Dimitrijević, Silvana

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orcid::0000-0003-1670-4275
  • Dimitrijević, Silvana (5)
  • Dimitrijević, Silvana B. (3)

Author's Bibliography

Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system

Cvetković, Vesna S.; Nikolić, Nebojša D.; Petrović, Nataša M.; Barudžija, Tanja S.; Dimitrijević, Silvana B.; Jovićević, Jovan N.

(Serbian Society of Corrosion and Materials Protection (UISKoZaM), 2023)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Nikolić, Nebojša D.
AU  - Petrović, Nataša M.
AU  - Barudžija, Tanja S.
AU  - Dimitrijević, Silvana B.
AU  - Jovićević, Jovan N.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6346
AB  - The electrochemical deposition of Zn onto Au from a choline chloride/ethylene glycol deep eutectic system containing different ZnCl2 concentrations has been investigated. The voltammetric results demonstrated that Zn electrodeposition commences in the zinc underpotential deposition (UPD) and proceeds through to the zinc overpotential deposition (OPD) region. The results of X-ray diffraction analysis revealed that the deposit prepared at a relatively low Zn overpotential of – 0.050 V vs. Zn was composed of cubic AuZn alloy. The morphology of the deposit has been characterized by means of a scanning electron microscope and displays a relatively compact and dendrite-free Zn/Au alloy deposit formed.
PB  - Serbian Society of Corrosion and Materials Protection (UISKoZaM)
C3  - Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
T1  - Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system
SP  - POSTER-171
EP  - POSTER-175
UR  - https://hdl.handle.net/21.15107/rcub_cer_6346
ER  - 
@conference{
author = "Cvetković, Vesna S. and Nikolić, Nebojša D. and Petrović, Nataša M. and Barudžija, Tanja S. and Dimitrijević, Silvana B. and Jovićević, Jovan N.",
year = "2023",
abstract = "The electrochemical deposition of Zn onto Au from a choline chloride/ethylene glycol deep eutectic system containing different ZnCl2 concentrations has been investigated. The voltammetric results demonstrated that Zn electrodeposition commences in the zinc underpotential deposition (UPD) and proceeds through to the zinc overpotential deposition (OPD) region. The results of X-ray diffraction analysis revealed that the deposit prepared at a relatively low Zn overpotential of – 0.050 V vs. Zn was composed of cubic AuZn alloy. The morphology of the deposit has been characterized by means of a scanning electron microscope and displays a relatively compact and dendrite-free Zn/Au alloy deposit formed.",
publisher = "Serbian Society of Corrosion and Materials Protection (UISKoZaM)",
journal = "Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia",
title = "Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system",
pages = "POSTER-171-POSTER-175",
url = "https://hdl.handle.net/21.15107/rcub_cer_6346"
}
Cvetković, V. S., Nikolić, N. D., Petrović, N. M., Barudžija, T. S., Dimitrijević, S. B.,& Jovićević, J. N.. (2023). Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
Serbian Society of Corrosion and Materials Protection (UISKoZaM)., POSTER-171-POSTER-175.
https://hdl.handle.net/21.15107/rcub_cer_6346
Cvetković VS, Nikolić ND, Petrović NM, Barudžija TS, Dimitrijević SB, Jovićević JN. Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia. 2023;:POSTER-171-POSTER-175.
https://hdl.handle.net/21.15107/rcub_cer_6346 .
Cvetković, Vesna S., Nikolić, Nebojša D., Petrović, Nataša M., Barudžija, Tanja S., Dimitrijević, Silvana B., Jovićević, Jovan N., "Zn/Au alloys formation by Zn electrodeposition from a deep eutectic system" in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia (2023):POSTER-171-POSTER-175,
https://hdl.handle.net/21.15107/rcub_cer_6346 .

Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride

Cvetković, Vesna S.; Nikolić, Nebojša D.; Košević, Milica; Barudžija, Tanja S.; Dimitrijević, Silvana B.; Jovićević, Jovan N.

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Nikolić, Nebojša D.
AU  - Košević, Milica
AU  - Barudžija, Tanja S.
AU  - Dimitrijević, Silvana B.
AU  - Jovićević, Jovan N.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6760
AB  - In this work, the electrochemical deposition of copper
onto palladium working substrate from ChCl/EG (1:2 ratio) DES electrolyte at
50°C was investigated. Additionally, the Cu(II) electroreduction process was
studied by potentiodynamic measurements, cyclic voltammetry,
chronoamperometry, in the electrolytes with different concentrations of Cu(II)
ions ranging from 0.1 M to 0.5 M.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
T1  - Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride
SP  - 142
EP  - 142
UR  - https://hdl.handle.net/21.15107/rcub_cer_6760
ER  - 
@conference{
author = "Cvetković, Vesna S. and Nikolić, Nebojša D. and Košević, Milica and Barudžija, Tanja S. and Dimitrijević, Silvana B. and Jovićević, Jovan N.",
year = "2023",
abstract = "In this work, the electrochemical deposition of copper
onto palladium working substrate from ChCl/EG (1:2 ratio) DES electrolyte at
50°C was investigated. Additionally, the Cu(II) electroreduction process was
studied by potentiodynamic measurements, cyclic voltammetry,
chronoamperometry, in the electrolytes with different concentrations of Cu(II)
ions ranging from 0.1 M to 0.5 M.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia",
title = "Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride",
pages = "142-142",
url = "https://hdl.handle.net/21.15107/rcub_cer_6760"
}
Cvetković, V. S., Nikolić, N. D., Košević, M., Barudžija, T. S., Dimitrijević, S. B.,& Jovićević, J. N.. (2023). Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 142-142.
https://hdl.handle.net/21.15107/rcub_cer_6760
Cvetković VS, Nikolić ND, Košević M, Barudžija TS, Dimitrijević SB, Jovićević JN. Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia. 2023;:142-142.
https://hdl.handle.net/21.15107/rcub_cer_6760 .
Cvetković, Vesna S., Nikolić, Nebojša D., Košević, Milica, Barudžija, Tanja S., Dimitrijević, Silvana B., Jovićević, Jovan N., "Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia (2023):142-142,
https://hdl.handle.net/21.15107/rcub_cer_6760 .

Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts

Nikolić, Nebojša D.; Lović, Jelena D.; Ignjatović, Nenad; Dimitrijević, Silvana B.

(Lausanne, Switzerland : International Society of Electrochemistry, 2023)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Lović, Jelena D.
AU  - Ignjatović, Nenad
AU  - Dimitrijević, Silvana B.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6573
AB  - Sn-Pd electrocatalysts convenient for a possible application in direct ethanol fuel cell were produced by two electrochemical deposition method. In the first step, Sn dendrites of various degree of ramification were electrodeposited by potentiostatically on cathodic potentials of –1200, –1400, –1600 and –1800 mV vs. Ag/AgCl. Electrodeposition of tin was performed from 20 g/l SnCl2 × 2H2O in 250 g/l NaOH electrolyte at the room temperature on Cu electrodes. In the second step, Pd was electrodeposited galvanostatically at a current density of –5 mA cm-2 on the electrodes with electrodeposited Sn dendrites. Electrodeposition of Pd was performed from 1 M NH4Cl and 0.01 M PdCl2 at the room temperature. The processes of electrochemical deposition of Sn and Pd were performed with amounts of the electricity of 400 and 267 mC, giving an atomic ratio synthesized the electrocatalysts of 60 at.% Sn‒40 at.% Pd. Morpological and elemental analysis of the Sn-Pd electrocatalysts was performed by scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. The particle size distribution (PSD) was used to estimate a size of Sn dendrites.
PB  - Lausanne, Switzerland : International Society of Electrochemistry
C3  - 74th Annual Meeting of the International Society of Electrochemistry, "Bridging Scientific Disciplines to Address the World’s Challenges," Program, 3 - 8 September 2023 Lyon, France
T1  - Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts
SP  - S09-P-038
UR  - https://hdl.handle.net/21.15107/rcub_cer_6573
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Lović, Jelena D. and Ignjatović, Nenad and Dimitrijević, Silvana B.",
year = "2023",
abstract = "Sn-Pd electrocatalysts convenient for a possible application in direct ethanol fuel cell were produced by two electrochemical deposition method. In the first step, Sn dendrites of various degree of ramification were electrodeposited by potentiostatically on cathodic potentials of –1200, –1400, –1600 and –1800 mV vs. Ag/AgCl. Electrodeposition of tin was performed from 20 g/l SnCl2 × 2H2O in 250 g/l NaOH electrolyte at the room temperature on Cu electrodes. In the second step, Pd was electrodeposited galvanostatically at a current density of –5 mA cm-2 on the electrodes with electrodeposited Sn dendrites. Electrodeposition of Pd was performed from 1 M NH4Cl and 0.01 M PdCl2 at the room temperature. The processes of electrochemical deposition of Sn and Pd were performed with amounts of the electricity of 400 and 267 mC, giving an atomic ratio synthesized the electrocatalysts of 60 at.% Sn‒40 at.% Pd. Morpological and elemental analysis of the Sn-Pd electrocatalysts was performed by scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. The particle size distribution (PSD) was used to estimate a size of Sn dendrites.",
publisher = "Lausanne, Switzerland : International Society of Electrochemistry",
journal = "74th Annual Meeting of the International Society of Electrochemistry, "Bridging Scientific Disciplines to Address the World’s Challenges," Program, 3 - 8 September 2023 Lyon, France",
title = "Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts",
pages = "S09-P-038",
url = "https://hdl.handle.net/21.15107/rcub_cer_6573"
}
Nikolić, N. D., Lović, J. D., Ignjatović, N.,& Dimitrijević, S. B.. (2023). Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts. in 74th Annual Meeting of the International Society of Electrochemistry, "Bridging Scientific Disciplines to Address the World’s Challenges," Program, 3 - 8 September 2023 Lyon, France
Lausanne, Switzerland : International Society of Electrochemistry., S09-P-038.
https://hdl.handle.net/21.15107/rcub_cer_6573
Nikolić ND, Lović JD, Ignjatović N, Dimitrijević SB. Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts. in 74th Annual Meeting of the International Society of Electrochemistry, "Bridging Scientific Disciplines to Address the World’s Challenges," Program, 3 - 8 September 2023 Lyon, France. 2023;:S09-P-038.
https://hdl.handle.net/21.15107/rcub_cer_6573 .
Nikolić, Nebojša D., Lović, Jelena D., Ignjatović, Nenad, Dimitrijević, Silvana B., "Influence of Morphology of Sn Dendrites as Sub-layer on Electrolcatalytic Performance of Sn-Pd Electrocatalysts" in 74th Annual Meeting of the International Society of Electrochemistry, "Bridging Scientific Disciplines to Address the World’s Challenges," Program, 3 - 8 September 2023 Lyon, France (2023):S09-P-038,
https://hdl.handle.net/21.15107/rcub_cer_6573 .

Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction

Lović, Jelena; Nikolić, Nebojša D.; Živković, Predrag; Dimitrijević, Silvana; Stevanović, Maja

(Society of Chemists and Technologists of Macedonia, 2023)

TY  - JOUR
AU  - Lović, Jelena
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag
AU  - Dimitrijević, Silvana
AU  - Stevanović, Maja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6301
AB  - A series of bimetallic Sn-Pd catalysts were prepared by a template-free two step electrodeposition method. According to this method, Sn was electrodeposited firstly in potentiostatic or galvanostatic regime on Cu electrodes in the form of dendrites, then Pd was galvanostatically electrodeposited in the second step on the electrode with the electrodeposited Sn dendrites. The produced Sn-Pd electrocatalysts were compared with an electrocatalyst obtained by Pd electrodeposition on a bare Cu electrode. The morphological and elemental analysis of Sn-Pd and Pd electrocatalysts was performed by means of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) techniques. The dendrites of various shapes and degree of branching were obtained by Sn deposition depending on electrodeposition regime, while Pd was electrodeposited in a form of compact Pd islands on both Sn dendrites and the Cu electrode. Cyclic voltammetry (CV) was applied for the electrochemical examination of Sn-Pd and Pd catalysts towards the ethanol oxidation reaction (EOR) in the alkaline solution. The electrocatalyst Sn0.6-Pd0.4 with an atomic ratio of 60 at.% Sn-40 at.% Pd showed higher oxidation efficiency and better tolerance towards intermediate species in EOR than the other examined electrocatalysts . It was shown that the lower fraction of Pd, relative to Sn, was crucial to achieving optimal synergy of Sn with Pd thus contributing to enhanced electrochemical behavior regarding EOR.
AB  - Серија на биметални катализатори со различни односи на Sn:Pd беа подготвени со методот
на двостепена електродепозиција без користење шаблонски протокол. Според овој метод, прво Sn во форма на дендрити беше нанесен електрохемиски во потенциостатски или галваностатски режим врз површината на Cu-електроди. Потоа, во вториот чекор, Pd беше галваностатски нанесен на електродата врз нанесените дендрити од Sn. Вака добиените Sn:Pd-електрокатализатори беа споредени со електрокатализатори добиени со нанесување на Pd на чиста Cu електрода. Морфолошката и елементарната анализа на Sn:Pd и Pd-електрокатализаторите беше направена со помош на скенирачка електронска микроскопија (SEM) и со примена на рендгенска спектроскопија со енергетска дисперзија (EDS). Дендритите со различни форми и различен степен на разгранување беа добиени со нанесување Sn во зависност од режимот на електродепозиција, додека Pd беше нанесен во форма на компактни острови врз дендритите од Pd и Sn на површината на Cu-електродата. Цикличната волтаметрија (CV) беше применета за електрохемиското испитување на Sn:Pd и Pd-катализаторите во од аспект на оксидацијата на етанолот во алкална средина. Eлектрокатализаторот Sn0.6-Pd0,4 со атомски однос од 60 % Sn и 40 % Pd покажа поголема 
ефикасност на оксидација и поголема толеранција во однос на интермедијарните супстрати 
отколку другите испитани електрокатализатори. Се покажа дека помал удел на Pd во однос на Sn е еден од клучните фактори за обезбедување оптимална синергија на Sn со Pd, при што на овој начин беше забележана зголемена електрохемиска активност односно оксидацијата на етанолот.
PB  - Society of Chemists and Technologists of Macedonia
PB  - Ss. Cyril and Methodius University in Skopje
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction
T1  - Влијание на режимот на електродепозицијата и на односите на Sn:Pd во Sn-Pd-електрокатализаторите врз оксидацијата на етанолот
VL  - 42
DO  - 10.20450/mjcce.2023.2702
ER  - 
@article{
author = "Lović, Jelena and Nikolić, Nebojša D. and Živković, Predrag and Dimitrijević, Silvana and Stevanović, Maja",
year = "2023",
abstract = "A series of bimetallic Sn-Pd catalysts were prepared by a template-free two step electrodeposition method. According to this method, Sn was electrodeposited firstly in potentiostatic or galvanostatic regime on Cu electrodes in the form of dendrites, then Pd was galvanostatically electrodeposited in the second step on the electrode with the electrodeposited Sn dendrites. The produced Sn-Pd electrocatalysts were compared with an electrocatalyst obtained by Pd electrodeposition on a bare Cu electrode. The morphological and elemental analysis of Sn-Pd and Pd electrocatalysts was performed by means of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) techniques. The dendrites of various shapes and degree of branching were obtained by Sn deposition depending on electrodeposition regime, while Pd was electrodeposited in a form of compact Pd islands on both Sn dendrites and the Cu electrode. Cyclic voltammetry (CV) was applied for the electrochemical examination of Sn-Pd and Pd catalysts towards the ethanol oxidation reaction (EOR) in the alkaline solution. The electrocatalyst Sn0.6-Pd0.4 with an atomic ratio of 60 at.% Sn-40 at.% Pd showed higher oxidation efficiency and better tolerance towards intermediate species in EOR than the other examined electrocatalysts . It was shown that the lower fraction of Pd, relative to Sn, was crucial to achieving optimal synergy of Sn with Pd thus contributing to enhanced electrochemical behavior regarding EOR., Серија на биметални катализатори со различни односи на Sn:Pd беа подготвени со методот
на двостепена електродепозиција без користење шаблонски протокол. Според овој метод, прво Sn во форма на дендрити беше нанесен електрохемиски во потенциостатски или галваностатски режим врз површината на Cu-електроди. Потоа, во вториот чекор, Pd беше галваностатски нанесен на електродата врз нанесените дендрити од Sn. Вака добиените Sn:Pd-електрокатализатори беа споредени со електрокатализатори добиени со нанесување на Pd на чиста Cu електрода. Морфолошката и елементарната анализа на Sn:Pd и Pd-електрокатализаторите беше направена со помош на скенирачка електронска микроскопија (SEM) и со примена на рендгенска спектроскопија со енергетска дисперзија (EDS). Дендритите со различни форми и различен степен на разгранување беа добиени со нанесување Sn во зависност од режимот на електродепозиција, додека Pd беше нанесен во форма на компактни острови врз дендритите од Pd и Sn на површината на Cu-електродата. Цикличната волтаметрија (CV) беше применета за електрохемиското испитување на Sn:Pd и Pd-катализаторите во од аспект на оксидацијата на етанолот во алкална средина. Eлектрокатализаторот Sn0.6-Pd0,4 со атомски однос од 60 % Sn и 40 % Pd покажа поголема 
ефикасност на оксидација и поголема толеранција во однос на интермедијарните супстрати 
отколку другите испитани електрокатализатори. Се покажа дека помал удел на Pd во однос на Sn е еден од клучните фактори за обезбедување оптимална синергија на Sn со Pd, при што на овој начин беше забележана зголемена електрохемиска активност односно оксидацијата на етанолот.",
publisher = "Society of Chemists and Technologists of Macedonia, Ss. Cyril and Methodius University in Skopje",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction, Влијание на режимот на електродепозицијата и на односите на Sn:Pd во Sn-Pd-електрокатализаторите врз оксидацијата на етанолот",
volume = "42",
doi = "10.20450/mjcce.2023.2702"
}
Lović, J., Nikolić, N. D., Živković, P., Dimitrijević, S.,& Stevanović, M.. (2023). Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction. in Macedonian Journal of Chemistry and Chemical Engineering
Society of Chemists and Technologists of Macedonia., 42.
https://doi.org/10.20450/mjcce.2023.2702
Lović J, Nikolić ND, Živković P, Dimitrijević S, Stevanović M. Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction. in Macedonian Journal of Chemistry and Chemical Engineering. 2023;42.
doi:10.20450/mjcce.2023.2702 .
Lović, Jelena, Nikolić, Nebojša D., Živković, Predrag, Dimitrijević, Silvana, Stevanović, Maja, "Influence of electrodeposition regime and Sn:Pd ratios in Sn-Pd electrocatalysts on ethanol oxidation reaction" in Macedonian Journal of Chemistry and Chemical Engineering, 42 (2023),
https://doi.org/10.20450/mjcce.2023.2702 . .

A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells

Lović, Jelena; Eraković Pantović, Sanja; Rakočević, Lazar; Ignjatović, Nenad L.; Dimitrijević, Silvana; Nikolić, Nebojša D.

(MDPI, 2023)

TY  - JOUR
AU  - Lović, Jelena
AU  - Eraković Pantović, Sanja
AU  - Rakočević, Lazar
AU  - Ignjatović, Nenad L.
AU  - Dimitrijević, Silvana
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5515
AB  - Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for 
potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current 
density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.
PB  - MDPI
T2  - Processes
T1  - A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells
VL  - 11
IS  - 1
SP  - 120
DO  - 10.3390/pr11010120
ER  - 
@article{
author = "Lović, Jelena and Eraković Pantović, Sanja and Rakočević, Lazar and Ignjatović, Nenad L. and Dimitrijević, Silvana and Nikolić, Nebojša D.",
year = "2023",
abstract = "Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for 
potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current 
density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.",
publisher = "MDPI",
journal = "Processes",
title = "A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells",
volume = "11",
number = "1",
pages = "120",
doi = "10.3390/pr11010120"
}
Lović, J., Eraković Pantović, S., Rakočević, L., Ignjatović, N. L., Dimitrijević, S.,& Nikolić, N. D.. (2023). A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells. in Processes
MDPI., 11(1), 120.
https://doi.org/10.3390/pr11010120
Lović J, Eraković Pantović S, Rakočević L, Ignjatović NL, Dimitrijević S, Nikolić ND. A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells. in Processes. 2023;11(1):120.
doi:10.3390/pr11010120 .
Lović, Jelena, Eraković Pantović, Sanja, Rakočević, Lazar, Ignjatović, Nenad L., Dimitrijević, Silvana, Nikolić, Nebojša D., "A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells" in Processes, 11, no. 1 (2023):120,
https://doi.org/10.3390/pr11010120 . .
2

Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl

Stanić, Petar; Vukićević, Nataša; Cvetković, Vesna S.; Pavlović, Miroslav; Dimitrijević, Silvana; Šmit, Biljana; Živković, Marija

(Serbian Chemical Society, 2022)

TY  - JOUR
AU  - Stanić, Petar
AU  - Vukićević, Nataša
AU  - Cvetković, Vesna S.
AU  - Pavlović, Miroslav
AU  - Dimitrijević, Silvana
AU  - Šmit, Biljana
AU  - Živković, Marija
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5845
AB  - Several 2-thiohydаntоin–Shiff base derivatives were prepared as ecofriendly
corrosion inhibitors for mild steel in acid environment. Their anticorrosion
properties were studied on mild steel in 0.5 M HCl solution as corrosion
electrolyte by using usuаl grаvimеtriс and different elесtrосhemicаl techniques
(wеight lоss mеаsurеmеnt, pоtеntiоdynаmiс pоlаrizаtiоn and pоtеntiоstаtiс
еlесtrосhеmicаl impеdаnсе sресtrоscору). Mild steel surface was characterized
using two analytical techniques, scanning electron microscopy for surface morphology
and elemental composition and atomic force microscopy. The study
has shown that the inhibiting action of these environmentally benign inhibitors
synthesized from inexpensive commercially available starting materials could
be attributed to adsorption on the metal surface.
AB  - Неколико деривата Шифових база 2-тиохидантоина су направљени као еколошки прихватљиви инхибитори корозије меког челика у киселој средини. Њихова антикорозиона својства су испитана на меком челику у 0,5 M раствору HCl као корозионом електролиту, користећи уобичајене гравиметријске и различите електрохемијске технике (мерење губитка масе, потенциодинамичка поларизација, потенциостатска спектроскопија електрохемијске импеданције). Површина меког челика је окарактерисана двема аналитичким техникама, скенирајућом електронском микроскопијом за морфологију површине и елементарни састав и микроскопијом атомске силе. Студија је показала да се инхибиторно деловање ових еколошки бенигних инхибитора, синтетисаних из јефтиних комерцијално доступних полазних материјала, може приписати адсорпцији инхибитора на површини меког челика.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl
T1  - Антикорозиона активност деривата шифових база 2-тиохидантоина за меки челик у 0,5 m hcl
VL  - 87
IS  - 12
SP  - 1409
EP  - 1423
DO  - 10.2298/JSC220412071S
ER  - 
@article{
author = "Stanić, Petar and Vukićević, Nataša and Cvetković, Vesna S. and Pavlović, Miroslav and Dimitrijević, Silvana and Šmit, Biljana and Živković, Marija",
year = "2022",
abstract = "Several 2-thiohydаntоin–Shiff base derivatives were prepared as ecofriendly
corrosion inhibitors for mild steel in acid environment. Their anticorrosion
properties were studied on mild steel in 0.5 M HCl solution as corrosion
electrolyte by using usuаl grаvimеtriс and different elесtrосhemicаl techniques
(wеight lоss mеаsurеmеnt, pоtеntiоdynаmiс pоlаrizаtiоn and pоtеntiоstаtiс
еlесtrосhеmicаl impеdаnсе sресtrоscору). Mild steel surface was characterized
using two analytical techniques, scanning electron microscopy for surface morphology
and elemental composition and atomic force microscopy. The study
has shown that the inhibiting action of these environmentally benign inhibitors
synthesized from inexpensive commercially available starting materials could
be attributed to adsorption on the metal surface., Неколико деривата Шифових база 2-тиохидантоина су направљени као еколошки прихватљиви инхибитори корозије меког челика у киселој средини. Њихова антикорозиона својства су испитана на меком челику у 0,5 M раствору HCl као корозионом електролиту, користећи уобичајене гравиметријске и различите електрохемијске технике (мерење губитка масе, потенциодинамичка поларизација, потенциостатска спектроскопија електрохемијске импеданције). Површина меког челика је окарактерисана двема аналитичким техникама, скенирајућом електронском микроскопијом за морфологију површине и елементарни састав и микроскопијом атомске силе. Студија је показала да се инхибиторно деловање ових еколошки бенигних инхибитора, синтетисаних из јефтиних комерцијално доступних полазних материјала, може приписати адсорпцији инхибитора на површини меког челика.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl, Антикорозиона активност деривата шифових база 2-тиохидантоина за меки челик у 0,5 m hcl",
volume = "87",
number = "12",
pages = "1409-1423",
doi = "10.2298/JSC220412071S"
}
Stanić, P., Vukićević, N., Cvetković, V. S., Pavlović, M., Dimitrijević, S., Šmit, B.,& Živković, M.. (2022). Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 87(12), 1409-1423.
https://doi.org/10.2298/JSC220412071S
Stanić P, Vukićević N, Cvetković VS, Pavlović M, Dimitrijević S, Šmit B, Živković M. Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl. in Journal of the Serbian Chemical Society. 2022;87(12):1409-1423.
doi:10.2298/JSC220412071S .
Stanić, Petar, Vukićević, Nataša, Cvetković, Vesna S., Pavlović, Miroslav, Dimitrijević, Silvana, Šmit, Biljana, Živković, Marija, "Anticorrosion activity of 2-thiоhуdantoin–Shiff base derivatives for mild steel in 0.5 M HCl" in Journal of the Serbian Chemical Society, 87, no. 12 (2022):1409-1423,
https://doi.org/10.2298/JSC220412071S . .

Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium

Stanić, Petar B.; Vukićević, Nataša M.; Cvetković, Vesna S.; Pavlović, Miroslav M.; Dimitrijević, Silvana; Šmit, Biljana

(Institute for Information Technologies, University of Kragujevac, Serbia, 2021)

TY  - CONF
AU  - Stanić, Petar B.
AU  - Vukićević, Nataša M.
AU  - Cvetković, Vesna S.
AU  - Pavlović, Miroslav M.
AU  - Dimitrijević, Silvana
AU  - Šmit, Biljana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6161
AB  - Four 2-thiohydantoin derivatives were synthesized and their corrosion inhibition properties on mild
steel (MS) in 0.5M HCl solution was evaluated using usual gravimetric and electrochemical methods (weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS). Morphology of the metal surface was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The study has shown that these compounds provide good protection for mild steel against corrosion in the acidic medium.
PB  - Institute for Information Technologies, University of Kragujevac, Serbia
C3  - 1st International Conference on Chemo and Bioinformatics, October 26-27, 2021, Kragujevac, Serbia
T1  - Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium
SP  - 157
EP  - 160
DO  - 10.46793/ICCBI21.157S
ER  - 
@conference{
author = "Stanić, Petar B. and Vukićević, Nataša M. and Cvetković, Vesna S. and Pavlović, Miroslav M. and Dimitrijević, Silvana and Šmit, Biljana",
year = "2021",
abstract = "Four 2-thiohydantoin derivatives were synthesized and their corrosion inhibition properties on mild
steel (MS) in 0.5M HCl solution was evaluated using usual gravimetric and electrochemical methods (weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS). Morphology of the metal surface was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The study has shown that these compounds provide good protection for mild steel against corrosion in the acidic medium.",
publisher = "Institute for Information Technologies, University of Kragujevac, Serbia",
journal = "1st International Conference on Chemo and Bioinformatics, October 26-27, 2021, Kragujevac, Serbia",
title = "Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium",
pages = "157-160",
doi = "10.46793/ICCBI21.157S"
}
Stanić, P. B., Vukićević, N. M., Cvetković, V. S., Pavlović, M. M., Dimitrijević, S.,& Šmit, B.. (2021). Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium. in 1st International Conference on Chemo and Bioinformatics, October 26-27, 2021, Kragujevac, Serbia
Institute for Information Technologies, University of Kragujevac, Serbia., 157-160.
https://doi.org/10.46793/ICCBI21.157S
Stanić PB, Vukićević NM, Cvetković VS, Pavlović MM, Dimitrijević S, Šmit B. Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium. in 1st International Conference on Chemo and Bioinformatics, October 26-27, 2021, Kragujevac, Serbia. 2021;:157-160.
doi:10.46793/ICCBI21.157S .
Stanić, Petar B., Vukićević, Nataša M., Cvetković, Vesna S., Pavlović, Miroslav M., Dimitrijević, Silvana, Šmit, Biljana, "Electrochemical investigation of 2-thiohydantoin derivatives as corrosion inhibitors for mild steel in acidic medium" in 1st International Conference on Chemo and Bioinformatics, October 26-27, 2021, Kragujevac, Serbia (2021):157-160,
https://doi.org/10.46793/ICCBI21.157S . .

Energy efficient pulse-reverse regimes of electrodeposition

Stević, Zoran; Vlahović, Milica; Martinović, Sanja; Dimitrijević, Stevan; Dimitrijević, Silvana; Stević, Miša

(Union of Mechanical and Electrical Engineers and Technicains of Serbia (SMEITS), 2017)

TY  - CONF
AU  - Stević, Zoran
AU  - Vlahović, Milica
AU  - Martinović, Sanja
AU  - Dimitrijević, Stevan
AU  - Dimitrijević, Silvana
AU  - Stević, Miša
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7260
AB  - Pulse reverse power modes are used in order to obtain metal coatings with similar or better characteristics, compared with the coatings produced by constant current. Pulse reverse modes increase production and energy efficiency of electroplating cells with the use of higher density currents. In this paper, we investigate optimisation of systems for standard electrodeposition by choosing the suitable duration and intensity of the pulses. It was shown that energy efficiency of the process can be achieved with satisfactory quality of coatings and without expensive and often dangerous additives in the electrolyte.
PB  - Union of Mechanical and Electrical Engineers and Technicains of Serbia (SMEITS)
PB  - Society for Renewable Electrical Power Sources
C3  - Proceedings - 5th International Conference on Renewable Electrical Power Sources-MKOIEE, 12 and 13 October 2017, Sava Center, Belgrade / Zbornik radova - pisanih za 5. Međunarodnu konferenciju o obnovljivim izvorima električne energije, 12. i 13. oktobar 2017, Sava centar, Beograd
T1  - Energy efficient pulse-reverse regimes of electrodeposition
T1  - Energetski efikasni pulsno-reverzni režimi galvanizacije
SP  - 179
EP  - 184
UR  - https://hdl.handle.net/21.15107/rcub_cer_7260
ER  - 
@conference{
author = "Stević, Zoran and Vlahović, Milica and Martinović, Sanja and Dimitrijević, Stevan and Dimitrijević, Silvana and Stević, Miša",
year = "2017",
abstract = "Pulse reverse power modes are used in order to obtain metal coatings with similar or better characteristics, compared with the coatings produced by constant current. Pulse reverse modes increase production and energy efficiency of electroplating cells with the use of higher density currents. In this paper, we investigate optimisation of systems for standard electrodeposition by choosing the suitable duration and intensity of the pulses. It was shown that energy efficiency of the process can be achieved with satisfactory quality of coatings and without expensive and often dangerous additives in the electrolyte.",
publisher = "Union of Mechanical and Electrical Engineers and Technicains of Serbia (SMEITS), Society for Renewable Electrical Power Sources",
journal = "Proceedings - 5th International Conference on Renewable Electrical Power Sources-MKOIEE, 12 and 13 October 2017, Sava Center, Belgrade / Zbornik radova - pisanih za 5. Međunarodnu konferenciju o obnovljivim izvorima električne energije, 12. i 13. oktobar 2017, Sava centar, Beograd",
title = "Energy efficient pulse-reverse regimes of electrodeposition, Energetski efikasni pulsno-reverzni režimi galvanizacije",
pages = "179-184",
url = "https://hdl.handle.net/21.15107/rcub_cer_7260"
}
Stević, Z., Vlahović, M., Martinović, S., Dimitrijević, S., Dimitrijević, S.,& Stević, M.. (2017). Energy efficient pulse-reverse regimes of electrodeposition. in Proceedings - 5th International Conference on Renewable Electrical Power Sources-MKOIEE, 12 and 13 October 2017, Sava Center, Belgrade / Zbornik radova - pisanih za 5. Međunarodnu konferenciju o obnovljivim izvorima električne energije, 12. i 13. oktobar 2017, Sava centar, Beograd
Union of Mechanical and Electrical Engineers and Technicains of Serbia (SMEITS)., 179-184.
https://hdl.handle.net/21.15107/rcub_cer_7260
Stević Z, Vlahović M, Martinović S, Dimitrijević S, Dimitrijević S, Stević M. Energy efficient pulse-reverse regimes of electrodeposition. in Proceedings - 5th International Conference on Renewable Electrical Power Sources-MKOIEE, 12 and 13 October 2017, Sava Center, Belgrade / Zbornik radova - pisanih za 5. Međunarodnu konferenciju o obnovljivim izvorima električne energije, 12. i 13. oktobar 2017, Sava centar, Beograd. 2017;:179-184.
https://hdl.handle.net/21.15107/rcub_cer_7260 .
Stević, Zoran, Vlahović, Milica, Martinović, Sanja, Dimitrijević, Stevan, Dimitrijević, Silvana, Stević, Miša, "Energy efficient pulse-reverse regimes of electrodeposition" in Proceedings - 5th International Conference on Renewable Electrical Power Sources-MKOIEE, 12 and 13 October 2017, Sava Center, Belgrade / Zbornik radova - pisanih za 5. Međunarodnu konferenciju o obnovljivim izvorima električne energije, 12. i 13. oktobar 2017, Sava centar, Beograd (2017):179-184,
https://hdl.handle.net/21.15107/rcub_cer_7260 .