Petrović, Zoran

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Recycling of Oily Waste Packaging by Pyrolysis

Dugić, Pero; Petrović, Zoran; Pavlović, Stefan; Aleksić, Vojislav; Milovanović, Biljana

(Society for robotics of B&H - Društvo za robotiku u Bosni i Hercegovini, 2016)

TY  - CONF
AU  - Dugić, Pero
AU  - Petrović, Zoran
AU  - Pavlović, Stefan
AU  - Aleksić, Vojislav
AU  - Milovanović, Biljana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3830
AB  - For commercial packing of lubricants, the most commonly used are polyethylene packing which are different designs and volume. After emptying the contents, used packing ending up as waste material in municipal landfills, and in our environment by irresponsible behavior of users (roadside, forests and rivers). It is known the fact that the polyethylene packing materials and mineral oils are decomposed very slowly. The big problem is the fact that the bottles after emptying the contents, i.e. outflow of lubricants in the passenger vehicles and commercial vehicles, construction and agricultural equipment and chainsaws, drop behind a certain amount of lubricants, which further endanger the environment (particularly water and land), and thus the health of the population. In developed countries there is an organized management, almost of all aspects of polymer waste and used fuel. The collected amount of waste are used for the recovery of polymer materials, for energy, and a variety of chemical products (processes of pyrolysis and gasification). In our country has not established management of collection and disposal of waste yet. Number of passenger vehicles, trucks and other vehicles, as well as to agricultural mechanization are growing, and because of their age or condition of the engine, are increased consumption of motor oil and other liquid lubricants. This leads to the formation of large quantities of waste polyethylene packing in which drop behind a certain amount of lubricants. In this paper are described the results of investigation process of pyrolysis oily polyethylene waste in a laboratory reactor for the purpose of obtaining liquid hydrocarbons. The results of investigation can be used for process design for larger proportion, and the resulting products may have commercial applications. Therefore, this method for oily polyethylene waste has not only environmental, but also economic effect.
AB  - Za komercijalno pakovanje maziva, najčešće se koristi polietilenska ambalaža različitog dizajna i zapremine. Nakon pražnjenja sadržaja, korišćena ambalaža završava kao otpadni materijal na komunalnim deponijama, a često, neodgovornim odnosom korisnika, završava u našoj okolini (pored saobraćajnica, u šumama i rijekama). Poznata je činjenica da se polietilenski ambalažni materijal i mineralna ulja veoma sporo razgrađuju. Veliki problem predstavlja činjenica da u bocama nakon pražnjenja sadržaja, tj. izlivanja maziva u putničke i teretne automobile, građevinsku i poljoprivrednu mehanizaciju, te motorne pile, zaostaje određena količina maziva, čime se dodatno ugrožava životna sredina (naročito vode i zemljište), a time i zdravlje stanovništva. U razvijenim zemljama EU postoji organizovano upravljanje skoro svim vidovima polimernog otpada, kao i korištenim mazivima. Sakupljene količine otpada koriste se za ponovno dobijanje polimernih materijala, za dobijanje energije, te niza hemijskih proizvoda (procesima pirolize i gasifikacije). U našoj zemlji još nije uspostavljen organizovani način sakupljanja i konačnog zbrinjavanja ovog otpada. Broj putničkih automobila, teretnih i drugih vozila, kao i poljoprivrede mehanizacije je u porastu, a zbog njihove starosti, odnosno stanja motora, povećana je potrošnja motornih ulja i drugih teþnih maziva. To dovodi do nastajanja i veće količine otpadne polietilenske ambalaže u kojoj zaostaje određena količina maziva. U radu su opisani rezultati istraživanja procesa pirolize zauljenog polietilenskog otpada u laboratorijskom reaktoru, u svrhu dobijanja tečnih ugljovodonika. Rezultati istraživanja mogu poslužiti za projektovanje procesa veće razmjere, a dobijeni proizvodi mogu imati komercijalnu primjenu. Zbog toga, ovaj postupak zbrinjavanja zauljenog polietilenskog otpada ima ne samo ekološki, nego i ekonomski efekat.
PB  - Society for robotics of B&H - Društvo za robotiku u Bosni i Hercegovini
C3  - 3th International Conference New Technology, "NT-2016", 13.05-14.05.2016., Mostar, Bosnia and Herzegovina
T1  - Recycling of Oily Waste Packaging by Pyrolysis
T1  - Reciklaža zauljene otpadne ambalaže procesom pirolize
SP  - 32
EP  - 32
UR  - https://hdl.handle.net/21.15107/rcub_cer_3830
ER  - 
@conference{
author = "Dugić, Pero and Petrović, Zoran and Pavlović, Stefan and Aleksić, Vojislav and Milovanović, Biljana",
year = "2016",
abstract = "For commercial packing of lubricants, the most commonly used are polyethylene packing which are different designs and volume. After emptying the contents, used packing ending up as waste material in municipal landfills, and in our environment by irresponsible behavior of users (roadside, forests and rivers). It is known the fact that the polyethylene packing materials and mineral oils are decomposed very slowly. The big problem is the fact that the bottles after emptying the contents, i.e. outflow of lubricants in the passenger vehicles and commercial vehicles, construction and agricultural equipment and chainsaws, drop behind a certain amount of lubricants, which further endanger the environment (particularly water and land), and thus the health of the population. In developed countries there is an organized management, almost of all aspects of polymer waste and used fuel. The collected amount of waste are used for the recovery of polymer materials, for energy, and a variety of chemical products (processes of pyrolysis and gasification). In our country has not established management of collection and disposal of waste yet. Number of passenger vehicles, trucks and other vehicles, as well as to agricultural mechanization are growing, and because of their age or condition of the engine, are increased consumption of motor oil and other liquid lubricants. This leads to the formation of large quantities of waste polyethylene packing in which drop behind a certain amount of lubricants. In this paper are described the results of investigation process of pyrolysis oily polyethylene waste in a laboratory reactor for the purpose of obtaining liquid hydrocarbons. The results of investigation can be used for process design for larger proportion, and the resulting products may have commercial applications. Therefore, this method for oily polyethylene waste has not only environmental, but also economic effect., Za komercijalno pakovanje maziva, najčešće se koristi polietilenska ambalaža različitog dizajna i zapremine. Nakon pražnjenja sadržaja, korišćena ambalaža završava kao otpadni materijal na komunalnim deponijama, a često, neodgovornim odnosom korisnika, završava u našoj okolini (pored saobraćajnica, u šumama i rijekama). Poznata je činjenica da se polietilenski ambalažni materijal i mineralna ulja veoma sporo razgrađuju. Veliki problem predstavlja činjenica da u bocama nakon pražnjenja sadržaja, tj. izlivanja maziva u putničke i teretne automobile, građevinsku i poljoprivrednu mehanizaciju, te motorne pile, zaostaje određena količina maziva, čime se dodatno ugrožava životna sredina (naročito vode i zemljište), a time i zdravlje stanovništva. U razvijenim zemljama EU postoji organizovano upravljanje skoro svim vidovima polimernog otpada, kao i korištenim mazivima. Sakupljene količine otpada koriste se za ponovno dobijanje polimernih materijala, za dobijanje energije, te niza hemijskih proizvoda (procesima pirolize i gasifikacije). U našoj zemlji još nije uspostavljen organizovani način sakupljanja i konačnog zbrinjavanja ovog otpada. Broj putničkih automobila, teretnih i drugih vozila, kao i poljoprivrede mehanizacije je u porastu, a zbog njihove starosti, odnosno stanja motora, povećana je potrošnja motornih ulja i drugih teþnih maziva. To dovodi do nastajanja i veće količine otpadne polietilenske ambalaže u kojoj zaostaje određena količina maziva. U radu su opisani rezultati istraživanja procesa pirolize zauljenog polietilenskog otpada u laboratorijskom reaktoru, u svrhu dobijanja tečnih ugljovodonika. Rezultati istraživanja mogu poslužiti za projektovanje procesa veće razmjere, a dobijeni proizvodi mogu imati komercijalnu primjenu. Zbog toga, ovaj postupak zbrinjavanja zauljenog polietilenskog otpada ima ne samo ekološki, nego i ekonomski efekat.",
publisher = "Society for robotics of B&H - Društvo za robotiku u Bosni i Hercegovini",
journal = "3th International Conference New Technology, "NT-2016", 13.05-14.05.2016., Mostar, Bosnia and Herzegovina",
title = "Recycling of Oily Waste Packaging by Pyrolysis, Reciklaža zauljene otpadne ambalaže procesom pirolize",
pages = "32-32",
url = "https://hdl.handle.net/21.15107/rcub_cer_3830"
}
Dugić, P., Petrović, Z., Pavlović, S., Aleksić, V.,& Milovanović, B.. (2016). Recycling of Oily Waste Packaging by Pyrolysis. in 3th International Conference New Technology, "NT-2016", 13.05-14.05.2016., Mostar, Bosnia and Herzegovina
Society for robotics of B&H - Društvo za robotiku u Bosni i Hercegovini., 32-32.
https://hdl.handle.net/21.15107/rcub_cer_3830
Dugić P, Petrović Z, Pavlović S, Aleksić V, Milovanović B. Recycling of Oily Waste Packaging by Pyrolysis. in 3th International Conference New Technology, "NT-2016", 13.05-14.05.2016., Mostar, Bosnia and Herzegovina. 2016;:32-32.
https://hdl.handle.net/21.15107/rcub_cer_3830 .
Dugić, Pero, Petrović, Zoran, Pavlović, Stefan, Aleksić, Vojislav, Milovanović, Biljana, "Recycling of Oily Waste Packaging by Pyrolysis" in 3th International Conference New Technology, "NT-2016", 13.05-14.05.2016., Mostar, Bosnia and Herzegovina (2016):32-32,
https://hdl.handle.net/21.15107/rcub_cer_3830 .

Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils

Milovanović, Biljana; Petrović, Zoran; Dugić, Pero; Miljanović, Krsto

(Academy of Sciences and Arts of the Republic of Srpska, 2015)

TY  - CONF
AU  - Milovanović, Biljana
AU  - Petrović, Zoran
AU  - Dugić, Pero
AU  - Miljanović, Krsto
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3892
AB  - Conventional base oils are obtained separating undesirable compounds by physical processes, and their quality depends on the quality of petroleum. These oils have higher amount of aromatic hydrocarbons and sulfur compounds and have worse physico-chemical characteristics of base oils obtained with modern techniques. The final treatment of these oils can be made by hydrogen or active aluminosilicate clay. In this paper was investigated the effect modified bentonite by acid from the site Šipovo on content of aromatics and some physico-chemical characteristics (viscosity, index of viscosity, index of refractive, color, density and demulsibility) of sample on base oil. Contens of aromatics was determined by IR spectroskopy (IR) and UV spectrophotometry (UV). The results of investigation showed that there is a slight reduction in aromatic content and change of tested physico-chemical characteristics, and realized effects of processing tested oil by acid are similar effects processing by activated clay.
PB  - Academy of Sciences and Arts of the Republic of Srpska
C3  - Međunarodna konferencija "Savremeni materijali" 2015, Banja Luka
T1  - Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils
T1  - Uticaj modifikovanog betonita na sadržaj aromata i fizičko-hemijske karakteristike konvencionalnih biljnih ulja
SP  - 225
EP  - 235
UR  - https://hdl.handle.net/21.15107/rcub_cer_3892
ER  - 
@conference{
author = "Milovanović, Biljana and Petrović, Zoran and Dugić, Pero and Miljanović, Krsto",
year = "2015",
abstract = "Conventional base oils are obtained separating undesirable compounds by physical processes, and their quality depends on the quality of petroleum. These oils have higher amount of aromatic hydrocarbons and sulfur compounds and have worse physico-chemical characteristics of base oils obtained with modern techniques. The final treatment of these oils can be made by hydrogen or active aluminosilicate clay. In this paper was investigated the effect modified bentonite by acid from the site Šipovo on content of aromatics and some physico-chemical characteristics (viscosity, index of viscosity, index of refractive, color, density and demulsibility) of sample on base oil. Contens of aromatics was determined by IR spectroskopy (IR) and UV spectrophotometry (UV). The results of investigation showed that there is a slight reduction in aromatic content and change of tested physico-chemical characteristics, and realized effects of processing tested oil by acid are similar effects processing by activated clay.",
publisher = "Academy of Sciences and Arts of the Republic of Srpska",
journal = "Međunarodna konferencija "Savremeni materijali" 2015, Banja Luka",
title = "Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils, Uticaj modifikovanog betonita na sadržaj aromata i fizičko-hemijske karakteristike konvencionalnih biljnih ulja",
pages = "225-235",
url = "https://hdl.handle.net/21.15107/rcub_cer_3892"
}
Milovanović, B., Petrović, Z., Dugić, P.,& Miljanović, K.. (2015). Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils. in Međunarodna konferencija "Savremeni materijali" 2015, Banja Luka
Academy of Sciences and Arts of the Republic of Srpska., 225-235.
https://hdl.handle.net/21.15107/rcub_cer_3892
Milovanović B, Petrović Z, Dugić P, Miljanović K. Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils. in Međunarodna konferencija "Savremeni materijali" 2015, Banja Luka. 2015;:225-235.
https://hdl.handle.net/21.15107/rcub_cer_3892 .
Milovanović, Biljana, Petrović, Zoran, Dugić, Pero, Miljanović, Krsto, "Influence of modified bentonite on content of aromatics and physico-chemical characteristics of conventional base oils" in Međunarodna konferencija "Savremeni materijali" 2015, Banja Luka (2015):225-235,
https://hdl.handle.net/21.15107/rcub_cer_3892 .

Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom

Petrović, Zoran; Dugić, Pero; Aleksić, Vojislav; Begić, Sabina; Mićić, Vladan; Kljajić, Nevena; Milovanović, Biljana

(Academy of Sciences and Arts of the Republic of Srpska, 2014)

TY  - CONF
AU  - Petrović, Zoran
AU  - Dugić, Pero
AU  - Aleksić, Vojislav
AU  - Begić, Sabina
AU  - Mićić, Vladan
AU  - Kljajić, Nevena
AU  - Milovanović, Biljana
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3915
AB  - Solvent base oils of group API I contain larger quantities of aromatic compounds and sulfur, as compared to base oils of higher quality groups. Processing of base oils by commercial clays is performed in order to reduce the content of undesirable compounds, improving the color and oxidation stability. Commercial clays are based on aluminosilicates with a large specific surface area and developed porosity. Bentonite has good adsorption characteristics, which can be further improved by various methods of modification. In this paper, adsorption processing of solvent base oils is derived by acid-activated bentonite and commercial clay. The structural composition of starting oil and refined solvent oil (content of aromatics, paraffins, naphtenes and sulfur) is determined by following methods: IEC 590, UV, IP 346 and BAS ISO 20846. The results showed that processing of a solvent oil by activated bentonite leads to change of structural composition, similar to a change achived by processing with commercial clay.
PB  - Academy of Sciences and Arts of the Republic of Srpska
C3  - Međunarodna konferencija "Savremeni materijali" 2014, Banja Luka
T1  - Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom
T1  - Effect of Adsorption Processing of Solvent Base Oils by Activated Bentonite
SP  - 333
EP  - 344
UR  - https://hdl.handle.net/21.15107/rcub_cer_3915
ER  - 
@conference{
author = "Petrović, Zoran and Dugić, Pero and Aleksić, Vojislav and Begić, Sabina and Mićić, Vladan and Kljajić, Nevena and Milovanović, Biljana",
year = "2014",
abstract = "Solvent base oils of group API I contain larger quantities of aromatic compounds and sulfur, as compared to base oils of higher quality groups. Processing of base oils by commercial clays is performed in order to reduce the content of undesirable compounds, improving the color and oxidation stability. Commercial clays are based on aluminosilicates with a large specific surface area and developed porosity. Bentonite has good adsorption characteristics, which can be further improved by various methods of modification. In this paper, adsorption processing of solvent base oils is derived by acid-activated bentonite and commercial clay. The structural composition of starting oil and refined solvent oil (content of aromatics, paraffins, naphtenes and sulfur) is determined by following methods: IEC 590, UV, IP 346 and BAS ISO 20846. The results showed that processing of a solvent oil by activated bentonite leads to change of structural composition, similar to a change achived by processing with commercial clay.",
publisher = "Academy of Sciences and Arts of the Republic of Srpska",
journal = "Međunarodna konferencija "Savremeni materijali" 2014, Banja Luka",
title = "Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom, Effect of Adsorption Processing of Solvent Base Oils by Activated Bentonite",
pages = "333-344",
url = "https://hdl.handle.net/21.15107/rcub_cer_3915"
}
Petrović, Z., Dugić, P., Aleksić, V., Begić, S., Mićić, V., Kljajić, N.,& Milovanović, B.. (2014). Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom. in Međunarodna konferencija "Savremeni materijali" 2014, Banja Luka
Academy of Sciences and Arts of the Republic of Srpska., 333-344.
https://hdl.handle.net/21.15107/rcub_cer_3915
Petrović Z, Dugić P, Aleksić V, Begić S, Mićić V, Kljajić N, Milovanović B. Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom. in Međunarodna konferencija "Savremeni materijali" 2014, Banja Luka. 2014;:333-344.
https://hdl.handle.net/21.15107/rcub_cer_3915 .
Petrović, Zoran, Dugić, Pero, Aleksić, Vojislav, Begić, Sabina, Mićić, Vladan, Kljajić, Nevena, Milovanović, Biljana, "Efekti adsorpcione obrade solventnih baznih ulja aktiviranih bentonitom" in Međunarodna konferencija "Savremeni materijali" 2014, Banja Luka (2014):333-344,
https://hdl.handle.net/21.15107/rcub_cer_3915 .