TY  - DATA
AU  - Jevtović, Mima
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Radanović, Dušanka
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Mitić, Dragana
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6788
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7529
AB  - In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions.
AB  - 1.	Experimental section.
2.	Single crystal X-ray diffraction study.
3.	Computational details.
4.	Additional details
PB  - Elsevier
T2  - Inorganic Chemistry Communications
T1  - Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"
UR  - https://hdl.handle.net/21.15107/rcub_cer_7529
ER  - 

@misc{
author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina and Čobeljić, Božidar",
year = "2023",
abstract = "In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions., 1.	Experimental section.
2.	Single crystal X-ray diffraction study.
3.	Computational details.
4.	Additional details",
publisher = "Elsevier",
journal = "Inorganic Chemistry Communications",
title = "Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"",
url = "https://hdl.handle.net/21.15107/rcub_cer_7529"
}

Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K.,& Čobeljić, B.. (2023). Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey". in Inorganic Chemistry Communications
Elsevier..
https://hdl.handle.net/21.15107/rcub_cer_7529

Jevtović M, Pevec A, Turel I, Radanović D, Milčić M, Gruden M, Zlatar M, Mitić D, Anđelković K, Čobeljić B. Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey". in Inorganic Chemistry Communications. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_7529 .

Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"" in Inorganic Chemistry Communications (2023),
https://hdl.handle.net/21.15107/rcub_cer_7529 .

TY  - JOUR
AU  - Stojičkov, Marko
AU  - Zlatar, Matija
AU  - Mazzeo, Paolo Pio
AU  - Bacchi, Alessia
AU  - Radanović, Dušanka
AU  - Stevanović, Nevena
AU  - Jevtović, Mima
AU  - Novaković, Irena
AU  - Anđelković, Katarina
AU  - Sladić, Dušan
AU  - Čobeljić, Božidar
AU  - Gruden, Maja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6041
AB  - Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes.
PB  - Elsevier
T2  - Polyhedron
T1  - The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone
VL  - 237
SP  - 116389
DO  - 10.1016/j.poly.2023.116389
ER  - 

@article{
author = "Stojičkov, Marko and Zlatar, Matija and Mazzeo, Paolo Pio and Bacchi, Alessia and Radanović, Dušanka and Stevanović, Nevena and Jevtović, Mima and Novaković, Irena and Anđelković, Katarina and Sladić, Dušan and Čobeljić, Božidar and Gruden, Maja",
year = "2023",
abstract = "Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes.",
publisher = "Elsevier",
journal = "Polyhedron",
title = "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone",
volume = "237",
pages = "116389",
doi = "10.1016/j.poly.2023.116389"
}

Stojičkov, M., Zlatar, M., Mazzeo, P. P., Bacchi, A., Radanović, D., Stevanović, N., Jevtović, M., Novaković, I., Anđelković, K., Sladić, D., Čobeljić, B.,& Gruden, M.. (2023). The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone. in Polyhedron
Elsevier., 237, 116389.
https://doi.org/10.1016/j.poly.2023.116389

Stojičkov M, Zlatar M, Mazzeo PP, Bacchi A, Radanović D, Stevanović N, Jevtović M, Novaković I, Anđelković K, Sladić D, Čobeljić B, Gruden M. The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone. in Polyhedron. 2023;237:116389.
doi:10.1016/j.poly.2023.116389 .

Stojičkov, Marko, Zlatar, Matija, Mazzeo, Paolo Pio, Bacchi, Alessia, Radanović, Dušanka, Stevanović, Nevena, Jevtović, Mima, Novaković, Irena, Anđelković, Katarina, Sladić, Dušan, Čobeljić, Božidar, Gruden, Maja, "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone" in Polyhedron, 237 (2023):116389,
https://doi.org/10.1016/j.poly.2023.116389 . .

TY  - JOUR
AU  - Stojičkov, Marko
AU  - Zlatar, Matija
AU  - Mazzeo, Paolo Pio
AU  - Bacchi, Alessia
AU  - Radanović, Dušanka
AU  - Stevanović, Nevena
AU  - Jevtović, Mima
AU  - Novaković, Irena
AU  - Anđelković, Katarina
AU  - Sladić, Dušan
AU  - Čobeljić, Božidar
AU  - Gruden, Maja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6042
AB  - Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes.
PB  - Elsevier
T2  - Polyhedron
T1  - The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone
VL  - 237
SP  - 116389
DO  - 10.1016/j.poly.2023.116389
ER  - 

@article{
author = "Stojičkov, Marko and Zlatar, Matija and Mazzeo, Paolo Pio and Bacchi, Alessia and Radanović, Dušanka and Stevanović, Nevena and Jevtović, Mima and Novaković, Irena and Anđelković, Katarina and Sladić, Dušan and Čobeljić, Božidar and Gruden, Maja",
year = "2023",
abstract = "Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes.",
publisher = "Elsevier",
journal = "Polyhedron",
title = "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone",
volume = "237",
pages = "116389",
doi = "10.1016/j.poly.2023.116389"
}

Stojičkov, M., Zlatar, M., Mazzeo, P. P., Bacchi, A., Radanović, D., Stevanović, N., Jevtović, M., Novaković, I., Anđelković, K., Sladić, D., Čobeljić, B.,& Gruden, M.. (2023). The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone. in Polyhedron
Elsevier., 237, 116389.
https://doi.org/10.1016/j.poly.2023.116389

Stojičkov M, Zlatar M, Mazzeo PP, Bacchi A, Radanović D, Stevanović N, Jevtović M, Novaković I, Anđelković K, Sladić D, Čobeljić B, Gruden M. The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone. in Polyhedron. 2023;237:116389.
doi:10.1016/j.poly.2023.116389 .

Stojičkov, Marko, Zlatar, Matija, Mazzeo, Paolo Pio, Bacchi, Alessia, Radanović, Dušanka, Stevanović, Nevena, Jevtović, Mima, Novaković, Irena, Anđelković, Katarina, Sladić, Dušan, Čobeljić, Božidar, Gruden, Maja, "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone" in Polyhedron, 237 (2023):116389,
https://doi.org/10.1016/j.poly.2023.116389 . .

TY  - DATA
AU  - Stojičkov, Marko
AU  - Zlatar, Matija
AU  - Mazzeo, Paolo Pio
AU  - Bacchi, Alessia
AU  - Radanović, Dušanka
AU  - Stevanović, Nevena
AU  - Jevtović, Mima
AU  - Novaković, Irena
AU  - Anđelković, Katarina
AU  - Sladić, Dušan
AU  - Čobeljić, Božidar
AU  - Gruden, Maja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6043
AB  - Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes.
AB  - Additional crystallographic  and computational results, and the Cartesian coordinates of all DFT  optimized structures
PB  - Elsevier
T2  - Polyhedron
T1  - Electronic Supplementary Information (ESI) for: "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone"
UR  - https://hdl.handle.net/21.15107/rcub_cer_6043
ER  - 

@misc{
author = "Stojičkov, Marko and Zlatar, Matija and Mazzeo, Paolo Pio and Bacchi, Alessia and Radanović, Dušanka and Stevanović, Nevena and Jevtović, Mima and Novaković, Irena and Anđelković, Katarina and Sladić, Dušan and Čobeljić, Božidar and Gruden, Maja",
year = "2023",
abstract = "Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) have been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In both complexes, the thiosemicarbazone ligand is coordinated in deprotonated form through the NNS donor set of atoms. However, while Fe(III) complex is in the doublet ground state with distorted octahedral geometry, the coordination environment around Mn(II) is distorted trigonal-prismatic, and the sextet state is found to be the ground state. DFT calculations were performed to rationalize spin state preferences, and continuous shape measure describes the deviation from ideal six-coordinated polyhedral geometries in the ground and excited states. Antimicrobial activity (against a panel of Gram-negative and Gram-positive bacteria, two yeast, and one fungal strain), brine shrimp assay, and DPPH radical scavenging activity of both complexes were evaluated, and these results relate to the electronic structure of the complexes., Additional crystallographic  and computational results, and the Cartesian coordinates of all DFT  optimized structures",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Electronic Supplementary Information (ESI) for: "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone"",
url = "https://hdl.handle.net/21.15107/rcub_cer_6043"
}

Stojičkov, M., Zlatar, M., Mazzeo, P. P., Bacchi, A., Radanović, D., Stevanović, N., Jevtović, M., Novaković, I., Anđelković, K., Sladić, D., Čobeljić, B.,& Gruden, M.. (2023). Electronic Supplementary Information (ESI) for: "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone". in Polyhedron
Elsevier..
https://hdl.handle.net/21.15107/rcub_cer_6043

Stojičkov M, Zlatar M, Mazzeo PP, Bacchi A, Radanović D, Stevanović N, Jevtović M, Novaković I, Anđelković K, Sladić D, Čobeljić B, Gruden M. Electronic Supplementary Information (ESI) for: "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone". in Polyhedron. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6043 .

Stojičkov, Marko, Zlatar, Matija, Mazzeo, Paolo Pio, Bacchi, Alessia, Radanović, Dušanka, Stevanović, Nevena, Jevtović, Mima, Novaković, Irena, Anđelković, Katarina, Sladić, Dušan, Čobeljić, Božidar, Gruden, Maja, "Electronic Supplementary Information (ESI) for: "The interplay between spin states, geometries and biological activity of Fe(III) and Mn(II) complexes with thiosemicarbazone"" in Polyhedron (2023),
https://hdl.handle.net/21.15107/rcub_cer_6043 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Gruden, Maja
AU  - Zlatar, Matija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6570
AB  - Mn(II) and Fe(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole have been synthesized and characterized by single-crystal X-ray diffraction. Two complexes have the same ligand system – bis tridentate coordination of the thiosemicarbazone ligand through the NNS donor set of atoms. Furthermore, the central metal ions in both cases have the same d5
 electronic configuration. However, measured magnetism and analysis of the crystal geometries 
show that these two complexes have a different number of unpaired electrons. We 
rationalized the results by electronic structure calculations based on density functional 
theory. High-spin Mn(II) complex has trigonal-prismatic geometry with ionic metal-ligand bonding. Hund's rule of maximum multiplicity is responsible for its sextet spin-ground state. On the other hand, low-spin Fe(III) complex has octahedral coordination and strong metal-ligand covalency with delocalization of spin density toward ligands. Low-spin, doublet state is favored because of the nephelauxetic effect, i.e., smaller pairing energy in Fe(III) complex. Our results show that the difference in the electronic structure of the two complexes, i.e., different spin-ground states, directly affects these molecules' structure, magnetism, reactivity, and biological activities.
PB  - Viena, Austria : Institute of Applied Synthetic Chemistry, TU Wien
PB  - ChemIT e.U.
C3  - 6th EuChemS Inorganic  Chemistry Conference, September 3 – 7, 2023, Institute of Applied Synthetic Chemistry, TU Wien, Austria
T1  - Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone
SP  - PO-133
EP  - PO-133
UR  - https://hdl.handle.net/21.15107/rcub_cer_6570
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Gruden, Maja and Zlatar, Matija",
year = "2023",
abstract = "Mn(II) and Fe(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole have been synthesized and characterized by single-crystal X-ray diffraction. Two complexes have the same ligand system – bis tridentate coordination of the thiosemicarbazone ligand through the NNS donor set of atoms. Furthermore, the central metal ions in both cases have the same d5
 electronic configuration. However, measured magnetism and analysis of the crystal geometries 
show that these two complexes have a different number of unpaired electrons. We 
rationalized the results by electronic structure calculations based on density functional 
theory. High-spin Mn(II) complex has trigonal-prismatic geometry with ionic metal-ligand bonding. Hund's rule of maximum multiplicity is responsible for its sextet spin-ground state. On the other hand, low-spin Fe(III) complex has octahedral coordination and strong metal-ligand covalency with delocalization of spin density toward ligands. Low-spin, doublet state is favored because of the nephelauxetic effect, i.e., smaller pairing energy in Fe(III) complex. Our results show that the difference in the electronic structure of the two complexes, i.e., different spin-ground states, directly affects these molecules' structure, magnetism, reactivity, and biological activities.",
publisher = "Viena, Austria : Institute of Applied Synthetic Chemistry, TU Wien, ChemIT e.U.",
journal = "6th EuChemS Inorganic  Chemistry Conference, September 3 – 7, 2023, Institute of Applied Synthetic Chemistry, TU Wien, Austria",
title = "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone",
pages = "PO-133-PO-133",
url = "https://hdl.handle.net/21.15107/rcub_cer_6570"
}

Savić, M., Jevtović, M., Čobeljić, B., Gruden, M.,& Zlatar, M.. (2023). Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone. in 6th EuChemS Inorganic  Chemistry Conference, September 3 – 7, 2023, Institute of Applied Synthetic Chemistry, TU Wien, Austria
Viena, Austria : Institute of Applied Synthetic Chemistry, TU Wien., PO-133-PO-133.
https://hdl.handle.net/21.15107/rcub_cer_6570

Savić M, Jevtović M, Čobeljić B, Gruden M, Zlatar M. Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone. in 6th EuChemS Inorganic  Chemistry Conference, September 3 – 7, 2023, Institute of Applied Synthetic Chemistry, TU Wien, Austria. 2023;:PO-133-PO-133.
https://hdl.handle.net/21.15107/rcub_cer_6570 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Gruden, Maja, Zlatar, Matija, "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone" in 6th EuChemS Inorganic  Chemistry Conference, September 3 – 7, 2023, Institute of Applied Synthetic Chemistry, TU Wien, Austria (2023):PO-133-PO-133,
https://hdl.handle.net/21.15107/rcub_cer_6570 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Gruden, Maja
AU  - Zlatar, Matija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6572
AB  - Mn(II) and Fe(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole have been synthesized and characterized by single-crystal X-ray diffraction. Two complexes have the same ligand system – bis tridentate coordination of the thiosemicarbazone ligand through the NNS donor set of atoms. Furthermore, the central metal ions in both cases have the same d5 electronic configuration. However, measured magnetism and analysis of the crystal geometries show that these two complexes have a different number of unpaired electrons. We rationalized the results by electronic structure calculations based on density functional theory. High-spin Mn(II) complex has trigonal-prismatic geometry with ionic metal-ligand bonding. Hund's rule of maximum multiplicity is responsible for its sextet spin-ground state. On the other hand, low-spin Fe(III) complex has octahedral coordination and strong metal-ligand covalency with delocalization of spin density toward ligands. Low-spin, doublet state is favored because of the nephelauxetic effect, i.e., smaller pairing energy in Fe(III) complex. Our results show that the difference in the electronic structure of the two complexes, i.e., different spin-ground states, directly affects these molecules' structure, magnetism, reactivity, and biological activities.
PB  - TMMagCat Project
T1  - Poster presentation: "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone"
UR  - https://hdl.handle.net/21.15107/rcub_cer_6572
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Gruden, Maja and Zlatar, Matija",
year = "2023",
abstract = "Mn(II) and Fe(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole have been synthesized and characterized by single-crystal X-ray diffraction. Two complexes have the same ligand system – bis tridentate coordination of the thiosemicarbazone ligand through the NNS donor set of atoms. Furthermore, the central metal ions in both cases have the same d5 electronic configuration. However, measured magnetism and analysis of the crystal geometries show that these two complexes have a different number of unpaired electrons. We rationalized the results by electronic structure calculations based on density functional theory. High-spin Mn(II) complex has trigonal-prismatic geometry with ionic metal-ligand bonding. Hund's rule of maximum multiplicity is responsible for its sextet spin-ground state. On the other hand, low-spin Fe(III) complex has octahedral coordination and strong metal-ligand covalency with delocalization of spin density toward ligands. Low-spin, doublet state is favored because of the nephelauxetic effect, i.e., smaller pairing energy in Fe(III) complex. Our results show that the difference in the electronic structure of the two complexes, i.e., different spin-ground states, directly affects these molecules' structure, magnetism, reactivity, and biological activities.",
publisher = "TMMagCat Project",
title = "Poster presentation: "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone"",
url = "https://hdl.handle.net/21.15107/rcub_cer_6572"
}

Savić, M., Jevtović, M., Čobeljić, B., Gruden, M.,& Zlatar, M.. (2023). Poster presentation: "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone". 
TMMagCat Project..
https://hdl.handle.net/21.15107/rcub_cer_6572

Savić M, Jevtović M, Čobeljić B, Gruden M, Zlatar M. Poster presentation: "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone". 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6572 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Gruden, Maja, Zlatar, Matija, "Poster presentation: "Spin states of Mn(II) and Fe(III) complexes with thiosemicarbazone"" (2023),
https://hdl.handle.net/21.15107/rcub_cer_6572 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Zlatar, Matija
AU  - Gruden, Maja
AU  - Mitić, Dragana
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6608
AB  - The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand 
with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water 
mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The 
tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion 
through NNO set of donor atoms forming two five-membered chelate rings and the other three 
coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was 
characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was 
defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. 
DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.
PB  - Belgrade, Serbia : Materials Research Society of Serbia
C3  - Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program  and  Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro
T1  - Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent
SP  - 114
EP  - 114
UR  - https://hdl.handle.net/21.15107/rcub_cer_6608
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Zlatar, Matija and Gruden, Maja and Mitić, Dragana and Čobeljić, Božidar and Anđelković, Katarina",
year = "2023",
abstract = "The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand 
with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water 
mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The 
tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion 
through NNO set of donor atoms forming two five-membered chelate rings and the other three 
coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was 
characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was 
defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. 
DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.",
publisher = "Belgrade, Serbia : Materials Research Society of Serbia",
journal = "Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program  and  Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro",
title = "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent",
pages = "114-114",
url = "https://hdl.handle.net/21.15107/rcub_cer_6608"
}

Savić, M., Jevtović, M., Zlatar, M., Gruden, M., Mitić, D., Čobeljić, B.,& Anđelković, K.. (2023). Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program  and  Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro
Belgrade, Serbia : Materials Research Society of Serbia., 114-114.
https://hdl.handle.net/21.15107/rcub_cer_6608

Savić M, Jevtović M, Zlatar M, Gruden M, Mitić D, Čobeljić B, Anđelković K. Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program  and  Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro. 2023;:114-114.
https://hdl.handle.net/21.15107/rcub_cer_6608 .

Savić, Milica, Jevtović, Mima, Zlatar, Matija, Gruden, Maja, Mitić, Dragana, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent" in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program  and  Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro (2023):114-114,
https://hdl.handle.net/21.15107/rcub_cer_6608 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Zlatar, Matija
AU  - Gruden, Maja
AU  - Mitić, Dragana
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6609
AB  - The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.
PB  - Belgrade, Serbia : Materials Research Society of Serbia
T1  - Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"
UR  - https://hdl.handle.net/21.15107/rcub_cer_6609
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Zlatar, Matija and Gruden, Maja and Mitić, Dragana and Čobeljić, Božidar and Anđelković, Katarina",
year = "2023",
abstract = "The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.",
publisher = "Belgrade, Serbia : Materials Research Society of Serbia",
title = "Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"",
url = "https://hdl.handle.net/21.15107/rcub_cer_6609"
}

Savić, M., Jevtović, M., Zlatar, M., Gruden, M., Mitić, D., Čobeljić, B.,& Anđelković, K.. (2023). Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent". 
Belgrade, Serbia : Materials Research Society of Serbia..
https://hdl.handle.net/21.15107/rcub_cer_6609

Savić M, Jevtović M, Zlatar M, Gruden M, Mitić D, Čobeljić B, Anđelković K. Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent". 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6609 .

Savić, Milica, Jevtović, Mima, Zlatar, Matija, Gruden, Maja, Mitić, Dragana, Čobeljić, Božidar, Anđelković, Katarina, "Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"" (2023),
https://hdl.handle.net/21.15107/rcub_cer_6609 .

TY  - JOUR
AU  - Jevtović, Mima
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Radanović, Dušanka
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Mitić, Dragana
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6766
AB  - In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions.
PB  - Elsevier
T2  - Inorganic Chemistry Communications
T1  - Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey
VL  - 158
SP  - 111582
DO  - 10.1016/j.inoche.2023.111582
ER  - 

@article{
author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina and Čobeljić, Božidar",
year = "2023",
abstract = "In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions.",
publisher = "Elsevier",
journal = "Inorganic Chemistry Communications",
title = "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey",
volume = "158",
pages = "111582",
doi = "10.1016/j.inoche.2023.111582"
}

Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K.,& Čobeljić, B.. (2023). Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications
Elsevier., 158, 111582.
https://doi.org/10.1016/j.inoche.2023.111582

Jevtović M, Pevec A, Turel I, Radanović D, Milčić M, Gruden M, Zlatar M, Mitić D, Anđelković K, Čobeljić B. Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications. 2023;158:111582.
doi:10.1016/j.inoche.2023.111582 .

Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" in Inorganic Chemistry Communications, 158 (2023):111582,
https://doi.org/10.1016/j.inoche.2023.111582 . .

TY  - JOUR
AU  - Jevtović, Mima
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Radanović, Dušanka
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Mitić, Dragana
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6788
AB  - In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions.
PB  - Elsevier
T2  - Inorganic Chemistry Communications
T1  - Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey
VL  - 158
SP  - 111582
DO  - 10.1016/j.inoche.2023.111582
ER  - 

@article{
author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina and Čobeljić, Božidar",
year = "2023",
abstract = "In this paper, we report the  synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex,  [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex,  [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor  set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient  conditions.",
publisher = "Elsevier",
journal = "Inorganic Chemistry Communications",
title = "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey",
volume = "158",
pages = "111582",
doi = "10.1016/j.inoche.2023.111582"
}

Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K.,& Čobeljić, B.. (2023). Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications
Elsevier., 158, 111582.
https://doi.org/10.1016/j.inoche.2023.111582

Jevtović M, Pevec A, Turel I, Radanović D, Milčić M, Gruden M, Zlatar M, Mitić D, Anđelković K, Čobeljić B. Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications. 2023;158:111582.
doi:10.1016/j.inoche.2023.111582 .

Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" in Inorganic Chemistry Communications, 158 (2023):111582,
https://doi.org/10.1016/j.inoche.2023.111582 . .

TY  - CONF
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Zlatar, Matija
AU  - Savić, Milica
AU  - Jevtović, Mima
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6305
AB  - The ligand (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide (HL) was obtained from the condensation of 2-acetylthiazole and thiosemicarbazide.  Upon reacting HL with Zn(BF4)2.6H20 and NaN3 in a solvent mixture of water/methanol, mononuclear Zn(II) complex 1 with the composition [ZnL(N3)2] was obtained.  Complex 1 crystallises in the monoclinic crystal system with space group No.14 (P21/c cell setting).  The unit cell of 1 contains four [ZnL(N3)2] asymmetric units. The Zn(II) site shows a distorted pentacoordinated geometry,  almost midway between the square pyramid and trigonal bipyramid.
AB  - Кондензационом реакцијом 2-адетилтиазола и тиосемикарбазида добијен је лиганд (Е)-2(1-(тиазол-2-ил)етилендиен)хидразин-1-карботиоамид (HL).  Комплекс 1 опште формуле [ZnL(N3)2] добијен је у реакцији лиrанда са Zn(BF4)2.6H20 и NaN3, у смеши меrанол/вода.  Из података рендreнтске сlруктурне анализе утврђено је да комплекс кристалише у моноклиничном кристапном систему просторне трупе Р21lс.  Јединична ћелија комплекса 1 састоји се од четири асиметричне [ZnL(N3)] јединице. Геометрија око пентакоординованог Zп(II) је искривљена,  између квадратнo-пирамидaлне и тригонanно-бипирамидaлне геометрије.
PB  - Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo
C3  - 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
T1  - Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylthiazole and thiosemicarbazide
T1  - Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида
SP  - 34
EP  - 35
UR  - https://hdl.handle.net/21.15107/rcub_cer_6305
ER  - 

@conference{
author = "Čobeljić, Božidar and Pevec, Andrej and Zlatar, Matija and Savić, Milica and Jevtović, Mima",
year = "2023",
abstract = "The ligand (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide (HL) was obtained from the condensation of 2-acetylthiazole and thiosemicarbazide.  Upon reacting HL with Zn(BF4)2.6H20 and NaN3 in a solvent mixture of water/methanol, mononuclear Zn(II) complex 1 with the composition [ZnL(N3)2] was obtained.  Complex 1 crystallises in the monoclinic crystal system with space group No.14 (P21/c cell setting).  The unit cell of 1 contains four [ZnL(N3)2] asymmetric units. The Zn(II) site shows a distorted pentacoordinated geometry,  almost midway between the square pyramid and trigonal bipyramid., Кондензационом реакцијом 2-адетилтиазола и тиосемикарбазида добијен је лиганд (Е)-2(1-(тиазол-2-ил)етилендиен)хидразин-1-карботиоамид (HL).  Комплекс 1 опште формуле [ZnL(N3)2] добијен је у реакцији лиrанда са Zn(BF4)2.6H20 и NaN3, у смеши меrанол/вода.  Из података рендreнтске сlруктурне анализе утврђено је да комплекс кристалише у моноклиничном кристапном систему просторне трупе Р21lс.  Јединична ћелија комплекса 1 састоји се од четири асиметричне [ZnL(N3)] јединице. Геометрија око пентакоординованог Zп(II) је искривљена,  између квадратнo-пирамидaлне и тригонanно-бипирамидaлне геометрије.",
publisher = "Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo",
journal = "28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova",
title = "Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylthiazole and thiosemicarbazide, Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида",
pages = "34-35",
url = "https://hdl.handle.net/21.15107/rcub_cer_6305"
}

Čobeljić, B., Pevec, A., Zlatar, M., Savić, M.,& Jevtović, M.. (2023). Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylthiazole and thiosemicarbazide. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo., 34-35.
https://hdl.handle.net/21.15107/rcub_cer_6305

Čobeljić B, Pevec A, Zlatar M, Savić M, Jevtović M. Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylthiazole and thiosemicarbazide. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova. 2023;:34-35.
https://hdl.handle.net/21.15107/rcub_cer_6305 .

Čobeljić, Božidar, Pevec, Andrej, Zlatar, Matija, Savić, Milica, Jevtović, Mima, "Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylthiazole and thiosemicarbazide" in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova (2023):34-35,
https://hdl.handle.net/21.15107/rcub_cer_6305 .

TY  - CONF
AU  - Anđelković, Katarina
AU  - Pevec, Andrej
AU  - Mitić, Dragana
AU  - Jevtović, Mima
AU  - Savić, Milica
AU  - Stevanović, Nevena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6306
AB  - In the reaction of HLC1 with Zn(BF4)2.6H20 and NaN3 in molar ratio 1 : 1 : 4 in acetonitrile/water/methanol mixture of solvents, an mononuclear Zn(II) complex (1) was obtained, with composition [ZnL(N3)2]. In complex 1, the ligand is coordinated in deprotonated, formally neutral, zwitterionic form to Zn(II) ion through the pyridine nitrogen, the imine nitrogen, and the carbonyl oxygen atoms, forming a pentacoordinated complex.
AB  - Мононуклеарни азидо комплекс Zn(II), [ZnL(N3)2] (1), добијен је у реакцији Zn(BF4)2•6Н20, NaN3 и кондензационог производа 2-ацетилпиридина и Жираровог П реагенса (HLCl) у молском односу 1: 4: 1 у смеши растварача ацетонитрил/метанол/вода. У комплексу 1 јон Zn(II) је пентакоординован NNO донорским сетом атома лиганда (L) и са два азидо лиганда (Слика 1). Лиганд (L) је координован у депротонованом, формалио неутрапном, цвитерјонском облику, преко пиридинског азота, азометинског азота и карбонилног кисеоника.
PB  - Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo
C3  - 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
T1  - Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent
T1  - Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилпиридина и Жираровог П реагенса
SP  - 40
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_cer_6306
ER  - 

@conference{
author = "Anđelković, Katarina and Pevec, Andrej and Mitić, Dragana and Jevtović, Mima and Savić, Milica and Stevanović, Nevena",
year = "2023",
abstract = "In the reaction of HLC1 with Zn(BF4)2.6H20 and NaN3 in molar ratio 1 : 1 : 4 in acetonitrile/water/methanol mixture of solvents, an mononuclear Zn(II) complex (1) was obtained, with composition [ZnL(N3)2]. In complex 1, the ligand is coordinated in deprotonated, formally neutral, zwitterionic form to Zn(II) ion through the pyridine nitrogen, the imine nitrogen, and the carbonyl oxygen atoms, forming a pentacoordinated complex., Мононуклеарни азидо комплекс Zn(II), [ZnL(N3)2] (1), добијен је у реакцији Zn(BF4)2•6Н20, NaN3 и кондензационог производа 2-ацетилпиридина и Жираровог П реагенса (HLCl) у молском односу 1: 4: 1 у смеши растварача ацетонитрил/метанол/вода. У комплексу 1 јон Zn(II) је пентакоординован NNO донорским сетом атома лиганда (L) и са два азидо лиганда (Слика 1). Лиганд (L) је координован у депротонованом, формалио неутрапном, цвитерјонском облику, преко пиридинског азота, азометинског азота и карбонилног кисеоника.",
publisher = "Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo",
journal = "28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova",
title = "Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent, Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилпиридина и Жираровог П реагенса",
pages = "40-41",
url = "https://hdl.handle.net/21.15107/rcub_cer_6306"
}

Anđelković, K., Pevec, A., Mitić, D., Jevtović, M., Savić, M.,& Stevanović, N.. (2023). Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo., 40-41.
https://hdl.handle.net/21.15107/rcub_cer_6306

Anđelković K, Pevec A, Mitić D, Jevtović M, Savić M, Stevanović N. Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova. 2023;:40-41.
https://hdl.handle.net/21.15107/rcub_cer_6306 .

Anđelković, Katarina, Pevec, Andrej, Mitić, Dragana, Jevtović, Mima, Savić, Milica, Stevanović, Nevena, "Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent" in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova (2023):40-41,
https://hdl.handle.net/21.15107/rcub_cer_6306 .

TY  - CONF
AU  - Jevtović, Mima
AU  - Pevec, Andrej
AU  - Šumar Ristović, Maja
AU  - Savić, Milica
AU  - Mitić, Dragana
AU  - Stevanović, Nevena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6307
AB  - The reaction of the HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1 carbothioamide, with the metal salt MnCl2.4H20 in a molar ratio 1:1 in methanol/water mixture results in the formation of bis Mn(II) complex with composition [MnL2]. Complex crystallizes in the triclinic crystal system with space group P-1. The asymmetric unit consists of two crystallographically independent [Mn(L)2] complex molecules. The Mn(II) ion is hexacoordinated with two tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described as a distorted trigonal prism.
AB  - У реакцији лиганда HL, (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1 карботиоамид, са MnCl2•4Н2= у молском односу 1: 1 у смеши метанол/вода добијен је комплекс, опште формуле [MnL2]. Комплекс кристалише у триклиничном кристалном систему просторне групе Р-1. Асиметрична јединица комплекса састоји се од два кристалографски независна молекула комплекса [MnL2]. Jон Мn(II) је хексакоординован преко два тридентатно депротонована лиганда која садрже NNS донорски сет атома. Геометрија око централног металног јона је искривљена тригонална-призма.
PB  - Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo
C3  - 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
T1  - Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole
T1  - Синтеза и карактеризација комплекса Mn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида
SP  - 50
EP  - 51
UR  - https://hdl.handle.net/21.15107/rcub_cer_6307
ER  - 

@conference{
author = "Jevtović, Mima and Pevec, Andrej and Šumar Ristović, Maja and Savić, Milica and Mitić, Dragana and Stevanović, Nevena",
year = "2023",
abstract = "The reaction of the HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1 carbothioamide, with the metal salt MnCl2.4H20 in a molar ratio 1:1 in methanol/water mixture results in the formation of bis Mn(II) complex with composition [MnL2]. Complex crystallizes in the triclinic crystal system with space group P-1. The asymmetric unit consists of two crystallographically independent [Mn(L)2] complex molecules. The Mn(II) ion is hexacoordinated with two tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described as a distorted trigonal prism., У реакцији лиганда HL, (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1 карботиоамид, са MnCl2•4Н2= у молском односу 1: 1 у смеши метанол/вода добијен је комплекс, опште формуле [MnL2]. Комплекс кристалише у триклиничном кристалном систему просторне групе Р-1. Асиметрична јединица комплекса састоји се од два кристалографски независна молекула комплекса [MnL2]. Jон Мn(II) је хексакоординован преко два тридентатно депротонована лиганда која садрже NNS донорски сет атома. Геометрија око централног металног јона је искривљена тригонална-призма.",
publisher = "Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo",
journal = "28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova",
title = "Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole, Синтеза и карактеризација комплекса Mn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида",
pages = "50-51",
url = "https://hdl.handle.net/21.15107/rcub_cer_6307"
}

Jevtović, M., Pevec, A., Šumar Ristović, M., Savić, M., Mitić, D.,& Stevanović, N.. (2023). Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo., 50-51.
https://hdl.handle.net/21.15107/rcub_cer_6307

Jevtović M, Pevec A, Šumar Ristović M, Savić M, Mitić D, Stevanović N. Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova. 2023;:50-51.
https://hdl.handle.net/21.15107/rcub_cer_6307 .

Jevtović, Mima, Pevec, Andrej, Šumar Ristović, Maja, Savić, Milica, Mitić, Dragana, Stevanović, Nevena, "Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole" in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova (2023):50-51,
https://hdl.handle.net/21.15107/rcub_cer_6307 .

TY  - CONF
AU  - Savić, Milica
AU  - Pevec, Andrej
AU  - Radanović, Dušanka
AU  - Zlatar, Matija
AU  - Jevtović, Mima
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6308
AB  - The HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1-carbothioamide, was obtained from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction of the ligand HL with Fe(BF4)2.6H20 in a molar ratio 1:1 in methanol results in the formation of bis-ligand Fe(III) complex with composition [Fe(L)2]BF4.H2O. The Fe(III) ion with L form six-coordinate complexes [Fe(L)2]3F4.H20 (1) in which two deprotonated ligand molecules coordinate in a mer arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor atoms. Complex crystallizes in the orthorhombic crystal system with space group Pbca. The asymmetric unit consists of a complex cation [Fe(L)2]+, BF4- counter anion, and one water molecule.
AB  - Лиганд (HL), (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1-карботиоамид, добијен је у кондензационој реакцији тиосемикарбазида и 2-ацетилтиазола у води. Реакција лиганда и Fe(BF4)2•бН20 у молском односу 1: 1 у метанолу резултовалаје добијањем бис-лиганд комплекса Fe(III), формуле [Fe(L)2]BF4•Н20. Координовањем два молекула депротонованог лиганда (L), преко NNS донорског сета атома формира се mer окружење око Fe(III) јона искривљене октаедарске геометрије. Комплекс кристалише у орторомбичном кристалном систему, у просторној групи Pbca. Асиметричнајединица комплекса састоји се од комплексног катјона [Fe(L)2]+, анјона BF4- и једног молекула воде.
PB  - Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo
C3  - 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
T1  - Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole
T1  - Синтеза и карактеризација комплекса Fe(III) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида
SP  - 78
EP  - 79
UR  - https://hdl.handle.net/21.15107/rcub_cer_6308
ER  - 

@conference{
author = "Savić, Milica and Pevec, Andrej and Radanović, Dušanka and Zlatar, Matija and Jevtović, Mima",
year = "2023",
abstract = "The HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1-carbothioamide, was obtained from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction of the ligand HL with Fe(BF4)2.6H20 in a molar ratio 1:1 in methanol results in the formation of bis-ligand Fe(III) complex with composition [Fe(L)2]BF4.H2O. The Fe(III) ion with L form six-coordinate complexes [Fe(L)2]3F4.H20 (1) in which two deprotonated ligand molecules coordinate in a mer arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor atoms. Complex crystallizes in the orthorhombic crystal system with space group Pbca. The asymmetric unit consists of a complex cation [Fe(L)2]+, BF4- counter anion, and one water molecule., Лиганд (HL), (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1-карботиоамид, добијен је у кондензационој реакцији тиосемикарбазида и 2-ацетилтиазола у води. Реакција лиганда и Fe(BF4)2•бН20 у молском односу 1: 1 у метанолу резултовалаје добијањем бис-лиганд комплекса Fe(III), формуле [Fe(L)2]BF4•Н20. Координовањем два молекула депротонованог лиганда (L), преко NNS донорског сета атома формира се mer окружење око Fe(III) јона искривљене октаедарске геометрије. Комплекс кристалише у орторомбичном кристалном систему, у просторној групи Pbca. Асиметричнајединица комплекса састоји се од комплексног катјона [Fe(L)2]+, анјона BF4- и једног молекула воде.",
publisher = "Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo",
journal = "28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova",
title = "Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole, Синтеза и карактеризација комплекса Fe(III) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида",
pages = "78-79",
url = "https://hdl.handle.net/21.15107/rcub_cer_6308"
}

Savić, M., Pevec, A., Radanović, D., Zlatar, M.,& Jevtović, M.. (2023). Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova
Belgrade, Serbia : Serbian Cristallographic Soceity // Beograd, Srbija : Srpsko kristalografsko društvo., 78-79.
https://hdl.handle.net/21.15107/rcub_cer_6308

Savić M, Pevec A, Radanović D, Zlatar M, Jevtović M. Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova. 2023;:78-79.
https://hdl.handle.net/21.15107/rcub_cer_6308 .

Savić, Milica, Pevec, Andrej, Radanović, Dušanka, Zlatar, Matija, Jevtović, Mima, "Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole" in 28th Conference of the Serbian Crystallographic Society - Abstracts, June 14–15th, 2023 Čačak, Serbia / XXVIII Konferencija Srpskog kristalografskog društva - izvodi radova (2023):78-79,
https://hdl.handle.net/21.15107/rcub_cer_6308 .

TY  - CONF
AU  - Anđelković, Katarina
AU  - Pevec, Andrej
AU  - Mitić, Dragana
AU  - Jevtović, Mima
AU  - Savić, Milica
AU  - Stevanović, Nevena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6309
AB  - In the reaction of HLC1 with Zn(BF4)2.6H20 and NaN3 in molar ratio 1 : 1 : 4 in acetonitrile/water/methanol mixture of solvents, an mononuclear Zn(II) complex (1) was obtained, with composition [ZnL(N3)2]. In complex 1, the ligand is coordinated in deprotonated, formally neutral, zwitterionic form to Zn(II) ion through the pyridine nitrogen, the imine nitrogen, and the carbonyl oxygen atoms, forming a pentacoordinated complex.
AB  - Мононуклеарни азидо комплекс Zn(II), [ZnL(N3)2] (1), добијен је у реакцији Zn(BF4)2•6Н20, NaN3 и кондензационог производа 2-ацетилпиридина и Жираровог П реагенса (HLCl) у молском односу 1: 4: 1 у смеши растварача ацетонитрил/метанол/вода. У комплексу 1 јон Zn(II) је пентакоординован NNO донорским сетом атома лиганда (L) и са два азидо лиганда (Слика 1). Лиганд (L) је координован у депротонованом, формалио неутрапном, цвитерјонском облику, преко пиридинског азота, азометинског азота и карбонилног кисеоника.
PB  - TMMagCat Project
T1  - Poster presentation: Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent
T1  - Постерска презентација: Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилпиридина и Жираровог П реагенса
UR  - https://hdl.handle.net/21.15107/rcub_cer_6309
ER  - 

@conference{
author = "Anđelković, Katarina and Pevec, Andrej and Mitić, Dragana and Jevtović, Mima and Savić, Milica and Stevanović, Nevena",
year = "2023",
abstract = "In the reaction of HLC1 with Zn(BF4)2.6H20 and NaN3 in molar ratio 1 : 1 : 4 in acetonitrile/water/methanol mixture of solvents, an mononuclear Zn(II) complex (1) was obtained, with composition [ZnL(N3)2]. In complex 1, the ligand is coordinated in deprotonated, formally neutral, zwitterionic form to Zn(II) ion through the pyridine nitrogen, the imine nitrogen, and the carbonyl oxygen atoms, forming a pentacoordinated complex., Мононуклеарни азидо комплекс Zn(II), [ZnL(N3)2] (1), добијен је у реакцији Zn(BF4)2•6Н20, NaN3 и кондензационог производа 2-ацетилпиридина и Жираровог П реагенса (HLCl) у молском односу 1: 4: 1 у смеши растварача ацетонитрил/метанол/вода. У комплексу 1 јон Zn(II) је пентакоординован NNO донорским сетом атома лиганда (L) и са два азидо лиганда (Слика 1). Лиганд (L) је координован у депротонованом, формалио неутрапном, цвитерјонском облику, преко пиридинског азота, азометинског азота и карбонилног кисеоника.",
publisher = "TMMagCat Project",
title = "Poster presentation: Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent, Постерска презентација: Синтеза и карактеризација азидо комплекса Zn(II) са кондензaционим производом 2-ацетилпиридина и Жираровог П реагенса",
url = "https://hdl.handle.net/21.15107/rcub_cer_6309"
}

Anđelković, K., Pevec, A., Mitić, D., Jevtović, M., Savić, M.,& Stevanović, N.. (2023). Poster presentation: Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent. 
TMMagCat Project..
https://hdl.handle.net/21.15107/rcub_cer_6309

Anđelković K, Pevec A, Mitić D, Jevtović M, Savić M, Stevanović N. Poster presentation: Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6309 .

Anđelković, Katarina, Pevec, Andrej, Mitić, Dragana, Jevtović, Mima, Savić, Milica, Stevanović, Nevena, "Poster presentation: Synthesis and characterization of azido Zn(II) complex with the condensation product of 2-acetylpyridine and Girard's P reagent" (2023),
https://hdl.handle.net/21.15107/rcub_cer_6309 .

TY  - CONF
AU  - Jevtović, Mima
AU  - Pevec, Andrej
AU  - Šumar Ristović, Maja
AU  - Savić, Milica
AU  - Mitić, Dragana
AU  - Stevanović, Nevena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6310
AB  - The reaction of the HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1 carbothioamide, with the metal salt MnCl2.4H20 in a molar ratio 1:1 in methanol/water mixture results in the formation of bis Mn(II) complex with composition [MnL2]. Complex crystallizes in the triclinic crystal system with space group P-1. The asymmetric unit consists of two crystallographically independent [Mn(L)2] complex molecules. The Mn(II) ion is hexacoordinated with two tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described as a distorted trigonal prism.
AB  - У реакцији лиганда HL, (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1 карботиоамид, са MnCl2•4Н2= у молском односу 1: 1 у смеши метанол/вода добијен је комплекс, опште формуле [MnL2]. Комплекс кристалише у триклиничном кристалном систему просторне групе Р-1. Асиметрична јединица комплекса састоји се од два кристалографски независна молекула комплекса [MnL2]. Jон Мn(II) је хексакоординован преко два тридентатно депротонована лиганда која садрже NNS донорски сет атома. Геометрија око централног металног јона је искривљена тригонална-призма.
PB  - TMMagCat Project
T1  - Poster presentation: Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole
T1  - Постерска презентација: Синтеза и карактеризација комплекса Mn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида
UR  - https://hdl.handle.net/21.15107/rcub_cer_6310
ER  - 

@conference{
author = "Jevtović, Mima and Pevec, Andrej and Šumar Ristović, Maja and Savić, Milica and Mitić, Dragana and Stevanović, Nevena",
year = "2023",
abstract = "The reaction of the HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1 carbothioamide, with the metal salt MnCl2.4H20 in a molar ratio 1:1 in methanol/water mixture results in the formation of bis Mn(II) complex with composition [MnL2]. Complex crystallizes in the triclinic crystal system with space group P-1. The asymmetric unit consists of two crystallographically independent [Mn(L)2] complex molecules. The Mn(II) ion is hexacoordinated with two tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described as a distorted trigonal prism., У реакцији лиганда HL, (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1 карботиоамид, са MnCl2•4Н2= у молском односу 1: 1 у смеши метанол/вода добијен је комплекс, опште формуле [MnL2]. Комплекс кристалише у триклиничном кристалном систему просторне групе Р-1. Асиметрична јединица комплекса састоји се од два кристалографски независна молекула комплекса [MnL2]. Jон Мn(II) је хексакоординован преко два тридентатно депротонована лиганда која садрже NNS донорски сет атома. Геометрија око централног металног јона је искривљена тригонална-призма.",
publisher = "TMMagCat Project",
title = "Poster presentation: Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole, Постерска презентација: Синтеза и карактеризација комплекса Mn(II) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида",
url = "https://hdl.handle.net/21.15107/rcub_cer_6310"
}

Jevtović, M., Pevec, A., Šumar Ristović, M., Savić, M., Mitić, D.,& Stevanović, N.. (2023). Poster presentation: Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. 
TMMagCat Project..
https://hdl.handle.net/21.15107/rcub_cer_6310

Jevtović M, Pevec A, Šumar Ristović M, Savić M, Mitić D, Stevanović N. Poster presentation: Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6310 .

Jevtović, Mima, Pevec, Andrej, Šumar Ristović, Maja, Savić, Milica, Mitić, Dragana, Stevanović, Nevena, "Poster presentation: Synthesis and characterization of Mn(II) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole" (2023),
https://hdl.handle.net/21.15107/rcub_cer_6310 .

TY  - CONF
AU  - Savić, Milica
AU  - Pevec, Andrej
AU  - Radanović, Dušanka
AU  - Zlatar, Matija
AU  - Jevtović, Mima
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6311
AB  - The HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1-carbothioamide, was obtained from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction of the ligand HL with Fe(BF4)2.6H20 in a molar ratio 1:1 in methanol results in the formation of bis-ligand Fe(III) complex with composition [Fe(L)2]BF4.H2O. The Fe(III) ion with L form six-coordinate complexes [Fe(L)2]3F4.H20 (1) in which two deprotonated ligand molecules coordinate in a mer arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor atoms. Complex crystallizes in the orthorhombic crystal system with space group Pbca. The asymmetric unit consists of a complex cation [Fe(L)2]+, BF4- counter anion, and one water molecule.
AB  - Лиганд (HL), (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1-карботиоамид, добијен је у кондензационој реакцији тиосемикарбазида и 2-ацетилтиазола у води. Реакција лиганда и Fe(BF4)2•бН20 у молском односу 1: 1 у метанолу резултовалаје добијањем бис-лиганд комплекса Fe(III), формуле [Fe(L)2]BF4•Н20. Координовањем два молекула депротонованог лиганда (L), преко NNS донорског сета атома формира се mer окружење око Fe(III) јона искривљене октаедарске геометрије. Комплекс кристалише у орторомбичном кристалном систему, у просторној групи Pbca. Асиметричнајединица комплекса састоји се од комплексног катјона [Fe(L)2]+, анјона BF4- и једног молекула воде.
PB  - TMMagCat Project
T1  - Poster presentation: Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole
T1  - Постерска презентација: Синтеза и карактеризација комплекса Fe(III) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида
UR  - https://hdl.handle.net/21.15107/rcub_cer_6311
ER  - 

@conference{
author = "Savić, Milica and Pevec, Andrej and Radanović, Dušanka and Zlatar, Matija and Jevtović, Mima",
year = "2023",
abstract = "The HL ligand, (E)-2-(1-(thiazol-2-ypethylidene)hydrazine-1-carbothioamide, was obtained from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction of the ligand HL with Fe(BF4)2.6H20 in a molar ratio 1:1 in methanol results in the formation of bis-ligand Fe(III) complex with composition [Fe(L)2]BF4.H2O. The Fe(III) ion with L form six-coordinate complexes [Fe(L)2]3F4.H20 (1) in which two deprotonated ligand molecules coordinate in a mer arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor atoms. Complex crystallizes in the orthorhombic crystal system with space group Pbca. The asymmetric unit consists of a complex cation [Fe(L)2]+, BF4- counter anion, and one water molecule., Лиганд (HL), (Е)-2-(1-(тиазол-2-ил)етилиден)хидразин-1-карботиоамид, добијен је у кондензационој реакцији тиосемикарбазида и 2-ацетилтиазола у води. Реакција лиганда и Fe(BF4)2•бН20 у молском односу 1: 1 у метанолу резултовалаје добијањем бис-лиганд комплекса Fe(III), формуле [Fe(L)2]BF4•Н20. Координовањем два молекула депротонованог лиганда (L), преко NNS донорског сета атома формира се mer окружење око Fe(III) јона искривљене октаедарске геометрије. Комплекс кристалише у орторомбичном кристалном систему, у просторној групи Pbca. Асиметричнајединица комплекса састоји се од комплексног катјона [Fe(L)2]+, анјона BF4- и једног молекула воде.",
publisher = "TMMagCat Project",
title = "Poster presentation: Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole, Постерска презентација: Синтеза и карактеризација комплекса Fe(III) са кондензaционим производом 2-ацетилтиазола и тиосемикарбазида",
url = "https://hdl.handle.net/21.15107/rcub_cer_6311"
}

Savić, M., Pevec, A., Radanović, D., Zlatar, M.,& Jevtović, M.. (2023). Poster presentation: Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. 
TMMagCat Project..
https://hdl.handle.net/21.15107/rcub_cer_6311

Savić M, Pevec A, Radanović D, Zlatar M, Jevtović M. Poster presentation: Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_6311 .

Savić, Milica, Pevec, Andrej, Radanović, Dušanka, Zlatar, Matija, Jevtović, Mima, "Poster presentation: Synthesis and characterization of Fe(III) complex with the condensation product of thiosemicarbazide and 2-acetylthiazole" (2023),
https://hdl.handle.net/21.15107/rcub_cer_6311 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
AU  - Mitić, Dragana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7316
AB  - Poster presented at The Training School of COST action CA21101 COSY ,,Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and
astrophysical application", Belgrade, Serbia, 19th – 22nd September 2023.
PB  - TMMagCat project
T1  - Poster presentation: Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole
UR  - https://hdl.handle.net/21.15107/rcub_cer_7316
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina and Mitić, Dragana",
year = "2023",
abstract = "Poster presented at The Training School of COST action CA21101 COSY ,,Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and
astrophysical application", Belgrade, Serbia, 19th – 22nd September 2023.",
publisher = "TMMagCat project",
title = "Poster presentation: Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole",
url = "https://hdl.handle.net/21.15107/rcub_cer_7316"
}

Savić, M., Jevtović, M., Čobeljić, B., Anđelković, K.,& Mitić, D.. (2023). Poster presentation: Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole. 
TMMagCat project..
https://hdl.handle.net/21.15107/rcub_cer_7316

Savić M, Jevtović M, Čobeljić B, Anđelković K, Mitić D. Poster presentation: Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_7316 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, Mitić, Dragana, "Poster presentation: Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole" (2023),
https://hdl.handle.net/21.15107/rcub_cer_7316 .

TY  - CONF
AU  - Jevtović, Mima
AU  - Savić, Milica
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
AU  - Mitić, Dragana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7318
AB  - Poster presented at The Training School of COST action CA21101 COSY ,,Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and аstrophysical applications" , Belgradе, Serbia,19th – 22nd September 2023.
PB  - TMMagCat project
T1  - Poster presentation: Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations
UR  - https://hdl.handle.net/21.15107/rcub_cer_7318
ER  - 

@conference{
author = "Jevtović, Mima and Savić, Milica and Anđelković, Katarina and Čobeljić, Božidar and Mitić, Dragana",
year = "2023",
abstract = "Poster presented at The Training School of COST action CA21101 COSY ,,Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and аstrophysical applications" , Belgradе, Serbia,19th – 22nd September 2023.",
publisher = "TMMagCat project",
title = "Poster presentation: Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations",
url = "https://hdl.handle.net/21.15107/rcub_cer_7318"
}

Jevtović, M., Savić, M., Anđelković, K., Čobeljić, B.,& Mitić, D.. (2023). Poster presentation: Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations. 
TMMagCat project..
https://hdl.handle.net/21.15107/rcub_cer_7318

Jevtović M, Savić M, Anđelković K, Čobeljić B, Mitić D. Poster presentation: Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations. 2023;.
https://hdl.handle.net/21.15107/rcub_cer_7318 .

Jevtović, Mima, Savić, Milica, Anđelković, Katarina, Čobeljić, Božidar, Mitić, Dragana, "Poster presentation: Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations" (2023),
https://hdl.handle.net/21.15107/rcub_cer_7318 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
AU  - Mitić, Dragana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7317
AB  - The HL ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide, was obtained  from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction  of the HL ligand with the metal salt MnCl2·4H2O in a molar ratio 1:1 in methanol/water mixture  results in the formation of bis Mn(II) complex with composition [MnL2]. Complex 1 crystallizes  in the triclinic crystal system with space group P−1. The Mn(II) ion is hexacoordinated with two  tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described  as a distorted trigonal prism (Fig. 1). The reaction of the ligand HL with Fe(BF4)2·6H2O in a molar ratio 1:1 in methanol results in the  formation of bis Fe(III) complex with composition [Fe(L)2]BF4·H2O. The Fe(III) ion with L  form six-coordinate complex in which two deprotonated ligand molecules coordinate in a mer  arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor  atoms (Fig. 1). Complex 2 crystallizes in the orthorhombic crystal system with space group Pbca.
PB  - COST action CA21101 (COSY)
C3  - Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade
T1  - Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole
SP  - 51
EP  - 51
UR  - https://hdl.handle.net/21.15107/rcub_cer_7317
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina and Mitić, Dragana",
year = "2023",
abstract = "The HL ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide, was obtained  from the condensation reaction of thiosemicarbazide and 2-acetylthiazole in water. The reaction  of the HL ligand with the metal salt MnCl2·4H2O in a molar ratio 1:1 in methanol/water mixture  results in the formation of bis Mn(II) complex with composition [MnL2]. Complex 1 crystallizes  in the triclinic crystal system with space group P−1. The Mn(II) ion is hexacoordinated with two  tridentate ligands L through NNS sets of donor atoms. The geometry around the Mn is described  as a distorted trigonal prism (Fig. 1). The reaction of the ligand HL with Fe(BF4)2·6H2O in a molar ratio 1:1 in methanol results in the  formation of bis Fe(III) complex with composition [Fe(L)2]BF4·H2O. The Fe(III) ion with L  form six-coordinate complex in which two deprotonated ligand molecules coordinate in a mer  arrangement, forming a distorted octahedral complex by chelation through NNS sets of donor  atoms (Fig. 1). Complex 2 crystallizes in the orthorhombic crystal system with space group Pbca.",
publisher = "COST action CA21101 (COSY)",
journal = "Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade",
title = "Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole",
pages = "51-51",
url = "https://hdl.handle.net/21.15107/rcub_cer_7317"
}

Savić, M., Jevtović, M., Čobeljić, B., Anđelković, K.,& Mitić, D.. (2023). Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade
COST action CA21101 (COSY)., 51-51.
https://hdl.handle.net/21.15107/rcub_cer_7317

Savić M, Jevtović M, Čobeljić B, Anđelković K, Mitić D. Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade. 2023;:51-51.
https://hdl.handle.net/21.15107/rcub_cer_7317 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, Mitić, Dragana, "Synthesis and characterization of Mn(II) and Fe(III) complexes with the condensation product of thiosemicarbazide and 2-acetylthiazole" in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade (2023):51-51,
https://hdl.handle.net/21.15107/rcub_cer_7317 .

TY  - CONF
AU  - Jevtović, Mima
AU  - Savić, Milica
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
AU  - Mitić, Dragana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7319
AB  - The ligand (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide (HL1 ) was obtained  from the condensation of 2-acetylthiazole and thiosemicarbazide. Upon reacting HL1 with  Zn(BF4)2·6H2O and NaN3 in a solvent mixture of water/methanol, mononuclear Zn(II) complex  1 with the composition [ZnL1 (N3)2] was obtained. In complex 1, Zn(II) is pentacoordinated with  the thiazole nitrogen, the azomethine nitrogen, and thiolate sulfur atoms from the deprotonated  hydrazone ligand, as well as with two azido ligands. Complex 1 crystallises in the monoclinic  crystal system with space group No.14 (P21/c cell setting). The unit cell of 1 contains four  [ZnL1 (N3)] asymmetric units. In complex 1, the Zn(II) site shows a distorted geometry, almost  midway between the square pyramid and trigonal bipyramid, established on the basis of a  calculated τ5 parameter of 0.46. The hydrazone ligand (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)-pyridine1-ium chloride (HL2 Cl) was obtained from the condensation reaction of 2-acetylpyridine and  Girard's P reagent. Reaction of HL2 Cl with Zn(BF4)2·6H2O and NaN3, in a mixture of  acetonitrile/water/methanol, gives mononuclear Zn(II) complex 2 with the composition  [ZnL2 (N3)2]. Reaction of HL2 Cl with Zn(BF4)2·6H2O and NaN3, in a mixture of  acetonitrile/water/methanol, gives mononuclear Zn(II) complex 2 with the composition  [ZnL2 (N3)2]. In complex 2, the Zn(II) ion has fivefold coordination with NNO-set of donor  atoms of L2 and two nitrogen atoms from the azido ligands. The calculated τ5 value of 0.08 for  [ZnL2 (N3)2] indicates that the five-coordination geometry of the Zn(II) ion is slightly distorted  square pyramidal. Evaluation of the catalytic properties of the Zn(II) complexes in the KA2 reaction shows that the  most active compound, when used as a catalyst, is complex 1. It leads to a 92 % isolated yield of  the desired propargylamine product. The catalytic activity results are in full agreement with the  findings of the DFT calculations. Complex 1 shows the highest value of molecular softness and  the lowest value of molecular hardness. This correlation, between experimental and theoretical  results, is excellently visualised in the linear relationship between the isolated yield of the  desired propargylamine product and the calculated molecular softness, S.
PB  - COST action CA21101 (COSY)
C3  - Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade
T1  - Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations
SP  - 36
EP  - 36
UR  - https://hdl.handle.net/21.15107/rcub_cer_7319
ER  - 

@conference{
author = "Jevtović, Mima and Savić, Milica and Anđelković, Katarina and Čobeljić, Božidar and Mitić, Dragana",
year = "2023",
abstract = "The ligand (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide (HL1 ) was obtained  from the condensation of 2-acetylthiazole and thiosemicarbazide. Upon reacting HL1 with  Zn(BF4)2·6H2O and NaN3 in a solvent mixture of water/methanol, mononuclear Zn(II) complex  1 with the composition [ZnL1 (N3)2] was obtained. In complex 1, Zn(II) is pentacoordinated with  the thiazole nitrogen, the azomethine nitrogen, and thiolate sulfur atoms from the deprotonated  hydrazone ligand, as well as with two azido ligands. Complex 1 crystallises in the monoclinic  crystal system with space group No.14 (P21/c cell setting). The unit cell of 1 contains four  [ZnL1 (N3)] asymmetric units. In complex 1, the Zn(II) site shows a distorted geometry, almost  midway between the square pyramid and trigonal bipyramid, established on the basis of a  calculated τ5 parameter of 0.46. The hydrazone ligand (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)-pyridine1-ium chloride (HL2 Cl) was obtained from the condensation reaction of 2-acetylpyridine and  Girard's P reagent. Reaction of HL2 Cl with Zn(BF4)2·6H2O and NaN3, in a mixture of  acetonitrile/water/methanol, gives mononuclear Zn(II) complex 2 with the composition  [ZnL2 (N3)2]. Reaction of HL2 Cl with Zn(BF4)2·6H2O and NaN3, in a mixture of  acetonitrile/water/methanol, gives mononuclear Zn(II) complex 2 with the composition  [ZnL2 (N3)2]. In complex 2, the Zn(II) ion has fivefold coordination with NNO-set of donor  atoms of L2 and two nitrogen atoms from the azido ligands. The calculated τ5 value of 0.08 for  [ZnL2 (N3)2] indicates that the five-coordination geometry of the Zn(II) ion is slightly distorted  square pyramidal. Evaluation of the catalytic properties of the Zn(II) complexes in the KA2 reaction shows that the  most active compound, when used as a catalyst, is complex 1. It leads to a 92 % isolated yield of  the desired propargylamine product. The catalytic activity results are in full agreement with the  findings of the DFT calculations. Complex 1 shows the highest value of molecular softness and  the lowest value of molecular hardness. This correlation, between experimental and theoretical  results, is excellently visualised in the linear relationship between the isolated yield of the  desired propargylamine product and the calculated molecular softness, S.",
publisher = "COST action CA21101 (COSY)",
journal = "Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade",
title = "Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations",
pages = "36-36",
url = "https://hdl.handle.net/21.15107/rcub_cer_7319"
}

Jevtović, M., Savić, M., Anđelković, K., Čobeljić, B.,& Mitić, D.. (2023). Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations. in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade
COST action CA21101 (COSY)., 36-36.
https://hdl.handle.net/21.15107/rcub_cer_7319

Jevtović M, Savić M, Anđelković K, Čobeljić B, Mitić D. Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations. in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade. 2023;:36-36.
https://hdl.handle.net/21.15107/rcub_cer_7319 .

Jevtović, Mima, Savić, Milica, Anđelković, Katarina, Čobeljić, Božidar, Mitić, Dragana, "Synthesis of a New Family of Zn(II) Hydrazone Complexes: Characterisation, Catalytic Activity, and DFT Calculations" in Book of abstracts - COST Training School, COST action CA21101 COSY, "Multiscale modeling of the properties of compounds: From isolated molecules to 3D materials relevant for industrial and astrophysical applications," 19th - 22nd September, 2023, Belgrade (2023):36-36,
https://hdl.handle.net/21.15107/rcub_cer_7319 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7451
AB  - The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-
(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade : Serbian Young Chemists’ Club
C3  - 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia
T1  - Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex
SP  - 69
EP  - 69
UR  - https://hdl.handle.net/21.15107/rcub_cer_7451
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina",
year = "2023",
abstract = "The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-
(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists’ Club",
journal = "9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia",
title = "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex",
pages = "69-69",
url = "https://hdl.handle.net/21.15107/rcub_cer_7451"
}

Savić, M., Jevtović, M., Čobeljić, B.,& Anđelković, K.. (2023). Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia
Belgrade : Serbian Chemical Society., 69-69.
https://hdl.handle.net/21.15107/rcub_cer_7451

Savić M, Jevtović M, Čobeljić B, Anđelković K. Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia. 2023;:69-69.
https://hdl.handle.net/21.15107/rcub_cer_7451 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex" in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia (2023):69-69,
https://hdl.handle.net/21.15107/rcub_cer_7451 .

TY  - CONF
AU  - Savić, Milica
AU  - Jevtović, Mima
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7452
AB  - The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.
PB  - TMMagCat project
T1  - Poster presentation: "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex"
UR  - https://hdl.handle.net/21.15107/rcub_cer_7452
ER  - 

@conference{
author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina",
year = "2023",
abstract = "The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.",
publisher = "TMMagCat project",
title = "Poster presentation: "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex"",
url = "https://hdl.handle.net/21.15107/rcub_cer_7452"
}

Savić, M., Jevtović, M., Čobeljić, B.,& Anđelković, K.. (2023). Poster presentation: "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex". 
TMMagCat project..
https://hdl.handle.net/21.15107/rcub_cer_7452

Savić M, Jevtović M, Čobeljić B, Anđelković K. Poster presentation: "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex". 2023;.
https://hdl.handle.net/21.15107/rcub_cer_7452 .

Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, "Poster presentation: "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex"" (2023),
https://hdl.handle.net/21.15107/rcub_cer_7452 .

TY  - CONF
AU  - Stevanović, Nevena
AU  - Zlatar, Matija
AU  - Jevtović, Mima
AU  - Gruden, Maja
AU  - Šumar, Maja
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5081
AB  - The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations.
AB  - U reakciji liganda HLCl sa solima metala Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O i NaN3 u metanolu, dobijeni su mononuklearni kompleksi koordinacionog broja pet: [CuL(N3)(CH3OH)]BF4 (1) i [ZnL(N3)2] (2) i dinuklearni kompleks [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3). Kompleksi 1, 2 i 3 okarakterisani su elementalnom analizom, IC spektroskopijom, rendgenskom stukturnom analizom i DFT proračunima.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
T1  - Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation
T1  - Hidrazonski kompleksi Cu(II), Mn(II) i Zn(II) sa kvaternernim  amonijum fragmentom: sinteza, karakterizacija i DFT proračuni
SP  - 127
UR  - https://hdl.handle.net/21.15107/rcub_cer_5081
ER  - 

@conference{
author = "Stevanović, Nevena and Zlatar, Matija and Jevtović, Mima and Gruden, Maja and Šumar, Maja and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations., U reakciji liganda HLCl sa solima metala Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O i NaN3 u metanolu, dobijeni su mononuklearni kompleksi koordinacionog broja pet: [CuL(N3)(CH3OH)]BF4 (1) i [ZnL(N3)2] (2) i dinuklearni kompleks [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3). Kompleksi 1, 2 i 3 okarakterisani su elementalnom analizom, IC spektroskopijom, rendgenskom stukturnom analizom i DFT proračunima.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine",
title = "Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation, Hidrazonski kompleksi Cu(II), Mn(II) i Zn(II) sa kvaternernim  amonijum fragmentom: sinteza, karakterizacija i DFT proračuni",
pages = "127",
url = "https://hdl.handle.net/21.15107/rcub_cer_5081"
}

Stevanović, N., Zlatar, M., Jevtović, M., Gruden, M., Šumar, M., Anđelković, K.,& Čobeljić, B.. (2022). Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
Belgrade : Serbian Chemical Society., 127.
https://hdl.handle.net/21.15107/rcub_cer_5081

Stevanović N, Zlatar M, Jevtović M, Gruden M, Šumar M, Anđelković K, Čobeljić B. Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine. 2022;:127.
https://hdl.handle.net/21.15107/rcub_cer_5081 .

Stevanović, Nevena, Zlatar, Matija, Jevtović, Mima, Gruden, Maja, Šumar, Maja, Anđelković, Katarina, Čobeljić, Božidar, "Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation" in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine (2022):127,
https://hdl.handle.net/21.15107/rcub_cer_5081 .

TY  - CONF
AU  - Savić, Milica
AU  - Stevanović, Nevena
AU  - Jevtović, Mima
AU  - Gruden, Maja
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5083
AB  - Poster presented at: 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022.
PB  - TMMagCat project
T1  - Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole
UR  - https://hdl.handle.net/21.15107/rcub_cer_5083
ER  - 

@conference{
author = "Savić, Milica and Stevanović, Nevena and Jevtović, Mima and Gruden, Maja and Anđelković, Katarina and Čobeljić, Božidar and Zlatar, Matija",
year = "2022",
abstract = "Poster presented at: 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022.",
publisher = "TMMagCat project",
title = "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole",
url = "https://hdl.handle.net/21.15107/rcub_cer_5083"
}

Savić, M., Stevanović, N., Jevtović, M., Gruden, M., Anđelković, K., Čobeljić, B.,& Zlatar, M.. (2022). Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. 
TMMagCat project..
https://hdl.handle.net/21.15107/rcub_cer_5083

Savić M, Stevanović N, Jevtović M, Gruden M, Anđelković K, Čobeljić B, Zlatar M. Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. 2022;.
https://hdl.handle.net/21.15107/rcub_cer_5083 .

Savić, Milica, Stevanović, Nevena, Jevtović, Mima, Gruden, Maja, Anđelković, Katarina, Čobeljić, Božidar, Zlatar, Matija, "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole" (2022),
https://hdl.handle.net/21.15107/rcub_cer_5083 .