TY  - JOUR
AU  - Lović, Jelena
AU  - Mijin, Dušan
AU  - Jovanović, Mica B.
AU  - Glavaski, Olivera S
AU  - Zeremski, Tijana
AU  - Petrović, Slobodan D.
AU  - Avramov Ivić, Milka
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1944
AB  - Tebuconazole, a pesticide that presents risks for ecosystems, groundwater and human health, was degraded on a gold electrode as the catalyst in 0.05 M NaHCO3 using cyclic voltammetry (CV). First, tebuconazole was characterized on the gold electrode using CV and square wave voltammetry (SWV). The gold electrode, being highly sensitive, provided linear relationships (currents vs. concentrations) in the range: (0.076-0.76 mu mol dm(-3)). Based on the CV measurements, the investigated process is irreversible and diffusion controlled. The observed catalytic role of the Au electrode in the oxidation of tebuconazole and the data obtained from CV and SWV provided the experimental conditions for the degradation of tebuconazole. The degradation was performed by continuous cycling followed by gas chromatography mass spectroscopy (GC MS) analysis. This enabled the catalytic elimination of tebuconazole for 60 min, which promoted the use of a gold electrode as the catalyst for the degradation of environmental pollutants. The scheme of the possible mechanism of tebuconazole degradation is given.
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Paris
T2  - Comptes Rendus Chimie
T1  - An investigation of tebuconazole degradation using a gold electrode
VL  - 19
IS  - 5
SP  - 639
EP  - 645
DO  - 10.1016/j.crci.2016.01.014
ER  - 

@article{
author = "Lović, Jelena and Mijin, Dušan and Jovanović, Mica B. and Glavaski, Olivera S and Zeremski, Tijana and Petrović, Slobodan D. and Avramov Ivić, Milka",
year = "2016",
abstract = "Tebuconazole, a pesticide that presents risks for ecosystems, groundwater and human health, was degraded on a gold electrode as the catalyst in 0.05 M NaHCO3 using cyclic voltammetry (CV). First, tebuconazole was characterized on the gold electrode using CV and square wave voltammetry (SWV). The gold electrode, being highly sensitive, provided linear relationships (currents vs. concentrations) in the range: (0.076-0.76 mu mol dm(-3)). Based on the CV measurements, the investigated process is irreversible and diffusion controlled. The observed catalytic role of the Au electrode in the oxidation of tebuconazole and the data obtained from CV and SWV provided the experimental conditions for the degradation of tebuconazole. The degradation was performed by continuous cycling followed by gas chromatography mass spectroscopy (GC MS) analysis. This enabled the catalytic elimination of tebuconazole for 60 min, which promoted the use of a gold electrode as the catalyst for the degradation of environmental pollutants. The scheme of the possible mechanism of tebuconazole degradation is given.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Paris",
journal = "Comptes Rendus Chimie",
title = "An investigation of tebuconazole degradation using a gold electrode",
volume = "19",
number = "5",
pages = "639-645",
doi = "10.1016/j.crci.2016.01.014"
}

Lović, J., Mijin, D., Jovanović, M. B., Glavaski, O. S., Zeremski, T., Petrović, S. D.,& Avramov Ivić, M.. (2016). An investigation of tebuconazole degradation using a gold electrode. in Comptes Rendus Chimie
Elsevier France-Editions Scientifiques Medicales Elsevier, Paris., 19(5), 639-645.
https://doi.org/10.1016/j.crci.2016.01.014

Lović J, Mijin D, Jovanović MB, Glavaski OS, Zeremski T, Petrović SD, Avramov Ivić M. An investigation of tebuconazole degradation using a gold electrode. in Comptes Rendus Chimie. 2016;19(5):639-645.
doi:10.1016/j.crci.2016.01.014 .

Lović, Jelena, Mijin, Dušan, Jovanović, Mica B., Glavaski, Olivera S, Zeremski, Tijana, Petrović, Slobodan D., Avramov Ivić, Milka, "An investigation of tebuconazole degradation using a gold electrode" in Comptes Rendus Chimie, 19, no. 5 (2016):639-645,
https://doi.org/10.1016/j.crci.2016.01.014 . .

TY  - JOUR
AU  - Glavaski, O S
AU  - Petrovic, S D
AU  - Mijin, Dušan
AU  - Jovanović, Mica B.
AU  - Dugandzic, A M
AU  - Zeremski, Tijana
AU  - Avramov Ivić, Milka
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1393
AB  - For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes
VL  - 26
IS  - 9
SP  - 1877
EP  - 1880
DO  - 10.1002/elan.201400249
ER  - 

@article{
author = "Glavaski, O S and Petrovic, S D and Mijin, Dušan and Jovanović, Mica B. and Dugandzic, A M and Zeremski, Tijana and Avramov Ivić, Milka",
year = "2014",
abstract = "For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes",
volume = "26",
number = "9",
pages = "1877-1880",
doi = "10.1002/elan.201400249"
}

Glavaski, O. S., Petrovic, S. D., Mijin, D., Jovanović, M. B., Dugandzic, A. M., Zeremski, T.,& Avramov Ivić, M.. (2014). Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis
Wiley-Blackwell, Malden., 26(9), 1877-1880.
https://doi.org/10.1002/elan.201400249

Glavaski OS, Petrovic SD, Mijin D, Jovanović MB, Dugandzic AM, Zeremski T, Avramov Ivić M. Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis. 2014;26(9):1877-1880.
doi:10.1002/elan.201400249 .

Glavaski, O S, Petrovic, S D, Mijin, Dušan, Jovanović, Mica B., Dugandzic, A M, Zeremski, Tijana, Avramov Ivić, Milka, "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes" in Electroanalysis, 26, no. 9 (2014):1877-1880,
https://doi.org/10.1002/elan.201400249 . .

TY  - JOUR
AU  - Bulat, Petar
AU  - Avramov Ivić, Milka
AU  - Jovanović, Mica B.
AU  - Petrović, Slobodan D.
AU  - Miljus, Dragan
AU  - Todorovic, Tanja
AU  - Miladinov-Mikov, Marica M.
AU  - Bogdanovic, Milka
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/884
AB  - There is growing concern that pollution from petrochemical and oil refinery installations in Pancevo (Serbia) has increased the incidence of various diseases including cancer The aim of our study was to investigate cancer incidence in Pancevo and to compare it with the region of central Serbia. Cancer incidence data were obtained from the corresponding Serbian Cancer Registries. Systematic local monitoring of benzene, toluene and methyl mercaptane in the atmosphere within Pancevo's industrial area indicated that the average monthly and yearly concentrations often exceeded permitted levels proposed by EU standards (5 mu gm(-3)). Cancer incidence was lower in Pancevo than in central Serbia (the standardised incidence for all types of cancers in Pancevo was 218.3 and in central Serbia it was 241.7 per 100,000 inhabitants). The available data do not allow us to correlate air pollution in Pancevo with increased cancer incidence.
PB  - Collegium Antropologicum, Zagreb
T2  - Collegium Antropologicum
T1  - Cancer Incidence in a Population Living Near a Petrochemical Facility and Oil Refinery
VL  - 35
IS  - 2
SP  - 377
EP  - 383
UR  - https://hdl.handle.net/21.15107/rcub_cer_884
ER  - 

@article{
author = "Bulat, Petar and Avramov Ivić, Milka and Jovanović, Mica B. and Petrović, Slobodan D. and Miljus, Dragan and Todorovic, Tanja and Miladinov-Mikov, Marica M. and Bogdanovic, Milka",
year = "2011",
abstract = "There is growing concern that pollution from petrochemical and oil refinery installations in Pancevo (Serbia) has increased the incidence of various diseases including cancer The aim of our study was to investigate cancer incidence in Pancevo and to compare it with the region of central Serbia. Cancer incidence data were obtained from the corresponding Serbian Cancer Registries. Systematic local monitoring of benzene, toluene and methyl mercaptane in the atmosphere within Pancevo's industrial area indicated that the average monthly and yearly concentrations often exceeded permitted levels proposed by EU standards (5 mu gm(-3)). Cancer incidence was lower in Pancevo than in central Serbia (the standardised incidence for all types of cancers in Pancevo was 218.3 and in central Serbia it was 241.7 per 100,000 inhabitants). The available data do not allow us to correlate air pollution in Pancevo with increased cancer incidence.",
publisher = "Collegium Antropologicum, Zagreb",
journal = "Collegium Antropologicum",
title = "Cancer Incidence in a Population Living Near a Petrochemical Facility and Oil Refinery",
volume = "35",
number = "2",
pages = "377-383",
url = "https://hdl.handle.net/21.15107/rcub_cer_884"
}

Bulat, P., Avramov Ivić, M., Jovanović, M. B., Petrović, S. D., Miljus, D., Todorovic, T., Miladinov-Mikov, M. M.,& Bogdanovic, M.. (2011). Cancer Incidence in a Population Living Near a Petrochemical Facility and Oil Refinery. in Collegium Antropologicum
Collegium Antropologicum, Zagreb., 35(2), 377-383.
https://hdl.handle.net/21.15107/rcub_cer_884

Bulat P, Avramov Ivić M, Jovanović MB, Petrović SD, Miljus D, Todorovic T, Miladinov-Mikov MM, Bogdanovic M. Cancer Incidence in a Population Living Near a Petrochemical Facility and Oil Refinery. in Collegium Antropologicum. 2011;35(2):377-383.
https://hdl.handle.net/21.15107/rcub_cer_884 .

Bulat, Petar, Avramov Ivić, Milka, Jovanović, Mica B., Petrović, Slobodan D., Miljus, Dragan, Todorovic, Tanja, Miladinov-Mikov, Marica M., Bogdanovic, Milka, "Cancer Incidence in a Population Living Near a Petrochemical Facility and Oil Refinery" in Collegium Antropologicum, 35, no. 2 (2011):377-383,
https://hdl.handle.net/21.15107/rcub_cer_884 .

TY  - JOUR
AU  - Tomasević, Andjelka V.
AU  - Avramov Ivić, Milka
AU  - Petrović, Slobodan D.
AU  - Jovanović, Mica B.
AU  - Mijin, Dušan
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/534
AB  - A gold electrode was used for the qualitative and quantitative electrochemical determination of analytical methomyl in a neutral electrolyte (0.050 M NaHCO3) using cyclic linear sweep voltammetry. In the potential range from -800 mV vs. SCE to 1000 mV vs. SCE the analytical methomyl was quantitatively determined in the concentration range 4.0-16 mg L-1. In the potential range from -1300 mV vs. SCE to 1300 mV vs. SCE, methomyl was qualitatively determined by two anodic and four cathodic reactions. Cycling the potential in this range for 150 min caused the degradation of the molecule, which was confirmed by HPLC analysis. On the other hand, technical methomyl exhibited an inhibition of the gold electrode surface due to the impurities.
AB  - U radu su dati rezultati ispitivanja elektrohemijskog ponašanja aktivnosti metomila (analitičkog i tehničkog proizvoda) na elektrodi od zlata u neutralnom elektrolitu (0,050 M NaHCO3). HPLC je korišćena za analizu elektrolita u toku elektrohemijske reakcije. Maksimalna vrednost visine strujnog vrha oksidacije čistog metomila na 600 mV prema ZKE u 0,050 M NaHCO3 na 50 mV s-1 je linearna funkcija njegove koncentracije u opsegu 4-16 mg L-1 što je omogućilo razvijanje metode za njegovo kvantitativno određiva- nje. Analitički metomil je kvalitativno određen detekcijom reproduktivne četiri anodne i jedne katodne reakcije u opsegu potencijala od -1300 do 1300 mV prema ZKE. Potencijal je cikliziran 150 min u navedenom opsegu i analiza anodnih i katodnih reakcija na početku, u toku i na kraju cikliziranja potencijala je ukazala na degradaciju molekula metomila. Tokom cikliziranja potencijala, HPLC analiza elektrolita je pokazala smanjenje koncentracija metomila kao posledicu njegove degradacije. Tehnički metomil nije pogodan za ispitivanje pod navedenim uslovima jer prisutne nečistoće inhibiraju površinu elektrode.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - A study of the electrochemical behavior of methomyl on a gold electrode in a neutral electrolyte
T1  - Proučavanje elektrohemijskog ponašanja metomila na elektrodi od zlata u neutralnom elektrolitu
VL  - 74
IS  - 5
SP  - 573
EP  - 579
DO  - 10.2298/JSC0905573T
ER  - 

@article{
author = "Tomasević, Andjelka V. and Avramov Ivić, Milka and Petrović, Slobodan D. and Jovanović, Mica B. and Mijin, Dušan",
year = "2009",
abstract = "A gold electrode was used for the qualitative and quantitative electrochemical determination of analytical methomyl in a neutral electrolyte (0.050 M NaHCO3) using cyclic linear sweep voltammetry. In the potential range from -800 mV vs. SCE to 1000 mV vs. SCE the analytical methomyl was quantitatively determined in the concentration range 4.0-16 mg L-1. In the potential range from -1300 mV vs. SCE to 1300 mV vs. SCE, methomyl was qualitatively determined by two anodic and four cathodic reactions. Cycling the potential in this range for 150 min caused the degradation of the molecule, which was confirmed by HPLC analysis. On the other hand, technical methomyl exhibited an inhibition of the gold electrode surface due to the impurities., U radu su dati rezultati ispitivanja elektrohemijskog ponašanja aktivnosti metomila (analitičkog i tehničkog proizvoda) na elektrodi od zlata u neutralnom elektrolitu (0,050 M NaHCO3). HPLC je korišćena za analizu elektrolita u toku elektrohemijske reakcije. Maksimalna vrednost visine strujnog vrha oksidacije čistog metomila na 600 mV prema ZKE u 0,050 M NaHCO3 na 50 mV s-1 je linearna funkcija njegove koncentracije u opsegu 4-16 mg L-1 što je omogućilo razvijanje metode za njegovo kvantitativno određiva- nje. Analitički metomil je kvalitativno određen detekcijom reproduktivne četiri anodne i jedne katodne reakcije u opsegu potencijala od -1300 do 1300 mV prema ZKE. Potencijal je cikliziran 150 min u navedenom opsegu i analiza anodnih i katodnih reakcija na početku, u toku i na kraju cikliziranja potencijala je ukazala na degradaciju molekula metomila. Tokom cikliziranja potencijala, HPLC analiza elektrolita je pokazala smanjenje koncentracija metomila kao posledicu njegove degradacije. Tehnički metomil nije pogodan za ispitivanje pod navedenim uslovima jer prisutne nečistoće inhibiraju površinu elektrode.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "A study of the electrochemical behavior of methomyl on a gold electrode in a neutral electrolyte, Proučavanje elektrohemijskog ponašanja metomila na elektrodi od zlata u neutralnom elektrolitu",
volume = "74",
number = "5",
pages = "573-579",
doi = "10.2298/JSC0905573T"
}

Tomasević, A. V., Avramov Ivić, M., Petrović, S. D., Jovanović, M. B.,& Mijin, D.. (2009). A study of the electrochemical behavior of methomyl on a gold electrode in a neutral electrolyte. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 74(5), 573-579.
https://doi.org/10.2298/JSC0905573T

Tomasević AV, Avramov Ivić M, Petrović SD, Jovanović MB, Mijin D. A study of the electrochemical behavior of methomyl on a gold electrode in a neutral electrolyte. in Journal of the Serbian Chemical Society. 2009;74(5):573-579.
doi:10.2298/JSC0905573T .

Tomasević, Andjelka V., Avramov Ivić, Milka, Petrović, Slobodan D., Jovanović, Mica B., Mijin, Dušan, "A study of the electrochemical behavior of methomyl on a gold electrode in a neutral electrolyte" in Journal of the Serbian Chemical Society, 74, no. 5 (2009):573-579,
https://doi.org/10.2298/JSC0905573T . .

TY  - JOUR
AU  - Avramov Ivić, Milka
AU  - Petrović, Slobodan D.
AU  - Mijin, Dušan
AU  - Živković, Predrag M.
AU  - Kosovic, IM
AU  - Drjevic, KM
AU  - Jovanović, Mica B.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/237
AB  - The aim of the present study was to examine the oxidative properties and an assay of azithromycin and Hemomycin (R) at a gold electrode in neutral electrolyte using cyclic linear sweep voltammetry. The maximum value of the current of the oxidation peak of pure azithromycin and azithromycin from Hemomycin (R) at 0.6 V versus SCE in 0.05 M NaHCO3 and in a mixture methanol -0.05 M NaHCO3 (1:1) at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range of 0.235-0.588 mg/cm(3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the values of the current peak concerning the concentration of antibiotic in the investigated concentration range. The role of methanol, when present, is discussed. In the case of azithromycin, the presence of methanol leads to higher current peak values. However, in the case of Hemonlycin (R), methanol should be avoided because of its inhibiting influence on the qualitative and quantitative determination of azithromycin and on the azithromycin/lactose, separation.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Electrochimica Acta
T1  - Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte
VL  - 51
IS  - 12
SP  - 2407
EP  - 2416
DO  - 10.1016/j.electacta.2005.07.032
ER  - 

@article{
author = "Avramov Ivić, Milka and Petrović, Slobodan D. and Mijin, Dušan and Živković, Predrag M. and Kosovic, IM and Drjevic, KM and Jovanović, Mica B.",
year = "2006",
abstract = "The aim of the present study was to examine the oxidative properties and an assay of azithromycin and Hemomycin (R) at a gold electrode in neutral electrolyte using cyclic linear sweep voltammetry. The maximum value of the current of the oxidation peak of pure azithromycin and azithromycin from Hemomycin (R) at 0.6 V versus SCE in 0.05 M NaHCO3 and in a mixture methanol -0.05 M NaHCO3 (1:1) at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range of 0.235-0.588 mg/cm(3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the values of the current peak concerning the concentration of antibiotic in the investigated concentration range. The role of methanol, when present, is discussed. In the case of azithromycin, the presence of methanol leads to higher current peak values. However, in the case of Hemonlycin (R), methanol should be avoided because of its inhibiting influence on the qualitative and quantitative determination of azithromycin and on the azithromycin/lactose, separation.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Electrochimica Acta",
title = "Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte",
volume = "51",
number = "12",
pages = "2407-2416",
doi = "10.1016/j.electacta.2005.07.032"
}

Avramov Ivić, M., Petrović, S. D., Mijin, D., Živković, P. M., Kosovic, I., Drjevic, K.,& Jovanović, M. B.. (2006). Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte. in Electrochimica Acta
Oxford : Pergamon-Elsevier Science Ltd., 51(12), 2407-2416.
https://doi.org/10.1016/j.electacta.2005.07.032

Avramov Ivić M, Petrović SD, Mijin D, Živković PM, Kosovic I, Drjevic K, Jovanović MB. Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte. in Electrochimica Acta. 2006;51(12):2407-2416.
doi:10.1016/j.electacta.2005.07.032 .

Avramov Ivić, Milka, Petrović, Slobodan D., Mijin, Dušan, Živković, Predrag M., Kosovic, IM, Drjevic, KM, Jovanović, Mica B., "Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte" in Electrochimica Acta, 51, no. 12 (2006):2407-2416,
https://doi.org/10.1016/j.electacta.2005.07.032 . .