Povrenović, Dragan

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  • Povrenović, Dragan (8)

Author's Bibliography

Prečišćavanje otpadnih voda primenom ozonizacije

Kovačina, Jovanka; Milošević, Milena D.; Božić, Aleksandra; Jovanović, Aleksandar; Marinković, Aleksandar D.; Onjia, Antonije E.; Povrenović, Dragan

(Beograd : Beogradska politehnika, 2019)

TY  - CONF
AU  - Kovačina, Jovanka
AU  - Milošević, Milena D.
AU  - Božić, Aleksandra
AU  - Jovanović, Aleksandar
AU  - Marinković, Aleksandar D.
AU  - Onjia, Antonije E.
AU  - Povrenović, Dragan
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3939
AB  - Usled razvoja industrije i rastom populacije tokom poslednjih godina javljaju se
problemi u vezi sa otpadnim vodama iz proizvodnje koje je neophodno rešavati na ekološki i
ekonomičan način. Sve otpadne vode iz postrojenja bez obzira kako su nastale sadrže štetne
materije koje mogu da imaju i određen stepen toksičnih primesa, moraju se prečistiti ako njihov
kvalitet ne odgovara zakonskim okvirima. Svrha tretmana otpadnih voda je uklanjanje štetnih
materija čime se postiže smanjnje stepena njene zagađenosti, a istovremeno se ostvaruje i određen
ekonomski i ekološki efekat, stoga je u ovom radu izvršeno prečišćavanje otpadne vode postupkom
taloženja upotrebom kalcijum-oksida u cilju uklanjanja koloidnih materija i teških metala. Većina
zagađujućih materija su organskog porekla i njihovo ukljanjanje vršiće se primenom naprednih
oksidacionih procesa korišćenjem ozona i ozona u kombinaciji sa ultrazvukom u cilju postizanja
kvaliteta vode koji odgovara zakonskoj regulativi. Proces prečišćavanja će se optimizovati u
odnosu na tehnološki postupak, koncentraciju, vreme tretmana i količinu primenjenog oksidacionog
sredstva. Stepen zagađenosti vode organskim jedinjenjima će se određivati na osnovu merenja
HPK, BPK i koncentracije teških metala (olovo, gvožđe, hrom, bakar, cink, aluminijum).
AB  - Due to the development of industry and population growth during the in recent years, there are problems with wastewater from production that needs to be addressed in an environmentally and economical way. All wastewaters from industry, no matter how they are created, contain harmful substances that may have some degree of toxicity, must be treated if their quality does not meet the legal requirements. The purpose of wastewater treatment is to remove
harmful substances, thereby reducing its pollution level, and at the same time, it also has a certain economic and environmental effect. Therefore, wastewater treatment was carried out in this work by precipitation using calcium oxide to remove colloidal substances and heavy metals. Most pollutants are of organic origin and their removal will be carried in this work out using advanced
oxidation processes using ozone, and ozone in combination with ultrasound to achieve water quality that complies with the law. The purification process will be optimized with respect to, method, time and amount of oxidizing agent applied. The degree of pollution of water by organic compounds will be determined on the basis of measurements of HPK, BOD and the concentration of heavy metals (lead, ferrum, chromium, copper, zinc, aluminum).
PB  - Beograd : Beogradska politehnika
C3  - Zbornik radova - Peti naučno-stručni skup politehnika
T1  - Prečišćavanje otpadnih voda primenom ozonizacije
T1  - Purification of waste water using ozonization
SP  - 142
EP  - 147
UR  - https://hdl.handle.net/21.15107/rcub_cer_3939
ER  - 
@conference{
author = "Kovačina, Jovanka and Milošević, Milena D. and Božić, Aleksandra and Jovanović, Aleksandar and Marinković, Aleksandar D. and Onjia, Antonije E. and Povrenović, Dragan",
year = "2019",
abstract = "Usled razvoja industrije i rastom populacije tokom poslednjih godina javljaju se
problemi u vezi sa otpadnim vodama iz proizvodnje koje je neophodno rešavati na ekološki i
ekonomičan način. Sve otpadne vode iz postrojenja bez obzira kako su nastale sadrže štetne
materije koje mogu da imaju i određen stepen toksičnih primesa, moraju se prečistiti ako njihov
kvalitet ne odgovara zakonskim okvirima. Svrha tretmana otpadnih voda je uklanjanje štetnih
materija čime se postiže smanjnje stepena njene zagađenosti, a istovremeno se ostvaruje i određen
ekonomski i ekološki efekat, stoga je u ovom radu izvršeno prečišćavanje otpadne vode postupkom
taloženja upotrebom kalcijum-oksida u cilju uklanjanja koloidnih materija i teških metala. Većina
zagađujućih materija su organskog porekla i njihovo ukljanjanje vršiće se primenom naprednih
oksidacionih procesa korišćenjem ozona i ozona u kombinaciji sa ultrazvukom u cilju postizanja
kvaliteta vode koji odgovara zakonskoj regulativi. Proces prečišćavanja će se optimizovati u
odnosu na tehnološki postupak, koncentraciju, vreme tretmana i količinu primenjenog oksidacionog
sredstva. Stepen zagađenosti vode organskim jedinjenjima će se određivati na osnovu merenja
HPK, BPK i koncentracije teških metala (olovo, gvožđe, hrom, bakar, cink, aluminijum)., Due to the development of industry and population growth during the in recent years, there are problems with wastewater from production that needs to be addressed in an environmentally and economical way. All wastewaters from industry, no matter how they are created, contain harmful substances that may have some degree of toxicity, must be treated if their quality does not meet the legal requirements. The purpose of wastewater treatment is to remove
harmful substances, thereby reducing its pollution level, and at the same time, it also has a certain economic and environmental effect. Therefore, wastewater treatment was carried out in this work by precipitation using calcium oxide to remove colloidal substances and heavy metals. Most pollutants are of organic origin and their removal will be carried in this work out using advanced
oxidation processes using ozone, and ozone in combination with ultrasound to achieve water quality that complies with the law. The purification process will be optimized with respect to, method, time and amount of oxidizing agent applied. The degree of pollution of water by organic compounds will be determined on the basis of measurements of HPK, BOD and the concentration of heavy metals (lead, ferrum, chromium, copper, zinc, aluminum).",
publisher = "Beograd : Beogradska politehnika",
journal = "Zbornik radova - Peti naučno-stručni skup politehnika",
title = "Prečišćavanje otpadnih voda primenom ozonizacije, Purification of waste water using ozonization",
pages = "142-147",
url = "https://hdl.handle.net/21.15107/rcub_cer_3939"
}
Kovačina, J., Milošević, M. D., Božić, A., Jovanović, A., Marinković, A. D., Onjia, A. E.,& Povrenović, D.. (2019). Prečišćavanje otpadnih voda primenom ozonizacije. in Zbornik radova - Peti naučno-stručni skup politehnika
Beograd : Beogradska politehnika., 142-147.
https://hdl.handle.net/21.15107/rcub_cer_3939
Kovačina J, Milošević MD, Božić A, Jovanović A, Marinković AD, Onjia AE, Povrenović D. Prečišćavanje otpadnih voda primenom ozonizacije. in Zbornik radova - Peti naučno-stručni skup politehnika. 2019;:142-147.
https://hdl.handle.net/21.15107/rcub_cer_3939 .
Kovačina, Jovanka, Milošević, Milena D., Božić, Aleksandra, Jovanović, Aleksandar, Marinković, Aleksandar D., Onjia, Antonije E., Povrenović, Dragan, "Prečišćavanje otpadnih voda primenom ozonizacije" in Zbornik radova - Peti naučno-stručni skup politehnika (2019):142-147,
https://hdl.handle.net/21.15107/rcub_cer_3939 .

Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići

Jovanović, Aleksandar; Kovačina, Jovanka; Marinković, Aleksandar D.; Onjia, Antonije E.; Povrenović, Dragan; Trišović, Tomislav

(University of Belgrade, Faculty of Technology and Metallurgy, 2019)

TY  - GEN
AU  - Jovanović, Aleksandar
AU  - Kovačina, Jovanka
AU  - Marinković, Aleksandar D.
AU  - Onjia, Antonije E.
AU  - Povrenović, Dragan
AU  - Trišović, Tomislav
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3941
AB  - Usled razvoja industrije i rastom populacije tokom poslednjih godina javljaju se problemi u vezi sa otpadnim vodama iz proizvodnje koje je neophodno rešavati na ekološki i ekonomičan način. Sve otpadne vode iz postrojenja bez obzira kako su nastale sadrže štetne materije koje mogu da imaju i određen stepen toksičnih primesa, moraju se prečistiti ako njihov kvalitet ne odgovara zakonskim okvirima. Svrha tretmana otpadnih voda je uklanjanje štetnih materija čime se postiže smanjenje stepena njene zagađenosti, a istovremeno se ostvaruje i određen ekonomski i ekološki efekat. Ovo tehničko rešenje predstavlja optimizaciju procesa prečišćavanje otpadnih voda Fabrike streljačke municije u Uzićima. Otpadna voda je prečišćavana postupkom taloženja uz upotrebu kalcijum-oksida u cilju uklanjanja koloidnih materija i teških metala. Većina zagađujućih materija su organskog porekla i njihovo ukljanjanje vršeno je primenom naprednih oksidacionih procesa korišćenjem ozona i ozona u kombinaciji sa ultrazvukom u cilju postizanja kvaliteta vode koji odgovara zakonskoj regulativi. Unapređeni procesi oksidacije predstavljaju najefikasnije metode za uklanjanje i degradaciju teško rastvornih zagađujućih materija iz otpadnih voda. Proces prečišćavanja je optimizovan u odnosu na tehnološki postupak, koncentraciju, vreme tretmana i količinu primenjenog oksidacionog sredstva. Stepen zagađenosti vode organskim jedinjenjima je određivati na osnovu merenja HPK, BPK i koncentracije teških metala (olovo, gvožđe, hrom, bakar, cink, aluminijum).
AB  - Due to the development of industry and population growth in recent years, there are problems related to industrial wastewater that needs to be addressed in an environmentally friendly and economical way. All wastewater from plants, regardless of how it was generated, contains harmful substances that may have a certain degree of toxic impurities and must be treated if its quality does not meet the legal requirements. The purpose of wastewater treatment is the removal of harmful substances, which reduces the degree of its pollution, and at the same time achieves a certain economic and environmental effect. This technical solution ensures the optimization of the wastewater treatment process of the Ammunition Factory in Uzići. Wastewater is purified by a precipitation process using calcium oxide to remove colloidal substances and heavy metals. Most of the pollutants are of organic origin and their removal is performed by applying advanced oxidation processes using ozone and ozone in combination with ultrasound in order to achieve water quality that complies with legal regulations. Advanced oxidation processes are the most efficient methods for removing and degrading poorly soluble pollutants from wastewater. The purification process is optimized in terms of the technological process, concentration, treatment time and the amount of oxidizing agent applied. The degree of water pollution with organic compounds is determined on the basis of measurements of HPK, BOD and the concentration of heavy metals (lead, iron, chromium, copper, zinc, aluminum).
PB  - University of Belgrade, Faculty of Technology and Metallurgy
T1  - Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići
UR  - https://hdl.handle.net/21.15107/rcub_cer_3941
ER  - 
@misc{
author = "Jovanović, Aleksandar and Kovačina, Jovanka and Marinković, Aleksandar D. and Onjia, Antonije E. and Povrenović, Dragan and Trišović, Tomislav",
year = "2019",
abstract = "Usled razvoja industrije i rastom populacije tokom poslednjih godina javljaju se problemi u vezi sa otpadnim vodama iz proizvodnje koje je neophodno rešavati na ekološki i ekonomičan način. Sve otpadne vode iz postrojenja bez obzira kako su nastale sadrže štetne materije koje mogu da imaju i određen stepen toksičnih primesa, moraju se prečistiti ako njihov kvalitet ne odgovara zakonskim okvirima. Svrha tretmana otpadnih voda je uklanjanje štetnih materija čime se postiže smanjenje stepena njene zagađenosti, a istovremeno se ostvaruje i određen ekonomski i ekološki efekat. Ovo tehničko rešenje predstavlja optimizaciju procesa prečišćavanje otpadnih voda Fabrike streljačke municije u Uzićima. Otpadna voda je prečišćavana postupkom taloženja uz upotrebu kalcijum-oksida u cilju uklanjanja koloidnih materija i teških metala. Većina zagađujućih materija su organskog porekla i njihovo ukljanjanje vršeno je primenom naprednih oksidacionih procesa korišćenjem ozona i ozona u kombinaciji sa ultrazvukom u cilju postizanja kvaliteta vode koji odgovara zakonskoj regulativi. Unapređeni procesi oksidacije predstavljaju najefikasnije metode za uklanjanje i degradaciju teško rastvornih zagađujućih materija iz otpadnih voda. Proces prečišćavanja je optimizovan u odnosu na tehnološki postupak, koncentraciju, vreme tretmana i količinu primenjenog oksidacionog sredstva. Stepen zagađenosti vode organskim jedinjenjima je određivati na osnovu merenja HPK, BPK i koncentracije teških metala (olovo, gvožđe, hrom, bakar, cink, aluminijum)., Due to the development of industry and population growth in recent years, there are problems related to industrial wastewater that needs to be addressed in an environmentally friendly and economical way. All wastewater from plants, regardless of how it was generated, contains harmful substances that may have a certain degree of toxic impurities and must be treated if its quality does not meet the legal requirements. The purpose of wastewater treatment is the removal of harmful substances, which reduces the degree of its pollution, and at the same time achieves a certain economic and environmental effect. This technical solution ensures the optimization of the wastewater treatment process of the Ammunition Factory in Uzići. Wastewater is purified by a precipitation process using calcium oxide to remove colloidal substances and heavy metals. Most of the pollutants are of organic origin and their removal is performed by applying advanced oxidation processes using ozone and ozone in combination with ultrasound in order to achieve water quality that complies with legal regulations. Advanced oxidation processes are the most efficient methods for removing and degrading poorly soluble pollutants from wastewater. The purification process is optimized in terms of the technological process, concentration, treatment time and the amount of oxidizing agent applied. The degree of water pollution with organic compounds is determined on the basis of measurements of HPK, BOD and the concentration of heavy metals (lead, iron, chromium, copper, zinc, aluminum).",
publisher = "University of Belgrade, Faculty of Technology and Metallurgy",
title = "Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići",
url = "https://hdl.handle.net/21.15107/rcub_cer_3941"
}
Jovanović, A., Kovačina, J., Marinković, A. D., Onjia, A. E., Povrenović, D.,& Trišović, T.. (2019). Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići. 
University of Belgrade, Faculty of Technology and Metallurgy..
https://hdl.handle.net/21.15107/rcub_cer_3941
Jovanović A, Kovačina J, Marinković AD, Onjia AE, Povrenović D, Trišović T. Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići. 2019;.
https://hdl.handle.net/21.15107/rcub_cer_3941 .
Jovanović, Aleksandar, Kovačina, Jovanka, Marinković, Aleksandar D., Onjia, Antonije E., Povrenović, Dragan, Trišović, Tomislav, "Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići" (2019),
https://hdl.handle.net/21.15107/rcub_cer_3941 .

Drying of waste water treatment sludge in fluidized bed of inert particles

Đuriš, Mihal; Arsenijević, Zorana; Povrenović, Dragan; Kaluđerović Radoičić, Tatjana

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS, 2019)

TY  - JOUR
AU  - Đuriš, Mihal
AU  - Arsenijević, Zorana
AU  - Povrenović, Dragan
AU  - Kaluđerović Radoičić, Tatjana
PY  - 2019
UR  - https://izdanja.smeits.rs/index.php/procteh/article/view/6028
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4458
AB  - Waste  water  treatment  sludge  is  generated  in  increasing  
quantities,   as   the   amount   of   treated   municipal   and   
industrial  waste  water  increases.  Also,  the  requirements  
concerning the conditions of sludge storage/landfill or reuse are 
growing.  Due  to  these  reasons,  new  solutions  regarding  sludge  
treatment, management and utilization are needed [1]. The benefits 
of  drying  waste  water  treatment  sludge  can  be  seen  in  several  
aspects:  the  dried  sludge  can  be  stored  for  longer  periods  of  time  
and  further  used  as  an  organic  fertilizer,  it  can  be  a  source  of  
useful  (active)  microorganisms  that  can  be  reused  in  waste  water  
treatment.  Drying  also  enables  incineration  or  co-incineration  of  
sludge.  Sludge  drying  process  reduces  mass  and  volume  of  the  
product, making its storage, transport, packaging and retail easier 
[2-4].
AB  - Sušenjem mulja iz procesa prečišćavanja otpadnih voda mogu se dobiti dva glavna upotrebljiva proizvoda: osušeni mulj može se skladištiti i koristiti kao organsko đubrivo, a može sadržati i aktivne (žive) mikroorganizme koji se ponovo mogu koristiti u tretmanu otpadnih voda. Sušenje suspenzija i pasta u fluidizovanom sloju inertnih čestica predstavlja atraktivnu alternativu ostalim postupcima sušenja u pogledu osnovnih kriterijuma za ocenu efikasnosti kao što su specifični kapacitet isparavanja, specifični utrošak toplote i specifični utrošak vazduha. Visoka efikasnost sušenja je rezultat velikih kontaktnih površina i velikih temperaturnih razlika između ulaznog i izlaznog toka vazduha za sušenje. Intenzivno mešanje inertnih čestica tokom agregativne fluidizacije obezbeđuje približno jednaku temperaturu u celoj zapremini sloja te ne postoji rizik od lokalnog pregrevanja. U radu su prikazani rezultati ispitivanja sušenja mulja na pilot postrojenju za sušenje suspenzija i pasta nominalnog kapaciteta isparavanja do20 kgH2O/h, čiji je centralni deo cilindrična kolona prečnika 215 mm sa fluidizovanim slojem staklenih sfera. Ispitivan je uticaj operativnih uslova na performanse sistema za sušenje i na kvalitet praškastog osušenog aktivnog mulja. Glavni cilj je da se odrede optimalne temperature sušenja mulja pri kojima bi korisni mikroorganizmu u mulju ostali aktivni (živi), a pri kojim aktivni mulj može da se koristi kao oragansko đubrivo. Izvršena je analiza efikasnosti sušenja sa stanovišta kapaciteta isparavanja i potrošnje vazduha u cilju boljeg sagledavanja performansi sistema za sušenje. Jednostavni bilansi mase i toplote adekvatno predviđaju radni režim sistema za sušenje u fluidizovanom sloju inertnog materijala.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS
T2  - Procesna tehnika
T1  - Drying of waste water treatment sludge in fluidized bed of inert particles
T1  - Sušenje mulja iz procesa prečišćavanja otpadnih voda u fluidizovanom sloju inertnih čestica
VL  - 31
IS  - 2
SP  - 14
EP  - 18
DO  - 10.24094/ptc.019.31.2.14
ER  - 
@article{
author = "Đuriš, Mihal and Arsenijević, Zorana and Povrenović, Dragan and Kaluđerović Radoičić, Tatjana",
year = "2019",
abstract = "Waste  water  treatment  sludge  is  generated  in  increasing  
quantities,   as   the   amount   of   treated   municipal   and   
industrial  waste  water  increases.  Also,  the  requirements  
concerning the conditions of sludge storage/landfill or reuse are 
growing.  Due  to  these  reasons,  new  solutions  regarding  sludge  
treatment, management and utilization are needed [1]. The benefits 
of  drying  waste  water  treatment  sludge  can  be  seen  in  several  
aspects:  the  dried  sludge  can  be  stored  for  longer  periods  of  time  
and  further  used  as  an  organic  fertilizer,  it  can  be  a  source  of  
useful  (active)  microorganisms  that  can  be  reused  in  waste  water  
treatment.  Drying  also  enables  incineration  or  co-incineration  of  
sludge.  Sludge  drying  process  reduces  mass  and  volume  of  the  
product, making its storage, transport, packaging and retail easier 
[2-4]., Sušenjem mulja iz procesa prečišćavanja otpadnih voda mogu se dobiti dva glavna upotrebljiva proizvoda: osušeni mulj može se skladištiti i koristiti kao organsko đubrivo, a može sadržati i aktivne (žive) mikroorganizme koji se ponovo mogu koristiti u tretmanu otpadnih voda. Sušenje suspenzija i pasta u fluidizovanom sloju inertnih čestica predstavlja atraktivnu alternativu ostalim postupcima sušenja u pogledu osnovnih kriterijuma za ocenu efikasnosti kao što su specifični kapacitet isparavanja, specifični utrošak toplote i specifični utrošak vazduha. Visoka efikasnost sušenja je rezultat velikih kontaktnih površina i velikih temperaturnih razlika između ulaznog i izlaznog toka vazduha za sušenje. Intenzivno mešanje inertnih čestica tokom agregativne fluidizacije obezbeđuje približno jednaku temperaturu u celoj zapremini sloja te ne postoji rizik od lokalnog pregrevanja. U radu su prikazani rezultati ispitivanja sušenja mulja na pilot postrojenju za sušenje suspenzija i pasta nominalnog kapaciteta isparavanja do20 kgH2O/h, čiji je centralni deo cilindrična kolona prečnika 215 mm sa fluidizovanim slojem staklenih sfera. Ispitivan je uticaj operativnih uslova na performanse sistema za sušenje i na kvalitet praškastog osušenog aktivnog mulja. Glavni cilj je da se odrede optimalne temperature sušenja mulja pri kojima bi korisni mikroorganizmu u mulju ostali aktivni (živi), a pri kojim aktivni mulj može da se koristi kao oragansko đubrivo. Izvršena je analiza efikasnosti sušenja sa stanovišta kapaciteta isparavanja i potrošnje vazduha u cilju boljeg sagledavanja performansi sistema za sušenje. Jednostavni bilansi mase i toplote adekvatno predviđaju radni režim sistema za sušenje u fluidizovanom sloju inertnog materijala.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS",
journal = "Procesna tehnika",
title = "Drying of waste water treatment sludge in fluidized bed of inert particles, Sušenje mulja iz procesa prečišćavanja otpadnih voda u fluidizovanom sloju inertnih čestica",
volume = "31",
number = "2",
pages = "14-18",
doi = "10.24094/ptc.019.31.2.14"
}
Đuriš, M., Arsenijević, Z., Povrenović, D.,& Kaluđerović Radoičić, T.. (2019). Drying of waste water treatment sludge in fluidized bed of inert particles. in Procesna tehnika
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije - SMEITS., 31(2), 14-18.
https://doi.org/10.24094/ptc.019.31.2.14
Đuriš M, Arsenijević Z, Povrenović D, Kaluđerović Radoičić T. Drying of waste water treatment sludge in fluidized bed of inert particles. in Procesna tehnika. 2019;31(2):14-18.
doi:10.24094/ptc.019.31.2.14 .
Đuriš, Mihal, Arsenijević, Zorana, Povrenović, Dragan, Kaluđerović Radoičić, Tatjana, "Drying of waste water treatment sludge in fluidized bed of inert particles" in Procesna tehnika, 31, no. 2 (2019):14-18,
https://doi.org/10.24094/ptc.019.31.2.14 . .

Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis

Milićević, Sonja; Martinović, Sanja; Milošević, Vladan; Stojanović, Jovica; Povrenović, Dragan

(Springer, 2018)

TY  - JOUR
AU  - Milićević, Sonja
AU  - Martinović, Sanja
AU  - Milošević, Vladan
AU  - Stojanović, Jovica
AU  - Povrenović, Dragan
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2366
AB  - Systematic modification of three structurally different minerals (zeolite, mica, and vermiculite) was carried out with the aim of determining the modification mechanism and exposing the hydrophobic surface that can be used as a sorbent for many organic compounds. Mechanism of modification with cationic surfactant depends strongly on the mineral type. In order to identify the influence of aluminosilicates structural differences on the modification process, adsorption experiments with organic matter and water vapor, supplemented with the DTA/TG analysis, were performed. The cation exchange capacity (CEC) value was 1454>560>28meqkg(-1) for zeolite (clinoptilolite), vermiculite, and mica (muscovite), respectively. Despite its CEC value, vermiculite adsorbed three times the amount of organic matter than did clinoptilolite due to the porous structure of zeolite, which acted to limit the adsorption only on the external exchangeable cations. If the loading amount is equal to the CEC or the external cation exchange capacity for clinoptilolite (ECEC approximate to 10% CEC), the monolayer will form while mineral surface will have hydrophobic character. Only one active center exists at the surface of the clinoptilolite that was identified by DTA curves with a sharp and defined peak around 300 degrees C and by the mass loss at the TG diagrams. Two significant and equal active centers were observed in vermiculite, one for the exchange of the surface cations and the other for the interlayer cations and H2O molecules. Muscovite CEC is negligible, and due to the absence of any other functional groups, the modification of this mineral was impossible.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis
VL  - 134
IS  - 2
SP  - 1011
EP  - 1019
DO  - 10.1007/s10973-018-7351-3
ER  - 
@article{
author = "Milićević, Sonja and Martinović, Sanja and Milošević, Vladan and Stojanović, Jovica and Povrenović, Dragan",
year = "2018",
abstract = "Systematic modification of three structurally different minerals (zeolite, mica, and vermiculite) was carried out with the aim of determining the modification mechanism and exposing the hydrophobic surface that can be used as a sorbent for many organic compounds. Mechanism of modification with cationic surfactant depends strongly on the mineral type. In order to identify the influence of aluminosilicates structural differences on the modification process, adsorption experiments with organic matter and water vapor, supplemented with the DTA/TG analysis, were performed. The cation exchange capacity (CEC) value was 1454>560>28meqkg(-1) for zeolite (clinoptilolite), vermiculite, and mica (muscovite), respectively. Despite its CEC value, vermiculite adsorbed three times the amount of organic matter than did clinoptilolite due to the porous structure of zeolite, which acted to limit the adsorption only on the external exchangeable cations. If the loading amount is equal to the CEC or the external cation exchange capacity for clinoptilolite (ECEC approximate to 10% CEC), the monolayer will form while mineral surface will have hydrophobic character. Only one active center exists at the surface of the clinoptilolite that was identified by DTA curves with a sharp and defined peak around 300 degrees C and by the mass loss at the TG diagrams. Two significant and equal active centers were observed in vermiculite, one for the exchange of the surface cations and the other for the interlayer cations and H2O molecules. Muscovite CEC is negligible, and due to the absence of any other functional groups, the modification of this mineral was impossible.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis",
volume = "134",
number = "2",
pages = "1011-1019",
doi = "10.1007/s10973-018-7351-3"
}
Milićević, S., Martinović, S., Milošević, V., Stojanović, J.,& Povrenović, D.. (2018). Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis. in Journal of Thermal Analysis and Calorimetry
Springer., 134(2), 1011-1019.
https://doi.org/10.1007/s10973-018-7351-3
Milićević S, Martinović S, Milošević V, Stojanović J, Povrenović D. Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis. in Journal of Thermal Analysis and Calorimetry. 2018;134(2):1011-1019.
doi:10.1007/s10973-018-7351-3 .
Milićević, Sonja, Martinović, Sanja, Milošević, Vladan, Stojanović, Jovica, Povrenović, Dragan, "Differences in coating mechanism of structurally different aluminosilicates observed through the thermal analysis" in Journal of Thermal Analysis and Calorimetry, 134, no. 2 (2018):1011-1019,
https://doi.org/10.1007/s10973-018-7351-3 . .
3
2
2
3

Predicting the copper adsorption capacity on different zeolites

Milićević, Sonja; Povrenović, Dragan; Milošević, Vladan; Martinović, Sanja

(University of Belgrade, Technical Faculty Bor, 2017)

TY  - JOUR
AU  - Milićević, Sonja
AU  - Povrenović, Dragan
AU  - Milošević, Vladan
AU  - Martinović, Sanja
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2060
AB  - In this paper the ability of three natural zeolites from different localities (Vranjska banja-VB, Igroš-I and Baia Mare-BM deposits) to remove copper has been investigated. These three zeolites were subjected to the elementary analysis as well as XRDP and DTA/TG analysis due to complete characterization. Cation exchange capacity of VB, I and BM zeolites were 150.1, 169.2, and 176.5 meq/100g. The maximum adsorption capacity for the copper adsorption on VB, I and BM-zeolites were 7.75, 8.51, and 11.18 mg/g. Based on the obtained results the mathematical expression that describes correlation between the CEC and copper adsorption capacity has been developed. This linear dependance has been tested with the vast variety of experimental results. According to this expression it is possible to predict the copper adsorption capacity for different zeolites based only on their CEC value.
AB  - U radu su prikazani rezultati ispitivanja uklanjanja jona bakra primenom tri prirodna zeolita sa različitih lokaliteta (Vranjska banja-VB, Igroš-I i Baia Mare-BM). U cilju karakterizacije zeolita, izvršena su ispitivanja elementarnog sastava, kao i rentgenska (XRDP) i termijska analiza (DTA/TG). Kapaciteti katjonske izmene (CEC) ispitivanih zeolita VB, I i BM iznose 150,1, 169,2 i 176,5 meq/100g. Maksimalni adsorpcioni kapaciteti bakra na VB, I i BM zeolitima iznose 7,75, 8,51, i 11,18 mg/g. Na osnovu ostvarenih rezultata, dobijena je matematička zavisnost koja dobro opisuje vezu između vrednosti CEC i adsorpcionog kapaciteta za bakar. Ova lineralna zavisnost je testirana primenom različitih eksperimentalnih rezultata. Primenom ove zavisnosti moguće je da se predvidi vrednost adsorpcionog kapaciteta bakra na različitim zeolitima poznavanjem njegove CEC vrednosti. .
PB  - University of Belgrade, Technical Faculty Bor
T2  - Journal of Mining and Metallurgy A: Mining
T1  - Predicting the copper adsorption capacity on different zeolites
T1  - Predviđanje adsorpcionog kapaciteta bakra na različitim zeolitima
VL  - 53
IS  - 1
SP  - 57
EP  - 63
DO  - 10.5937/JMMA1701057M
ER  - 
@article{
author = "Milićević, Sonja and Povrenović, Dragan and Milošević, Vladan and Martinović, Sanja",
year = "2017",
abstract = "In this paper the ability of three natural zeolites from different localities (Vranjska banja-VB, Igroš-I and Baia Mare-BM deposits) to remove copper has been investigated. These three zeolites were subjected to the elementary analysis as well as XRDP and DTA/TG analysis due to complete characterization. Cation exchange capacity of VB, I and BM zeolites were 150.1, 169.2, and 176.5 meq/100g. The maximum adsorption capacity for the copper adsorption on VB, I and BM-zeolites were 7.75, 8.51, and 11.18 mg/g. Based on the obtained results the mathematical expression that describes correlation between the CEC and copper adsorption capacity has been developed. This linear dependance has been tested with the vast variety of experimental results. According to this expression it is possible to predict the copper adsorption capacity for different zeolites based only on their CEC value., U radu su prikazani rezultati ispitivanja uklanjanja jona bakra primenom tri prirodna zeolita sa različitih lokaliteta (Vranjska banja-VB, Igroš-I i Baia Mare-BM). U cilju karakterizacije zeolita, izvršena su ispitivanja elementarnog sastava, kao i rentgenska (XRDP) i termijska analiza (DTA/TG). Kapaciteti katjonske izmene (CEC) ispitivanih zeolita VB, I i BM iznose 150,1, 169,2 i 176,5 meq/100g. Maksimalni adsorpcioni kapaciteti bakra na VB, I i BM zeolitima iznose 7,75, 8,51, i 11,18 mg/g. Na osnovu ostvarenih rezultata, dobijena je matematička zavisnost koja dobro opisuje vezu između vrednosti CEC i adsorpcionog kapaciteta za bakar. Ova lineralna zavisnost je testirana primenom različitih eksperimentalnih rezultata. Primenom ove zavisnosti moguće je da se predvidi vrednost adsorpcionog kapaciteta bakra na različitim zeolitima poznavanjem njegove CEC vrednosti. .",
publisher = "University of Belgrade, Technical Faculty Bor",
journal = "Journal of Mining and Metallurgy A: Mining",
title = "Predicting the copper adsorption capacity on different zeolites, Predviđanje adsorpcionog kapaciteta bakra na različitim zeolitima",
volume = "53",
number = "1",
pages = "57-63",
doi = "10.5937/JMMA1701057M"
}
Milićević, S., Povrenović, D., Milošević, V.,& Martinović, S.. (2017). Predicting the copper adsorption capacity on different zeolites. in Journal of Mining and Metallurgy A: Mining
University of Belgrade, Technical Faculty Bor., 53(1), 57-63.
https://doi.org/10.5937/JMMA1701057M
Milićević S, Povrenović D, Milošević V, Martinović S. Predicting the copper adsorption capacity on different zeolites. in Journal of Mining and Metallurgy A: Mining. 2017;53(1):57-63.
doi:10.5937/JMMA1701057M .
Milićević, Sonja, Povrenović, Dragan, Milošević, Vladan, Martinović, Sanja, "Predicting the copper adsorption capacity on different zeolites" in Journal of Mining and Metallurgy A: Mining, 53, no. 1 (2017):57-63,
https://doi.org/10.5937/JMMA1701057M . .
1

Concentration method for the mining wastewater-valorization of the copper

Milićević, Sonja; Milošević, Vladan; Vlahović, Milica; Martinović, Sanja; Povrenović, Dragan

(The Regional Environmental Center for Central and Eastern Europe, 2013)

TY  - CONF
AU  - Milićević, Sonja
AU  - Milošević, Vladan
AU  - Vlahović, Milica
AU  - Martinović, Sanja
AU  - Povrenović, Dragan
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7313
AB  - During the mining process of copper exploitation, a large amount of wastewater is generated. Not only do the copper ions contaminate the water but also represent a great loss for the copper production industry. Negative charges surface of zeolite has been used for adsorption of copper. The batch and dynamic experiments have been conducted. After the adsorption, the zeolite has been regenerated with the concentrated solution of Na-salt. The volume of the regenerative solution is 30 times smaller compared to the total amount of the waste solution that has been purified and the concentation of the obtained solution is 12 gCu2+/dm3.
PB  - The Regional Environmental Center for Central and Eastern Europe
C3  - International Science Conference  Reporting for Sustainability, Conference Proceedings, 7th-10th May 2013, Bečići, Montenegro
T1  - Concentration method for the mining wastewater-valorization of the copper
SP  - 431
EP  - 435
UR  - https://hdl.handle.net/21.15107/rcub_cer_7313
ER  - 
@conference{
author = "Milićević, Sonja and Milošević, Vladan and Vlahović, Milica and Martinović, Sanja and Povrenović, Dragan",
year = "2013",
abstract = "During the mining process of copper exploitation, a large amount of wastewater is generated. Not only do the copper ions contaminate the water but also represent a great loss for the copper production industry. Negative charges surface of zeolite has been used for adsorption of copper. The batch and dynamic experiments have been conducted. After the adsorption, the zeolite has been regenerated with the concentrated solution of Na-salt. The volume of the regenerative solution is 30 times smaller compared to the total amount of the waste solution that has been purified and the concentation of the obtained solution is 12 gCu2+/dm3.",
publisher = "The Regional Environmental Center for Central and Eastern Europe",
journal = "International Science Conference  Reporting for Sustainability, Conference Proceedings, 7th-10th May 2013, Bečići, Montenegro",
title = "Concentration method for the mining wastewater-valorization of the copper",
pages = "431-435",
url = "https://hdl.handle.net/21.15107/rcub_cer_7313"
}
Milićević, S., Milošević, V., Vlahović, M., Martinović, S.,& Povrenović, D.. (2013). Concentration method for the mining wastewater-valorization of the copper. in International Science Conference  Reporting for Sustainability, Conference Proceedings, 7th-10th May 2013, Bečići, Montenegro
The Regional Environmental Center for Central and Eastern Europe., 431-435.
https://hdl.handle.net/21.15107/rcub_cer_7313
Milićević S, Milošević V, Vlahović M, Martinović S, Povrenović D. Concentration method for the mining wastewater-valorization of the copper. in International Science Conference  Reporting for Sustainability, Conference Proceedings, 7th-10th May 2013, Bečići, Montenegro. 2013;:431-435.
https://hdl.handle.net/21.15107/rcub_cer_7313 .
Milićević, Sonja, Milošević, Vladan, Vlahović, Milica, Martinović, Sanja, Povrenović, Dragan, "Concentration method for the mining wastewater-valorization of the copper" in International Science Conference  Reporting for Sustainability, Conference Proceedings, 7th-10th May 2013, Bečići, Montenegro (2013):431-435,
https://hdl.handle.net/21.15107/rcub_cer_7313 .

Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite

Milićević, Sonja; Milošević, Vladan; Povrenović, Dragan; Stojanović, Jovica; Martinović, Sanja; Babić, Biljana

(Springer, 2013)

TY  - JOUR
AU  - Milićević, Sonja
AU  - Milošević, Vladan
AU  - Povrenović, Dragan
AU  - Stojanović, Jovica
AU  - Martinović, Sanja
AU  - Babić, Biljana
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6897
AB  - The increasing levels of industrial wastewater released to the environment present a serious
threat to human health, living resources, and ecological systems. Fe-modified zeolites were developed and tested for removal of Cu2+ and Zn2+ from contaminated water. The surfaces of the naturally occurring zeolite, clinoptilolite, were modified with Fe(III) oxyhydroxides using three different methods, denoted I, II, and III (FeCli1 , FeCli2, and FeNaCli1, respectively). The oxyhydroxides were prepared in Method I using 0.1 M FeCl3 · H2O in an acetate buffer (pH = 3.6); in Method II, using 10% FeCl3 · H2O solution in 0.1 M KOH (pH = 10); and Method III was the same as Method I except the clinoptilolite was pretreated with NaCl. Newly synthesized materials from these three methods were then tested for their ability to enhance the sorption capacity for Cu and Zn compared to the natural sample (Cli). Powder X-ray diffraction measurements and the chemical composition of these modified samples confirmed that
clinoptilolite maintained its structure while amorphous Fe3+ species were synthesized. The specific surface area (BET method) of both the natural and modified clinoptilolite increased by 2 and 7.5 times for Methods I and II, respectively. Scanning electron microscopy and energy dispersive X-ray spectroscopy revealed that CaO was formed during Method I (FeCli1). Throughout the adsorption process, the hydrolysis of CaO and the release of OH¯ caused the precipitation of Cu and Zn hydroxide, which made the determination of the sorption capacity of FeCli1 impossible. This phenomenon was avoided in Method III (FeNaCli1) because of the absence of exchangeable Ca2+. The adsorption experiments with method II resulted in
double-enchanced adsoprtion capacity. Laboratory batch experiments have shown that the sorption capacities increased in the following order: Cli < FeCli2 < FeNaCli1, for Cu: 0.121 mmol/g < 0.251 mmol/g < 0.403 mmol/g and for Zn: 0.128 mmol/g < 0.234 mmol/g < 0.381 mmol/g.
PB  - Springer
T2  - Clay and Clay Minerals
T1  - Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite
VL  - 61
VL  - 517
IS  - 6
SP  - 508
DO  - 10.1346/CCMN.2013.0610603
ER  - 
@article{
author = "Milićević, Sonja and Milošević, Vladan and Povrenović, Dragan and Stojanović, Jovica and Martinović, Sanja and Babić, Biljana",
year = "2013",
abstract = "The increasing levels of industrial wastewater released to the environment present a serious
threat to human health, living resources, and ecological systems. Fe-modified zeolites were developed and tested for removal of Cu2+ and Zn2+ from contaminated water. The surfaces of the naturally occurring zeolite, clinoptilolite, were modified with Fe(III) oxyhydroxides using three different methods, denoted I, II, and III (FeCli1 , FeCli2, and FeNaCli1, respectively). The oxyhydroxides were prepared in Method I using 0.1 M FeCl3 · H2O in an acetate buffer (pH = 3.6); in Method II, using 10% FeCl3 · H2O solution in 0.1 M KOH (pH = 10); and Method III was the same as Method I except the clinoptilolite was pretreated with NaCl. Newly synthesized materials from these three methods were then tested for their ability to enhance the sorption capacity for Cu and Zn compared to the natural sample (Cli). Powder X-ray diffraction measurements and the chemical composition of these modified samples confirmed that
clinoptilolite maintained its structure while amorphous Fe3+ species were synthesized. The specific surface area (BET method) of both the natural and modified clinoptilolite increased by 2 and 7.5 times for Methods I and II, respectively. Scanning electron microscopy and energy dispersive X-ray spectroscopy revealed that CaO was formed during Method I (FeCli1). Throughout the adsorption process, the hydrolysis of CaO and the release of OH¯ caused the precipitation of Cu and Zn hydroxide, which made the determination of the sorption capacity of FeCli1 impossible. This phenomenon was avoided in Method III (FeNaCli1) because of the absence of exchangeable Ca2+. The adsorption experiments with method II resulted in
double-enchanced adsoprtion capacity. Laboratory batch experiments have shown that the sorption capacities increased in the following order: Cli < FeCli2 < FeNaCli1, for Cu: 0.121 mmol/g < 0.251 mmol/g < 0.403 mmol/g and for Zn: 0.128 mmol/g < 0.234 mmol/g < 0.381 mmol/g.",
publisher = "Springer",
journal = "Clay and Clay Minerals",
title = "Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite",
volume = "61, 517",
number = "6",
pages = "508",
doi = "10.1346/CCMN.2013.0610603"
}
Milićević, S., Milošević, V., Povrenović, D., Stojanović, J., Martinović, S.,& Babić, B.. (2013). Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite. in Clay and Clay Minerals
Springer., 61(6), 508.
https://doi.org/10.1346/CCMN.2013.0610603
Milićević S, Milošević V, Povrenović D, Stojanović J, Martinović S, Babić B. Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite. in Clay and Clay Minerals. 2013;61(6):508.
doi:10.1346/CCMN.2013.0610603 .
Milićević, Sonja, Milošević, Vladan, Povrenović, Dragan, Stojanović, Jovica, Martinović, Sanja, Babić, Biljana, "Removal of heavy metals from aqueous solutions using natural and Fe(III) oxyhydroxide clinoptilolite" in Clay and Clay Minerals, 61, no. 6 (2013):508,
https://doi.org/10.1346/CCMN.2013.0610603 . .
12
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11

Removal of metal cations from wastewater using recycled wool-based non-woven material

Radetić, Maja; Radojević, Darinka; Ilić, Vesna; Povrenović, Dragan; Potkonjak, Branislav; Puač, Nevena; Jovančić, Petar M.

(Belgrade : Serbian Chemical Society, 2007)

TY  - JOUR
AU  - Radetić, Maja
AU  - Radojević, Darinka
AU  - Ilić, Vesna
AU  - Povrenović, Dragan
AU  - Potkonjak, Branislav
AU  - Puač, Nevena
AU  - Jovančić, Petar M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4260
AB  - In this study, the effect of low-temperature air plasma, biopolymer chitosan
and hydrogen peroxide treatment of recycled wool-based non-woven material
on metal cation uptake was investigated. Recycled wool-based material either as an
untreated or modified material showed ability to bind all investigated metal cations
in the following order: Pb2+>Cu2+>Zn2+>Co2+. Material performed good selectivity
due to distinct sorption rates of studied metal cations.
AB  - U ovom radu je ispitan uticaj obrade netkanog materijala na bazi vune kao
sekundarne sirovine niskotemperaturnom plazmom, biopolimerom hitozanom i vodonik-
peroksidom na sorpciju katjona metala. Materijal na bazi vune kao sekundarne
sirovine bilo kao neobra|en ili modifikovan, poseduje sposobnost vezivawa katjona
metala prema slede}em redosledu: Pb2+>Cu2+>Zn2+>Co2+. Materijal pokazuje dobru
selektivnost usled razli~ite brzine sorpcije ispitivanih katjona metala.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Removal of metal cations from wastewater using recycled wool-based non-woven material
T1  - Уклањање катјона метала из отпадне воде нетканим материјалом на бази вуне као секундарне сировине
VL  - 72
IS  - 6
SP  - 605
EP  - 614
DO  - 10.2298/JSC0706605R
ER  - 
@article{
author = "Radetić, Maja and Radojević, Darinka and Ilić, Vesna and Povrenović, Dragan and Potkonjak, Branislav and Puač, Nevena and Jovančić, Petar M.",
year = "2007",
abstract = "In this study, the effect of low-temperature air plasma, biopolymer chitosan
and hydrogen peroxide treatment of recycled wool-based non-woven material
on metal cation uptake was investigated. Recycled wool-based material either as an
untreated or modified material showed ability to bind all investigated metal cations
in the following order: Pb2+>Cu2+>Zn2+>Co2+. Material performed good selectivity
due to distinct sorption rates of studied metal cations., U ovom radu je ispitan uticaj obrade netkanog materijala na bazi vune kao
sekundarne sirovine niskotemperaturnom plazmom, biopolimerom hitozanom i vodonik-
peroksidom na sorpciju katjona metala. Materijal na bazi vune kao sekundarne
sirovine bilo kao neobra|en ili modifikovan, poseduje sposobnost vezivawa katjona
metala prema slede}em redosledu: Pb2+>Cu2+>Zn2+>Co2+. Materijal pokazuje dobru
selektivnost usled razli~ite brzine sorpcije ispitivanih katjona metala.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of metal cations from wastewater using recycled wool-based non-woven material, Уклањање катјона метала из отпадне воде нетканим материјалом на бази вуне као секундарне сировине",
volume = "72",
number = "6",
pages = "605-614",
doi = "10.2298/JSC0706605R"
}
Radetić, M., Radojević, D., Ilić, V., Povrenović, D., Potkonjak, B., Puač, N.,& Jovančić, P. M.. (2007). Removal of metal cations from wastewater using recycled wool-based non-woven material. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 72(6), 605-614.
https://doi.org/10.2298/JSC0706605R
Radetić M, Radojević D, Ilić V, Povrenović D, Potkonjak B, Puač N, Jovančić PM. Removal of metal cations from wastewater using recycled wool-based non-woven material. in Journal of the Serbian Chemical Society. 2007;72(6):605-614.
doi:10.2298/JSC0706605R .
Radetić, Maja, Radojević, Darinka, Ilić, Vesna, Povrenović, Dragan, Potkonjak, Branislav, Puač, Nevena, Jovančić, Petar M., "Removal of metal cations from wastewater using recycled wool-based non-woven material" in Journal of the Serbian Chemical Society, 72, no. 6 (2007):605-614,
https://doi.org/10.2298/JSC0706605R . .
9
9
10