Ćosović, Vladan

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Authority KeyName Variants
orcid::0000-0001-7644-4036
  • Ćosović, Vladan (114)
Projects
Advanced multicomponent metal systems and nanostructured materials with diverse functional properties Dizajniranje nanokristalnih magnetnih materijala tipa (Nd,Pr)FeB i komponenti na bazi smart magnetnih materijala
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission
AdCatFC - Advanced Catalysts for Low Temperature Fuel Cells: From Model System to Sustainable Catalysts Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies
Synthesis and characterization of novel functional polymers and polymeric nanocomposites Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200131 (University of Belgrade, Technical Faculty, Bor)
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Termodinamika i fazna ravnoteža lemnih materijala bez olova
Predefined functional properties polymer composite materials processes and equipment development Microbial diversity study and characterization of beneficial environmental microorganisms
Development of methodologies and devices for noise protection of urban envirnoment Grant Agency of the Czech Republic - GAP108/11/1350
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology Development of ecological knowledge-based advanced materials and technologies for multifuncional application
CEITEC from the Ministry of Education; Youth and Sports of the Czech Republic under the National Sustainability Programme II LQ1601 COST Action - MP0903
Czech Ministry of Education, Youth and Sports - 1M0512 Czech Ministry of Education, Youth and Sports - IM0512
Czech Ministry of Education, Youth and Sports under the Project 1M6198959201 and by the Czech Academy of Sciences under the Project V0Z20410507 "Electroconducting composite materials based on lignocellulose and copper powders prepared by constant and programmed current-voltage electrolysis regimes“ (ELBAKOM140283), Ministry of Science and Technology of the Republic of Srpska
European Regional Development Fund - CZ.1.05/1.1.00/02.0068 European Regional Development Fund through CEITEC-Central European Institute of Technology - CZ.1.05/1.1.00/02.0068
Horizon 2020 research and innovation programme under grant agreement No 870292 (BioICEP) info:eu-repo/grantAgreement/MESTD-2020/inst/200131/RS//
Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200042 (University of Belgrade, Institute of Molecular Genetics and Genetic Engineering) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)

Author's Bibliography

Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties

Gojgić-Cvijović, Gordana; Jakovljević, Dragica; Živković, Ljiljana S.; Ćosović, Vladan; Pavlović, Vladimir B.; Nikolić, Ivana; Maravić, Nikola; Dokić, Ljubica

(Elsevier, 2023)

TY  - JOUR
AU  - Gojgić-Cvijović, Gordana
AU  - Jakovljević, Dragica
AU  - Živković, Ljiljana S.
AU  - Ćosović, Vladan
AU  - Pavlović, Vladimir B.
AU  - Nikolić, Ivana
AU  - Maravić, Nikola
AU  - Dokić, Ljubica
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6560
AB  - In this study, levan from Bacillus licheniformis NS032 was modified in an aqueous medium by octenyl succinic
anhydride (OSA), and the properties of the obtained derivatives were studied. The maximum efficiency in the
synthesis reaction was achieved at 40 ◦C and a polysaccharide slurry concentration of 30 %. Increasing the
reagent concentration (2–10 %) led to an increase in the degree of substitution (0.016–0.048). Structures of
derivatives were confirmed by FTIR and NMR. Scanning electronic microscopy, thermogravimetry, and dynamic
light scattering analyses showed that the derivatives with degrees of substitution of 0.025 and 0.036 retained
levan’s porous structure and thermostability and showed better colloidal stability than the native polysaccharide.
The intrinsic viscosity of derivatives increased upon modification, while the surface tension of the 1 % solution
was lowered to 61 mN/m. Oil-in-water emulsions prepared with sunflower oil (10 % and 20 %) by mechanical
homogenization and 2 and 10 % derivatives in the continuous phase showed mean oil droplet sizes of 106–195
μm, while the distribution curves exhibited bimodal character. The studied derivatives have a good capacity to
stabilize emulsions, as they have a creaming index ranging from 73 % to 94 %. The OSA-modified levans could
have potential applications in new formulations of emulsion-based systems.
PB  - Elsevier
T2  - International Journal of Biological Macromolecules
T1  - Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties
VL  - 242
SP  - 124837
DO  - 10.1016/j.ijbiomac.2023.124837
ER  - 
@article{
author = "Gojgić-Cvijović, Gordana and Jakovljević, Dragica and Živković, Ljiljana S. and Ćosović, Vladan and Pavlović, Vladimir B. and Nikolić, Ivana and Maravić, Nikola and Dokić, Ljubica",
year = "2023",
abstract = "In this study, levan from Bacillus licheniformis NS032 was modified in an aqueous medium by octenyl succinic
anhydride (OSA), and the properties of the obtained derivatives were studied. The maximum efficiency in the
synthesis reaction was achieved at 40 ◦C and a polysaccharide slurry concentration of 30 %. Increasing the
reagent concentration (2–10 %) led to an increase in the degree of substitution (0.016–0.048). Structures of
derivatives were confirmed by FTIR and NMR. Scanning electronic microscopy, thermogravimetry, and dynamic
light scattering analyses showed that the derivatives with degrees of substitution of 0.025 and 0.036 retained
levan’s porous structure and thermostability and showed better colloidal stability than the native polysaccharide.
The intrinsic viscosity of derivatives increased upon modification, while the surface tension of the 1 % solution
was lowered to 61 mN/m. Oil-in-water emulsions prepared with sunflower oil (10 % and 20 %) by mechanical
homogenization and 2 and 10 % derivatives in the continuous phase showed mean oil droplet sizes of 106–195
μm, while the distribution curves exhibited bimodal character. The studied derivatives have a good capacity to
stabilize emulsions, as they have a creaming index ranging from 73 % to 94 %. The OSA-modified levans could
have potential applications in new formulations of emulsion-based systems.",
publisher = "Elsevier",
journal = "International Journal of Biological Macromolecules",
title = "Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties",
volume = "242",
pages = "124837",
doi = "10.1016/j.ijbiomac.2023.124837"
}
Gojgić-Cvijović, G., Jakovljević, D., Živković, L. S., Ćosović, V., Pavlović, V. B., Nikolić, I., Maravić, N.,& Dokić, L.. (2023). Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties. in International Journal of Biological Macromolecules
Elsevier., 242, 124837.
https://doi.org/10.1016/j.ijbiomac.2023.124837
Gojgić-Cvijović G, Jakovljević D, Živković LS, Ćosović V, Pavlović VB, Nikolić I, Maravić N, Dokić L. Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties. in International Journal of Biological Macromolecules. 2023;242:124837.
doi:10.1016/j.ijbiomac.2023.124837 .
Gojgić-Cvijović, Gordana, Jakovljević, Dragica, Živković, Ljiljana S., Ćosović, Vladan, Pavlović, Vladimir B., Nikolić, Ivana, Maravić, Nikola, Dokić, Ljubica, "Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties" in International Journal of Biological Macromolecules, 242 (2023):124837,
https://doi.org/10.1016/j.ijbiomac.2023.124837 . .
1
1

Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin

Ponjavić, Marijana; Malagurski, Ivana; Lazić, Jelena; Jeremić, Sanja; Pavlović, Vladimir; Prlainović, Nevena; Maksimović, Vesna; Ćosović, Vladan; Atanase, Leonard Ionut

(Switzerland : Multidisciplinary Digital Publishing Institute (MDPI), 2023)

TY  - JOUR
AU  - Ponjavić, Marijana
AU  - Malagurski, Ivana
AU  - Lazić, Jelena
AU  - Jeremić, Sanja
AU  - Pavlović, Vladimir
AU  - Prlainović, Nevena
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Atanase, Leonard Ionut
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5690
AB  - The quest for sustainable biomaterials with excellent biocompatibility and tailorable
properties has put polyhydroxyalkanoates (PHAs) into the research spotlight. However, high production
costs and the lack of bioactivity limit their market penetration. To address this, poly(3-
hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was combined with a bacterial pigment with strong
anticancer activity, prodigiosin (PG), to obtain functionally enhanced PHBV-based biomaterials. The
samples were produced in the form of films 115.6–118.8  m in thickness using the solvent casting
method. The effects of PG incorporation on the physical properties (morphology, biopolymer crystallinity
and thermal stability) and functionality of the obtained biomaterials were investigated. PG
has acted as a nucleating agent, in turn affecting the degree of crystallinity, thermal stability and
morphology of the films. All samples with PG had a more organized internal structure and higher
melting and degradation temperatures. The calculated degree of crystallinity of the PHBV copolymer
was 53%, while the PG1, PG3 and PG3 films had values of 64.0%, 63.9% and 69.2%, respectively.
Cytotoxicity studies have shown the excellent anticancer activity of films against HCT116 (colon
cancer) cells, thus advancing PHBV biomedical application potential.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - International Journal of Molecular Sciences
T1  - Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin
VL  - 24
SP  - 1906
DO  - 10.3390/ijms24031906
ER  - 
@article{
author = "Ponjavić, Marijana and Malagurski, Ivana and Lazić, Jelena and Jeremić, Sanja and Pavlović, Vladimir and Prlainović, Nevena and Maksimović, Vesna and Ćosović, Vladan and Atanase, Leonard Ionut",
year = "2023",
abstract = "The quest for sustainable biomaterials with excellent biocompatibility and tailorable
properties has put polyhydroxyalkanoates (PHAs) into the research spotlight. However, high production
costs and the lack of bioactivity limit their market penetration. To address this, poly(3-
hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was combined with a bacterial pigment with strong
anticancer activity, prodigiosin (PG), to obtain functionally enhanced PHBV-based biomaterials. The
samples were produced in the form of films 115.6–118.8  m in thickness using the solvent casting
method. The effects of PG incorporation on the physical properties (morphology, biopolymer crystallinity
and thermal stability) and functionality of the obtained biomaterials were investigated. PG
has acted as a nucleating agent, in turn affecting the degree of crystallinity, thermal stability and
morphology of the films. All samples with PG had a more organized internal structure and higher
melting and degradation temperatures. The calculated degree of crystallinity of the PHBV copolymer
was 53%, while the PG1, PG3 and PG3 films had values of 64.0%, 63.9% and 69.2%, respectively.
Cytotoxicity studies have shown the excellent anticancer activity of films against HCT116 (colon
cancer) cells, thus advancing PHBV biomedical application potential.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "International Journal of Molecular Sciences",
title = "Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin",
volume = "24",
pages = "1906",
doi = "10.3390/ijms24031906"
}
Ponjavić, M., Malagurski, I., Lazić, J., Jeremić, S., Pavlović, V., Prlainović, N., Maksimović, V., Ćosović, V.,& Atanase, L. I.. (2023). Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin. in International Journal of Molecular Sciences
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 24, 1906.
https://doi.org/10.3390/ijms24031906
Ponjavić M, Malagurski I, Lazić J, Jeremić S, Pavlović V, Prlainović N, Maksimović V, Ćosović V, Atanase LI. Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin. in International Journal of Molecular Sciences. 2023;24:1906.
doi:10.3390/ijms24031906 .
Ponjavić, Marijana, Malagurski, Ivana, Lazić, Jelena, Jeremić, Sanja, Pavlović, Vladimir, Prlainović, Nevena, Maksimović, Vesna, Ćosović, Vladan, Atanase, Leonard Ionut, "Advancing PHBV Biomedical Potential with the Incorporation of Bacterial Biopigment Prodigiosin" in International Journal of Molecular Sciences, 24 (2023):1906,
https://doi.org/10.3390/ijms24031906 . .
2
10

Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Maksimović, Vesna; Ćosović, Vladan; Nikolić, Nebojša D.; Krstajić Pajić, Mila; Rogan, Jelena

(Srpska akademija nauka i umetnosti, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
AU  - Krstajić Pajić, Mila
AU  - Rogan, Jelena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6327
AB  - Горивне ћелије са метанолом (DMFC) као горивом cу веома перспектпвни извори енергије за стационарне и преносиве електричне уређаје пре свега због своје високе ефикасности и ниске емисије загађујућих материја, ниске радне температуре, велике густине енергије, нетоксичних и еколошки прихватљивих карактеристика. Међутим, њихова шира комерцијална употреба ограничена је факторима као што су: високи трошкови племенитог метала у електрокатализатору (на пример, Pt) и лоша радна издржљивост, односно брза деградација катализатора. У овом раду је представљена активност електрооксидације метанола код PtSn, PtSnO2, PtZn и PtSnZn катализатора у киселој средини. Стабилне наночестице cу успешно синтетизоване модификованим полиол поступком уз помоћ микроталасне пећнице. Ефекти састава, степена легирања, величине и морфологије синтерованих честица на електрокаталитичку активност су испитивани СО стрипинг волтаметријом и реакцијом електрооксидације метанола. Добијени резултати указују на појачане каталитичке актигвности за реакцију оксидације метанола побољшану отпорност на инхибицију СО, након додавања Sn или  Zn у Pt катализатор.
PB  - Srpska akademija nauka i umetnosti
C3  - Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd
T1  - Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola
SP  - 18
EP  - 18
UR  - https://hdl.handle.net/21.15107/rcub_cer_6327
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Maksimović, Vesna and Ćosović, Vladan and Nikolić, Nebojša D. and Krstajić Pajić, Mila and Rogan, Jelena",
year = "2023",
abstract = "Горивне ћелије са метанолом (DMFC) као горивом cу веома перспектпвни извори енергије за стационарне и преносиве електричне уређаје пре свега због своје високе ефикасности и ниске емисије загађујућих материја, ниске радне температуре, велике густине енергије, нетоксичних и еколошки прихватљивих карактеристика. Међутим, њихова шира комерцијална употреба ограничена је факторима као што су: високи трошкови племенитог метала у електрокатализатору (на пример, Pt) и лоша радна издржљивост, односно брза деградација катализатора. У овом раду је представљена активност електрооксидације метанола код PtSn, PtSnO2, PtZn и PtSnZn катализатора у киселој средини. Стабилне наночестице cу успешно синтетизоване модификованим полиол поступком уз помоћ микроталасне пећнице. Ефекти састава, степена легирања, величине и морфологије синтерованих честица на електрокаталитичку активност су испитивани СО стрипинг волтаметријом и реакцијом електрооксидације метанола. Добијени резултати указују на појачане каталитичке актигвности за реакцију оксидације метанола побољшану отпорност на инхибицију СО, након додавања Sn или  Zn у Pt катализатор.",
publisher = "Srpska akademija nauka i umetnosti",
journal = "Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd",
title = "Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola",
pages = "18-18",
url = "https://hdl.handle.net/21.15107/rcub_cer_6327"
}
Stevanović, S., Milošević, D., Tripković, D., Maksimović, V., Ćosović, V., Nikolić, N. D., Krstajić Pajić, M.,& Rogan, J.. (2023). Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola. in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd
Srpska akademija nauka i umetnosti., 18-18.
https://hdl.handle.net/21.15107/rcub_cer_6327
Stevanović S, Milošević D, Tripković D, Maksimović V, Ćosović V, Nikolić ND, Krstajić Pajić M, Rogan J. Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola. in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd. 2023;:18-18.
https://hdl.handle.net/21.15107/rcub_cer_6327 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Maksimović, Vesna, Ćosović, Vladan, Nikolić, Nebojša D., Krstajić Pajić, Mila, Rogan, Jelena, "Platinski katalizatori na ugljeničnoj osnovi za efikasnu oksidaciju metanola" in Srpska akademija nauka i umetnosti: savremena stremljenja u elektrohemiji u procesu prelaska na obnovljive izvore energije, Knjiga izvoda, 05/06/2023, Beoograd (2023):18-18,
https://hdl.handle.net/21.15107/rcub_cer_6327 .

Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts

Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Maksimović, Vesna M.; Nikolić, Nebojša D.; Stevanović, Sanja

(Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala, 2023)

TY  - CONF
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna M.
AU  - Nikolić, Nebojša D.
AU  - Stevanović, Sanja
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6497
AB  - One of the most popular alternative sources of energy are direct methanol fuel cells (DMFCs) with platinum-based catalysts due to their non-toxicity, reduced emissions of hazardous pollutants and high energy density. However, significant challenges of the scientific community related to Pt catalysts are the high cost, depletable resources and formation of poisoning species i.e. CO, during the methanol oxidation reaction. To reduce the amount of expensive Pt and susceptibility of Pt to poisoning species and simultaneously improve its catalytic performance, recent studies are focusing on the synthesis of Pt alloys in which a certain amount of platinum is replaced with less expensive metals such as Ru, Sn, Ni, Cu, Rh and Co. The usage of carbon (Vulcan XC-72R) for catalyst support enables high dispersion of metal, high surface area and good electrical conductivity improving overall performances of DMFCs. In this work, PtZn/C and PtSnZn/C catalysts were synthesized by the microwave-assisted polyol method. The structure and morphology of the catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TG) and X-ray diffraction (XRD) analysis. The activity and stability of synthesized catalysts for methanol oxidation in 0.5 M sulfuric acid were investigated. It was demonstrated that the activity of the platinum catalysts was improved thanks to the synergistic effects caused by the addition of different metals, such are bifunctional and electronic effects.
PB  - Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala
C3  - Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
T1  - Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts
T1  - Elektrooksidacija metanola na binarnim i ternarnim platinskim katalizatorima na ugljeničnom nosaču
SP  - POSTER-169
EP  - POSTER-170
UR  - https://hdl.handle.net/21.15107/rcub_cer_6497
ER  - 
@conference{
author = "Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Maksimović, Vesna M. and Nikolić, Nebojša D. and Stevanović, Sanja",
year = "2023",
abstract = "One of the most popular alternative sources of energy are direct methanol fuel cells (DMFCs) with platinum-based catalysts due to their non-toxicity, reduced emissions of hazardous pollutants and high energy density. However, significant challenges of the scientific community related to Pt catalysts are the high cost, depletable resources and formation of poisoning species i.e. CO, during the methanol oxidation reaction. To reduce the amount of expensive Pt and susceptibility of Pt to poisoning species and simultaneously improve its catalytic performance, recent studies are focusing on the synthesis of Pt alloys in which a certain amount of platinum is replaced with less expensive metals such as Ru, Sn, Ni, Cu, Rh and Co. The usage of carbon (Vulcan XC-72R) for catalyst support enables high dispersion of metal, high surface area and good electrical conductivity improving overall performances of DMFCs. In this work, PtZn/C and PtSnZn/C catalysts were synthesized by the microwave-assisted polyol method. The structure and morphology of the catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TG) and X-ray diffraction (XRD) analysis. The activity and stability of synthesized catalysts for methanol oxidation in 0.5 M sulfuric acid were investigated. It was demonstrated that the activity of the platinum catalysts was improved thanks to the synergistic effects caused by the addition of different metals, such are bifunctional and electronic effects.",
publisher = "Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala",
journal = "Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia",
title = "Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts, Elektrooksidacija metanola na binarnim i ternarnim platinskim katalizatorima na ugljeničnom nosaču",
pages = "POSTER-169-POSTER-170",
url = "https://hdl.handle.net/21.15107/rcub_cer_6497"
}
Milošević, D., Tripković, D., Ćosović, V., Maksimović, V. M., Nikolić, N. D.,& Stevanović, S.. (2023). Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala., POSTER-169-POSTER-170.
https://hdl.handle.net/21.15107/rcub_cer_6497
Milošević D, Tripković D, Ćosović V, Maksimović VM, Nikolić ND, Stevanović S. Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia. 2023;:POSTER-169-POSTER-170.
https://hdl.handle.net/21.15107/rcub_cer_6497 .
Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Maksimović, Vesna M., Nikolić, Nebojša D., Stevanović, Sanja, "Methanol electrooxidation on carbon-supported binary and ternary platinum catalysts" in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia (2023):POSTER-169-POSTER-170,
https://hdl.handle.net/21.15107/rcub_cer_6497 .

Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Nikolić, Nebojša D.; Maksimović, Vesna

(Skopje : Society of chemists and technologists of Macedonia, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6745
AB  - In order to achieve widespread application of fuel cell technology, the
development of an efficient and economical catalyst is a crucial step. Reducing the
diameter of catalyst particles, producing particles with a specific orientation surface,
and alloying noble metals with less expensive metals are possible approaches to
improve catalyst performance. This study will be focused on novel ways for creating
PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are
methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn
nanoparticles were produced using the microwave assisted polyol method and were
supported on high surface area carbon Vulcan XC-72R material. The electrochemical
behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry,
chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine
the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission
electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were
used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the
benefits of microwave synthesis and carefully adjusted metal alloying.
PB  - Skopje : Society of chemists and technologists of Macedonia
C3  - Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
T1  - Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells
SP  - 132
EP  - 132
UR  - https://hdl.handle.net/21.15107/rcub_cer_6745
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Nikolić, Nebojša D. and Maksimović, Vesna",
year = "2023",
abstract = "In order to achieve widespread application of fuel cell technology, the
development of an efficient and economical catalyst is a crucial step. Reducing the
diameter of catalyst particles, producing particles with a specific orientation surface,
and alloying noble metals with less expensive metals are possible approaches to
improve catalyst performance. This study will be focused on novel ways for creating
PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are
methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn
nanoparticles were produced using the microwave assisted polyol method and were
supported on high surface area carbon Vulcan XC-72R material. The electrochemical
behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry,
chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine
the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission
electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were
used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the
benefits of microwave synthesis and carefully adjusted metal alloying.",
publisher = "Skopje : Society of chemists and technologists of Macedonia",
journal = "Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia",
title = "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells",
pages = "132-132",
url = "https://hdl.handle.net/21.15107/rcub_cer_6745"
}
Stevanović, S., Milošević, D., Tripković, D., Ćosović, V., Nikolić, N. D.,& Maksimović, V.. (2023). Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia
Skopje : Society of chemists and technologists of Macedonia., 132-132.
https://hdl.handle.net/21.15107/rcub_cer_6745
Stevanović S, Milošević D, Tripković D, Ćosović V, Nikolić ND, Maksimović V. Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia. 2023;:132-132.
https://hdl.handle.net/21.15107/rcub_cer_6745 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Nikolić, Nebojša D., Maksimović, Vesna, "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells" in Book of abstracts - 26th Congress of Chemists and Technologysts of Macedonia, 20–23 September 2023, Metropol Lake Resort Ohrid, N. Macedonia (2023):132-132,
https://hdl.handle.net/21.15107/rcub_cer_6745 .

The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction

Milošević, Dragana; Stevanović, Sanja; Nikolić, Nebojša D.; Tripković, Dušan; Vukašinović, Ivana; Ćosović, Vladan; Nikolić, Nebojša D.

(Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine, 2023)

TY  - CONF
AU  - Milošević, Dragana
AU  - Stevanović, Sanja
AU  - Nikolić, Nebojša D.
AU  - Tripković, Dušan
AU  - Vukašinović, Ivana
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6790
AB  - This work highlights a simple and efficient approach for the development of
PtZn catalyst materials with tunable content of Zn. Nanoparticles of PtZn
deposited on high surface area carbon Vulcan XC-72R material were
synthesized by microwave-assisted polyol method, giving control over the size
and dispersion of nanoparticles. Cyclic voltammetry and electrooxidation of
adsorbed CO were used to investigate the electrochemical behavior of
synthesized catalysts: PtZn/C (90:10); PtZn/C (85:15) and PtZn/C (75:25). It
was found that PtZn/C catalysts have high electrocatalytic performance in
methanol oxidation reactions. In comparison to the corresponding catalyst with
the different Zn loading, it was concluded that PtZn (90:10)/C catalyst had
better activity compared to PtZn/C (85:15) and PtZn/C (75:25) catalysts. The
observed high catalytic activity in the methanol oxidation reaction of
synthesized catalysts can be ascribed to the very efficient microwave synthesis
and well-balanced content of Zn as alloying metal.
AB  - Ovaj rad predstavlja jednostavan i efikasan pristup za razvoj PtZn katalizatora sa različitim sadržajem Zn. Nanočestice PtZn istaložene na ugljeničnom materijalu Vulcan XC-72R velike površine, sintetisane su poliol metodom pomoću mikrotalasne pećnice, dajući kontrolu nad veličinom i disperzijom nanočestica. Za ispitivanje elektrohemijskog ponašanja sintetisanih katalizatora PtZn/C (90:10); PtZn/C (85:15) i PtZn/C (75:25) korišćeni su ciklična voltametrija i elektrooksidacija adsorbovanog CO. Utvrđeno je da PtZn/C katalizatori imaju visoke elektrokatalitičke performanse u reakcijama oksidacije metanola. Poređenjem katalizatora sa različitim sadržajem Zn, zaključeno je da PtZn/C (90:10) katalizator ima bolju aktivnost u odnosu na PtZn (85:15) i PtZn (75:25) katalizatore. Uočena visoka katalitička aktivnost sintetisanih katalizatora u reakciji oksidacije metanola može se pripisati veoma efikasnoj mikrotalasnoj sintezi i dobro izbalansiranom dodavanju Zn kao legirajućeg metala sa različitim sadržajem u PtZn/C katalizatorima.
PB  - Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine
C3  - 5th International symposium on corrosion and materials protection, environmental protection and protection against fire, Proceedings, 26-29. September 2023, Bar / Peti međunarodni simpozijum o koroziji i zaštiti materijala, životnoj sredini i zaštiti od požara, knjiga radova, 26-29. septembar 2023 godine, Bar
T1  - The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction
T1  - Uticaj sadržaja Zn na aktivnost PtZn katalizatora u reakciji elektrooksidacije metanola
SP  - 49
EP  - 56
UR  - https://hdl.handle.net/21.15107/rcub_cer_6790
ER  - 
@conference{
author = "Milošević, Dragana and Stevanović, Sanja and Nikolić, Nebojša D. and Tripković, Dušan and Vukašinović, Ivana and Ćosović, Vladan and Nikolić, Nebojša D.",
year = "2023",
abstract = "This work highlights a simple and efficient approach for the development of
PtZn catalyst materials with tunable content of Zn. Nanoparticles of PtZn
deposited on high surface area carbon Vulcan XC-72R material were
synthesized by microwave-assisted polyol method, giving control over the size
and dispersion of nanoparticles. Cyclic voltammetry and electrooxidation of
adsorbed CO were used to investigate the electrochemical behavior of
synthesized catalysts: PtZn/C (90:10); PtZn/C (85:15) and PtZn/C (75:25). It
was found that PtZn/C catalysts have high electrocatalytic performance in
methanol oxidation reactions. In comparison to the corresponding catalyst with
the different Zn loading, it was concluded that PtZn (90:10)/C catalyst had
better activity compared to PtZn/C (85:15) and PtZn/C (75:25) catalysts. The
observed high catalytic activity in the methanol oxidation reaction of
synthesized catalysts can be ascribed to the very efficient microwave synthesis
and well-balanced content of Zn as alloying metal., Ovaj rad predstavlja jednostavan i efikasan pristup za razvoj PtZn katalizatora sa različitim sadržajem Zn. Nanočestice PtZn istaložene na ugljeničnom materijalu Vulcan XC-72R velike površine, sintetisane su poliol metodom pomoću mikrotalasne pećnice, dajući kontrolu nad veličinom i disperzijom nanočestica. Za ispitivanje elektrohemijskog ponašanja sintetisanih katalizatora PtZn/C (90:10); PtZn/C (85:15) i PtZn/C (75:25) korišćeni su ciklična voltametrija i elektrooksidacija adsorbovanog CO. Utvrđeno je da PtZn/C katalizatori imaju visoke elektrokatalitičke performanse u reakcijama oksidacije metanola. Poređenjem katalizatora sa različitim sadržajem Zn, zaključeno je da PtZn/C (90:10) katalizator ima bolju aktivnost u odnosu na PtZn (85:15) i PtZn (75:25) katalizatore. Uočena visoka katalitička aktivnost sintetisanih katalizatora u reakciji oksidacije metanola može se pripisati veoma efikasnoj mikrotalasnoj sintezi i dobro izbalansiranom dodavanju Zn kao legirajućeg metala sa različitim sadržajem u PtZn/C katalizatorima.",
publisher = "Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine",
journal = "5th International symposium on corrosion and materials protection, environmental protection and protection against fire, Proceedings, 26-29. September 2023, Bar / Peti međunarodni simpozijum o koroziji i zaštiti materijala, životnoj sredini i zaštiti od požara, knjiga radova, 26-29. septembar 2023 godine, Bar",
title = "The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction, Uticaj sadržaja Zn na aktivnost PtZn katalizatora u reakciji elektrooksidacije metanola",
pages = "49-56",
url = "https://hdl.handle.net/21.15107/rcub_cer_6790"
}
Milošević, D., Stevanović, S., Nikolić, N. D., Tripković, D., Vukašinović, I., Ćosović, V.,& Nikolić, N. D.. (2023). The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction. in 5th International symposium on corrosion and materials protection, environmental protection and protection against fire, Proceedings, 26-29. September 2023, Bar / Peti međunarodni simpozijum o koroziji i zaštiti materijala, životnoj sredini i zaštiti od požara, knjiga radova, 26-29. septembar 2023 godine, Bar
Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine., 49-56.
https://hdl.handle.net/21.15107/rcub_cer_6790
Milošević D, Stevanović S, Nikolić ND, Tripković D, Vukašinović I, Ćosović V, Nikolić ND. The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction. in 5th International symposium on corrosion and materials protection, environmental protection and protection against fire, Proceedings, 26-29. September 2023, Bar / Peti međunarodni simpozijum o koroziji i zaštiti materijala, životnoj sredini i zaštiti od požara, knjiga radova, 26-29. septembar 2023 godine, Bar. 2023;:49-56.
https://hdl.handle.net/21.15107/rcub_cer_6790 .
Milošević, Dragana, Stevanović, Sanja, Nikolić, Nebojša D., Tripković, Dušan, Vukašinović, Ivana, Ćosović, Vladan, Nikolić, Nebojša D., "The influence of Zn content on the activity of PtZn catalysts in methanol electrooxidation reaction" in 5th International symposium on corrosion and materials protection, environmental protection and protection against fire, Proceedings, 26-29. September 2023, Bar / Peti međunarodni simpozijum o koroziji i zaštiti materijala, životnoj sredini i zaštiti od požara, knjiga radova, 26-29. septembar 2023 godine, Bar (2023):49-56,
https://hdl.handle.net/21.15107/rcub_cer_6790 .

Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Maksimović, Vesna M.; Nikolić, Nebojša D.

(Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna M.
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6496
AB  - Polymer electrolyte membrane fuel cells (PEMFCs) are pure electrochemical energy converters that are key components of energy sources for vehicles and for stationary and portable energy suppliers. Searching for a good catalyst for the ethanol oxidation reaction is one of the most significant issues in material science. To increase the economic potential of fuel cell technology, catalyst must be extremely active, stable, and inexpensive. Due to its high catalytic activity, structural and chemical stability, and widespread use in commercial fuel cells, platinum is still the material of choice for making cathodes. Although there is extensive continuing research to reduce the Pt concentration while keeping the high catalytic activity, its high cost remains a barrier to a wider adoption of fuel cell technology.Therefore, the potential for cost reduction lies in the optimization of the catalyst, i.e. obtaining the maximum catalytic efficiency with the lowest possible content of noble metals. The focus of this research will be on novel synthesis techniques for PtSnZn catalysts with better efficiency and durability for the ethanol oxidation reaction. This research demonstrates the potential of studying new PtSnZn catalytic materials as catalysts for the oxidation of ethanol. This study used the microwave assisted polyol technique to create PtZn and PtSnZn nanoparticles supported on high surface area carbon Vulcan XC-72R material. By using cyclic voltammetry, electro-oxidation of adsorbed CO, and the chronoamperometric method, the electrochemical behavior of synthesized catalysts was examined. X-ray diffractometry, transmission electron microscopy analysis and thermogravimetric analysis were applied to obtain the physicochemical properties of the catalyst. The advantages of microwave synthesis and carefully balanced metal alloying in the PtSnZn/C catalysts led to a high catalytic activity of the synthesized catalyst in the ethanol oxidation reaction compared to the Pt/C catalyst.
PB  - Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala
C3  - Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
T1  - Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction
T1  - Promotivni efekat Zn u platinskom katalizatoru za efikasnu reakciju elektrooksidacije etanola
SP  - POSTER-102
EP  - POSTER-103
UR  - https://hdl.handle.net/21.15107/rcub_cer_6496
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Maksimović, Vesna M. and Nikolić, Nebojša D.",
year = "2023",
abstract = "Polymer electrolyte membrane fuel cells (PEMFCs) are pure electrochemical energy converters that are key components of energy sources for vehicles and for stationary and portable energy suppliers. Searching for a good catalyst for the ethanol oxidation reaction is one of the most significant issues in material science. To increase the economic potential of fuel cell technology, catalyst must be extremely active, stable, and inexpensive. Due to its high catalytic activity, structural and chemical stability, and widespread use in commercial fuel cells, platinum is still the material of choice for making cathodes. Although there is extensive continuing research to reduce the Pt concentration while keeping the high catalytic activity, its high cost remains a barrier to a wider adoption of fuel cell technology.Therefore, the potential for cost reduction lies in the optimization of the catalyst, i.e. obtaining the maximum catalytic efficiency with the lowest possible content of noble metals. The focus of this research will be on novel synthesis techniques for PtSnZn catalysts with better efficiency and durability for the ethanol oxidation reaction. This research demonstrates the potential of studying new PtSnZn catalytic materials as catalysts for the oxidation of ethanol. This study used the microwave assisted polyol technique to create PtZn and PtSnZn nanoparticles supported on high surface area carbon Vulcan XC-72R material. By using cyclic voltammetry, electro-oxidation of adsorbed CO, and the chronoamperometric method, the electrochemical behavior of synthesized catalysts was examined. X-ray diffractometry, transmission electron microscopy analysis and thermogravimetric analysis were applied to obtain the physicochemical properties of the catalyst. The advantages of microwave synthesis and carefully balanced metal alloying in the PtSnZn/C catalysts led to a high catalytic activity of the synthesized catalyst in the ethanol oxidation reaction compared to the Pt/C catalyst.",
publisher = "Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala",
journal = "Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia",
title = "Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction, Promotivni efekat Zn u platinskom katalizatoru za efikasnu reakciju elektrooksidacije etanola",
pages = "POSTER-102-POSTER-103",
url = "https://hdl.handle.net/21.15107/rcub_cer_6496"
}
Stevanović, S., Milošević, D., Tripković, D., Ćosović, V., Maksimović, V. M.,& Nikolić, N. D.. (2023). Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia
Serbian society of corrosion and materials protection (UISKoZaM) / Udruženje inženjera Srbije za koroziju i zaštitu materijala., POSTER-102-POSTER-103.
https://hdl.handle.net/21.15107/rcub_cer_6496
Stevanović S, Milošević D, Tripković D, Ćosović V, Maksimović VM, Nikolić ND. Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction. in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia. 2023;:POSTER-102-POSTER-103.
https://hdl.handle.net/21.15107/rcub_cer_6496 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Maksimović, Vesna M., Nikolić, Nebojša D., "Promoting effect of Zn in platinum catalyst for effective methanol electrooxidation reaction" in Proceedings - XXIV YuCorr International Conference, Meeting Point of the Science and Practice in the Fields of Corrosion, Materials and Environmental Protection, May 28-31, 2023, Divčibare, Serbia (2023):POSTER-102-POSTER-103,
https://hdl.handle.net/21.15107/rcub_cer_6496 .

Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers

Putić, Lana; Stajić-Trošić, Jasna; Ćosović, Vladan; Grujić, Aleksandar; Milanović, Jovana; Pilić, Branka; Stanković, Snežana

(Taylor and Francis, 2023)

TY  - JOUR
AU  - Putić, Lana
AU  - Stajić-Trošić, Jasna
AU  - Ćosović, Vladan
AU  - Grujić, Aleksandar
AU  - Milanović, Jovana
AU  - Pilić, Branka
AU  - Stanković, Snežana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5252
AB  - This study investigates the effect of surface modification by deposition of electrospun fibers on properties and performance of three different microporous polypropylene/polyethylene (PP/PE) commercial nonwoven membrane supports (Novatexx 2430, 2465 and 2473). Polyamide (nylon 6) nanofiber webs with a small number of defects and fibers of about 100 nanometer diameter were successfully deposited onto a surface of the selected membrane supports. FESEM was used to examine microstructure and morphology of the unmodified substrates and the prepared composite two-layer membranes. DSC was applied to investigate thermal stability and FT-IR analysis to confirm the chemical composition of the studied membranes. Saline water permeability tests of the prepared two-layer composite membranes were carried out. The largest pressure difference was measured for PA nanofiber/Novatexx 2430 sample, which was ascribed to a denser net structure of the membrane support and possibly to the newly formed layer of dissolved salts on the membrane surface.
PB  - Taylor and Francis
T2  - Journal of the Textile Institute
T1  - Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers
VL  - 114
IS  - 1
SP  - 110
EP  - 121
DO  - 10.1080/00405000.2021.2024343
ER  - 
@article{
author = "Putić, Lana and Stajić-Trošić, Jasna and Ćosović, Vladan and Grujić, Aleksandar and Milanović, Jovana and Pilić, Branka and Stanković, Snežana",
year = "2023",
abstract = "This study investigates the effect of surface modification by deposition of electrospun fibers on properties and performance of three different microporous polypropylene/polyethylene (PP/PE) commercial nonwoven membrane supports (Novatexx 2430, 2465 and 2473). Polyamide (nylon 6) nanofiber webs with a small number of defects and fibers of about 100 nanometer diameter were successfully deposited onto a surface of the selected membrane supports. FESEM was used to examine microstructure and morphology of the unmodified substrates and the prepared composite two-layer membranes. DSC was applied to investigate thermal stability and FT-IR analysis to confirm the chemical composition of the studied membranes. Saline water permeability tests of the prepared two-layer composite membranes were carried out. The largest pressure difference was measured for PA nanofiber/Novatexx 2430 sample, which was ascribed to a denser net structure of the membrane support and possibly to the newly formed layer of dissolved salts on the membrane surface.",
publisher = "Taylor and Francis",
journal = "Journal of the Textile Institute",
title = "Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers",
volume = "114",
number = "1",
pages = "110-121",
doi = "10.1080/00405000.2021.2024343"
}
Putić, L., Stajić-Trošić, J., Ćosović, V., Grujić, A., Milanović, J., Pilić, B.,& Stanković, S.. (2023). Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers. in Journal of the Textile Institute
Taylor and Francis., 114(1), 110-121.
https://doi.org/10.1080/00405000.2021.2024343
Putić L, Stajić-Trošić J, Ćosović V, Grujić A, Milanović J, Pilić B, Stanković S. Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers. in Journal of the Textile Institute. 2023;114(1):110-121.
doi:10.1080/00405000.2021.2024343 .
Putić, Lana, Stajić-Trošić, Jasna, Ćosović, Vladan, Grujić, Aleksandar, Milanović, Jovana, Pilić, Branka, Stanković, Snežana, "Characterization of microporous PP/PE nonwoven mats surface modified by deposition of electrospun nanofibers" in Journal of the Textile Institute, 114, no. 1 (2023):110-121,
https://doi.org/10.1080/00405000.2021.2024343 . .
1
1

Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements

Radojković, Bojana; Jegdić, Bore; Marunkić, Dunja; Pejić, Jovanka; Simović, Anđela; Ćosović, Vladan; Bajat, Jelena

(Springer Nature, 2023)

TY  - JOUR
AU  - Radojković, Bojana
AU  - Jegdić, Bore
AU  - Marunkić, Dunja
AU  - Pejić, Jovanka
AU  - Simović, Anđela
AU  - Ćosović, Vladan
AU  - Bajat, Jelena
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6938
AB  - This paper examined the degree of sensitization (DOS) to intergranular corrosion (IGC) and the level of electrical conductivity of the welded and non-welded AISI 304 stainless steel to obtain a suitable correlation. The DOS was determined by the double loop electrochemical potentiokinetic reactivation method (DL EPR), while the level of electrical conductivity was measured using a commercial device (non-destructive method). After electrochemical etching in oxalic acid, the microstructure of the specimen surface was analyzed by scanning electron microscopy (SEM). At DOS greater than ~ 0.5%, a clear linear dependence between the electrical conductivity and the value of the DOS was obtained, while there was a higher deviation from linearity for lower DOS values. The mentioned correlations were discussed in the sense of the precipitation kinetics of the Cr-carbide and the formation of Cr-depleted areas of different levels near the grain boundaries. Cr-depleted areas during anodic polarization measurements show lower resistance to pit formation. The presence of Cr-depleted areas in the vicinity of grain boundaries and the reduction of carbon content in the austenite crystal lattice increases the electrical conductivity of the stainless steel.
PB  - Springer Nature
PB  - The Korean Institute of Metals and Materials
T2  - Metals and Materials International
T1  - Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements
DO  - https://doi.org/10.1007/s12540-023-01536-1
ER  - 
@article{
author = "Radojković, Bojana and Jegdić, Bore and Marunkić, Dunja and Pejić, Jovanka and Simović, Anđela and Ćosović, Vladan and Bajat, Jelena",
year = "2023",
abstract = "This paper examined the degree of sensitization (DOS) to intergranular corrosion (IGC) and the level of electrical conductivity of the welded and non-welded AISI 304 stainless steel to obtain a suitable correlation. The DOS was determined by the double loop electrochemical potentiokinetic reactivation method (DL EPR), while the level of electrical conductivity was measured using a commercial device (non-destructive method). After electrochemical etching in oxalic acid, the microstructure of the specimen surface was analyzed by scanning electron microscopy (SEM). At DOS greater than ~ 0.5%, a clear linear dependence between the electrical conductivity and the value of the DOS was obtained, while there was a higher deviation from linearity for lower DOS values. The mentioned correlations were discussed in the sense of the precipitation kinetics of the Cr-carbide and the formation of Cr-depleted areas of different levels near the grain boundaries. Cr-depleted areas during anodic polarization measurements show lower resistance to pit formation. The presence of Cr-depleted areas in the vicinity of grain boundaries and the reduction of carbon content in the austenite crystal lattice increases the electrical conductivity of the stainless steel.",
publisher = "Springer Nature, The Korean Institute of Metals and Materials",
journal = "Metals and Materials International",
title = "Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements",
doi = "https://doi.org/10.1007/s12540-023-01536-1"
}
Radojković, B., Jegdić, B., Marunkić, D., Pejić, J., Simović, A., Ćosović, V.,& Bajat, J.. (2023). Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements. in Metals and Materials International
Springer Nature..
https://doi.org/https://doi.org/10.1007/s12540-023-01536-1
Radojković B, Jegdić B, Marunkić D, Pejić J, Simović A, Ćosović V, Bajat J. Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements. in Metals and Materials International. 2023;.
doi:https://doi.org/10.1007/s12540-023-01536-1 .
Radojković, Bojana, Jegdić, Bore, Marunkić, Dunja, Pejić, Jovanka, Simović, Anđela, Ćosović, Vladan, Bajat, Jelena, "Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements" in Metals and Materials International (2023),
https://doi.org/https://doi.org/10.1007/s12540-023-01536-1 . .

Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction

Milošević, Dragana; Stevanović, Sanja; Tripković, Dušan; Vukašinović, Ivana; Maksimović, Vesna; Ćosović, Vladan; Nikolić, Nebojša D.

(MDPI, 2023)

TY  - JOUR
AU  - Milošević, Dragana
AU  - Stevanović, Sanja
AU  - Tripković, Dušan
AU  - Vukašinović, Ivana
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6313
AB  - This work highlights the potential for the synthesis of new PtSnZn catalysts with enhanced efficiency and durability for methanol oxidation reaction (MOR) in low-temperature fuel cells. In this research, PtZn and PtSnZn nanoparticles deposited on high surface area Vulcan XC-72R Carbon support were created by a microwave-assisted polyol method. The electrochemical performances of synthesized catalysts were analyzed by cyclic voltammetry and by the electrooxidation of adsorbed CO and the chronoamperometric method. The physicochemical properties of obtained catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TGA) analysis, energy dispersive spectroscopy (EDS) and by X-ray diffraction (XRD). The obtained findings showed the successful synthesis of platinum-based catalysts. It was established that PtSnZn/C and PtZn/C catalysts have high electrocatalytic performance in methanol oxidation reactions. Catalysts stability tests were obtained by chronoamperometry. Stability tests also confirmed decreased poisoning and indicated improved stability and better tolerance to CO-like intermediate species. According to activity and stability measurements, the PtSnZn/C catalyst possesses the best electrochemical properties for the methanol oxidation reaction. The observed great electrocatalytic activity in the methanol oxidation reaction of synthesized catalysts can be attributed to the beneficial effects of microwave synthesis and the well-balanced addition of alloying metals in PtSnZn/C catalysts.
PB  - MDPI
T2  - Materials
T1  - Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction
VL  - 16
IS  - 13
SP  - 4617
DO  - https://doi.org/10.3390/ma16134617
ER  - 
@article{
author = "Milošević, Dragana and Stevanović, Sanja and Tripković, Dušan and Vukašinović, Ivana and Maksimović, Vesna and Ćosović, Vladan and Nikolić, Nebojša D.",
year = "2023",
abstract = "This work highlights the potential for the synthesis of new PtSnZn catalysts with enhanced efficiency and durability for methanol oxidation reaction (MOR) in low-temperature fuel cells. In this research, PtZn and PtSnZn nanoparticles deposited on high surface area Vulcan XC-72R Carbon support were created by a microwave-assisted polyol method. The electrochemical performances of synthesized catalysts were analyzed by cyclic voltammetry and by the electrooxidation of adsorbed CO and the chronoamperometric method. The physicochemical properties of obtained catalysts were characterized by transmission electron microscopy (TEM), thermogravimetric (TGA) analysis, energy dispersive spectroscopy (EDS) and by X-ray diffraction (XRD). The obtained findings showed the successful synthesis of platinum-based catalysts. It was established that PtSnZn/C and PtZn/C catalysts have high electrocatalytic performance in methanol oxidation reactions. Catalysts stability tests were obtained by chronoamperometry. Stability tests also confirmed decreased poisoning and indicated improved stability and better tolerance to CO-like intermediate species. According to activity and stability measurements, the PtSnZn/C catalyst possesses the best electrochemical properties for the methanol oxidation reaction. The observed great electrocatalytic activity in the methanol oxidation reaction of synthesized catalysts can be attributed to the beneficial effects of microwave synthesis and the well-balanced addition of alloying metals in PtSnZn/C catalysts.",
publisher = "MDPI",
journal = "Materials",
title = "Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction",
volume = "16",
number = "13",
pages = "4617",
doi = "https://doi.org/10.3390/ma16134617"
}
Milošević, D., Stevanović, S., Tripković, D., Vukašinović, I., Maksimović, V., Ćosović, V.,& Nikolić, N. D.. (2023). Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction. in Materials
MDPI., 16(13), 4617.
https://doi.org/https://doi.org/10.3390/ma16134617
Milošević D, Stevanović S, Tripković D, Vukašinović I, Maksimović V, Ćosović V, Nikolić ND. Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction. in Materials. 2023;16(13):4617.
doi:https://doi.org/10.3390/ma16134617 .
Milošević, Dragana, Stevanović, Sanja, Tripković, Dušan, Vukašinović, Ivana, Maksimović, Vesna, Ćosović, Vladan, Nikolić, Nebojša D., "Design of Pt-Sn-Zn Nanomaterials for Successful Methanol Electrooxidation Reaction" in Materials, 16, no. 13 (2023):4617,
https://doi.org/https://doi.org/10.3390/ma16134617 . .

Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation

Ponjavić, Marijana; Stevanović, Sanja; Nikodinović-Runić, Jasmina; Jeremić, Sanja; Ćosović, Vladan; Maksimović, Vesna

(Elsevier BV, 2022)

TY  - JOUR
AU  - Ponjavić, Marijana
AU  - Stevanović, Sanja
AU  - Nikodinović-Runić, Jasmina
AU  - Jeremić, Sanja
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5573
AB  - Bacterial nanocellulose, BNC, has emerged as a new class of nanomaterials recognized as renewable, biodegradable, biocompatible and material for versatile applications. BNC also proved as a perfect support matrix for metallic nanoparticle synthesis and appeared as suitable alternative for widely used carbon based materials. Following the idea to replace commonly used carbon based materials for platinum supports with the green and sustainable one, BNC appeared as an excellent candidate. Herein, microwave assisted synthesis has been reported for the first time for platinum nanoparticles supported on BNC as green material. Bacterial nanocelullose-platinum catalyst, Pt/BNC, was investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), atomic force microscopy (AFM), X-ray diffractometry (XRD) and transmission-electron microscopy (TEM) analysis. The obtained results confirmed successful synthesis of new Pt-based catalyst. It was found that Pt/BNC catalyst has high electrocatalytic performance in methanol oxidation reaction. Green/sustainable catalytic system is highly desirable and provided by the elegant microwave assisted synthesis of Pt/BNC will pave the way for a larger scale application and expedite the market penetration of such fuel cells.
PB  - Elsevier BV
T2  - International Journal of Biological Macromolecules
T1  - Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation
VL  - 223
SP  - 1474
EP  - 1484
DO  - 10.1016/j.ijbiomac.2022.10.278
ER  - 
@article{
author = "Ponjavić, Marijana and Stevanović, Sanja and Nikodinović-Runić, Jasmina and Jeremić, Sanja and Ćosović, Vladan and Maksimović, Vesna",
year = "2022",
abstract = "Bacterial nanocellulose, BNC, has emerged as a new class of nanomaterials recognized as renewable, biodegradable, biocompatible and material for versatile applications. BNC also proved as a perfect support matrix for metallic nanoparticle synthesis and appeared as suitable alternative for widely used carbon based materials. Following the idea to replace commonly used carbon based materials for platinum supports with the green and sustainable one, BNC appeared as an excellent candidate. Herein, microwave assisted synthesis has been reported for the first time for platinum nanoparticles supported on BNC as green material. Bacterial nanocelullose-platinum catalyst, Pt/BNC, was investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), atomic force microscopy (AFM), X-ray diffractometry (XRD) and transmission-electron microscopy (TEM) analysis. The obtained results confirmed successful synthesis of new Pt-based catalyst. It was found that Pt/BNC catalyst has high electrocatalytic performance in methanol oxidation reaction. Green/sustainable catalytic system is highly desirable and provided by the elegant microwave assisted synthesis of Pt/BNC will pave the way for a larger scale application and expedite the market penetration of such fuel cells.",
publisher = "Elsevier BV",
journal = "International Journal of Biological Macromolecules",
title = "Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation",
volume = "223",
pages = "1474-1484",
doi = "10.1016/j.ijbiomac.2022.10.278"
}
Ponjavić, M., Stevanović, S., Nikodinović-Runić, J., Jeremić, S., Ćosović, V.,& Maksimović, V.. (2022). Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation. in International Journal of Biological Macromolecules
Elsevier BV., 223, 1474-1484.
https://doi.org/10.1016/j.ijbiomac.2022.10.278
Ponjavić M, Stevanović S, Nikodinović-Runić J, Jeremić S, Ćosović V, Maksimović V. Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation. in International Journal of Biological Macromolecules. 2022;223:1474-1484.
doi:10.1016/j.ijbiomac.2022.10.278 .
Ponjavić, Marijana, Stevanović, Sanja, Nikodinović-Runić, Jasmina, Jeremić, Sanja, Ćosović, Vladan, Maksimović, Vesna, "Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation" in International Journal of Biological Macromolecules, 223 (2022):1474-1484,
https://doi.org/10.1016/j.ijbiomac.2022.10.278 . .
3
2
3

Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support

Ponjavić, Marijana; Stevanović, Sanja; Jeremić, Sanja; Nikodinović-Runić, Jasmina; Ćosović, Vladan; Maksimović, Vesna

(Banja Luka : University in Banjaluka, Faculty of Technology, 2022)

TY  - CONF
AU  - Ponjavić, Marijana
AU  - Stevanović, Sanja
AU  - Jeremić, Sanja
AU  - Nikodinović-Runić, Jasmina
AU  - Ćosović, Vladan
AU  - Maksimović, Vesna
PY  - 2022
UR  - https://savjetovanje.tf.unibl.org/home/digital-library/book-of-abstracts/
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5939
AB  - The main objective of this work was to prepare new platinum supported catalyst on BNC/PVA composite as nanoparticles carrier, designed for electrocatalytic applications. For that purpose, BNC/Pt suspension was mixed with 1 wt% PVA solution and BNC/PVA/Pt catalyst in the form of film was successfully synthesized. The structure and thermal properties of catalyst were characterized by ATR-FTIR and TG analysis, respectively, while its crystallinity was investigated 
by XRD analysis. Electrocatalytic potential of BNC/PVA/Pt catalyst was tested in methanol 
oxidation reaction. Remarkable catalytic activity of new Pt based catalyst was confirmed. The 
obtained results for catalyst activity was comparable to those obtained for preferentially used 
carbon based Pt supports pointing that BNC based composited can be considered as great 
substitution of carbon based materials with the green one.
PB  - Banja Luka : University in Banjaluka, Faculty of Technology
C3  - Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
T1  - Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support
SP  - 33
EP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_cer_5939
ER  - 
@conference{
author = "Ponjavić, Marijana and Stevanović, Sanja and Jeremić, Sanja and Nikodinović-Runić, Jasmina and Ćosović, Vladan and Maksimović, Vesna",
year = "2022",
abstract = "The main objective of this work was to prepare new platinum supported catalyst on BNC/PVA composite as nanoparticles carrier, designed for electrocatalytic applications. For that purpose, BNC/Pt suspension was mixed with 1 wt% PVA solution and BNC/PVA/Pt catalyst in the form of film was successfully synthesized. The structure and thermal properties of catalyst were characterized by ATR-FTIR and TG analysis, respectively, while its crystallinity was investigated 
by XRD analysis. Electrocatalytic potential of BNC/PVA/Pt catalyst was tested in methanol 
oxidation reaction. Remarkable catalytic activity of new Pt based catalyst was confirmed. The 
obtained results for catalyst activity was comparable to those obtained for preferentially used 
carbon based Pt supports pointing that BNC based composited can be considered as great 
substitution of carbon based materials with the green one.",
publisher = "Banja Luka : University in Banjaluka, Faculty of Technology",
journal = "Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka",
title = "Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support",
pages = "33-33",
url = "https://hdl.handle.net/21.15107/rcub_cer_5939"
}
Ponjavić, M., Stevanović, S., Jeremić, S., Nikodinović-Runić, J., Ćosović, V.,& Maksimović, V.. (2022). Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support. in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka
Banja Luka : University in Banjaluka, Faculty of Technology., 33-33.
https://hdl.handle.net/21.15107/rcub_cer_5939
Ponjavić M, Stevanović S, Jeremić S, Nikodinović-Runić J, Ćosović V, Maksimović V. Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support. in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka. 2022;:33-33.
https://hdl.handle.net/21.15107/rcub_cer_5939 .
Ponjavić, Marijana, Stevanović, Sanja, Jeremić, Sanja, Nikodinović-Runić, Jasmina, Ćosović, Vladan, Maksimović, Vesna, "Electrochemical potential of poly(viniyl acohol) modified bacterial nanocellulose as platinum nanoparticles support" in Book of abstracts – XIV International scientific conference of chemists, technologists and environmentalists of Republic of Srpska, October 21-22, 2022, Banja Luka (2022):33-33,
https://hdl.handle.net/21.15107/rcub_cer_5939 .

Study of thermal properties and microstructure of the Ag–Ge alloys

Manasijević, Dragan; Balanović, Ljubiša; Marković, Ivana; Gorgievski, Milan; Stamenković, Uroš; Minić, Duško; Premović, Milena; Đorđević, Aleksandar; Ćosović, Vladan

(Springer, 2022)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Marković, Ivana
AU  - Gorgievski, Milan
AU  - Stamenković, Uroš
AU  - Minić, Duško
AU  - Premović, Milena
AU  - Đorđević, Aleksandar
AU  - Ćosović, Vladan
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4808
AB  - Microstructure, phase transitions and thermal properties including thermal diffusivity and thermal conductivity of four Ag–Ge alloys with 20, 40, 60 and 80 at % of Ge were experimentally investigated in this study. Observation and analysis of the alloy microstructures and morphologies of (Ge) phase in the hypereutectic alloys were carried out using optical microscopy and scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM–EDS). Phase transitions of the alloys were studied using differential scanning calorimetry (DSC). Experimentally determined temperature of the eutectic reaction was 650.9 °C. The xenon flash method was used for thermal diffusivity measurements in the temperature range from 25 to 400 °C. Based on the measured values of thermal diffusivity, thermal conductivity of the solid Ag–Ge alloys was determined. It was found that both thermal diffusivity and thermal conductivity show a minimum at 20 at % Ge which is close to the eutectic composition. The obtained results were compared with the results of thermodynamic calculation and literature data, and a close agreement was observed.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Study of thermal properties and microstructure of the Ag–Ge alloys
VL  - 147
SP  - 1955
EP  - 1964
DO  - 10.1007/s10973-021-10664-y
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Marković, Ivana and Gorgievski, Milan and Stamenković, Uroš and Minić, Duško and Premović, Milena and Đorđević, Aleksandar and Ćosović, Vladan",
year = "2022",
abstract = "Microstructure, phase transitions and thermal properties including thermal diffusivity and thermal conductivity of four Ag–Ge alloys with 20, 40, 60 and 80 at % of Ge were experimentally investigated in this study. Observation and analysis of the alloy microstructures and morphologies of (Ge) phase in the hypereutectic alloys were carried out using optical microscopy and scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM–EDS). Phase transitions of the alloys were studied using differential scanning calorimetry (DSC). Experimentally determined temperature of the eutectic reaction was 650.9 °C. The xenon flash method was used for thermal diffusivity measurements in the temperature range from 25 to 400 °C. Based on the measured values of thermal diffusivity, thermal conductivity of the solid Ag–Ge alloys was determined. It was found that both thermal diffusivity and thermal conductivity show a minimum at 20 at % Ge which is close to the eutectic composition. The obtained results were compared with the results of thermodynamic calculation and literature data, and a close agreement was observed.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Study of thermal properties and microstructure of the Ag–Ge alloys",
volume = "147",
pages = "1955-1964",
doi = "10.1007/s10973-021-10664-y"
}
Manasijević, D., Balanović, L., Marković, I., Gorgievski, M., Stamenković, U., Minić, D., Premović, M., Đorđević, A.,& Ćosović, V.. (2022). Study of thermal properties and microstructure of the Ag–Ge alloys. in Journal of Thermal Analysis and Calorimetry
Springer., 147, 1955-1964.
https://doi.org/10.1007/s10973-021-10664-y
Manasijević D, Balanović L, Marković I, Gorgievski M, Stamenković U, Minić D, Premović M, Đorđević A, Ćosović V. Study of thermal properties and microstructure of the Ag–Ge alloys. in Journal of Thermal Analysis and Calorimetry. 2022;147:1955-1964.
doi:10.1007/s10973-021-10664-y .
Manasijević, Dragan, Balanović, Ljubiša, Marković, Ivana, Gorgievski, Milan, Stamenković, Uroš, Minić, Duško, Premović, Milena, Đorđević, Aleksandar, Ćosović, Vladan, "Study of thermal properties and microstructure of the Ag–Ge alloys" in Journal of Thermal Analysis and Calorimetry, 147 (2022):1955-1964,
https://doi.org/10.1007/s10973-021-10664-y . .
3
3

Thermal transport properties and microstructure of the solid Bi-Cu alloys

Manasijević, Dragan; Balanović, Ljubiša; Marković, Ivana; Ćosović, Vladan; Gorgievski, Milan; Stamenković, Uroš; Božinović, Kristina

(Belgrade : Association of Metallurgical Engineers of Serbia ( AMES ), 2022)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Marković, Ivana
AU  - Ćosović, Vladan
AU  - Gorgievski, Milan
AU  - Stamenković, Uroš
AU  - Božinović, Kristina
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5368
AB  - Thermal transport properties of solid Bi-Cu alloys have been investigated over a wide composition range and temperature range ranging from 25 to 250 °C. The flash method was used to determine thermal diffusivity. Thermal diffusivity was discovered to decrease continuously with increasing temperature and bismuth content. The indirect Archimedean method was used to determine the density of the Bi-Cu alloys at 25 °C. The obtained results show that the density of the studied alloys decreases slightly as the copper content increases. Thermal conductivity of the alloys was calculated using measured diffusivity, density, and a calculated specific heat capacity. The thermal conductivity of the studied Bi-Cu alloys decreases with increasing temperature and bismuth content, similar to thermal diffusivity. SEM with energy dispersive X-ray spectrometry (EDS) and differential scanning calorimetry (DSC) were used to examine the microstructure and melting behavior of Bi-Cu alloys, respectively. The eutectic temperature was measured to be 269.9±0.1 °C, and the measured phase transition temperatures and heat effects were compared to thermodynamic calculations using the CALPHAD method.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia  ( AMES )
T2  - Metallurgical and Materials Engineering
T1  - Thermal transport properties and microstructure of the solid Bi-Cu alloys
VL  - 28
IS  - 3
SP  - 503
EP  - 514
DO  - 10.30544/841
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Marković, Ivana and Ćosović, Vladan and Gorgievski, Milan and Stamenković, Uroš and Božinović, Kristina",
year = "2022",
abstract = "Thermal transport properties of solid Bi-Cu alloys have been investigated over a wide composition range and temperature range ranging from 25 to 250 °C. The flash method was used to determine thermal diffusivity. Thermal diffusivity was discovered to decrease continuously with increasing temperature and bismuth content. The indirect Archimedean method was used to determine the density of the Bi-Cu alloys at 25 °C. The obtained results show that the density of the studied alloys decreases slightly as the copper content increases. Thermal conductivity of the alloys was calculated using measured diffusivity, density, and a calculated specific heat capacity. The thermal conductivity of the studied Bi-Cu alloys decreases with increasing temperature and bismuth content, similar to thermal diffusivity. SEM with energy dispersive X-ray spectrometry (EDS) and differential scanning calorimetry (DSC) were used to examine the microstructure and melting behavior of Bi-Cu alloys, respectively. The eutectic temperature was measured to be 269.9±0.1 °C, and the measured phase transition temperatures and heat effects were compared to thermodynamic calculations using the CALPHAD method.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia  ( AMES )",
journal = "Metallurgical and Materials Engineering",
title = "Thermal transport properties and microstructure of the solid Bi-Cu alloys",
volume = "28",
number = "3",
pages = "503-514",
doi = "10.30544/841"
}
Manasijević, D., Balanović, L., Marković, I., Ćosović, V., Gorgievski, M., Stamenković, U.,& Božinović, K.. (2022). Thermal transport properties and microstructure of the solid Bi-Cu alloys. in Metallurgical and Materials Engineering
Belgrade : Association of Metallurgical Engineers of Serbia  ( AMES )., 28(3), 503-514.
https://doi.org/10.30544/841
Manasijević D, Balanović L, Marković I, Ćosović V, Gorgievski M, Stamenković U, Božinović K. Thermal transport properties and microstructure of the solid Bi-Cu alloys. in Metallurgical and Materials Engineering. 2022;28(3):503-514.
doi:10.30544/841 .
Manasijević, Dragan, Balanović, Ljubiša, Marković, Ivana, Ćosović, Vladan, Gorgievski, Milan, Stamenković, Uroš, Božinović, Kristina, "Thermal transport properties and microstructure of the solid Bi-Cu alloys" in Metallurgical and Materials Engineering, 28, no. 3 (2022):503-514,
https://doi.org/10.30544/841 . .
1

Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction

Stevanović, Sanja; Ponjavić, Marijana; Nikodinović-Runić, Jasmina; Maksimović, Vesna; Ćosović, Vladan

(Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM), 2021)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Ponjavić, Marijana
AU  - Nikodinović-Runić, Jasmina
AU  - Maksimović, Vesna
AU  - Ćosović, Vladan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4876
AB  - Catalysts support is essential for nanostructured noble metal catalysts activity and stability since that interaction between the metal particle and the support can affect metal particle size and dispersion. Over the last few decades, the most popular catalysts supports are carbon based materials: Vulcan XC-72 carbon black (CB), multi-walled carbon nanotubes (MWCNTs) and graphene. However, their cost-effective production remains a challenge since most of these materials are obtained by pyrolysis of coal or petroleum. Not less negligible is their negative impact on the environment during synthesis because these processes include release of carbon dioxide and other harmful organic products into the atmosphere. Applications of bacterial nanocelluloses as a catalyst support has attracted a great attention since it can be easily synthesized and is an inexpensive, biodegradable, sustainable and green material. Bacterial nanocellulose (BNC) was produced utilizing the Komagataeibacter medellinensis ID13488 strain. Stable Pt nanoparticles supported on BNC (Pt/BNC) have been synthetized from a precursor solution of H2PtCl6 by microwave assisted polyol procedure. Catalytic activity was tested for methanol oxidation reaction in sulfuric acid solution. The Fourier transform infrared spectroscopy was used to confirm the structure of bacterial nanocellulose as well as after synthesis of Pt-BNC catalyst. Coupled differential scanning calorimetry (DSC) / thermogravimetric (TG) analysis revealed no loss of platinum during synthesis process. XRD analysis showed characteristic peaks for fcc crystalline structure of Pt/BNC and particle size of 1,7 nm. The activity of the Pt/BNC, catalyst for methanol oxidation was evaluated from potentiodynamic measurements in 0.5 M H2SO4 + 0.5 M CH3OH solution. The results obtained indicate enhanced catalytic activities for methanol oxidation reaction.
AB  - Podloge katalizatora imaju veoma važnu ulogu tokom sinteze katalizatora sa plemenitim metalima obzirom da od njihove interakcije sa metalom zavisi veličina čestica i njihova disperzija tokom procesa sinteze. Tokom poslednjih nekoliko decenija kao najčešće korišćene podloge za platinske katalizatore su korišćene podloge na bazi uglljenika: ugalj razvijene površine (Vulcan XC), ugljenične nanotube ili grafen. Međutim, proces dobijanja ovih materijala ima visoke cene zbog toga što se za njihovo dobijanje koriste procesi pirolize uglja ili nafte. Ništa manje zanemarljiv je i negativan uticaj ovih procesa na okolinu pošto procesi sinteze uključuju oslobađanje ugljen dioksida i drugih štetnih materija u atmosferu. Primena bakterijskih nanoceluloza kao nosača katalizatora privukla je veliku pažnju jer se mogu lako sintetizovati i predstavljaju jeftin, biorazgradiv, održiv i zeleni materijal. Bakterijska nanoceluloza (BNC) proizvedena je upotrebom soja Komagataeibacter medellinensis ID13488. Stabilne Pt nanočestice suspendovane na BNC (Pt/BNC) sintetizovane su iz prekursorskog H2PtCl6 rastvora poliol postupkom uz pomoć mikrotalasne pećnice. Ispitivana je katalitička aktivnost reakcije oksidacije metanola u rastvoru sumporne kiseline. Infracrvena spektroskopija Fourierove transformacije je korišćena za potvrdu strukture same bakterijske nanoceluloze, kao i nakon sinteze Pt-BNC katalizatora. Diferencijalna skenirajuća kalorimetrija (DSC) / termogravimetrijska (TG) analiza nije otkrila gubitak platine tokom procesa sinteze. XRD analiza pokazala je karakteristične vrhove za fcc kristalnu strukturu Pt/BNC i veličinu čestica od 1,7 nm. Aktivnost Pt/BNC, katalizatora za oksidaciju metanola, procenjena je iz potenciodinamičkih merenja u 0,5 M H2SO4 + 0,5 M CH3OH rastvoru. Dobijeni rezultati ukazuju na pojačanu katalitičku aktivnost reakcije oksidacije metanola.
PB  - Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
T1  - Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction
T1  - Bakterijska celuloza kao podloga za platinske kataliztore za reakciju elektrooksidacije metanola
SP  - 49
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_cer_4876
ER  - 
@conference{
author = "Stevanović, Sanja and Ponjavić, Marijana and Nikodinović-Runić, Jasmina and Maksimović, Vesna and Ćosović, Vladan",
year = "2021",
abstract = "Catalysts support is essential for nanostructured noble metal catalysts activity and stability since that interaction between the metal particle and the support can affect metal particle size and dispersion. Over the last few decades, the most popular catalysts supports are carbon based materials: Vulcan XC-72 carbon black (CB), multi-walled carbon nanotubes (MWCNTs) and graphene. However, their cost-effective production remains a challenge since most of these materials are obtained by pyrolysis of coal or petroleum. Not less negligible is their negative impact on the environment during synthesis because these processes include release of carbon dioxide and other harmful organic products into the atmosphere. Applications of bacterial nanocelluloses as a catalyst support has attracted a great attention since it can be easily synthesized and is an inexpensive, biodegradable, sustainable and green material. Bacterial nanocellulose (BNC) was produced utilizing the Komagataeibacter medellinensis ID13488 strain. Stable Pt nanoparticles supported on BNC (Pt/BNC) have been synthetized from a precursor solution of H2PtCl6 by microwave assisted polyol procedure. Catalytic activity was tested for methanol oxidation reaction in sulfuric acid solution. The Fourier transform infrared spectroscopy was used to confirm the structure of bacterial nanocellulose as well as after synthesis of Pt-BNC catalyst. Coupled differential scanning calorimetry (DSC) / thermogravimetric (TG) analysis revealed no loss of platinum during synthesis process. XRD analysis showed characteristic peaks for fcc crystalline structure of Pt/BNC and particle size of 1,7 nm. The activity of the Pt/BNC, catalyst for methanol oxidation was evaluated from potentiodynamic measurements in 0.5 M H2SO4 + 0.5 M CH3OH solution. The results obtained indicate enhanced catalytic activities for methanol oxidation reaction., Podloge katalizatora imaju veoma važnu ulogu tokom sinteze katalizatora sa plemenitim metalima obzirom da od njihove interakcije sa metalom zavisi veličina čestica i njihova disperzija tokom procesa sinteze. Tokom poslednjih nekoliko decenija kao najčešće korišćene podloge za platinske katalizatore su korišćene podloge na bazi uglljenika: ugalj razvijene površine (Vulcan XC), ugljenične nanotube ili grafen. Međutim, proces dobijanja ovih materijala ima visoke cene zbog toga što se za njihovo dobijanje koriste procesi pirolize uglja ili nafte. Ništa manje zanemarljiv je i negativan uticaj ovih procesa na okolinu pošto procesi sinteze uključuju oslobađanje ugljen dioksida i drugih štetnih materija u atmosferu. Primena bakterijskih nanoceluloza kao nosača katalizatora privukla je veliku pažnju jer se mogu lako sintetizovati i predstavljaju jeftin, biorazgradiv, održiv i zeleni materijal. Bakterijska nanoceluloza (BNC) proizvedena je upotrebom soja Komagataeibacter medellinensis ID13488. Stabilne Pt nanočestice suspendovane na BNC (Pt/BNC) sintetizovane su iz prekursorskog H2PtCl6 rastvora poliol postupkom uz pomoć mikrotalasne pećnice. Ispitivana je katalitička aktivnost reakcije oksidacije metanola u rastvoru sumporne kiseline. Infracrvena spektroskopija Fourierove transformacije je korišćena za potvrdu strukture same bakterijske nanoceluloze, kao i nakon sinteze Pt-BNC katalizatora. Diferencijalna skenirajuća kalorimetrija (DSC) / termogravimetrijska (TG) analiza nije otkrila gubitak platine tokom procesa sinteze. XRD analiza pokazala je karakteristične vrhove za fcc kristalnu strukturu Pt/BNC i veličinu čestica od 1,7 nm. Aktivnost Pt/BNC, katalizatora za oksidaciju metanola, procenjena je iz potenciodinamičkih merenja u 0,5 M H2SO4 + 0,5 M CH3OH rastvoru. Dobijeni rezultati ukazuju na pojačanu katalitičku aktivnost reakcije oksidacije metanola.",
publisher = "Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija",
title = "Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction, Bakterijska celuloza kao podloga za platinske kataliztore za reakciju elektrooksidacije metanola",
pages = "49-50",
url = "https://hdl.handle.net/21.15107/rcub_cer_4876"
}
Stevanović, S., Ponjavić, M., Nikodinović-Runić, J., Maksimović, V.,& Ćosović, V.. (2021). Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija
Belgrade : Serbian Society of Corrosion and Materials Protection (UISKOZAM)., 49-50.
https://hdl.handle.net/21.15107/rcub_cer_4876
Stevanović S, Ponjavić M, Nikodinović-Runić J, Maksimović V, Ćosović V. Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija. 2021;:49-50.
https://hdl.handle.net/21.15107/rcub_cer_4876 .
Stevanović, Sanja, Ponjavić, Marijana, Nikodinović-Runić, Jasmina, Maksimović, Vesna, Ćosović, Vladan, "Bacterial nanocellulose as green support for platinum catalysts in methanol electrooxidation reaction" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings XXII YuCorr International Conference / Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova XXII YuCorr [Jugoslovenska korozija] Međunarodna konferencija (2021):49-50,
https://hdl.handle.net/21.15107/rcub_cer_4876 .

Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System

Milosavljević, Milan; Premović, Milena; Minić, Duško; Ćosović, Vladan; Đorđević, Aleksandar; Tomović, Milica

(Brazil : SCI FLO, 2021)

TY  - JOUR
AU  - Milosavljević, Milan
AU  - Premović, Milena
AU  - Minić, Duško
AU  - Ćosović, Vladan
AU  - Đorđević, Aleksandar
AU  - Tomović, Milica
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4765
AB  - Phase diagram of the Bi-Ce-Ge ternary system has been investigated experimentally and thermodynamically extrapolated by using Pandat software. Experimental results were obtained using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Examined ternary samples belong to two isothermal sections at 400 and 600 °C as well as three vertical sections Bi-CuGe, Cu-BiGe, and Ge-BiCu. No ternary compound has been detected in the equilibrated samples from the selected isothermal sections. Based on the presented experimental data and available literature data, description of the ternary system has been developed. A reasonable agreement between the experimental data and the calculated phase equilibria was obtained. As an example, ternary Cu80Bi10Ge10 alloy was selected for solidification simulations according to Scheil and Lever Rule assumptions as well as for simulation of the total fraction of each solid at different temperatures, latent heat, and total heat.
PB  - Brazil : SCI FLO
T2  - Materials Research
T1  - Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System
VL  - 24
IS  - 6
DO  - 10.1590/1980-5373-MR-2021-0201
ER  - 
@article{
author = "Milosavljević, Milan and Premović, Milena and Minić, Duško and Ćosović, Vladan and Đorđević, Aleksandar and Tomović, Milica",
year = "2021",
abstract = "Phase diagram of the Bi-Ce-Ge ternary system has been investigated experimentally and thermodynamically extrapolated by using Pandat software. Experimental results were obtained using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Examined ternary samples belong to two isothermal sections at 400 and 600 °C as well as three vertical sections Bi-CuGe, Cu-BiGe, and Ge-BiCu. No ternary compound has been detected in the equilibrated samples from the selected isothermal sections. Based on the presented experimental data and available literature data, description of the ternary system has been developed. A reasonable agreement between the experimental data and the calculated phase equilibria was obtained. As an example, ternary Cu80Bi10Ge10 alloy was selected for solidification simulations according to Scheil and Lever Rule assumptions as well as for simulation of the total fraction of each solid at different temperatures, latent heat, and total heat.",
publisher = "Brazil : SCI FLO",
journal = "Materials Research",
title = "Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System",
volume = "24",
number = "6",
doi = "10.1590/1980-5373-MR-2021-0201"
}
Milosavljević, M., Premović, M., Minić, D., Ćosović, V., Đorđević, A.,& Tomović, M.. (2021). Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System. in Materials Research
Brazil : SCI FLO., 24(6).
https://doi.org/10.1590/1980-5373-MR-2021-0201
Milosavljević M, Premović M, Minić D, Ćosović V, Đorđević A, Tomović M. Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System. in Materials Research. 2021;24(6).
doi:10.1590/1980-5373-MR-2021-0201 .
Milosavljević, Milan, Premović, Milena, Minić, Duško, Ćosović, Vladan, Đorđević, Aleksandar, Tomović, Milica, "Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System" in Materials Research, 24, no. 6 (2021),
https://doi.org/10.1590/1980-5373-MR-2021-0201 . .

Structural and thermal properties of Sn–Ag alloys

Manasijević, Dragan; Balanović, Ljubiša; Marković, Ljubiša; Gorgievski, Milan; Stamenković, Uroš; Đorđević, Aleksandar; Minić, Duško; Ćosović, Vladan

(Elsevier, 2021)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Marković, Ljubiša
AU  - Gorgievski, Milan
AU  - Stamenković, Uroš
AU  - Đorđević, Aleksandar
AU  - Minić, Duško
AU  - Ćosović, Vladan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4817
AB  - Microstructure and thermal properties of slowly cooled Sn–10% Ag and Sn–20% Ag alloys were experimentally investigated in this study. It was found that microstructure of the studied alloys is composed of large, plate-like grains of Ag3Sn intermetallic phase in the Sn-rich eutectic matrix. Phase transition temperatures and corresponding heat effects were experimentally determined and compared with the results of thermodynamic and phase equilibria calculations using the CALPHAD (CALculation of PHAse Diagrams) method and optimized thermodynamic parameters from literature. The xenon flash method was employed for the measurements of thermal diffusivity and determination of thermal conductivity in the temperature range from 25 to 150 °C. The results show that the thermal diffusivity and thermal conductivity gradually decrease with increasing temperature. The determined values of thermal conductivities of the investigated alloys are very close to each other and only slightly higher than that of pure tin. The contributions of electrons and phonons to the thermal conductivity of the studied alloys at room temperature were determined using the Wiedemann-Franz law and the obtained values of the thermal and electrical conductivities. The percentage contributions of the phonon component to the thermal conductivity for Sn–10% Ag and Sn–20% Ag alloys at 25 °C were found to be 20.5% and 28.9%, respectively.
PB  - Elsevier
T2  - Solid State Sciences
T1  - Structural and thermal properties of Sn–Ag alloys
VL  - 119
SP  - 106685
DO  - 10.1016/j.solidstatesciences.2021.106685
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Marković, Ljubiša and Gorgievski, Milan and Stamenković, Uroš and Đorđević, Aleksandar and Minić, Duško and Ćosović, Vladan",
year = "2021",
abstract = "Microstructure and thermal properties of slowly cooled Sn–10% Ag and Sn–20% Ag alloys were experimentally investigated in this study. It was found that microstructure of the studied alloys is composed of large, plate-like grains of Ag3Sn intermetallic phase in the Sn-rich eutectic matrix. Phase transition temperatures and corresponding heat effects were experimentally determined and compared with the results of thermodynamic and phase equilibria calculations using the CALPHAD (CALculation of PHAse Diagrams) method and optimized thermodynamic parameters from literature. The xenon flash method was employed for the measurements of thermal diffusivity and determination of thermal conductivity in the temperature range from 25 to 150 °C. The results show that the thermal diffusivity and thermal conductivity gradually decrease with increasing temperature. The determined values of thermal conductivities of the investigated alloys are very close to each other and only slightly higher than that of pure tin. The contributions of electrons and phonons to the thermal conductivity of the studied alloys at room temperature were determined using the Wiedemann-Franz law and the obtained values of the thermal and electrical conductivities. The percentage contributions of the phonon component to the thermal conductivity for Sn–10% Ag and Sn–20% Ag alloys at 25 °C were found to be 20.5% and 28.9%, respectively.",
publisher = "Elsevier",
journal = "Solid State Sciences",
title = "Structural and thermal properties of Sn–Ag alloys",
volume = "119",
pages = "106685",
doi = "10.1016/j.solidstatesciences.2021.106685"
}
Manasijević, D., Balanović, L., Marković, L., Gorgievski, M., Stamenković, U., Đorđević, A., Minić, D.,& Ćosović, V.. (2021). Structural and thermal properties of Sn–Ag alloys. in Solid State Sciences
Elsevier., 119, 106685.
https://doi.org/10.1016/j.solidstatesciences.2021.106685
Manasijević D, Balanović L, Marković L, Gorgievski M, Stamenković U, Đorđević A, Minić D, Ćosović V. Structural and thermal properties of Sn–Ag alloys. in Solid State Sciences. 2021;119:106685.
doi:10.1016/j.solidstatesciences.2021.106685 .
Manasijević, Dragan, Balanović, Ljubiša, Marković, Ljubiša, Gorgievski, Milan, Stamenković, Uroš, Đorđević, Aleksandar, Minić, Duško, Ćosović, Vladan, "Structural and thermal properties of Sn–Ag alloys" in Solid State Sciences, 119 (2021):106685,
https://doi.org/10.1016/j.solidstatesciences.2021.106685 . .
8
9

Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems

Đorđević, Aleksandar; Premović, Milena; Minić, Duško; Ćosović, Vladan; Manasijević, Dragan

(Elsevier, 2020)

TY  - JOUR
AU  - Đorđević, Aleksandar
AU  - Premović, Milena
AU  - Minić, Duško
AU  - Ćosović, Vladan
AU  - Manasijević, Dragan
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3344
AB  - Due to the wide application of systems based on germanium ternary Bi-Ga-Ge and Bi-Ge-Zn systems were experimentally tested in this study. Used experimental techniques were scanning electron microscope with energy dispersive spectroscopy (SEM-EDS), x-ray diffraction (XRD) and differential thermal analysis (DTA). Three groups of samples were prepared and tested. Alloys were from two isothermal sections at 100 and 300 °C and three vertical sections. Obtained results of experimental tests were compared with predicted phase diagrams. Comparison of EDS and DTA results with calculated phase diagrams of the ternary Bi-Ga-Ge system results in good agreement. While for Bi-Ge-Zn was necessary to introduce new ternary parameters. Introduced ternary parameters were based on experimental results from this study. The thermodynamic descriptions of the ternary Bi-Ga-Ge and Bi-Ge-Zn systems have been developed by using CALPHAD method. Reasonable agreement between experimental data and the calculated phase diagrams has been reached for both ternary Bi-Ga-Ge and Bi-Ge-Zn systems. The liquid projection and invariant equilibria have been calculated by using obtained thermodynamic parameters.
PB  - Elsevier
T2  - Journal of Chemical Thermodynamics
T1  - Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems
VL  - 142
SP  - 106000
DO  - 10.1016/j.jct.2019.106000
ER  - 
@article{
author = "Đorđević, Aleksandar and Premović, Milena and Minić, Duško and Ćosović, Vladan and Manasijević, Dragan",
year = "2020",
abstract = "Due to the wide application of systems based on germanium ternary Bi-Ga-Ge and Bi-Ge-Zn systems were experimentally tested in this study. Used experimental techniques were scanning electron microscope with energy dispersive spectroscopy (SEM-EDS), x-ray diffraction (XRD) and differential thermal analysis (DTA). Three groups of samples were prepared and tested. Alloys were from two isothermal sections at 100 and 300 °C and three vertical sections. Obtained results of experimental tests were compared with predicted phase diagrams. Comparison of EDS and DTA results with calculated phase diagrams of the ternary Bi-Ga-Ge system results in good agreement. While for Bi-Ge-Zn was necessary to introduce new ternary parameters. Introduced ternary parameters were based on experimental results from this study. The thermodynamic descriptions of the ternary Bi-Ga-Ge and Bi-Ge-Zn systems have been developed by using CALPHAD method. Reasonable agreement between experimental data and the calculated phase diagrams has been reached for both ternary Bi-Ga-Ge and Bi-Ge-Zn systems. The liquid projection and invariant equilibria have been calculated by using obtained thermodynamic parameters.",
publisher = "Elsevier",
journal = "Journal of Chemical Thermodynamics",
title = "Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems",
volume = "142",
pages = "106000",
doi = "10.1016/j.jct.2019.106000"
}
Đorđević, A., Premović, M., Minić, D., Ćosović, V.,& Manasijević, D.. (2020). Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems. in Journal of Chemical Thermodynamics
Elsevier., 142, 106000.
https://doi.org/10.1016/j.jct.2019.106000
Đorđević A, Premović M, Minić D, Ćosović V, Manasijević D. Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems. in Journal of Chemical Thermodynamics. 2020;142:106000.
doi:10.1016/j.jct.2019.106000 .
Đorđević, Aleksandar, Premović, Milena, Minić, Duško, Ćosović, Vladan, Manasijević, Dragan, "Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems" in Journal of Chemical Thermodynamics, 142 (2020):106000,
https://doi.org/10.1016/j.jct.2019.106000 . .
2
2
2

Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems

Đorđević, Aleksandar; Premović, Milena; Minić, Duško; Ćosović, Vladan; Manasijević, Dragan

(Elsevier, 2020)

TY  - JOUR
AU  - Đorđević, Aleksandar
AU  - Premović, Milena
AU  - Minić, Duško
AU  - Ćosović, Vladan
AU  - Manasijević, Dragan
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3361
AB  - Due to the wide application of systems based on germanium ternary Bi-Ga-Ge and Bi-Ge-Zn systems were experimentally tested in this study. Used experimental techniques were scanning electron microscope with energy dispersive spectroscopy (SEM-EDS), x-ray diffraction (XRD) and differential thermal analysis (DTA). Three groups of samples were prepared and tested. Alloys were from two isothermal sections at 100 and 300 °C and three vertical sections. Obtained results of experimental tests were compared with predicted phase diagrams. Comparison of EDS and DTA results with calculated phase diagrams of the ternary Bi-Ga-Ge system results in good agreement. While for Bi-Ge-Zn was necessary to introduce new ternary parameters. Introduced ternary parameters were based on experimental results from this study. The thermodynamic descriptions of the ternary Bi-Ga-Ge and Bi-Ge-Zn systems have been developed by using CALPHAD method. Reasonable agreement between experimental data and the calculated phase diagrams has been reached for both ternary Bi-Ga-Ge and Bi-Ge-Zn systems. The liquid projection and invariant equilibria have been calculated by using obtained thermodynamic parameters.
PB  - Elsevier
T2  - Journal of Chemical Thermodynamics
T1  - Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems
VL  - 142
SP  - 106000
DO  - 10.1016/j.jct.2019.106000
ER  - 
@article{
author = "Đorđević, Aleksandar and Premović, Milena and Minić, Duško and Ćosović, Vladan and Manasijević, Dragan",
year = "2020",
abstract = "Due to the wide application of systems based on germanium ternary Bi-Ga-Ge and Bi-Ge-Zn systems were experimentally tested in this study. Used experimental techniques were scanning electron microscope with energy dispersive spectroscopy (SEM-EDS), x-ray diffraction (XRD) and differential thermal analysis (DTA). Three groups of samples were prepared and tested. Alloys were from two isothermal sections at 100 and 300 °C and three vertical sections. Obtained results of experimental tests were compared with predicted phase diagrams. Comparison of EDS and DTA results with calculated phase diagrams of the ternary Bi-Ga-Ge system results in good agreement. While for Bi-Ge-Zn was necessary to introduce new ternary parameters. Introduced ternary parameters were based on experimental results from this study. The thermodynamic descriptions of the ternary Bi-Ga-Ge and Bi-Ge-Zn systems have been developed by using CALPHAD method. Reasonable agreement between experimental data and the calculated phase diagrams has been reached for both ternary Bi-Ga-Ge and Bi-Ge-Zn systems. The liquid projection and invariant equilibria have been calculated by using obtained thermodynamic parameters.",
publisher = "Elsevier",
journal = "Journal of Chemical Thermodynamics",
title = "Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems",
volume = "142",
pages = "106000",
doi = "10.1016/j.jct.2019.106000"
}
Đorđević, A., Premović, M., Minić, D., Ćosović, V.,& Manasijević, D.. (2020). Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems. in Journal of Chemical Thermodynamics
Elsevier., 142, 106000.
https://doi.org/10.1016/j.jct.2019.106000
Đorđević A, Premović M, Minić D, Ćosović V, Manasijević D. Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems. in Journal of Chemical Thermodynamics. 2020;142:106000.
doi:10.1016/j.jct.2019.106000 .
Đorđević, Aleksandar, Premović, Milena, Minić, Duško, Ćosović, Vladan, Manasijević, Dragan, "Experimental examination and thermodynamic description of the ternary Bi-Ge-Ga,Zn systems" in Journal of Chemical Thermodynamics, 142 (2020):106000,
https://doi.org/10.1016/j.jct.2019.106000 . .
2
2
2

Thermal characterization of the In–Sn–Zn eutectic alloy

Manasijević, Dragan; Balanović, Ljubiša; Ćosović, Vladan; Minić, Duško; Premović, Milena; Gorgievski, Milan; Stamenković, Uroš; Talijan, Nadežda M.

(Belgrade : Association of Metallurgical Engineers of Serbia, 2020)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Ćosović, Vladan
AU  - Minić, Duško
AU  - Premović, Milena
AU  - Gorgievski, Milan
AU  - Stamenković, Uroš
AU  - Talijan, Nadežda M.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3391
AB  - Thermal properties, including melting temperature, latent heat of melting, specific heat capacity and thermal conductivity, of a low-melting In–Sn–Zn eutectic alloy were investigated in this work. The In–Sn–Zn eutectic alloy with nominal composition 52.7In-44.9Sn-2.4Zn (at.%) was prepared by the melting of pure metals under an argon atmosphere. The conducted assessment consisted of both theoretical and experimental approaches. Differential scanning calorimetry (DSC) was used for the measurement of melting temperature and latent heat, and the obtained results were compared with the results of thermodynamic calculations. The measured melting temperature and the latent heat of melting for the In–Sn–Zn eutectic alloy are 106.5±0.1 °C and 28.3±0.1 Jg-1, respectively. Thermal diffusivity and thermal conductivity of the In–Sn–Zn eutectic alloy were studied by the xenon-flash method. The determined thermal conductivity of the investigated eutectic alloy at 25 °C is 42.2±3.4 Wm-1K-1. Apart from providing insight into the possibility for application of the investigated alloy as the metallic phase-change material, the obtained values of thermal properties can also be utilized as input parameters for various simulation processes such as casting and soldering.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
T2  - Metallurgical and Materials Engineering
T1  - Thermal characterization of the In–Sn–Zn eutectic alloy
VL  - 25
IS  - 04
SP  - 325
EP  - 334
DO  - 10.30544/456
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Ćosović, Vladan and Minić, Duško and Premović, Milena and Gorgievski, Milan and Stamenković, Uroš and Talijan, Nadežda M.",
year = "2020",
abstract = "Thermal properties, including melting temperature, latent heat of melting, specific heat capacity and thermal conductivity, of a low-melting In–Sn–Zn eutectic alloy were investigated in this work. The In–Sn–Zn eutectic alloy with nominal composition 52.7In-44.9Sn-2.4Zn (at.%) was prepared by the melting of pure metals under an argon atmosphere. The conducted assessment consisted of both theoretical and experimental approaches. Differential scanning calorimetry (DSC) was used for the measurement of melting temperature and latent heat, and the obtained results were compared with the results of thermodynamic calculations. The measured melting temperature and the latent heat of melting for the In–Sn–Zn eutectic alloy are 106.5±0.1 °C and 28.3±0.1 Jg-1, respectively. Thermal diffusivity and thermal conductivity of the In–Sn–Zn eutectic alloy were studied by the xenon-flash method. The determined thermal conductivity of the investigated eutectic alloy at 25 °C is 42.2±3.4 Wm-1K-1. Apart from providing insight into the possibility for application of the investigated alloy as the metallic phase-change material, the obtained values of thermal properties can also be utilized as input parameters for various simulation processes such as casting and soldering.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical and Materials Engineering",
title = "Thermal characterization of the In–Sn–Zn eutectic alloy",
volume = "25",
number = "04",
pages = "325-334",
doi = "10.30544/456"
}
Manasijević, D., Balanović, L., Ćosović, V., Minić, D., Premović, M., Gorgievski, M., Stamenković, U.,& Talijan, N. M.. (2020). Thermal characterization of the In–Sn–Zn eutectic alloy. in Metallurgical and Materials Engineering
Belgrade : Association of Metallurgical Engineers of Serbia., 25(04), 325-334.
https://doi.org/10.30544/456
Manasijević D, Balanović L, Ćosović V, Minić D, Premović M, Gorgievski M, Stamenković U, Talijan NM. Thermal characterization of the In–Sn–Zn eutectic alloy. in Metallurgical and Materials Engineering. 2020;25(04):325-334.
doi:10.30544/456 .
Manasijević, Dragan, Balanović, Ljubiša, Ćosović, Vladan, Minić, Duško, Premović, Milena, Gorgievski, Milan, Stamenković, Uroš, Talijan, Nadežda M., "Thermal characterization of the In–Sn–Zn eutectic alloy" in Metallurgical and Materials Engineering, 25, no. 04 (2020):325-334,
https://doi.org/10.30544/456 . .
1
3
4

Microstructure and thermal properties of Bi-Sn eutectic alloy

Manasijević, Ivana; Balanović, Ljubiša; Stamenković, Uroš; Gorgievski, Milan; Ćosović, Vladan

(München : Carl Hanser Verlag, 2020)

TY  - JOUR
AU  - Manasijević, Ivana
AU  - Balanović, Ljubiša
AU  - Stamenković, Uroš
AU  - Gorgievski, Milan
AU  - Ćosović, Vladan
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3775
AB  - Alloys based on Sn and Bi are considered to be one of the best soft lead-free solders due to their low melting temperature and low price. In addition, Bi-Sn alloy with a eutectic composition represents a promising candidate as a metallic phase change material (PCM) for use in the field of  thermal energy storage (TES). The accurate knowledge of microstructural and thermophysical properties such as the latent heat of melting, thermal conductivity, specific heat capacity is of crucial importance for PCM selection. Thus, the aim of the current study has been to determine the  microstructure, latent heat of melting and thermal conductivity of a eutectic alloy from the binary Bi-Sn system.
PB  - München : Carl Hanser Verlag
T2  - Materials Testing
T1  - Microstructure and thermal properties of Bi-Sn eutectic alloy
VL  - 62
IS  - 2
SP  - 184
EP  - 188
DO  - 10.3139/120.111470
ER  - 
@article{
author = "Manasijević, Ivana and Balanović, Ljubiša and Stamenković, Uroš and Gorgievski, Milan and Ćosović, Vladan",
year = "2020",
abstract = "Alloys based on Sn and Bi are considered to be one of the best soft lead-free solders due to their low melting temperature and low price. In addition, Bi-Sn alloy with a eutectic composition represents a promising candidate as a metallic phase change material (PCM) for use in the field of  thermal energy storage (TES). The accurate knowledge of microstructural and thermophysical properties such as the latent heat of melting, thermal conductivity, specific heat capacity is of crucial importance for PCM selection. Thus, the aim of the current study has been to determine the  microstructure, latent heat of melting and thermal conductivity of a eutectic alloy from the binary Bi-Sn system.",
publisher = "München : Carl Hanser Verlag",
journal = "Materials Testing",
title = "Microstructure and thermal properties of Bi-Sn eutectic alloy",
volume = "62",
number = "2",
pages = "184-188",
doi = "10.3139/120.111470"
}
Manasijević, I., Balanović, L., Stamenković, U., Gorgievski, M.,& Ćosović, V.. (2020). Microstructure and thermal properties of Bi-Sn eutectic alloy. in Materials Testing
München : Carl Hanser Verlag., 62(2), 184-188.
https://doi.org/10.3139/120.111470
Manasijević I, Balanović L, Stamenković U, Gorgievski M, Ćosović V. Microstructure and thermal properties of Bi-Sn eutectic alloy. in Materials Testing. 2020;62(2):184-188.
doi:10.3139/120.111470 .
Manasijević, Ivana, Balanović, Ljubiša, Stamenković, Uroš, Gorgievski, Milan, Ćosović, Vladan, "Microstructure and thermal properties of Bi-Sn eutectic alloy" in Materials Testing, 62, no. 2 (2020):184-188,
https://doi.org/10.3139/120.111470 . .
1
1

Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy

Manasijević, Dragan; Balanović, Ljubiša; Holjevac Grgurić, Tamara; Gorgievski, Milan; Marković, Ivana; Ćosović, Vladan; Premović, Milena; Minić, Duško

(Association of Metallurgical Engineers of Serbia (AMES), 2020)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Holjevac Grgurić, Tamara
AU  - Gorgievski, Milan
AU  - Marković, Ivana
AU  - Ćosović, Vladan
AU  - Premović, Milena
AU  - Minić, Duško
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3781
AB  - Low-melting alloys, based on bismuth and indium, have found commercial use in soldering, safety devices, coatings, and bonding applications. In this respect, the accurate knowledge  of  their  thermal  properties  such  as  melting  and  solidification  temperatures, latent heat of melting, supercooling tendency, etc. is of large importance. In the present research,   low-melting   alloy   with   nominal   composition   Bi40In40Pb20(at.   %)   was investigated by means of scanning electron microscopy(SEM) with energy dispersive X-ray spectrometry (EDS) and by differential scanning calorimetry (DSC). Microstructural and chemical (SEM-EDS) analysis has revealed the existence of two coexisting phases in the  prepared  alloy,  which  was  identified  as  BiInand  (Pb).  Melting  and  solidification temperatures  and  the  related  heat  effects  were  measured  by  the  DSC  technique.  The solidus temperature obtained from the DSC heating curves was 76.3 °C and the solidus temperature  obtained  from  the  corresponding  DSC  cooling  runs  was  61.2  °C.  The experimentally  obtained  results  were  compared  with  the  results  of  thermodynamic calculation according to CALPHAD (calculation of phase diagram) approach, and a close agreement was noticed.
PB  - Association of Metallurgical Engineers of Serbia (AMES)
T2  - Metallurgical and Materials Engineering
T1  - Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy
VL  - 26
IS  - 4
SP  - 385
EP  - 394
DO  - 10.30544/564
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Holjevac Grgurić, Tamara and Gorgievski, Milan and Marković, Ivana and Ćosović, Vladan and Premović, Milena and Minić, Duško",
year = "2020",
abstract = "Low-melting alloys, based on bismuth and indium, have found commercial use in soldering, safety devices, coatings, and bonding applications. In this respect, the accurate knowledge  of  their  thermal  properties  such  as  melting  and  solidification  temperatures, latent heat of melting, supercooling tendency, etc. is of large importance. In the present research,   low-melting   alloy   with   nominal   composition   Bi40In40Pb20(at.   %)   was investigated by means of scanning electron microscopy(SEM) with energy dispersive X-ray spectrometry (EDS) and by differential scanning calorimetry (DSC). Microstructural and chemical (SEM-EDS) analysis has revealed the existence of two coexisting phases in the  prepared  alloy,  which  was  identified  as  BiInand  (Pb).  Melting  and  solidification temperatures  and  the  related  heat  effects  were  measured  by  the  DSC  technique.  The solidus temperature obtained from the DSC heating curves was 76.3 °C and the solidus temperature  obtained  from  the  corresponding  DSC  cooling  runs  was  61.2  °C.  The experimentally  obtained  results  were  compared  with  the  results  of  thermodynamic calculation according to CALPHAD (calculation of phase diagram) approach, and a close agreement was noticed.",
publisher = "Association of Metallurgical Engineers of Serbia (AMES)",
journal = "Metallurgical and Materials Engineering",
title = "Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy",
volume = "26",
number = "4",
pages = "385-394",
doi = "10.30544/564"
}
Manasijević, D., Balanović, L., Holjevac Grgurić, T., Gorgievski, M., Marković, I., Ćosović, V., Premović, M.,& Minić, D.. (2020). Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy. in Metallurgical and Materials Engineering
Association of Metallurgical Engineers of Serbia (AMES)., 26(4), 385-394.
https://doi.org/10.30544/564
Manasijević D, Balanović L, Holjevac Grgurić T, Gorgievski M, Marković I, Ćosović V, Premović M, Minić D. Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy. in Metallurgical and Materials Engineering. 2020;26(4):385-394.
doi:10.30544/564 .
Manasijević, Dragan, Balanović, Ljubiša, Holjevac Grgurić, Tamara, Gorgievski, Milan, Marković, Ivana, Ćosović, Vladan, Premović, Milena, Minić, Duško, "Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy" in Metallurgical and Materials Engineering, 26, no. 4 (2020):385-394,
https://doi.org/10.30544/564 . .

Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy

Manasijević, Dragan; Balanović, Ljubiša; Holjevac Grgurić, Tamara; Gorgievski, Milan; Marković, Ivana; Ćosović, Vladan; Premović, Milena; Minić, Duško

(Serbia : Association of Metallurgical Engineers of Serbia, 2020)

TY  - JOUR
AU  - Manasijević, Dragan
AU  - Balanović, Ljubiša
AU  - Holjevac Grgurić, Tamara
AU  - Gorgievski, Milan
AU  - Marković, Ivana
AU  - Ćosović, Vladan
AU  - Premović, Milena
AU  - Minić, Duško
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4222
AB  - Low-melting alloys, based on bismuth and indium, have found commercial use in soldering, safety devices, coatings, and bonding applications. In this respect, the accurate knowledge of their thermal properties such as melting and solidification temperatures, latent heat of melting, supercooling tendency, etc. is of large importance. In the present research, low-melting alloy with nominal composition Bi40In40Pb20 (at. %) was investigated by means of scanning electron microscopy (SEM) with energy dispersive Xray spectrometry (EDS) and by differential scanning calorimetry (DSC). Microstructural and chemical (SEM-EDS) analysis has revealed the existence of two coexisting phases in the prepared alloy, which was identified as BiIn and (Pb). Melting and solidification temperatures and the related heat effects were measured by the DSC technique. The solidus temperature obtained from the DSC heating curves was 76.3 °C and the solidus temperature obtained from the corresponding DSC cooling runs was 61.2 °C. The experimentally obtained results were compared with the results of thermodynamic calculation according to CALPHAD (calculation of phase diagram) approach, and a close agreement was noticed.
PB  - Serbia : Association of Metallurgical Engineers of Serbia
T2  - Metallurgical & Materials Engineering
T1  - Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy
VL  - 26
IS  - 4
SP  - 385
EP  - 394
DO  - 10.30544/564
ER  - 
@article{
author = "Manasijević, Dragan and Balanović, Ljubiša and Holjevac Grgurić, Tamara and Gorgievski, Milan and Marković, Ivana and Ćosović, Vladan and Premović, Milena and Minić, Duško",
year = "2020",
abstract = "Low-melting alloys, based on bismuth and indium, have found commercial use in soldering, safety devices, coatings, and bonding applications. In this respect, the accurate knowledge of their thermal properties such as melting and solidification temperatures, latent heat of melting, supercooling tendency, etc. is of large importance. In the present research, low-melting alloy with nominal composition Bi40In40Pb20 (at. %) was investigated by means of scanning electron microscopy (SEM) with energy dispersive Xray spectrometry (EDS) and by differential scanning calorimetry (DSC). Microstructural and chemical (SEM-EDS) analysis has revealed the existence of two coexisting phases in the prepared alloy, which was identified as BiIn and (Pb). Melting and solidification temperatures and the related heat effects were measured by the DSC technique. The solidus temperature obtained from the DSC heating curves was 76.3 °C and the solidus temperature obtained from the corresponding DSC cooling runs was 61.2 °C. The experimentally obtained results were compared with the results of thermodynamic calculation according to CALPHAD (calculation of phase diagram) approach, and a close agreement was noticed.",
publisher = "Serbia : Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering",
title = "Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy",
volume = "26",
number = "4",
pages = "385-394",
doi = "10.30544/564"
}
Manasijević, D., Balanović, L., Holjevac Grgurić, T., Gorgievski, M., Marković, I., Ćosović, V., Premović, M.,& Minić, D.. (2020). Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy. in Metallurgical & Materials Engineering
Serbia : Association of Metallurgical Engineers of Serbia., 26(4), 385-394.
https://doi.org/10.30544/564
Manasijević D, Balanović L, Holjevac Grgurić T, Gorgievski M, Marković I, Ćosović V, Premović M, Minić D. Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy. in Metallurgical & Materials Engineering. 2020;26(4):385-394.
doi:10.30544/564 .
Manasijević, Dragan, Balanović, Ljubiša, Holjevac Grgurić, Tamara, Gorgievski, Milan, Marković, Ivana, Ćosović, Vladan, Premović, Milena, Minić, Duško, "Thermal and microstructural analysis of the low-melting Bi-In-Pb alloy" in Metallurgical & Materials Engineering, 26, no. 4 (2020):385-394,
https://doi.org/10.30544/564 . .

The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites

Stajčić, Aleksandar; Radović, Ivana; Ćosović, Vladan; Grujić, Aleksandar; Stajić-Trošić, Jasna; Jančić-Heinemann, Radmila

(Belgrade : Association for ETRAN Society, 2019)

TY  - JOUR
AU  - Stajčić, Aleksandar
AU  - Radović, Ivana
AU  - Ćosović, Vladan
AU  - Grujić, Aleksandar
AU  - Stajić-Trošić, Jasna
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3232
AB  - This study presents preparation and characterization of ethyl cellulose based nanocomposites. Successful use of simple solvent casting technique provided nanocomposites with high loads of barium ferrite magnetic nanopowder in the polymer matrix, promising significant improvement of mechanical properties. Investigation of morphology revealed formation of agglomerates that are still on nanoscopic level. Nanocomposite thin films with a higher content of the magnetic powder showed substantial enhancement of break strength, elongation and microhardness compared to the pure ethyl cellulose, which was the primary aim of this research.
AB  - Ова студија представља припрему и карактеризацију нанокомпозита на бази етил целулозе. Успешна употреба једноставне технике изливања обезбедила је нанокомпозите са великим уделом магнетног нанопраха баријум ферита у полимерној матрици, обећавајући значајно побољшање механичких својстава. Истраживањем морфологије откривено је формирање агломерата који су и даље на наноскопском нивоу. Нанокомпозитни танки филмови са већим садржајем магнетног праха показали су значајно повећање прекидне чврстоће, издужења и микротврдоће у поређењу са чистом етил целулозом, што је био главни циљ овог истраживања.
PB  - Belgrade : Association for ETRAN Society
T2  - Science of Sintering
T1  - The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites
VL  - 51
IS  - 3
SP  - 277
EP  - 283
DO  - 10.2298/SOS1903277S
ER  - 
@article{
author = "Stajčić, Aleksandar and Radović, Ivana and Ćosović, Vladan and Grujić, Aleksandar and Stajić-Trošić, Jasna and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "This study presents preparation and characterization of ethyl cellulose based nanocomposites. Successful use of simple solvent casting technique provided nanocomposites with high loads of barium ferrite magnetic nanopowder in the polymer matrix, promising significant improvement of mechanical properties. Investigation of morphology revealed formation of agglomerates that are still on nanoscopic level. Nanocomposite thin films with a higher content of the magnetic powder showed substantial enhancement of break strength, elongation and microhardness compared to the pure ethyl cellulose, which was the primary aim of this research., Ова студија представља припрему и карактеризацију нанокомпозита на бази етил целулозе. Успешна употреба једноставне технике изливања обезбедила је нанокомпозите са великим уделом магнетног нанопраха баријум ферита у полимерној матрици, обећавајући значајно побољшање механичких својстава. Истраживањем морфологије откривено је формирање агломерата који су и даље на наноскопском нивоу. Нанокомпозитни танки филмови са већим садржајем магнетног праха показали су значајно повећање прекидне чврстоће, издужења и микротврдоће у поређењу са чистом етил целулозом, што је био главни циљ овог истраживања.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "Science of Sintering",
title = "The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites",
volume = "51",
number = "3",
pages = "277-283",
doi = "10.2298/SOS1903277S"
}
Stajčić, A., Radović, I., Ćosović, V., Grujić, A., Stajić-Trošić, J.,& Jančić-Heinemann, R.. (2019). The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites. in Science of Sintering
Belgrade : Association for ETRAN Society., 51(3), 277-283.
https://doi.org/10.2298/SOS1903277S
Stajčić A, Radović I, Ćosović V, Grujić A, Stajić-Trošić J, Jančić-Heinemann R. The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites. in Science of Sintering. 2019;51(3):277-283.
doi:10.2298/SOS1903277S .
Stajčić, Aleksandar, Radović, Ivana, Ćosović, Vladan, Grujić, Aleksandar, Stajić-Trošić, Jasna, Jančić-Heinemann, Radmila, "The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites" in Science of Sintering, 51, no. 3 (2019):277-283,
https://doi.org/10.2298/SOS1903277S . .
2
3
4

Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil

Mandić, Mina; Spasić, Jelena; Ponjavić, Marijana; Nikolić, Marija S.; Ćosović, Vladan; O'Connor, Kevin E.; Nikodinović-Runić, Jasmina; Đokić, Lidija; Jeremić, Sanja

(Elsevier, 2019)

TY  - JOUR
AU  - Mandić, Mina
AU  - Spasić, Jelena
AU  - Ponjavić, Marijana
AU  - Nikolić, Marija S.
AU  - Ćosović, Vladan
AU  - O'Connor, Kevin E.
AU  - Nikodinović-Runić, Jasmina
AU  - Đokić, Lidija
AU  - Jeremić, Sanja
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2955
AB  - Petrochemical plastics are generally recalcitrant to microbial degradation and accumulate in the environment. Biodegradable polymers obtained synthetically like poly(ε-caprolactone) (PCL) or polyhydroxyalkanoates (PHA), obtained biotechnologically, have shown great potential as a replacement for petroleum-based plastics. Nevertheless, their biodegradation and environmental faith have been less examined. In this study, thin films of PCL (200 μm) and medium chain length PHA (mcl-PHA, 70 M fraction of 3-hydroxyoctanoate and 30 M fraction of 3-hydroxydecanoate, 600 μm) were exposed to total protein preparations (extracellular proteins combined with a crude cell extract) of soil isolates Pseudomonas chlororaphis B-561 and Streptomyces sp. BV315 that had been grown on waste cooking oil as a sole carbon source. Biodegradation potential of two polyesters was evaluated in buffer with total protein preparations and in a laboratory compost model system augmented with selected bacteria. Overall, PCL showed better biodegradation properties in comparison to mcl-PHA. Both materials showed surface erosion after 4-weeks of exposure to total protein preparations of both strains, with a moderate weight loss of 1.3% when P. chlororaphis B-561 was utilized. In laboratory compost model system PCL and mcl-PHA showed significant weight loss ranging from 13 to 17% when Streptomyces sp. BV315 culture was used. Similar weight loss of PCL and mcl-PHA was achieved for 4 and 8 weeks, respectively indicating slower degradation of mcl-PHA. Growth on waste cooking oil as a sole carbon source increased the potential of both tested strains to degrade PCL and mcl-PHA, making them good candidates for augmentation of compost cultures in waste management of both waste cooking oils and biodegradable polymers.
PB  - Elsevier
T2  - Polymer Degradation and Stability
T1  - Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil
VL  - 162
SP  - 160
EP  - 168
DO  - 10.1016/j.polymdegradstab.2019.02.012
ER  - 
@article{
author = "Mandić, Mina and Spasić, Jelena and Ponjavić, Marijana and Nikolić, Marija S. and Ćosović, Vladan and O'Connor, Kevin E. and Nikodinović-Runić, Jasmina and Đokić, Lidija and Jeremić, Sanja",
year = "2019",
abstract = "Petrochemical plastics are generally recalcitrant to microbial degradation and accumulate in the environment. Biodegradable polymers obtained synthetically like poly(ε-caprolactone) (PCL) or polyhydroxyalkanoates (PHA), obtained biotechnologically, have shown great potential as a replacement for petroleum-based plastics. Nevertheless, their biodegradation and environmental faith have been less examined. In this study, thin films of PCL (200 μm) and medium chain length PHA (mcl-PHA, 70 M fraction of 3-hydroxyoctanoate and 30 M fraction of 3-hydroxydecanoate, 600 μm) were exposed to total protein preparations (extracellular proteins combined with a crude cell extract) of soil isolates Pseudomonas chlororaphis B-561 and Streptomyces sp. BV315 that had been grown on waste cooking oil as a sole carbon source. Biodegradation potential of two polyesters was evaluated in buffer with total protein preparations and in a laboratory compost model system augmented with selected bacteria. Overall, PCL showed better biodegradation properties in comparison to mcl-PHA. Both materials showed surface erosion after 4-weeks of exposure to total protein preparations of both strains, with a moderate weight loss of 1.3% when P. chlororaphis B-561 was utilized. In laboratory compost model system PCL and mcl-PHA showed significant weight loss ranging from 13 to 17% when Streptomyces sp. BV315 culture was used. Similar weight loss of PCL and mcl-PHA was achieved for 4 and 8 weeks, respectively indicating slower degradation of mcl-PHA. Growth on waste cooking oil as a sole carbon source increased the potential of both tested strains to degrade PCL and mcl-PHA, making them good candidates for augmentation of compost cultures in waste management of both waste cooking oils and biodegradable polymers.",
publisher = "Elsevier",
journal = "Polymer Degradation and Stability",
title = "Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil",
volume = "162",
pages = "160-168",
doi = "10.1016/j.polymdegradstab.2019.02.012"
}
Mandić, M., Spasić, J., Ponjavić, M., Nikolić, M. S., Ćosović, V., O'Connor, K. E., Nikodinović-Runić, J., Đokić, L.,& Jeremić, S.. (2019). Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil. in Polymer Degradation and Stability
Elsevier., 162, 160-168.
https://doi.org/10.1016/j.polymdegradstab.2019.02.012
Mandić M, Spasić J, Ponjavić M, Nikolić MS, Ćosović V, O'Connor KE, Nikodinović-Runić J, Đokić L, Jeremić S. Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil. in Polymer Degradation and Stability. 2019;162:160-168.
doi:10.1016/j.polymdegradstab.2019.02.012 .
Mandić, Mina, Spasić, Jelena, Ponjavić, Marijana, Nikolić, Marija S., Ćosović, Vladan, O'Connor, Kevin E., Nikodinović-Runić, Jasmina, Đokić, Lidija, Jeremić, Sanja, "Biodegradation of poly(ε-caprolactone) (PCL) and medium chain length polyhydroxyalkanoate (mcl-PHA) using whole cells and cell free protein preparations of Pseudomonas and Streptomyces strains grown on waste cooking oil" in Polymer Degradation and Stability, 162 (2019):160-168,
https://doi.org/10.1016/j.polymdegradstab.2019.02.012 . .
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