Terlecki-Baričević, Ana V.

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  • Terlecki-Baričević, Ana V. (12)
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Author's Bibliography

Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts

Khristova, M.S.; Petrović, Srđan; Terlecki-Baričević, Ana V.; Mehandjiev, D.R.

(Versita, Warsaw, 2009)

TY  - JOUR
AU  - Khristova, M.S.
AU  - Petrović, Srđan
AU  - Terlecki-Baričević, Ana V.
AU  - Mehandjiev, D.R.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/621
AB  - The perovskite type oxides (nominal formula LaTi0.5 Mg0.5O3) with addition of Pd were prepared by annealing the ethanol solution of precursors in nitrogen flow at 1200°C and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of NO (NO-TPD). Their activity was evaluated for NO reduction by CO under stoichiometric and oxidizing conditions and for direct decomposition of NO. Pd substituted samples exhibited high NO reduction activity and selectivity towards N2. Nearly complete elimination of NO was achieved at 200°C. Two simultaneous reactions, NO reduction by CO and direct decomposition of NO as well as two forms of NO adsorption were observed on the surface of Pd substituted perovskite samples. The distribution of Pd in different catalytically active sites or complexes on at the catalyst surface may be responsible for the proceeding of two reactions: NO reduction with CO and direct NO decomposition.
PB  - Versita, Warsaw
T2  - Central European Journal of Chemistry
T1  - Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts
VL  - 7
IS  - 4
SP  - 857
EP  - 863
DO  - 10.2478/s11532-009-0065-4
ER  - 
@article{
author = "Khristova, M.S. and Petrović, Srđan and Terlecki-Baričević, Ana V. and Mehandjiev, D.R.",
year = "2009",
abstract = "The perovskite type oxides (nominal formula LaTi0.5 Mg0.5O3) with addition of Pd were prepared by annealing the ethanol solution of precursors in nitrogen flow at 1200°C and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of NO (NO-TPD). Their activity was evaluated for NO reduction by CO under stoichiometric and oxidizing conditions and for direct decomposition of NO. Pd substituted samples exhibited high NO reduction activity and selectivity towards N2. Nearly complete elimination of NO was achieved at 200°C. Two simultaneous reactions, NO reduction by CO and direct decomposition of NO as well as two forms of NO adsorption were observed on the surface of Pd substituted perovskite samples. The distribution of Pd in different catalytically active sites or complexes on at the catalyst surface may be responsible for the proceeding of two reactions: NO reduction with CO and direct NO decomposition.",
publisher = "Versita, Warsaw",
journal = "Central European Journal of Chemistry",
title = "Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts",
volume = "7",
number = "4",
pages = "857-863",
doi = "10.2478/s11532-009-0065-4"
}
Khristova, M.S., Petrović, S., Terlecki-Baričević, A. V.,& Mehandjiev, D.R.. (2009). Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts. in Central European Journal of Chemistry
Versita, Warsaw., 7(4), 857-863.
https://doi.org/10.2478/s11532-009-0065-4
Khristova M, Petrović S, Terlecki-Baričević AV, Mehandjiev D. Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts. in Central European Journal of Chemistry. 2009;7(4):857-863.
doi:10.2478/s11532-009-0065-4 .
Khristova, M.S., Petrović, Srđan, Terlecki-Baričević, Ana V., Mehandjiev, D.R., "Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts" in Central European Journal of Chemistry, 7, no. 4 (2009):857-863,
https://doi.org/10.2478/s11532-009-0065-4 . .
10
8
10

LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation

Petrović, Srđan; Terlecki-Baričević, Ana V.; Karanovic, Lj.; Kirilov-Stefanov, P.; Zdujić, Miodrag; Dondur, Vera; Paneva, Daniela; Mitov, I.; Rakić, Vesna M.

(Elsevier, 2008)

TY  - JOUR
AU  - Petrović, Srđan
AU  - Terlecki-Baričević, Ana V.
AU  - Karanovic, Lj.
AU  - Kirilov-Stefanov, P.
AU  - Zdujić, Miodrag
AU  - Dondur, Vera
AU  - Paneva, Daniela
AU  - Mitov, I.
AU  - Rakić, Vesna M.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/399
AB  - Two new series of perovskite-type oxides LaMO3 (M = Mg, Ti, Fe) with different ratio Mg/Fe (MF) and Ti/Fe (TF) in the B cation site were prepared by annealing the precursor, obtained by the mechanochemical activation (MCA) of constituent metal oxides, at 1000 degrees C in air. In addition, two closely related perovskites LaFeO3 (LF) and LaTi0.5Mg0.5O3 (TM (50:50)) were synthesized in the similar way. Using MCA method, perovskites were obtained in rather short time and at room temperature. The samples were characterized by X-ray powder diffraction (XRPD), Xray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), temperature programmed desorption of oxygen (TPD), Mossbauer spectroscopy, BET surface area measurements and tested in methane deep oxidation. According to XRPD analysis all synthesized samples are almost single perovskite phase, with trace amounts of La2O3 phase. Data of Mossbauer spectroscopy identify Fe 31 in octahedral coordination. The activity of perovskite in methane deep oxidation increases in the order TM (50:50)  LT  MF series  LT  TF series. Higher activity of TF samples in respect to MF with similar Fe content can be related to the structural characteristic., mainly to the presence of predominantly most labile oxygen species evidenced by TPD at lowest temperature of oxygen evaluation. In used experimental conditions, the Fe substituted perovskite are thermal stable up to the temperature of 850 degrees C. The stability of Fe active sites is probably the most important parameter responsible for thermal stability of perovskite, but the atomic surface composition also should be taken into account.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation
VL  - 79
IS  - 2
SP  - 186
EP  - 198
DO  - 10.1016/j.apcatb.2007.10.022
ER  - 
@article{
author = "Petrović, Srđan and Terlecki-Baričević, Ana V. and Karanovic, Lj. and Kirilov-Stefanov, P. and Zdujić, Miodrag and Dondur, Vera and Paneva, Daniela and Mitov, I. and Rakić, Vesna M.",
year = "2008",
abstract = "Two new series of perovskite-type oxides LaMO3 (M = Mg, Ti, Fe) with different ratio Mg/Fe (MF) and Ti/Fe (TF) in the B cation site were prepared by annealing the precursor, obtained by the mechanochemical activation (MCA) of constituent metal oxides, at 1000 degrees C in air. In addition, two closely related perovskites LaFeO3 (LF) and LaTi0.5Mg0.5O3 (TM (50:50)) were synthesized in the similar way. Using MCA method, perovskites were obtained in rather short time and at room temperature. The samples were characterized by X-ray powder diffraction (XRPD), Xray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), temperature programmed desorption of oxygen (TPD), Mossbauer spectroscopy, BET surface area measurements and tested in methane deep oxidation. According to XRPD analysis all synthesized samples are almost single perovskite phase, with trace amounts of La2O3 phase. Data of Mossbauer spectroscopy identify Fe 31 in octahedral coordination. The activity of perovskite in methane deep oxidation increases in the order TM (50:50)  LT  MF series  LT  TF series. Higher activity of TF samples in respect to MF with similar Fe content can be related to the structural characteristic., mainly to the presence of predominantly most labile oxygen species evidenced by TPD at lowest temperature of oxygen evaluation. In used experimental conditions, the Fe substituted perovskite are thermal stable up to the temperature of 850 degrees C. The stability of Fe active sites is probably the most important parameter responsible for thermal stability of perovskite, but the atomic surface composition also should be taken into account.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation",
volume = "79",
number = "2",
pages = "186-198",
doi = "10.1016/j.apcatb.2007.10.022"
}
Petrović, S., Terlecki-Baričević, A. V., Karanovic, Lj., Kirilov-Stefanov, P., Zdujić, M., Dondur, V., Paneva, D., Mitov, I.,& Rakić, V. M.. (2008). LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation. in Applied Catalysis B-Environmental
Elsevier., 79(2), 186-198.
https://doi.org/10.1016/j.apcatb.2007.10.022
Petrović S, Terlecki-Baričević AV, Karanovic L, Kirilov-Stefanov P, Zdujić M, Dondur V, Paneva D, Mitov I, Rakić VM. LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation. in Applied Catalysis B-Environmental. 2008;79(2):186-198.
doi:10.1016/j.apcatb.2007.10.022 .
Petrović, Srđan, Terlecki-Baričević, Ana V., Karanovic, Lj., Kirilov-Stefanov, P., Zdujić, Miodrag, Dondur, Vera, Paneva, Daniela, Mitov, I., Rakić, Vesna M., "LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation" in Applied Catalysis B-Environmental, 79, no. 2 (2008):186-198,
https://doi.org/10.1016/j.apcatb.2007.10.022 . .
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81

Catalytic combustion of methane over Pd containing perovskite type oxides

Petrović, Srđan; Karanovic, L; Stefanov, PK; Zdujić, Miodrag; Terlecki-Baričević, Ana V.

(Elsevier, 2005)

TY  - JOUR
AU  - Petrović, Srđan
AU  - Karanovic, L
AU  - Stefanov, PK
AU  - Zdujić, Miodrag
AU  - Terlecki-Baričević, Ana V.
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/180
AB  - The mixed perovskite type oxides with nominal formula LaTi0.5Mg0.5-xPdxO3, (0  LT = x  LT = 0.10) were prepared by anneling the ethanol solution of precursor in nitrogen flow at 1200 degrees C. X-ray powder diffraction (XRPD) analysis shows that the orthorhombic perovskite structure was found in all investigated samples. However, at least a part of palladium is not incorporated into perovskite structure and remains as separate phase, which is reduced to Pd-0 at 1200 degrees C. X-ray photoelectron spectroscopy (XPS) reveled the presence of Pd2+, which indicate a reoxidation of Pd-0 in the surface layers during cooling. The Pd content in the samples has a small influence on the methane oxidation activity below the temperature of 500 degrees C. At temperatures higher than 500 C, the methane oxidation activity of the sample with x = 0.05 exceeds the activity of the sample with x = 0.10. The sharp increase of methane oxidation activity over the sample with lower content of palladium at about 500 degrees C was ascribed to the higher dispersion of PdO and Pd-0 phases. Thus, the higher contribution of lattice oxygen and possible local change in oxidation state of palladium can be a reason for the enhanced activity. Contrary to the supported Pd/Al2O3 catalyst, the incorporation of palladium into perovskite matrix and interaction of PdO-Pd-0 benefits the activity of smaller particles at higher reaction temperatures.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - Catalytic combustion of methane over Pd containing perovskite type oxides
VL  - 58
IS  - 1-2
SP  - 133
EP  - 141
DO  - 10.1016/j.apcatb.2004.11.020
ER  - 
@article{
author = "Petrović, Srđan and Karanovic, L and Stefanov, PK and Zdujić, Miodrag and Terlecki-Baričević, Ana V.",
year = "2005",
abstract = "The mixed perovskite type oxides with nominal formula LaTi0.5Mg0.5-xPdxO3, (0  LT = x  LT = 0.10) were prepared by anneling the ethanol solution of precursor in nitrogen flow at 1200 degrees C. X-ray powder diffraction (XRPD) analysis shows that the orthorhombic perovskite structure was found in all investigated samples. However, at least a part of palladium is not incorporated into perovskite structure and remains as separate phase, which is reduced to Pd-0 at 1200 degrees C. X-ray photoelectron spectroscopy (XPS) reveled the presence of Pd2+, which indicate a reoxidation of Pd-0 in the surface layers during cooling. The Pd content in the samples has a small influence on the methane oxidation activity below the temperature of 500 degrees C. At temperatures higher than 500 C, the methane oxidation activity of the sample with x = 0.05 exceeds the activity of the sample with x = 0.10. The sharp increase of methane oxidation activity over the sample with lower content of palladium at about 500 degrees C was ascribed to the higher dispersion of PdO and Pd-0 phases. Thus, the higher contribution of lattice oxygen and possible local change in oxidation state of palladium can be a reason for the enhanced activity. Contrary to the supported Pd/Al2O3 catalyst, the incorporation of palladium into perovskite matrix and interaction of PdO-Pd-0 benefits the activity of smaller particles at higher reaction temperatures.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "Catalytic combustion of methane over Pd containing perovskite type oxides",
volume = "58",
number = "1-2",
pages = "133-141",
doi = "10.1016/j.apcatb.2004.11.020"
}
Petrović, S., Karanovic, L., Stefanov, P., Zdujić, M.,& Terlecki-Baričević, A. V.. (2005). Catalytic combustion of methane over Pd containing perovskite type oxides. in Applied Catalysis B-Environmental
Elsevier., 58(1-2), 133-141.
https://doi.org/10.1016/j.apcatb.2004.11.020
Petrović S, Karanovic L, Stefanov P, Zdujić M, Terlecki-Baričević AV. Catalytic combustion of methane over Pd containing perovskite type oxides. in Applied Catalysis B-Environmental. 2005;58(1-2):133-141.
doi:10.1016/j.apcatb.2004.11.020 .
Petrović, Srđan, Karanovic, L, Stefanov, PK, Zdujić, Miodrag, Terlecki-Baričević, Ana V., "Catalytic combustion of methane over Pd containing perovskite type oxides" in Applied Catalysis B-Environmental, 58, no. 1-2 (2005):133-141,
https://doi.org/10.1016/j.apcatb.2004.11.020 . .
36
40
44

Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture

Grbić, Boško; Radić, Nenad; Terlecki-Baričević, Ana V.

(Elsevier, 2004)

TY  - JOUR
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Terlecki-Baričević, Ana V.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4077
AB  - The oxidation of n-hexane and toluene mixtures in air over Pt/Al2O3 catalysts with mean Pt crystallite sizes of 1.0 and 15.5 nm has been studied. Measurements were performed in an external recycle reactor at temperatures in the range of 120–181 °C, in a concentration range of one hydrocarbon from 500 to 10,000 ppm. The mutual inhibition of the oxidation activity of n-hexane and toluene in the mixtures was observed for both Pt crystallite sizes. The structure sensitivity previously established for the oxidation of single components remains valid for their mixture. The mixture model oxidation based on a Mars van Krevelen mechanism fits very well experimental data at lower temperatures (for n-hexane: 148–160 °C; for toluene: 120–140 °C), whereas at higher temperatures the model predicts higher values for catalysts with both Pt crystallite sizes. The mixture model based on equilibrium adsorption of hydrocarbons and strong adsorption of oxygen fits exceptionally well experimental data in the whole investigated temperature range. For catalysts with a mean Pt crystallite size of 1.0 nm the evaluated ratio of adsorption coefficients of n-hexane and toluene is 9, and for the catalysts with a mean Pt crystallite size of 15.5 nm the ratio is 0.13. The evaluated ratios of adsorption coefficients point out that n-hexane is more strongly bound than toluene for catalysts with smaller Pt crystallites, while at larger Pt crystallites toluene is more strongly adsorbed than n-hexane.
PB  - Elsevier
T2  - Applied Catalysis B - Environmental
T1  - Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture
VL  - 50
IS  - 3
SP  - 161
EP  - 166
DO  - 10.1016/j.apcatb.2004.01.012
ER  - 
@article{
author = "Grbić, Boško and Radić, Nenad and Terlecki-Baričević, Ana V.",
year = "2004",
abstract = "The oxidation of n-hexane and toluene mixtures in air over Pt/Al2O3 catalysts with mean Pt crystallite sizes of 1.0 and 15.5 nm has been studied. Measurements were performed in an external recycle reactor at temperatures in the range of 120–181 °C, in a concentration range of one hydrocarbon from 500 to 10,000 ppm. The mutual inhibition of the oxidation activity of n-hexane and toluene in the mixtures was observed for both Pt crystallite sizes. The structure sensitivity previously established for the oxidation of single components remains valid for their mixture. The mixture model oxidation based on a Mars van Krevelen mechanism fits very well experimental data at lower temperatures (for n-hexane: 148–160 °C; for toluene: 120–140 °C), whereas at higher temperatures the model predicts higher values for catalysts with both Pt crystallite sizes. The mixture model based on equilibrium adsorption of hydrocarbons and strong adsorption of oxygen fits exceptionally well experimental data in the whole investigated temperature range. For catalysts with a mean Pt crystallite size of 1.0 nm the evaluated ratio of adsorption coefficients of n-hexane and toluene is 9, and for the catalysts with a mean Pt crystallite size of 15.5 nm the ratio is 0.13. The evaluated ratios of adsorption coefficients point out that n-hexane is more strongly bound than toluene for catalysts with smaller Pt crystallites, while at larger Pt crystallites toluene is more strongly adsorbed than n-hexane.",
publisher = "Elsevier",
journal = "Applied Catalysis B - Environmental",
title = "Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture",
volume = "50",
number = "3",
pages = "161-166",
doi = "10.1016/j.apcatb.2004.01.012"
}
Grbić, B., Radić, N.,& Terlecki-Baričević, A. V.. (2004). Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture. in Applied Catalysis B - Environmental
Elsevier., 50(3), 161-166.
https://doi.org/10.1016/j.apcatb.2004.01.012
Grbić B, Radić N, Terlecki-Baričević AV. Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture. in Applied Catalysis B - Environmental. 2004;50(3):161-166.
doi:10.1016/j.apcatb.2004.01.012 .
Grbić, Boško, Radić, Nenad, Terlecki-Baričević, Ana V., "Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture" in Applied Catalysis B - Environmental, 50, no. 3 (2004):161-166,
https://doi.org/10.1016/j.apcatb.2004.01.012 . .
49
51
56

Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect

Radić, Nenad; Grbić, Boško; Terlecki-Baričević, Ana V.

(Elsevier, 2004)

TY  - JOUR
AU  - Radić, Nenad
AU  - Grbić, Boško
AU  - Terlecki-Baričević, Ana V.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4118
AB  - The kinetics of n-hexane and toluene complete oxidation has been studied over 0.12% Pt/Al 2 O 3 catalysts. Measurements were performed in an external recycle reactor. Reaction rates were measured as a function of temperature and reactants concentrations for two platinum crystallite sizes, 1.0 and 15.5 nm. The turnover frequency (TOF) for the oxidation of both hydrocarbons is about 10 times higher for the 15.5 nm than for the 1.0 nm Pt crystallite size. The reaction constants are calculated according to Mars van Krevelen (MVK) mechanism. The oxygen chemisorption rate constant (k O ) is the same during the n-hexane and the toluene oxidation for each sizes of platinum crystallite. For both hydrocarbons the oxygen chemisorption rate constant and the surface reaction rate constant (k i ) are higher for 15.5 nm than for 1.0 nm crystallite size. The activation energy for k O decreases with the increase of the Pt crystallite size. The activation energy for k i is independent on the Pt crystallite size for both hydrocarbons. The values of kinetic constants reveal that the increase of the reaction rate for large Pt crystallites could be related to the lower activation energy for k O . This implies that on large Pt crystallites oxygen is held on Pt atoms with a lower bond strength that on small Pt crystallites, which explains the structure sensitivity found for n-hexane and toluene oxidation.
PB  - Elsevier
T2  - Applied Catalysis B: Environmental
T1  - Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect
VL  - 50
IS  - 3
SP  - 153
EP  - 159
DO  - 10.1016/j.apcatb.2004.01.011
ER  - 
@article{
author = "Radić, Nenad and Grbić, Boško and Terlecki-Baričević, Ana V.",
year = "2004",
abstract = "The kinetics of n-hexane and toluene complete oxidation has been studied over 0.12% Pt/Al 2 O 3 catalysts. Measurements were performed in an external recycle reactor. Reaction rates were measured as a function of temperature and reactants concentrations for two platinum crystallite sizes, 1.0 and 15.5 nm. The turnover frequency (TOF) for the oxidation of both hydrocarbons is about 10 times higher for the 15.5 nm than for the 1.0 nm Pt crystallite size. The reaction constants are calculated according to Mars van Krevelen (MVK) mechanism. The oxygen chemisorption rate constant (k O ) is the same during the n-hexane and the toluene oxidation for each sizes of platinum crystallite. For both hydrocarbons the oxygen chemisorption rate constant and the surface reaction rate constant (k i ) are higher for 15.5 nm than for 1.0 nm crystallite size. The activation energy for k O decreases with the increase of the Pt crystallite size. The activation energy for k i is independent on the Pt crystallite size for both hydrocarbons. The values of kinetic constants reveal that the increase of the reaction rate for large Pt crystallites could be related to the lower activation energy for k O . This implies that on large Pt crystallites oxygen is held on Pt atoms with a lower bond strength that on small Pt crystallites, which explains the structure sensitivity found for n-hexane and toluene oxidation.",
publisher = "Elsevier",
journal = "Applied Catalysis B: Environmental",
title = "Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect",
volume = "50",
number = "3",
pages = "153-159",
doi = "10.1016/j.apcatb.2004.01.011"
}
Radić, N., Grbić, B.,& Terlecki-Baričević, A. V.. (2004). Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect. in Applied Catalysis B: Environmental
Elsevier., 50(3), 153-159.
https://doi.org/10.1016/j.apcatb.2004.01.011
Radić N, Grbić B, Terlecki-Baričević AV. Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect. in Applied Catalysis B: Environmental. 2004;50(3):153-159.
doi:10.1016/j.apcatb.2004.01.011 .
Radić, Nenad, Grbić, Boško, Terlecki-Baričević, Ana V., "Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts: Platinum crystallite size effect" in Applied Catalysis B: Environmental, 50, no. 3 (2004):153-159,
https://doi.org/10.1016/j.apcatb.2004.01.011 . .
124
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123

Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]

Skala, Dejan; Orlović, Aleksandar; Marković, Bojana; Terlecki-Baričević, Ana V.; Jovanović, D.

(Association of the Chemical Engineers of Serbia, 2002)

TY  - JOUR
AU  - Skala, Dejan
AU  - Orlović, Aleksandar
AU  - Marković, Bojana
AU  - Terlecki-Baričević, Ana V.
AU  - Jovanović, D.
PY  - 2002
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/83
AB  - The performed investigations were directed toward the analysis of the performance and activity of the fresh and regenerated Cyanamid HDS 20C catalyst in a laboratory batch reactor (2 dm3) for the HDS of the diesel fraction (light gas oil, LGO). Testing of the regenerated catalyst was performed with light gas oil (LGO) of different characteristics. The determined values of the reaction rate constant were compared to some published data in the literature for the HDS of specific sulfur compounds as well as the values of the activation energy. The rates of deactivation of the fresh and regenerated catalyst actually existed compared to some other results recently published in the literature. However, such an observed differences were not sufficient to derive a relation which could be used for the determination of the rate of catalyst deactivation.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]
VL  - 8
IS  - 4
SP  - 529
EP  - 532
UR  - https://hdl.handle.net/21.15107/rcub_cer_83
ER  - 
@article{
author = "Skala, Dejan and Orlović, Aleksandar and Marković, Bojana and Terlecki-Baričević, Ana V. and Jovanović, D.",
year = "2002",
abstract = "The performed investigations were directed toward the analysis of the performance and activity of the fresh and regenerated Cyanamid HDS 20C catalyst in a laboratory batch reactor (2 dm3) for the HDS of the diesel fraction (light gas oil, LGO). Testing of the regenerated catalyst was performed with light gas oil (LGO) of different characteristics. The determined values of the reaction rate constant were compared to some published data in the literature for the HDS of specific sulfur compounds as well as the values of the activation energy. The rates of deactivation of the fresh and regenerated catalyst actually existed compared to some other results recently published in the literature. However, such an observed differences were not sufficient to derive a relation which could be used for the determination of the rate of catalyst deactivation.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]",
volume = "8",
number = "4",
pages = "529-532",
url = "https://hdl.handle.net/21.15107/rcub_cer_83"
}
Skala, D., Orlović, A., Marković, B., Terlecki-Baričević, A. V.,& Jovanović, D.. (2002). Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Association of the Chemical Engineers of Serbia., 8(4), 529-532.
https://hdl.handle.net/21.15107/rcub_cer_83
Skala D, Orlović A, Marković B, Terlecki-Baričević AV, Jovanović D. Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2002;8(4):529-532.
https://hdl.handle.net/21.15107/rcub_cer_83 .
Skala, Dejan, Orlović, Aleksandar, Marković, Bojana, Terlecki-Baričević, Ana V., Jovanović, D., "Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 8, no. 4 (2002):529-532,
https://hdl.handle.net/21.15107/rcub_cer_83 .

The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport

Rožić, Ljiljana; Novaković, Tatjana; Jovanović, Nadežda N.; Terlecki-Baričević, Ana V.; Grbavčić, Željko

(Serbian Chemical Society, 2001)

TY  - JOUR
AU  - Rožić, Ljiljana
AU  - Novaković, Tatjana
AU  - Jovanović, Nadežda N.
AU  - Terlecki-Baričević, Ana V.
AU  - Grbavčić, Željko
PY  - 2001
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/32
AB  - The dehydration kinetics of gibbsite to activated alumina was investigated at four different temperatures between 883 K and 943 K in a reactor for pneumatic transport in the dilute two phase flow regime. The first order kinetic behavior of this reaction with respect to the water content of the solid material was proved and an activation energy of 66.5 kJ/mol was calculated. The effect of residence time on the water content is given and compared with theoretical calculations. The water content and other characteristics of the products depend on two main parameters, one is the short residence time and the other is the temperature of the dehydration of gibbsite. The short residence time of the gibbsite particles in a reactor for pneumatic transport prevents crystallization into new phases, as established from XRD analysis data. Reactive amorphous alumina powder, with a specific surface area of 250 m2/g, suitable as a precursor for catalyst supports is obtained.
AB  - Kratkovremena termička razgradnja gibsita je vršena u reaktoru za pneumatski transport čestica na temperaturama iznad 883 K i vremenu boravka ispod 1 sekunde. Dobijeni aktivirani prah ima visok stepen amorfizacije i mali procenat polaznog gibsita utvrđen rendgenostrukturnom analizom. Kinetika parcijalne dehidratacije gibsita je određivana u temperaturnom intervalu od 883 K do 943 K. Pokazano je da je reakcija dehidratacije gibsita prvog reda u odnosu na sadržaj vode u čvrstom materijalu i izračunata energija aktivacije iznosi 66.5 kJ/mol. Određeno je optimalno vreme boravka čestica gibsita i temperatura dehidratacije gibsita u poluindustrijskom postrojenju, kao i uticaj temperature aktivacije na sadržaj vode u aktiviranom produktu.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport
T1  - Kinetika parcijalne dehidratacije gibsita u reaktoru sa pneumatskim transportom
VL  - 66
IS  - 4
SP  - 273
EP  - 280
UR  - https://hdl.handle.net/21.15107/rcub_cer_32
ER  - 
@article{
author = "Rožić, Ljiljana and Novaković, Tatjana and Jovanović, Nadežda N. and Terlecki-Baričević, Ana V. and Grbavčić, Željko",
year = "2001",
abstract = "The dehydration kinetics of gibbsite to activated alumina was investigated at four different temperatures between 883 K and 943 K in a reactor for pneumatic transport in the dilute two phase flow regime. The first order kinetic behavior of this reaction with respect to the water content of the solid material was proved and an activation energy of 66.5 kJ/mol was calculated. The effect of residence time on the water content is given and compared with theoretical calculations. The water content and other characteristics of the products depend on two main parameters, one is the short residence time and the other is the temperature of the dehydration of gibbsite. The short residence time of the gibbsite particles in a reactor for pneumatic transport prevents crystallization into new phases, as established from XRD analysis data. Reactive amorphous alumina powder, with a specific surface area of 250 m2/g, suitable as a precursor for catalyst supports is obtained., Kratkovremena termička razgradnja gibsita je vršena u reaktoru za pneumatski transport čestica na temperaturama iznad 883 K i vremenu boravka ispod 1 sekunde. Dobijeni aktivirani prah ima visok stepen amorfizacije i mali procenat polaznog gibsita utvrđen rendgenostrukturnom analizom. Kinetika parcijalne dehidratacije gibsita je određivana u temperaturnom intervalu od 883 K do 943 K. Pokazano je da je reakcija dehidratacije gibsita prvog reda u odnosu na sadržaj vode u čvrstom materijalu i izračunata energija aktivacije iznosi 66.5 kJ/mol. Određeno je optimalno vreme boravka čestica gibsita i temperatura dehidratacije gibsita u poluindustrijskom postrojenju, kao i uticaj temperature aktivacije na sadržaj vode u aktiviranom produktu.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport, Kinetika parcijalne dehidratacije gibsita u reaktoru sa pneumatskim transportom",
volume = "66",
number = "4",
pages = "273-280",
url = "https://hdl.handle.net/21.15107/rcub_cer_32"
}
Rožić, L., Novaković, T., Jovanović, N. N., Terlecki-Baričević, A. V.,& Grbavčić, Ž.. (2001). The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 66(4), 273-280.
https://hdl.handle.net/21.15107/rcub_cer_32
Rožić L, Novaković T, Jovanović NN, Terlecki-Baričević AV, Grbavčić Ž. The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport. in Journal of the Serbian Chemical Society. 2001;66(4):273-280.
https://hdl.handle.net/21.15107/rcub_cer_32 .
Rožić, Ljiljana, Novaković, Tatjana, Jovanović, Nadežda N., Terlecki-Baričević, Ana V., Grbavčić, Željko, "The kinetics of the partial dehydration of gibbsite to activated alumina in a reactor for pneumatic transport" in Journal of the Serbian Chemical Society, 66, no. 4 (2001):273-280,
https://hdl.handle.net/21.15107/rcub_cer_32 .

Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites

Terlecki-Baričević, Ana V.; Petrović, Srđan; Jovanović, Dušan M.; Karanović, Lj.; Marinova, C.

(Serbian Chemical Society, 2000)

TY  - JOUR
AU  - Terlecki-Baričević, Ana V.
AU  - Petrović, Srđan
AU  - Jovanović, Dušan M.
AU  - Karanović, Lj.
AU  - Marinova, C.
PY  - 2000
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4
AB  - The oxidation of CO over La1-ySryCr1-xRuxO3 perovskite type oxides with y=0.3 and 0 £x £0.100 have been studied. X-ray fluorescence analysis confirmed that content of elements in the bulk corresponds to the established nominal perovskite stoichiometry, indicating that no significant oxidation of ruthenium into volatile polyvalent oxides with their consequent escape from the sample occurred in air up to the temperature of 1000 ºC. According to X-ray diffraction analysis, all samples achieved the perovskite hexagonal with the presence of some SrCrO4. X-ray photoelectron spectroscopy analysis of ruthenium samples shows higher Ru and Sr surface concentrations than in the bulk. The binding energy for Ru3p is virtually the same in all samples and consistent with that of Ru4+ (463.6.464.3eV). Kinetic studies were performed in a differential recycle reactor with a recycling ratio 80. The results show that substitution of Ru4+ for Cr3+ in La1-ySryCrO3 leads to a significant increase in both the activity and the activation energy. The global CO oxidation rate, referred on the BET surface area, correlates with the surface Ru4+ atomic concentration. Hence, the activity reflect the surface enrichment in ruthenium. Moreover, an identical apparent activation energy E = 93 kJ/mol and the same specific rate per ruthenium surface ion were obtained for samples with a Ru content x ‡ 0.05 suggest that exposed Ru4+ ions mainly participate in the reaction.
AB  - Predmet ovog rada je ispitivanje katalitičke aktivnosti mešanih oksida La1-ySryCr1-xRuxO3 strukture perovskita sa y = 0,3 i 0,025 £ x £ 0,100 u oksidaciji ugljenmonoksida. Visoka saglasnost unete i X-fluoroscentnom analizom nađene količine rutenijuma u uzorcima kalcinisanim na 100ºC u vazduhu, ukazuje na to da nije došlo do značajne oksidacije Ru do isparljivih polivalentnih oksida i njihovog otparavanja iz uzorka. Analiza difraktograma X-zraka je pokazala da je u svim uzorcima pored perovskitne faze prisutan i manji udeo SrCrO4 faze. Koncentracije Sr i Ru u površinskim slojevima, izračunate iz X-fotoelektronske spektroskopije, su veće u odnosu na njihovu koncentraciju u masi. Energija veze Ru3p je ista za sve uzorke i karakteristična je za Ru4+. Kinetika oksidacije ugljenmonoksida ispitivana je u diferencijalnom recirkulacionom reaktoru. Rezultati pokazuju da delimična zamena Cr3+ sa Ru4+ u La1-ySryCrO3 dovodi do znatnog porasta aktivnosti i energije aktivacije. Ukupna brzina oksidacija CO, obračunata po jedinici specifične površine, je skoro proporcionalna porastu atomske koncentracije Ru4+ na površini uzorka, odnosno Rux ‡ 0,05 dobivena je ista prividna energija aktivacije od E = 93 kJ/mol i ista specifična brzina oksidacije po površinskom jonu Ru4+,što ukazuje na to da su joni Ru4+ izloženi i da oni prevashodno učestvuju u reakciji.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites
T1  - Katalitička svojstva La1-ySryCr1-xRuxO3 perovskita u oksidaciji ugljenmonoksida
VL  - 65
IS  - 1
SP  - 15
EP  - 25
DO  - 10.2298/JSC0001015T
ER  - 
@article{
author = "Terlecki-Baričević, Ana V. and Petrović, Srđan and Jovanović, Dušan M. and Karanović, Lj. and Marinova, C.",
year = "2000",
abstract = "The oxidation of CO over La1-ySryCr1-xRuxO3 perovskite type oxides with y=0.3 and 0 £x £0.100 have been studied. X-ray fluorescence analysis confirmed that content of elements in the bulk corresponds to the established nominal perovskite stoichiometry, indicating that no significant oxidation of ruthenium into volatile polyvalent oxides with their consequent escape from the sample occurred in air up to the temperature of 1000 ºC. According to X-ray diffraction analysis, all samples achieved the perovskite hexagonal with the presence of some SrCrO4. X-ray photoelectron spectroscopy analysis of ruthenium samples shows higher Ru and Sr surface concentrations than in the bulk. The binding energy for Ru3p is virtually the same in all samples and consistent with that of Ru4+ (463.6.464.3eV). Kinetic studies were performed in a differential recycle reactor with a recycling ratio 80. The results show that substitution of Ru4+ for Cr3+ in La1-ySryCrO3 leads to a significant increase in both the activity and the activation energy. The global CO oxidation rate, referred on the BET surface area, correlates with the surface Ru4+ atomic concentration. Hence, the activity reflect the surface enrichment in ruthenium. Moreover, an identical apparent activation energy E = 93 kJ/mol and the same specific rate per ruthenium surface ion were obtained for samples with a Ru content x ‡ 0.05 suggest that exposed Ru4+ ions mainly participate in the reaction., Predmet ovog rada je ispitivanje katalitičke aktivnosti mešanih oksida La1-ySryCr1-xRuxO3 strukture perovskita sa y = 0,3 i 0,025 £ x £ 0,100 u oksidaciji ugljenmonoksida. Visoka saglasnost unete i X-fluoroscentnom analizom nađene količine rutenijuma u uzorcima kalcinisanim na 100ºC u vazduhu, ukazuje na to da nije došlo do značajne oksidacije Ru do isparljivih polivalentnih oksida i njihovog otparavanja iz uzorka. Analiza difraktograma X-zraka je pokazala da je u svim uzorcima pored perovskitne faze prisutan i manji udeo SrCrO4 faze. Koncentracije Sr i Ru u površinskim slojevima, izračunate iz X-fotoelektronske spektroskopije, su veće u odnosu na njihovu koncentraciju u masi. Energija veze Ru3p je ista za sve uzorke i karakteristična je za Ru4+. Kinetika oksidacije ugljenmonoksida ispitivana je u diferencijalnom recirkulacionom reaktoru. Rezultati pokazuju da delimična zamena Cr3+ sa Ru4+ u La1-ySryCrO3 dovodi do znatnog porasta aktivnosti i energije aktivacije. Ukupna brzina oksidacija CO, obračunata po jedinici specifične površine, je skoro proporcionalna porastu atomske koncentracije Ru4+ na površini uzorka, odnosno Rux ‡ 0,05 dobivena je ista prividna energija aktivacije od E = 93 kJ/mol i ista specifična brzina oksidacije po površinskom jonu Ru4+,što ukazuje na to da su joni Ru4+ izloženi i da oni prevashodno učestvuju u reakciji.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites, Katalitička svojstva La1-ySryCr1-xRuxO3 perovskita u oksidaciji ugljenmonoksida",
volume = "65",
number = "1",
pages = "15-25",
doi = "10.2298/JSC0001015T"
}
Terlecki-Baričević, A. V., Petrović, S., Jovanović, D. M., Karanović, Lj.,& Marinova, C.. (2000). Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 65(1), 15-25.
https://doi.org/10.2298/JSC0001015T
Terlecki-Baričević AV, Petrović S, Jovanović DM, Karanović L, Marinova C. Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites. in Journal of the Serbian Chemical Society. 2000;65(1):15-25.
doi:10.2298/JSC0001015T .
Terlecki-Baričević, Ana V., Petrović, Srđan, Jovanović, Dušan M., Karanović, Lj., Marinova, C., "Characterization and carbon monoxide oxidation activity of La1-ySryCr1-xRuxO3 perovskites" in Journal of the Serbian Chemical Society, 65, no. 1 (2000):15-25,
https://doi.org/10.2298/JSC0001015T . .
2
2

Properties of activated alumina obtained by flash calcination of gibbsite

Jovanović, Nadežda N.; Novaković, Tatjana; Janaćković, Jovan; Terlecki-Baričević, Ana V.

(Elsevier, 1992)

TY  - JOUR
AU  - Jovanović, Nadežda N.
AU  - Novaković, Tatjana
AU  - Janaćković, Jovan
AU  - Terlecki-Baričević, Ana V.
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4732
AB  - On exposing gibbsite, with granulation below 10 μm to flash calcination of 0.5 s in the regime of pneumatic transport and at temperatures above 883 K, a microcrystalline material with a high degree of amorphization was obtained, as established from data of XRD analysis. It was shown that at 883 K the mechanism of gibbsite dehydration changes with a decrease of the activation energy from 141 to 53 kJ/mol. The obtained activated alumina is characterized by a specific surface area of over 200 m2/g and a pore structure with micro- and mesopores developed in the inside of grains of the starting material.
PB  - Elsevier
T2  - Journal of Colloid And Interface Science
T1  - Properties of activated alumina obtained by flash calcination of gibbsite
VL  - 150
IS  - 1
SP  - 36
EP  - 41
DO  - 10.1016/0021-9797(92)90265-N
ER  - 
@article{
author = "Jovanović, Nadežda N. and Novaković, Tatjana and Janaćković, Jovan and Terlecki-Baričević, Ana V.",
year = "1992",
abstract = "On exposing gibbsite, with granulation below 10 μm to flash calcination of 0.5 s in the regime of pneumatic transport and at temperatures above 883 K, a microcrystalline material with a high degree of amorphization was obtained, as established from data of XRD analysis. It was shown that at 883 K the mechanism of gibbsite dehydration changes with a decrease of the activation energy from 141 to 53 kJ/mol. The obtained activated alumina is characterized by a specific surface area of over 200 m2/g and a pore structure with micro- and mesopores developed in the inside of grains of the starting material.",
publisher = "Elsevier",
journal = "Journal of Colloid And Interface Science",
title = "Properties of activated alumina obtained by flash calcination of gibbsite",
volume = "150",
number = "1",
pages = "36-41",
doi = "10.1016/0021-9797(92)90265-N"
}
Jovanović, N. N., Novaković, T., Janaćković, J.,& Terlecki-Baričević, A. V.. (1992). Properties of activated alumina obtained by flash calcination of gibbsite. in Journal of Colloid And Interface Science
Elsevier., 150(1), 36-41.
https://doi.org/10.1016/0021-9797(92)90265-N
Jovanović NN, Novaković T, Janaćković J, Terlecki-Baričević AV. Properties of activated alumina obtained by flash calcination of gibbsite. in Journal of Colloid And Interface Science. 1992;150(1):36-41.
doi:10.1016/0021-9797(92)90265-N .
Jovanović, Nadežda N., Novaković, Tatjana, Janaćković, Jovan, Terlecki-Baričević, Ana V., "Properties of activated alumina obtained by flash calcination of gibbsite" in Journal of Colloid And Interface Science, 150, no. 1 (1992):36-41,
https://doi.org/10.1016/0021-9797(92)90265-N . .
26
22

Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites

Jovanović, Dušan M.; Dondur, Vera T.; Terlecki-Baričević, Ana V.; Grbić, Boško

(Elsevier, 1991)

TY  - CHAP
AU  - Jovanović, Dušan M.
AU  - Dondur, Vera T.
AU  - Terlecki-Baričević, Ana V.
AU  - Grbić, Boško
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4366
AB  - Single phase perovskites, as LaCoO3, LaCrO3, La Co0 5 Cr0 5O3, La0.7Sr0 3CrO3 and La0 7Sr0 3Cr0 95Ru0 05O3, were synthesized and three-way activity and sulfur tolerance were measured in a pulse-flame catalyst testing system in a wide range of redox-potential (R). Comparison of activities indicates that perovskite with ruthenium ion has the best redox behaviour in the redox potential interval 0.75<R<1.40. On the basis of experimental data, the sulfur resistant matrix La0.7Sr0.3 CrO3 was synthetized and the highly active sulfur resistant ruthenium perovskite catalyst, was prepared.
PB  - Elsevier
T2  - Studies in Surface Science and Catalysis - Catalysis and Automotive Pollution Control II
T1  - Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites
VL  - 71
IS  - C
SP  - 371
EP  - 379
DO  - 10.1016/S0167-2991(08)62989-4
ER  - 
@inbook{
author = "Jovanović, Dušan M. and Dondur, Vera T. and Terlecki-Baričević, Ana V. and Grbić, Boško",
year = "1991",
abstract = "Single phase perovskites, as LaCoO3, LaCrO3, La Co0 5 Cr0 5O3, La0.7Sr0 3CrO3 and La0 7Sr0 3Cr0 95Ru0 05O3, were synthesized and three-way activity and sulfur tolerance were measured in a pulse-flame catalyst testing system in a wide range of redox-potential (R). Comparison of activities indicates that perovskite with ruthenium ion has the best redox behaviour in the redox potential interval 0.75<R<1.40. On the basis of experimental data, the sulfur resistant matrix La0.7Sr0.3 CrO3 was synthetized and the highly active sulfur resistant ruthenium perovskite catalyst, was prepared.",
publisher = "Elsevier",
journal = "Studies in Surface Science and Catalysis - Catalysis and Automotive Pollution Control II",
booktitle = "Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites",
volume = "71",
number = "C",
pages = "371-379",
doi = "10.1016/S0167-2991(08)62989-4"
}
Jovanović, D. M., Dondur, V. T., Terlecki-Baričević, A. V.,& Grbić, B.. (1991). Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites. in Studies in Surface Science and Catalysis - Catalysis and Automotive Pollution Control II
Elsevier., 71(C), 371-379.
https://doi.org/10.1016/S0167-2991(08)62989-4
Jovanović DM, Dondur VT, Terlecki-Baričević AV, Grbić B. Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites. in Studies in Surface Science and Catalysis - Catalysis and Automotive Pollution Control II. 1991;71(C):371-379.
doi:10.1016/S0167-2991(08)62989-4 .
Jovanović, Dušan M., Dondur, Vera T., Terlecki-Baričević, Ana V., Grbić, Boško, "Three-Way Activity and Sulfur Tolerance of Single Phase Perovskites" in Studies in Surface Science and Catalysis - Catalysis and Automotive Pollution Control II, 71, no. C (1991):371-379,
https://doi.org/10.1016/S0167-2991(08)62989-4 . .
2
5

Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides

Dyakova, E.; Terlecki-Baričević, Ana V.; Mehandjiev, Dimitar R.; Zhecheva, Ekaterina N.; Grbić, Boško

(Springer, 1991)

TY  - JOUR
AU  - Dyakova, E.
AU  - Terlecki-Baričević, Ana V.
AU  - Mehandjiev, Dimitar R.
AU  - Zhecheva, Ekaterina N.
AU  - Grbić, Boško
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3480
AB  - Carbon monoxide oxidation activity and aging of Cu1-xCrxCo2O4 (0<x<1) spinels in the presence of sulfur oxides have been studied. The results obtained indicate that the sulfur tolerance is related to the presence of octahedral Co3+ (Oh) and Cu2+ (Oh) ions in the ternary spinels.
PB  - Springer
T2  - Reaction Kinetics & Catalysis Letters
T1  - Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides
VL  - 43
IS  - 2
SP  - 521
EP  - 526
DO  - 10.1007/BF02064722
ER  - 
@article{
author = "Dyakova, E. and Terlecki-Baričević, Ana V. and Mehandjiev, Dimitar R. and Zhecheva, Ekaterina N. and Grbić, Boško",
year = "1991",
abstract = "Carbon monoxide oxidation activity and aging of Cu1-xCrxCo2O4 (0<x<1) spinels in the presence of sulfur oxides have been studied. The results obtained indicate that the sulfur tolerance is related to the presence of octahedral Co3+ (Oh) and Cu2+ (Oh) ions in the ternary spinels.",
publisher = "Springer",
journal = "Reaction Kinetics & Catalysis Letters",
title = "Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides",
volume = "43",
number = "2",
pages = "521-526",
doi = "10.1007/BF02064722"
}
Dyakova, E., Terlecki-Baričević, A. V., Mehandjiev, D. R., Zhecheva, E. N.,& Grbić, B.. (1991). Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides. in Reaction Kinetics & Catalysis Letters
Springer., 43(2), 521-526.
https://doi.org/10.1007/BF02064722
Dyakova E, Terlecki-Baričević AV, Mehandjiev DR, Zhecheva EN, Grbić B. Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides. in Reaction Kinetics & Catalysis Letters. 1991;43(2):521-526.
doi:10.1007/BF02064722 .
Dyakova, E., Terlecki-Baričević, Ana V., Mehandjiev, Dimitar R., Zhecheva, Ekaterina N., Grbić, Boško, "Oxidation of carbon monoxide over Cu1-xCrxCo2O4 in the presence of sulfur oxides" in Reaction Kinetics & Catalysis Letters, 43, no. 2 (1991):521-526,
https://doi.org/10.1007/BF02064722 . .
7
9

Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds

Angelov, Stephan A.; Mehanđiev, Dimitar R.; Piperov, B.; Zarkov, V.; Terlecki-Baričević, Ana V.; Jovanović, Dušan M.; Jovanović, Žarko D.

(Elsevier, 1985)

TY  - JOUR
AU  - Angelov, Stephan A.
AU  - Mehanđiev, Dimitar R.
AU  - Piperov, B.
AU  - Zarkov, V.
AU  - Terlecki-Baričević, Ana V.
AU  - Jovanović, Dušan M.
AU  - Jovanović, Žarko D.
PY  - 1985
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4190
AB  - The influence of the copper content in CuxCo3-xO4 (0 ≫ × ≫ 1) mixed oxides on carbon monoxide oxidation in the presence of SO2 was investigated. The average oxidation rate was found to increase very slowly with increasing x, whereas the resistance to SO2 poisoning increases substantially at values of x higher than 0.2.
PB  - Elsevier
T2  - Applied Catalysis
T1  - Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds
VL  - 16
IS  - 3
SP  - 431
EP  - 437
DO  - 10.1016/S0166-9834(00)84405-X
ER  - 
@article{
author = "Angelov, Stephan A. and Mehanđiev, Dimitar R. and Piperov, B. and Zarkov, V. and Terlecki-Baričević, Ana V. and Jovanović, Dušan M. and Jovanović, Žarko D.",
year = "1985",
abstract = "The influence of the copper content in CuxCo3-xO4 (0 ≫ × ≫ 1) mixed oxides on carbon monoxide oxidation in the presence of SO2 was investigated. The average oxidation rate was found to increase very slowly with increasing x, whereas the resistance to SO2 poisoning increases substantially at values of x higher than 0.2.",
publisher = "Elsevier",
journal = "Applied Catalysis",
title = "Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds",
volume = "16",
number = "3",
pages = "431-437",
doi = "10.1016/S0166-9834(00)84405-X"
}
Angelov, S. A., Mehanđiev, D. R., Piperov, B., Zarkov, V., Terlecki-Baričević, A. V., Jovanović, D. M.,& Jovanović, Ž. D.. (1985). Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds. in Applied Catalysis
Elsevier., 16(3), 431-437.
https://doi.org/10.1016/S0166-9834(00)84405-X
Angelov SA, Mehanđiev DR, Piperov B, Zarkov V, Terlecki-Baričević AV, Jovanović DM, Jovanović ŽD. Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds. in Applied Catalysis. 1985;16(3):431-437.
doi:10.1016/S0166-9834(00)84405-X .
Angelov, Stephan A., Mehanđiev, Dimitar R., Piperov, B., Zarkov, V., Terlecki-Baričević, Ana V., Jovanović, Dušan M., Jovanović, Žarko D., "Carbon monoxide oxidation on mixed spinels CuxCo3-xO4 (0 ≫ × ≫ 1) in the presence of sulphur compounds" in Applied Catalysis, 16, no. 3 (1985):431-437,
https://doi.org/10.1016/S0166-9834(00)84405-X . .
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