a pet od mješavina stabljike duhana s ostalim navedenim sirovinama u odnosu  50:50. Utvrđeno je da svi briketi ispunjavaju ekološke kriterije u pogledu ograničenja emisije dušikova oksida (NOx ), sumporova dioksida,  ugljikova monoksida i ugljikova dioksida. Sadržaj nikotina u dimnim plinovima (<10 mg/kg) znatno je ispod maksimalne vrijednosti koju  dopušta Europska unija. Prihvatljive su ogrjevne vrijednosti svih uzoraka biomase iako su ispod kriterija za specifikacije i klase čvrstih  biogoriva (≥16,0 MJ/kg), osim za kukuruzni oklasak i bukovu piljevinu, kao i njihove mješavine sa stabljikama duhana. Naši nalazi stoga  idu u prilog uporabi stabljika duhana kao održivoga biogoriva.",
publisher = "Walter de Gruyter GmbH",
journal = "Archives of Industrial Hygiene and Toxicology",
title = "Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal, Energetska i emisijska svojstva briketa od stabljika berlej duhana i njihovih kombinacija sa drugom biomasom kao obećavajuća  zamjena za ugljen",
volume = "74",
number = "1",
pages = "61-68",
doi = "10.2478/aiht-2023-74-3630"
}
Malnar, M., Radojičić, V., Kulić, G., Dinić, Z.,& Cvetković, O.. (2023). Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal. in Archives of Industrial Hygiene and Toxicology
Walter de Gruyter GmbH., 74(1), 61-68.
https://doi.org/10.2478/aiht-2023-74-3630
Malnar M, Radojičić V, Kulić G, Dinić Z, Cvetković O. Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal. in Archives of Industrial Hygiene and Toxicology. 2023;74(1):61-68.
doi:10.2478/aiht-2023-74-3630 .
Malnar, Maja, Radojičić, Vesna, Kulić, Gordana, Dinić, Zoran, Cvetković, Olga, "Energy and emission properties of burley tobacco stalk briquettes and its combinations with other biomass as promising replacement for coal" in Archives of Industrial Hygiene and Toxicology, 74, no. 1 (2023):61-68,
https://doi.org/10.2478/aiht-2023-74-3630 . .
1
2
2

Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy

Cvetković, Olga; Pivić, Radmila; Dinić, Zoran; Maksimović, Jelena; Trifunović, Snežana; Dželetović, Željko

(Belgrade, Serbia : Engineering Society for Corrosion, 2016)

TY  - JOUR
AU  - Cvetković, Olga
AU  - Pivić, Radmila
AU  - Dinić, Zoran
AU  - Maksimović, Jelena
AU  - Trifunović, Snežana
AU  - Dželetović, Željko
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1866
AB  - According to scientific community and professional specialists, urging necessity to increase capacity of sources of energy can be partially achieved by using biomass as a raw material. This approach is justified by both economic and ecological reasons. In this paper the results of chemical study of the biomass Miscanthus × giganteus Greef et Deu. cultivated in the Republic of Serbia in the experimental field of the Institute for Application of Nuclear Energy in Zemun were presented. Study of an amount of ashes, elemental analysis of the biomass, and calorific value of the biomass (both higher and lower), which are critical parameters when estimating the quality of a biofuel, points out the possibility of utilization of the miscantus biomass as a fuel. Samples of the plant material for this study were collected during two harvesting periods: in the fall, when the biological yield is the highest, and at the end of the winter, when a highest quality biomass with respect to the combustion is obtained do to a decrease in moisture content and remobilization of the macro- and micronutrients from the above-ground parts of the plants to the rhizomes. Values of the studied parameters indicate that biomass meets the 'green' energy requirements because the amounts of oxides of nitrogen and sulphur in the combustion products would not threaten current quality of the environment and the amount of carbon dioxide produced would be consumed in the process of photosynthesis. Results of the chemical analyses strongly suggest to a high potential of utilization of the miscantus biomass as a biofuel (renewable source of energy) to generate thermal energy.
AB  - Delimičan odgovor stručne i naučne javnosti na pitanje kako povećati kapacitete energetskih izvora je upotreba biomase kao sirovine, kako iz ekonomskih, tako i iz ekoloških razloga. U ovom radu su prikazani rezultati fizičko-hemijskih ispitivanja biomase miskantusa (Miscanthus × giganteus Greef et Deu.), gajenog na teritoriji Republike Srbije, oglednom polju Instituta za primenu nuklearne energije, Zemun. Ispitivanjem količine pepela, elementarnog sastava biomase i kalorične vrednosti biomase (donje i gornje), koji su presudni za procenu kvaliteta biogoriva, ukazano je na mogućnost eksploatacije biomase miskantusa kao biogoriva. Prikupljanje uzoraka biljnog materijala za ovo istraživanje izvršeno je u dva žetvena roka: u jesen - vreme maksimuma biološkog prinosa i krajem zime, kada se dobija kvalitetnija biomasa za sagorevanje usled smanjenja sadržaja vlage i remobilizacije makro- i mikrohraniva iz nadzemnih delova rizoma. Vrednosti ispitivanih parametara pokazuju da biomasa ispunjava zahteve 'zelene' energije, jer produkti sagorevanja biomase svojom količinom (oksidi N i S) ne bi ugrožavali postojeći kvalitet životne sredine, a količina nastalog ugljenik (IV) - oksida ne bi predstavljala ekološki problem, jer bi se dalje uključila u proces fotosinteze. Rezultati hemijskih analiza argumentovano ukazuju na veliki potencijal upotrebe biomase miskantusa kao biogoriva (obnovljivog izvora energije) u proizvodnji toplotne energije.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy
T1  - Hemijska ispitivanja miskantusa gajenog u Srbiji - potencijalni obnovljiv izvor energije
VL  - 57
IS  - 3
SP  - 412
EP  - 417
DO  - 10.5937/ZasMat1603412C
ER  - 
@article{
author = "Cvetković, Olga and Pivić, Radmila and Dinić, Zoran and Maksimović, Jelena and Trifunović, Snežana and Dželetović, Željko",
year = "2016",
abstract = "According to scientific community and professional specialists, urging necessity to increase capacity of sources of energy can be partially achieved by using biomass as a raw material. This approach is justified by both economic and ecological reasons. In this paper the results of chemical study of the biomass Miscanthus × giganteus Greef et Deu. cultivated in the Republic of Serbia in the experimental field of the Institute for Application of Nuclear Energy in Zemun were presented. Study of an amount of ashes, elemental analysis of the biomass, and calorific value of the biomass (both higher and lower), which are critical parameters when estimating the quality of a biofuel, points out the possibility of utilization of the miscantus biomass as a fuel. Samples of the plant material for this study were collected during two harvesting periods: in the fall, when the biological yield is the highest, and at the end of the winter, when a highest quality biomass with respect to the combustion is obtained do to a decrease in moisture content and remobilization of the macro- and micronutrients from the above-ground parts of the plants to the rhizomes. Values of the studied parameters indicate that biomass meets the 'green' energy requirements because the amounts of oxides of nitrogen and sulphur in the combustion products would not threaten current quality of the environment and the amount of carbon dioxide produced would be consumed in the process of photosynthesis. Results of the chemical analyses strongly suggest to a high potential of utilization of the miscantus biomass as a biofuel (renewable source of energy) to generate thermal energy., Delimičan odgovor stručne i naučne javnosti na pitanje kako povećati kapacitete energetskih izvora je upotreba biomase kao sirovine, kako iz ekonomskih, tako i iz ekoloških razloga. U ovom radu su prikazani rezultati fizičko-hemijskih ispitivanja biomase miskantusa (Miscanthus × giganteus Greef et Deu.), gajenog na teritoriji Republike Srbije, oglednom polju Instituta za primenu nuklearne energije, Zemun. Ispitivanjem količine pepela, elementarnog sastava biomase i kalorične vrednosti biomase (donje i gornje), koji su presudni za procenu kvaliteta biogoriva, ukazano je na mogućnost eksploatacije biomase miskantusa kao biogoriva. Prikupljanje uzoraka biljnog materijala za ovo istraživanje izvršeno je u dva žetvena roka: u jesen - vreme maksimuma biološkog prinosa i krajem zime, kada se dobija kvalitetnija biomasa za sagorevanje usled smanjenja sadržaja vlage i remobilizacije makro- i mikrohraniva iz nadzemnih delova rizoma. Vrednosti ispitivanih parametara pokazuju da biomasa ispunjava zahteve 'zelene' energije, jer produkti sagorevanja biomase svojom količinom (oksidi N i S) ne bi ugrožavali postojeći kvalitet životne sredine, a količina nastalog ugljenik (IV) - oksida ne bi predstavljala ekološki problem, jer bi se dalje uključila u proces fotosinteze. Rezultati hemijskih analiza argumentovano ukazuju na veliki potencijal upotrebe biomase miskantusa kao biogoriva (obnovljivog izvora energije) u proizvodnji toplotne energije.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy, Hemijska ispitivanja miskantusa gajenog u Srbiji - potencijalni obnovljiv izvor energije",
volume = "57",
number = "3",
pages = "412-417",
doi = "10.5937/ZasMat1603412C"
}
Cvetković, O., Pivić, R., Dinić, Z., Maksimović, J., Trifunović, S.,& Dželetović, Ž.. (2016). Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 57(3), 412-417.
https://doi.org/10.5937/ZasMat1603412C
Cvetković O, Pivić R, Dinić Z, Maksimović J, Trifunović S, Dželetović Ž. Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy. in Zaštita materijala. 2016;57(3):412-417.
doi:10.5937/ZasMat1603412C .
Cvetković, Olga, Pivić, Radmila, Dinić, Zoran, Maksimović, Jelena, Trifunović, Snežana, Dželetović, Željko, "Chemical investigation of miscanthus × giganteus Greef et Deu. Cultivated in Serbia: A potential renewable source of energy" in Zaštita materijala, 57, no. 3 (2016):412-417,
https://doi.org/10.5937/ZasMat1603412C . .
1