Abu Rabi-Stanković, Andjela S.

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13f125b2-2633-45fb-ae78-ea50ebcb3137
  • Abu Rabi-Stanković, Andjela S. (9)
  • Abu Rabi, Anđela (2)
  • Abu Rabi, Andjela (2)
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Author's Bibliography

Methanol electrooxidation on PtRu modified zeolite X

Mojović, Zorica; Mudrinić, Tihana; Abu Rabi-Stanković, Andjela S.; Ivanović-Šašić, Ana; Marinović, Sanja; Žunić, Marija; Jovanović, Dušan M.

(International Institute for the Science of Sintering, Beograd, 2013)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Mudrinić, Tihana
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Ivanović-Šašić, Ana
AU  - Marinović, Sanja
AU  - Žunić, Marija
AU  - Jovanović, Dušan M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1363
AB  - Zeolite NaX (faujasite type) was used as a support for platinum-ruthenium catalyst. A procedure for thermal decomposition of noble metal acetylacetonates to deposit noble metal clusters on the surface of solid support was adapted by authors to introduce noble metal clusters in zeolite cavities. The effectiveness of this composite material for methanol electrooxidation from alkaline solution was investigated by cyclic voltammetry. The influence of the concentration of supporting electrolyte, scan rate and rotation rate on the reaction of methanol oxidation was investigated. The obtained activity was compared with literature data for similar catalysts.
AB  - Zeolit NaX (fožazitnog tipa) korišćen je kao nosač za platina-rutenijumski katalizator. Autori su prilagodili proceduru termalne dekompozicije plemenitih metalnih acetilacetonata kojom su nanošeni klasteri plemenitih metala na površinu čvrste podloge, kako bi se klasteri plemenitih metala su uveli u šupljine zeolita. Efikasnost ovih kompozitnih materijala za reakciju elektrooksidacije metanola je ispitana cikličnom voltametrijom. Ispitan je uticaj koncentracije inertnog (osnovnog) elektrolita, brzine polarizacije i brzine rotacije elektrode na reakciju oksidacije metanola. Dobijena aktivnost je upoređena sa literaturnim podacima za slične katalizatore.
PB  - International Institute for the Science of Sintering, Beograd
T2  - Science of Sintering
T1  - Methanol electrooxidation on PtRu modified zeolite X
VL  - 45
IS  - 1
SP  - 89
EP  - 96
DO  - 10.2298/SOS1301089M
ER  - 
@article{
author = "Mojović, Zorica and Mudrinić, Tihana and Abu Rabi-Stanković, Andjela S. and Ivanović-Šašić, Ana and Marinović, Sanja and Žunić, Marija and Jovanović, Dušan M.",
year = "2013",
abstract = "Zeolite NaX (faujasite type) was used as a support for platinum-ruthenium catalyst. A procedure for thermal decomposition of noble metal acetylacetonates to deposit noble metal clusters on the surface of solid support was adapted by authors to introduce noble metal clusters in zeolite cavities. The effectiveness of this composite material for methanol electrooxidation from alkaline solution was investigated by cyclic voltammetry. The influence of the concentration of supporting electrolyte, scan rate and rotation rate on the reaction of methanol oxidation was investigated. The obtained activity was compared with literature data for similar catalysts., Zeolit NaX (fožazitnog tipa) korišćen je kao nosač za platina-rutenijumski katalizator. Autori su prilagodili proceduru termalne dekompozicije plemenitih metalnih acetilacetonata kojom su nanošeni klasteri plemenitih metala na površinu čvrste podloge, kako bi se klasteri plemenitih metala su uveli u šupljine zeolita. Efikasnost ovih kompozitnih materijala za reakciju elektrooksidacije metanola je ispitana cikličnom voltametrijom. Ispitan je uticaj koncentracije inertnog (osnovnog) elektrolita, brzine polarizacije i brzine rotacije elektrode na reakciju oksidacije metanola. Dobijena aktivnost je upoređena sa literaturnim podacima za slične katalizatore.",
publisher = "International Institute for the Science of Sintering, Beograd",
journal = "Science of Sintering",
title = "Methanol electrooxidation on PtRu modified zeolite X",
volume = "45",
number = "1",
pages = "89-96",
doi = "10.2298/SOS1301089M"
}
Mojović, Z., Mudrinić, T., Abu Rabi-Stanković, A. S., Ivanović-Šašić, A., Marinović, S., Žunić, M.,& Jovanović, D. M.. (2013). Methanol electrooxidation on PtRu modified zeolite X. in Science of Sintering
International Institute for the Science of Sintering, Beograd., 45(1), 89-96.
https://doi.org/10.2298/SOS1301089M
Mojović Z, Mudrinić T, Abu Rabi-Stanković AS, Ivanović-Šašić A, Marinović S, Žunić M, Jovanović DM. Methanol electrooxidation on PtRu modified zeolite X. in Science of Sintering. 2013;45(1):89-96.
doi:10.2298/SOS1301089M .
Mojović, Zorica, Mudrinić, Tihana, Abu Rabi-Stanković, Andjela S., Ivanović-Šašić, Ana, Marinović, Sanja, Žunić, Marija, Jovanović, Dušan M., "Methanol electrooxidation on PtRu modified zeolite X" in Science of Sintering, 45, no. 1 (2013):89-96,
https://doi.org/10.2298/SOS1301089M . .
7
7
8

Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation

Mojović, Zorica; Jović-Jovičić, Nataša; Milutinović Nikolić, Aleksandra; Banković, Predrag; Abu Rabi-Stanković, Andjela S.; Jovanović, Dušan M.

(Wiley-Blackwell, Hoboken, 2013)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Jović-Jovičić, Nataša
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Jovanović, Dušan M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1226
AB  - In this article partial and complete substitution of cations in the interlayer region of clay with different amounts of hexadecyl trimethylammonium bromide (HDTMABr) was performed. The aim was to investigate the influence of HDTMA/bentonite ratio on phenol electrooxidation. Multisweep cyclic voltammetry was applied to analyze the behavior of clay modified glassy carbon electrode. The influence of phenol concentration was investigated. HDTMA/clay ratio plays key role in phenol oxidation on these electrodes. There is definite amount of surfactant that should be present in bentonite sample in order to achieve good current response and prolonged life of the electrode. The reaction order in respect to phenol was determined to be around 2.
PB  - Wiley-Blackwell, Hoboken
T2  - Environmental Progress & Sustainable Energy
T1  - Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation
VL  - 32
IS  - 4
SP  - 1124
EP  - 1128
DO  - 10.1002/ep.11739
ER  - 
@article{
author = "Mojović, Zorica and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Banković, Predrag and Abu Rabi-Stanković, Andjela S. and Jovanović, Dušan M.",
year = "2013",
abstract = "In this article partial and complete substitution of cations in the interlayer region of clay with different amounts of hexadecyl trimethylammonium bromide (HDTMABr) was performed. The aim was to investigate the influence of HDTMA/bentonite ratio on phenol electrooxidation. Multisweep cyclic voltammetry was applied to analyze the behavior of clay modified glassy carbon electrode. The influence of phenol concentration was investigated. HDTMA/clay ratio plays key role in phenol oxidation on these electrodes. There is definite amount of surfactant that should be present in bentonite sample in order to achieve good current response and prolonged life of the electrode. The reaction order in respect to phenol was determined to be around 2.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "Environmental Progress & Sustainable Energy",
title = "Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation",
volume = "32",
number = "4",
pages = "1124-1128",
doi = "10.1002/ep.11739"
}
Mojović, Z., Jović-Jovičić, N., Milutinović Nikolić, A., Banković, P., Abu Rabi-Stanković, A. S.,& Jovanović, D. M.. (2013). Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation. in Environmental Progress & Sustainable Energy
Wiley-Blackwell, Hoboken., 32(4), 1124-1128.
https://doi.org/10.1002/ep.11739
Mojović Z, Jović-Jovičić N, Milutinović Nikolić A, Banković P, Abu Rabi-Stanković AS, Jovanović DM. Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation. in Environmental Progress & Sustainable Energy. 2013;32(4):1124-1128.
doi:10.1002/ep.11739 .
Mojović, Zorica, Jović-Jovičić, Nataša, Milutinović Nikolić, Aleksandra, Banković, Predrag, Abu Rabi-Stanković, Andjela S., Jovanović, Dušan M., "Influence of HDTMA/Bentonite Ratio on Phenol Electrooxidation" in Environmental Progress & Sustainable Energy, 32, no. 4 (2013):1124-1128,
https://doi.org/10.1002/ep.11739 . .
1
1

Electrooxidation of p-nitrophenol on organobentonite modified electrodes

Abu Rabi-Stanković, Andjela S.; Mojović, Zorica; Milutinović Nikolić, Aleksandra; Jović-Jovičić, Nataša; Banković, Predrag; Žunić, Marija; Jovanović, Dušan M.

(Elsevier, 2013)

TY  - JOUR
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Mojović, Zorica
AU  - Milutinović Nikolić, Aleksandra
AU  - Jović-Jovičić, Nataša
AU  - Banković, Predrag
AU  - Žunić, Marija
AU  - Jovanović, Dušan M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1336
AB  - A natural bentonite, modified with different quaternary ammonium cations, hexadecyl trimethylammonium, (HDTMA), dodecyl trimethylammonium (DTMA) and tetramethylammonium (TMA), was used as an electrode material in a p-nitrophenol (p-NP) electrooxidation. On the basis of electrochemical response, TMA-modified bentonite (TMA-B) electrode was chosen for further investigations. The influence of TMA loading on the electrochemical properties of the TMA-B electrodes toward p-NP electrooxidation was examined. Electrode sensitivity toward p-NP was performed. The detection limit for p-NP of 1 . 10(-6) mol dm(-3) was obtained.
PB  - Elsevier
T2  - Applied Clay Science
T1  - Electrooxidation of p-nitrophenol on organobentonite modified electrodes
SP  - 61
EP  - 67
DO  - 10.1016/j.clay.2013.04.003
ER  - 
@article{
author = "Abu Rabi-Stanković, Andjela S. and Mojović, Zorica and Milutinović Nikolić, Aleksandra and Jović-Jovičić, Nataša and Banković, Predrag and Žunić, Marija and Jovanović, Dušan M.",
year = "2013",
abstract = "A natural bentonite, modified with different quaternary ammonium cations, hexadecyl trimethylammonium, (HDTMA), dodecyl trimethylammonium (DTMA) and tetramethylammonium (TMA), was used as an electrode material in a p-nitrophenol (p-NP) electrooxidation. On the basis of electrochemical response, TMA-modified bentonite (TMA-B) electrode was chosen for further investigations. The influence of TMA loading on the electrochemical properties of the TMA-B electrodes toward p-NP electrooxidation was examined. Electrode sensitivity toward p-NP was performed. The detection limit for p-NP of 1 . 10(-6) mol dm(-3) was obtained.",
publisher = "Elsevier",
journal = "Applied Clay Science",
title = "Electrooxidation of p-nitrophenol on organobentonite modified electrodes",
pages = "61-67",
doi = "10.1016/j.clay.2013.04.003"
}
Abu Rabi-Stanković, A. S., Mojović, Z., Milutinović Nikolić, A., Jović-Jovičić, N., Banković, P., Žunić, M.,& Jovanović, D. M.. (2013). Electrooxidation of p-nitrophenol on organobentonite modified electrodes. in Applied Clay Science
Elsevier., 61-67.
https://doi.org/10.1016/j.clay.2013.04.003
Abu Rabi-Stanković AS, Mojović Z, Milutinović Nikolić A, Jović-Jovičić N, Banković P, Žunić M, Jovanović DM. Electrooxidation of p-nitrophenol on organobentonite modified electrodes. in Applied Clay Science. 2013;:61-67.
doi:10.1016/j.clay.2013.04.003 .
Abu Rabi-Stanković, Andjela S., Mojović, Zorica, Milutinović Nikolić, Aleksandra, Jović-Jovičić, Nataša, Banković, Predrag, Žunić, Marija, Jovanović, Dušan M., "Electrooxidation of p-nitrophenol on organobentonite modified electrodes" in Applied Clay Science (2013):61-67,
https://doi.org/10.1016/j.clay.2013.04.003 . .
20
13
20

Oxidation of hydroxide ions at platinum-modified zeolite electrode

Mudrinić, Tihana; Mojović, Zorica; Abu Rabi-Stanković, Andjela S.; Ivanović-Šašić, Ana; Milutinović Nikolić, Aleksandra; Jovanović, Dušan M.

(Association of Chemical Engineers of Serbia, 2012)

TY  - JOUR
AU  - Mudrinić, Tihana
AU  - Mojović, Zorica
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Ivanović-Šašić, Ana
AU  - Milutinović Nikolić, Aleksandra
AU  - Jovanović, Dušan M.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1043
AB  - NaX zeolite was modified by platinum via impregnation/thermal decomposition technique, using Pt(II)-acetyl acetonate in acetone as an impregnating solution. The samples were characterized by scanning electron microscopy (SEM) and cyclic voltammetry methods. The mixture of modified zeolite and 10 wt.% of carbon black, in a form of thin layer, was pasted to a glassy carbon surface. With this mixture as the electrode material, oxidation of hydroxide ions was studied by cyclic voltammetry. The response of modified zeolite electrodes was compared with bare platinum electrode and platinum electrode covered with Nafion film.
AB  - Zeolit tipa NaX je modifikovan platinom tehnikom impregnacija/termalna degradacija. Kao impregnirajući rastvor je korišćen rastvor Pt (II) acetilacetonata u acetonu. Uzorci su okarakterisani metodama skenirajuće elektronske mikroskopije (SEM) i ciklične voltametrije. Modifikovani zeolit je homogeno dispergovan u rastvoru Nafiona (5 mas.%) u mešavini izopropil alkohola i vode, pomoću ultrazvučnog kupatila. Elektronska provodljivost uzorka je poboljšana dodatkom 10 mas.% ugljenika (carbon black Vulcan XC72 (Cabot Corp.)) u suspenziju. Kap suspenzije je postavljena na površinu elektrode o staklastog ugljenika. Nakon isparavanja rastvarača na elektrodi je formiran tanak film. Oksidacija hidroksilanih jona je ispitana na ovako formiranoj elektrodi metodom ciklične voltametrije. Na osnovu SEM mikrografija moglo se uočiti da ne postoji značajna razlika u obliku i veličini čestica polaznog zeolita i zeolita modifikovanog platinum. Rezultati EDX analize su značajno varirali u zavisnosti od mesta na uzorku na kome je izvršena analiza. Sadržaj platine se kretao u intervalu 1-10 mas.%. Reakcija oksidacija hidroksilnih jona je, poređenja radi, ispitana na čistoj platinskoj elektrodi i platinskoj elektrodi pokrivenoj filmom Nafiona. Na platinskoj elektrodi, kako čistoj tako i pokrivenoj Nafionom, dobijen je očekivani sigmoidalni talas sa platoom, koji odgovara graničnoj difuzionoj struji. Prisustvo Nafiona na platinskoj elektrodi dovelo je do nižih graničnih struja pri oksidaciji hidroksilnih jona. Međutim, reproduktivnost ciklovoltamograma je značajno poboljšana, a povećan je i opseg potencijala u kome se dobija jasno definisan plato. Ciklovoltamogrami zeolitske platinisane elektrode, snimljeni pri istim uslovima kao i platinska elektroda, ispoljili su pojavu pika usled velikog koncentracionog gradijenta. Tafelovi nagibi Nafionom pokrivene platinske elektrode i zeolitske platinisane elektrode pokazuju značajnu zavisnost od koncentracije hidroksilnih jona, dok Tafelovi nagibi čiste platinske elektrode nisu zavisili od koncentracije analita. Granična gustina struje pokazuje linearnu zavisnost od koncentracije hidroksilnih jona sa dobrim korelacinim faktorom, za sve tri ispitivane elektrode.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Oxidation of hydroxide ions at platinum-modified zeolite electrode
T1  - Izvod oksidacija hidroksilnih jona na zeolitu modifikovanom platinom
VL  - 66
IS  - 5
SP  - 759
EP  - 767
DO  - 10.2298/HEMIND111223027M
ER  - 
@article{
author = "Mudrinić, Tihana and Mojović, Zorica and Abu Rabi-Stanković, Andjela S. and Ivanović-Šašić, Ana and Milutinović Nikolić, Aleksandra and Jovanović, Dušan M.",
year = "2012",
abstract = "NaX zeolite was modified by platinum via impregnation/thermal decomposition technique, using Pt(II)-acetyl acetonate in acetone as an impregnating solution. The samples were characterized by scanning electron microscopy (SEM) and cyclic voltammetry methods. The mixture of modified zeolite and 10 wt.% of carbon black, in a form of thin layer, was pasted to a glassy carbon surface. With this mixture as the electrode material, oxidation of hydroxide ions was studied by cyclic voltammetry. The response of modified zeolite electrodes was compared with bare platinum electrode and platinum electrode covered with Nafion film., Zeolit tipa NaX je modifikovan platinom tehnikom impregnacija/termalna degradacija. Kao impregnirajući rastvor je korišćen rastvor Pt (II) acetilacetonata u acetonu. Uzorci su okarakterisani metodama skenirajuće elektronske mikroskopije (SEM) i ciklične voltametrije. Modifikovani zeolit je homogeno dispergovan u rastvoru Nafiona (5 mas.%) u mešavini izopropil alkohola i vode, pomoću ultrazvučnog kupatila. Elektronska provodljivost uzorka je poboljšana dodatkom 10 mas.% ugljenika (carbon black Vulcan XC72 (Cabot Corp.)) u suspenziju. Kap suspenzije je postavljena na površinu elektrode o staklastog ugljenika. Nakon isparavanja rastvarača na elektrodi je formiran tanak film. Oksidacija hidroksilanih jona je ispitana na ovako formiranoj elektrodi metodom ciklične voltametrije. Na osnovu SEM mikrografija moglo se uočiti da ne postoji značajna razlika u obliku i veličini čestica polaznog zeolita i zeolita modifikovanog platinum. Rezultati EDX analize su značajno varirali u zavisnosti od mesta na uzorku na kome je izvršena analiza. Sadržaj platine se kretao u intervalu 1-10 mas.%. Reakcija oksidacija hidroksilnih jona je, poređenja radi, ispitana na čistoj platinskoj elektrodi i platinskoj elektrodi pokrivenoj filmom Nafiona. Na platinskoj elektrodi, kako čistoj tako i pokrivenoj Nafionom, dobijen je očekivani sigmoidalni talas sa platoom, koji odgovara graničnoj difuzionoj struji. Prisustvo Nafiona na platinskoj elektrodi dovelo je do nižih graničnih struja pri oksidaciji hidroksilnih jona. Međutim, reproduktivnost ciklovoltamograma je značajno poboljšana, a povećan je i opseg potencijala u kome se dobija jasno definisan plato. Ciklovoltamogrami zeolitske platinisane elektrode, snimljeni pri istim uslovima kao i platinska elektroda, ispoljili su pojavu pika usled velikog koncentracionog gradijenta. Tafelovi nagibi Nafionom pokrivene platinske elektrode i zeolitske platinisane elektrode pokazuju značajnu zavisnost od koncentracije hidroksilnih jona, dok Tafelovi nagibi čiste platinske elektrode nisu zavisili od koncentracije analita. Granična gustina struje pokazuje linearnu zavisnost od koncentracije hidroksilnih jona sa dobrim korelacinim faktorom, za sve tri ispitivane elektrode.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Oxidation of hydroxide ions at platinum-modified zeolite electrode, Izvod oksidacija hidroksilnih jona na zeolitu modifikovanom platinom",
volume = "66",
number = "5",
pages = "759-767",
doi = "10.2298/HEMIND111223027M"
}
Mudrinić, T., Mojović, Z., Abu Rabi-Stanković, A. S., Ivanović-Šašić, A., Milutinović Nikolić, A.,& Jovanović, D. M.. (2012). Oxidation of hydroxide ions at platinum-modified zeolite electrode. in Hemijska industrija
Association of Chemical Engineers of Serbia., 66(5), 759-767.
https://doi.org/10.2298/HEMIND111223027M
Mudrinić T, Mojović Z, Abu Rabi-Stanković AS, Ivanović-Šašić A, Milutinović Nikolić A, Jovanović DM. Oxidation of hydroxide ions at platinum-modified zeolite electrode. in Hemijska industrija. 2012;66(5):759-767.
doi:10.2298/HEMIND111223027M .
Mudrinić, Tihana, Mojović, Zorica, Abu Rabi-Stanković, Andjela S., Ivanović-Šašić, Ana, Milutinović Nikolić, Aleksandra, Jovanović, Dušan M., "Oxidation of hydroxide ions at platinum-modified zeolite electrode" in Hemijska industrija, 66, no. 5 (2012):759-767,
https://doi.org/10.2298/HEMIND111223027M . .
3
1
2

Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X

Mojović, Zorica; Banković, Predrag; Jović-Jovičić, Nataša; Abu Rabi-Stanković, Andjela S.; Milutinović Nikolić, Aleksandra; Jovanović, Dušan M.

(Springer, Dordrecht, 2012)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Banković, Predrag
AU  - Jović-Jovičić, Nataša
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Milutinović Nikolić, Aleksandra
AU  - Jovanović, Dušan M.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1101
AB  - Zeolite NaX was modified by Pt and Pt/Ru nanodispersed metallic clusters. This modification was achieved by zeolite impregnation with acetylacetonate salt/acetone solution, followed by acetone evaporation and thermal decomposition of organometallic complex. Samples characterization was performed by X-ray diffraction analysis, nitrogen adsorption-desorption measurements and Raman spectroscopy. The incorporation of metal into zeolite cavities induced the amorphisation of the zeolite framework on the local level. The mixture of modified zeolite and 10 wt% of carbon black, in a form of thin layer, was pasted to a glassy carbon surface by Nafion. Electrocatalytic properties of metal-modified zeolites were tested in CO electrooxidation reaction. The mutual influence between Pt and Ru atoms enhanced electroactivity of Pt/Ru-modified zeolite toward carbon monoxide electrooxidation. The behavior of untreated 13X zeolite was investigated under the same condition in order to asses the influence of the support. Gradual deactivation of 13X electrode occurred.
PB  - Springer, Dordrecht
T2  - Journal of Porous Materials
T1  - Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X
VL  - 19
IS  - 5
SP  - 695
EP  - 703
DO  - 10.1007/s10934-011-9521-6
ER  - 
@article{
author = "Mojović, Zorica and Banković, Predrag and Jović-Jovičić, Nataša and Abu Rabi-Stanković, Andjela S. and Milutinović Nikolić, Aleksandra and Jovanović, Dušan M.",
year = "2012",
abstract = "Zeolite NaX was modified by Pt and Pt/Ru nanodispersed metallic clusters. This modification was achieved by zeolite impregnation with acetylacetonate salt/acetone solution, followed by acetone evaporation and thermal decomposition of organometallic complex. Samples characterization was performed by X-ray diffraction analysis, nitrogen adsorption-desorption measurements and Raman spectroscopy. The incorporation of metal into zeolite cavities induced the amorphisation of the zeolite framework on the local level. The mixture of modified zeolite and 10 wt% of carbon black, in a form of thin layer, was pasted to a glassy carbon surface by Nafion. Electrocatalytic properties of metal-modified zeolites were tested in CO electrooxidation reaction. The mutual influence between Pt and Ru atoms enhanced electroactivity of Pt/Ru-modified zeolite toward carbon monoxide electrooxidation. The behavior of untreated 13X zeolite was investigated under the same condition in order to asses the influence of the support. Gradual deactivation of 13X electrode occurred.",
publisher = "Springer, Dordrecht",
journal = "Journal of Porous Materials",
title = "Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X",
volume = "19",
number = "5",
pages = "695-703",
doi = "10.1007/s10934-011-9521-6"
}
Mojović, Z., Banković, P., Jović-Jovičić, N., Abu Rabi-Stanković, A. S., Milutinović Nikolić, A.,& Jovanović, D. M.. (2012). Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X. in Journal of Porous Materials
Springer, Dordrecht., 19(5), 695-703.
https://doi.org/10.1007/s10934-011-9521-6
Mojović Z, Banković P, Jović-Jovičić N, Abu Rabi-Stanković AS, Milutinović Nikolić A, Jovanović DM. Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X. in Journal of Porous Materials. 2012;19(5):695-703.
doi:10.1007/s10934-011-9521-6 .
Mojović, Zorica, Banković, Predrag, Jović-Jovičić, Nataša, Abu Rabi-Stanković, Andjela S., Milutinović Nikolić, Aleksandra, Jovanović, Dušan M., "Carbon monoxide electrooxidation on Pt and PtRu modified zeolite X" in Journal of Porous Materials, 19, no. 5 (2012):695-703,
https://doi.org/10.1007/s10934-011-9521-6 . .
14
14
14

P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode

Abu Rabi-Stanković, Andjela S.; Milutinović Nikolić, Aleksandra; Jović-Jovičić, Nataša; Banković, Predrag; Žunić, Marija; Mojović, Zorica; Jovanović, Dušan M.

(Clay Minerals Soc, Chantilly, 2012)

TY  - JOUR
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Milutinović Nikolić, Aleksandra
AU  - Jović-Jovičić, Nataša
AU  - Banković, Predrag
AU  - Žunić, Marija
AU  - Mojović, Zorica
AU  - Jovanović, Dušan M.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1102
AB  - Phenol and its derivatives arc regarded as 'priority pollutants' and p-nitrophenol (p-NP), in particular, is of great interest due to its toxicity and frequent presence in waste waters and fresh waters. Straightforward, inexpensive methods to identify p-NP in water, however, is lacking. In the present study, an electrochemical technique using clay-modified electrodes to measure p-NP was investigated as a potentially promising method to fill that gap. A glassy carbon electrode (GCE) was modified with a thin layer of Na-enriched bentonite and a series of benzyltrimethylammonium (BTMA(+))-bentonites (BTMA(+)-B) in order to confirm these materials as p-NP electrosensitive. A series of organobentonites was synthesized using different BTMA(+)/bentonite ratios. The materials obtained were characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, and a low-temperature nitrogen adsorption-desorption method. A monolayer arrangement of BTMA(+) within the interlamellar region of beidellite-rich smectite was confirmed. Deterioration of the textural properties was observed with increase of BTMA(+). loading. The electro-oxidation of p-NP in an acidic medium on BTMA(+)-B-modified GCE was investigated. The cyclic voltammetry method with a three-electrode cell was used. The reference electrode was Ag/AgCl in 3 M KCl and a Pt foil was the counter electrode. For each electrochemical measurement, a different BTMA(+) loading in BTMA(+)-B was used as the material for GCE coating and applied as the working electrode. The electrochemical activity of BTMA(+)-B-based electrodes increased with BTMA(+) loading. The results confirmed that the organophylic character of the BTMA(+)-B-modified surface was the main influence on the electrochemical activity of the BTMA(+)-B-based GCE; the influence of textural properties was almost negligible. The increased electrode activity toward p-NP was achieved by the adsorption of p-NP on the electrode surface, the process that commonly precedes the electro-oxidation. The present study showed that synthesized materials could potentially be used in an electrochemical test for the presence of p-NP in water solutions.
PB  - Clay Minerals Soc, Chantilly
T2  - Clays and Clay Minerals
T1  - P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode
VL  - 60
IS  - 3
SP  - 291
EP  - 299
DO  - 10.1346/CCMN.2012.0600306
ER  - 
@article{
author = "Abu Rabi-Stanković, Andjela S. and Milutinović Nikolić, Aleksandra and Jović-Jovičić, Nataša and Banković, Predrag and Žunić, Marija and Mojović, Zorica and Jovanović, Dušan M.",
year = "2012",
abstract = "Phenol and its derivatives arc regarded as 'priority pollutants' and p-nitrophenol (p-NP), in particular, is of great interest due to its toxicity and frequent presence in waste waters and fresh waters. Straightforward, inexpensive methods to identify p-NP in water, however, is lacking. In the present study, an electrochemical technique using clay-modified electrodes to measure p-NP was investigated as a potentially promising method to fill that gap. A glassy carbon electrode (GCE) was modified with a thin layer of Na-enriched bentonite and a series of benzyltrimethylammonium (BTMA(+))-bentonites (BTMA(+)-B) in order to confirm these materials as p-NP electrosensitive. A series of organobentonites was synthesized using different BTMA(+)/bentonite ratios. The materials obtained were characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, and a low-temperature nitrogen adsorption-desorption method. A monolayer arrangement of BTMA(+) within the interlamellar region of beidellite-rich smectite was confirmed. Deterioration of the textural properties was observed with increase of BTMA(+). loading. The electro-oxidation of p-NP in an acidic medium on BTMA(+)-B-modified GCE was investigated. The cyclic voltammetry method with a three-electrode cell was used. The reference electrode was Ag/AgCl in 3 M KCl and a Pt foil was the counter electrode. For each electrochemical measurement, a different BTMA(+) loading in BTMA(+)-B was used as the material for GCE coating and applied as the working electrode. The electrochemical activity of BTMA(+)-B-based electrodes increased with BTMA(+) loading. The results confirmed that the organophylic character of the BTMA(+)-B-modified surface was the main influence on the electrochemical activity of the BTMA(+)-B-based GCE; the influence of textural properties was almost negligible. The increased electrode activity toward p-NP was achieved by the adsorption of p-NP on the electrode surface, the process that commonly precedes the electro-oxidation. The present study showed that synthesized materials could potentially be used in an electrochemical test for the presence of p-NP in water solutions.",
publisher = "Clay Minerals Soc, Chantilly",
journal = "Clays and Clay Minerals",
title = "P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode",
volume = "60",
number = "3",
pages = "291-299",
doi = "10.1346/CCMN.2012.0600306"
}
Abu Rabi-Stanković, A. S., Milutinović Nikolić, A., Jović-Jovičić, N., Banković, P., Žunić, M., Mojović, Z.,& Jovanović, D. M.. (2012). P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode. in Clays and Clay Minerals
Clay Minerals Soc, Chantilly., 60(3), 291-299.
https://doi.org/10.1346/CCMN.2012.0600306
Abu Rabi-Stanković AS, Milutinović Nikolić A, Jović-Jovičić N, Banković P, Žunić M, Mojović Z, Jovanović DM. P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode. in Clays and Clay Minerals. 2012;60(3):291-299.
doi:10.1346/CCMN.2012.0600306 .
Abu Rabi-Stanković, Andjela S., Milutinović Nikolić, Aleksandra, Jović-Jovičić, Nataša, Banković, Predrag, Žunić, Marija, Mojović, Zorica, Jovanović, Dušan M., "P-nitrophenol electro-oxidation on a btma(+)-bentonite-modified electrode" in Clays and Clay Minerals, 60, no. 3 (2012):291-299,
https://doi.org/10.1346/CCMN.2012.0600306 . .
9
8
10

Electrocatalytic behavior of nickel impregnated zeolite electrode

Mojović, Zorica; Banković, Predrag; Jović-Jovičić, Nataša; Milutinović Nikolić, Aleksandra; Abu Rabi-Stanković, Andjela S.; Jovanović, Dušan M.

(Oxford : Pergamon-Elsevier Science Ltd, 2011)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Banković, Predrag
AU  - Jović-Jovičić, Nataša
AU  - Milutinović Nikolić, Aleksandra
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Jovanović, Dušan M.
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/810
AB  - In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - International Journal of Hydrogen Energy
T1  - Electrocatalytic behavior of nickel impregnated zeolite electrode
VL  - 36
IS  - 21
SP  - 13343
EP  - 13351
DO  - 10.1016/j.ijhydene.2011.07.097
ER  - 
@article{
author = "Mojović, Zorica and Banković, Predrag and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Abu Rabi-Stanković, Andjela S. and Jovanović, Dušan M.",
year = "2011",
abstract = "In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "International Journal of Hydrogen Energy",
title = "Electrocatalytic behavior of nickel impregnated zeolite electrode",
volume = "36",
number = "21",
pages = "13343-13351",
doi = "10.1016/j.ijhydene.2011.07.097"
}
Mojović, Z., Banković, P., Jović-Jovičić, N., Milutinović Nikolić, A., Abu Rabi-Stanković, A. S.,& Jovanović, D. M.. (2011). Electrocatalytic behavior of nickel impregnated zeolite electrode. in International Journal of Hydrogen Energy
Oxford : Pergamon-Elsevier Science Ltd., 36(21), 13343-13351.
https://doi.org/10.1016/j.ijhydene.2011.07.097
Mojović Z, Banković P, Jović-Jovičić N, Milutinović Nikolić A, Abu Rabi-Stanković AS, Jovanović DM. Electrocatalytic behavior of nickel impregnated zeolite electrode. in International Journal of Hydrogen Energy. 2011;36(21):13343-13351.
doi:10.1016/j.ijhydene.2011.07.097 .
Mojović, Zorica, Banković, Predrag, Jović-Jovičić, Nataša, Milutinović Nikolić, Aleksandra, Abu Rabi-Stanković, Andjela S., Jovanović, Dušan M., "Electrocatalytic behavior of nickel impregnated zeolite electrode" in International Journal of Hydrogen Energy, 36, no. 21 (2011):13343-13351,
https://doi.org/10.1016/j.ijhydene.2011.07.097 . .
28
27
29

Phenol determination on HDTMA-bentonite-based electrodes

Mojović, Zorica; Jović-Jovičić, Nataša; Milutinović Nikolić, Aleksandra; Banković, Predrag; Abu Rabi-Stanković, Andjela S.; Jovanović, Dušan M.

(Elsevier, 2011)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Jović-Jovičić, Nataša
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Jovanović, Dušan M.
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/839
AB  - The partial and complete substitution of cations in the interlayer region of clay with different amounts of hexadecyl trimethylammonium bromide (HDTMABr) was performed. The aim was to synthesize organo-bentonites to be used as constituents of porous electrodes for the electrooxidation of phenol. Domestic clay from Bogovina was subjected to a common procedure of the production of organo-bentonites. It included the following steps: grinding, sieving, Na-exchange, cation exchange and drying. The samples were characterized by X-ray diffraction (XRD) analysis, while the textural properties were evaluated by nitrogen physisorption. The multisweep cyclic voltammetry was applied to analyze the behavior of the clay modified glassy carbon electrode. The influences of the surfactant loading and pH of the support electrolyte were investigated. Rapid deactivation of electrodes occurred in an acidic environment, while good stability of the investigated electrodes was obtained in alkaline medium.
PB  - Elsevier
T2  - Journal of Hazardous Materials
T1  - Phenol determination on HDTMA-bentonite-based electrodes
VL  - 194
SP  - 178
EP  - 184
DO  - 10.1016/j.jhazmat.2011.07.084
ER  - 
@article{
author = "Mojović, Zorica and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Banković, Predrag and Abu Rabi-Stanković, Andjela S. and Jovanović, Dušan M.",
year = "2011",
abstract = "The partial and complete substitution of cations in the interlayer region of clay with different amounts of hexadecyl trimethylammonium bromide (HDTMABr) was performed. The aim was to synthesize organo-bentonites to be used as constituents of porous electrodes for the electrooxidation of phenol. Domestic clay from Bogovina was subjected to a common procedure of the production of organo-bentonites. It included the following steps: grinding, sieving, Na-exchange, cation exchange and drying. The samples were characterized by X-ray diffraction (XRD) analysis, while the textural properties were evaluated by nitrogen physisorption. The multisweep cyclic voltammetry was applied to analyze the behavior of the clay modified glassy carbon electrode. The influences of the surfactant loading and pH of the support electrolyte were investigated. Rapid deactivation of electrodes occurred in an acidic environment, while good stability of the investigated electrodes was obtained in alkaline medium.",
publisher = "Elsevier",
journal = "Journal of Hazardous Materials",
title = "Phenol determination on HDTMA-bentonite-based electrodes",
volume = "194",
pages = "178-184",
doi = "10.1016/j.jhazmat.2011.07.084"
}
Mojović, Z., Jović-Jovičić, N., Milutinović Nikolić, A., Banković, P., Abu Rabi-Stanković, A. S.,& Jovanović, D. M.. (2011). Phenol determination on HDTMA-bentonite-based electrodes. in Journal of Hazardous Materials
Elsevier., 194, 178-184.
https://doi.org/10.1016/j.jhazmat.2011.07.084
Mojović Z, Jović-Jovičić N, Milutinović Nikolić A, Banković P, Abu Rabi-Stanković AS, Jovanović DM. Phenol determination on HDTMA-bentonite-based electrodes. in Journal of Hazardous Materials. 2011;194:178-184.
doi:10.1016/j.jhazmat.2011.07.084 .
Mojović, Zorica, Jović-Jovičić, Nataša, Milutinović Nikolić, Aleksandra, Banković, Predrag, Abu Rabi-Stanković, Andjela S., Jovanović, Dušan M., "Phenol determination on HDTMA-bentonite-based electrodes" in Journal of Hazardous Materials, 194 (2011):178-184,
https://doi.org/10.1016/j.jhazmat.2011.07.084 . .
34
25
32

Electrooxidation of phenol on different organo bentonite-based electrodes

Mojović, Zorica; Jović-Jovičić, Nataša; Banković, Predrag; Žunić, Marija; Abu Rabi-Stanković, Andjela S.; Milutinović Nikolić, Aleksandra; Jovanović, Dušan M.

(Elsevier, 2011)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Jović-Jovičić, Nataša
AU  - Banković, Predrag
AU  - Žunić, Marija
AU  - Abu Rabi-Stanković, Andjela S.
AU  - Milutinović Nikolić, Aleksandra
AU  - Jovanović, Dušan M.
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/840
AB  - Bentonite was modified by the exchange of inorganic cations with hexadecyl trimethylammonium, dodecyl trimethylammonium or tetramethylammonium cation. The obtained materials were characterized by physisorption of nitrogen and X-ray diffraction analysis. Multisweep cyclic voltammetry was applied to analyze phenol response on different organo bentonite-based electrodes. The aim of the investigation was to determine the influence of the type of modifying agent on the electrochemical performance of the investigated electrodes. All electrodes exhibited similar electrochemical behavior but with different intensities of the electrochemical response and Tafel slopes. The difference in Tafel slopes reflected different level of involvement of pores in the phenol electrooxidation.
PB  - Elsevier
T2  - Applied Clay Science
T1  - Electrooxidation of phenol on different organo bentonite-based electrodes
VL  - 53
IS  - 2
SP  - 331
EP  - 335
DO  - 10.1016/j.clay.2010.12.008
ER  - 
@article{
author = "Mojović, Zorica and Jović-Jovičić, Nataša and Banković, Predrag and Žunić, Marija and Abu Rabi-Stanković, Andjela S. and Milutinović Nikolić, Aleksandra and Jovanović, Dušan M.",
year = "2011",
abstract = "Bentonite was modified by the exchange of inorganic cations with hexadecyl trimethylammonium, dodecyl trimethylammonium or tetramethylammonium cation. The obtained materials were characterized by physisorption of nitrogen and X-ray diffraction analysis. Multisweep cyclic voltammetry was applied to analyze phenol response on different organo bentonite-based electrodes. The aim of the investigation was to determine the influence of the type of modifying agent on the electrochemical performance of the investigated electrodes. All electrodes exhibited similar electrochemical behavior but with different intensities of the electrochemical response and Tafel slopes. The difference in Tafel slopes reflected different level of involvement of pores in the phenol electrooxidation.",
publisher = "Elsevier",
journal = "Applied Clay Science",
title = "Electrooxidation of phenol on different organo bentonite-based electrodes",
volume = "53",
number = "2",
pages = "331-335",
doi = "10.1016/j.clay.2010.12.008"
}
Mojović, Z., Jović-Jovičić, N., Banković, P., Žunić, M., Abu Rabi-Stanković, A. S., Milutinović Nikolić, A.,& Jovanović, D. M.. (2011). Electrooxidation of phenol on different organo bentonite-based electrodes. in Applied Clay Science
Elsevier., 53(2), 331-335.
https://doi.org/10.1016/j.clay.2010.12.008
Mojović Z, Jović-Jovičić N, Banković P, Žunić M, Abu Rabi-Stanković AS, Milutinović Nikolić A, Jovanović DM. Electrooxidation of phenol on different organo bentonite-based electrodes. in Applied Clay Science. 2011;53(2):331-335.
doi:10.1016/j.clay.2010.12.008 .
Mojović, Zorica, Jović-Jovičić, Nataša, Banković, Predrag, Žunić, Marija, Abu Rabi-Stanković, Andjela S., Milutinović Nikolić, Aleksandra, Jovanović, Dušan M., "Electrooxidation of phenol on different organo bentonite-based electrodes" in Applied Clay Science, 53, no. 2 (2011):331-335,
https://doi.org/10.1016/j.clay.2010.12.008 . .
13
12
14

The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5

Adnađević, Borivoj K.; Mojović, Zorica; Abu Rabi, Andjela

(Springer, New York, 2008)

TY  - JOUR
AU  - Adnađević, Borivoj K.
AU  - Mojović, Zorica
AU  - Abu Rabi, Andjela
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/414
AB  - The kinetics of the isothermal adsorption of ethanol from an aqueous solution onto a hydrophobic zeolite of the NaZSM-5 type in the temperature range 298-333 K was investigated. Specific shape parameters of the adsorption degree curves were determined. The changes in the specific shape parameters of the adsorption degree curves with temperature were determined. The kinetic parameters of ethanol adsorption (E-a, ln A) were determined by the initial rate, the saturation rate and the maximum rate methods as well as from the Johnson, Mehl and Avramy equation. The kinetic model of ethanol adsorption kt=[1-(1-alpha)(1/3)] was determined by the "model fitting" method. Ethanol adsorption from aqueous solution onto NaZSM-5 is a kinetically controlled process limited by the rate of three-dimensional movement of the boundary layer of the adsorption phase. A model for the mechanism of ethanol adsorption onto NaZSM-5 is suggested on the basis of the kinetic model. Ethanol molecules in aqueous solution are associated in clusters. The activation energy of the adsorption process corresponds to the energy required for the detachment of an ethanol molecule from a cluster and its adsorption onto the zeolite.
PB  - Springer, New York
T2  - Adsorption-Journal of the International Adsorption Society
T1  - The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5
VL  - 14
IS  - 1
SP  - 123
EP  - 131
DO  - 10.1007/s10450-007-9077-6
ER  - 
@article{
author = "Adnađević, Borivoj K. and Mojović, Zorica and Abu Rabi, Andjela",
year = "2008",
abstract = "The kinetics of the isothermal adsorption of ethanol from an aqueous solution onto a hydrophobic zeolite of the NaZSM-5 type in the temperature range 298-333 K was investigated. Specific shape parameters of the adsorption degree curves were determined. The changes in the specific shape parameters of the adsorption degree curves with temperature were determined. The kinetic parameters of ethanol adsorption (E-a, ln A) were determined by the initial rate, the saturation rate and the maximum rate methods as well as from the Johnson, Mehl and Avramy equation. The kinetic model of ethanol adsorption kt=[1-(1-alpha)(1/3)] was determined by the "model fitting" method. Ethanol adsorption from aqueous solution onto NaZSM-5 is a kinetically controlled process limited by the rate of three-dimensional movement of the boundary layer of the adsorption phase. A model for the mechanism of ethanol adsorption onto NaZSM-5 is suggested on the basis of the kinetic model. Ethanol molecules in aqueous solution are associated in clusters. The activation energy of the adsorption process corresponds to the energy required for the detachment of an ethanol molecule from a cluster and its adsorption onto the zeolite.",
publisher = "Springer, New York",
journal = "Adsorption-Journal of the International Adsorption Society",
title = "The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5",
volume = "14",
number = "1",
pages = "123-131",
doi = "10.1007/s10450-007-9077-6"
}
Adnađević, B. K., Mojović, Z.,& Abu Rabi, A.. (2008). The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5. in Adsorption-Journal of the International Adsorption Society
Springer, New York., 14(1), 123-131.
https://doi.org/10.1007/s10450-007-9077-6
Adnađević BK, Mojović Z, Abu Rabi A. The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5. in Adsorption-Journal of the International Adsorption Society. 2008;14(1):123-131.
doi:10.1007/s10450-007-9077-6 .
Adnađević, Borivoj K., Mojović, Zorica, Abu Rabi, Andjela, "The kinetics of ethanol adsorption from the aqueous phase onto zeolite NaZSM-5" in Adsorption-Journal of the International Adsorption Society, 14, no. 1 (2008):123-131,
https://doi.org/10.1007/s10450-007-9077-6 . .
12
12
13

Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces

Jašin, Danijela M.; Abu Rabi, Anđela; Mentus, Slavko; Jovanović, Dušan M.

(Elsevier, 2007)

TY  - JOUR
AU  - Jašin, Danijela M.
AU  - Abu Rabi, Anđela
AU  - Mentus, Slavko
AU  - Jovanović, Dušan M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4253
AB  - From aqueous solutions, gold was deposited on freshly polished titanium surface either by displacement reaction or by potentiodynamic polarization. Both of these procedures resulted in the formation of Au/TiO2 composite layer over the titanium surface, although with quite different Au content. The electrochemical behaviour of these composite layers was examined in 0.1 M NaOH solution, both oxygen free and oxygen saturated, using rotating disc technique. In the potential region of oxygen reduction reaction, the Au/TiO2 layer obtained by potentiodynamic polarization, displayed the voltammetric curve similar to that observed on (1 0 0) plane of Au monocrystal. The Koutecky-Levich analysis evidenced that 4e- route of oxygen reduction dominates on both type of composite layers.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces
VL  - 52
IS  - 13
SP  - 4581
EP  - 4588
DO  - 10.1016/j.electacta.2006.12.071
ER  - 
@article{
author = "Jašin, Danijela M. and Abu Rabi, Anđela and Mentus, Slavko and Jovanović, Dušan M.",
year = "2007",
abstract = "From aqueous solutions, gold was deposited on freshly polished titanium surface either by displacement reaction or by potentiodynamic polarization. Both of these procedures resulted in the formation of Au/TiO2 composite layer over the titanium surface, although with quite different Au content. The electrochemical behaviour of these composite layers was examined in 0.1 M NaOH solution, both oxygen free and oxygen saturated, using rotating disc technique. In the potential region of oxygen reduction reaction, the Au/TiO2 layer obtained by potentiodynamic polarization, displayed the voltammetric curve similar to that observed on (1 0 0) plane of Au monocrystal. The Koutecky-Levich analysis evidenced that 4e- route of oxygen reduction dominates on both type of composite layers.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces",
volume = "52",
number = "13",
pages = "4581-4588",
doi = "10.1016/j.electacta.2006.12.071"
}
Jašin, D. M., Abu Rabi, A., Mentus, S.,& Jovanović, D. M.. (2007). Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces. in Electrochimica Acta
Elsevier., 52(13), 4581-4588.
https://doi.org/10.1016/j.electacta.2006.12.071
Jašin DM, Abu Rabi A, Mentus S, Jovanović DM. Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces. in Electrochimica Acta. 2007;52(13):4581-4588.
doi:10.1016/j.electacta.2006.12.071 .
Jašin, Danijela M., Abu Rabi, Anđela, Mentus, Slavko, Jovanović, Dušan M., "Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite surfaces" in Electrochimica Acta, 52, no. 13 (2007):4581-4588,
https://doi.org/10.1016/j.electacta.2006.12.071 . .
25
21
26

Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5

Adnađević, Borivoj; Mojović, Zorica; Abu Rabi, Anđela; Jovanović, Jelena D.

(Wiley-Blackwell, 2007)

TY  - JOUR
AU  - Adnađević, Borivoj
AU  - Mojović, Zorica
AU  - Abu Rabi, Anđela
AU  - Jovanović, Jelena D.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4261
AB  - The kinetic parameters of the selective isothermal adsorption of ethanol from an
aqueous solution onto a hydrophobic zeolite type NaZSM-5 were determined
using a series of the so-called standard methods (the initial rate, the saturation
rate and the maximum rate methods). The kinetic model of ethanol adsorption
was determined by the “model fitting” method. The dependence of the kinetic
parameters on the degree of adsorption and the presence of a compensation effect
were determined by the isoconversional method. The complex changes of the
activation energy and pre-exponential factor with the degree of adsorption were
explained by the model of the activation energy distribution of elemental adsorption
processes.
PB  - Wiley-Blackwell
T2  - Chemical Engineering and Technology
T1  - Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5
VL  - 30
IS  - 9
SP  - 1228
EP  - 1234
DO  - 10.1002/ceat.200700147
ER  - 
@article{
author = "Adnađević, Borivoj and Mojović, Zorica and Abu Rabi, Anđela and Jovanović, Jelena D.",
year = "2007",
abstract = "The kinetic parameters of the selective isothermal adsorption of ethanol from an
aqueous solution onto a hydrophobic zeolite type NaZSM-5 were determined
using a series of the so-called standard methods (the initial rate, the saturation
rate and the maximum rate methods). The kinetic model of ethanol adsorption
was determined by the “model fitting” method. The dependence of the kinetic
parameters on the degree of adsorption and the presence of a compensation effect
were determined by the isoconversional method. The complex changes of the
activation energy and pre-exponential factor with the degree of adsorption were
explained by the model of the activation energy distribution of elemental adsorption
processes.",
publisher = "Wiley-Blackwell",
journal = "Chemical Engineering and Technology",
title = "Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5",
volume = "30",
number = "9",
pages = "1228-1234",
doi = "10.1002/ceat.200700147"
}
Adnađević, B., Mojović, Z., Abu Rabi, A.,& Jovanović, J. D.. (2007). Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5. in Chemical Engineering and Technology
Wiley-Blackwell., 30(9), 1228-1234.
https://doi.org/10.1002/ceat.200700147
Adnađević B, Mojović Z, Abu Rabi A, Jovanović JD. Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5. in Chemical Engineering and Technology. 2007;30(9):1228-1234.
doi:10.1002/ceat.200700147 .
Adnađević, Borivoj, Mojović, Zorica, Abu Rabi, Anđela, Jovanović, Jelena D., "Isoconversional Kinetic Analysis of Isothermal Selective Ethanol Adsorption on Zeolite Type NaZSM-5" in Chemical Engineering and Technology, 30, no. 9 (2007):1228-1234,
https://doi.org/10.1002/ceat.200700147 . .
3
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The influence of acid treatment on the nanostructure and textural properties of bentonite clays

Vuković, Zorica; Milutinović Nikolić, Aleksandra; Krstić, Jugoslav; Abu Rabi, Andjela; Novaković, Tatjana; Jovanović, Dušan M.

(Trans Tech Publications Ltd, Durnten-Zurich, 2005)

TY  - JOUR
AU  - Vuković, Zorica
AU  - Milutinović Nikolić, Aleksandra
AU  - Krstić, Jugoslav
AU  - Abu Rabi, Andjela
AU  - Novaković, Tatjana
AU  - Jovanović, Dušan M.
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/174
AB  - The nanostructure and textural properties of acid-activated bentonite clays from the Bogovina coalmine were investigated. The acid activation was performed with HCl in the concentration range 1.5-7.5 M. The atomic force microscopy followed by image analysis was used in order to establish the influence of the acid treatment on the size of bentonite particles. Nitrogen adsorption-desorption isotherms at -196 degrees C were used to estimate the specific surface area, pore volume and pore size distribution. The acid treatment reduces the size of bentonite particles and increases the specific surface area and pore volume of the investigated bentonites. These effects are improved by increasing the acid concentration up to 4.5 M HCl Further increase in acid concentration does not result in development of new porous structure.
PB  - Trans Tech Publications Ltd, Durnten-Zurich
T2  - Current Research in Advanced Materials and Processes
T1  - The influence of acid treatment on the nanostructure and textural properties of bentonite clays
VL  - 494
SP  - 339
EP  - 344
DO  - 10.4028/www.scientific.net/MSF.494.339
ER  - 
@article{
author = "Vuković, Zorica and Milutinović Nikolić, Aleksandra and Krstić, Jugoslav and Abu Rabi, Andjela and Novaković, Tatjana and Jovanović, Dušan M.",
year = "2005",
abstract = "The nanostructure and textural properties of acid-activated bentonite clays from the Bogovina coalmine were investigated. The acid activation was performed with HCl in the concentration range 1.5-7.5 M. The atomic force microscopy followed by image analysis was used in order to establish the influence of the acid treatment on the size of bentonite particles. Nitrogen adsorption-desorption isotherms at -196 degrees C were used to estimate the specific surface area, pore volume and pore size distribution. The acid treatment reduces the size of bentonite particles and increases the specific surface area and pore volume of the investigated bentonites. These effects are improved by increasing the acid concentration up to 4.5 M HCl Further increase in acid concentration does not result in development of new porous structure.",
publisher = "Trans Tech Publications Ltd, Durnten-Zurich",
journal = "Current Research in Advanced Materials and Processes",
title = "The influence of acid treatment on the nanostructure and textural properties of bentonite clays",
volume = "494",
pages = "339-344",
doi = "10.4028/www.scientific.net/MSF.494.339"
}
Vuković, Z., Milutinović Nikolić, A., Krstić, J., Abu Rabi, A., Novaković, T.,& Jovanović, D. M.. (2005). The influence of acid treatment on the nanostructure and textural properties of bentonite clays. in Current Research in Advanced Materials and Processes
Trans Tech Publications Ltd, Durnten-Zurich., 494, 339-344.
https://doi.org/10.4028/www.scientific.net/MSF.494.339
Vuković Z, Milutinović Nikolić A, Krstić J, Abu Rabi A, Novaković T, Jovanović DM. The influence of acid treatment on the nanostructure and textural properties of bentonite clays. in Current Research in Advanced Materials and Processes. 2005;494:339-344.
doi:10.4028/www.scientific.net/MSF.494.339 .
Vuković, Zorica, Milutinović Nikolić, Aleksandra, Krstić, Jugoslav, Abu Rabi, Andjela, Novaković, Tatjana, Jovanović, Dušan M., "The influence of acid treatment on the nanostructure and textural properties of bentonite clays" in Current Research in Advanced Materials and Processes, 494 (2005):339-344,
https://doi.org/10.4028/www.scientific.net/MSF.494.339 . .
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