Maksimović, Vesna M.

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Authority KeyName Variants
orcid::0000-0002-8326-4938
  • Maksimović, Vesna M. (39)
  • Maksimović, Vesna (13)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies
AdCatFC - Advanced Catalysts for Low Temperature Fuel Cells: From Model System to Sustainable Catalysts Deposition of ultrafinepowders of metals and alloys and nanostructured surfaces by electrochemical techniques
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Horizon 2020 research and innovation programme under grant agreement No 870292 (BioICEP) Effects of laser radiation and plasma on novel materials in their synthesis, modification, and analysis
Molecular mechanisms of physiological and pharmacological control of inflammation and cancer Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200042 (University of Belgrade, Institute of Molecular Genetics and Genetic Engineering)
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Magnetic and radionuclide labeled nanostructured materials for medical applications
Biofizička istraživanja membranskih procesa: interakcija membranskih receptora i kanala sa spoljašnjim faktorima i intracelularna regulacija Fiziološka i farmakološka modulacija imunoinflamatornih i malignih bolesti
Research and verification of the multidisciplinary forensic methods in BioECOLogics - Value-added biologics through eco-sustainable routes
Ministry of Science of the Republic of Serbia under the research project Project LA/P/0140/202019 of the Associate Laboratory Institute for Health and Bioeconomy—i4HB
Project MESTD, br. 1806: Electrodeposition of metal powders at a constant and at a periodically changing rate The national funds from FCT—Fundação para a Ciência e a Tecnologia, in the scope of the project UIDP/04378/2020 and UIDB/04378/2020 of the Research Unit on Applied Molecular Biosciences—UCIBIO

Author's Bibliography

Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin

Ponjavić, Marijana; Malagurski, Ivana; Lazić, Jelena; Jeremić, Sanja; Pavlović, Vladimir; Prlainović, Nevena; Maksimović, Vesna; Ćosović, Vladan; Atanase, Leonard Ionut

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Ponjavić, Marijana
AU  - Malagurski, Ivana
AU  - Lazić, Jelena
AU  - Jeremić, Sanja
AU  - Pavlović, Vladimir
AU  - Prlainović, Nevena
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Atanase, Leonard Ionut
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5690
AB  - The quest for sustainable biomaterials with excellent biocompatibility and tailorable
properties has put polyhydroxyalkanoates (PHAs) into the research spotlight. However, high production
costs and the lack of bioactivity limit their market penetration. To address this, poly(3-
hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was combined with a bacterial pigment with strong
anticancer activity, prodigiosin (PG), to obtain functionally enhanced PHBV-based biomaterials. The
samples were produced in the form of films 115.6–118.8  m in thickness using the solvent casting
method. The effects of PG incorporation on the physical properties (morphology, biopolymer crystallinity
and thermal stability) and functionality of the obtained biomaterials were investigated. PG
has acted as a nucleating agent, in turn affecting the degree of crystallinity, thermal stability and
morphology of the films. All samples with PG had a more organized internal structure and higher
melting and degradation temperatures. The calculated degree of crystallinity of the PHBV copolymer
was 53%, while the PG1, PG3 and PG3 films had values of 64.0%, 63.9% and 69.2%, respectively.
Cytotoxicity studies have shown the excellent anticancer activity of films against HCT116 (colon
cancer) cells, thus advancing PHBV biomedical application potential.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - International Journal of Molecular Sciences
T1  - Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin
VL  - 24
SP  - 1906
DO  - 10.3390/ijms24031906
ER  - 
@article{
author = "Ponjavić, Marijana and Malagurski, Ivana and Lazić, Jelena and Jeremić, Sanja and Pavlović, Vladimir and Prlainović, Nevena and Maksimović, Vesna and Ćosović, Vladan and Atanase, Leonard Ionut",
year = "2023",
abstract = "The quest for sustainable biomaterials with excellent biocompatibility and tailorable
properties has put polyhydroxyalkanoates (PHAs) into the research spotlight. However, high production
costs and the lack of bioactivity limit their market penetration. To address this, poly(3-
hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was combined with a bacterial pigment with strong
anticancer activity, prodigiosin (PG), to obtain functionally enhanced PHBV-based biomaterials. The
samples were produced in the form of films 115.6–118.8  m in thickness using the solvent casting
method. The effects of PG incorporation on the physical properties (morphology, biopolymer crystallinity
and thermal stability) and functionality of the obtained biomaterials were investigated. PG
has acted as a nucleating agent, in turn affecting the degree of crystallinity, thermal stability and
morphology of the films. All samples with PG had a more organized internal structure and higher
melting and degradation temperatures. The calculated degree of crystallinity of the PHBV copolymer
was 53%, while the PG1, PG3 and PG3 films had values of 64.0%, 63.9% and 69.2%, respectively.
Cytotoxicity studies have shown the excellent anticancer activity of films against HCT116 (colon
cancer) cells, thus advancing PHBV biomedical application potential.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "International Journal of Molecular Sciences",
title = "Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin",
volume = "24",
pages = "1906",
doi = "10.3390/ijms24031906"
}
Ponjavić, M., Malagurski, I., Lazić, J., Jeremić, S., Pavlović, V., Prlainović, N., Maksimović, V., Ćosović, V.,& Atanase, L. I.. (2023). Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin. in International Journal of Molecular Sciences
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 24, 1906.
https://doi.org/10.3390/ijms24031906
Ponjavić M, Malagurski I, Lazić J, Jeremić S, Pavlović V, Prlainović N, Maksimović V, Ćosović V, Atanase LI. Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin. in International Journal of Molecular Sciences. 2023;24:1906.
doi:10.3390/ijms24031906 .
Ponjavić, Marijana, Malagurski, Ivana, Lazić, Jelena, Jeremić, Sanja, Pavlović, Vladimir, Prlainović, Nevena, Maksimović, Vesna, Ćosović, Vladan, Atanase, Leonard Ionut, "Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin" in International Journal of Molecular Sciences, 24 (2023):1906,
https://doi.org/10.3390/ijms24031906 . .
2
10

Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Maksimović, Vesna; Ćosović, Vladan; Nikolić, Nebojša D.; Krstajić Pajić, Mila; Rogan, Jelena

(Srpska akademija nauka i umetnosti, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
AU  - Krstajić Pajić, Mila
AU  - Rogan, Jelena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6327
AB  - Горивне ћелије са метанолом (DMFC) као горивом cу веома перспектпвни извори енергије за стационарне и преносиве електричне уређаје пре свега због своје високе ефикасности и ниске емисије загађујућих материја, ниске радне температуре, велике густине енергије, нетоксичних и еколошки прихватљивих карактеристика. Међутим, њихова шира комерцијална употреба ограничена је факторима као што су: високи трошкови племенитог метала у електрокатализатору (на пример, Pt) и лоша радна издржљивост, односно брза деградација катализатора. У овом раду је представљена активност електрооксидације метанола код PtSn, PtSnO2, PtZn и PtSnZn катализатора у киселој средини. Стабилне наночестице cу успешно синтетизоване модификованим полиол поступком уз помоћ микроталасне пећнице. Ефекти састава, степена легирања, величине и морфологије синтерованих честица на електрокаталитичку активност су испитивани СО стрипинг волтаметријом и реакцијом електрооксидације метанола. Добијени резултати указују на појачане каталитичке актигвности за реакцију оксидације метанола побољшану отпорност на инхибицију СО, након додавања Sn или  Zn у Pt катализатор.
PB  - Srpska akademija nauka i umetnosti
C3  - Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd
T1  - Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola
SP  - 18
EP  - 18
UR  - https://hdl.handle.net/21.15107/rcub_cer_6327
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Maksimović, Vesna and Ćosović, Vladan and Nikolić, Nebojša D. and Krstajić Pajić, Mila and Rogan, Jelena",
year = "2023",
abstract = "Горивне ћелије са метанолом (DMFC) као горивом cу веома перспектпвни извори енергије за стационарне и преносиве електричне уређаје пре свега због своје високе ефикасности и ниске емисије загађујућих материја, ниске радне температуре, велике густине енергије, нетоксичних и еколошки прихватљивих карактеристика. Међутим, њихова шира комерцијална употреба ограничена је факторима као што су: високи трошкови племенитог метала у електрокатализатору (на пример, Pt) и лоша радна издржљивост, односно брза деградација катализатора. У овом раду је представљена активност електрооксидације метанола код PtSn, PtSnO2, PtZn и PtSnZn катализатора у киселој средини. Стабилне наночестице cу успешно синтетизоване модификованим полиол поступком уз помоћ микроталасне пећнице. Ефекти састава, степена легирања, величине и морфологије синтерованих честица на електрокаталитичку активност су испитивани СО стрипинг волтаметријом и реакцијом електрооксидације метанола. Добијени резултати указују на појачане каталитичке актигвности за реакцију оксидације метанола побољшану отпорност на инхибицију СО, након додавања Sn или  Zn у Pt катализатор.",
publisher = "Srpska akademija nauka i umetnosti",
journal = "Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd",
title = "Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola",
pages = "18-18",
url = "https://hdl.handle.net/21.15107/rcub_cer_6327"
}
Stevanović, S., Milošević, D., Tripković, D., Maksimović, V., Ćosović, V., Nikolić, N. D., Krstajić Pajić, M.,& Rogan, J.. (2023). Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola. in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd
Srpska akademija nauka i umetnosti., 18-18.
https://hdl.handle.net/21.15107/rcub_cer_6327
Stevanović S, Milošević D, Tripković D, Maksimović V, Ćosović V, Nikolić ND, Krstajić Pajić M, Rogan J. Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola. in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd. 2023;:18-18.
https://hdl.handle.net/21.15107/rcub_cer_6327 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Maksimović, Vesna, Ćosović, Vladan, Nikolić, Nebojša D., Krstajić Pajić, Mila, Rogan, Jelena, "Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola" in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd (2023):18-18,
https://hdl.handle.net/21.15107/rcub_cer_6327 .

Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts

Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Maksimović, Vesna M.; Nikolić, Nebojša D.; Stevanović, Sanja

(Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala, 2023)

TY  - CONF
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna M.
AU  - Nikolić, Nebojša D.
AU  - Stevanović, Sanja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6497
AB  - One of the most popular alternative sources of energy are direct methanol fuel cells (DMFCs) with platinum-based catalysts due to their non-toxicity, reduced emissions of hazardous pollutants and high energy density. However, significant challenges of the scientific community related to Pt catalysts are the high cost, depletable resources and formation of poisoning species i.e. CO, during the methanol oxidation reaction. To reduce the amount of expensive Pt and susceptibility of Pt to poisoning species and simultaneously improve its catalytic performance, recent studies are focusing on the synthesis of Pt alloys in which a certain amount of platinum is replaced with less expensive metals such as Ru, Sn, Ni, Cu, Rh and Co. The usage of carbon (Vulcan XC-72R) for catalyst support enables high dispersion of metal, high surface area and good electrical conductivity improving overall performances of DMFCs. In this work, PtZn/C and PtSnZn/C catalysts were synthesized by the microwave-assisted polyol method. The structure and morphology of the catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TG) and X-ray diffraction (XRD) analysis. The activity and stability of synthesized catalysts for methanol oxidation in 0.5 M sulfuric acid were investigated. It was demonstrated that the activity of the platinum catalysts was improved thanks to the synergistic effects caused by the addition of different metals, such are bifunctional and electronic effects.
PB  - Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala
C3  - Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
T1  - Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts
T1  - Elektrooksidacija metanola na binarnim i ternarnim platinskim katalizatorima na ugljeničnom nosaču
SP  - POSTER-169
EP  - POSTER-170
UR  - https://hdl.handle.net/21.15107/rcub_cer_6497
ER  - 
@conference{
author = "Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Maksimović, Vesna M. and Nikolić, Nebojša D. and Stevanović, Sanja",
year = "2023",
abstract = "One of the most popular alternative sources of energy are direct methanol fuel cells (DMFCs) with platinum-based catalysts due to their non-toxicity, reduced emissions of hazardous pollutants and high energy density. However, significant challenges of the scientific community related to Pt catalysts are the high cost, depletable resources and formation of poisoning species i.e. CO, during the methanol oxidation reaction. To reduce the amount of expensive Pt and susceptibility of Pt to poisoning species and simultaneously improve its catalytic performance, recent studies are focusing on the synthesis of Pt alloys in which a certain amount of platinum is replaced with less expensive metals such as Ru, Sn, Ni, Cu, Rh and Co. The usage of carbon (Vulcan XC-72R) for catalyst support enables high dispersion of metal, high surface area and good electrical conductivity improving overall performances of DMFCs. In this work, PtZn/C and PtSnZn/C catalysts were synthesized by the microwave-assisted polyol method. The structure and morphology of the catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TG) and X-ray diffraction (XRD) analysis. The activity and stability of synthesized catalysts for methanol oxidation in 0.5 M sulfuric acid were investigated. It was demonstrated that the activity of the platinum catalysts was improved thanks to the synergistic effects caused by the addition of different metals, such are bifunctional and electronic effects.",
publisher = "Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala",
journal = "Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia",
title = "Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts, Elektrooksidacija metanola na binarnim i ternarnim platinskim katalizatorima na ugljeničnom nosaču",
pages = "POSTER-169-POSTER-170",
url = "https://hdl.handle.net/21.15107/rcub_cer_6497"
}
Milošević, D., Tripković, D., Ćosović, V., Maksimović, V. M., Nikolić, N. D.,& Stevanović, S.. (2023). Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala., POSTER-169-POSTER-170.
https://hdl.handle.net/21.15107/rcub_cer_6497
Milošević D, Tripković D, Ćosović V, Maksimović VM, Nikolić ND, Stevanović S. Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia. 2023;:POSTER-169-POSTER-170.
https://hdl.handle.net/21.15107/rcub_cer_6497 .
Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Maksimović, Vesna M., Nikolić, Nebojša D., Stevanović, Sanja, "Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts" in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia (2023):POSTER-169-POSTER-170,
https://hdl.handle.net/21.15107/rcub_cer_6497 .

Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Nikolić, Nebojša D.; Maksimović, Vesna

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6745
AB  - In order to achieve widespread application of fuel cell technology, the
development of an efficient and economical catalyst is a crucial step. Reducing the
diameter of catalyst particles, producing particles with a specific orientation surface,
and alloying noble metals with less expensive metals are possible approaches to
improve catalyst performance. This study will be focused on novel ways for creating
PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are
methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn
nanoparticles were produced using the microwave assisted polyol method and were
supported on high surface area carbon Vulcan XC-72R material. The electrochemical
behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry,
chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine
the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission
electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were
used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the
benefits of microwave synthesis and carefully adjusted metal alloying.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
T1  - Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells
SP  - 132
EP  - 132
UR  - https://hdl.handle.net/21.15107/rcub_cer_6745
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Nikolić, Nebojša D. and Maksimović, Vesna",
year = "2023",
abstract = "In order to achieve widespread application of fuel cell technology, the
development of an efficient and economical catalyst is a crucial step. Reducing the
diameter of catalyst particles, producing particles with a specific orientation surface,
and alloying noble metals with less expensive metals are possible approaches to
improve catalyst performance. This study will be focused on novel ways for creating
PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are
methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn
nanoparticles were produced using the microwave assisted polyol method and were
supported on high surface area carbon Vulcan XC-72R material. The electrochemical
behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry,
chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine
the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission
electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were
used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the
benefits of microwave synthesis and carefully adjusted metal alloying.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia",
title = "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells",
pages = "132-132",
url = "https://hdl.handle.net/21.15107/rcub_cer_6745"
}
Stevanović, S., Milošević, D., Tripković, D., Ćosović, V., Nikolić, N. D.,& Maksimović, V.. (2023). Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 132-132.
https://hdl.handle.net/21.15107/rcub_cer_6745
Stevanović S, Milošević D, Tripković D, Ćosović V, Nikolić ND, Maksimović V. Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia. 2023;:132-132.
https://hdl.handle.net/21.15107/rcub_cer_6745 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Nikolić, Nebojša D., Maksimović, Vesna, "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia (2023):132-132,
https://hdl.handle.net/21.15107/rcub_cer_6745 .

Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Maksimović, Vesna M.; Nikolić, Nebojša D.

(Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna M.
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6496
AB  - Polymer electrolyte membrane fuel cells (PEMFCs) are pure electrochemical energy converters that are key components of energy sources for vehicles and for stationary and portable energy suppliers. Searching for a good catalyst for the ethanol oxidation reaction is one of the most significant issues in material science. To increase the economic potential of fuel cell technology, catalyst must be extremely active, stable, and inexpensive. Due to its high catalytic activity, structural and chemical stability, and widespread use in commercial fuel cells, platinum is still the material of choice for making cathodes. Although there is extensive continuing research to reduce the Pt concentration while keeping the high catalytic activity, its high cost remains a barrier to a wider adoption of fuel cell technology.Therefore, the potential for cost reduction lies in the optimization of the catalyst, i.e. obtaining the maximum catalytic efficiency with the lowest possible content of noble metals. The focus of this research will be on novel synthesis techniques for PtSnZn catalysts with better efficiency and durability for the ethanol oxidation reaction. This research demonstrates the potential of studying new PtSnZn catalytic materials as catalysts for the oxidation of ethanol. This study used the microwave assisted polyol technique to create PtZn and PtSnZn nanoparticles supported on high surface area carbon Vulcan XC-72R material. By using cyclic voltammetry, electro-oxidation of adsorbed CO, and the chronoamperometric method, the electrochemical behavior of synthesized catalysts was examined. X-ray diffractometry, transmission electron microscopy analysis and thermogravimetric analysis were applied to obtain the physicochemical properties of the catalyst. The advantages of microwave synthesis and carefully balanced metal alloying in the PtSnZn/C catalysts led to a high catalytic activity of the synthesized catalyst in the ethanol oxidation reaction compared to the Pt/C catalyst.
PB  - Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala
C3  - Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
T1  - Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction
T1  - Promotivni efekat Zn u platinskom katalizatoru za efikasnu reakciju elektrooksidacije etanola
SP  - POSTER-102
EP  - POSTER-103
UR  - https://hdl.handle.net/21.15107/rcub_cer_6496
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Maksimović, Vesna M. and Nikolić, Nebojša D.",
year = "2023",
abstract = "Polymer electrolyte membrane fuel cells (PEMFCs) are pure electrochemical energy converters that are key components of energy sources for vehicles and for stationary and portable energy suppliers. Searching for a good catalyst for the ethanol oxidation reaction is one of the most significant issues in material science. To increase the economic potential of fuel cell technology, catalyst must be extremely active, stable, and inexpensive. Due to its high catalytic activity, structural and chemical stability, and widespread use in commercial fuel cells, platinum is still the material of choice for making cathodes. Although there is extensive continuing research to reduce the Pt concentration while keeping the high catalytic activity, its high cost remains a barrier to a wider adoption of fuel cell technology.Therefore, the potential for cost reduction lies in the optimization of the catalyst, i.e. obtaining the maximum catalytic efficiency with the lowest possible content of noble metals. The focus of this research will be on novel synthesis techniques for PtSnZn catalysts with better efficiency and durability for the ethanol oxidation reaction. This research demonstrates the potential of studying new PtSnZn catalytic materials as catalysts for the oxidation of ethanol. This study used the microwave assisted polyol technique to create PtZn and PtSnZn nanoparticles supported on high surface area carbon Vulcan XC-72R material. By using cyclic voltammetry, electro-oxidation of adsorbed CO, and the chronoamperometric method, the electrochemical behavior of synthesized catalysts was examined. X-ray diffractometry, transmission electron microscopy analysis and thermogravimetric analysis were applied to obtain the physicochemical properties of the catalyst. The advantages of microwave synthesis and carefully balanced metal alloying in the PtSnZn/C catalysts led to a high catalytic activity of the synthesized catalyst in the ethanol oxidation reaction compared to the Pt/C catalyst.",
publisher = "Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala",
journal = "Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia",
title = "Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction, Promotivni efekat Zn u platinskom katalizatoru za efikasnu reakciju elektrooksidacije etanola",
pages = "POSTER-102-POSTER-103",
url = "https://hdl.handle.net/21.15107/rcub_cer_6496"
}
Stevanović, S., Milošević, D., Tripković, D., Ćosović, V., Maksimović, V. M.,& Nikolić, N. D.. (2023). Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala., POSTER-102-POSTER-103.
https://hdl.handle.net/21.15107/rcub_cer_6496
Stevanović S, Milošević D, Tripković D, Ćosović V, Maksimović VM, Nikolić ND. Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia. 2023;:POSTER-102-POSTER-103.
https://hdl.handle.net/21.15107/rcub_cer_6496 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Maksimović, Vesna M., Nikolić, Nebojša D., "Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction" in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia (2023):POSTER-102-POSTER-103,
https://hdl.handle.net/21.15107/rcub_cer_6496 .

Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites

Nikolić, Nebojša D.; Lović, Jelena; Maksimović, Vesna; Stevanović, Sanja

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Lović, Jelena
AU  - Maksimović, Vesna
AU  - Stevanović, Sanja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6717
AB  - Tin dendrites found wide application in various industries.1 They can be obtained by both non-electrochemical and electrochemical methods of synthesis. In this study, they were produced by a galvanostatic regime of electrolysis from alkaline hydroxide solution at a current density of –3 mA cm–2, 1.5 times larger than the limiting diffusion current density, with an amount of the electricity of 200 and 400 mC. In the dependence of an amount of the passed electricity, Sn dendrites of various morphology and crystal orientation were obtained: the fern-like dendrites predominantly oriented in (220), (440) crystal planes are obtained with 200 mC and the spear-like and the dendrites with prismatic branches showing the strong (200),(400) preferred orientationwere obtained with 400 mC.
The strong correlation between morphology and structure of Sn dendrites is established and it can be explained by analysis of chronopotentiometry response obtained at the given current density and by morphological and structural analyses of Sn dendrites obtained by a potentiostatic regime at cathodic potentials corresponding to values attained after the passed amount of the electricity of 200 and 400 mC. The chronopotentiometry response after spent 200 mC was dominantly in the (–1600 –1740) mV vs. Ag/AgCl range, and the fern-like dendrites with the strong (220), (440) preferred orientation were obtained in this potential range. After spent 400 mC, the chronopotentiometry response was about –1200 mV vs. Ag/AgCl, and the spear-like and the dendrites with prismatic branches with the strong (200),(400) preferred orientationwere obtained at this cathodic potential.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
T1  - Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites
SP  - 136
EP  - 136
UR  - https://hdl.handle.net/21.15107/rcub_cer_6717
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Lović, Jelena and Maksimović, Vesna and Stevanović, Sanja",
year = "2023",
abstract = "Tin dendrites found wide application in various industries.1 They can be obtained by both non-electrochemical and electrochemical methods of synthesis. In this study, they were produced by a galvanostatic regime of electrolysis from alkaline hydroxide solution at a current density of –3 mA cm–2, 1.5 times larger than the limiting diffusion current density, with an amount of the electricity of 200 and 400 mC. In the dependence of an amount of the passed electricity, Sn dendrites of various morphology and crystal orientation were obtained: the fern-like dendrites predominantly oriented in (220), (440) crystal planes are obtained with 200 mC and the spear-like and the dendrites with prismatic branches showing the strong (200),(400) preferred orientationwere obtained with 400 mC.
The strong correlation between morphology and structure of Sn dendrites is established and it can be explained by analysis of chronopotentiometry response obtained at the given current density and by morphological and structural analyses of Sn dendrites obtained by a potentiostatic regime at cathodic potentials corresponding to values attained after the passed amount of the electricity of 200 and 400 mC. The chronopotentiometry response after spent 200 mC was dominantly in the (–1600 –1740) mV vs. Ag/AgCl range, and the fern-like dendrites with the strong (220), (440) preferred orientation were obtained in this potential range. After spent 400 mC, the chronopotentiometry response was about –1200 mV vs. Ag/AgCl, and the spear-like and the dendrites with prismatic branches with the strong (200),(400) preferred orientationwere obtained at this cathodic potential.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia",
title = "Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites",
pages = "136-136",
url = "https://hdl.handle.net/21.15107/rcub_cer_6717"
}
Nikolić, N. D., Lović, J., Maksimović, V.,& Stevanović, S.. (2023). Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 136-136.
https://hdl.handle.net/21.15107/rcub_cer_6717
Nikolić ND, Lović J, Maksimović V, Stevanović S. Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia. 2023;:136-136.
https://hdl.handle.net/21.15107/rcub_cer_6717 .
Nikolić, Nebojša D., Lović, Jelena, Maksimović, Vesna, Stevanović, Sanja, "Correlation Between Morphology and Structure of Galvanostatically Electrodeposited Tin Dendrites" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia (2023):136-136,
https://hdl.handle.net/21.15107/rcub_cer_6717 .

Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction

Milošević, Dragana; Stevanović, Sanja; Tripković, Dušan; Vukašinović, Ivana; Maksimović, Vesna; Ćosović, Vladan; Nikolić, Nebojša D.

(MDPI, 2023)

TY  - JOUR
AU  - Milošević, Dragana
AU  - Stevanović, Sanja
AU  - Tripković, Dušan
AU  - Vukašinović, Ivana
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6313
AB  - This work highlights the potential for the synthesis of new PtSnZn catalysts with enhanced efficiency and durability for methanol oxidation reaction (MOR) in low-temperature fuel cells. In this research, PtZn and PtSnZn nanoparticles deposited on high surface area Vulcan XC-72R Carbon support were created by a microwave-assisted polyol method. The electrochemical performances of synthesized catalysts were analyzed by cyclic voltammetry and by the electrooxidation of adsorbed CO and the chronoamperometric method. The physicochemical properties of obtained catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TGA) analysis, energy dispersive spectroscopy (EDS) and by X-ray diffraction (XRD). The obtained findings showed the successful synthesis of platinum-based catalysts. It was established that PtSnZn/C and PtZn/C catalysts have high electrocatalytic performance in methanol oxidation reactions. Catalysts stability tests were obtained by chronoamperometry. Stability tests also confirmed decreased poisoning and indicated improved stability and better tolerance to CO-like intermediate species. According to activity and stability measurements, the PtSnZn/C catalyst possesses the best electrochemical properties for the methanol oxidation reaction. The observed great electrocatalytic activity in the methanol oxidation reaction of synthesized catalysts can be attributed to the beneficial effects of microwave synthesis and the well-balanced addition of alloying metals in PtSnZn/C catalysts.
PB  - MDPI
T2  - Materials
T1  - Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction
VL  - 16
IS  - 13
SP  - 4617
DO  - https://doi.org/10.3390/ma16134617
ER  - 
@article{
author = "Milošević, Dragana and Stevanović, Sanja and Tripković, Dušan and Vukašinović, Ivana and Maksimović, Vesna and Ćosović, Vladan and Nikolić, Nebojša D.",
year = "2023",
abstract = "This work highlights the potential for the synthesis of new PtSnZn catalysts with enhanced efficiency and durability for methanol oxidation reaction (MOR) in low-temperature fuel cells. In this research, PtZn and PtSnZn nanoparticles deposited on high surface area Vulcan XC-72R Carbon support were created by a microwave-assisted polyol method. The electrochemical performances of synthesized catalysts were analyzed by cyclic voltammetry and by the electrooxidation of adsorbed CO and the chronoamperometric method. The physicochemical properties of obtained catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TGA) analysis, energy dispersive spectroscopy (EDS) and by X-ray diffraction (XRD). The obtained findings showed the successful synthesis of platinum-based catalysts. It was established that PtSnZn/C and PtZn/C catalysts have high electrocatalytic performance in methanol oxidation reactions. Catalysts stability tests were obtained by chronoamperometry. Stability tests also confirmed decreased poisoning and indicated improved stability and better tolerance to CO-like intermediate species. According to activity and stability measurements, the PtSnZn/C catalyst possesses the best electrochemical properties for the methanol oxidation reaction. The observed great electrocatalytic activity in the methanol oxidation reaction of synthesized catalysts can be attributed to the beneficial effects of microwave synthesis and the well-balanced addition of alloying metals in PtSnZn/C catalysts.",
publisher = "MDPI",
journal = "Materials",
title = "Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction",
volume = "16",
number = "13",
pages = "4617",
doi = "https://doi.org/10.3390/ma16134617"
}
Milošević, D., Stevanović, S., Tripković, D., Vukašinović, I., Maksimović, V., Ćosović, V.,& Nikolić, N. D.. (2023). Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction. in Materials
MDPI., 16(13), 4617.
https://doi.org/https://doi.org/10.3390/ma16134617
Milošević D, Stevanović S, Tripković D, Vukašinović I, Maksimović V, Ćosović V, Nikolić ND. Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction. in Materials. 2023;16(13):4617.
doi:https://doi.org/10.3390/ma16134617 .
Milošević, Dragana, Stevanović, Sanja, Tripković, Dušan, Vukašinović, Ivana, Maksimović, Vesna, Ćosović, Vladan, Nikolić, Nebojša D., "Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction" in Materials, 16, no. 13 (2023):4617,
https://doi.org/https://doi.org/10.3390/ma16134617 . .

The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response

Lović, Jelena; Nikolić, Nebojša D.; Maksimović, Vesna

(Springer Nature, 2023)

TY  - JOUR
AU  - Lović, Jelena
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5558
AB  - The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendritic
particles has been investigated. Sn dendrites were electrodeposited at the current density 1.5 times larger than the limiting diffusion
current density (− 3 mA cm−
2) with various amounts of the electricity (200 and 400 mC), and the obtained morphology
and structure of the particles were characterized by SEM and XRD techniques, respectively. The strong effect of the amount
of spent electricity on the morphology and structure of the particles was observed, and it is explained by morphological and
structural analysis of Sn particles produced potentiostatically at various cathodic potentials selected to be in line with the
recorded chronopotentiometry response. The strong correlation among chronopotentiometry response, morphology, and
structure of the Sn dendrites was established. The spear-like and the dendrites with prismatic branches possessed the strong
(200),(400) preferred orientation, and they were obtained with a chronopotentiometry response of about − 1200 mV vs. Ag/
AgCl. The chronopotentiometry responses in the − 1210 ÷ − 1740 mV vs. Ag/AgCl range caused a formation of the fern-like
dendrites with the strong (220),(440) preferred orientation. Based on the obtained results, it follows that the chronopotentiometry
analysis represents good diagnostic criteria for obtaining Sn powder particles of desired morphology and structure.
PB  - Springer Nature
T2  - Journal of Solid State Electrochemistry
T1  - The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response
DO  - 10.1007/s10008-023-05380-6
ER  - 
@article{
author = "Lović, Jelena and Nikolić, Nebojša D. and Maksimović, Vesna",
year = "2023",
abstract = "The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendritic
particles has been investigated. Sn dendrites were electrodeposited at the current density 1.5 times larger than the limiting diffusion
current density (− 3 mA cm−
2) with various amounts of the electricity (200 and 400 mC), and the obtained morphology
and structure of the particles were characterized by SEM and XRD techniques, respectively. The strong effect of the amount
of spent electricity on the morphology and structure of the particles was observed, and it is explained by morphological and
structural analysis of Sn particles produced potentiostatically at various cathodic potentials selected to be in line with the
recorded chronopotentiometry response. The strong correlation among chronopotentiometry response, morphology, and
structure of the Sn dendrites was established. The spear-like and the dendrites with prismatic branches possessed the strong
(200),(400) preferred orientation, and they were obtained with a chronopotentiometry response of about − 1200 mV vs. Ag/
AgCl. The chronopotentiometry responses in the − 1210 ÷ − 1740 mV vs. Ag/AgCl range caused a formation of the fern-like
dendrites with the strong (220),(440) preferred orientation. Based on the obtained results, it follows that the chronopotentiometry
analysis represents good diagnostic criteria for obtaining Sn powder particles of desired morphology and structure.",
publisher = "Springer Nature",
journal = "Journal of Solid State Electrochemistry",
title = "The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response",
doi = "10.1007/s10008-023-05380-6"
}
Lović, J., Nikolić, N. D.,& Maksimović, V.. (2023). The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response. in Journal of Solid State Electrochemistry
Springer Nature..
https://doi.org/10.1007/s10008-023-05380-6
Lović J, Nikolić ND, Maksimović V. The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response. in Journal of Solid State Electrochemistry. 2023;.
doi:10.1007/s10008-023-05380-6 .
Lović, Jelena, Nikolić, Nebojša D., Maksimović, Vesna, "The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response" in Journal of Solid State Electrochemistry (2023),
https://doi.org/10.1007/s10008-023-05380-6 . .

Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation

Ponjavić, Marijana; Stevanović, Sanja; Nikodinović-Runić, Jasmina; Jeremić, Sanja; Ćosović, Vladan; Maksimović, Vesna

(Elsevier BV, 2022)

TY  - JOUR
AU  - Ponjavić, Marijana
AU  - Stevanović, Sanja
AU  - Nikodinović-Runić, Jasmina
AU  - Jeremić, Sanja
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5573
AB  - Bacterial nanocellulose, BNC, has emerged as a new class of nanomaterials recognized as renewable, biodegradable, biocompatible and material for versatile applications. BNC also proved as a perfect support matrix for metallic nanoparticle synthesis and appeared as suitable alternative for widely used carbon based materials. Following the idea to replace commonly used carbon based materials for platinum supports with the green and sustainable one, BNC appeared as an excellent candidate. Herein, microwave assisted synthesis has been reported for the first time for platinum nanoparticles supported on BNC as green material. Bacterial nanocelullose-platinum catalyst, Pt/BNC, was investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), atomic force microscopy (AFM), X-ray diffractometry (XRD) and transmission-electron microscopy (TEM) analysis. The obtained results confirmed successful synthesis of new Pt-based catalyst. It was found that Pt/BNC catalyst has high electrocatalytic performance in methanol oxidation reaction. Green/sustainable catalytic system is highly desirable and provided by the elegant microwave assisted synthesis of Pt/BNC will pave the way for a larger scale application and expedite the market penetration of such fuel cells.
PB  - Elsevier BV
T2  - International Journal of Biological Macromolecules
T1  - Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation
VL  - 223
SP  - 1474
EP  - 1484
DO  - 10.1016/j.ijbiomac.2022.10.278
ER  - 
@article{
author = "Ponjavić, Marijana and Stevanović, Sanja and Nikodinović-Runić, Jasmina and Jeremić, Sanja and Ćosović, Vladan and Maksimović, Vesna",
year = "2022",
abstract = "Bacterial nanocellulose, BNC, has emerged as a new class of nanomaterials recognized as renewable, biodegradable, biocompatible and material for versatile applications. BNC also proved as a perfect support matrix for metallic nanoparticle synthesis and appeared as suitable alternative for widely used carbon based materials. Following the idea to replace commonly used carbon based materials for platinum supports with the green and sustainable one, BNC appeared as an excellent candidate. Herein, microwave assisted synthesis has been reported for the first time for platinum nanoparticles supported on BNC as green material. Bacterial nanocelullose-platinum catalyst, Pt/BNC, was investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), atomic force microscopy (AFM), X-ray diffractometry (XRD) and transmission-electron microscopy (TEM) analysis. The obtained results confirmed successful synthesis of new Pt-based catalyst. It was found that Pt/BNC catalyst has high electrocatalytic performance in methanol oxidation reaction. Green/sustainable catalytic system is highly desirable and provided by the elegant microwave assisted synthesis of Pt/BNC will pave the way for a larger scale application and expedite the market penetration of such fuel cells.",
publisher = "Elsevier BV",
journal = "International Journal of Biological Macromolecules",
title = "Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation",
volume = "223",
pages = "1474-1484",
doi = "10.1016/j.ijbiomac.2022.10.278"
}
Ponjavić, M., Stevanović, S., Nikodinović-Runić, J., Jeremić, S., Ćosović, V.,& Maksimović, V.. (2022). Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation. in International Journal of Biological Macromolecules
Elsevier BV., 223, 1474-1484.
https://doi.org/10.1016/j.ijbiomac.2022.10.278
Ponjavić M, Stevanović S, Nikodinović-Runić J, Jeremić S, Ćosović V, Maksimović V. Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation. in International Journal of Biological Macromolecules. 2022;223:1474-1484.
doi:10.1016/j.ijbiomac.2022.10.278 .
Ponjavić, Marijana, Stevanović, Sanja, Nikodinović-Runić, Jasmina, Jeremić, Sanja, Ćosović, Vladan, Maksimović, Vesna, "Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation" in International Journal of Biological Macromolecules, 223 (2022):1474-1484,
https://doi.org/10.1016/j.ijbiomac.2022.10.278 . .
3
2
3

Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support

Ponjavić, Marijana; Stevanović, Sanja; Jeremić, Sanja; Nikodinović-Runić, Jasmina; Ćosović, Vladan; Maksimović, Vesna

(Banja Luka : University in Banjaluka, Faculty of Technology, 2022)

TY  - CONF
AU  - Ponjavić, Marijana
AU  - Stevanović, Sanja
AU  - Jeremić, Sanja
AU  - Nikodinović-Runić, Jasmina
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna
PY  - 2022
UR  - https://savjetovanje.tf.unibl.org/home/digital-library/book-of-abstracts/
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5939
AB  - The main objective of this work was to prepare new platinum supported catalyst on BNC/PVA composite as nanoparticles carrier, designed for electrocatalytic applications. For that purpose, BNC/Pt suspension was mixed with 1 wt% PVA solution and BNC/PVA/Pt catalyst in the form of film was successfully synthesized. The structure and thermal properties of catalyst were characterized by ATR-FTIR and TG analysis, respectively, while its crystallinity was investigated 
by XRD analysis. Electrocatalytic potential of BNC/PVA/Pt catalyst was tested in methanol 
oxidation reaction. Remarkable catalytic activity of new Pt based catalyst was confirmed. The 
obtained results for catalyst activity was comparable to those obtained for preferentially used 
carbon based Pt supports pointing that BNC based composited can be considered as great 
substitution of carbon based materials with the green one.
PB  - Banja Luka : University in Banjaluka, Faculty of Technology
C3  - Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
T1  - Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support
SP  - 33
EP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_cer_5939
ER  - 
@conference{
author = "Ponjavić, Marijana and Stevanović, Sanja and Jeremić, Sanja and Nikodinović-Runić, Jasmina and Ćosović, Vladan and Maksimović, Vesna",
year = "2022",
abstract = "The main objective of this work was to prepare new platinum supported catalyst on BNC/PVA composite as nanoparticles carrier, designed for electrocatalytic applications. For that purpose, BNC/Pt suspension was mixed with 1 wt% PVA solution and BNC/PVA/Pt catalyst in the form of film was successfully synthesized. The structure and thermal properties of catalyst were characterized by ATR-FTIR and TG analysis, respectively, while its crystallinity was investigated 
by XRD analysis. Electrocatalytic potential of BNC/PVA/Pt catalyst was tested in methanol 
oxidation reaction. Remarkable catalytic activity of new Pt based catalyst was confirmed. The 
obtained results for catalyst activity was comparable to those obtained for preferentially used 
carbon based Pt supports pointing that BNC based composited can be considered as great 
substitution of carbon based materials with the green one.",
publisher = "Banja Luka : University in Banjaluka, Faculty of Technology",
journal = "Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka",
title = "Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support",
pages = "33-33",
url = "https://hdl.handle.net/21.15107/rcub_cer_5939"
}
Ponjavić, M., Stevanović, S., Jeremić, S., Nikodinović-Runić, J., Ćosović, V.,& Maksimović, V.. (2022). Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support. in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
Banja Luka : University in Banjaluka, Faculty of Technology., 33-33.
https://hdl.handle.net/21.15107/rcub_cer_5939
Ponjavić M, Stevanović S, Jeremić S, Nikodinović-Runić J, Ćosović V, Maksimović V. Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support. in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka. 2022;:33-33.
https://hdl.handle.net/21.15107/rcub_cer_5939 .
Ponjavić, Marijana, Stevanović, Sanja, Jeremić, Sanja, Nikodinović-Runić, Jasmina, Ćosović, Vladan, Maksimović, Vesna, "Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support" in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka (2022):33-33,
https://hdl.handle.net/21.15107/rcub_cer_5939 .

Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes

Lović, Jelena D.; Nikolić, Nebojša D.; Maksimović, Vesna M.; Živković, Predrag, M.

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Lović, Jelena D.
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna M.
AU  - Živković, Predrag, M.
PY  - 2022
UR  - https://elmina.tmf.bg.ac.rs/index.php/book-of-abstracts
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5226
AB  - In this study, Sn powders were electrodeposited from an alkaline electrolyte containing 20 g/l SnCl2 × 2H2O in 250 g/l NaOH at the room temperature by application of both potentiostatic and 
galvanostatic regimes of the electrolysis. Electrodeposition was performed at various cathodic 
potentials (−1185, – 1200, −1270, – 1400, – 1600 and – 1800 mV vs. Ag/AgCl), and at a current 
density outside the plateau of the limiting diffusion current density (−3.0 mA cm-2). Morphology of 
Sn particles is characterized by scanning electron microscope (SEM) and crystal structure by X-ray 
diffraction (XRD).
PB  - Belgrade : Serbian Academy of Sciences and Arts
PB  - Belgrade : Faculty of Technology and Metallurgy, University of Belgrade
C3  - Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022
T1  - Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes
SP  - 90
EP  - 91
UR  - https://hdl.handle.net/21.15107/rcub_cer_5226
ER  - 
@conference{
author = "Lović, Jelena D. and Nikolić, Nebojša D. and Maksimović, Vesna M. and Živković, Predrag, M.",
year = "2022",
abstract = "In this study, Sn powders were electrodeposited from an alkaline electrolyte containing 20 g/l SnCl2 × 2H2O in 250 g/l NaOH at the room temperature by application of both potentiostatic and 
galvanostatic regimes of the electrolysis. Electrodeposition was performed at various cathodic 
potentials (−1185, – 1200, −1270, – 1400, – 1600 and – 1800 mV vs. Ag/AgCl), and at a current 
density outside the plateau of the limiting diffusion current density (−3.0 mA cm-2). Morphology of 
Sn particles is characterized by scanning electron microscope (SEM) and crystal structure by X-ray 
diffraction (XRD).",
publisher = "Belgrade : Serbian Academy of Sciences and Arts, Belgrade : Faculty of Technology and Metallurgy, University of Belgrade",
journal = "Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022",
title = "Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes",
pages = "90-91",
url = "https://hdl.handle.net/21.15107/rcub_cer_5226"
}
Lović, J. D., Nikolić, N. D., Maksimović, V. M.,& Živković, P. M.. (2022). Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes. in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022
Belgrade : Serbian Academy of Sciences and Arts., 90-91.
https://hdl.handle.net/21.15107/rcub_cer_5226
Lović JD, Nikolić ND, Maksimović VM, Živković PM. Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes. in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022. 2022;:90-91.
https://hdl.handle.net/21.15107/rcub_cer_5226 .
Lović, Jelena D., Nikolić, Nebojša D., Maksimović, Vesna M., Živković, Predrag, M., "Morphological and Structural Characterization of Tin Dendritic Nanostructures Produced by Various Electrodeposition Processes" in Program and Book of Abstracts - Second International Conference on Electron Microscopy of Nanostructures, ELMINA 2022 (2022):90-91,
https://hdl.handle.net/21.15107/rcub_cer_5226 .

Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites

Nikolić, Nebojša D.; Lović, Jelena; Maksimović, Vesna M.

(Beograd : Serbian Society of Corrosion and Materials Protection UISKOZAM / Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM, 2022)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Lović, Jelena
AU  - Maksimović, Vesna M.
PY  - 2022
UR  - http://sitzam.org.rs/YUCORR/XXIII_YuCorr_Proceedings_Knjiga_Radova.pdf
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5220
AB  - Tin dendrites were synthesized via electrochemical route from the alkaline electrolyte applying both 
potentiostatic and galvanostatic regimes of the electrodeposition. Various both cathodic potentials 
and amounts of the passed electricity were used for Sn electrodeposition in the potentiostatic regime. Morphology and structure of synthesized tin dendritic particles were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, respectively. Depending on the applied cathodic potential, morphology of tin dendrites changed from the needle-like and the spear-like to very ramified dendrites of various shape. The branchy Sn dendrites were of two dimensional (2D) shape constructed from stalk and branches developed from it (primary (P) branches), classifying them into 2D(P) type according to Wranglen`s definition of a dendrite. The XRD analysis of produced tin particles showed that the needle-like and the spear-like dendrites represented monocrystals (200) orientation, while Sn crystallites in the potenciostatically obtained 2D(P) dendrites were predominately oriented in (440) plane. Morphology of tin particles was also correlated with polarization characteristics for this system, confirming belonging tin to the group of the normal metals, characterized by the high values of the exchange current density and overpotential for hydrogen evolution reaction, and by the low melting point.
AB  - Dendriti kalaja su bili sintetizovani elektrohemijskim putem iz alkalnog elektrolita primenjujući i potenciostatski i galvanostatski režim elektrohemijskog taloženja. Elektrohemijsko taloženje kalaja u potenciostatskom režimu je vršeno na različitim katodnim potencijalima i sa različitim količinama naelektrisanja. Morfologija i struktura sintetizovanih dendritičnih čestica kalaja su okarakterisane tehnikom skenirajuće elektronske mikroskopije (SEM) i rentgensko difrakcionom analizom. U 
zavisnosti od primenjenog katodnog potencijala, morfologija dendrita kalaja se menjala od igličastih i dendrita nalik koplju do veoma razgranatih dendrita. Veoma razgranati kalajni dendriti su bili dvodimenzionalnog (2D) oblika izgrađeni od stabla i grana razvijenih iz stabla (primarne (P) grane), klasifikujući ih u 2D(P) tip prema Vranglenovoj definiciji dendrita. Rentgensko-difrakciona analiza je pokazala da igličasti i dendriti nalik koplju su predstavljali monokristale (200) orijentacije, dok su 
kristaliti kalaja u potenciostatski dobijenim 2D(P) dendritima bili predominantno orijentisani u (440) ravni. Morfologija čestica kalaja je bila takođe korelisana sa polarizacionim arakteristikama za ovaj sistem, potvrđujući pripadnost kalaja grupi normalnih metala okarakterisanih visokim vrednostima gustine struje izmene i prenapetosti za reakciju izdvajanja vodonika, i niskom tačkom topljenja.
PB  - Beograd : Serbian Society of Corrosion and Materials Protection UISKOZAM / Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM
C3  - Proceedings - XXIII YuCorr – Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, Divčibare, Serbia, May 2022
T1  - Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites
T1  - Uticaj parametra i režima elektrohemijskog taloženja na morfologiju i strukturu  dendrita kalaja
SP  - POSTER-154
UR  - https://hdl.handle.net/21.15107/rcub_cer_5220
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Lović, Jelena and Maksimović, Vesna M.",
year = "2022",
abstract = "Tin dendrites were synthesized via electrochemical route from the alkaline electrolyte applying both 
potentiostatic and galvanostatic regimes of the electrodeposition. Various both cathodic potentials 
and amounts of the passed electricity were used for Sn electrodeposition in the potentiostatic regime. Morphology and structure of synthesized tin dendritic particles were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, respectively. Depending on the applied cathodic potential, morphology of tin dendrites changed from the needle-like and the spear-like to very ramified dendrites of various shape. The branchy Sn dendrites were of two dimensional (2D) shape constructed from stalk and branches developed from it (primary (P) branches), classifying them into 2D(P) type according to Wranglen`s definition of a dendrite. The XRD analysis of produced tin particles showed that the needle-like and the spear-like dendrites represented monocrystals (200) orientation, while Sn crystallites in the potenciostatically obtained 2D(P) dendrites were predominately oriented in (440) plane. Morphology of tin particles was also correlated with polarization characteristics for this system, confirming belonging tin to the group of the normal metals, characterized by the high values of the exchange current density and overpotential for hydrogen evolution reaction, and by the low melting point., Dendriti kalaja su bili sintetizovani elektrohemijskim putem iz alkalnog elektrolita primenjujući i potenciostatski i galvanostatski režim elektrohemijskog taloženja. Elektrohemijsko taloženje kalaja u potenciostatskom režimu je vršeno na različitim katodnim potencijalima i sa različitim količinama naelektrisanja. Morfologija i struktura sintetizovanih dendritičnih čestica kalaja su okarakterisane tehnikom skenirajuće elektronske mikroskopije (SEM) i rentgensko difrakcionom analizom. U 
zavisnosti od primenjenog katodnog potencijala, morfologija dendrita kalaja se menjala od igličastih i dendrita nalik koplju do veoma razgranatih dendrita. Veoma razgranati kalajni dendriti su bili dvodimenzionalnog (2D) oblika izgrađeni od stabla i grana razvijenih iz stabla (primarne (P) grane), klasifikujući ih u 2D(P) tip prema Vranglenovoj definiciji dendrita. Rentgensko-difrakciona analiza je pokazala da igličasti i dendriti nalik koplju su predstavljali monokristale (200) orijentacije, dok su 
kristaliti kalaja u potenciostatski dobijenim 2D(P) dendritima bili predominantno orijentisani u (440) ravni. Morfologija čestica kalaja je bila takođe korelisana sa polarizacionim arakteristikama za ovaj sistem, potvrđujući pripadnost kalaja grupi normalnih metala okarakterisanih visokim vrednostima gustine struje izmene i prenapetosti za reakciju izdvajanja vodonika, i niskom tačkom topljenja.",
publisher = "Beograd : Serbian Society of Corrosion and Materials Protection UISKOZAM / Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM",
journal = "Proceedings - XXIII YuCorr – Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, Divčibare, Serbia, May 2022",
title = "Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites, Uticaj parametra i režima elektrohemijskog taloženja na morfologiju i strukturu  dendrita kalaja",
pages = "POSTER-154",
url = "https://hdl.handle.net/21.15107/rcub_cer_5220"
}
Nikolić, N. D., Lović, J.,& Maksimović, V. M.. (2022). Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites. in Proceedings - XXIII YuCorr – Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, Divčibare, Serbia, May 2022
Beograd : Serbian Society of Corrosion and Materials Protection UISKOZAM / Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM., POSTER-154.
https://hdl.handle.net/21.15107/rcub_cer_5220
Nikolić ND, Lović J, Maksimović VM. Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites. in Proceedings - XXIII YuCorr – Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, Divčibare, Serbia, May 2022. 2022;:POSTER-154.
https://hdl.handle.net/21.15107/rcub_cer_5220 .
Nikolić, Nebojša D., Lović, Jelena, Maksimović, Vesna M., "Influence of Parameters and Regimes of the Electrodeposition on Morphology and Structure of Tin Dendrites" in Proceedings - XXIII YuCorr – Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, Divčibare, Serbia, May 2022 (2022):POSTER-154,
https://hdl.handle.net/21.15107/rcub_cer_5220 .

Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures

Nikolić, Nebojša D.; Lović, Jelena; Maksimović, Vesna; Živković, Predrag M.

(MDPI, 2022)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Lović, Jelena
AU  - Maksimović, Vesna
AU  - Živković, Predrag M.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5172
AB  - The formation of tin dendritic nanostructures by electrolysis from the alkaline electrolyte
has been investigated. Morphology and structure of Sn dendrites produced applying both potentiostatic and galvanostatic regimes of the electrolysis are characterized by SEM and XRD, respectively. Depending on the applied cathodic potentials, three types of Sn dendrites were obtained: (a) needle like and spear-like, (b) fern-like, and (c) stem-like dendrites. The very branchy dendrites with branches of the prismatic shape obtained by the galvanostatic regime of electrolysis represented a
novel type of Sn dendrites, not previously reported in the literature. To explain the formation of
various dendritic forms, correlation with the polarization characteristics for this electrodeposition
system is considered. The needle-like and the spear-like dendrites represented monocrystals of
(200),(400) preferred orientation, the fern-like dendrites exhibited the predominant (220),(440) preferred
orientation, while in the stem-like particles Sn crystallites were oriented to a greater extent in
the (440) crystal plane than in other planes. The galvanostatically synthesized Sn particles possessed the strong (200),(400) preferred orientation. The strong influence of parameters and regimes of
electrodeposition on structural characteristics of Sn dendrites is explained by the fundamental laws
of electrocrystallization taking into consideration the concept of slow-growing and fast-growing
crystal planes.
PB  - MDPI
T2  - Metals
T1  - Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures
VL  - 12
IS  - 7
SP  - 1201
DO  - 10.3390/met12071201
ER  - 
@article{
author = "Nikolić, Nebojša D. and Lović, Jelena and Maksimović, Vesna and Živković, Predrag M.",
year = "2022",
abstract = "The formation of tin dendritic nanostructures by electrolysis from the alkaline electrolyte
has been investigated. Morphology and structure of Sn dendrites produced applying both potentiostatic and galvanostatic regimes of the electrolysis are characterized by SEM and XRD, respectively. Depending on the applied cathodic potentials, three types of Sn dendrites were obtained: (a) needle like and spear-like, (b) fern-like, and (c) stem-like dendrites. The very branchy dendrites with branches of the prismatic shape obtained by the galvanostatic regime of electrolysis represented a
novel type of Sn dendrites, not previously reported in the literature. To explain the formation of
various dendritic forms, correlation with the polarization characteristics for this electrodeposition
system is considered. The needle-like and the spear-like dendrites represented monocrystals of
(200),(400) preferred orientation, the fern-like dendrites exhibited the predominant (220),(440) preferred
orientation, while in the stem-like particles Sn crystallites were oriented to a greater extent in
the (440) crystal plane than in other planes. The galvanostatically synthesized Sn particles possessed the strong (200),(400) preferred orientation. The strong influence of parameters and regimes of
electrodeposition on structural characteristics of Sn dendrites is explained by the fundamental laws
of electrocrystallization taking into consideration the concept of slow-growing and fast-growing
crystal planes.",
publisher = "MDPI",
journal = "Metals",
title = "Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures",
volume = "12",
number = "7",
pages = "1201",
doi = "10.3390/met12071201"
}
Nikolić, N. D., Lović, J., Maksimović, V.,& Živković, P. M.. (2022). Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures. in Metals
MDPI., 12(7), 1201.
https://doi.org/10.3390/met12071201
Nikolić ND, Lović J, Maksimović V, Živković PM. Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures. in Metals. 2022;12(7):1201.
doi:10.3390/met12071201 .
Nikolić, Nebojša D., Lović, Jelena, Maksimović, Vesna, Živković, Predrag M., "Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures" in Metals, 12, no. 7 (2022):1201,
https://doi.org/10.3390/met12071201 . .
3

Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction

Stevanović, Sanja; Ponjavić, Marijana; Nikodinović-Runić, Jasmina; Maksimović, Vesna; Ćosović, Vladan

(Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM), 2021)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Ponjavić, Marijana
AU  - Nikodinović-Runić, Jasmina
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4876
AB  - Catalysts support is essential for nanostructured noble metal catalysts activity and stability since that interaction between the metal particle and the support can affect metal particle size and dispersion. Over the last few decades, the most popular catalysts supports are carbon based materials: Vulcan XC-72 carbon black (CB), multi-walled carbon nanotubes (MWCNTs) and graphene. However, their cost-effective production remains a challenge since most of these materials are obtained by pyrolysis of coal or petroleum. Not less negligible is their negative impact on the environment during synthesis because these processes include release of carbon dioxide and other harmful organic products into the atmosphere. Applications of bacterial nanocelluloses as a catalyst support has attracted a great attention since it can be easily synthesized and is an inexpensive, biodegradable, sustainable and green material. Bacterial nanocellulose (BNC) was produced utilizing the Komagataeibacter medellinensis ID13488 strain. Stable Pt nanoparticles supported on BNC (Pt/BNC) have been synthetized from a precursor solution of H2PtCl6 by microwave assisted polyol procedure. Catalytic activity was tested for methanol oxidation reaction in sulfuric acid solution. The Fourier transform infrared spectroscopy was used to confirm the structure of bacterial nanocellulose as well as after synthesis of Pt-BNC catalyst. Coupled differential scanning calorimetry (DSC) / thermogravimetric (TG) analysis revealed no loss of platinum during synthesis process. XRD analysis showed characteristic peaks for fcc crystalline structure of Pt/BNC and particle size of 1,7 nm. The activity of the Pt/BNC, catalyst for methanol oxidation was evaluated from potentiodynamic measurements in 0.5 M H2SO4 + 0.5 M CH3OH solution. The results obtained indicate enhanced catalytic activities for methanol oxidation reaction.
AB  - Podloge katalizatora imaju veoma važnu ulogu tokom sinteze katalizatora sa plemenitim metalima obzirom da od njihove interakcije sa metalom zavisi veličina čestica i njihova disperzija tokom procesa sinteze. Tokom poslednjih nekoliko decenija kao najčešće korišćene podloge za platinske katalizatore su korišćene podloge na bazi uglljenika: ugalj razvijene površine (Vulcan XC), ugljenične nanotube ili grafen. Međutim, proces dobijanja ovih materijala ima visoke cene zbog toga što se za njihovo dobijanje koriste procesi pirolize uglja ili nafte. Ništa manje zanemarljiv je i negativan uticaj ovih procesa na okolinu pošto procesi sinteze uključuju oslobađanje ugljen dioksida i drugih štetnih materija u atmosferu. Primena bakterijskih nanoceluloza kao nosača katalizatora privukla je veliku pažnju jer se mogu lako sintetizovati i predstavljaju jeftin, biorazgradiv, održiv i zeleni materijal. Bakterijska nanoceluloza (BNC) proizvedena je upotrebom soja Komagataeibacter medellinensis ID13488. Stabilne Pt nanočestice suspendovane na BNC (Pt/BNC) sintetizovane su iz prekursorskog H2PtCl6 rastvora poliol postupkom uz pomoć mikrotalasne pećnice. Ispitivana je katalitička aktivnost reakcije oksidacije metanola u rastvoru sumporne kiseline. Infracrvena spektroskopija Fourierove transformacije je korišćena za potvrdu strukture same bakterijske nanoceluloze, kao i nakon sinteze Pt-BNC katalizatora. Diferencijalna skenirajuća kalorimetrija (DSC) / termogravimetrijska (TG) analiza nije otkrila gubitak platine tokom procesa sinteze. XRD analiza pokazala je karakteristične vrhove za fcc kristalnu strukturu Pt/BNC i veličinu čestica od 1,7 nm. Aktivnost Pt/BNC, katalizatora za oksidaciju metanola, procenjena je iz potenciodinamičkih merenja u 0,5 M H2SO4 + 0,5 M CH3OH rastvoru. Dobijeni rezultati ukazuju na pojačanu katalitičku aktivnost reakcije oksidacije metanola.
PB  - Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
T1  - Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction
T1  - Bakterijska celuloza kao podloga za platinske kataliztore za reakciju elektrooksidacije metanola
SP  - 49
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_cer_4876
ER  - 
@conference{
author = "Stevanović, Sanja and Ponjavić, Marijana and Nikodinović-Runić, Jasmina and Maksimović, Vesna and Ćosović, Vladan",
year = "2021",
abstract = "Catalysts support is essential for nanostructured noble metal catalysts activity and stability since that interaction between the metal particle and the support can affect metal particle size and dispersion. Over the last few decades, the most popular catalysts supports are carbon based materials: Vulcan XC-72 carbon black (CB), multi-walled carbon nanotubes (MWCNTs) and graphene. However, their cost-effective production remains a challenge since most of these materials are obtained by pyrolysis of coal or petroleum. Not less negligible is their negative impact on the environment during synthesis because these processes include release of carbon dioxide and other harmful organic products into the atmosphere. Applications of bacterial nanocelluloses as a catalyst support has attracted a great attention since it can be easily synthesized and is an inexpensive, biodegradable, sustainable and green material. Bacterial nanocellulose (BNC) was produced utilizing the Komagataeibacter medellinensis ID13488 strain. Stable Pt nanoparticles supported on BNC (Pt/BNC) have been synthetized from a precursor solution of H2PtCl6 by microwave assisted polyol procedure. Catalytic activity was tested for methanol oxidation reaction in sulfuric acid solution. The Fourier transform infrared spectroscopy was used to confirm the structure of bacterial nanocellulose as well as after synthesis of Pt-BNC catalyst. Coupled differential scanning calorimetry (DSC) / thermogravimetric (TG) analysis revealed no loss of platinum during synthesis process. XRD analysis showed characteristic peaks for fcc crystalline structure of Pt/BNC and particle size of 1,7 nm. The activity of the Pt/BNC, catalyst for methanol oxidation was evaluated from potentiodynamic measurements in 0.5 M H2SO4 + 0.5 M CH3OH solution. The results obtained indicate enhanced catalytic activities for methanol oxidation reaction., Podloge katalizatora imaju veoma važnu ulogu tokom sinteze katalizatora sa plemenitim metalima obzirom da od njihove interakcije sa metalom zavisi veličina čestica i njihova disperzija tokom procesa sinteze. Tokom poslednjih nekoliko decenija kao najčešće korišćene podloge za platinske katalizatore su korišćene podloge na bazi uglljenika: ugalj razvijene površine (Vulcan XC), ugljenične nanotube ili grafen. Međutim, proces dobijanja ovih materijala ima visoke cene zbog toga što se za njihovo dobijanje koriste procesi pirolize uglja ili nafte. Ništa manje zanemarljiv je i negativan uticaj ovih procesa na okolinu pošto procesi sinteze uključuju oslobađanje ugljen dioksida i drugih štetnih materija u atmosferu. Primena bakterijskih nanoceluloza kao nosača katalizatora privukla je veliku pažnju jer se mogu lako sintetizovati i predstavljaju jeftin, biorazgradiv, održiv i zeleni materijal. Bakterijska nanoceluloza (BNC) proizvedena je upotrebom soja Komagataeibacter medellinensis ID13488. Stabilne Pt nanočestice suspendovane na BNC (Pt/BNC) sintetizovane su iz prekursorskog H2PtCl6 rastvora poliol postupkom uz pomoć mikrotalasne pećnice. Ispitivana je katalitička aktivnost reakcije oksidacije metanola u rastvoru sumporne kiseline. Infracrvena spektroskopija Fourierove transformacije je korišćena za potvrdu strukture same bakterijske nanoceluloze, kao i nakon sinteze Pt-BNC katalizatora. Diferencijalna skenirajuća kalorimetrija (DSC) / termogravimetrijska (TG) analiza nije otkrila gubitak platine tokom procesa sinteze. XRD analiza pokazala je karakteristične vrhove za fcc kristalnu strukturu Pt/BNC i veličinu čestica od 1,7 nm. Aktivnost Pt/BNC, katalizatora za oksidaciju metanola, procenjena je iz potenciodinamičkih merenja u 0,5 M H2SO4 + 0,5 M CH3OH rastvoru. Dobijeni rezultati ukazuju na pojačanu katalitičku aktivnost reakcije oksidacije metanola.",
publisher = "Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija",
title = "Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction, Bakterijska celuloza kao podloga za platinske kataliztore za reakciju elektrooksidacije metanola",
pages = "49-50",
url = "https://hdl.handle.net/21.15107/rcub_cer_4876"
}
Stevanović, S., Ponjavić, M., Nikodinović-Runić, J., Maksimović, V.,& Ćosović, V.. (2021). Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)., 49-50.
https://hdl.handle.net/21.15107/rcub_cer_4876
Stevanović S, Ponjavić M, Nikodinović-Runić J, Maksimović V, Ćosović V. Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija. 2021;:49-50.
https://hdl.handle.net/21.15107/rcub_cer_4876 .
Stevanović, Sanja, Ponjavić, Marijana, Nikodinović-Runić, Jasmina, Maksimović, Vesna, Ćosović, Vladan, "Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija (2021):49-50,
https://hdl.handle.net/21.15107/rcub_cer_4876 .

Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes

Nikolić, Nebojša D.; Maksimović, Vesna M.; Avramović, Ljiljana

(MDPI, 2021)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna M.
AU  - Avramović, Ljiljana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4680
AB  - In this review paper, morphologies of metal powders produced by the constant (potentiostatic
and galvanostatic) regimes of electrolysis from aqueous electrolytes are correlated with
their crystal structure at the semiquantitative level. The main parameters affecting the shape of
powder particles are the exchange current density (rate of electrochemical process) and overpotential for hydrogen evolution reaction. Depending on them, various shapes of dendrites (the needles, the two-dimensional (2D) fern-like, and the three-dimensional (3D) pine-like dendrites), and the particles formed under vigorous hydrogen evolution (cauliflower-like and spongy-like particles) are produced by these regimes of electrolysis. By decreasing the exchange current density value, the crystal structure of the powder particles is changed from the strong (111) preferred orientation obtained for the needle-like (silver) and the 2D (lead) dendrites to the randomly orientated crystallites in particles with the spherical morphology (the 3D dendrites and the cauliflower-like and the spongylike particles). The formation of metal powders by molten salt electrolysis and by electrolysis in deep eutectic solvents (DESs) and the crystallographic aspects of dendritic growth are also mentioned in this review.
PB  - MDPI
T2  - Metals
T1  - Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes
VL  - 11
IS  - 6
SP  - 859
DO  - 10.3390/met11060859
ER  - 
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna M. and Avramović, Ljiljana",
year = "2021",
abstract = "In this review paper, morphologies of metal powders produced by the constant (potentiostatic
and galvanostatic) regimes of electrolysis from aqueous electrolytes are correlated with
their crystal structure at the semiquantitative level. The main parameters affecting the shape of
powder particles are the exchange current density (rate of electrochemical process) and overpotential for hydrogen evolution reaction. Depending on them, various shapes of dendrites (the needles, the two-dimensional (2D) fern-like, and the three-dimensional (3D) pine-like dendrites), and the particles formed under vigorous hydrogen evolution (cauliflower-like and spongy-like particles) are produced by these regimes of electrolysis. By decreasing the exchange current density value, the crystal structure of the powder particles is changed from the strong (111) preferred orientation obtained for the needle-like (silver) and the 2D (lead) dendrites to the randomly orientated crystallites in particles with the spherical morphology (the 3D dendrites and the cauliflower-like and the spongylike particles). The formation of metal powders by molten salt electrolysis and by electrolysis in deep eutectic solvents (DESs) and the crystallographic aspects of dendritic growth are also mentioned in this review.",
publisher = "MDPI",
journal = "Metals",
title = "Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes",
volume = "11",
number = "6",
pages = "859",
doi = "10.3390/met11060859"
}
Nikolić, N. D., Maksimović, V. M.,& Avramović, L.. (2021). Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes. in Metals
MDPI., 11(6), 859.
https://doi.org/10.3390/met11060859
Nikolić ND, Maksimović VM, Avramović L. Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes. in Metals. 2021;11(6):859.
doi:10.3390/met11060859 .
Nikolić, Nebojša D., Maksimović, Vesna M., Avramović, Ljiljana, "Correlation of Morphology and Crystal Structure of Metal Powders Produced by Electrolysis Processes" in Metals, 11, no. 6 (2021):859,
https://doi.org/10.3390/met11060859 . .
14
2
14

Influence of regime of electrolysis on morphology and structure of copper dendrites

Nikolić, Nebojša D.; Maksimović, Vesna M.; Baščarević, Zvezdana; Živković, Predrag M.; Pavlović, Miomir G.

(Belgrade : Serbian Society of Corrosion and Materials Protection UISKOZAM, 2021)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna M.
AU  - Baščarević, Zvezdana
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir G.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4874
AB  - Comparative analysis of morphological and structural features of copper dendrites obtained by potentiostatic and galvanostatic regimes of electrolysis was made. The 3D (three dimensional) pine-like dendrites composed from stalk and corncob-like forms as branches, with the sharp tips of both stalk and branches, were obtained by the potentiostatic regime of electrolysis with all analyzed amounts of passed electricity. On the other hand, with increasing the amount of the passed electricity the shape of 3D pine-line dendrites obtained by the galvanostatic regime of electrolysis changed than those with the sharp tips of stalk and branches to those which the tips finished globules. Comparing with Cu deposits obtained at overpotentials which belonged to different types of electrodeposition control, it is concluded that overpotential at the end of passed amount of the electricity plays crucial role in the final shape of galvanostatically produced Cu dendrites. Irrespective of the shape of Cu dendrites, crystallites of copper were random oriented in the both types of dendrites.
AB  - Napravljena je uporedna analiza morfoloških i strukturnih karakteristika dendrita bakra dobijenih potenciostatskim i galvanostatskim režimima elektrolize. Trodimenzionalni (3D) dendriti nalik stablu bora izgrađeni od stabla i grana koje nalikuju klipovima kukuruza, sa oštrim vrhovima, su bili dobijeni potenciostatskim režimom elektrolize sa svim analiziranim količinama propuštenog naelektrisanja. Na drugoj strani, sa povećanjem količine propuštenog naelektrisanja oblik 3D dendrita dobijenih galvanostatskim režimom elektrolize se menjao od onih sa oštrim vrhovima i stalka i grana do onih čiji vrhovi su se završavali globulama. Poređenjem sa talozima bakra dobijenim na prenapetostima koje su pripadale različitim tipovima kontrole procesa elektrohemijskog taloženja, zaključeno je da prenapetost na kraju propuštene količine naelektrisanja igra presudnu ulogu u krajnjem obliku galvanostatski proizvedenih Cu dendrita. Bez obzira na oblik Cu dendrita, kristaliti bakra su bili slučajno orijentisani u oba tipa dendrita.
PB  - Belgrade : Serbian Society of Corrosion and Materials Protection UISKOZAM
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
T1  - Influence of regime of electrolysis on morphology and structure of copper dendrites
T1  - Uticaj režima elektrolize na morfologiju i strukturu dendrita bakra
SP  - 145
UR  - https://hdl.handle.net/21.15107/rcub_cer_4874
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Maksimović, Vesna M. and Baščarević, Zvezdana and Živković, Predrag M. and Pavlović, Miomir G.",
year = "2021",
abstract = "Comparative analysis of morphological and structural features of copper dendrites obtained by potentiostatic and galvanostatic regimes of electrolysis was made. The 3D (three dimensional) pine-like dendrites composed from stalk and corncob-like forms as branches, with the sharp tips of both stalk and branches, were obtained by the potentiostatic regime of electrolysis with all analyzed amounts of passed electricity. On the other hand, with increasing the amount of the passed electricity the shape of 3D pine-line dendrites obtained by the galvanostatic regime of electrolysis changed than those with the sharp tips of stalk and branches to those which the tips finished globules. Comparing with Cu deposits obtained at overpotentials which belonged to different types of electrodeposition control, it is concluded that overpotential at the end of passed amount of the electricity plays crucial role in the final shape of galvanostatically produced Cu dendrites. Irrespective of the shape of Cu dendrites, crystallites of copper were random oriented in the both types of dendrites., Napravljena je uporedna analiza morfoloških i strukturnih karakteristika dendrita bakra dobijenih potenciostatskim i galvanostatskim režimima elektrolize. Trodimenzionalni (3D) dendriti nalik stablu bora izgrađeni od stabla i grana koje nalikuju klipovima kukuruza, sa oštrim vrhovima, su bili dobijeni potenciostatskim režimom elektrolize sa svim analiziranim količinama propuštenog naelektrisanja. Na drugoj strani, sa povećanjem količine propuštenog naelektrisanja oblik 3D dendrita dobijenih galvanostatskim režimom elektrolize se menjao od onih sa oštrim vrhovima i stalka i grana do onih čiji vrhovi su se završavali globulama. Poređenjem sa talozima bakra dobijenim na prenapetostima koje su pripadale različitim tipovima kontrole procesa elektrohemijskog taloženja, zaključeno je da prenapetost na kraju propuštene količine naelektrisanja igra presudnu ulogu u krajnjem obliku galvanostatski proizvedenih Cu dendrita. Bez obzira na oblik Cu dendrita, kristaliti bakra su bili slučajno orijentisani u oba tipa dendrita.",
publisher = "Belgrade : Serbian Society of Corrosion and Materials Protection UISKOZAM",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija",
title = "Influence of regime of electrolysis on morphology and structure of copper dendrites, Uticaj režima elektrolize na morfologiju i strukturu dendrita bakra",
pages = "145",
url = "https://hdl.handle.net/21.15107/rcub_cer_4874"
}
Nikolić, N. D., Maksimović, V. M., Baščarević, Z., Živković, P. M.,& Pavlović, M. G.. (2021). Influence of regime of electrolysis on morphology and structure of copper dendrites. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
Belgrade : Serbian Society of Corrosion and Materials Protection UISKOZAM., 145.
https://hdl.handle.net/21.15107/rcub_cer_4874
Nikolić ND, Maksimović VM, Baščarević Z, Živković PM, Pavlović MG. Influence of regime of electrolysis on morphology and structure of copper dendrites. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija. 2021;:145.
https://hdl.handle.net/21.15107/rcub_cer_4874 .
Nikolić, Nebojša D., Maksimović, Vesna M., Baščarević, Zvezdana, Živković, Predrag M., Pavlović, Miomir G., "Influence of regime of electrolysis on morphology and structure of copper dendrites" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija (2021):145,
https://hdl.handle.net/21.15107/rcub_cer_4874 .

Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders

Maksimović, Vesna M.; Kusigerski, Vladan B.; Stoiljković, Milovan; Maletaškić, Jelena; Nikolić, Nebojša D.

(Elsevier, 2020)

TY  - JOUR
AU  - Maksimović, Vesna M.
AU  - Kusigerski, Vladan B.
AU  - Stoiljković, Milovan
AU  - Maletaškić, Jelena
AU  - Nikolić, Nebojša D.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3575
AB  - Nickel−cobalt (Ni−Co) alloy powders were produced galvanostatically by using sulphate electrolytes with
various ratios of Ni2+/Co2+ (mole ratios). The morphology, phase structure, chemical composition and magnetic
properties were examined by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic emission
spectrometer (AES), and SQUID-based magnetometer, respectively. Morphology of the particles changed from
cauliflower-like and dendritic to coral-like and spongy-like ones with increasing Ni2+/Co2+ ratio from 0.25 to 4.0. XRD
analysis of the Ni−Co powders revealed that the decrease of Ni2+/Co2+ ratios (the increase of Co content) caused a
change of structure from face centered cubic (FCC) obtained for the ratios of 4.0, 1.5 and 0.67 to a mixture of FCC and
hexagonal closed-packed (HCP) phases for the ratio of 0.25. The increasing content of nickel led to change of
mechanism of electrolysis from irregular (up to ~40 wt.% Ni in the electrolytes) to close to equilibrium (between
~40 and 60 wt.% Ni in the electrolytes) and anomalous co-deposition (over 60 wt.% Ni in the electrolytes) type. All of
the obtained Ni−Co alloy samples behaved as soft magnetic materials while their magnetic parameters showed
immediate composition dependence since both coercivity and saturation magnetization almost linearly increased with
increase of the Co content.
PB  - Elsevier
T2  - Transactions of Nonferrows Metals Society of China
T1  - Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders
VL  - 30
IS  - 4
SP  - 1046
EP  - 1057
DO  - 10.1016/S1003-6326(20)65276-1
ER  - 
@article{
author = "Maksimović, Vesna M. and Kusigerski, Vladan B. and Stoiljković, Milovan and Maletaškić, Jelena and Nikolić, Nebojša D.",
year = "2020",
abstract = "Nickel−cobalt (Ni−Co) alloy powders were produced galvanostatically by using sulphate electrolytes with
various ratios of Ni2+/Co2+ (mole ratios). The morphology, phase structure, chemical composition and magnetic
properties were examined by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic emission
spectrometer (AES), and SQUID-based magnetometer, respectively. Morphology of the particles changed from
cauliflower-like and dendritic to coral-like and spongy-like ones with increasing Ni2+/Co2+ ratio from 0.25 to 4.0. XRD
analysis of the Ni−Co powders revealed that the decrease of Ni2+/Co2+ ratios (the increase of Co content) caused a
change of structure from face centered cubic (FCC) obtained for the ratios of 4.0, 1.5 and 0.67 to a mixture of FCC and
hexagonal closed-packed (HCP) phases for the ratio of 0.25. The increasing content of nickel led to change of
mechanism of electrolysis from irregular (up to ~40 wt.% Ni in the electrolytes) to close to equilibrium (between
~40 and 60 wt.% Ni in the electrolytes) and anomalous co-deposition (over 60 wt.% Ni in the electrolytes) type. All of
the obtained Ni−Co alloy samples behaved as soft magnetic materials while their magnetic parameters showed
immediate composition dependence since both coercivity and saturation magnetization almost linearly increased with
increase of the Co content.",
publisher = "Elsevier",
journal = "Transactions of Nonferrows Metals Society of China",
title = "Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders",
volume = "30",
number = "4",
pages = "1046-1057",
doi = "10.1016/S1003-6326(20)65276-1"
}
Maksimović, V. M., Kusigerski, V. B., Stoiljković, M., Maletaškić, J.,& Nikolić, N. D.. (2020). Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders. in Transactions of Nonferrows Metals Society of China
Elsevier., 30(4), 1046-1057.
https://doi.org/10.1016/S1003-6326(20)65276-1
Maksimović VM, Kusigerski VB, Stoiljković M, Maletaškić J, Nikolić ND. Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders. in Transactions of Nonferrows Metals Society of China. 2020;30(4):1046-1057.
doi:10.1016/S1003-6326(20)65276-1 .
Maksimović, Vesna M., Kusigerski, Vladan B., Stoiljković, Milovan, Maletaškić, Jelena, Nikolić, Nebojša D., "Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders" in Transactions of Nonferrows Metals Society of China, 30, no. 4 (2020):1046-1057,
https://doi.org/10.1016/S1003-6326(20)65276-1 . .
3
3

Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders

Avramović, Ljiljana; Maksimović, Vesna M.; Baščarević, Zvezdana; Ignjatović, Nenad; Bugarin, Mile; Marković, Radmila; Nikolić, Nebojša D.

(MDPI, 2019)

TY  - JOUR
AU  - Avramović, Ljiljana
AU  - Maksimović, Vesna M.
AU  - Baščarević, Zvezdana
AU  - Ignjatović, Nenad
AU  - Bugarin, Mile
AU  - Marković, Radmila
AU  - Nikolić, Nebojša D.
PY  - 2019
UR  - https://www.mdpi.com/2075-4701/9/1/56
UR  - http://dais.sanu.ac.rs/123456789/4770
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2608
AB  - Three different forms of Cu powder particles obtained by either galvanostatic electrolysis or a non-electrolytic method were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD) and particle size distribution (PSD). Electrolytic procedures were performed under different hydrogen evolution conditions, leading to the formation of either 3D branched dendrites or disperse cauliflower-like particles. The third type of particles were compact agglomerates of the Cu grains, whose structural characteristics indicated that they were formed by a non-electrolytic method. Unlike the sharp tips that characterize the usual form of Cu dendrites, the ends of both the trunk and branches were globules in the formed dendrites, indicating that a novel type of Cu dendrites was formed in this investigation. Although the macro structures of the particles were extremely varied, they had very similar micro structures because they were constructed by spherical grains. The Cu crystallites were randomly oriented in the dendrites and compact agglomerates of the Cu grains, while the disperse cauliflower-like particles showed (220) and (311) preferred orientation. This indicates that the applied current density affects not only the morphology of the particles, but also their crystal structure. The best performance, defined by the largest specific surface area and the smallest particle size, was by the galvanostatically produced powder consisting of disperse cauliflower-like particles.
PB  - MDPI
T2  - Metals
T1  - Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders
VL  - 9
IS  - 1
SP  - 56
DO  - 10.3390/met9010056
ER  - 
@article{
author = "Avramović, Ljiljana and Maksimović, Vesna M. and Baščarević, Zvezdana and Ignjatović, Nenad and Bugarin, Mile and Marković, Radmila and Nikolić, Nebojša D.",
year = "2019",
abstract = "Three different forms of Cu powder particles obtained by either galvanostatic electrolysis or a non-electrolytic method were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD) and particle size distribution (PSD). Electrolytic procedures were performed under different hydrogen evolution conditions, leading to the formation of either 3D branched dendrites or disperse cauliflower-like particles. The third type of particles were compact agglomerates of the Cu grains, whose structural characteristics indicated that they were formed by a non-electrolytic method. Unlike the sharp tips that characterize the usual form of Cu dendrites, the ends of both the trunk and branches were globules in the formed dendrites, indicating that a novel type of Cu dendrites was formed in this investigation. Although the macro structures of the particles were extremely varied, they had very similar micro structures because they were constructed by spherical grains. The Cu crystallites were randomly oriented in the dendrites and compact agglomerates of the Cu grains, while the disperse cauliflower-like particles showed (220) and (311) preferred orientation. This indicates that the applied current density affects not only the morphology of the particles, but also their crystal structure. The best performance, defined by the largest specific surface area and the smallest particle size, was by the galvanostatically produced powder consisting of disperse cauliflower-like particles.",
publisher = "MDPI",
journal = "Metals",
title = "Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders",
volume = "9",
number = "1",
pages = "56",
doi = "10.3390/met9010056"
}
Avramović, L., Maksimović, V. M., Baščarević, Z., Ignjatović, N., Bugarin, M., Marković, R.,& Nikolić, N. D.. (2019). Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders. in Metals
MDPI., 9(1), 56.
https://doi.org/10.3390/met9010056
Avramović L, Maksimović VM, Baščarević Z, Ignjatović N, Bugarin M, Marković R, Nikolić ND. Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders. in Metals. 2019;9(1):56.
doi:10.3390/met9010056 .
Avramović, Ljiljana, Maksimović, Vesna M., Baščarević, Zvezdana, Ignjatović, Nenad, Bugarin, Mile, Marković, Radmila, Nikolić, Nebojša D., "Influence of the Shape of Copper Powder Particles on the Crystal Structure and Some Decisive Characteristics of the Metal Powders" in Metals, 9, no. 1 (2019):56,
https://doi.org/10.3390/met9010056 . .
25
15
28

Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death

Čairović, Aleksandra D.; Stanimirović, Dragan D.; Krajnović, Tamara T.; Dojčinović, Biljana; Maksimović, Vesna M.; Cvijović-Alagić, Ivana Lj.

(Serbian Biological Society, 2019)

TY  - JOUR
AU  - Čairović, Aleksandra D.
AU  - Stanimirović, Dragan D.
AU  - Krajnović, Tamara T.
AU  - Dojčinović, Biljana
AU  - Maksimović, Vesna M.
AU  - Cvijović-Alagić, Ivana Lj.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2993
AB  - The biological quality and chemical composition of alloys used in dental practice change during heat treatment.
Often the residues of the previous cast are not disposed of but are reused and recycled until consumed. Thus, manufactured dental restorations have modified biological quality and chemical composition, and compromised biocompatibility. The aim of this study was to investigate the influence of repeated casting on the cytotoxicity of the silver-palladium (Ag-Pd) alloy. Our results showed that repeated casting of the Ag-Pd dental alloy affected its biocompatibility by promoting toxicity against transformed fibroblasts in a contact-independent manner. A strong decrease in cell proliferation, induction of senescence and massive cell death were observed in cultures exposed only to a medium previously incubated with dental alloy samples. The obtained data indicated that toxicity mediated by the accumulation of the Ag, Pd, Cu and Zn cations released from the Ag-Pd material was enhanced by recasting. The induction of cell senescence and subsequent apoptotic
and necrotic death were accompanied by amplified intracellular production of reactive oxygen and nitrogen species, suggesting their involvement in the cell destruction process. Therefore, compromised biocompatibility after recasting with the Ag-Pd alloy can be the cause of serious local cell destruction, as observed in clinical practice.
PB  - Serbian Biological Society
T2  - Archives of Biological Sciences
T1  - Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death
VL  - 71
IS  - 2
SP  - 347
EP  - 356
DO  - 10.2298/ABS190305017C
ER  - 
@article{
author = "Čairović, Aleksandra D. and Stanimirović, Dragan D. and Krajnović, Tamara T. and Dojčinović, Biljana and Maksimović, Vesna M. and Cvijović-Alagić, Ivana Lj.",
year = "2019",
abstract = "The biological quality and chemical composition of alloys used in dental practice change during heat treatment.
Often the residues of the previous cast are not disposed of but are reused and recycled until consumed. Thus, manufactured dental restorations have modified biological quality and chemical composition, and compromised biocompatibility. The aim of this study was to investigate the influence of repeated casting on the cytotoxicity of the silver-palladium (Ag-Pd) alloy. Our results showed that repeated casting of the Ag-Pd dental alloy affected its biocompatibility by promoting toxicity against transformed fibroblasts in a contact-independent manner. A strong decrease in cell proliferation, induction of senescence and massive cell death were observed in cultures exposed only to a medium previously incubated with dental alloy samples. The obtained data indicated that toxicity mediated by the accumulation of the Ag, Pd, Cu and Zn cations released from the Ag-Pd material was enhanced by recasting. The induction of cell senescence and subsequent apoptotic
and necrotic death were accompanied by amplified intracellular production of reactive oxygen and nitrogen species, suggesting their involvement in the cell destruction process. Therefore, compromised biocompatibility after recasting with the Ag-Pd alloy can be the cause of serious local cell destruction, as observed in clinical practice.",
publisher = "Serbian Biological Society",
journal = "Archives of Biological Sciences",
title = "Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death",
volume = "71",
number = "2",
pages = "347-356",
doi = "10.2298/ABS190305017C"
}
Čairović, A. D., Stanimirović, D. D., Krajnović, T. T., Dojčinović, B., Maksimović, V. M.,& Cvijović-Alagić, I. Lj.. (2019). Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death. in Archives of Biological Sciences
Serbian Biological Society., 71(2), 347-356.
https://doi.org/10.2298/ABS190305017C
Čairović AD, Stanimirović DD, Krajnović TT, Dojčinović B, Maksimović VM, Cvijović-Alagić IL. Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death. in Archives of Biological Sciences. 2019;71(2):347-356.
doi:10.2298/ABS190305017C .
Čairović, Aleksandra D., Stanimirović, Dragan D., Krajnović, Tamara T., Dojčinović, Biljana, Maksimović, Vesna M., Cvijović-Alagić, Ivana Lj., "Recasting as a booster of Ag-Pd alloy cytotoxicity: induction of cell senescence prior to mass cell death" in Archives of Biological Sciences, 71, no. 2 (2019):347-356,
https://doi.org/10.2298/ABS190305017C . .

Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions

Nikolić, Nebojša D.; Avramović, Ljiljana; Ivanović, Evica; Maksimović, Vesna M.; Baščarević, Zvezdana; Ignjatović, Nenad

(Elsevier, 2019)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Avramović, Ljiljana
AU  - Ivanović, Evica
AU  - Maksimović, Vesna M.
AU  - Baščarević, Zvezdana
AU  - Ignjatović, Nenad
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S100363261965034X
UR  - http://dais.sanu.ac.rs/123456789/6371
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3048
AB  - Production of copper powders by the potentiostatic electrolysis under different hydrogen evolution conditions was investigated. Copper powders were characterized by the scanning electron microscope (SEM), X-ray diffraction (XRD), particle size distribution (PSD), and by the determination of the specific surface area (SSA) of the formed powders. Depending on quantity of hydrogen generated during electrolysis, the two types of particles were formed: dendrites and cauliflower-like particles. The dendrites were formed without, while cauliflower-like particles with the quantity of evolved hydrogen enough to achieve strong effect on hydrodynamic conditions in the near-electrode layer. Although macro structure of the particles was very different, they showed similar micro structure. Namely, both types of the particles consisted of small agglomerates of approximately spherical Cu grains at the micro level. The existence of the spherical morphology was just responsible for random orientation of Cu crystallites in both types of particles. The SSA of cauliflower-like particles was more than two times larger than that of the dendrites, while their size was considerably smaller than that of the dendritic particles. In this way, the useful benefit of Cu powder formation in the conditions of vigorous hydrogen evolution is shown.
PB  - Elsevier
T2  - Transactions of Nonferrous Metals Society of China
T1  - Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions
VL  - 29
IS  - 6
SP  - 1275
EP  - 1284
DO  - 10.1016/S1003-6326(19)65034-X
ER  - 
@article{
author = "Nikolić, Nebojša D. and Avramović, Ljiljana and Ivanović, Evica and Maksimović, Vesna M. and Baščarević, Zvezdana and Ignjatović, Nenad",
year = "2019",
abstract = "Production of copper powders by the potentiostatic electrolysis under different hydrogen evolution conditions was investigated. Copper powders were characterized by the scanning electron microscope (SEM), X-ray diffraction (XRD), particle size distribution (PSD), and by the determination of the specific surface area (SSA) of the formed powders. Depending on quantity of hydrogen generated during electrolysis, the two types of particles were formed: dendrites and cauliflower-like particles. The dendrites were formed without, while cauliflower-like particles with the quantity of evolved hydrogen enough to achieve strong effect on hydrodynamic conditions in the near-electrode layer. Although macro structure of the particles was very different, they showed similar micro structure. Namely, both types of the particles consisted of small agglomerates of approximately spherical Cu grains at the micro level. The existence of the spherical morphology was just responsible for random orientation of Cu crystallites in both types of particles. The SSA of cauliflower-like particles was more than two times larger than that of the dendrites, while their size was considerably smaller than that of the dendritic particles. In this way, the useful benefit of Cu powder formation in the conditions of vigorous hydrogen evolution is shown.",
publisher = "Elsevier",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions",
volume = "29",
number = "6",
pages = "1275-1284",
doi = "10.1016/S1003-6326(19)65034-X"
}
Nikolić, N. D., Avramović, L., Ivanović, E., Maksimović, V. M., Baščarević, Z.,& Ignjatović, N.. (2019). Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions. in Transactions of Nonferrous Metals Society of China
Elsevier., 29(6), 1275-1284.
https://doi.org/10.1016/S1003-6326(19)65034-X
Nikolić ND, Avramović L, Ivanović E, Maksimović VM, Baščarević Z, Ignjatović N. Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions. in Transactions of Nonferrous Metals Society of China. 2019;29(6):1275-1284.
doi:10.1016/S1003-6326(19)65034-X .
Nikolić, Nebojša D., Avramović, Ljiljana, Ivanović, Evica, Maksimović, Vesna M., Baščarević, Zvezdana, Ignjatović, Nenad, "Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions" in Transactions of Nonferrous Metals Society of China, 29, no. 6 (2019):1275-1284,
https://doi.org/10.1016/S1003-6326(19)65034-X . .
17
15
20

Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions

Nikolić, Nebojša D.; Avramović, Ljiljana; Ivanović, Evica; Maksimović, Vesna M.; Baščarević, Zvezdana; Ignjatović, Nenad

(Elsevier, 2019)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Avramović, Ljiljana
AU  - Ivanović, Evica
AU  - Maksimović, Vesna M.
AU  - Baščarević, Zvezdana
AU  - Ignjatović, Nenad
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S100363261965034X
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3049
AB  - Production of copper powders by the potentiostatic electrolysis under different hydrogen evolution conditions was investigated. Copper powders were characterized by the scanning electron microscope (SEM), X-ray diffraction (XRD), particle size distribution (PSD), and by the determination of the specific surface area (SSA) of the formed powders. Depending on quantity of hydrogen generated during electrolysis, the two types of particles were formed: dendrites and cauliflower-like particles. The dendrites were formed without, while cauliflower-like particles with the quantity of evolved hydrogen enough to achieve strong effect on hydrodynamic conditions in the near-electrode layer. Although macro structure of the particles was very different, they showed similar micro structure. Namely, both types of the particles consisted of small agglomerates of approximately spherical Cu grains at the micro level. The existence of the spherical morphology was just responsible for random orientation of Cu crystallites in both types of particles. The SSA of cauliflower-like particles was more than two times larger than that of the dendrites, while their size was considerably smaller than that of the dendritic particles. In this way, the useful benefit of Cu powder formation in the conditions of vigorous hydrogen evolution is shown.
PB  - Elsevier
T2  - Transactions of Nonferrous Metals Society of China
T1  - Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions
VL  - 29
IS  - 6
SP  - 1275
EP  - 1284
DO  - 10.1016/S1003-6326(19)65034-X
ER  - 
@article{
author = "Nikolić, Nebojša D. and Avramović, Ljiljana and Ivanović, Evica and Maksimović, Vesna M. and Baščarević, Zvezdana and Ignjatović, Nenad",
year = "2019",
abstract = "Production of copper powders by the potentiostatic electrolysis under different hydrogen evolution conditions was investigated. Copper powders were characterized by the scanning electron microscope (SEM), X-ray diffraction (XRD), particle size distribution (PSD), and by the determination of the specific surface area (SSA) of the formed powders. Depending on quantity of hydrogen generated during electrolysis, the two types of particles were formed: dendrites and cauliflower-like particles. The dendrites were formed without, while cauliflower-like particles with the quantity of evolved hydrogen enough to achieve strong effect on hydrodynamic conditions in the near-electrode layer. Although macro structure of the particles was very different, they showed similar micro structure. Namely, both types of the particles consisted of small agglomerates of approximately spherical Cu grains at the micro level. The existence of the spherical morphology was just responsible for random orientation of Cu crystallites in both types of particles. The SSA of cauliflower-like particles was more than two times larger than that of the dendrites, while their size was considerably smaller than that of the dendritic particles. In this way, the useful benefit of Cu powder formation in the conditions of vigorous hydrogen evolution is shown.",
publisher = "Elsevier",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions",
volume = "29",
number = "6",
pages = "1275-1284",
doi = "10.1016/S1003-6326(19)65034-X"
}
Nikolić, N. D., Avramović, L., Ivanović, E., Maksimović, V. M., Baščarević, Z.,& Ignjatović, N.. (2019). Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions. in Transactions of Nonferrous Metals Society of China
Elsevier., 29(6), 1275-1284.
https://doi.org/10.1016/S1003-6326(19)65034-X
Nikolić ND, Avramović L, Ivanović E, Maksimović VM, Baščarević Z, Ignjatović N. Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions. in Transactions of Nonferrous Metals Society of China. 2019;29(6):1275-1284.
doi:10.1016/S1003-6326(19)65034-X .
Nikolić, Nebojša D., Avramović, Ljiljana, Ivanović, Evica, Maksimović, Vesna M., Baščarević, Zvezdana, Ignjatović, Nenad, "Comparative morphological and crystallographic analysis of copper powders obtained under different electrolysis conditions" in Transactions of Nonferrous Metals Society of China, 29, no. 6 (2019):1275-1284,
https://doi.org/10.1016/S1003-6326(19)65034-X . .
17
15
19

Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases

Nikolić, Nebojša D.; Maksimović, Vesna M.; Branković, Goran; Živković, Predrag M.; Pavlović, Miomir

(Belgrade, Serbia : Engineering Society for Corrosion, 2018)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna M.
AU  - Branković, Goran
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2276
AB  - Lead and nickel powder particles were produced by the processes of electrolysis and characterized by scanning electron microscope (SEM). The X-ray diffraction (XRD) analysis of the produced particles was done. Morphologies of Pb and Ni particles were correlated with their crystal structure at the semi quantitative level by determination of 'Texture Coefficients' (TC) and 'Relative Texture Coefficient' (RTC). The two dimensional (2D) dendritic particles of lead of different degree of ramification were obtained by the potentiostatic regime of electrolysis from the nitrate, acetate and hydroxide electrolyte. The spongy-like particles of nickel constructed from holes formed of the detached hydrogen bubbles and surrounded by cauliflower-like agglomerates of approximately spherical grains (the honeycomb-like structure) were obtained by the galvanostatic regime of electrolysis from the chloride electrolyte. Although crystallites were dominantly oriented in the (111) plane in both Pb and Ni particles, analysis of the XRD data showed different preferred orientation of the formed particles. All types of Pb dendritic particles showed the strong (111) preferred orientation, while crystallites of Ni in the spongy-like particles were almost random oriented. The obtained results were discussed following Winand's classification of metals on the normal, intermediate and inert metals based on their values of the exchange current density, melting point and overpotential for hydrogen evolution reaction.
AB  - Čestice praha olova i nikla proizvedene su procesima elektrolize i okarakterisane skenirajućim elektronskim mikroskopom. Urađena je i rendgeno-strukturna analiza dobijenih čestica. Morfologije čestica olova i nikla su korelisane sa njihovom kristalnom strukturom na polukvantitativnom nivou određivanjem 'Teksturnog koeficijenta' (TC) i 'Relativnog teksturnog koeficijenta' (RTC). Dvodimen- zionalne (2D) dendritične čestice olova različitog stepena razgranatosti dobijene su potenciostatskim režimom elektrolize iz nitratnog, acetatnog i hidroksilnog elektrolita. Čestice nikla sunđerastog oblika u čijoj strukturi se uočavaju rupe formirane odvajanjem mehurova vodonika okružene karfiolastim aglomeratima približno sferičnih zrna (struktura pčelinjeg saća) dobijene su galvanostatskim režimom elektrolize iz hloridnog elektrolita. Premda su kristaliti dominantno orijentisani u (111) ravni i u česticama praha olova i nikla, analiza rendgenograma je pokazala njihove različite dominantne orijentacije. Svi tipovi olovnih dendritičnih čestica su pokazali strogu (111) dominantnu orijentaciju, dok kristaliti nikla u sunđerastim česticama su bili skoro slučajno orijentisani. Dobijeni rezultati su diskuto- vani sledeći Vinjadovu klasifikaciju metala na normalne, intermedijalne i inertne, zasnovane na njihovim vrednostima gustine struje izmene, tačke topljenja i prenapetosti za reakciju izdvajanja vodonika.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases
T1  - Korelacija izmedju orijentacije kristala i morfologije elektrolitički proizvedenih praškastih čestica - analiza graničnih slučajeva
VL  - 59
IS  - 2
SP  - 256
EP  - 264
DO  - 10.5937/ZasMat1802256N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna M. and Branković, Goran and Živković, Predrag M. and Pavlović, Miomir",
year = "2018",
abstract = "Lead and nickel powder particles were produced by the processes of electrolysis and characterized by scanning electron microscope (SEM). The X-ray diffraction (XRD) analysis of the produced particles was done. Morphologies of Pb and Ni particles were correlated with their crystal structure at the semi quantitative level by determination of 'Texture Coefficients' (TC) and 'Relative Texture Coefficient' (RTC). The two dimensional (2D) dendritic particles of lead of different degree of ramification were obtained by the potentiostatic regime of electrolysis from the nitrate, acetate and hydroxide electrolyte. The spongy-like particles of nickel constructed from holes formed of the detached hydrogen bubbles and surrounded by cauliflower-like agglomerates of approximately spherical grains (the honeycomb-like structure) were obtained by the galvanostatic regime of electrolysis from the chloride electrolyte. Although crystallites were dominantly oriented in the (111) plane in both Pb and Ni particles, analysis of the XRD data showed different preferred orientation of the formed particles. All types of Pb dendritic particles showed the strong (111) preferred orientation, while crystallites of Ni in the spongy-like particles were almost random oriented. The obtained results were discussed following Winand's classification of metals on the normal, intermediate and inert metals based on their values of the exchange current density, melting point and overpotential for hydrogen evolution reaction., Čestice praha olova i nikla proizvedene su procesima elektrolize i okarakterisane skenirajućim elektronskim mikroskopom. Urađena je i rendgeno-strukturna analiza dobijenih čestica. Morfologije čestica olova i nikla su korelisane sa njihovom kristalnom strukturom na polukvantitativnom nivou određivanjem 'Teksturnog koeficijenta' (TC) i 'Relativnog teksturnog koeficijenta' (RTC). Dvodimen- zionalne (2D) dendritične čestice olova različitog stepena razgranatosti dobijene su potenciostatskim režimom elektrolize iz nitratnog, acetatnog i hidroksilnog elektrolita. Čestice nikla sunđerastog oblika u čijoj strukturi se uočavaju rupe formirane odvajanjem mehurova vodonika okružene karfiolastim aglomeratima približno sferičnih zrna (struktura pčelinjeg saća) dobijene su galvanostatskim režimom elektrolize iz hloridnog elektrolita. Premda su kristaliti dominantno orijentisani u (111) ravni i u česticama praha olova i nikla, analiza rendgenograma je pokazala njihove različite dominantne orijentacije. Svi tipovi olovnih dendritičnih čestica su pokazali strogu (111) dominantnu orijentaciju, dok kristaliti nikla u sunđerastim česticama su bili skoro slučajno orijentisani. Dobijeni rezultati su diskuto- vani sledeći Vinjadovu klasifikaciju metala na normalne, intermedijalne i inertne, zasnovane na njihovim vrednostima gustine struje izmene, tačke topljenja i prenapetosti za reakciju izdvajanja vodonika.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases, Korelacija izmedju orijentacije kristala i morfologije elektrolitički proizvedenih praškastih čestica - analiza graničnih slučajeva",
volume = "59",
number = "2",
pages = "256-264",
doi = "10.5937/ZasMat1802256N"
}
Nikolić, N. D., Maksimović, V. M., Branković, G., Živković, P. M.,& Pavlović, M.. (2018). Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 59(2), 256-264.
https://doi.org/10.5937/ZasMat1802256N
Nikolić ND, Maksimović VM, Branković G, Živković PM, Pavlović M. Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases. in Zaštita materijala. 2018;59(2):256-264.
doi:10.5937/ZasMat1802256N .
Nikolić, Nebojša D., Maksimović, Vesna M., Branković, Goran, Živković, Predrag M., Pavlović, Miomir, "Correlation between crystal orientation and morphology of electrolytically produced powder particles: Analysis of the limiting cases" in Zaštita materijala, 59, no. 2 (2018):256-264,
https://doi.org/10.5937/ZasMat1802256N . .
4

Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures

Avramović, Ljiljana; Ivanović, Evica; Maksimović, Vesna M.; Pavlović, Miroslav M.; Vuković, Marina; Stevanović, Jasmina; Nikolić, Nebojša D.

(Elsevier, 2018)

TY  - JOUR
AU  - Avramović, Ljiljana
AU  - Ivanović, Evica
AU  - Maksimović, Vesna M.
AU  - Pavlović, Miroslav M.
AU  - Vuković, Marina
AU  - Stevanović, Jasmina
AU  - Nikolić, Nebojša D.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2372
AB  - Silver dendritic nanonstructures obtained by the potentiostatic electrolysis from different electrolytes at different overpotentials were characterized by the scanning electron microscopy (SEM) technique and X-ray diffraction analysis of the produced particles. The needle-like and fern-like dendrites were formed from the nitrate electrolyte at overpotentials inside and outside plateaus of the limiting diffusion current density, respectively. The three-dimensional pine-like dendrites constructed from approximately spherical grains were formed from the ammonium electrolyte at overpotentials both inside and outside plateaus of the limiting diffusion current density. The morphology of silver dendrites was correlated with their crystal structure at the semi quantiative level. The change of crystal orientation from the strong (111) preferred orientation for the needle-like dendrites to almost randomly orientied spherical grains in the pine-like dendrites obtained at the overpotential outside the plateau of the limiting diffusion current density was observed. This trend in change of crystal orientation and morphology of Ag nanostructures was accompanied by considerable increase of the specific surface area (SSA) of the produced powders. The average crystallite sizes were in the range of 38-50 nm, proving nanostructural character of the formed Ag particles.
PB  - Elsevier
T2  - Transactions of Nonferrous Metals Society of China
T1  - Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures
VL  - 28
IS  - 9
SP  - 1903
EP  - 1912
DO  - 10.1016/S1003-6326(18)64835-6
ER  - 
@article{
author = "Avramović, Ljiljana and Ivanović, Evica and Maksimović, Vesna M. and Pavlović, Miroslav M. and Vuković, Marina and Stevanović, Jasmina and Nikolić, Nebojša D.",
year = "2018",
abstract = "Silver dendritic nanonstructures obtained by the potentiostatic electrolysis from different electrolytes at different overpotentials were characterized by the scanning electron microscopy (SEM) technique and X-ray diffraction analysis of the produced particles. The needle-like and fern-like dendrites were formed from the nitrate electrolyte at overpotentials inside and outside plateaus of the limiting diffusion current density, respectively. The three-dimensional pine-like dendrites constructed from approximately spherical grains were formed from the ammonium electrolyte at overpotentials both inside and outside plateaus of the limiting diffusion current density. The morphology of silver dendrites was correlated with their crystal structure at the semi quantiative level. The change of crystal orientation from the strong (111) preferred orientation for the needle-like dendrites to almost randomly orientied spherical grains in the pine-like dendrites obtained at the overpotential outside the plateau of the limiting diffusion current density was observed. This trend in change of crystal orientation and morphology of Ag nanostructures was accompanied by considerable increase of the specific surface area (SSA) of the produced powders. The average crystallite sizes were in the range of 38-50 nm, proving nanostructural character of the formed Ag particles.",
publisher = "Elsevier",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures",
volume = "28",
number = "9",
pages = "1903-1912",
doi = "10.1016/S1003-6326(18)64835-6"
}
Avramović, L., Ivanović, E., Maksimović, V. M., Pavlović, M. M., Vuković, M., Stevanović, J.,& Nikolić, N. D.. (2018). Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures. in Transactions of Nonferrous Metals Society of China
Elsevier., 28(9), 1903-1912.
https://doi.org/10.1016/S1003-6326(18)64835-6
Avramović L, Ivanović E, Maksimović VM, Pavlović MM, Vuković M, Stevanović J, Nikolić ND. Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures. in Transactions of Nonferrous Metals Society of China. 2018;28(9):1903-1912.
doi:10.1016/S1003-6326(18)64835-6 .
Avramović, Ljiljana, Ivanović, Evica, Maksimović, Vesna M., Pavlović, Miroslav M., Vuković, Marina, Stevanović, Jasmina, Nikolić, Nebojša D., "Correlation between crystal structure and morphology of potentiostatically electrodeposited silver dendritic nanostructures" in Transactions of Nonferrous Metals Society of China, 28, no. 9 (2018):1903-1912,
https://doi.org/10.1016/S1003-6326(18)64835-6 . .
3
19
10
17

Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics

Nikolić, Nebojša D.; Avramović, Ljiljana; Maksimović, Vesna; Pavlović, Miroslav; Perać, Sanja; Stevanović, Jasmina; Bugarin, Mile

(Bulgaria, Sofia : Institute of Physical Chemistry, Bulgarian Academy of Science, 2017)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Avramović, Ljiljana
AU  - Maksimović, Vesna
AU  - Pavlović, Miroslav
AU  - Perać, Sanja
AU  - Stevanović, Jasmina
AU  - Bugarin, Mile
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6650
AB  - Silver powder particles of nanostructured characteristics were produced by the galvanostatic regime of electrolysis and compared with those obtained by chemical reduction with hydrazine. 
Morphology of all types of powder particles was examined by the technique of scanning electron 
microscopy (SEM), while crystallographic characteristics were examined by the X-ray diffraction 
(XRD) analysis of the obtained particles. Morphology of the electrochemically produced powder 
particles strongly depended on the type of used electrolyte. The irregular crystals and the needle-like dendrites were predominately formed from the nitrate (acid) electrolyte. On the other hand, the 
3D pine-like dendrites very similar to Cu dendrites [1] were formed by the electrodeposition from 
the ammonium (alcali) electrolyte. Simultaneously, the particles of spherical shape were formed by 
chemical reduction with hydrazine. The difference in morphology of electrochemically produced 
Ag powders can be explained by different rate of the electrochemical process by which they are 
formed. Namely, the ammonium electrolyte belongs to the group of the complex electrolyte and 
formation of this complex lowers the exchange current density for Ag causing a transfer of Ag from 
the group of the normal metals (metals with the high values of the exchange current density) to the 
group of the intermediate metals (metals with the medium values of the exchange current density). 
Irrespective of the way of preparation of Ag powder, Ag crystallites in all types of powder particles 
were predominantly oriented in the (111) plane. Formation of powder particles of the different shape with the strong (111) preferred orientation was discussed and explained by the consideration of the general characteristics of the growth of a crystal in the crystallization and 
electrocrystallization processes. Analogy between these two types of processes was made and discussed.
PB  - Bulgaria, Sofia : Institute of Physical Chemistry, Bulgarian Academy of Science
C3  - Programme and Book of Abstracts - 12th International Workshop on Electrodeposited Nanostructures (EDNANO - 12), March 16-18, Sofia, Bulgaria
T1  - Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics
SP  - 47
EP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_cer_6650
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Avramović, Ljiljana and Maksimović, Vesna and Pavlović, Miroslav and Perać, Sanja and Stevanović, Jasmina and Bugarin, Mile",
year = "2017",
abstract = "Silver powder particles of nanostructured characteristics were produced by the galvanostatic regime of electrolysis and compared with those obtained by chemical reduction with hydrazine. 
Morphology of all types of powder particles was examined by the technique of scanning electron 
microscopy (SEM), while crystallographic characteristics were examined by the X-ray diffraction 
(XRD) analysis of the obtained particles. Morphology of the electrochemically produced powder 
particles strongly depended on the type of used electrolyte. The irregular crystals and the needle-like dendrites were predominately formed from the nitrate (acid) electrolyte. On the other hand, the 
3D pine-like dendrites very similar to Cu dendrites [1] were formed by the electrodeposition from 
the ammonium (alcali) electrolyte. Simultaneously, the particles of spherical shape were formed by 
chemical reduction with hydrazine. The difference in morphology of electrochemically produced 
Ag powders can be explained by different rate of the electrochemical process by which they are 
formed. Namely, the ammonium electrolyte belongs to the group of the complex electrolyte and 
formation of this complex lowers the exchange current density for Ag causing a transfer of Ag from 
the group of the normal metals (metals with the high values of the exchange current density) to the 
group of the intermediate metals (metals with the medium values of the exchange current density). 
Irrespective of the way of preparation of Ag powder, Ag crystallites in all types of powder particles 
were predominantly oriented in the (111) plane. Formation of powder particles of the different shape with the strong (111) preferred orientation was discussed and explained by the consideration of the general characteristics of the growth of a crystal in the crystallization and 
electrocrystallization processes. Analogy between these two types of processes was made and discussed.",
publisher = "Bulgaria, Sofia : Institute of Physical Chemistry, Bulgarian Academy of Science",
journal = "Programme and Book of Abstracts - 12th International Workshop on Electrodeposited Nanostructures (EDNANO - 12), March 16-18, Sofia, Bulgaria",
title = "Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_cer_6650"
}
Nikolić, N. D., Avramović, L., Maksimović, V., Pavlović, M., Perać, S., Stevanović, J.,& Bugarin, M.. (2017). Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics. in Programme and Book of Abstracts - 12th International Workshop on Electrodeposited Nanostructures (EDNANO - 12), March 16-18, Sofia, Bulgaria
Bulgaria, Sofia : Institute of Physical Chemistry, Bulgarian Academy of Science., 47-47.
https://hdl.handle.net/21.15107/rcub_cer_6650
Nikolić ND, Avramović L, Maksimović V, Pavlović M, Perać S, Stevanović J, Bugarin M. Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics. in Programme and Book of Abstracts - 12th International Workshop on Electrodeposited Nanostructures (EDNANO - 12), March 16-18, Sofia, Bulgaria. 2017;:47-47.
https://hdl.handle.net/21.15107/rcub_cer_6650 .
Nikolić, Nebojša D., Avramović, Ljiljana, Maksimović, Vesna, Pavlović, Miroslav, Perać, Sanja, Stevanović, Jasmina, Bugarin, Mile, "Comparative analysis of chemically and electrochemically produced silver powders of nanostructural characteristics" in Programme and Book of Abstracts - 12th International Workshop on Electrodeposited Nanostructures (EDNANO - 12), March 16-18, Sofia, Bulgaria (2017):47-47,
https://hdl.handle.net/21.15107/rcub_cer_6650 .

Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis

Nikolić, Nebojša D.; Avramović, Ljiljana; Maksimović, Vesna; Pavlović, Miroslav; Vuković, Marina; Stevanović, Jasmina; Pavlović, Miomir

(Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (UISKOZAM) / Beograd, Srbija : Udruženje inženjera Srbije za koroziju i zaštitu materijala (UISKOZAM), 2017)

TY  - CONF
AU  - Nikolić, Nebojša D.
AU  - Avramović, Ljiljana
AU  - Maksimović, Vesna
AU  - Pavlović, Miroslav
AU  - Vuković, Marina
AU  - Stevanović, Jasmina
AU  - Pavlović, Miomir
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6644
AB  - Morphologies of silver powder particles obtained by chemical and electrochemical processes of 
synthesis were correlated with their crystal structure. Reduction with hydrazine was used for the 
synthesis of Ag powder by the chemical process. The different kinds of electrolytes (the nitrate and 
the ammonium ones), regimes of electrolysis (the galvanostatic and the potentiostatic ones) and 
overpotentials of the electrodeposition were used for production of Ag powders by electrolysis. 
Morphologies of synthesized particles strongly depended on the method of synthesis and conditions of electrolysis. Agglomerates of approximately spherical grains were formed with hydrazine as the reducing agent. In the dependence of conditions and regimes of electrolysis, various forms of dendritic particles, such as the needle-like, fern-like and pine-like dendrites, were formed. The preferred orientation of Ag particles changed from the strong (111) preferred orientation for the Ag particles obtained by the electrolysis from the nitrate electrolyte in the galvanostatic regime and at the overpotential outside plateau of the limiting diffusion current density to almost random oriented Ag crystallites for chemically synthesized particles and the pine-like particles obtained from the ammonium electrolyte by the galvanostatic and those produced by the potentiostatic regime outside plateau of the limiting diffusion current density.
AB  - Morfologije čestica praha srebra dobijene hemijskim i elektrohemijskim procesima sinteze su povezane sa njihovom kristalnom strukturom. Proces redukcije sa hidrazinom je bio korišćen za hemijsku sintezu praha srebra. Različite vrste elektrolita (nitratni i amonijačni), režimi elektrolize (galvanostatski i potenciostatski) i prenapetosti elektrohemijskog taloženja su korišćene za proizvodnju praha srebra elektrolizom. Aglomerati približno sferičnih zrna su bili formirani sa hidrazinom kao redukcionim sredstvom. U zavisnosti od uslova i režima elektrolize, različite forme dendritičnih čestica, kao što su igličasti dendriti i oni nalik paprati i boru, su bili formirani. Preferencijalna orijentacija čestica srebra se menjala od stroge (111) preferencijalne orijentacije 
za čestice dobijene elektrolizom iz nitratnog elektrolita galvanostatskim režimom i na prenapetosti 
izvan platoa granične difuzione gustine struje do skoro slučajno orijentisanih kristalita srebra kod 
hemijski sintetizovanih čestica i onih nalik boru dobijenih iz amonijačnog elektrolita galvanostatskim režimom i potenciostatskim režimom na prenapetosti izvan platoa granične difuzione gustine struje.
PB  - Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (UISKOZAM) / Beograd, Srbija : Udruženje inženjera Srbije za koroziju i zaštitu materijala (UISKOZAM)
C3  - Proceedings - XIX YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, September 12-15, Tara Mountain, Serbia
T1  - Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis
T1  - Uzajamna veza između orijentacije kristala i morfologije čestica praha srebra dobijenih različitim metoda sinteze i uslova elektrolize
SP  - 118
EP  - 119
UR  - https://hdl.handle.net/21.15107/rcub_cer_6644
ER  - 
@conference{
author = "Nikolić, Nebojša D. and Avramović, Ljiljana and Maksimović, Vesna and Pavlović, Miroslav and Vuković, Marina and Stevanović, Jasmina and Pavlović, Miomir",
year = "2017",
abstract = "Morphologies of silver powder particles obtained by chemical and electrochemical processes of 
synthesis were correlated with their crystal structure. Reduction with hydrazine was used for the 
synthesis of Ag powder by the chemical process. The different kinds of electrolytes (the nitrate and 
the ammonium ones), regimes of electrolysis (the galvanostatic and the potentiostatic ones) and 
overpotentials of the electrodeposition were used for production of Ag powders by electrolysis. 
Morphologies of synthesized particles strongly depended on the method of synthesis and conditions of electrolysis. Agglomerates of approximately spherical grains were formed with hydrazine as the reducing agent. In the dependence of conditions and regimes of electrolysis, various forms of dendritic particles, such as the needle-like, fern-like and pine-like dendrites, were formed. The preferred orientation of Ag particles changed from the strong (111) preferred orientation for the Ag particles obtained by the electrolysis from the nitrate electrolyte in the galvanostatic regime and at the overpotential outside plateau of the limiting diffusion current density to almost random oriented Ag crystallites for chemically synthesized particles and the pine-like particles obtained from the ammonium electrolyte by the galvanostatic and those produced by the potentiostatic regime outside plateau of the limiting diffusion current density., Morfologije čestica praha srebra dobijene hemijskim i elektrohemijskim procesima sinteze su povezane sa njihovom kristalnom strukturom. Proces redukcije sa hidrazinom je bio korišćen za hemijsku sintezu praha srebra. Različite vrste elektrolita (nitratni i amonijačni), režimi elektrolize (galvanostatski i potenciostatski) i prenapetosti elektrohemijskog taloženja su korišćene za proizvodnju praha srebra elektrolizom. Aglomerati približno sferičnih zrna su bili formirani sa hidrazinom kao redukcionim sredstvom. U zavisnosti od uslova i režima elektrolize, različite forme dendritičnih čestica, kao što su igličasti dendriti i oni nalik paprati i boru, su bili formirani. Preferencijalna orijentacija čestica srebra se menjala od stroge (111) preferencijalne orijentacije 
za čestice dobijene elektrolizom iz nitratnog elektrolita galvanostatskim režimom i na prenapetosti 
izvan platoa granične difuzione gustine struje do skoro slučajno orijentisanih kristalita srebra kod 
hemijski sintetizovanih čestica i onih nalik boru dobijenih iz amonijačnog elektrolita galvanostatskim režimom i potenciostatskim režimom na prenapetosti izvan platoa granične difuzione gustine struje.",
publisher = "Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (UISKOZAM) / Beograd, Srbija : Udruženje inženjera Srbije za koroziju i zaštitu materijala (UISKOZAM)",
journal = "Proceedings - XIX YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, September 12-15, Tara Mountain, Serbia",
title = "Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis, Uzajamna veza između orijentacije kristala i morfologije čestica praha srebra dobijenih različitim metoda sinteze i uslova elektrolize",
pages = "118-119",
url = "https://hdl.handle.net/21.15107/rcub_cer_6644"
}
Nikolić, N. D., Avramović, L., Maksimović, V., Pavlović, M., Vuković, M., Stevanović, J.,& Pavlović, M.. (2017). Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis. in Proceedings - XIX YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, September 12-15, Tara Mountain, Serbia
Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (UISKOZAM) / Beograd, Srbija : Udruženje inženjera Srbije za koroziju i zaštitu materijala (UISKOZAM)., 118-119.
https://hdl.handle.net/21.15107/rcub_cer_6644
Nikolić ND, Avramović L, Maksimović V, Pavlović M, Vuković M, Stevanović J, Pavlović M. Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis. in Proceedings - XIX YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, September 12-15, Tara Mountain, Serbia. 2017;:118-119.
https://hdl.handle.net/21.15107/rcub_cer_6644 .
Nikolić, Nebojša D., Avramović, Ljiljana, Maksimović, Vesna, Pavlović, Miroslav, Vuković, Marina, Stevanović, Jasmina, Pavlović, Miomir, "Correlation between crystal orientation and morphology of silver powder particles obtained by different methods of synthesis and conditions of electrolysis" in Proceedings - XIX YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, September 12-15, Tara Mountain, Serbia (2017):118-119,
https://hdl.handle.net/21.15107/rcub_cer_6644 .