Nastasović, Aleksandra

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Authority KeyName Variants
orcid::0000-0002-8589-6437
  • Nastasović, Aleksandra (132)
Projects
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection
Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes Synthesis and characterization of novel functional polymers and polymeric nanocomposites
Oxide-based environmentally-friendly porous materials for genotoxic substances removal Magnetic and radionuclide labeled nanostructured materials for medical applications
Nove metode i tehnike za separaciju i specijaciju hemijskih elemenata u tragovima, organskih supstanci i radionuklida i identifikaciju njihovih izvora Agrobiodiversity and land-use change in Serbia: an integrated biodiversity assessment of key functional groups of arthropods and plant pathogens
Research and verification of the multidisciplinary forensic methods in Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Studies of enzyme interactions with toxic and pharmacologically active molecules
Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications Directed synthesis, structure and properties of multifunctional materials
Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
Mezoporozni i nanomaterijali u katalitičkim i sorpcionim procesima 451-03-9/2021-14/200026
451-03-9/2021-14/200135 COST Action COSY (CA21101)
European Regional Development Fund Operational Programme Science and Education for Smart Growth [BG05M2OP001-1.001-0008] Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)
Development of embedded systems with connected services and digital technology Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing
Geopolymers - technology for converting the industrial waste into functional materials Ministry of Education, Science and Technological Development of the Republic of Serbia - 37201

Author's Bibliography

Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition

Tadić, Tamara; Marković, Bojana; Pavlović, Vladimir B.; Bulatović, Sandra; Nastasović, Aleksandra; Onjia, Antonije E.

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Pavlović, Vladimir B.
AU  - Bulatović, Sandra
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6757
AB  - Aniline, the main representative of aromatic amines, occurs in a large number
of industries, such as the production of textiles, plastics, medicines, pesticides,
rubber, and varnishes.1 Due to practicality and efficiency, a molecularly imprinted
polymers (MIPs) can be used as sorbents for removing aniline.2 In this study,
magnetic molecularly imprinted polymer was synthesized via suspension
copolymerization while characterization was performed by various methods in order
to obtain an efficient sorbent for the aniline removal from an aqueous solution.
Fourier transform infrared spectroscopy (FT-IR) confirmed characteristic vibrational
bands which suggested successful synthesis of MIP, nitrogen gas adsorption-desorption
measurements as well as mercury porosimetry have shown that the most
dominant pores were mesopores, while scanning electron microscopy with energy
dispersive X-ray spectroscopy (SEM-EDX) confirmed a 3D spherical porous
structure with all the expected elements.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
T1  - Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition
SP  - 178
EP  - 178
UR  - https://hdl.handle.net/21.15107/rcub_cer_6757
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Pavlović, Vladimir B. and Bulatović, Sandra and Nastasović, Aleksandra and Onjia, Antonije E.",
year = "2023",
abstract = "Aniline, the main representative of aromatic amines, occurs in a large number
of industries, such as the production of textiles, plastics, medicines, pesticides,
rubber, and varnishes.1 Due to practicality and efficiency, a molecularly imprinted
polymers (MIPs) can be used as sorbents for removing aniline.2 In this study,
magnetic molecularly imprinted polymer was synthesized via suspension
copolymerization while characterization was performed by various methods in order
to obtain an efficient sorbent for the aniline removal from an aqueous solution.
Fourier transform infrared spectroscopy (FT-IR) confirmed characteristic vibrational
bands which suggested successful synthesis of MIP, nitrogen gas adsorption-desorption
measurements as well as mercury porosimetry have shown that the most
dominant pores were mesopores, while scanning electron microscopy with energy
dispersive X-ray spectroscopy (SEM-EDX) confirmed a 3D spherical porous
structure with all the expected elements.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia",
title = "Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition",
pages = "178-178",
url = "https://hdl.handle.net/21.15107/rcub_cer_6757"
}
Tadić, T., Marković, B., Pavlović, V. B., Bulatović, S., Nastasović, A.,& Onjia, A. E.. (2023). Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 178-178.
https://hdl.handle.net/21.15107/rcub_cer_6757
Tadić T, Marković B, Pavlović VB, Bulatović S, Nastasović A, Onjia AE. Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia. 2023;:178-178.
https://hdl.handle.net/21.15107/rcub_cer_6757 .
Tadić, Tamara, Marković, Bojana, Pavlović, Vladimir B., Bulatović, Sandra, Nastasović, Aleksandra, Onjia, Antonije E., "Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for Aniline Recognition" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia (2023):178-178,
https://hdl.handle.net/21.15107/rcub_cer_6757 .

Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer

Bulatović, Sandra; Marković, Bojana; Tadić, Tamara; Nastasović, Aleksandra; Ilić, Mila; Randjelović, Danijela; Nedić, Natalija

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Tadić, Tamara
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Randjelović, Danijela
AU  - Nedić, Natalija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6692
AB  - Macroporous (glycidyl methacrylate) GMA-based composite was
synthesized via suspension polymerization in the presence of 2 wt. % magnetic
nanoparticles and functionalized with triethylenetetramine. Copper was immobilized
on composite by contacting modified copolymer with 0.1 M solution of CuCl2, at pH
5, and 25 ̊C. The obtained composite was characterized by mercury porosimetry,
Fourier transform infrared spectroscopy (FTIR) analysis and atomic force
microscopy (AFM). GMA-based composites, due to their properties (size, porosity,
etc.), and the presence of reactive epoxy group, have found a variety of applications
as sorbents, enzyme supports, in biomedical applications, for metal and organic
compounds sorption.1
The antimicrobial activity of the synthesized GMA/Cu copolymer against
Staphylococcus aureus, Escherichia coli, Candida albicans and Aspergillus niger as
representatives for Gram-positive bacteria, Gram-negative bacteria, yeast and fungi
were investigated in this study.2 The copolymer displayed good antimicrobial activity
against all analyzed microbes, which makes it a material that can be potentially used
for biomedical (antibacterial and antifungal) applications.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
T1  - Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer
SP  - 163
EP  - 163
UR  - https://hdl.handle.net/21.15107/rcub_cer_6692
ER  - 
@conference{
author = "Bulatović, Sandra and Marković, Bojana and Tadić, Tamara and Nastasović, Aleksandra and Ilić, Mila and Randjelović, Danijela and Nedić, Natalija",
year = "2023",
abstract = "Macroporous (glycidyl methacrylate) GMA-based composite was
synthesized via suspension polymerization in the presence of 2 wt. % magnetic
nanoparticles and functionalized with triethylenetetramine. Copper was immobilized
on composite by contacting modified copolymer with 0.1 M solution of CuCl2, at pH
5, and 25 ̊C. The obtained composite was characterized by mercury porosimetry,
Fourier transform infrared spectroscopy (FTIR) analysis and atomic force
microscopy (AFM). GMA-based composites, due to their properties (size, porosity,
etc.), and the presence of reactive epoxy group, have found a variety of applications
as sorbents, enzyme supports, in biomedical applications, for metal and organic
compounds sorption.1
The antimicrobial activity of the synthesized GMA/Cu copolymer against
Staphylococcus aureus, Escherichia coli, Candida albicans and Aspergillus niger as
representatives for Gram-positive bacteria, Gram-negative bacteria, yeast and fungi
were investigated in this study.2 The copolymer displayed good antimicrobial activity
against all analyzed microbes, which makes it a material that can be potentially used
for biomedical (antibacterial and antifungal) applications.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia",
title = "Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer",
pages = "163-163",
url = "https://hdl.handle.net/21.15107/rcub_cer_6692"
}
Bulatović, S., Marković, B., Tadić, T., Nastasović, A., Ilić, M., Randjelović, D.,& Nedić, N.. (2023). Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 163-163.
https://hdl.handle.net/21.15107/rcub_cer_6692
Bulatović S, Marković B, Tadić T, Nastasović A, Ilić M, Randjelović D, Nedić N. Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia. 2023;:163-163.
https://hdl.handle.net/21.15107/rcub_cer_6692 .
Bulatović, Sandra, Marković, Bojana, Tadić, Tamara, Nastasović, Aleksandra, Ilić, Mila, Randjelović, Danijela, Nedić, Natalija, "Determination of Antimicrobial Activity Of Copper Activated Macroporous GMA Based Copolymer" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia (2023):163-163,
https://hdl.handle.net/21.15107/rcub_cer_6692 .

Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design

Tadić, Tamara; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra; Ilić, Mila; Vuković, Zorica; Onjia, Antonije

(University of East Sarajevo, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Vuković, Zorica
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6763
AB  - In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. The obtained macroporous
copolymer was syntesized via suspension copolymerization and was characterized by Fourier
transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The
parameters which affect sorption efficiency of the lindane were: pH, sorption time (tsor), ion
strength (ion), rpm, and dose of sorbent. These variables were optimized by the experimental
design which include Plackett-Burman Design (PBD) and Central Composite Design (CCD).
After screening step by the PBD, the optimum conditions were obtained by the CCD where the
values were investigated in two levels. The design of experiment showed that the ion strength
and dose of sorbent were the most significant parameters, while the other variables do not have
such an effect on sorption efficiency. Accordingly, the optimum conditions to reach the maximum
recovery were: pH 8, 180 min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/l dose of
sorbent. The results showed that the studied copolymer could be an efficient sorbent for trace
lindane in water with recoveries above 80 %.
PB  - University of East Sarajevo, Faculty of Technology
C3  - Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
T1  - Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design
SP  - 124
EP  - 124
UR  - https://hdl.handle.net/21.15107/rcub_cer_6763
ER  - 
@conference{
author = "Tadić, Tamara and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Ilić, Mila and Vuković, Zorica and Onjia, Antonije",
year = "2023",
abstract = "In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. The obtained macroporous
copolymer was syntesized via suspension copolymerization and was characterized by Fourier
transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The
parameters which affect sorption efficiency of the lindane were: pH, sorption time (tsor), ion
strength (ion), rpm, and dose of sorbent. These variables were optimized by the experimental
design which include Plackett-Burman Design (PBD) and Central Composite Design (CCD).
After screening step by the PBD, the optimum conditions were obtained by the CCD where the
values were investigated in two levels. The design of experiment showed that the ion strength
and dose of sorbent were the most significant parameters, while the other variables do not have
such an effect on sorption efficiency. Accordingly, the optimum conditions to reach the maximum
recovery were: pH 8, 180 min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/l dose of
sorbent. The results showed that the studied copolymer could be an efficient sorbent for trace
lindane in water with recoveries above 80 %.",
publisher = "University of East Sarajevo, Faculty of Technology",
journal = "Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina",
title = "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design",
pages = "124-124",
url = "https://hdl.handle.net/21.15107/rcub_cer_6763"
}
Tadić, T., Bulatović, S., Marković, B., Nastasović, A., Ilić, M., Vuković, Z.,& Onjia, A.. (2023). Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
University of East Sarajevo, Faculty of Technology., 124-124.
https://hdl.handle.net/21.15107/rcub_cer_6763
Tadić T, Bulatović S, Marković B, Nastasović A, Ilić M, Vuković Z, Onjia A. Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina. 2023;:124-124.
https://hdl.handle.net/21.15107/rcub_cer_6763 .
Tadić, Tamara, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Ilić, Mila, Vuković, Zorica, Onjia, Antonije, "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design" in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina (2023):124-124,
https://hdl.handle.net/21.15107/rcub_cer_6763 .

Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design

Tadić, Tamara; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra; Ilić, Mila; Vuković, Zorica; Onjia, Antonije

(University of East Sarajevo, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Vuković, Zorica
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6768
AB  - In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. Macroporous copolymer
was syntesized via suspension copolymerization and characterized by Fourier transform infrared
spectroscopy (FT-IR), and scanning electron microscopy (SEM). The parameters which affect
sorption efficiency of the lindane were: pH, sorption time (tsorp), ion strength (ion), rpm, and dose
of sorbent. These variables were optimized by the experimental design which include Plackett-
Burman Design (PBD) and Central Composite Design (CCD). After screening step by the PBD,
the optimum conditions were obtained by the CCD where the values were investigated in two
levels. The design of experiment showed that the ion strength and dose of sorbent were the most
significant parameters, while the other variables do not have such an effect on sorption
efficiency. Accordingly, the optimum conditions to reach the maximum recovery were: pH 8, 180
min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/L dose of sorbent. The results showed
that the studied copolymer could be an efficient sorbent for trace lindane in water with
recoveries above 80 %.
PB  - University of East Sarajevo, Faculty of Technology
C3  - Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
T1  - Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design
SP  - 253
EP  - 257
UR  - https://hdl.handle.net/21.15107/rcub_cer_6768
ER  - 
@conference{
author = "Tadić, Tamara and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Ilić, Mila and Vuković, Zorica and Onjia, Antonije",
year = "2023",
abstract = "In the present study, synthesized macroporous copolymer was used for the sorption of lindane
from an aqueous solution. This organochlorine pesticide is classified, according to US EPA, as
mutagenic and teratogenic. Residues of lindane can persist in the environment, migrate long
distances, and cause widespread contamination. In this way, lindane residues can reach the
human body through the food chain. The usage of this pesticide is banned in most countries.
However, lindane remains a serious toxicological problem at industrial sites where lindane was
used coupled with improper wastewater disposal and has led to serious contamination. In
addition, some countries still allow the production and use of lindane, and despite localized
restrictions, lindane contamination remains a global problem. Taking into account these
reasons, its removal from the environment is of a great significance. Macroporous copolymer
was syntesized via suspension copolymerization and characterized by Fourier transform infrared
spectroscopy (FT-IR), and scanning electron microscopy (SEM). The parameters which affect
sorption efficiency of the lindane were: pH, sorption time (tsorp), ion strength (ion), rpm, and dose
of sorbent. These variables were optimized by the experimental design which include Plackett-
Burman Design (PBD) and Central Composite Design (CCD). After screening step by the PBD,
the optimum conditions were obtained by the CCD where the values were investigated in two
levels. The design of experiment showed that the ion strength and dose of sorbent were the most
significant parameters, while the other variables do not have such an effect on sorption
efficiency. Accordingly, the optimum conditions to reach the maximum recovery were: pH 8, 180
min sorption time, 300 rpm, 2 w/v % ion strength and 8 g/L dose of sorbent. The results showed
that the studied copolymer could be an efficient sorbent for trace lindane in water with
recoveries above 80 %.",
publisher = "University of East Sarajevo, Faculty of Technology",
journal = "Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina",
title = "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design",
pages = "253-257",
url = "https://hdl.handle.net/21.15107/rcub_cer_6768"
}
Tadić, T., Bulatović, S., Marković, B., Nastasović, A., Ilić, M., Vuković, Z.,& Onjia, A.. (2023). Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
University of East Sarajevo, Faculty of Technology., 253-257.
https://hdl.handle.net/21.15107/rcub_cer_6768
Tadić T, Bulatović S, Marković B, Nastasović A, Ilić M, Vuković Z, Onjia A. Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina. 2023;:253-257.
https://hdl.handle.net/21.15107/rcub_cer_6768 .
Tadić, Tamara, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Ilić, Mila, Vuković, Zorica, Onjia, Antonije, "Optimization of lindane sorption from aqueous solution by macroporous copolymer using experimental design" in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina (2023):253-257,
https://hdl.handle.net/21.15107/rcub_cer_6768 .

Validation of an adsorption kinetic model for lindane removal by a porous polymer

Ilić, Mila; Tadić, Tamara; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra

(Croatian Society of Chemical Engineers, 2023)

TY  - CONF
AU  - Ilić, Mila
AU  - Tadić, Tamara
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6758
AB  - Lindane was one of the most commonly used organochlorine pesticides for controlling a wide
range of horticultural, agricultural, and public health pests during the second half of the 20th
century. [1] Owing to its toxic nature, bioaccumulation capability, and long transportable
nature, it belongs to a group of persistent organic pollutants (POPs). [2] Although lindane use
has been restricted or even banned, its residues persist and represent a serious environmental
problem since lindane residues are still found in water, sediments, soil, plants, and
animals. [3] Therefore, there is a growing interest in lindane removal or degradation by various
methods. In this context, sorption has received considerable attention as one of the most
effective and simplest technological approaches for the removal of lindane. In the present
study, we investigated the kinetics of the lindane sorption process onto a porous
functionalized copolymer based on glycidyl methacrylate. Five widely used isotherm kinetic
models (pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power
models) were employed via non-linear and linear fitting. The extent of kinetic model
compatibility was evaluated through seven error functions. According to the obtained results,
the pseudo-second-order model was the best-fitting kinetic model for describing the kinetics
of lindane sorption by the investigated sorbent.
PB  - Croatian Society of Chemical Engineers
C3  - Book of Abstracts - 28th Croatian Meeting of Chemists and Chemical Engineers (28HSKIKI), March 28-31, 2023, Rovinj, Croatia
T1  - Validation of an adsorption kinetic model for lindane removal by a porous polymer
SP  - 190
EP  - 190
UR  - https://hdl.handle.net/21.15107/rcub_cer_6758
ER  - 
@conference{
author = "Ilić, Mila and Tadić, Tamara and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra",
year = "2023",
abstract = "Lindane was one of the most commonly used organochlorine pesticides for controlling a wide
range of horticultural, agricultural, and public health pests during the second half of the 20th
century. [1] Owing to its toxic nature, bioaccumulation capability, and long transportable
nature, it belongs to a group of persistent organic pollutants (POPs). [2] Although lindane use
has been restricted or even banned, its residues persist and represent a serious environmental
problem since lindane residues are still found in water, sediments, soil, plants, and
animals. [3] Therefore, there is a growing interest in lindane removal or degradation by various
methods. In this context, sorption has received considerable attention as one of the most
effective and simplest technological approaches for the removal of lindane. In the present
study, we investigated the kinetics of the lindane sorption process onto a porous
functionalized copolymer based on glycidyl methacrylate. Five widely used isotherm kinetic
models (pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power
models) were employed via non-linear and linear fitting. The extent of kinetic model
compatibility was evaluated through seven error functions. According to the obtained results,
the pseudo-second-order model was the best-fitting kinetic model for describing the kinetics
of lindane sorption by the investigated sorbent.",
publisher = "Croatian Society of Chemical Engineers",
journal = "Book of Abstracts - 28th Croatian Meeting of Chemists and Chemical Engineers (28HSKIKI), March 28-31, 2023, Rovinj, Croatia",
title = "Validation of an adsorption kinetic model for lindane removal by a porous polymer",
pages = "190-190",
url = "https://hdl.handle.net/21.15107/rcub_cer_6758"
}
Ilić, M., Tadić, T., Bulatović, S., Marković, B.,& Nastasović, A.. (2023). Validation of an adsorption kinetic model for lindane removal by a porous polymer. in Book of Abstracts - 28th Croatian Meeting of Chemists and Chemical Engineers (28HSKIKI), March 28-31, 2023, Rovinj, Croatia
Croatian Society of Chemical Engineers., 190-190.
https://hdl.handle.net/21.15107/rcub_cer_6758
Ilić M, Tadić T, Bulatović S, Marković B, Nastasović A. Validation of an adsorption kinetic model for lindane removal by a porous polymer. in Book of Abstracts - 28th Croatian Meeting of Chemists and Chemical Engineers (28HSKIKI), March 28-31, 2023, Rovinj, Croatia. 2023;:190-190.
https://hdl.handle.net/21.15107/rcub_cer_6758 .
Ilić, Mila, Tadić, Tamara, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, "Validation of an adsorption kinetic model for lindane removal by a porous polymer" in Book of Abstracts - 28th Croatian Meeting of Chemists and Chemical Engineers (28HSKIKI), March 28-31, 2023, Rovinj, Croatia (2023):190-190,
https://hdl.handle.net/21.15107/rcub_cer_6758 .

Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata

Bulatović, Sandra; Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Ilić, Mila; Nedić, Natalija

(Belgrade : Serbian Chemical Society, 2023)

TY  - CONF
AU  - Bulatović, Sandra
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Nedić, Natalija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6771
AB  - Organohlorni pesticid - lindan, smatra se potencijalno kancerogenim jedinjenjem. Lindan i
njegovi ostaci mogu da opstanu u životnoj sredini veoma dugo, migrirajući i potencijalno
izazivajući zagađenje životne sredine. Ostaci lindana mogu dospeti i u ljudski organizam
kroz lanac ishrane, jer je ovo potencijalno toksično jedinjenje sklono bioakumulaciji.
Kontaminacija lindanom je globalni problem, a njegovo uklanjanje iz životne sredine je
neophodno. U ovom istraživanju sorpcija lindana iz vodenog rastvora urađena je sa
makroporoznim kopolimerom na bazi glicidil metakrilata, koji se pokazao kao veoma
efikasan sorbent, sa sorpcijom lindana od oko 0%. Za određivanje koncentracije lindana
korišćena je analitička tehnika, gasna hromatografija sa detektorom za hvatanje elektrona
GC-ECD. Osim sorpcije, uspešno je urađena i desorpcija lindana.
AB  - Organochlorine pesticide - lindane, is considered as potentially carcinogenic compound. Lindane and its residues can persist in the environment for a very long period, migrating and potentially causing environmental pollution. Residues of lindane can also enter the human body through the food chain, because this potentially toxic compound is prone to bioaccumulation. Lindane contamination is a global problem, and its removal from the environment is essential. In this research, the sorption of lindane from an aqueous solution was performed with a macroporous copolymer based on glycidyl methacrylate, which proved to be a very effective sorbent, with lindane sorption of about 80%. An analytical technique, gas chromatography with an electron capture detector GC-ECD, was used to determine the concentration of lindane. In addition to sorption, desorption of lindane was also successfully performed.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine
T1  - Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata
T1  - Sorption of lindane from water using a macroporous copolymer  based on glycidyl methacrylate
SP  - 122
EP  - 122
UR  - https://hdl.handle.net/21.15107/rcub_cer_6771
ER  - 
@conference{
author = "Bulatović, Sandra and Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Ilić, Mila and Nedić, Natalija",
year = "2023",
abstract = "Organohlorni pesticid - lindan, smatra se potencijalno kancerogenim jedinjenjem. Lindan i
njegovi ostaci mogu da opstanu u životnoj sredini veoma dugo, migrirajući i potencijalno
izazivajući zagađenje životne sredine. Ostaci lindana mogu dospeti i u ljudski organizam
kroz lanac ishrane, jer je ovo potencijalno toksično jedinjenje sklono bioakumulaciji.
Kontaminacija lindanom je globalni problem, a njegovo uklanjanje iz životne sredine je
neophodno. U ovom istraživanju sorpcija lindana iz vodenog rastvora urađena je sa
makroporoznim kopolimerom na bazi glicidil metakrilata, koji se pokazao kao veoma
efikasan sorbent, sa sorpcijom lindana od oko 0%. Za određivanje koncentracije lindana
korišćena je analitička tehnika, gasna hromatografija sa detektorom za hvatanje elektrona
GC-ECD. Osim sorpcije, uspešno je urađena i desorpcija lindana., Organochlorine pesticide - lindane, is considered as potentially carcinogenic compound. Lindane and its residues can persist in the environment for a very long period, migrating and potentially causing environmental pollution. Residues of lindane can also enter the human body through the food chain, because this potentially toxic compound is prone to bioaccumulation. Lindane contamination is a global problem, and its removal from the environment is essential. In this research, the sorption of lindane from an aqueous solution was performed with a macroporous copolymer based on glycidyl methacrylate, which proved to be a very effective sorbent, with lindane sorption of about 80%. An analytical technique, gas chromatography with an electron capture detector GC-ECD, was used to determine the concentration of lindane. In addition to sorption, desorption of lindane was also successfully performed.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine",
title = "Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata, Sorption of lindane from water using a macroporous copolymer  based on glycidyl methacrylate",
pages = "122-122",
url = "https://hdl.handle.net/21.15107/rcub_cer_6771"
}
Bulatović, S., Tadić, T., Marković, B., Nastasović, A., Ilić, M.,& Nedić, N.. (2023). Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata. in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine
Belgrade : Serbian Chemical Society., 122-122.
https://hdl.handle.net/21.15107/rcub_cer_6771
Bulatović S, Tadić T, Marković B, Nastasović A, Ilić M, Nedić N. Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata. in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine. 2023;:122-122.
https://hdl.handle.net/21.15107/rcub_cer_6771 .
Bulatović, Sandra, Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Ilić, Mila, Nedić, Natalija, "Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata" in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine (2023):122-122,
https://hdl.handle.net/21.15107/rcub_cer_6771 .

Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate

Bulatović, Sandra; Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Ilić, Mila; Nedić, Natalija

(Belgrade : Serbian Chemical Society, 2023)

TY  - CONF
AU  - Bulatović, Sandra
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Ilić, Mila
AU  - Nedić, Natalija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6772
AB  - Organochlorine pesticide - lindane, according to the US EPA classification, is considered
as potentially carcinogenic compound. Although the usage of this pesticide is banned in
many countries, it is still used in some. As persistent organic compound, lindane and its
residues can persist in the environment for a very long time, migrating over long distances,
potentially causing environmental pollution. Lindane residues can reach the human body
through the food chain, because this potentially toxic compound is prone to
bioaccumulation, and this is serious toxicological problem especially at industrial and
agricultural sites where lindane has been used directly, or has reached due to improper
wastewater disposal. Despite bans on its use, lindane contamination remains a global
problem, and its removal from the environment is of crucial importance. In this research,
for the sorption of lindane from an aqueous solution, a macroporous copolymer based on
glycidyl methacrylate was utilized, which proved to be a very effective sorbent, with
lindane sorption of about 80 %. Analytical technique, Gas Chromatography with an
Electron Capture Detector (GC-ECD), was used for determination of lindane
concentration. In addition to sorption, desorption of lindane was also successfully
performed using different solvents, which confirmed the possibility of recycling and reuse
of the investigated polymer.
AB  - Organohlorni pesticid - lindan, prema US EPA klasifikaciji, smatra se potencijalno kancerogenim jedinjenjem. Iako je upotreba ovog pesticida zabranjena u mnogim zemljama, u nekim se i dalje koristi. Kao perzistentno organsko jedinjenje, lindan i njegovi ostaci mogu da opstanu u životnoj sredini veoma dugo, migrirajući na velike udaljenosti, potencijalno izazivajući zagađenje životne sredine. Ostaci lindana mogu da dospeju u ljudski organizam kroz lanac ishrane, jer je ovo potencijalno toksično jedinjenje sklono bioakumulaciji, a to je ozbiljan toksikološki problem posebno u industrijskim i poljoprivrednim lokacijama gde se lindan direktno koristio ili je dospeo usled nepravilnog odlaganja otpadnih voda. Uprkos zabranama njegove upotrebe, kontaminacija lindanom ostaje globalni problem, a njegovo uklanjanje iz životne sredine je od ključnog značaja. U 
ovom istraživanju sorpcija lindana iz vodenog rastvora urađena je sa makroporoznim 
kopolimerom na bazi glicidil metakrilata, koji se pokazao kao veoma efikasan sorbent, sa sorpcijom lindana od oko 0 %. Za određivanje koncentracije lindana korišćena je analitička tehnika, gasna hromatografija sa detektorom za hvatanje elektrona GC-ECD (Gas Chromatography with an Electron Capture Detector). Osim sorpcije, uspešno je urađena i desorpcija lindana korišćenjem različitih rastvarača, što je potvrdilo mogućnost reciklaže i ponovne upotrebe ispitivanog polimera.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine
T1  - Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate
T1  - Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata
SP  - 160
EP  - 163
UR  - https://hdl.handle.net/21.15107/rcub_cer_6772
ER  - 
@conference{
author = "Bulatović, Sandra and Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Ilić, Mila and Nedić, Natalija",
year = "2023",
abstract = "Organochlorine pesticide - lindane, according to the US EPA classification, is considered
as potentially carcinogenic compound. Although the usage of this pesticide is banned in
many countries, it is still used in some. As persistent organic compound, lindane and its
residues can persist in the environment for a very long time, migrating over long distances,
potentially causing environmental pollution. Lindane residues can reach the human body
through the food chain, because this potentially toxic compound is prone to
bioaccumulation, and this is serious toxicological problem especially at industrial and
agricultural sites where lindane has been used directly, or has reached due to improper
wastewater disposal. Despite bans on its use, lindane contamination remains a global
problem, and its removal from the environment is of crucial importance. In this research,
for the sorption of lindane from an aqueous solution, a macroporous copolymer based on
glycidyl methacrylate was utilized, which proved to be a very effective sorbent, with
lindane sorption of about 80 %. Analytical technique, Gas Chromatography with an
Electron Capture Detector (GC-ECD), was used for determination of lindane
concentration. In addition to sorption, desorption of lindane was also successfully
performed using different solvents, which confirmed the possibility of recycling and reuse
of the investigated polymer., Organohlorni pesticid - lindan, prema US EPA klasifikaciji, smatra se potencijalno kancerogenim jedinjenjem. Iako je upotreba ovog pesticida zabranjena u mnogim zemljama, u nekim se i dalje koristi. Kao perzistentno organsko jedinjenje, lindan i njegovi ostaci mogu da opstanu u životnoj sredini veoma dugo, migrirajući na velike udaljenosti, potencijalno izazivajući zagađenje životne sredine. Ostaci lindana mogu da dospeju u ljudski organizam kroz lanac ishrane, jer je ovo potencijalno toksično jedinjenje sklono bioakumulaciji, a to je ozbiljan toksikološki problem posebno u industrijskim i poljoprivrednim lokacijama gde se lindan direktno koristio ili je dospeo usled nepravilnog odlaganja otpadnih voda. Uprkos zabranama njegove upotrebe, kontaminacija lindanom ostaje globalni problem, a njegovo uklanjanje iz životne sredine je od ključnog značaja. U 
ovom istraživanju sorpcija lindana iz vodenog rastvora urađena je sa makroporoznim 
kopolimerom na bazi glicidil metakrilata, koji se pokazao kao veoma efikasan sorbent, sa sorpcijom lindana od oko 0 %. Za određivanje koncentracije lindana korišćena je analitička tehnika, gasna hromatografija sa detektorom za hvatanje elektrona GC-ECD (Gas Chromatography with an Electron Capture Detector). Osim sorpcije, uspešno je urađena i desorpcija lindana korišćenjem različitih rastvarača, što je potvrdilo mogućnost reciklaže i ponovne upotrebe ispitivanog polimera.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine",
title = "Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate, Sorpcija lindana iz vode pomoću makroporoznog kopolimera na bazi glicidil metakrilata",
pages = "160-163",
url = "https://hdl.handle.net/21.15107/rcub_cer_6772"
}
Bulatović, S., Tadić, T., Marković, B., Nastasović, A., Ilić, M.,& Nedić, N.. (2023). Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate. in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine
Belgrade : Serbian Chemical Society., 160-163.
https://hdl.handle.net/21.15107/rcub_cer_6772
Bulatović S, Tadić T, Marković B, Nastasović A, Ilić M, Nedić N. Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate. in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine. 2023;:160-163.
https://hdl.handle.net/21.15107/rcub_cer_6772 .
Bulatović, Sandra, Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Ilić, Mila, Nedić, Natalija, "Sorption of lindane from water using a macroporous copolymer based on glycidyl methacrylate" in Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, Novi Sad, Serbia, June 1-2, 2023 / Kratki izvodi radova, kjniga radova - 59. Savetovanje Srpskog hemijskog društva, Novi Sad, 9. i 10. jun 2023. godine (2023):160-163,
https://hdl.handle.net/21.15107/rcub_cer_6772 .

Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism

Tadić, Tamara; Marković, Bojana; Ilić, Mila; Nastasović, Aleksandra; Onjia, Antonije

(University in Banjaluka, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Ilić, Mila
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6984
AB  - Lindane belongs to the persistent organic pollutants (POPs) group, which can cause carcinogenic, endocrine, and neurological problems in an organism. The widespread presence of lindane in the environment demands efficient methods of its removal. In the present work, we investigated the removal of lindane from an aqueous solution using a synthesized macroporous copolymer surface modified with different functional groups through two-step post-functionalization. The modified copolymer was characterized by Fourier transform infrared spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), and mercury intrusion porosimetry. For the kinetics of lindane sorption, pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power models were used via linear and non-linear regression analyses. The quality of the fitting of each model to experimental data was assessed based on seven error functions: coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the sum of the errors squared (SSE), sum of the absolute errors (EABS), and average relative error (ARE). The investigation of error estimation methods showed that the pseudo-second-order model best fits the experimental kinetics data for both regression analyses. The mechanism of lindane sorption was investigated by subjecting the data to the liquid film diffusion model, intraparticle diffusion model, Bangham, and Boyd models. The results showed that intraparticle diffusion was not the sole rate-controlling step; film-diffusion also affected the sorption process.
PB  - University in Banjaluka, Faculty of Technology
C3  - Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
T1  - Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism
SP  - 300
EP  - 306
UR  - https://hdl.handle.net/21.15107/rcub_cer_6984
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Ilić, Mila and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "Lindane belongs to the persistent organic pollutants (POPs) group, which can cause carcinogenic, endocrine, and neurological problems in an organism. The widespread presence of lindane in the environment demands efficient methods of its removal. In the present work, we investigated the removal of lindane from an aqueous solution using a synthesized macroporous copolymer surface modified with different functional groups through two-step post-functionalization. The modified copolymer was characterized by Fourier transform infrared spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), and mercury intrusion porosimetry. For the kinetics of lindane sorption, pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power models were used via linear and non-linear regression analyses. The quality of the fitting of each model to experimental data was assessed based on seven error functions: coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the sum of the errors squared (SSE), sum of the absolute errors (EABS), and average relative error (ARE). The investigation of error estimation methods showed that the pseudo-second-order model best fits the experimental kinetics data for both regression analyses. The mechanism of lindane sorption was investigated by subjecting the data to the liquid film diffusion model, intraparticle diffusion model, Bangham, and Boyd models. The results showed that intraparticle diffusion was not the sole rate-controlling step; film-diffusion also affected the sorption process.",
publisher = "University in Banjaluka, Faculty of Technology",
journal = "Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska",
title = "Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism",
pages = "300-306",
url = "https://hdl.handle.net/21.15107/rcub_cer_6984"
}
Tadić, T., Marković, B., Ilić, M., Nastasović, A.,& Onjia, A.. (2023). Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism. in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
University in Banjaluka, Faculty of Technology., 300-306.
https://hdl.handle.net/21.15107/rcub_cer_6984
Tadić T, Marković B, Ilić M, Nastasović A, Onjia A. Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism. in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska. 2023;:300-306.
https://hdl.handle.net/21.15107/rcub_cer_6984 .
Tadić, Tamara, Marković, Bojana, Ilić, Mila, Nastasović, Aleksandra, Onjia, Antonije, "Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism" in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska (2023):300-306,
https://hdl.handle.net/21.15107/rcub_cer_6984 .

Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism

Tadić, Tamara; Marković, Bojana; Ilić, Mila; Nastasović, Aleksandra; Onjia, Antonije

(University in Banjaluka, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Ilić, Mila
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6986
AB  - Lindane belongs to the persistent organic pollutants (POPs) group, which can cause carcinogenic, endocrine, and neurological problems in an organism. The widespread presence of lindane in the environment demands efficient methods of its removal. In the present work, we investigated the removal of lindane from an aqueous solution using a synthesized macroporous copolymer surface modified with different functional groups through two-step post-functionalization. The modified copolymer was characterized by Fourier transform infrared spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), and mercury intrusion porosimetry. For the kinetics of lindane sorption, pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power models were used via linear and non-linear regression analyses. The quality of the fitting of each model to experimental data was assessed based on seven error functions: coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the sum of the errors squared (SSE), sum of the absolute errors (EABS), and average relative error (ARE). The investigation of error estimation methods showed that the pseudo-second-order model best fits the experimental kinetics data for both regression analyses. The mechanism of lindane sorption was investigated by subjecting the data to the liquid film diffusion model, intraparticle diffusion model, Bangham, and Boyd models. The results showed that intraparticle diffusion was not the sole rate-controlling step; film-diffusion also affected the sorption process.
PB  - University in Banjaluka, Faculty of Technology
C3  - Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
T1  - Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism
SP  - 203
EP  - 203
UR  - https://hdl.handle.net/21.15107/rcub_cer_6986
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Ilić, Mila and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "Lindane belongs to the persistent organic pollutants (POPs) group, which can cause carcinogenic, endocrine, and neurological problems in an organism. The widespread presence of lindane in the environment demands efficient methods of its removal. In the present work, we investigated the removal of lindane from an aqueous solution using a synthesized macroporous copolymer surface modified with different functional groups through two-step post-functionalization. The modified copolymer was characterized by Fourier transform infrared spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), and mercury intrusion porosimetry. For the kinetics of lindane sorption, pseudo-first-order, pseudo-second-order, Elovich, Avrami, and fractional power models were used via linear and non-linear regression analyses. The quality of the fitting of each model to experimental data was assessed based on seven error functions: coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the sum of the errors squared (SSE), sum of the absolute errors (EABS), and average relative error (ARE). The investigation of error estimation methods showed that the pseudo-second-order model best fits the experimental kinetics data for both regression analyses. The mechanism of lindane sorption was investigated by subjecting the data to the liquid film diffusion model, intraparticle diffusion model, Bangham, and Boyd models. The results showed that intraparticle diffusion was not the sole rate-controlling step; film-diffusion also affected the sorption process.",
publisher = "University in Banjaluka, Faculty of Technology",
journal = "Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska",
title = "Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism",
pages = "203-203",
url = "https://hdl.handle.net/21.15107/rcub_cer_6986"
}
Tadić, T., Marković, B., Ilić, M., Nastasović, A.,& Onjia, A.. (2023). Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism. in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
University in Banjaluka, Faculty of Technology., 203-203.
https://hdl.handle.net/21.15107/rcub_cer_6986
Tadić T, Marković B, Ilić M, Nastasović A, Onjia A. Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism. in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska. 2023;:203-203.
https://hdl.handle.net/21.15107/rcub_cer_6986 .
Tadić, Tamara, Marković, Bojana, Ilić, Mila, Nastasović, Aleksandra, Onjia, Antonije, "Removal of lindane from aqueous solution by glycidyl methacrylate based chelating macroporous copolymer: kinetics and mechanism" in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska (2023):203-203,
https://hdl.handle.net/21.15107/rcub_cer_6986 .

Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer

Marković, Bojana; Stefanović, Ivan; Tadić, Tamara; Sandić, Zvjezdana; Bulatović, Sandra; Nastasović, Aleksandra; Onjia, Antonije

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Marković, Bojana
AU  - Stefanović, Ivan
AU  - Tadić, Tamara
AU  - Sandić, Zvjezdana
AU  - Bulatović, Sandra
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6737
AB  - Hexavalent chromium, Cr(VI), is one of the most notorious pollutants with
health and environmental impacts due to carcinogenic, teratogenic, and mutagenic
effects on the human organism.1 Therefore, treating wastewater containing Cr(VI)
before discharge into the aquatic system is extremely necessary. In this study, the
nonlinear regression method was used to determine the kinetic and isotherm
parameters for Cr(VI) sorption from aqueous solution on hexamethylene diaminemodified 177btain177177ous copolymer based on glycidyl methacrylate (PGEHMD).2 The Avrami kinetic model provides the best correlation of the experimental data with R2 = 0.994 and χ2 = 0.004, while the Freundlich isotherm model best described the Cr(VI) sorption onto PGE-HMD copolymer indicating a heterogenous sorption process.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
T1  - Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer
SP  - 177
EP  - 177
UR  - https://hdl.handle.net/21.15107/rcub_cer_6737
ER  - 
@conference{
author = "Marković, Bojana and Stefanović, Ivan and Tadić, Tamara and Sandić, Zvjezdana and Bulatović, Sandra and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "Hexavalent chromium, Cr(VI), is one of the most notorious pollutants with
health and environmental impacts due to carcinogenic, teratogenic, and mutagenic
effects on the human organism.1 Therefore, treating wastewater containing Cr(VI)
before discharge into the aquatic system is extremely necessary. In this study, the
nonlinear regression method was used to determine the kinetic and isotherm
parameters for Cr(VI) sorption from aqueous solution on hexamethylene diaminemodified 177btain177177ous copolymer based on glycidyl methacrylate (PGEHMD).2 The Avrami kinetic model provides the best correlation of the experimental data with R2 = 0.994 and χ2 = 0.004, while the Freundlich isotherm model best described the Cr(VI) sorption onto PGE-HMD copolymer indicating a heterogenous sorption process.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia",
title = "Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer",
pages = "177-177",
url = "https://hdl.handle.net/21.15107/rcub_cer_6737"
}
Marković, B., Stefanović, I., Tadić, T., Sandić, Z., Bulatović, S., Nastasović, A.,& Onjia, A.. (2023). Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 177-177.
https://hdl.handle.net/21.15107/rcub_cer_6737
Marković B, Stefanović I, Tadić T, Sandić Z, Bulatović S, Nastasović A, Onjia A. Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia. 2023;:177-177.
https://hdl.handle.net/21.15107/rcub_cer_6737 .
Marković, Bojana, Stefanović, Ivan, Tadić, Tamara, Sandić, Zvjezdana, Bulatović, Sandra, Nastasović, Aleksandra, Onjia, Antonije, "Kinetic and Isotherm Non-Linear Study of Cr(VI) Sorption onto Amino-Modified Macroporous GMA Based Copolymer" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023 Metropol Lake Resort Ohrid, N. Macedonia (2023):177-177,
https://hdl.handle.net/21.15107/rcub_cer_6737 .

Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium

Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Suručić, Ljiljana T.; Sandić, Zvjezdana; Onjia, Antonije

(University in Banjaluka, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Suručić, Ljiljana T.
AU  - Sandić, Zvjezdana
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6987
AB  - This study evaluated the equilibrium, kinetics, and thermodynamics of vanadium sorption from aqueous solution onto nanocomposite functionalized with diethylene triamine in batch conditions. The effects of temperature, solution pH, and initial concentration of vanadium were examined. The maximum sorption capacity of vanadium on the tested sorbent was achieved at pH 6. The sorption capacity increased with increasing temperature and initial concentration. The equilibrium adsorption data were analyzed using Langmuir, Freundlich, Temkin, Jovanovic, Toth, Sips, Khan, and Redlich-Peterson isotherm models. The kinetics data were studied using pseudo-first-order, pseudo-second-order, the fractional power, Elovich, and Avrami models. A non-linear fitting method was used to compare the best fitting of the equilibrium and kinetic data. The sorption equilibrium data were best represented by the Langmuir, Khan, Toth, and Redlich–Peterson isotherms. The adsorption kinetics was estimated to follow the pseudo-second-order kinetic model. The mechanism of vanadium sorption was analyzed with intra-particle, Bangham, Boyd, and liquid film diffusion models. It was observed that the sorption process was controlled by the film-diffusion as well as the pore-diffusion. Thermodynamic parameters (change of standard enthalpy (ΔH°), standard entropy (ΔS°), and standard free energy (ΔG°)) suggested that the sorption of vanadium onto functionalized nanocomposite was a spontaneous and endothermic process.
PB  - University in Banjaluka, Faculty of Technology
C3  - Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
T1  - Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium
SP  - 202
EP  - 202
UR  - https://hdl.handle.net/21.15107/rcub_cer_6987
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Suručić, Ljiljana T. and Sandić, Zvjezdana and Onjia, Antonije",
year = "2023",
abstract = "This study evaluated the equilibrium, kinetics, and thermodynamics of vanadium sorption from aqueous solution onto nanocomposite functionalized with diethylene triamine in batch conditions. The effects of temperature, solution pH, and initial concentration of vanadium were examined. The maximum sorption capacity of vanadium on the tested sorbent was achieved at pH 6. The sorption capacity increased with increasing temperature and initial concentration. The equilibrium adsorption data were analyzed using Langmuir, Freundlich, Temkin, Jovanovic, Toth, Sips, Khan, and Redlich-Peterson isotherm models. The kinetics data were studied using pseudo-first-order, pseudo-second-order, the fractional power, Elovich, and Avrami models. A non-linear fitting method was used to compare the best fitting of the equilibrium and kinetic data. The sorption equilibrium data were best represented by the Langmuir, Khan, Toth, and Redlich–Peterson isotherms. The adsorption kinetics was estimated to follow the pseudo-second-order kinetic model. The mechanism of vanadium sorption was analyzed with intra-particle, Bangham, Boyd, and liquid film diffusion models. It was observed that the sorption process was controlled by the film-diffusion as well as the pore-diffusion. Thermodynamic parameters (change of standard enthalpy (ΔH°), standard entropy (ΔS°), and standard free energy (ΔG°)) suggested that the sorption of vanadium onto functionalized nanocomposite was a spontaneous and endothermic process.",
publisher = "University in Banjaluka, Faculty of Technology",
journal = "Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska",
title = "Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium",
pages = "202-202",
url = "https://hdl.handle.net/21.15107/rcub_cer_6987"
}
Tadić, T., Marković, B., Nastasović, A., Suručić, L. T., Sandić, Z.,& Onjia, A.. (2023). Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium. in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
University in Banjaluka, Faculty of Technology., 202-202.
https://hdl.handle.net/21.15107/rcub_cer_6987
Tadić T, Marković B, Nastasović A, Suručić LT, Sandić Z, Onjia A. Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium. in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska. 2023;:202-202.
https://hdl.handle.net/21.15107/rcub_cer_6987 .
Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Suručić, Ljiljana T., Sandić, Zvjezdana, Onjia, Antonije, "Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium" in Book of abstracts - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska (2023):202-202,
https://hdl.handle.net/21.15107/rcub_cer_6987 .

Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium

Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Suručić, Ljiljana T.; Sandić, Zvjezdana

(University in Banjaluka, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Suručić, Ljiljana T.
AU  - Sandić, Zvjezdana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6985
AB  - This study evaluated the equilibrium, kinetics, and thermodynamics of vanadium sorption from
aqueous solution onto nanocomposite functionalized with diethylene triamine in batch conditions.
The effects of temperature, solution pH, and initial concentration of vanadium were examined. The
maximum sorption capacity of vanadium on the tested sorbent was achieved at pH 6. The sorption
capacity increased with increasing temperature and initial concentration. The equilibrium adsorption data were analyzed using Langmuir, Freundlich, Temkin, Jovanovic, Toth, Sips, Khan, and Redlich- Peterson isotherm models. The kinetics data were studied using pseudo-first-order, pseudo-secondorder, the fractional power, Elovich, and Avrami models. A non-linear fitting method was used to compare the best fitting of the equilibrium and kinetic data. The sorption equilibrium data were best represented by the Langmuir, Khan, Toth, and Redlich–Peterson isotherms. The adsorption kinetics was estimated to follow the pseudo-second-order kinetic model. The mechanism of vanadium sorption was analyzed with intra-particle, Bangham, Boyd, and liquid film diffusion models. It was observed that the sorption process was controlled by the film-diffusion as well as the pore-diffusion. Thermodynamic parameters (change of standard enthalpy (ΔH°), standard entropy (ΔS°), and standard free energy (ΔG°)) suggested that the sorption of vanadium onto functionalized nanocomposite was a spontaneous and endothermic process.
PB  - University in Banjaluka, Faculty of Technology
C3  - Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
T1  - Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium
SP  - 292
EP  - 299
UR  - https://hdl.handle.net/21.15107/rcub_cer_6985
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Suručić, Ljiljana T. and Sandić, Zvjezdana",
year = "2023",
abstract = "This study evaluated the equilibrium, kinetics, and thermodynamics of vanadium sorption from
aqueous solution onto nanocomposite functionalized with diethylene triamine in batch conditions.
The effects of temperature, solution pH, and initial concentration of vanadium were examined. The
maximum sorption capacity of vanadium on the tested sorbent was achieved at pH 6. The sorption
capacity increased with increasing temperature and initial concentration. The equilibrium adsorption data were analyzed using Langmuir, Freundlich, Temkin, Jovanovic, Toth, Sips, Khan, and Redlich- Peterson isotherm models. The kinetics data were studied using pseudo-first-order, pseudo-secondorder, the fractional power, Elovich, and Avrami models. A non-linear fitting method was used to compare the best fitting of the equilibrium and kinetic data. The sorption equilibrium data were best represented by the Langmuir, Khan, Toth, and Redlich–Peterson isotherms. The adsorption kinetics was estimated to follow the pseudo-second-order kinetic model. The mechanism of vanadium sorption was analyzed with intra-particle, Bangham, Boyd, and liquid film diffusion models. It was observed that the sorption process was controlled by the film-diffusion as well as the pore-diffusion. Thermodynamic parameters (change of standard enthalpy (ΔH°), standard entropy (ΔS°), and standard free energy (ΔG°)) suggested that the sorption of vanadium onto functionalized nanocomposite was a spontaneous and endothermic process.",
publisher = "University in Banjaluka, Faculty of Technology",
journal = "Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska",
title = "Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium",
pages = "292-299",
url = "https://hdl.handle.net/21.15107/rcub_cer_6985"
}
Tadić, T., Marković, B., Nastasović, A., Suručić, L. T.,& Sandić, Z.. (2023). Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium. in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
University in Banjaluka, Faculty of Technology., 292-299.
https://hdl.handle.net/21.15107/rcub_cer_6985
Tadić T, Marković B, Nastasović A, Suručić LT, Sandić Z. Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium. in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska. 2023;:292-299.
https://hdl.handle.net/21.15107/rcub_cer_6985 .
Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Suručić, Ljiljana T., Sandić, Zvjezdana, "Study of isothermal, kinetic, and thermodynamic parameters for sorption of vanadium" in Proceedings - XIV International Scientific Conference of Chemists, Technologists and Environmentalists of Republic of Srpska (2023):292-299,
https://hdl.handle.net/21.15107/rcub_cer_6985 .

Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent

Tadić, Tamara; Sandić, Zvjezdana; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra; Onjia, Antonije

(University of East Sarajevo, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Sandić, Zvjezdana
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6767
AB  - Silver as one of the most known precious metal is used on a large scale in various industrial
branches and the release of silver ions from such industrial activities potentially can cause
serious environmental problems. Therefore, the removal of this metal from wastewater is a great
challenge, and it is crucial for the quality improvement of the environment. Porous polymer
materials with high specific surface areas and other specific physical and chemical
characteristics have gained much attention as sorbents in the field of environmental protection.
In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
copolymer synthesized by suspension copolymerization and functionalized with
diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjucted
pH and room temperature. The sorption kinetics and isotherms were studied to establish the
mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO),
pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle
diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized
using Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions
such as coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chisquare
statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error
(RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average
relative error (ARE) were used to estimate the error deviations between theoretically predicted
and experimental values of sorption capacities. The best kinetic and isotherm models were
determined by normalizing eight error functions and finding the sum of normalized error value
(SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous aminofunctionalized
sorbent obeys the PSO kinetic model. In addition, the results indicate that
sorption was governed by intraparticle diffusion with the evident influence of liquid film
diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted
to the Redlich-Peterson isotherm model.
PB  - University of East Sarajevo, Faculty of Technology
C3  - Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
T1  - Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent
SP  - 125
EP  - 125
UR  - https://hdl.handle.net/21.15107/rcub_cer_6767
ER  - 
@conference{
author = "Tadić, Tamara and Sandić, Zvjezdana and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "Silver as one of the most known precious metal is used on a large scale in various industrial
branches and the release of silver ions from such industrial activities potentially can cause
serious environmental problems. Therefore, the removal of this metal from wastewater is a great
challenge, and it is crucial for the quality improvement of the environment. Porous polymer
materials with high specific surface areas and other specific physical and chemical
characteristics have gained much attention as sorbents in the field of environmental protection.
In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
copolymer synthesized by suspension copolymerization and functionalized with
diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjucted
pH and room temperature. The sorption kinetics and isotherms were studied to establish the
mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO),
pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle
diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized
using Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions
such as coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chisquare
statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error
(RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average
relative error (ARE) were used to estimate the error deviations between theoretically predicted
and experimental values of sorption capacities. The best kinetic and isotherm models were
determined by normalizing eight error functions and finding the sum of normalized error value
(SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous aminofunctionalized
sorbent obeys the PSO kinetic model. In addition, the results indicate that
sorption was governed by intraparticle diffusion with the evident influence of liquid film
diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted
to the Redlich-Peterson isotherm model.",
publisher = "University of East Sarajevo, Faculty of Technology",
journal = "Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina",
title = "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent",
pages = "125-125",
url = "https://hdl.handle.net/21.15107/rcub_cer_6767"
}
Tadić, T., Sandić, Z., Bulatović, S., Marković, B., Nastasović, A.,& Onjia, A.. (2023). Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
University of East Sarajevo, Faculty of Technology., 125-125.
https://hdl.handle.net/21.15107/rcub_cer_6767
Tadić T, Sandić Z, Bulatović S, Marković B, Nastasović A, Onjia A. Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina. 2023;:125-125.
https://hdl.handle.net/21.15107/rcub_cer_6767 .
Tadić, Tamara, Sandić, Zvjezdana, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Onjia, Antonije, "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent" in Book of abstracts - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina (2023):125-125,
https://hdl.handle.net/21.15107/rcub_cer_6767 .

Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent

Tadić, Tamara; Sandić, Zvjezdana; Bulatović, Sandra; Marković, Bojana; Nastasović, Aleksandra; Onjia, Antonije

(University of East Sarajevo, Faculty of Technology, 2023)

TY  - CONF
AU  - Tadić, Tamara
AU  - Sandić, Zvjezdana
AU  - Bulatović, Sandra
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6769
AB  - Silver as one of the most known precious metal is used on a large scale in various industrial
branches and the release of silver ions from such industrial activities potentially can cause
serious environmental problems. Therefore, the removal of this metal from wastewater is a great
challenge, and it is crucial for the quality improvement of the environment. Porous polymer
materials with high specific surface areas and other specific physical and chemical
characteristics have gained much attention as sorbents in the field of environmental protection.
In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
copolymer synthesized by suspension copolymerization and functionalized with
diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjusted
pH and room temperature. The sorption kinetics and isotherms were studied to establish the
mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO),
pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle
diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized using
Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions such as
coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square
statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error
(RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average
relative error (ARE) were used to estimate the error deviations between theoretically predicted
and experimental values of sorption capacities. The best kinetic and isotherm models were
determined by normalizing eight error functions and finding the sum of normalized error value
(SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous
amino-functionalized sorbent obeys the PSO kinetic model. In addition, the results indicate that
sorption was governed by intraparticle diffusion with the evident influence of liquid film
diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted
to the Redlich-Peterson isotherm model.
PB  - University of East Sarajevo, Faculty of Technology
C3  - Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
T1  - Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent
SP  - 244
EP  - 252
UR  - https://hdl.handle.net/21.15107/rcub_cer_6769
ER  - 
@conference{
author = "Tadić, Tamara and Sandić, Zvjezdana and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "Silver as one of the most known precious metal is used on a large scale in various industrial
branches and the release of silver ions from such industrial activities potentially can cause
serious environmental problems. Therefore, the removal of this metal from wastewater is a great
challenge, and it is crucial for the quality improvement of the environment. Porous polymer
materials with high specific surface areas and other specific physical and chemical
characteristics have gained much attention as sorbents in the field of environmental protection.
In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
copolymer synthesized by suspension copolymerization and functionalized with
diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjusted
pH and room temperature. The sorption kinetics and isotherms were studied to establish the
mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO),
pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle
diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized using
Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions such as
coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square
statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error
(RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average
relative error (ARE) were used to estimate the error deviations between theoretically predicted
and experimental values of sorption capacities. The best kinetic and isotherm models were
determined by normalizing eight error functions and finding the sum of normalized error value
(SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous
amino-functionalized sorbent obeys the PSO kinetic model. In addition, the results indicate that
sorption was governed by intraparticle diffusion with the evident influence of liquid film
diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted
to the Redlich-Peterson isotherm model.",
publisher = "University of East Sarajevo, Faculty of Technology",
journal = "Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina",
title = "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent",
pages = "244-252",
url = "https://hdl.handle.net/21.15107/rcub_cer_6769"
}
Tadić, T., Sandić, Z., Bulatović, S., Marković, B., Nastasović, A.,& Onjia, A.. (2023). Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina
University of East Sarajevo, Faculty of Technology., 244-252.
https://hdl.handle.net/21.15107/rcub_cer_6769
Tadić T, Sandić Z, Bulatović S, Marković B, Nastasović A, Onjia A. Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina. 2023;:244-252.
https://hdl.handle.net/21.15107/rcub_cer_6769 .
Tadić, Tamara, Sandić, Zvjezdana, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Onjia, Antonije, "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent" in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina (2023):244-252,
https://hdl.handle.net/21.15107/rcub_cer_6769 .

Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite

Tadić, Tamara; Marković, Bojana; Vuković, Zorica; Stefanov, Plamen; Maksin, Danijela; Nastasović, Aleksandra; Onjia, Antonije

(2023)

TY  - JOUR
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Vuković, Zorica
AU  - Stefanov, Plamen
AU  - Maksin, Danijela
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7190
AB  - A novel porous gold polymer composite was prepared by the functionalization of a glycidyl methacrylate-based copolymer (pGME) with ethylene diamine (pGME-en), and activation by gold (pGME-en/Au), in a simple batch adsorption procedure in an acid solution, at room temperature. Detailed characterization of the pGME-en before and after activation was performed. The main focuses of this research were the design of a method that can enable the recovery of gold and the reuse of this multipurpose sorbent as an antimicrobial agent. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis pointed out amine groups as the primary binding sites for Au activation, while hydroxyl groups also contributed to the chelation reaction. pGME-en exhibited fast gold adsorption with an adsorption half-time of 5 min and an equilibrium time of 30 min. The maximal adsorption capacity was about 187 mg/g. The analysis of sorption experimental data with a non-linear surface reaction and diffusion-based kinetic models revealed the pseudo-second-order and Avrami model as the best fit, with unambiguous control by liquid film and intra-particle diffusion. The biological activity studies against Staphylococcus aureus, Listeria monocytogenes, Escherichia coli, and Candida albicans revealed moderate activity of pGME-en/Au against different bacterial and fungal species. pGME-en/Au was stable in a saline solution, with a release of approximately 2.3 mg/g after 24 h.
T2  - Metals
T1  - Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite
VL  - 13
IS  - 11
SP  - 1864
DO  - 10.3390/met13111864
ER  - 
@article{
author = "Tadić, Tamara and Marković, Bojana and Vuković, Zorica and Stefanov, Plamen and Maksin, Danijela and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "A novel porous gold polymer composite was prepared by the functionalization of a glycidyl methacrylate-based copolymer (pGME) with ethylene diamine (pGME-en), and activation by gold (pGME-en/Au), in a simple batch adsorption procedure in an acid solution, at room temperature. Detailed characterization of the pGME-en before and after activation was performed. The main focuses of this research were the design of a method that can enable the recovery of gold and the reuse of this multipurpose sorbent as an antimicrobial agent. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis pointed out amine groups as the primary binding sites for Au activation, while hydroxyl groups also contributed to the chelation reaction. pGME-en exhibited fast gold adsorption with an adsorption half-time of 5 min and an equilibrium time of 30 min. The maximal adsorption capacity was about 187 mg/g. The analysis of sorption experimental data with a non-linear surface reaction and diffusion-based kinetic models revealed the pseudo-second-order and Avrami model as the best fit, with unambiguous control by liquid film and intra-particle diffusion. The biological activity studies against Staphylococcus aureus, Listeria monocytogenes, Escherichia coli, and Candida albicans revealed moderate activity of pGME-en/Au against different bacterial and fungal species. pGME-en/Au was stable in a saline solution, with a release of approximately 2.3 mg/g after 24 h.",
journal = "Metals",
title = "Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite",
volume = "13",
number = "11",
pages = "1864",
doi = "10.3390/met13111864"
}
Tadić, T., Marković, B., Vuković, Z., Stefanov, P., Maksin, D., Nastasović, A.,& Onjia, A.. (2023). Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite. in Metals, 13(11), 1864.
https://doi.org/10.3390/met13111864
Tadić T, Marković B, Vuković Z, Stefanov P, Maksin D, Nastasović A, Onjia A. Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite. in Metals. 2023;13(11):1864.
doi:10.3390/met13111864 .
Tadić, Tamara, Marković, Bojana, Vuković, Zorica, Stefanov, Plamen, Maksin, Danijela, Nastasović, Aleksandra, Onjia, Antonije, "Fast Gold Recovery from Aqueous Solutions and Assessment of Antimicrobial Activities of Novel Gold Composite" in Metals, 13, no. 11 (2023):1864,
https://doi.org/10.3390/met13111864 . .

Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite

Suručić, Ljiljana; Janjić, Goran; Marković, Bojana; Tadić, Tamara; Vuković, Zorica; Nastasović, Aleksandra; Onjia, Antonije

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Suručić, Ljiljana
AU  - Janjić, Goran
AU  - Marković, Bojana
AU  - Tadić, Tamara
AU  - Vuković, Zorica
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6329
AB  - A new magnetic amino-functionalized polymeric sorbent based on glycidyl methacrylate was synthesized and used in the separation of chromium Cr(VI) oxyanions sorption from aqueous solutions in a static batch system. The kinetic and isothermal parameters of the sorption process were determined. The experimental data were best fitted by a pseudo-second-order model with R2 = 0.994 and χ2 = 0.004. The sorption process of Cr(VI) removal by amino-functionalized sorbent was controlled by both intraparticle diffusion and liquid film diffusion. The equilibrium results showed that the sorption process is best described by the Freundlich model, followed closely by the Sips isotherm model, with a maximum sorption capacity of 64 mg/g. Quantum chemical modeling revealed that the sorption sites on the sorbent surface are fragments with diethylenetriamine and aminopropyl silane groups that coated the magnetic nanoparticles. The calculations showed that Cr(VI) oxyanions (Cr2O72−, CrO42− and HCrO4−) bind to both sorption sites, with diethylenetriamine centers slightly favored. The X-ray photoelectron spectroscopy (XPS) spectra demonstrate that the chromium bound to the sorbent in the form of Cr(III), indicating that the Cr(VI) can be converted on the surface of the sorbent to a less harmful form Cr(III) due to the sorbent’s chemical composition.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Materials
T1  - Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite
VL  - 16
IS  - 6
SP  - 2233
DO  - 10.3390/ma16062233
ER  - 
@article{
author = "Suručić, Ljiljana and Janjić, Goran and Marković, Bojana and Tadić, Tamara and Vuković, Zorica and Nastasović, Aleksandra and Onjia, Antonije",
year = "2023",
abstract = "A new magnetic amino-functionalized polymeric sorbent based on glycidyl methacrylate was synthesized and used in the separation of chromium Cr(VI) oxyanions sorption from aqueous solutions in a static batch system. The kinetic and isothermal parameters of the sorption process were determined. The experimental data were best fitted by a pseudo-second-order model with R2 = 0.994 and χ2 = 0.004. The sorption process of Cr(VI) removal by amino-functionalized sorbent was controlled by both intraparticle diffusion and liquid film diffusion. The equilibrium results showed that the sorption process is best described by the Freundlich model, followed closely by the Sips isotherm model, with a maximum sorption capacity of 64 mg/g. Quantum chemical modeling revealed that the sorption sites on the sorbent surface are fragments with diethylenetriamine and aminopropyl silane groups that coated the magnetic nanoparticles. The calculations showed that Cr(VI) oxyanions (Cr2O72−, CrO42− and HCrO4−) bind to both sorption sites, with diethylenetriamine centers slightly favored. The X-ray photoelectron spectroscopy (XPS) spectra demonstrate that the chromium bound to the sorbent in the form of Cr(III), indicating that the Cr(VI) can be converted on the surface of the sorbent to a less harmful form Cr(III) due to the sorbent’s chemical composition.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Materials",
title = "Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite",
volume = "16",
number = "6",
pages = "2233",
doi = "10.3390/ma16062233"
}
Suručić, L., Janjić, G., Marković, B., Tadić, T., Vuković, Z., Nastasović, A.,& Onjia, A.. (2023). Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite. in Materials
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 16(6), 2233.
https://doi.org/10.3390/ma16062233
Suručić L, Janjić G, Marković B, Tadić T, Vuković Z, Nastasović A, Onjia A. Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite. in Materials. 2023;16(6):2233.
doi:10.3390/ma16062233 .
Suručić, Ljiljana, Janjić, Goran, Marković, Bojana, Tadić, Tamara, Vuković, Zorica, Nastasović, Aleksandra, Onjia, Antonije, "Speciation of Hexavalent Chromium in Aqueous Solutions Using a Magnetic Silica-Coated Amino-Modified Glycidyl Methacrylate Polymer Nanocomposite" in Materials, 16, no. 6 (2023):2233,
https://doi.org/10.3390/ma16062233 . .
2
7
6

Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites

Stefanović, Ivan; Marković, Bojana; Nastasović, Aleksandra; Vuković, Zorica; Dapčević, Aleksandra; Pavlović, Vladimir B.

(Serbia : International Institute for the Science of Sintering (IISS), 2022)

TY  - JOUR
AU  - Stefanović, Ivan
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Vuković, Zorica
AU  - Dapčević, Aleksandra
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5425
AB  - The impact of the type and amounts of nanofiller on the features of the glycidyl methacrylate-co-ethylene glycol dimethacrylate (GMA-co-EGDMA)/organomodified montmorillonite (OMt) nanocomposites that were prepared by in situ radical suspension polymerization, was examined. Cloisite 30B and Cloisite 25A were used in this study as nanofillers, in amounts of 2 and 10 wt.%. The structure, morphology, thermal stability and porosity of the initial GMA-co-EGDMA copolymer and their nanocomposites were examined by ATR-FTIR analysis, wide angle X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TG) and mercury porosimetry. It has been established that both clay nanofillers were successfully incorporated into the structure of the initial copolymer, simultaneously on their surface and also on cross-sectional area. Prepared samples with 2 wt.% have predominantly exfoliated, while samples with 10 wt.% have some tactoids-aggregates structure of the OMt layers. Thermogravimetric analysis revealed that after ~ 30 % of degradation, all nanocomposites become more thermal stable than the initial copolymer. The obtained results indicate that porosity parameters can be easily modified with the addition of clay nanofillers and thus prepared nanocomposites adjusted to specific purposes.
AB  - Утицај врсте и количине нанопуниоца на својства глицидил-метакрила-kо-етилен-гликол диметакрилата (GMA-cо-ЕGDMA)/ органомодификованих монтморилонит (ОМt) нанокомпозита, који су припремљени in situ радикалском суспензионом полимеризацијом, су испитани. Комерцијалне глине (Cloisite 30B и Cloisite 25A) су коришћене у овом раду као нанопуниоци, у количинама од 2 и 10 мас.%. Структура, морфологија, термичка стабилност и порозност полазног GMA-cо-ЕGDMA кополимера и његових нанокомпозита испитани су инфрацрвеном спектроскопијом са Фуријеoвом трансформацијом, рендгенском дифракцијом, скенирајућом електронском микроскопијом са енергодисперзивном спектрометријом, трансмисионом електронском микроскопијом, термогравиметријском анализом и живином порозиметријом. Утврђено је да су оба нанопуниоца глине успешно уграђена у структуру полазног кополимера, истовремено на његовој површини као и на површини попречног пресека. Добијени узорци са 2 мас.% имају претежно ексфолирану структуру слојева глине, док узорци са 10 мас.% показују присуство тактоидних-агрегатих слојева глине. Термогравиметријска анализа је показала да након ~ 30% деградације, сви нанокомпозити постају термички стабилнији од полазног кополимера. Добијени резултати указују да се параметри порозности могу лако модификовати додавањем нанопуниоца глине и на тај начин добити нанокомпозити прилагођени специфичним наменама.
PB  - Serbia : International Institute for the Science of Sintering (IISS)
T2  - Science of Sintering
T1  - Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites
VL  - 54
IS  - 2
SP  - 189
EP  - 200
DO  - 10.2298/SOS2202189S
ER  - 
@article{
author = "Stefanović, Ivan and Marković, Bojana and Nastasović, Aleksandra and Vuković, Zorica and Dapčević, Aleksandra and Pavlović, Vladimir B.",
year = "2022",
abstract = "The impact of the type and amounts of nanofiller on the features of the glycidyl methacrylate-co-ethylene glycol dimethacrylate (GMA-co-EGDMA)/organomodified montmorillonite (OMt) nanocomposites that were prepared by in situ radical suspension polymerization, was examined. Cloisite 30B and Cloisite 25A were used in this study as nanofillers, in amounts of 2 and 10 wt.%. The structure, morphology, thermal stability and porosity of the initial GMA-co-EGDMA copolymer and their nanocomposites were examined by ATR-FTIR analysis, wide angle X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TG) and mercury porosimetry. It has been established that both clay nanofillers were successfully incorporated into the structure of the initial copolymer, simultaneously on their surface and also on cross-sectional area. Prepared samples with 2 wt.% have predominantly exfoliated, while samples with 10 wt.% have some tactoids-aggregates structure of the OMt layers. Thermogravimetric analysis revealed that after ~ 30 % of degradation, all nanocomposites become more thermal stable than the initial copolymer. The obtained results indicate that porosity parameters can be easily modified with the addition of clay nanofillers and thus prepared nanocomposites adjusted to specific purposes., Утицај врсте и количине нанопуниоца на својства глицидил-метакрила-kо-етилен-гликол диметакрилата (GMA-cо-ЕGDMA)/ органомодификованих монтморилонит (ОМt) нанокомпозита, који су припремљени in situ радикалском суспензионом полимеризацијом, су испитани. Комерцијалне глине (Cloisite 30B и Cloisite 25A) су коришћене у овом раду као нанопуниоци, у количинама од 2 и 10 мас.%. Структура, морфологија, термичка стабилност и порозност полазног GMA-cо-ЕGDMA кополимера и његових нанокомпозита испитани су инфрацрвеном спектроскопијом са Фуријеoвом трансформацијом, рендгенском дифракцијом, скенирајућом електронском микроскопијом са енергодисперзивном спектрометријом, трансмисионом електронском микроскопијом, термогравиметријском анализом и живином порозиметријом. Утврђено је да су оба нанопуниоца глине успешно уграђена у структуру полазног кополимера, истовремено на његовој површини као и на површини попречног пресека. Добијени узорци са 2 мас.% имају претежно ексфолирану структуру слојева глине, док узорци са 10 мас.% показују присуство тактоидних-агрегатих слојева глине. Термогравиметријска анализа је показала да након ~ 30% деградације, сви нанокомпозити постају термички стабилнији од полазног кополимера. Добијени резултати указују да се параметри порозности могу лако модификовати додавањем нанопуниоца глине и на тај начин добити нанокомпозити прилагођени специфичним наменама.",
publisher = "Serbia : International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites",
volume = "54",
number = "2",
pages = "189-200",
doi = "10.2298/SOS2202189S"
}
Stefanović, I., Marković, B., Nastasović, A., Vuković, Z., Dapčević, A.,& Pavlović, V. B.. (2022). Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites. in Science of Sintering
Serbia : International Institute for the Science of Sintering (IISS)., 54(2), 189-200.
https://doi.org/10.2298/SOS2202189S
Stefanović I, Marković B, Nastasović A, Vuković Z, Dapčević A, Pavlović VB. Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites. in Science of Sintering. 2022;54(2):189-200.
doi:10.2298/SOS2202189S .
Stefanović, Ivan, Marković, Bojana, Nastasović, Aleksandra, Vuković, Zorica, Dapčević, Aleksandra, Pavlović, Vladimir B., "Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites" in Science of Sintering, 54, no. 2 (2022):189-200,
https://doi.org/10.2298/SOS2202189S . .

Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia

Bulatović, Sandra; Ilić, Mila; Šolević Knudsen, Tatjana; Nastasović, Aleksandra

(Belgrade : Serbian Chemical Society, 2022)

TY  - CONF
AU  - Bulatović, Sandra
AU  - Ilić, Mila
AU  - Šolević Knudsen, Tatjana
AU  - Nastasović, Aleksandra
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6761
AB  - Bioremediation is cheap, efficient, green technology that provides degradation of
organic compounds by microorganisms. Products of biodegradation can be less toxic
compounds or CO2 and H2O, when biodegradation is complete. The aim of this research
was detection and biodegradation of petroleum pollutants in the groundwater from
alluvial aquifer of the Sava river in the vicinity of one of the largest district heating plants
in New Belgrade (Serbia). The heating plant “New Belgrade” has been using petroleum
products as fuel for decades. Total Petroleum Hydrocarbons (TPH) were analyzed in 10
groundwater samples collected from boreholes at the depths from 8 to 11 m. From these
samples, TPH were isolated using extraction method with n-hexane. TPH was further
analyzed by gas chromatography with flame ionization detector (GC-FID). In this study
bioremediation was applied in order to degrade TPH in the groundwater of the
investigated location. This research lasted for one year [1].
In the sample P-5 the initial concentration of TPH was 1.39 mg/L and it was 0.02 mg/L
at the end of the bioremediation, with TPH reduction of 98.55 %. In the sample P-6, the
initial concentration of TPH was 1.76 mg/L, while at the end of the bioremediation it
was 0.03 mg/L, with TPH reduction of 98.30 %. In the sample P-7, the initial
concentration of TPH was 1.57 mg/L, and at the end of bioremediation it was 0.03 mg/L
with TPH reduction of 98.09 %. It can be concluded that this approach was very
successful, with an efficiency of approximately 100 % [1, 2].
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade: Serbian Young Chemists' Club
C3  - 8th Conference of Young Chemists of Serbia, Book of Abstracts, 29 October 2022, Belgrade, Serbia
T1  - Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia
SP  - 52
EP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_cer_6761
ER  - 
@conference{
author = "Bulatović, Sandra and Ilić, Mila and Šolević Knudsen, Tatjana and Nastasović, Aleksandra",
year = "2022",
abstract = "Bioremediation is cheap, efficient, green technology that provides degradation of
organic compounds by microorganisms. Products of biodegradation can be less toxic
compounds or CO2 and H2O, when biodegradation is complete. The aim of this research
was detection and biodegradation of petroleum pollutants in the groundwater from
alluvial aquifer of the Sava river in the vicinity of one of the largest district heating plants
in New Belgrade (Serbia). The heating plant “New Belgrade” has been using petroleum
products as fuel for decades. Total Petroleum Hydrocarbons (TPH) were analyzed in 10
groundwater samples collected from boreholes at the depths from 8 to 11 m. From these
samples, TPH were isolated using extraction method with n-hexane. TPH was further
analyzed by gas chromatography with flame ionization detector (GC-FID). In this study
bioremediation was applied in order to degrade TPH in the groundwater of the
investigated location. This research lasted for one year [1].
In the sample P-5 the initial concentration of TPH was 1.39 mg/L and it was 0.02 mg/L
at the end of the bioremediation, with TPH reduction of 98.55 %. In the sample P-6, the
initial concentration of TPH was 1.76 mg/L, while at the end of the bioremediation it
was 0.03 mg/L, with TPH reduction of 98.30 %. In the sample P-7, the initial
concentration of TPH was 1.57 mg/L, and at the end of bioremediation it was 0.03 mg/L
with TPH reduction of 98.09 %. It can be concluded that this approach was very
successful, with an efficiency of approximately 100 % [1, 2].",
publisher = "Belgrade : Serbian Chemical Society, Belgrade: Serbian Young Chemists' Club",
journal = "8th Conference of Young Chemists of Serbia, Book of Abstracts, 29 October 2022, Belgrade, Serbia",
title = "Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia",
pages = "52-52",
url = "https://hdl.handle.net/21.15107/rcub_cer_6761"
}
Bulatović, S., Ilić, M., Šolević Knudsen, T.,& Nastasović, A.. (2022). Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia. in 8th Conference of Young Chemists of Serbia, Book of Abstracts, 29 October 2022, Belgrade, Serbia
Belgrade : Serbian Chemical Society., 52-52.
https://hdl.handle.net/21.15107/rcub_cer_6761
Bulatović S, Ilić M, Šolević Knudsen T, Nastasović A. Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia. in 8th Conference of Young Chemists of Serbia, Book of Abstracts, 29 October 2022, Belgrade, Serbia. 2022;:52-52.
https://hdl.handle.net/21.15107/rcub_cer_6761 .
Bulatović, Sandra, Ilić, Mila, Šolević Knudsen, Tatjana, Nastasović, Aleksandra, "Detection and bioremediation of petroleum pollutants in groundwater of alluvial aquifer of the Sava river, Serbia" in 8th Conference of Young Chemists of Serbia, Book of Abstracts, 29 October 2022, Belgrade, Serbia (2022):52-52,
https://hdl.handle.net/21.15107/rcub_cer_6761 .

Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline

Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Lukić, Jelena; Suručić, Ljiljana T.; Sandić, Zvjezdana; Onjia, Antonije

(Academy of Sciences and Arts of the Republic of Srpska, 2022)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Lukić, Jelena
AU  - Suručić, Ljiljana T.
AU  - Sandić, Zvjezdana
AU  - Onjia, Antonije
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7002
AB  - In this paper, three molecularly imprinted polymers (MIPs) with different molar ratios of amine (ethylene diamine) and template (aniline) (1:1, 2:1, 4:1) were synthesized by the surface imprinting method. The obtained MIPs were characterized by scanning electron microscopy and FTIR, and investigated as a potential aniline sorbents at different pH. The results showed that MIP (4:1) had good potential for the removal of aniline.
PB  - Academy of Sciences and Arts of the Republic of Srpska
C3  - Programme and the book of abstracts - XV International scientific conference Contemporary Materials 2022
T1  - Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline
SP  - 90
EP  - 91
UR  - https://hdl.handle.net/21.15107/rcub_cer_7002
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Lukić, Jelena and Suručić, Ljiljana T. and Sandić, Zvjezdana and Onjia, Antonije",
year = "2022",
abstract = "In this paper, three molecularly imprinted polymers (MIPs) with different molar ratios of amine (ethylene diamine) and template (aniline) (1:1, 2:1, 4:1) were synthesized by the surface imprinting method. The obtained MIPs were characterized by scanning electron microscopy and FTIR, and investigated as a potential aniline sorbents at different pH. The results showed that MIP (4:1) had good potential for the removal of aniline.",
publisher = "Academy of Sciences and Arts of the Republic of Srpska",
journal = "Programme and the book of abstracts - XV International scientific conference Contemporary Materials 2022",
title = "Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline",
pages = "90-91",
url = "https://hdl.handle.net/21.15107/rcub_cer_7002"
}
Tadić, T., Marković, B., Nastasović, A., Lukić, J., Suručić, L. T., Sandić, Z.,& Onjia, A.. (2022). Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline. in Programme and the book of abstracts - XV International scientific conference Contemporary Materials 2022
Academy of Sciences and Arts of the Republic of Srpska., 90-91.
https://hdl.handle.net/21.15107/rcub_cer_7002
Tadić T, Marković B, Nastasović A, Lukić J, Suručić LT, Sandić Z, Onjia A. Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline. in Programme and the book of abstracts - XV International scientific conference Contemporary Materials 2022. 2022;:90-91.
https://hdl.handle.net/21.15107/rcub_cer_7002 .
Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Lukić, Jelena, Suručić, Ljiljana T., Sandić, Zvjezdana, Onjia, Antonije, "Synthesis of Molecularly Imprinted Polymer as a Selective Sorbent of Aniline" in Programme and the book of abstracts - XV International scientific conference Contemporary Materials 2022 (2022):90-91,
https://hdl.handle.net/21.15107/rcub_cer_7002 .

Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite

Marković, Bojana; Tadić, Tamara; Suručić, Ljiljana T.; Nastasović, Aleksandra; Sandić, Zvjezdana; Onjia, Antonije

(Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Marković, Bojana
AU  - Tadić, Tamara
AU  - Suručić, Ljiljana T.
AU  - Nastasović, Aleksandra
AU  - Sandić, Zvjezdana
AU  - Onjia, Antonije
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6999
AB  - Kinetic, equilibrium and thermodynamic of arsenate sorption onto magnetic polymer sorbent based on glycidyl methacrylate were investigated. The maximum sorption capacity of 0.59 mg/g was obtained. The experimental data were analyzed by seven kinetic models and eight isotherm models. Nonlinear regression method was used to fit the data to the kinetic and isotherm models. Thus, two error functions; coefficient of determination and Chi-square statistic test were applied to evaluate the sorption data. It was shown that arsenate sorption obeys the pseudo-second-order model with evident influence of pore and film diffusion. The Freundlich and all three-parameter isotherm models proved to be the best representatives of arsenate sorption. Thermodynamic studies implied endothermic and spontaneous process in nature.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
T1  - Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite
VL  - II
SP  - 421
EP  - 424
UR  - https://hdl.handle.net/21.15107/rcub_cer_6999
ER  - 
@conference{
author = "Marković, Bojana and Tadić, Tamara and Suručić, Ljiljana T. and Nastasović, Aleksandra and Sandić, Zvjezdana and Onjia, Antonije",
year = "2022",
abstract = "Kinetic, equilibrium and thermodynamic of arsenate sorption onto magnetic polymer sorbent based on glycidyl methacrylate were investigated. The maximum sorption capacity of 0.59 mg/g was obtained. The experimental data were analyzed by seven kinetic models and eight isotherm models. Nonlinear regression method was used to fit the data to the kinetic and isotherm models. Thus, two error functions; coefficient of determination and Chi-square statistic test were applied to evaluate the sorption data. It was shown that arsenate sorption obeys the pseudo-second-order model with evident influence of pore and film diffusion. The Freundlich and all three-parameter isotherm models proved to be the best representatives of arsenate sorption. Thermodynamic studies implied endothermic and spontaneous process in nature.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia",
title = "Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite",
volume = "II",
pages = "421-424",
url = "https://hdl.handle.net/21.15107/rcub_cer_6999"
}
Marković, B., Tadić, T., Suručić, L. T., Nastasović, A., Sandić, Z.,& Onjia, A.. (2022). Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
Society of Physical Chemists of Serbia., II, 421-424.
https://hdl.handle.net/21.15107/rcub_cer_6999
Marković B, Tadić T, Suručić LT, Nastasović A, Sandić Z, Onjia A. Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia. 2022;II:421-424.
https://hdl.handle.net/21.15107/rcub_cer_6999 .
Marković, Bojana, Tadić, Tamara, Suručić, Ljiljana T., Nastasović, Aleksandra, Sandić, Zvjezdana, Onjia, Antonije, "Non-linear kinetic isotherms and thermodynamic behavior of As(V) onto hybrid nanocomposite" in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia, II (2022):421-424,
https://hdl.handle.net/21.15107/rcub_cer_6999 .

CO2 capture by amine porous polymeric sorbent

Marković, Bojana; Tadić, Tamara; Nastasović, Aleksandra; Radić, Nenad; Vuković, Zorica

(Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Marković, Bojana
AU  - Tadić, Tamara
AU  - Nastasović, Aleksandra
AU  - Radić, Nenad
AU  - Vuković, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6998
AB  - In this report, magnetic porous polymer functionalized with pentaethylenehexamine (mP-PEHA) was tested as CO2 sorbent. The sorbent mP-PEHA was characterized by Fourier transform infrared spectroscopy in ATR mode (FTIR-ATR), scanning electron microscopy (SEM) and mercury porosimetry. CO2 adsorption was determined using a pulse gas chromatographic method. At optimal adsorption conditions (20 °C), the CO2 sorption capacity reached 10.8 ml CO2/g (0.48 mmol CO2/g). Temperature-programmed desorption (TPD) experiments were conducted to calculate the activation energy of CO2 desorption. Low activation energy (18.34 kJ/mol) and high desorption rate, with a stable uptake in five adsorption/desorption cycles, suggest mP-PEHA as potentially excellent sorbent for CO2 absorption.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
T1  - CO2 capture by amine porous polymeric sorbent
VL  - II
SP  - 417
EP  - 420
UR  - https://hdl.handle.net/21.15107/rcub_cer_6998
ER  - 
@conference{
author = "Marković, Bojana and Tadić, Tamara and Nastasović, Aleksandra and Radić, Nenad and Vuković, Zorica",
year = "2022",
abstract = "In this report, magnetic porous polymer functionalized with pentaethylenehexamine (mP-PEHA) was tested as CO2 sorbent. The sorbent mP-PEHA was characterized by Fourier transform infrared spectroscopy in ATR mode (FTIR-ATR), scanning electron microscopy (SEM) and mercury porosimetry. CO2 adsorption was determined using a pulse gas chromatographic method. At optimal adsorption conditions (20 °C), the CO2 sorption capacity reached 10.8 ml CO2/g (0.48 mmol CO2/g). Temperature-programmed desorption (TPD) experiments were conducted to calculate the activation energy of CO2 desorption. Low activation energy (18.34 kJ/mol) and high desorption rate, with a stable uptake in five adsorption/desorption cycles, suggest mP-PEHA as potentially excellent sorbent for CO2 absorption.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia",
title = "CO2 capture by amine porous polymeric sorbent",
volume = "II",
pages = "417-420",
url = "https://hdl.handle.net/21.15107/rcub_cer_6998"
}
Marković, B., Tadić, T., Nastasović, A., Radić, N.,& Vuković, Z.. (2022). CO2 capture by amine porous polymeric sorbent. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
Society of Physical Chemists of Serbia., II, 417-420.
https://hdl.handle.net/21.15107/rcub_cer_6998
Marković B, Tadić T, Nastasović A, Radić N, Vuković Z. CO2 capture by amine porous polymeric sorbent. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia. 2022;II:417-420.
https://hdl.handle.net/21.15107/rcub_cer_6998 .
Marković, Bojana, Tadić, Tamara, Nastasović, Aleksandra, Radić, Nenad, Vuković, Zorica, "CO2 capture by amine porous polymeric sorbent" in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia, II (2022):417-420,
https://hdl.handle.net/21.15107/rcub_cer_6998 .

Application of macroporous nanocomposite in microextraction of aromatic amine from water

Tadić, Tamara; Marković, Bojana; Nastasović, Aleksandra; Suručić, Ljiljana T.; Onjia, Antonije

(Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Nastasović, Aleksandra
AU  - Suručić, Ljiljana T.
AU  - Onjia, Antonije
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6997
AB  - Magnetic macroporous poly(glycidyl methacrylate-co-trimethylolpropane trimethacrylate) nanocomposite was synthesized by suspension copolymerization. The obtained nanocomposite was characterized by Fourier transform infrared spectroscopy (FT-IR), mercury porosimetry and scanning electron microscopy (SEM). Such magnetic nanocomposite was applied as sorbent for a dispersive solid-phase microextraction (DSPME) for aniline preconcentration from water samples. The parameters affecting the microextraction were optimized. The screening of DSPME parameters was determined using Plackett-Burman design (PBD). For the optimization of the most important factors Central Composite Design (CCD) was used. The analysis of the results showed that the pH value and temperature of desorption were the most significant factors.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
T1  - Application of macroporous nanocomposite in microextraction of aromatic amine from water
VL  - II
SP  - 425
EP  - 428
UR  - https://hdl.handle.net/21.15107/rcub_cer_6997
ER  - 
@conference{
author = "Tadić, Tamara and Marković, Bojana and Nastasović, Aleksandra and Suručić, Ljiljana T. and Onjia, Antonije",
year = "2022",
abstract = "Magnetic macroporous poly(glycidyl methacrylate-co-trimethylolpropane trimethacrylate) nanocomposite was synthesized by suspension copolymerization. The obtained nanocomposite was characterized by Fourier transform infrared spectroscopy (FT-IR), mercury porosimetry and scanning electron microscopy (SEM). Such magnetic nanocomposite was applied as sorbent for a dispersive solid-phase microextraction (DSPME) for aniline preconcentration from water samples. The parameters affecting the microextraction were optimized. The screening of DSPME parameters was determined using Plackett-Burman design (PBD). For the optimization of the most important factors Central Composite Design (CCD) was used. The analysis of the results showed that the pH value and temperature of desorption were the most significant factors.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia",
title = "Application of macroporous nanocomposite in microextraction of aromatic amine from water",
volume = "II",
pages = "425-428",
url = "https://hdl.handle.net/21.15107/rcub_cer_6997"
}
Tadić, T., Marković, B., Nastasović, A., Suručić, L. T.,& Onjia, A.. (2022). Application of macroporous nanocomposite in microextraction of aromatic amine from water. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia
Society of Physical Chemists of Serbia., II, 425-428.
https://hdl.handle.net/21.15107/rcub_cer_6997
Tadić T, Marković B, Nastasović A, Suručić LT, Onjia A. Application of macroporous nanocomposite in microextraction of aromatic amine from water. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia. 2022;II:425-428.
https://hdl.handle.net/21.15107/rcub_cer_6997 .
Tadić, Tamara, Marković, Bojana, Nastasović, Aleksandra, Suručić, Ljiljana T., Onjia, Antonije, "Application of macroporous nanocomposite in microextraction of aromatic amine from water" in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2022, Belgrade, Serbia, II (2022):425-428,
https://hdl.handle.net/21.15107/rcub_cer_6997 .

Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods

Suručić, Ljiljana T.; Nastasović, Aleksandra; Marković, Bojana; Tadić, Tamara; Onjia, Antonije; Janjić, Goran

(University in Banjaluka, Faculty of Technology, 2022)

TY  - CONF
AU  - Suručić, Ljiljana T.
AU  - Nastasović, Aleksandra
AU  - Marković, Bojana
AU  - Tadić, Tamara
AU  - Onjia, Antonije
AU  - Janjić, Goran
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7001
AB  - Improving the affinity and selectivity of polymeric materials for sorbing ionic species, particularly
heavy metals that pose a high environmental risk, is crucial from an environmental standpoint.
Research on the mechanism of sorption can aid in selecting the optimal sorbent for a given
application. Sorption occurs as a result of various interactions. Sorption includes diffusion of ions
through solution (typically the quickest), diffusion of ions through the boundary layer surrounding
the sorbent surface, diffusion through the porous structure of the sorbent (intra-particle diffusion),
and binding to active sites on sorbent surfaces. Kinetic and equilibrium models explain the sorption
mechanism but not the nature of interactions, which is essential for predicting the selectivity and
efficiency of the sorbent based on particular ionic species. As a result, we were compelled to
approach the molecular level. Active sites on the surface of the magnetic aminofunctionalized
polymer, which are amino functional groups, are used to bind ions to the magnetic nanocomposite.
The sorption process can be viewed as the sum of ion-ligand unit interactions. Unit complex
formation and stability can be studied with statistical analysis and quantum chemical calculations.
The Cambridge database (CSD) improves the crystal structure of complex ion-ligand. Based on
binding energy, DFT (Density Functional Theory) predicts the stability of complex molecules (unit
ion-ligand interactions). To ensure an accurate calculation, it is essential to include all system
parameters, including sorbent structure, ligand properties, ligand charge under specific conditions,
ion forms and charges, and solvatation effects. In the early stages of research, defining the system's model lets researchers make theoretical predictions about the magnetic aminofunctionalized polymer sorbent's affinity and selectivity for certain ionic species.
PB  - University in Banjaluka, Faculty of Technology
C3  - Book of Abstracts - XIV Conference of  Chemists, Technologists and Environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
T1  - Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods
SP  - 20
EP  - 20
UR  - https://hdl.handle.net/21.15107/rcub_cer_7001
ER  - 
@conference{
author = "Suručić, Ljiljana T. and Nastasović, Aleksandra and Marković, Bojana and Tadić, Tamara and Onjia, Antonije and Janjić, Goran",
year = "2022",
abstract = "Improving the affinity and selectivity of polymeric materials for sorbing ionic species, particularly
heavy metals that pose a high environmental risk, is crucial from an environmental standpoint.
Research on the mechanism of sorption can aid in selecting the optimal sorbent for a given
application. Sorption occurs as a result of various interactions. Sorption includes diffusion of ions
through solution (typically the quickest), diffusion of ions through the boundary layer surrounding
the sorbent surface, diffusion through the porous structure of the sorbent (intra-particle diffusion),
and binding to active sites on sorbent surfaces. Kinetic and equilibrium models explain the sorption
mechanism but not the nature of interactions, which is essential for predicting the selectivity and
efficiency of the sorbent based on particular ionic species. As a result, we were compelled to
approach the molecular level. Active sites on the surface of the magnetic aminofunctionalized
polymer, which are amino functional groups, are used to bind ions to the magnetic nanocomposite.
The sorption process can be viewed as the sum of ion-ligand unit interactions. Unit complex
formation and stability can be studied with statistical analysis and quantum chemical calculations.
The Cambridge database (CSD) improves the crystal structure of complex ion-ligand. Based on
binding energy, DFT (Density Functional Theory) predicts the stability of complex molecules (unit
ion-ligand interactions). To ensure an accurate calculation, it is essential to include all system
parameters, including sorbent structure, ligand properties, ligand charge under specific conditions,
ion forms and charges, and solvatation effects. In the early stages of research, defining the system's model lets researchers make theoretical predictions about the magnetic aminofunctionalized polymer sorbent's affinity and selectivity for certain ionic species.",
publisher = "University in Banjaluka, Faculty of Technology",
journal = "Book of Abstracts - XIV Conference of  Chemists, Technologists and Environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka",
title = "Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods",
pages = "20-20",
url = "https://hdl.handle.net/21.15107/rcub_cer_7001"
}
Suručić, L. T., Nastasović, A., Marković, B., Tadić, T., Onjia, A.,& Janjić, G.. (2022). Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods. in Book of Abstracts - XIV Conference of  Chemists, Technologists and Environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
University in Banjaluka, Faculty of Technology., 20-20.
https://hdl.handle.net/21.15107/rcub_cer_7001
Suručić LT, Nastasović A, Marković B, Tadić T, Onjia A, Janjić G. Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods. in Book of Abstracts - XIV Conference of  Chemists, Technologists and Environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka. 2022;:20-20.
https://hdl.handle.net/21.15107/rcub_cer_7001 .
Suručić, Ljiljana T., Nastasović, Aleksandra, Marković, Bojana, Tadić, Tamara, Onjia, Antonije, Janjić, Goran, "Theoretical prediction of magnetic aminofunctionalized polymer sorbent performance using molecular modeling methods" in Book of Abstracts - XIV Conference of  Chemists, Technologists and Environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka (2022):20-20,
https://hdl.handle.net/21.15107/rcub_cer_7001 .

Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions

Nastasović, Aleksandra; Marković, Bojana; Suručić, Ljiljana; Onjia, Antonije

(MDPI, 2022)

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Marković, Bojana
AU  - Suručić, Ljiljana
AU  - Onjia, Antonije
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5245
AB  - The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.
PB  - MDPI
T2  - Metals
T1  - Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions
VL  - 12
IS  - 5
SP  - 814
DO  - 10.3390/met12050814
ER  - 
@article{
author = "Nastasović, Aleksandra and Marković, Bojana and Suručić, Ljiljana and Onjia, Antonije",
year = "2022",
abstract = "The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.",
publisher = "MDPI",
journal = "Metals",
title = "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions",
volume = "12",
number = "5",
pages = "814",
doi = "10.3390/met12050814"
}
Nastasović, A., Marković, B., Suručić, L.,& Onjia, A.. (2022). Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals
MDPI., 12(5), 814.
https://doi.org/10.3390/met12050814
Nastasović A, Marković B, Suručić L, Onjia A. Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals. 2022;12(5):814.
doi:10.3390/met12050814 .
Nastasović, Aleksandra, Marković, Bojana, Suručić, Ljiljana, Onjia, Antonije, "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions" in Metals, 12, no. 5 (2022):814,
https://doi.org/10.3390/met12050814 . .
9
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A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline

Tadić, Tamara; Marković, Bojana; Radulović, Jelena; Lukić, Jelena; Suručić, Ljiljana; Nastasović, Aleksandra; Onjia, Antonije

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2022)

TY  - JOUR
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Radulović, Jelena
AU  - Lukić, Jelena
AU  - Suručić, Ljiljana
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5378
AB  - A core-shell amino-functionalized glycidyl methacrylate magnetic molecularly imprinted polymer (MIP) was synthesized by the suspension polymerization/surface imprinting method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), mercury porosimetry, nitrogen gas adsorption–desorption, and elemental analysis. This MIP was used as the sorbent in dispersive solid-phase microextraction (DSPME) of aniline from textile wastewater prior to high-performance liquid chromatography-mass spectrometry (HPLC-MS) measurements. Since aniline is toxic and a probable human carcinogen, its determination in water is of great significance. This is a challenging task because aniline is usually present at trace levels. The effects of different DSPME variables on the preconcentration efficiency have been studied by using the Plackett–Burman screening design of experiments (DoE) followed by response surface methodology optimization using the Box-Behnken design. Thus, DoE enabled the investigation of several variables simultaneously. Under optimized conditions, aniline was effectively and selectively separated by a small amount of the DSPME sorbent and detected in real textile wastewater samples. The method detection limit of 1 ng mL−1 was attained, with good method linearity and acceptable recovery and precision. The results showed that the studied MIP could be a reliable DSPME sorbent for efficiently analyzing trace aniline in real wastewater samples.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Sustainability
T1  - A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline
VL  - 14
IS  - 15
SP  - 9222
DO  - 10.3390/su14159222
ER  - 
@article{
author = "Tadić, Tamara and Marković, Bojana and Radulović, Jelena and Lukić, Jelena and Suručić, Ljiljana and Nastasović, Aleksandra and Onjia, Antonije",
year = "2022",
abstract = "A core-shell amino-functionalized glycidyl methacrylate magnetic molecularly imprinted polymer (MIP) was synthesized by the suspension polymerization/surface imprinting method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), mercury porosimetry, nitrogen gas adsorption–desorption, and elemental analysis. This MIP was used as the sorbent in dispersive solid-phase microextraction (DSPME) of aniline from textile wastewater prior to high-performance liquid chromatography-mass spectrometry (HPLC-MS) measurements. Since aniline is toxic and a probable human carcinogen, its determination in water is of great significance. This is a challenging task because aniline is usually present at trace levels. The effects of different DSPME variables on the preconcentration efficiency have been studied by using the Plackett–Burman screening design of experiments (DoE) followed by response surface methodology optimization using the Box-Behnken design. Thus, DoE enabled the investigation of several variables simultaneously. Under optimized conditions, aniline was effectively and selectively separated by a small amount of the DSPME sorbent and detected in real textile wastewater samples. The method detection limit of 1 ng mL−1 was attained, with good method linearity and acceptable recovery and precision. The results showed that the studied MIP could be a reliable DSPME sorbent for efficiently analyzing trace aniline in real wastewater samples.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Sustainability",
title = "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline",
volume = "14",
number = "15",
pages = "9222",
doi = "10.3390/su14159222"
}
Tadić, T., Marković, B., Radulović, J., Lukić, J., Suručić, L., Nastasović, A.,& Onjia, A.. (2022). A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline. in Sustainability
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 14(15), 9222.
https://doi.org/10.3390/su14159222
Tadić T, Marković B, Radulović J, Lukić J, Suručić L, Nastasović A, Onjia A. A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline. in Sustainability. 2022;14(15):9222.
doi:10.3390/su14159222 .
Tadić, Tamara, Marković, Bojana, Radulović, Jelena, Lukić, Jelena, Suručić, Ljiljana, Nastasović, Aleksandra, Onjia, Antonije, "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline" in Sustainability, 14, no. 15 (2022):9222,
https://doi.org/10.3390/su14159222 . .
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