Pastor, Ferenc T.

Link to this page

Authority KeyName Variants
orcid::0000-0003-0813-9085
  • Pastor, Ferenc T. (9)
  • Pastor, Ferenc (2)
Projects
Modulation of antioxidative metabolism in plants for improvement of plant abiotic stress tolerance and identification of new biomarkers for application in remediation and monitoring of degraded biotopes Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Development of technologies and products based on mineral raw materials and waste biomass for protection of natural resources for safe food production
Content of bioactive components in small and stone fruits as affected by cultivar specificities and growing conditions, and obtaining biologically valuable products by improved and newly developed technologies Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200051 (Institute of General and Physical Chemistry, Belgrade)
Tiazolidni i sintetički analozi: reaktivnost, primena i biološka aktivnost Synthesis, characterization and activity of organic and coordination composition and their application in (bio) nanotechnology
Proučavanje odnosa reaktivnosti, nekovalentnih interakcija i strukture molekula i modelovanje hemijskih sistema Regulacija antioksidativnog metabolizma biljaka u toku rastenja, infekcije patogenima i delovanja abiotičkog stresa: mehanizmi transporta, signalizacije i otpornosti
Ministry of Science and Higher Education of the Russian Federation (agreement No. 075-15-2022-1135) and South Ural State University

Author's Bibliography

Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure

Mutić, Tijana; Stanković, Dalibor; Manojlović, Dragan; Petrić, Djordje; Pastor, Ferenc; Avdin, Vyacheslav V.; Ognjanović, Miloš; Stanković, Vesna

(MDPI AG, 2024)

TY  - JOUR
AU  - Mutić, Tijana
AU  - Stanković, Dalibor
AU  - Manojlović, Dragan
AU  - Petrić, Djordje
AU  - Pastor, Ferenc
AU  - Avdin, Vyacheslav V.
AU  - Ognjanović, Miloš
AU  - Stanković, Vesna
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7422
AB  - In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.
PB  - MDPI AG
T2  - Electrochem
T1  - Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure
VL  - 5
IS  - 1
SP  - 45
EP  - 56
DO  - 10.3390/electrochem5010003
ER  - 
@article{
author = "Mutić, Tijana and Stanković, Dalibor and Manojlović, Dragan and Petrić, Djordje and Pastor, Ferenc and Avdin, Vyacheslav V. and Ognjanović, Miloš and Stanković, Vesna",
year = "2024",
abstract = "In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.",
publisher = "MDPI AG",
journal = "Electrochem",
title = "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure",
volume = "5",
number = "1",
pages = "45-56",
doi = "10.3390/electrochem5010003"
}
Mutić, T., Stanković, D., Manojlović, D., Petrić, D., Pastor, F., Avdin, V. V., Ognjanović, M.,& Stanković, V.. (2024). Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem
MDPI AG., 5(1), 45-56.
https://doi.org/10.3390/electrochem5010003
Mutić T, Stanković D, Manojlović D, Petrić D, Pastor F, Avdin VV, Ognjanović M, Stanković V. Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem. 2024;5(1):45-56.
doi:10.3390/electrochem5010003 .
Mutić, Tijana, Stanković, Dalibor, Manojlović, Dragan, Petrić, Djordje, Pastor, Ferenc, Avdin, Vyacheslav V., Ognjanović, Miloš, Stanković, Vesna, "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure" in Electrochem, 5, no. 1 (2024):45-56,
https://doi.org/10.3390/electrochem5010003 . .
1

2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination

Pastor, Ferenc; Dojčinović, Biljana; Kodranov, Igor; Gorjanović, Stanislava; Ivanović, Tijana; Popović, Daniela; Miladinović, Jelena

(John Wiley and Sons Inc., 2023)

TY  - JOUR
AU  - Pastor, Ferenc
AU  - Dojčinović, Biljana
AU  - Kodranov, Igor
AU  - Gorjanović, Stanislava
AU  - Ivanović, Tijana
AU  - Popović, Daniela
AU  - Miladinović, Jelena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7181
AB  - Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV) methods have been developed for their simultaneous determination. The question was would there be some benefits if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89×10−10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The developed method was successfully applied for nickel content determination in real samples. The suitability of the developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61×10−11 M) is almost two orders of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+ determination from the same solution in two successive runs has significantly better analytical performances than the starting method for their simultaneous determination in one run.
PB  - John Wiley and Sons Inc.
T2  - Electroanalysis
T1  - 2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination
SP  - e202300259
DO  - 10.1002/elan.202300259
ER  - 
@article{
author = "Pastor, Ferenc and Dojčinović, Biljana and Kodranov, Igor and Gorjanović, Stanislava and Ivanović, Tijana and Popović, Daniela and Miladinović, Jelena",
year = "2023",
abstract = "Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV) methods have been developed for their simultaneous determination. The question was would there be some benefits if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89×10−10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The developed method was successfully applied for nickel content determination in real samples. The suitability of the developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61×10−11 M) is almost two orders of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+ determination from the same solution in two successive runs has significantly better analytical performances than the starting method for their simultaneous determination in one run.",
publisher = "John Wiley and Sons Inc.",
journal = "Electroanalysis",
title = "2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination",
pages = "e202300259",
doi = "10.1002/elan.202300259"
}
Pastor, F., Dojčinović, B., Kodranov, I., Gorjanović, S., Ivanović, T., Popović, D.,& Miladinović, J.. (2023). 2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis
John Wiley and Sons Inc.., e202300259.
https://doi.org/10.1002/elan.202300259
Pastor F, Dojčinović B, Kodranov I, Gorjanović S, Ivanović T, Popović D, Miladinović J. 2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis. 2023;:e202300259.
doi:10.1002/elan.202300259 .
Pastor, Ferenc, Dojčinović, Biljana, Kodranov, Igor, Gorjanović, Stanislava, Ivanović, Tijana, Popović, Daniela, Miladinović, Jelena, "2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination" in Electroanalysis (2023):e202300259,
https://doi.org/10.1002/elan.202300259 . .
1

Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography

Lugonja, Nikoleta; Gorjanović, Stanislava Ž.; Pastor, Ferenc T.; Marinković, Vesna; Miličić, Biljana; Vrvić, Miroslav; Spasić, Snežana

(Springer, 2021)

TY  - JOUR
AU  - Lugonja, Nikoleta
AU  - Gorjanović, Stanislava Ž.
AU  - Pastor, Ferenc T.
AU  - Marinković, Vesna
AU  - Miličić, Biljana
AU  - Vrvić, Miroslav
AU  - Spasić, Snežana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4574
AB  - Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.
PB  - Springer
T2  - Food Analytical Methods
T1  - Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography
DO  - 10.1007/s12161-021-02030-3
ER  - 
@article{
author = "Lugonja, Nikoleta and Gorjanović, Stanislava Ž. and Pastor, Ferenc T. and Marinković, Vesna and Miličić, Biljana and Vrvić, Miroslav and Spasić, Snežana",
year = "2021",
abstract = "Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.",
publisher = "Springer",
journal = "Food Analytical Methods",
title = "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography",
doi = "10.1007/s12161-021-02030-3"
}
Lugonja, N., Gorjanović, S. Ž., Pastor, F. T., Marinković, V., Miličić, B., Vrvić, M.,& Spasić, S.. (2021). Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods
Springer..
https://doi.org/10.1007/s12161-021-02030-3
Lugonja N, Gorjanović SŽ, Pastor FT, Marinković V, Miličić B, Vrvić M, Spasić S. Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods. 2021;.
doi:10.1007/s12161-021-02030-3 .
Lugonja, Nikoleta, Gorjanović, Stanislava Ž., Pastor, Ferenc T., Marinković, Vesna, Miličić, Biljana, Vrvić, Miroslav, Spasić, Snežana, "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography" in Food Analytical Methods (2021),
https://doi.org/10.1007/s12161-021-02030-3 . .
2
3

Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles

Stojićević, Aleksandra S.; Pastor, Ferenc T.; Gorjanović, Stanislava Ž.; Šolević Knudsen, Tatjana; Antić, Mališa

(Wiley, 2020)

TY  - JOUR
AU  - Stojićević, Aleksandra S.
AU  - Pastor, Ferenc T.
AU  - Gorjanović, Stanislava Ž.
AU  - Šolević Knudsen, Tatjana
AU  - Antić, Mališa
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3238
AB  - A direct current (DC) polarographic assay based on the decrease of anodic current of HydroxoPerhydroxoMercury (II) Complex (HPMC) formation in H2O2 solution in Clark Lubs (CL) buffer (pH 9.8) as working solution was previously applied to determine antioxidant (AO) capacity of water‐soluble compounds. Here, the applicability of HPMC assay was extended into samples poorly soluble in water such as the essential oils and extracts of Lamiaceae and Apiaceae species obtained by ultrasound‐assisted maceration (UAM) and Soxhlet extraction (SE) with 70 and 96% ethanol as well as individual compounds present. The influence of solvents miscible with water on HPMC anodic current was studied, and working solution was optimized. A modified HPMC method was applied to measure AO capacity of essential oils and extracts as well as compounds identified using gas chromatography‐mass spectrometer (GC‐MS) and gas chromatography with flame‐ionization detection (GC‐FID) (terpenoids and catechols) or known to be present (phenolic acids and flavonoids). A 1:1 mixture of CL buffer and ethanol was chosen as working solution. AO capacity of essential oils and extracts, established by modified HPMC assay, was in range of 1.2‐2.0 and 9.2‐38.4 (%/mL) while terpenoids and phenolics in range of 0.1‐0.5 and 13.5‐38.5 (%/mol), respectively. The superior AO capacity was ascribed to essential oils and extracts of Lamiaceae species and to extracts obtained with 70% ethanol. A higher AO capacity of extracts in comparison to essential oils was corroborated with a difference in phenolics and terpenoids capacity.
PB  - Wiley
T2  - Flavour and Fragrance Journal
T1  - Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles
VL  - 35
SP  - 219
EP  - 226
DO  - 10.1002/ffj.3555
ER  - 
@article{
author = "Stojićević, Aleksandra S. and Pastor, Ferenc T. and Gorjanović, Stanislava Ž. and Šolević Knudsen, Tatjana and Antić, Mališa",
year = "2020",
abstract = "A direct current (DC) polarographic assay based on the decrease of anodic current of HydroxoPerhydroxoMercury (II) Complex (HPMC) formation in H2O2 solution in Clark Lubs (CL) buffer (pH 9.8) as working solution was previously applied to determine antioxidant (AO) capacity of water‐soluble compounds. Here, the applicability of HPMC assay was extended into samples poorly soluble in water such as the essential oils and extracts of Lamiaceae and Apiaceae species obtained by ultrasound‐assisted maceration (UAM) and Soxhlet extraction (SE) with 70 and 96% ethanol as well as individual compounds present. The influence of solvents miscible with water on HPMC anodic current was studied, and working solution was optimized. A modified HPMC method was applied to measure AO capacity of essential oils and extracts as well as compounds identified using gas chromatography‐mass spectrometer (GC‐MS) and gas chromatography with flame‐ionization detection (GC‐FID) (terpenoids and catechols) or known to be present (phenolic acids and flavonoids). A 1:1 mixture of CL buffer and ethanol was chosen as working solution. AO capacity of essential oils and extracts, established by modified HPMC assay, was in range of 1.2‐2.0 and 9.2‐38.4 (%/mL) while terpenoids and phenolics in range of 0.1‐0.5 and 13.5‐38.5 (%/mol), respectively. The superior AO capacity was ascribed to essential oils and extracts of Lamiaceae species and to extracts obtained with 70% ethanol. A higher AO capacity of extracts in comparison to essential oils was corroborated with a difference in phenolics and terpenoids capacity.",
publisher = "Wiley",
journal = "Flavour and Fragrance Journal",
title = "Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles",
volume = "35",
pages = "219-226",
doi = "10.1002/ffj.3555"
}
Stojićević, A. S., Pastor, F. T., Gorjanović, S. Ž., Šolević Knudsen, T.,& Antić, M.. (2020). Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles. in Flavour and Fragrance Journal
Wiley., 35, 219-226.
https://doi.org/10.1002/ffj.3555
Stojićević AS, Pastor FT, Gorjanović SŽ, Šolević Knudsen T, Antić M. Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles. in Flavour and Fragrance Journal. 2020;35:219-226.
doi:10.1002/ffj.3555 .
Stojićević, Aleksandra S., Pastor, Ferenc T., Gorjanović, Stanislava Ž., Šolević Knudsen, Tatjana, Antić, Mališa, "Modification of DC polarographic antioxidant assay—Application to aromatic plants and their active principles" in Flavour and Fragrance Journal, 35 (2020):219-226,
https://doi.org/10.1002/ffj.3555 . .
2
2
2

Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment

Sostaric, Tatjana D.; Petrovic, Marija S.; Pastor, Ferenc T.; Lončarević, Davor; Petrovic, Jelena T.; Milojkovic, V Jelena; Stojanovic, Mirjana D.

(Elsevier, 2018)

TY  - JOUR
AU  - Sostaric, Tatjana D.
AU  - Petrovic, Marija S.
AU  - Pastor, Ferenc T.
AU  - Lončarević, Davor
AU  - Petrovic, Jelena T.
AU  - Milojkovic, V Jelena
AU  - Stojanovic, Mirjana D.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2295
AB  - Locally available apricot (Prunus armeniaca L.) shells classified as a waste product from fruit processing, were alkali activated in order to develop an efficient heavy metal ions sorbent for water purification. To examine the changes occurred after alkali treatment, raw (SH) and modified apricot shells (SHM) were thoroughly characterized in terms of their chemical composition and surface properties. Chemical analysis revealed that alkaline treatment causes the disintegration of hemicellulose (its content decreased from 19.2 to 3.5%), which was in accordance with FTIR results. SEM micrographs and the mercury intrusion porosimetry revealed a larger surface area and porosity of SHM. Bohem's acid-base titration method indicated that the most of the SHM surface carboxylic groups were in sodium salt form and together with the pH of points of zero charge showed increase of surface alkalinity after modification. Treatment with NaOH enhanced the adsorption capacity by 154, 61 and 90% for Cu2+, Zn2+ and Pb2+, respectively. The amount of cations released from SHM was almost equal to the amount of adsorbed metal ions, suggesting ion exchange mechanism. The pseudo-second order kinetic indicated that the heavy metals cations were bound predominantly by complexation. In order to establish the effectiveness of the biosorbent in real wastewater sample, SHM was employed for cleaning-up of drain water emanating from atomic adsorption spectrophotometer. The SHM showed high removal efficiency towards multiple metal ions. The amounts of Fe, Pb, Cu and Cr ions were reduced by 97, 87, 81 and 80%, respectively, while Ni and Zn amounts were reduced for 33 and 14%. Used biosorbent SHM can be successfully regenerated with HCl (desorption > 95%) and after regeneration biosorbent can be reused or it can be safely disposed.
PB  - Elsevier
T2  - Journal of Molecular Liquids
T1  - Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment
VL  - 259
SP  - 340
EP  - 349
DO  - 10.1016/j.molliq.2018.03.055
ER  - 
@article{
author = "Sostaric, Tatjana D. and Petrovic, Marija S. and Pastor, Ferenc T. and Lončarević, Davor and Petrovic, Jelena T. and Milojkovic, V Jelena and Stojanovic, Mirjana D.",
year = "2018",
abstract = "Locally available apricot (Prunus armeniaca L.) shells classified as a waste product from fruit processing, were alkali activated in order to develop an efficient heavy metal ions sorbent for water purification. To examine the changes occurred after alkali treatment, raw (SH) and modified apricot shells (SHM) were thoroughly characterized in terms of their chemical composition and surface properties. Chemical analysis revealed that alkaline treatment causes the disintegration of hemicellulose (its content decreased from 19.2 to 3.5%), which was in accordance with FTIR results. SEM micrographs and the mercury intrusion porosimetry revealed a larger surface area and porosity of SHM. Bohem's acid-base titration method indicated that the most of the SHM surface carboxylic groups were in sodium salt form and together with the pH of points of zero charge showed increase of surface alkalinity after modification. Treatment with NaOH enhanced the adsorption capacity by 154, 61 and 90% for Cu2+, Zn2+ and Pb2+, respectively. The amount of cations released from SHM was almost equal to the amount of adsorbed metal ions, suggesting ion exchange mechanism. The pseudo-second order kinetic indicated that the heavy metals cations were bound predominantly by complexation. In order to establish the effectiveness of the biosorbent in real wastewater sample, SHM was employed for cleaning-up of drain water emanating from atomic adsorption spectrophotometer. The SHM showed high removal efficiency towards multiple metal ions. The amounts of Fe, Pb, Cu and Cr ions were reduced by 97, 87, 81 and 80%, respectively, while Ni and Zn amounts were reduced for 33 and 14%. Used biosorbent SHM can be successfully regenerated with HCl (desorption > 95%) and after regeneration biosorbent can be reused or it can be safely disposed.",
publisher = "Elsevier",
journal = "Journal of Molecular Liquids",
title = "Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment",
volume = "259",
pages = "340-349",
doi = "10.1016/j.molliq.2018.03.055"
}
Sostaric, T. D., Petrovic, M. S., Pastor, F. T., Lončarević, D., Petrovic, J. T., Milojkovic, V. J.,& Stojanovic, M. D.. (2018). Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment. in Journal of Molecular Liquids
Elsevier., 259, 340-349.
https://doi.org/10.1016/j.molliq.2018.03.055
Sostaric TD, Petrovic MS, Pastor FT, Lončarević D, Petrovic JT, Milojkovic VJ, Stojanovic MD. Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment. in Journal of Molecular Liquids. 2018;259:340-349.
doi:10.1016/j.molliq.2018.03.055 .
Sostaric, Tatjana D., Petrovic, Marija S., Pastor, Ferenc T., Lončarević, Davor, Petrovic, Jelena T., Milojkovic, V Jelena, Stojanovic, Mirjana D., "Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment" in Journal of Molecular Liquids, 259 (2018):340-349,
https://doi.org/10.1016/j.molliq.2018.03.055 . .
85
40
82

Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment

Sostaric, Tatjana D.; Petrovic, Marija S.; Pastor, Ferenc T.; Lončarević, Davor; Petrovic, Jelena T.; Milojkovic, V Jelena; Stojanovic, Mirjana D.

(Elsevier, 2018)

TY  - JOUR
AU  - Sostaric, Tatjana D.
AU  - Petrovic, Marija S.
AU  - Pastor, Ferenc T.
AU  - Lončarević, Davor
AU  - Petrovic, Jelena T.
AU  - Milojkovic, V Jelena
AU  - Stojanovic, Mirjana D.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3338
AB  - Locally available apricot (Prunus armeniaca L.) shells classified as a waste product from fruit processing, were alkali activated in order to develop an efficient heavy metal ions sorbent for water purification. To examine the changes occurred after alkali treatment, raw (SH) and modified apricot shells (SHM) were thoroughly characterized in terms of their chemical composition and surface properties. Chemical analysis revealed that alkaline treatment causes the disintegration of hemicellulose (its content decreased from 19.2 to 3.5%), which was in accordance with FTIR results. SEM micrographs and the mercury intrusion porosimetry revealed a larger surface area and porosity of SHM. Bohem's acid-base titration method indicated that the most of the SHM surface carboxylic groups were in sodium salt form and together with the pH of points of zero charge showed increase of surface alkalinity after modification. Treatment with NaOH enhanced the adsorption capacity by 154, 61 and 90% for Cu2+, Zn2+ and Pb2+, respectively. The amount of cations released from SHM was almost equal to the amount of adsorbed metal ions, suggesting ion exchange mechanism. The pseudo-second order kinetic indicated that the heavy metals cations were bound predominantly by complexation. In order to establish the effectiveness of the biosorbent in real wastewater sample, SHM was employed for cleaning-up of drain water emanating from atomic adsorption spectrophotometer. The SHM showed high removal efficiency towards multiple metal ions. The amounts of Fe, Pb, Cu and Cr ions were reduced by 97, 87, 81 and 80%, respectively, while Ni and Zn amounts were reduced for 33 and 14%. Used biosorbent SHM can be successfully regenerated with HCl (desorption > 95%) and after regeneration biosorbent can be reused or it can be safely disposed.
PB  - Elsevier
T2  - Journal of Molecular Liquids
T1  - Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment
VL  - 259
SP  - 340
EP  - 349
DO  - 10.1016/j.molliq.2018.03.055
ER  - 
@article{
author = "Sostaric, Tatjana D. and Petrovic, Marija S. and Pastor, Ferenc T. and Lončarević, Davor and Petrovic, Jelena T. and Milojkovic, V Jelena and Stojanovic, Mirjana D.",
year = "2018",
abstract = "Locally available apricot (Prunus armeniaca L.) shells classified as a waste product from fruit processing, were alkali activated in order to develop an efficient heavy metal ions sorbent for water purification. To examine the changes occurred after alkali treatment, raw (SH) and modified apricot shells (SHM) were thoroughly characterized in terms of their chemical composition and surface properties. Chemical analysis revealed that alkaline treatment causes the disintegration of hemicellulose (its content decreased from 19.2 to 3.5%), which was in accordance with FTIR results. SEM micrographs and the mercury intrusion porosimetry revealed a larger surface area and porosity of SHM. Bohem's acid-base titration method indicated that the most of the SHM surface carboxylic groups were in sodium salt form and together with the pH of points of zero charge showed increase of surface alkalinity after modification. Treatment with NaOH enhanced the adsorption capacity by 154, 61 and 90% for Cu2+, Zn2+ and Pb2+, respectively. The amount of cations released from SHM was almost equal to the amount of adsorbed metal ions, suggesting ion exchange mechanism. The pseudo-second order kinetic indicated that the heavy metals cations were bound predominantly by complexation. In order to establish the effectiveness of the biosorbent in real wastewater sample, SHM was employed for cleaning-up of drain water emanating from atomic adsorption spectrophotometer. The SHM showed high removal efficiency towards multiple metal ions. The amounts of Fe, Pb, Cu and Cr ions were reduced by 97, 87, 81 and 80%, respectively, while Ni and Zn amounts were reduced for 33 and 14%. Used biosorbent SHM can be successfully regenerated with HCl (desorption > 95%) and after regeneration biosorbent can be reused or it can be safely disposed.",
publisher = "Elsevier",
journal = "Journal of Molecular Liquids",
title = "Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment",
volume = "259",
pages = "340-349",
doi = "10.1016/j.molliq.2018.03.055"
}
Sostaric, T. D., Petrovic, M. S., Pastor, F. T., Lončarević, D., Petrovic, J. T., Milojkovic, V. J.,& Stojanovic, M. D.. (2018). Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment. in Journal of Molecular Liquids
Elsevier., 259, 340-349.
https://doi.org/10.1016/j.molliq.2018.03.055
Sostaric TD, Petrovic MS, Pastor FT, Lončarević D, Petrovic JT, Milojkovic VJ, Stojanovic MD. Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment. in Journal of Molecular Liquids. 2018;259:340-349.
doi:10.1016/j.molliq.2018.03.055 .
Sostaric, Tatjana D., Petrovic, Marija S., Pastor, Ferenc T., Lončarević, Davor, Petrovic, Jelena T., Milojkovic, V Jelena, Stojanovic, Mirjana D., "Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment" in Journal of Molecular Liquids, 259 (2018):340-349,
https://doi.org/10.1016/j.molliq.2018.03.055 . .
85
40
82

Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays

Gorjanović, Stanislava Ž.; Alvarez-Suarez, Jose Miguel; Novaković, Miroslav; Pastor, Ferenc T.; Pezo, Lato; Battino, Maurizio; Suznjevic, Desanka Z.

(Academic Press Inc Elsevier Science, San Diego, 2013)

TY  - JOUR
AU  - Gorjanović, Stanislava Ž.
AU  - Alvarez-Suarez, Jose Miguel
AU  - Novaković, Miroslav
AU  - Pastor, Ferenc T.
AU  - Pezo, Lato
AU  - Battino, Maurizio
AU  - Suznjevic, Desanka Z.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1357
AB  - Hydrogen peroxide scavenging (HPS) activity of honey of different floral sources and its constituents such as predominant honey flavonoids, phenolic acids, amino and organic acids, and carbohydrates have been assessed by direct current (DC) polarographic assay. The assay was based on decrease of anodic current of hydrogen peroxide complex, formed in alkaline solution, at the potential of mercury dissolution. High correlations between honey HPS activity, its total phenolic content (FC-GAE), antioxidant activity measured by four standard methods (DPPH, TEAC, FRAP and ORAC), and also the relative antioxidant capacity index, were obtained. Statistical evaluation by ANOVA and F-test further confirmed the assay validity. The results for individual compounds showed that HPS activity of honey reflects an integrated action of a wide range of constituents, both phenolics and non-phenolics. The polarographic assay applied is a fast, reliable and low cost alternative to spectrophotometric antioxidant assays commonly applied in analysis of honey and can serve as an indicator of honey quality.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays
VL  - 30
IS  - 1
SP  - 13
EP  - 18
DO  - 10.1016/j.jfca.2012.12.004
ER  - 
@article{
author = "Gorjanović, Stanislava Ž. and Alvarez-Suarez, Jose Miguel and Novaković, Miroslav and Pastor, Ferenc T. and Pezo, Lato and Battino, Maurizio and Suznjevic, Desanka Z.",
year = "2013",
abstract = "Hydrogen peroxide scavenging (HPS) activity of honey of different floral sources and its constituents such as predominant honey flavonoids, phenolic acids, amino and organic acids, and carbohydrates have been assessed by direct current (DC) polarographic assay. The assay was based on decrease of anodic current of hydrogen peroxide complex, formed in alkaline solution, at the potential of mercury dissolution. High correlations between honey HPS activity, its total phenolic content (FC-GAE), antioxidant activity measured by four standard methods (DPPH, TEAC, FRAP and ORAC), and also the relative antioxidant capacity index, were obtained. Statistical evaluation by ANOVA and F-test further confirmed the assay validity. The results for individual compounds showed that HPS activity of honey reflects an integrated action of a wide range of constituents, both phenolics and non-phenolics. The polarographic assay applied is a fast, reliable and low cost alternative to spectrophotometric antioxidant assays commonly applied in analysis of honey and can serve as an indicator of honey quality.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays",
volume = "30",
number = "1",
pages = "13-18",
doi = "10.1016/j.jfca.2012.12.004"
}
Gorjanović, S. Ž., Alvarez-Suarez, J. M., Novaković, M., Pastor, F. T., Pezo, L., Battino, M.,& Suznjevic, D. Z.. (2013). Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 30(1), 13-18.
https://doi.org/10.1016/j.jfca.2012.12.004
Gorjanović SŽ, Alvarez-Suarez JM, Novaković M, Pastor FT, Pezo L, Battino M, Suznjevic DZ. Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays. in Journal of Food Composition and Analysis. 2013;30(1):13-18.
doi:10.1016/j.jfca.2012.12.004 .
Gorjanović, Stanislava Ž., Alvarez-Suarez, Jose Miguel, Novaković, Miroslav, Pastor, Ferenc T., Pezo, Lato, Battino, Maurizio, Suznjevic, Desanka Z., "Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays" in Journal of Food Composition and Analysis, 30, no. 1 (2013):13-18,
https://doi.org/10.1016/j.jfca.2012.12.004 . .
80
72
86

Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds

Gorjanović, Stanislava; Pastor, Ferenc T.; Vasic, Radica; Novaković, Miroslav; Simonović, Mladen; Milić, Sonja; Suznjevic, Desanka

(American Chemical Society (ACS), 2013)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc T.
AU  - Vasic, Radica
AU  - Novaković, Miroslav
AU  - Simonović, Mladen
AU  - Milić, Sonja
AU  - Suznjevic, Desanka
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1239
AB  - Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  LT  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin > catechin > rutin > xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.
PB  - American Chemical Society (ACS)
T2  - Journal of Agricultural and Food Chemistry
T1  - Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds
VL  - 61
IS  - 38
SP  - 9089
EP  - 9096
DO  - 10.1021/jf401718z
ER  - 
@article{
author = "Gorjanović, Stanislava and Pastor, Ferenc T. and Vasic, Radica and Novaković, Miroslav and Simonović, Mladen and Milić, Sonja and Suznjevic, Desanka",
year = "2013",
abstract = "Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  LT  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin > catechin > rutin > xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Agricultural and Food Chemistry",
title = "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds",
volume = "61",
number = "38",
pages = "9089-9096",
doi = "10.1021/jf401718z"
}
Gorjanović, S., Pastor, F. T., Vasic, R., Novaković, M., Simonović, M., Milić, S.,& Suznjevic, D.. (2013). Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry
American Chemical Society (ACS)., 61(38), 9089-9096.
https://doi.org/10.1021/jf401718z
Gorjanović S, Pastor FT, Vasic R, Novaković M, Simonović M, Milić S, Suznjevic D. Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry. 2013;61(38):9089-9096.
doi:10.1021/jf401718z .
Gorjanović, Stanislava, Pastor, Ferenc T., Vasic, Radica, Novaković, Miroslav, Simonović, Mladen, Milić, Sonja, Suznjevic, Desanka, "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds" in Journal of Agricultural and Food Chemistry, 61, no. 38 (2013):9089-9096,
https://doi.org/10.1021/jf401718z . .
25
23
29

Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids

Pastor, Ferenc T.; Drakulić, Branko

(Elsevier, 2010)

TY  - JOUR
AU  - Pastor, Ferenc T.
AU  - Drakulić, Branko
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5854
AB  - Half-wave reduction potentials of a set of twelve (E)-4-aryl-4-oxo-2-butenoic acids obtained by direct current polarography in methanol are reported. E1/2 is correlated with Hammett sigma values as well as with values of frontier molecular orbitals calculated at a semiempirical molecular orbital level. Constant potential electrolysis of a representative compound shows that the first polarographic wave corresponds to one-electron reduction. The isolation of the product proves reduction of the activated double bond.
PB  - Elsevier
T2  - Tetrahedron Letters
T1  - Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids
VL  - 51
IS  - 4
SP  - 734
EP  - 738
DO  - 10.1016/j.tetlet.2009.11.129
ER  - 
@article{
author = "Pastor, Ferenc T. and Drakulić, Branko",
year = "2010",
abstract = "Half-wave reduction potentials of a set of twelve (E)-4-aryl-4-oxo-2-butenoic acids obtained by direct current polarography in methanol are reported. E1/2 is correlated with Hammett sigma values as well as with values of frontier molecular orbitals calculated at a semiempirical molecular orbital level. Constant potential electrolysis of a representative compound shows that the first polarographic wave corresponds to one-electron reduction. The isolation of the product proves reduction of the activated double bond.",
publisher = "Elsevier",
journal = "Tetrahedron Letters",
title = "Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids",
volume = "51",
number = "4",
pages = "734-738",
doi = "10.1016/j.tetlet.2009.11.129"
}
Pastor, F. T.,& Drakulić, B.. (2010). Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids. in Tetrahedron Letters
Elsevier., 51(4), 734-738.
https://doi.org/10.1016/j.tetlet.2009.11.129
Pastor FT, Drakulić B. Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids. in Tetrahedron Letters. 2010;51(4):734-738.
doi:10.1016/j.tetlet.2009.11.129 .
Pastor, Ferenc T., Drakulić, Branko, "Linear free energy relationships of half-wave reduction potentials of (E)-4-aryl-4-oxo-2-butenoic acids" in Tetrahedron Letters, 51, no. 4 (2010):734-738,
https://doi.org/10.1016/j.tetlet.2009.11.129 . .
3
3
3

Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages

Gorjanović, Stanislava Ž.; Novaković, Miroslav; Vukosavljevic, Predrag V.; Pastor, Ferenc T.; Tešević, Vele; Sunjevic, Desanka Z.

(American Chemical Society (ACS), 2010)

TY  - JOUR
AU  - Gorjanović, Stanislava Ž.
AU  - Novaković, Miroslav
AU  - Vukosavljevic, Predrag V.
AU  - Pastor, Ferenc T.
AU  - Tešević, Vele
AU  - Sunjevic, Desanka Z.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/642
AB  - Total antioxidant (AO) activity of strong alcohol beverages such as wine and plum brandies, whiskeys, herbal and sweet fruit liqueurs have been assessed using a polarographic assay based on hydrogen peroxide scavenging (HPS). Rank of order of total AO activity, expressed as percentage of decrease of anodic oxidation current of hydrogen peroxide, was found analogous with total phenolic content estimated by Folin Ciocalteau (FC) assay and radical scavenging capacity against the stable free radical 1,1-dipheny1-2-picrylhydrazyl (DPPH). Application of the assay for surveying of a quarter century long maturation of plum brandy in oak barrel was demonstrated. In addition, influence of different storage conditions on preservation of AO activity of some herbal liqueurs was surveyed. Wide area of application of this simple, fast, low cost and reliable assay in analysis and quality monitoring of various strong alcohol beverages was confirmed.
PB  - American Chemical Society (ACS)
T2  - Journal of Agricultural and Food Chemistry
T1  - Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages
VL  - 58
IS  - 14
SP  - 8400
EP  - 8406
DO  - 10.1021/jf101158j
ER  - 
@article{
author = "Gorjanović, Stanislava Ž. and Novaković, Miroslav and Vukosavljevic, Predrag V. and Pastor, Ferenc T. and Tešević, Vele and Sunjevic, Desanka Z.",
year = "2010",
abstract = "Total antioxidant (AO) activity of strong alcohol beverages such as wine and plum brandies, whiskeys, herbal and sweet fruit liqueurs have been assessed using a polarographic assay based on hydrogen peroxide scavenging (HPS). Rank of order of total AO activity, expressed as percentage of decrease of anodic oxidation current of hydrogen peroxide, was found analogous with total phenolic content estimated by Folin Ciocalteau (FC) assay and radical scavenging capacity against the stable free radical 1,1-dipheny1-2-picrylhydrazyl (DPPH). Application of the assay for surveying of a quarter century long maturation of plum brandy in oak barrel was demonstrated. In addition, influence of different storage conditions on preservation of AO activity of some herbal liqueurs was surveyed. Wide area of application of this simple, fast, low cost and reliable assay in analysis and quality monitoring of various strong alcohol beverages was confirmed.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Agricultural and Food Chemistry",
title = "Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages",
volume = "58",
number = "14",
pages = "8400-8406",
doi = "10.1021/jf101158j"
}
Gorjanović, S. Ž., Novaković, M., Vukosavljevic, P. V., Pastor, F. T., Tešević, V.,& Sunjevic, D. Z.. (2010). Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages. in Journal of Agricultural and Food Chemistry
American Chemical Society (ACS)., 58(14), 8400-8406.
https://doi.org/10.1021/jf101158j
Gorjanović SŽ, Novaković M, Vukosavljevic PV, Pastor FT, Tešević V, Sunjevic DZ. Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages. in Journal of Agricultural and Food Chemistry. 2010;58(14):8400-8406.
doi:10.1021/jf101158j .
Gorjanović, Stanislava Ž., Novaković, Miroslav, Vukosavljevic, Predrag V., Pastor, Ferenc T., Tešević, Vele, Sunjevic, Desanka Z., "Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages" in Journal of Agricultural and Food Chemistry, 58, no. 14 (2010):8400-8406,
https://doi.org/10.1021/jf101158j . .
40
43
48

Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry

Minić, Dragica M.; Cekić, I.; Pastor, Ferenc T.; Jovanović, Vladislava M.; Marković, Rade

(Maik Nauka/Interperiodica/Springer, New York, 2007)

TY  - CONF
AU  - Minić, Dragica M.
AU  - Cekić, I.
AU  - Pastor, Ferenc T.
AU  - Jovanović, Vladislava M.
AU  - Marković, Rade
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/352
AB  - This study demonstrates the electrochemical activity of selected 2-alkylidene-4-oxothiazolidine compounds containing different substituents at the C5-position on the Pt-electrode in 0.1 M TBAHFP + MeCN in the potential range from -2 V to 2 V. The mechanism of electrode processes is discussed. It is shown that a chemical step is involved in irreversible electrochemical processes. The effect of the substituent at the C5-position on reduction and oxidation potentials is also noted. The regions of a linear dependence of the current peak on the concentration of the compounds examined are determined.
PB  - Maik Nauka/Interperiodica/Springer, New York
C3  - Russian Journal of Physical Chemistry A
T1  - Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry
VL  - 81
IS  - 9
SP  - 1458
EP  - 1462
DO  - 10.1134/S003602440709021X
ER  - 
@conference{
author = "Minić, Dragica M. and Cekić, I. and Pastor, Ferenc T. and Jovanović, Vladislava M. and Marković, Rade",
year = "2007",
abstract = "This study demonstrates the electrochemical activity of selected 2-alkylidene-4-oxothiazolidine compounds containing different substituents at the C5-position on the Pt-electrode in 0.1 M TBAHFP + MeCN in the potential range from -2 V to 2 V. The mechanism of electrode processes is discussed. It is shown that a chemical step is involved in irreversible electrochemical processes. The effect of the substituent at the C5-position on reduction and oxidation potentials is also noted. The regions of a linear dependence of the current peak on the concentration of the compounds examined are determined.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry",
volume = "81",
number = "9",
pages = "1458-1462",
doi = "10.1134/S003602440709021X"
}
Minić, D. M., Cekić, I., Pastor, F. T., Jovanović, V. M.,& Marković, R.. (2007). Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 81(9), 1458-1462.
https://doi.org/10.1134/S003602440709021X
Minić DM, Cekić I, Pastor FT, Jovanović VM, Marković R. Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry. in Russian Journal of Physical Chemistry A. 2007;81(9):1458-1462.
doi:10.1134/S003602440709021X .
Minić, Dragica M., Cekić, I., Pastor, Ferenc T., Jovanović, Vladislava M., Marković, Rade, "Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry" in Russian Journal of Physical Chemistry A, 81, no. 9 (2007):1458-1462,
https://doi.org/10.1134/S003602440709021X . .
2
2
2