Jovićević, Niko

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  • Jovićević, Niko (6)
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Author's Bibliography

Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt

Vukićević, Nataša; Cvetković, Vesna S.; Jovićević, Niko; Jovićević, Jovan N.

(Belgrade : ESG, 2021)

TY  - JOUR
AU  - Vukićević, Nataša
AU  - Cvetković, Vesna S.
AU  - Jovićević, Niko
AU  - Jovićević, Jovan N.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4679
AB  - The possibility of electrochemical underpotential deposition of aluminium onto palladium from equimolar AlCl3+NaCl melts at temperatures between 200 ° and 300 °C was investigated. Electrochemical techniques used were cyclic voltammetry, chronoamperometry, potentiodynamic polarization and open circuit measurements. The results were analyzed by SEM, EDX and XRD. It was found that аluminium deposits underpotentially onto palladium at around 0.200 V vs. Al from the chloroaluminate melt used. It was established that under the given conditions, Al underpotential deposition onto the palladium substrate can result in AlPd and Al3Pd4 alloy synthesis by solid-state interdiffusion. The surface alloys synthetized are well adhering, microcrystalline deposits, having highly developed surface area suitable for applications such as hydrogen purification filters.
PB  - Belgrade : ESG
T2  - International Journal of Electrochemical Science
T1  - Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt
VL  - 16
IS  - 1
SP  - 210663
DO  - 10.20964/2021.06.62
ER  - 
@article{
author = "Vukićević, Nataša and Cvetković, Vesna S. and Jovićević, Niko and Jovićević, Jovan N.",
year = "2021",
abstract = "The possibility of electrochemical underpotential deposition of aluminium onto palladium from equimolar AlCl3+NaCl melts at temperatures between 200 ° and 300 °C was investigated. Electrochemical techniques used were cyclic voltammetry, chronoamperometry, potentiodynamic polarization and open circuit measurements. The results were analyzed by SEM, EDX and XRD. It was found that аluminium deposits underpotentially onto palladium at around 0.200 V vs. Al from the chloroaluminate melt used. It was established that under the given conditions, Al underpotential deposition onto the palladium substrate can result in AlPd and Al3Pd4 alloy synthesis by solid-state interdiffusion. The surface alloys synthetized are well adhering, microcrystalline deposits, having highly developed surface area suitable for applications such as hydrogen purification filters.",
publisher = "Belgrade : ESG",
journal = "International Journal of Electrochemical Science",
title = "Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt",
volume = "16",
number = "1",
pages = "210663",
doi = "10.20964/2021.06.62"
}
Vukićević, N., Cvetković, V. S., Jovićević, N.,& Jovićević, J. N.. (2021). Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt. in International Journal of Electrochemical Science
Belgrade : ESG., 16(1), 210663.
https://doi.org/10.20964/2021.06.62
Vukićević N, Cvetković VS, Jovićević N, Jovićević JN. Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt. in International Journal of Electrochemical Science. 2021;16(1):210663.
doi:10.20964/2021.06.62 .
Vukićević, Nataša, Cvetković, Vesna S., Jovićević, Niko, Jovićević, Jovan N., "Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt" in International Journal of Electrochemical Science, 16, no. 1 (2021):210663,
https://doi.org/10.20964/2021.06.62 . .
1

Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature

Cvetković, Vesna S.; Vukićević, Nataša; Jovićević, Niko; Stevanović, Jasmina; Jovićević, Jovan N.

(Elsevier, 2020)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Vukićević, Nataša
AU  - Jovićević, Niko
AU  - Stevanović, Jasmina
AU  - Jovićević, Jovan N.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3486
AB  - The electrodeposition of aluminium on glassy carbon and aluminium substrates from AlCl3–urea deep eutectic solvent (DES) system at near room temperatures was investigated, without additional purification of the chemicals used to prepare the electrolyte and without rigorous control of moisture and oxygen present in the working space. The effects of changing temperature, working potential, controlled deposition current density and deposition time on the morphology of deposited aluminium without stirring of the electrolyte were recorded. Using potentiostatic and galvanostatic techniques, aluminium was electrodeposited from the deep eutectic solvent (n(AlCl3):n(urea)=1.6:1) onto glassy carbon and aluminium substrates at temperatures ranging from 25 to 50 °C. Using SEM, EDS and XRD techniques, substrates were studied and confirmed the presence of aluminium deposits following both potentiostatic and galvanostatic regimes. The shape and size of Al grains deposited depended on the time of deposition and varied in size from nanometers to micrometers and in shape from regular crystal forms to needle-like and flake-like structures.
PB  - Elsevier
T2  - Transactions of Nonferrous Metals Society of China
T1  - Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature
VL  - 30
IS  - 3
SP  - 823
EP  - 834
DO  - 10.1016/S1003-6326(20)65257-8
ER  - 
@article{
author = "Cvetković, Vesna S. and Vukićević, Nataša and Jovićević, Niko and Stevanović, Jasmina and Jovićević, Jovan N.",
year = "2020",
abstract = "The electrodeposition of aluminium on glassy carbon and aluminium substrates from AlCl3–urea deep eutectic solvent (DES) system at near room temperatures was investigated, without additional purification of the chemicals used to prepare the electrolyte and without rigorous control of moisture and oxygen present in the working space. The effects of changing temperature, working potential, controlled deposition current density and deposition time on the morphology of deposited aluminium without stirring of the electrolyte were recorded. Using potentiostatic and galvanostatic techniques, aluminium was electrodeposited from the deep eutectic solvent (n(AlCl3):n(urea)=1.6:1) onto glassy carbon and aluminium substrates at temperatures ranging from 25 to 50 °C. Using SEM, EDS and XRD techniques, substrates were studied and confirmed the presence of aluminium deposits following both potentiostatic and galvanostatic regimes. The shape and size of Al grains deposited depended on the time of deposition and varied in size from nanometers to micrometers and in shape from regular crystal forms to needle-like and flake-like structures.",
publisher = "Elsevier",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature",
volume = "30",
number = "3",
pages = "823-834",
doi = "10.1016/S1003-6326(20)65257-8"
}
Cvetković, V. S., Vukićević, N., Jovićević, N., Stevanović, J.,& Jovićević, J. N.. (2020). Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature. in Transactions of Nonferrous Metals Society of China
Elsevier., 30(3), 823-834.
https://doi.org/10.1016/S1003-6326(20)65257-8
Cvetković VS, Vukićević N, Jovićević N, Stevanović J, Jovićević JN. Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature. in Transactions of Nonferrous Metals Society of China. 2020;30(3):823-834.
doi:10.1016/S1003-6326(20)65257-8 .
Cvetković, Vesna S., Vukićević, Nataša, Jovićević, Niko, Stevanović, Jasmina, Jovićević, Jovan N., "Aluminium electrodeposition under novel conditions from AlCl3–urea deep eutectic solvent at room temperature" in Transactions of Nonferrous Metals Society of China, 30, no. 3 (2020):823-834,
https://doi.org/10.1016/S1003-6326(20)65257-8 . .
24
9
22

Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts

Cvetković, Vesna S.; Jovićević, Niko; Vukićević, Nataša; Jovićević, Jovan N.

(Belgrade : Serbian Chemical Society, 2019)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Jovićević, Niko
AU  - Vukićević, Nataša
AU  - Jovićević, Jovan N.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3381
AB  - Contrary to the widely accepted hypothesis that it is not possible, aluminum underpotential deposition (UPD) onto zirconium from a low temperature (200, 250 and 300 °C) equimolar chloroaluminate melt was recorded. Furthermore, it was shown that aluminum UPD facilitates alloy formation between the deposited aluminum monolayer and the zirconium substrate by interdiffusion. The aluminum/zirconium alloys formed at temperatures substantially lower than those needed for thermal preparation of the same alloys were Al3Zr2 and Al3Zr. The experimental techniques linear sweep voltammetry, potential step, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used for the characterization of the obtained electrode surfaces.
AB  - Насупрот широко прихваћеној хипотези по којој то није вероватно, установљено је постојање електрохемијског таложења алуминијума при потпотенцијалу на цирконијуму из нискотемпературног (200, 250 и 300 °C) еквимоларног хлороалуминатног растопа. Надаље, показано је да електрохемијско таложење алуминијума при потпотенцијалу омогућава формирање легура између исталоженог монослоја алуминијума и цирконијумове подлоге путем интердифузије. Легуре алуминијума и цирконијума
Al3Zr2 и Al3Zr формиране су на температурама које су значајно мање од оних потребних
за термичко припремање таквих легура. Коришћене експерименталне технике биле су
линеарне цикличка волтаметрија и потенциостатски пулс, скенирајућа електронска
микроскопија, енергетско дисперзивна спектроскопија и дифракција Х-зрака коришћене су за карактеризацију добијене електродне површине.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts
T1  - Легуре алуминијума и цирконијума добијене електрохемијским таложењем алуминијума при потпотенцијалу на цирконијуму из нискотемпературних AlCl3+NaCl растопа
VL  - 84
IS  - 11
SP  - 1329
EP  - 1344
DO  - 10.2298/JSC190620073C
ER  - 
@article{
author = "Cvetković, Vesna S. and Jovićević, Niko and Vukićević, Nataša and Jovićević, Jovan N.",
year = "2019",
abstract = "Contrary to the widely accepted hypothesis that it is not possible, aluminum underpotential deposition (UPD) onto zirconium from a low temperature (200, 250 and 300 °C) equimolar chloroaluminate melt was recorded. Furthermore, it was shown that aluminum UPD facilitates alloy formation between the deposited aluminum monolayer and the zirconium substrate by interdiffusion. The aluminum/zirconium alloys formed at temperatures substantially lower than those needed for thermal preparation of the same alloys were Al3Zr2 and Al3Zr. The experimental techniques linear sweep voltammetry, potential step, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used for the characterization of the obtained electrode surfaces., Насупрот широко прихваћеној хипотези по којој то није вероватно, установљено је постојање електрохемијског таложења алуминијума при потпотенцијалу на цирконијуму из нискотемпературног (200, 250 и 300 °C) еквимоларног хлороалуминатног растопа. Надаље, показано је да електрохемијско таложење алуминијума при потпотенцијалу омогућава формирање легура између исталоженог монослоја алуминијума и цирконијумове подлоге путем интердифузије. Легуре алуминијума и цирконијума
Al3Zr2 и Al3Zr формиране су на температурама које су значајно мање од оних потребних
за термичко припремање таквих легура. Коришћене експерименталне технике биле су
линеарне цикличка волтаметрија и потенциостатски пулс, скенирајућа електронска
микроскопија, енергетско дисперзивна спектроскопија и дифракција Х-зрака коришћене су за карактеризацију добијене електродне површине.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts, Легуре алуминијума и цирконијума добијене електрохемијским таложењем алуминијума при потпотенцијалу на цирконијуму из нискотемпературних AlCl3+NaCl растопа",
volume = "84",
number = "11",
pages = "1329-1344",
doi = "10.2298/JSC190620073C"
}
Cvetković, V. S., Jovićević, N., Vukićević, N.,& Jovićević, J. N.. (2019). Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 84(11), 1329-1344.
https://doi.org/10.2298/JSC190620073C
Cvetković VS, Jovićević N, Vukićević N, Jovićević JN. Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts. in Journal of the Serbian Chemical Society. 2019;84(11):1329-1344.
doi:10.2298/JSC190620073C .
Cvetković, Vesna S., Jovićević, Niko, Vukićević, Nataša, Jovićević, Jovan N., "Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1329-1344,
https://doi.org/10.2298/JSC190620073C . .
2
2
3

Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte

Cvetković, Vesna S.; Vukićević, Nataša M.; Jovićević, Niko; Jovićević, Jovan N.

(International Society of Electrochemistry, 2018)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Vukićević, Nataša M.
AU  - Jovićević, Niko
AU  - Jovićević, Jovan N.
PY  - 2018
UR  - http://annual69.ise-online.org
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6154
AB  - Electrochemical deposition/dissolution of aluminium to/from aluminium in deep eutectic solvent
(DES), made of the AlCl3+urea, at temperatures of 25 to 60°C have been investigated. The depositions were performed in potentiostatic modes. The morphology of the obtained deposits was characterized using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS).
Critical overpotential of aluminium deposition increased from around – 0.120 V at 25°C to
around – 0.050 V at 50°C. All recorded currents were generally speaking small, but would substantially increase with increasing working temperature (from 0.01 mA cm-2 up to 0.25 mA cm-2). Current/time transients recorded at overpotentials over – 0.100 V vs. Al indicate continuous three-dimensional nucleation and growth. Epitaxial growth over aluminium substrate was not observed under applied experimental conditions.
Electrodeposition/dissolution processes of aluminium under chosen conditions were reversible,
reproducible and slow (relatively small current densities, bellow 0.3 mA cm-2). Polarization curves
recorded noticeable dependence of aluminium deposition/dissolution reversible potential on temperature applied.
The deposits obtained showed variety of morphological shapes (needles, rods, flakes, Fig.1)
depending on the working temperature and potential applied. All the deposits were made of crystallites grouped randomly into more or less separate agglomerates which were positioned over lower layer of densely populated much smaller crystallites. Lower layer showed good adherence to the substrate and exhibited high surface area. Density of the crystallites distribution over the substrate and complicity of the crystal forms increased with the potentials applied.
PB  - International Society of Electrochemistry
C3  - 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy
T1  - Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte
UR  - https://hdl.handle.net/21.15107/rcub_cer_6154
ER  - 
@conference{
author = "Cvetković, Vesna S. and Vukićević, Nataša M. and Jovićević, Niko and Jovićević, Jovan N.",
year = "2018",
abstract = "Electrochemical deposition/dissolution of aluminium to/from aluminium in deep eutectic solvent
(DES), made of the AlCl3+urea, at temperatures of 25 to 60°C have been investigated. The depositions were performed in potentiostatic modes. The morphology of the obtained deposits was characterized using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS).
Critical overpotential of aluminium deposition increased from around – 0.120 V at 25°C to
around – 0.050 V at 50°C. All recorded currents were generally speaking small, but would substantially increase with increasing working temperature (from 0.01 mA cm-2 up to 0.25 mA cm-2). Current/time transients recorded at overpotentials over – 0.100 V vs. Al indicate continuous three-dimensional nucleation and growth. Epitaxial growth over aluminium substrate was not observed under applied experimental conditions.
Electrodeposition/dissolution processes of aluminium under chosen conditions were reversible,
reproducible and slow (relatively small current densities, bellow 0.3 mA cm-2). Polarization curves
recorded noticeable dependence of aluminium deposition/dissolution reversible potential on temperature applied.
The deposits obtained showed variety of morphological shapes (needles, rods, flakes, Fig.1)
depending on the working temperature and potential applied. All the deposits were made of crystallites grouped randomly into more or less separate agglomerates which were positioned over lower layer of densely populated much smaller crystallites. Lower layer showed good adherence to the substrate and exhibited high surface area. Density of the crystallites distribution over the substrate and complicity of the crystal forms increased with the potentials applied.",
publisher = "International Society of Electrochemistry",
journal = "69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy",
title = "Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte",
url = "https://hdl.handle.net/21.15107/rcub_cer_6154"
}
Cvetković, V. S., Vukićević, N. M., Jovićević, N.,& Jovićević, J. N.. (2018). Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte. in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy
International Society of Electrochemistry..
https://hdl.handle.net/21.15107/rcub_cer_6154
Cvetković VS, Vukićević NM, Jovićević N, Jovićević JN. Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte. in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy. 2018;.
https://hdl.handle.net/21.15107/rcub_cer_6154 .
Cvetković, Vesna S., Vukićević, Nataša M., Jovićević, Niko, Jovićević, Jovan N., "Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte" in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy (2018),
https://hdl.handle.net/21.15107/rcub_cer_6154 .

Aluminium underpotential deposition onto zirconium

Cvetković, Vesna S.; Jovićević, Niko; Vukićević, Nataša

(University of Belgrade - Technical Faculty in Bor, 2017)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Jovićević, Niko
AU  - Vukićević, Nataša
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5871
AB  - Attempts were made to electrodeposit aluminium at aluminium underpotential-UPD from a low
temperature equimolar ch/oroa/uminate melt (200 °C, 250 °C and 300 °C) onto zirconium. Experimental techniques used were linear sweep voltammetry, potential step and analytical techniques were scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. Contrary to the widely accepted hypothesis aluminium UPD on zirconium was observed. It was shown that aluminium UPD facilitates alloy formation between the deposited aluminium monolayer and the zirconium substrate by interdiffusion. XRD analysis revealed a number of aluminium/zirconium alloys formed at the temperatures substantially lower than those needed for thermal preparation of those same alloys.
PB  - University of Belgrade - Technical Faculty in Bor
C3  - Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia
T1  - Aluminium underpotential deposition onto zirconium
SP  - 241
EP  - 244
UR  - https://hdl.handle.net/21.15107/rcub_cer_5871
ER  - 
@conference{
author = "Cvetković, Vesna S. and Jovićević, Niko and Vukićević, Nataša",
year = "2017",
abstract = "Attempts were made to electrodeposit aluminium at aluminium underpotential-UPD from a low
temperature equimolar ch/oroa/uminate melt (200 °C, 250 °C and 300 °C) onto zirconium. Experimental techniques used were linear sweep voltammetry, potential step and analytical techniques were scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. Contrary to the widely accepted hypothesis aluminium UPD on zirconium was observed. It was shown that aluminium UPD facilitates alloy formation between the deposited aluminium monolayer and the zirconium substrate by interdiffusion. XRD analysis revealed a number of aluminium/zirconium alloys formed at the temperatures substantially lower than those needed for thermal preparation of those same alloys.",
publisher = "University of Belgrade - Technical Faculty in Bor",
journal = "Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia",
title = "Aluminium underpotential deposition onto zirconium",
pages = "241-244",
url = "https://hdl.handle.net/21.15107/rcub_cer_5871"
}
Cvetković, V. S., Jovićević, N.,& Vukićević, N.. (2017). Aluminium underpotential deposition onto zirconium. in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia
University of Belgrade - Technical Faculty in Bor., 241-244.
https://hdl.handle.net/21.15107/rcub_cer_5871
Cvetković VS, Jovićević N, Vukićević N. Aluminium underpotential deposition onto zirconium. in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia. 2017;:241-244.
https://hdl.handle.net/21.15107/rcub_cer_5871 .
Cvetković, Vesna S., Jovićević, Niko, Vukićević, Nataša, "Aluminium underpotential deposition onto zirconium" in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia (2017):241-244,
https://hdl.handle.net/21.15107/rcub_cer_5871 .

Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt

Cvetković, Vesna S.; Jovićević, Niko; Vukićević, Nataša; Jovićević, Jovan N.

(European Chemical Society, 2016)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Jovićević, Niko
AU  - Vukićević, Nataša
AU  - Jovićević, Jovan N.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5922
AB  - Aluminium was underpotentially deposited onto palladium substrate from the equimolar AlCl3+NaCl melt at 250º and 300 ºC. Electrochemical methods used were linear sweep voltammetry and potential step. The obtained samples were analysed by scanning electron microscopy, energy dispersive spectroscopy, atomic force microscopy and X-ray diffraction. The aluminium underpotential deposition is followed by interdiffusion of very thin Al deposit and Pd substrate which lead to the formation of surface Al-Pd intermetallic compounds. The constant-potential regions measured during the low-current stripping method corresponded to the coexistence of three pairs of the metallicintermetallic phases. This indicated that formation of Al-Pd alloys in a very controlled way and under technologically suitable conditions can be done at temperatures equal to and below 250ºC.
PB  - European Chemical Society
C3  - 6th EuCheMS Chemistry congress, 11 - 15 September, 2016, Seville, Spain
T1  - Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt
UR  - https://hdl.handle.net/21.15107/rcub_cer_5922
ER  - 
@conference{
author = "Cvetković, Vesna S. and Jovićević, Niko and Vukićević, Nataša and Jovićević, Jovan N.",
year = "2016",
abstract = "Aluminium was underpotentially deposited onto palladium substrate from the equimolar AlCl3+NaCl melt at 250º and 300 ºC. Electrochemical methods used were linear sweep voltammetry and potential step. The obtained samples were analysed by scanning electron microscopy, energy dispersive spectroscopy, atomic force microscopy and X-ray diffraction. The aluminium underpotential deposition is followed by interdiffusion of very thin Al deposit and Pd substrate which lead to the formation of surface Al-Pd intermetallic compounds. The constant-potential regions measured during the low-current stripping method corresponded to the coexistence of three pairs of the metallicintermetallic phases. This indicated that formation of Al-Pd alloys in a very controlled way and under technologically suitable conditions can be done at temperatures equal to and below 250ºC.",
publisher = "European Chemical Society",
journal = "6th EuCheMS Chemistry congress, 11 - 15 September, 2016, Seville, Spain",
title = "Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt",
url = "https://hdl.handle.net/21.15107/rcub_cer_5922"
}
Cvetković, V. S., Jovićević, N., Vukićević, N.,& Jovićević, J. N.. (2016). Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt. in 6th EuCheMS Chemistry congress, 11 - 15 September, 2016, Seville, Spain
European Chemical Society..
https://hdl.handle.net/21.15107/rcub_cer_5922
Cvetković VS, Jovićević N, Vukićević N, Jovićević JN. Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt. in 6th EuCheMS Chemistry congress, 11 - 15 September, 2016, Seville, Spain. 2016;.
https://hdl.handle.net/21.15107/rcub_cer_5922 .
Cvetković, Vesna S., Jovićević, Niko, Vukićević, Nataša, Jovićević, Jovan N., "Al-Pd alloy formation by aluminium underpotential deposition onto palladium from chloroaluminate melt" in 6th EuCheMS Chemistry congress, 11 - 15 September, 2016, Seville, Spain (2016),
https://hdl.handle.net/21.15107/rcub_cer_5922 .