TY  - JOUR
AU  - Stevanović, Jelena
AU  - Petrović, Srđan
AU  - Tadić, Nenad
AU  - Cvetanović, Katarina
AU  - Silva, Ana G.
AU  - Vasiljević-Radović, Dana
AU  - Sarajlić, Milija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5809
AB  - TiO2 and CeO2 are well known as oxygen sensing materials. Despite high sensitivity, the actual utilization of these materials in gas detection remains limited. Research conducted over the last two decades has revealed synergistic effects of TiO2-CeO2 mixed oxides that have the potential to improve some aspects of oxygen monitoring. However, there are no studies on the sensing properties of the TiO2-CeO2 obtained by mechanochemical treatment. We have tested the applicability of the mechanochemically treated TiO2-CeO2 for oxygen detection and presented the results in this study. The sensing layers are prepared as a porous structure by screen printing a thick film on a commercial substrate. The obtained structures were exposed to various O2 concentrations. The results of electrical measurements showed that TiO2-CeO2 films have a significantly lower resistance than pure oxide films. Mixtures of composition TiO2:CeO2 = 0.8:0.2, ground for 100 min, have the lowest electrical resistance among the tested materials. Mixtures of composition TiO2:CeO2 = 0.5:0.5 and ground for 100 min proved to be the most sensitive. The operating temperature can be as low as 320 °C, which places this sensor in the class of semiconductor sensors working at relatively lower temperatures.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Sensors
T1  - Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor
VL  - 23
IS  - 3
SP  - 1313
DO  - 10.3390/s23031313
ER  - 

@article{
author = "Stevanović, Jelena and Petrović, Srđan and Tadić, Nenad and Cvetanović, Katarina and Silva, Ana G. and Vasiljević-Radović, Dana and Sarajlić, Milija",
year = "2023",
abstract = "TiO2 and CeO2 are well known as oxygen sensing materials. Despite high sensitivity, the actual utilization of these materials in gas detection remains limited. Research conducted over the last two decades has revealed synergistic effects of TiO2-CeO2 mixed oxides that have the potential to improve some aspects of oxygen monitoring. However, there are no studies on the sensing properties of the TiO2-CeO2 obtained by mechanochemical treatment. We have tested the applicability of the mechanochemically treated TiO2-CeO2 for oxygen detection and presented the results in this study. The sensing layers are prepared as a porous structure by screen printing a thick film on a commercial substrate. The obtained structures were exposed to various O2 concentrations. The results of electrical measurements showed that TiO2-CeO2 films have a significantly lower resistance than pure oxide films. Mixtures of composition TiO2:CeO2 = 0.8:0.2, ground for 100 min, have the lowest electrical resistance among the tested materials. Mixtures of composition TiO2:CeO2 = 0.5:0.5 and ground for 100 min proved to be the most sensitive. The operating temperature can be as low as 320 °C, which places this sensor in the class of semiconductor sensors working at relatively lower temperatures.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Sensors",
title = "Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor",
volume = "23",
number = "3",
pages = "1313",
doi = "10.3390/s23031313"
}

Stevanović, J., Petrović, S., Tadić, N., Cvetanović, K., Silva, A. G., Vasiljević-Radović, D.,& Sarajlić, M.. (2023). Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor. in Sensors
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 23(3), 1313.
https://doi.org/10.3390/s23031313

Stevanović J, Petrović S, Tadić N, Cvetanović K, Silva AG, Vasiljević-Radović D, Sarajlić M. Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor. in Sensors. 2023;23(3):1313.
doi:10.3390/s23031313 .

Stevanović, Jelena, Petrović, Srđan, Tadić, Nenad, Cvetanović, Katarina, Silva, Ana G., Vasiljević-Radović, Dana, Sarajlić, Milija, "Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor" in Sensors, 23, no. 3 (2023):1313,
https://doi.org/10.3390/s23031313 . .

TY  - JOUR
AU  - Andrić, Stevan
AU  - Jokić, Ivana
AU  - Stevanović, Jelena
AU  - Spasenović, Marko
AU  - Frantlović, Miloš
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5583
AB  - Surfaces of adsorption-based gas sensors are often heterogeneous, with adsorption sites that differ in their affinities for gas particle binding. Knowing adsorption/desorption energies, surface densities and the relative abundance of sites of different types is important, because these parameters impact sensor sensitivity and selectivity, and are relevant for revealing the response-generating mechanisms. We show that the analysis of the noise of adsorption-based sensors can be used to study gas adsorption on heterogeneous sensing surfaces, which is applicable to industrially important liquid-phase exfoliated (LPE) graphene. Our results for CO2 adsorption on an LPE graphene surface, with different types of adsorption sites on graphene flake edges and basal planes, show that the noise spectrum data can be used to characterize such surfaces in terms of parameters that determine the sensing properties of the adsorbing material. Notably, the spectrum characteristic frequencies are an unambiguous indicator of the relative abundance of different types of adsorption sites on the sensing surface and their surface densities. We also demonstrate that spectrum features indicate the fraction of the binding sites that are already occupied by another gas species. The presented study can be applied to the design and production of graphene and other sensing surfaces with an optimal sensing performance.
PB  - MDPI AG
T2  - Chemosensors
T1  - Noise Spectrum as a Source of Information in Gas Sensors Based on Liquid-Phase Exfoliated Graphene
VL  - 10
IS  - 6
SP  - 224
DO  - 10.3390/chemosensors10060224
ER  - 

@article{
author = "Andrić, Stevan and Jokić, Ivana and Stevanović, Jelena and Spasenović, Marko and Frantlović, Miloš",
year = "2022",
abstract = "Surfaces of adsorption-based gas sensors are often heterogeneous, with adsorption sites that differ in their affinities for gas particle binding. Knowing adsorption/desorption energies, surface densities and the relative abundance of sites of different types is important, because these parameters impact sensor sensitivity and selectivity, and are relevant for revealing the response-generating mechanisms. We show that the analysis of the noise of adsorption-based sensors can be used to study gas adsorption on heterogeneous sensing surfaces, which is applicable to industrially important liquid-phase exfoliated (LPE) graphene. Our results for CO2 adsorption on an LPE graphene surface, with different types of adsorption sites on graphene flake edges and basal planes, show that the noise spectrum data can be used to characterize such surfaces in terms of parameters that determine the sensing properties of the adsorbing material. Notably, the spectrum characteristic frequencies are an unambiguous indicator of the relative abundance of different types of adsorption sites on the sensing surface and their surface densities. We also demonstrate that spectrum features indicate the fraction of the binding sites that are already occupied by another gas species. The presented study can be applied to the design and production of graphene and other sensing surfaces with an optimal sensing performance.",
publisher = "MDPI AG",
journal = "Chemosensors",
title = "Noise Spectrum as a Source of Information in Gas Sensors Based on Liquid-Phase Exfoliated Graphene",
volume = "10",
number = "6",
pages = "224",
doi = "10.3390/chemosensors10060224"
}

Andrić, S., Jokić, I., Stevanović, J., Spasenović, M.,& Frantlović, M.. (2022). Noise Spectrum as a Source of Information in Gas Sensors Based on Liquid-Phase Exfoliated Graphene. in Chemosensors
MDPI AG., 10(6), 224.
https://doi.org/10.3390/chemosensors10060224

Andrić S, Jokić I, Stevanović J, Spasenović M, Frantlović M. Noise Spectrum as a Source of Information in Gas Sensors Based on Liquid-Phase Exfoliated Graphene. in Chemosensors. 2022;10(6):224.
doi:10.3390/chemosensors10060224 .

Andrić, Stevan, Jokić, Ivana, Stevanović, Jelena, Spasenović, Marko, Frantlović, Miloš, "Noise Spectrum as a Source of Information in Gas Sensors Based on Liquid-Phase Exfoliated Graphene" in Chemosensors, 10, no. 6 (2022):224,
https://doi.org/10.3390/chemosensors10060224 . .

TY  - JOUR
AU  - Balaž, Ana Marija
AU  - Stevanović, Jelena
AU  - Ostafe, Raluca
AU  - Blažić, Marija
AU  - Ilić Đurđić, Karla
AU  - Fischer, Rainer
AU  - Prodanović, Radivoje
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3128
AB  - Cellobiose dehydrogenase (CDH, EC 1.1.99.18) from white rot fungi Phanerochaete chrysosporium can be used for constructing biosensors and biofuel cells, for bleaching cotton in textile industry, and recently, the enzyme has found an important application in biomedicine as an antimicrobial and antibiofilm agent. Stability and activity of the wild-type (wt) CDH and mutants at methionine residues in the presence of hydrogen peroxide were investigated. Saturation mutagenesis libraries were made at the only methionine in heme domain M65 and two methionines M685 and M738 in the flavin domain that were closest to the active site. After screening the libraries, three mutants with increased activity and stability in the presence of peroxide were found, M65F with 70% of residual activity after 6 h of incubation in 0.3 M hydrogen peroxide, M738S with 80% of residual activity and M685Y with over 90% of residual activity compared to wild-type CDH that retained 40% of original activity. Combined mutants showed no activity. The most stable mutant M685Y with 5.8 times increased half-life in the presence of peroxide showed also 2.5 times increased kcat for lactose compared to wtCDH and could be good candidate for applications in biofuel cells and biocatalysis for lactobionic acid production.
PB  - Springer International Publishing
T2  - Molecular Diversity
T1  - Semi‑rational design of cellobiose dehydrogenase for increased stability in the presence of peroxide
VL  - 24
SP  - 593
EP  - 601
DO  - 10.1007/s11030-019-09965-0
ER  - 

@article{
author = "Balaž, Ana Marija and Stevanović, Jelena and Ostafe, Raluca and Blažić, Marija and Ilić Đurđić, Karla and Fischer, Rainer and Prodanović, Radivoje",
year = "2020",
abstract = "Cellobiose dehydrogenase (CDH, EC 1.1.99.18) from white rot fungi Phanerochaete chrysosporium can be used for constructing biosensors and biofuel cells, for bleaching cotton in textile industry, and recently, the enzyme has found an important application in biomedicine as an antimicrobial and antibiofilm agent. Stability and activity of the wild-type (wt) CDH and mutants at methionine residues in the presence of hydrogen peroxide were investigated. Saturation mutagenesis libraries were made at the only methionine in heme domain M65 and two methionines M685 and M738 in the flavin domain that were closest to the active site. After screening the libraries, three mutants with increased activity and stability in the presence of peroxide were found, M65F with 70% of residual activity after 6 h of incubation in 0.3 M hydrogen peroxide, M738S with 80% of residual activity and M685Y with over 90% of residual activity compared to wild-type CDH that retained 40% of original activity. Combined mutants showed no activity. The most stable mutant M685Y with 5.8 times increased half-life in the presence of peroxide showed also 2.5 times increased kcat for lactose compared to wtCDH and could be good candidate for applications in biofuel cells and biocatalysis for lactobionic acid production.",
publisher = "Springer International Publishing",
journal = "Molecular Diversity",
title = "Semi‑rational design of cellobiose dehydrogenase for increased stability in the presence of peroxide",
volume = "24",
pages = "593-601",
doi = "10.1007/s11030-019-09965-0"
}

Balaž, A. M., Stevanović, J., Ostafe, R., Blažić, M., Ilić Đurđić, K., Fischer, R.,& Prodanović, R.. (2020). Semi‑rational design of cellobiose dehydrogenase for increased stability in the presence of peroxide. in Molecular Diversity
Springer International Publishing., 24, 593-601.
https://doi.org/10.1007/s11030-019-09965-0

Balaž AM, Stevanović J, Ostafe R, Blažić M, Ilić Đurđić K, Fischer R, Prodanović R. Semi‑rational design of cellobiose dehydrogenase for increased stability in the presence of peroxide. in Molecular Diversity. 2020;24:593-601.
doi:10.1007/s11030-019-09965-0 .

Balaž, Ana Marija, Stevanović, Jelena, Ostafe, Raluca, Blažić, Marija, Ilić Đurđić, Karla, Fischer, Rainer, Prodanović, Radivoje, "Semi‑rational design of cellobiose dehydrogenase for increased stability in the presence of peroxide" in Molecular Diversity, 24 (2020):593-601,
https://doi.org/10.1007/s11030-019-09965-0 . .

TY  - CONF
AU  - Stevanović, Jelena
AU  - Lazić, Žarko
AU  - Smiljanić, Milče M.
AU  - Radulović, Katarina
AU  - Randjelović, Danijela
AU  - Frantlović, Miloš
AU  - Sarajlić, Milija
PY  - 2019
UR  - https://www.etran.rs/2019/IcETRAN/About_Conference/
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4007
AB  - A consideration study for the application of the pressure sensor SP-12 developed and produced by ICTM CMT as an ultrasound sensor is given. The interaction of ultrasound with the sensor’s membrane was analytically described, but for the initial examination of its performance, Finite Elements Method simulation was applied. The sensor SP-12 has eigenfrequencies in the range from 200 kHz to the frequencies higher than 2 MHz. The amplitude of the output signal, which is proportional to Von Mises stress, is highest for the lowest frequency, and it exponentially decreases as the eigenfrequencies increase. This makes the sensor suitable for the ultrasound measurements in the range of hundreds of kHz
PB  - Belgrade : ETRAN Society
PB  - Belgrade : Akademska misao
C3  - Proceedings - 6th International Conference on Electrical, Electronics and Computing Engineering, IcETRAN 2019
T1  - A consideration of the use of ICTM SP-12 pressure sensor for ultrasound sensing
UR  - https://hdl.handle.net/21.15107/rcub_cer_4007
ER  - 

@conference{
author = "Stevanović, Jelena and Lazić, Žarko and Smiljanić, Milče M. and Radulović, Katarina and Randjelović, Danijela and Frantlović, Miloš and Sarajlić, Milija",
year = "2019",
abstract = "A consideration study for the application of the pressure sensor SP-12 developed and produced by ICTM CMT as an ultrasound sensor is given. The interaction of ultrasound with the sensor’s membrane was analytically described, but for the initial examination of its performance, Finite Elements Method simulation was applied. The sensor SP-12 has eigenfrequencies in the range from 200 kHz to the frequencies higher than 2 MHz. The amplitude of the output signal, which is proportional to Von Mises stress, is highest for the lowest frequency, and it exponentially decreases as the eigenfrequencies increase. This makes the sensor suitable for the ultrasound measurements in the range of hundreds of kHz",
publisher = "Belgrade : ETRAN Society, Belgrade : Akademska misao",
journal = "Proceedings - 6th International Conference on Electrical, Electronics and Computing Engineering, IcETRAN 2019",
title = "A consideration of the use of ICTM SP-12 pressure sensor for ultrasound sensing",
url = "https://hdl.handle.net/21.15107/rcub_cer_4007"
}

Stevanović, J., Lazić, Ž., Smiljanić, M. M., Radulović, K., Randjelović, D., Frantlović, M.,& Sarajlić, M.. (2019). A consideration of the use of ICTM SP-12 pressure sensor for ultrasound sensing. in Proceedings - 6th International Conference on Electrical, Electronics and Computing Engineering, IcETRAN 2019
Belgrade : ETRAN Society..
https://hdl.handle.net/21.15107/rcub_cer_4007

Stevanović J, Lazić Ž, Smiljanić MM, Radulović K, Randjelović D, Frantlović M, Sarajlić M. A consideration of the use of ICTM SP-12 pressure sensor for ultrasound sensing. in Proceedings - 6th International Conference on Electrical, Electronics and Computing Engineering, IcETRAN 2019. 2019;.
https://hdl.handle.net/21.15107/rcub_cer_4007 .

Stevanović, Jelena, Lazić, Žarko, Smiljanić, Milče M., Radulović, Katarina, Randjelović, Danijela, Frantlović, Miloš, Sarajlić, Milija, "A consideration of the use of ICTM SP-12 pressure sensor for ultrasound sensing" in Proceedings - 6th International Conference on Electrical, Electronics and Computing Engineering, IcETRAN 2019 (2019),
https://hdl.handle.net/21.15107/rcub_cer_4007 .