Radonjić, Vojkan

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  • Radonjić, Vojkan (8)
  • Radonjić, Vojkan D. (1)
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Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma

Radonjić, Vojkan D.

(Универзитет у Београду, Факултет за физичку хемију, 2022)

TY  - THES
AU  - Radonjić, Vojkan D.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6259
AB  - U okviru ove doktorske disertacije ispitivana je mogućnost sinteze aktivnog niklenog  katalizatora modifikovanog magnezijumom u reakciji hidrogenizacije suncokretovog ulja,  upotrebom perlita kao nosača katalizatora. Da bi se ispitala moguća aktivacija odabranog perlitnog  nosača (PF-295), on je tretiran u destilovanoj vodi na 90 °C, u 10 % rastvoru Na2CO3 na 90 °C i u 9 mol/dm3 HCl-u uz refluks na 100 °C. Karakterizacijom nosača nisu uočene značajne razlike u  morfologiji, teksturi i strukturi dobijenih materijala. Za sintezu prekursora na različito tretiranim nosačima korišćen je precipitacionodepozicioni postupak, upotrebom čvrstog Na2CO3 kao taložnog agensa nikl (nNi:nSiO2 = 1) i  magnezijum (nMg:nNi = 0,1) vrsta. Rezultati karakterizacija prekursora su pokazali da među njima  ne postoje značajne razlike, osim u vrednostima disperznosti (određene hemisorpcijom H2). Takođe  su uočene manje razlike u aktivnosti sintetisanih katalizatora u katalitičkim testovima hidrogenizacije suncokretovog ulja. Upotrebom različitih molskih odnosa (nNi:nSiO2 i nMg:nNi) dobijene su dve serije prekursora  koje su okarakterisane morfološki, teksturalno i strukturno. Prekursori serije sa različitim sadržajem  Ni pokazali su razlike u rezultatima svih karakterizacionih tehnika, a ove razlike su bile još  izraženije kod serije sa različitim sadržajem Mg, naročito vrednosti disperznosti Ni0 . Primenom  različitih temperatura redukcije (270 °C, 300 °C, 330 °C, 360 °C i 460 °C) i određivanjem vrednosti  disperzije Ni0 redukovanih prekursora, utvrđen je optimalni molski odnos nNi:nSiO2 . Optimalna temperatura redukcije ovog prekursora (nNi:nSiO2 = 0,25) određena je na osnovu rezultata katalitičkih  testova parcijalne hidrogenizacije suncokretovog ulja. Na ovoj temperaturi (345 °C) su redukovani  svi prekursori i ispitani su u katalitičkim testovima, nakon čega je određivan sadržaj masnih kiselina parcijalno hidrogenizovanog suncokretovog ulja gasno-hromatografskom analizom. Utvrđeno je da  najveću aktivnost pokazuje katalizator sa molskim odnosom nNi:nSiO2 = 0,25 i nMg:nNi = 0,1. Ovim je  pokazano da je moguće sintetisati aktivni nikleni katalizator za hidrogenizaciju suncokretovog ulja  upotrebom perlita kao nosača i magnezijuma kao promotora.
AB  - Within the scope of this doctoral dissertation, the synthesis of a nickel catalyst modified  with magnesium on perlite as support for the process of hydrogenation of sunflower oil was  investigated. To examine the possible activation of the selected perlite support (PF-295), it was  treated in distilled water at 90 °C, in 10% solution of Na2CO3 at 90 °C and in 9 mol/dm3 HCl with  reflux at 100 °C. No significant differences in the morphology, texture or structure of the obtained  materials were observed. For precursor synthesis, precipitation-deposition method was used with solid Na2CO3 as a  precipitating agent of nickel (nNi:nSiO2 = 1) and magnesium (nMg:nNi = 0.1) species. Synthesis of  Ni2+ precursors on various supports, using Mg as a modifier, no significant differences in the  synthesized precursors were also shown, exept the differences observed in the dispersion values  (measured by chemisorption of H2). Minor differences in the activity of afterwards synthesized  catalysts were observed in catalytic tests of the hydrogenation of sunflower oil. Variation of the values of two synthesis parameters (nNi:nSiO2 and nMg:nNi) yielded a series of  precursors, later characterized by morphological, textural and structural techniques. For different Ni  contents, precursors showed an obvious difference in their characterization, while differences in  characterization, especially in Ni0 dispersion, were were more obvious for different Mg contents in  precursors. Measuring the dispersion of Ni0 at different temperatures (270 °C, 300 °C, 330 °C, 360  °C and 460 °C), the optimal molar ratio of nNi:nSiO2 was obtained. Optimal reduction temperature of  this precursor (nNi:nSiO2 = 0.25) was established by their catalytic activity in partial hydrogenation  of sunflower oil. At this temperature (345 °C), all precursors were reduced and tested in catalytic  hydrogenation of sunflower oil, after which fatty acid composition was determined by gas  chromatography. The catalyst with the molar ratio nNi:nSiO2 = 0.25 and nMg:nNi = 0.1 showed the  highest activity. With this it was shown that it is possible to synthesize an active nickel catalyst for  the hydrogenation of sunflower oil using perlite as support and magnesium as promotor.
PB  - Универзитет у Београду, Факултет за физичку хемију
T2  - Универзитет у Београду
T1  - Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma
UR  - https://hdl.handle.net/21.15107/rcub_cer_6259
ER  - 
@phdthesis{
author = "Radonjić, Vojkan D.",
year = "2022",
abstract = "U okviru ove doktorske disertacije ispitivana je mogućnost sinteze aktivnog niklenog  katalizatora modifikovanog magnezijumom u reakciji hidrogenizacije suncokretovog ulja,  upotrebom perlita kao nosača katalizatora. Da bi se ispitala moguća aktivacija odabranog perlitnog  nosača (PF-295), on je tretiran u destilovanoj vodi na 90 °C, u 10 % rastvoru Na2CO3 na 90 °C i u 9 mol/dm3 HCl-u uz refluks na 100 °C. Karakterizacijom nosača nisu uočene značajne razlike u  morfologiji, teksturi i strukturi dobijenih materijala. Za sintezu prekursora na različito tretiranim nosačima korišćen je precipitacionodepozicioni postupak, upotrebom čvrstog Na2CO3 kao taložnog agensa nikl (nNi:nSiO2 = 1) i  magnezijum (nMg:nNi = 0,1) vrsta. Rezultati karakterizacija prekursora su pokazali da među njima  ne postoje značajne razlike, osim u vrednostima disperznosti (određene hemisorpcijom H2). Takođe  su uočene manje razlike u aktivnosti sintetisanih katalizatora u katalitičkim testovima hidrogenizacije suncokretovog ulja. Upotrebom različitih molskih odnosa (nNi:nSiO2 i nMg:nNi) dobijene su dve serije prekursora  koje su okarakterisane morfološki, teksturalno i strukturno. Prekursori serije sa različitim sadržajem  Ni pokazali su razlike u rezultatima svih karakterizacionih tehnika, a ove razlike su bile još  izraženije kod serije sa različitim sadržajem Mg, naročito vrednosti disperznosti Ni0 . Primenom  različitih temperatura redukcije (270 °C, 300 °C, 330 °C, 360 °C i 460 °C) i određivanjem vrednosti  disperzije Ni0 redukovanih prekursora, utvrđen je optimalni molski odnos nNi:nSiO2 . Optimalna temperatura redukcije ovog prekursora (nNi:nSiO2 = 0,25) određena je na osnovu rezultata katalitičkih  testova parcijalne hidrogenizacije suncokretovog ulja. Na ovoj temperaturi (345 °C) su redukovani  svi prekursori i ispitani su u katalitičkim testovima, nakon čega je određivan sadržaj masnih kiselina parcijalno hidrogenizovanog suncokretovog ulja gasno-hromatografskom analizom. Utvrđeno je da  najveću aktivnost pokazuje katalizator sa molskim odnosom nNi:nSiO2 = 0,25 i nMg:nNi = 0,1. Ovim je  pokazano da je moguće sintetisati aktivni nikleni katalizator za hidrogenizaciju suncokretovog ulja  upotrebom perlita kao nosača i magnezijuma kao promotora., Within the scope of this doctoral dissertation, the synthesis of a nickel catalyst modified  with magnesium on perlite as support for the process of hydrogenation of sunflower oil was  investigated. To examine the possible activation of the selected perlite support (PF-295), it was  treated in distilled water at 90 °C, in 10% solution of Na2CO3 at 90 °C and in 9 mol/dm3 HCl with  reflux at 100 °C. No significant differences in the morphology, texture or structure of the obtained  materials were observed. For precursor synthesis, precipitation-deposition method was used with solid Na2CO3 as a  precipitating agent of nickel (nNi:nSiO2 = 1) and magnesium (nMg:nNi = 0.1) species. Synthesis of  Ni2+ precursors on various supports, using Mg as a modifier, no significant differences in the  synthesized precursors were also shown, exept the differences observed in the dispersion values  (measured by chemisorption of H2). Minor differences in the activity of afterwards synthesized  catalysts were observed in catalytic tests of the hydrogenation of sunflower oil. Variation of the values of two synthesis parameters (nNi:nSiO2 and nMg:nNi) yielded a series of  precursors, later characterized by morphological, textural and structural techniques. For different Ni  contents, precursors showed an obvious difference in their characterization, while differences in  characterization, especially in Ni0 dispersion, were were more obvious for different Mg contents in  precursors. Measuring the dispersion of Ni0 at different temperatures (270 °C, 300 °C, 330 °C, 360  °C and 460 °C), the optimal molar ratio of nNi:nSiO2 was obtained. Optimal reduction temperature of  this precursor (nNi:nSiO2 = 0.25) was established by their catalytic activity in partial hydrogenation  of sunflower oil. At this temperature (345 °C), all precursors were reduced and tested in catalytic  hydrogenation of sunflower oil, after which fatty acid composition was determined by gas  chromatography. The catalyst with the molar ratio nNi:nSiO2 = 0.25 and nMg:nNi = 0.1 showed the  highest activity. With this it was shown that it is possible to synthesize an active nickel catalyst for  the hydrogenation of sunflower oil using perlite as support and magnesium as promotor.",
publisher = "Универзитет у Београду, Факултет за физичку хемију",
journal = "Универзитет у Београду",
title = "Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma",
url = "https://hdl.handle.net/21.15107/rcub_cer_6259"
}
Radonjić, V. D.. (2022). Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma. in Универзитет у Београду
Универзитет у Београду, Факултет за физичку хемију..
https://hdl.handle.net/21.15107/rcub_cer_6259
Radonjić VD. Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma. in Универзитет у Београду. 2022;.
https://hdl.handle.net/21.15107/rcub_cer_6259 .
Radonjić, Vojkan D., "Karakteristike niklenog katalizatora na perlitu sintetisanog pri različitim molskim odnosima nikla i magnezijuma" in Универзитет у Београду (2022),
https://hdl.handle.net/21.15107/rcub_cer_6259 .

Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni

Radonjić, Vojkan; Krstić, Jugoslav; Lončarević, Davor; Vukelić, Nikola; Jovanović, Dušan M.

(Belgrade : Association of the Chemical Engineers of Serbia AChE, 2019)

TY  - JOUR
AU  - Radonjić, Vojkan
AU  - Krstić, Jugoslav
AU  - Lončarević, Davor
AU  - Vukelić, Nikola
AU  - Jovanović, Dušan M.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3222
AB  - Use of broken honeycomb-like expanded perlite as support for magnesium modified nickel catalysts in process of partial hydrogenation of sunflower oil was studied. By the use of the precipitation-deposition method, two groups of precursors were synthesized: different Ni/SiO2 mole ratios with constant Mg/Ni mole ratio 0.1, and different Mg/Ni mole ratios with constant Ni/SiO2 mole ratio 0.25. Characterizations of precursors were done (scanning electron microscopy, diffuse reflectance UV–Vis, infrared spectroscopy, N2-physisorption, temperature programmed reduction (TPR) and He-pycnometry) to determine the material differences, considering the change in morphology, structure, texture and reducibility with overall Ni and Mg content. In addition, TPR and hydrogen chemisorption were performed in order to estimate the temperature reduction range of supported precursors and the dispersion degree of nickel in reduced precursors, respectively. The interaction between Ni2+ and perlite support was established. Different reducibility and dispersion were obtained as a function of Ni/SiO2 and Mg/Ni mole ratios. After the precursor’s reduction and paraffin oil impregnation, the obtained catalysts were tested in a sunflower oil hydrogenation reaction. Catalyst activity was monitored through the decrease of the refractive index and hydrogen consumption that gave the insight that the influence on catalyst activity represents the accessibility of triacylglycerols and not always the hydrogen determined dispersion degree
AB  - Proučavana je moguća upotreba ekspantiranog perlita, oblika lomljenog pčelinjeg saća,
kao nosača magnezijum modifikovanog niklenog katalizatora u procesu parcijalne hidrogenizacije suncokretovog ulja. Primenom precipitaciono-depozicione metode, sintetisane su dve grupe prekursora: različitog molskog odnosa Ni/SiO2 sa konstantnim Mg/Ni
molskim odnosom 0,1 i različitog Mg/Ni molskog odnosa sa konstantnim Ni/SiO2 molskim odnosom 0,25. Izvršena je karakterizacija prekursora (skenirajuća elektronska
mikroskopija, difuziona refleksiona ULj-Vid, infracrvena spektroskopija, N2-fizisorpcija,
temperaturski programirana redukcija - TPR i He-piknometrija) u cilju utvrđivanja razlika
u materijalu, uzimajući u obzir promene u morfologiji, strukturi, teksturi i reducibilnosti
ukupnog sadržaja Ni i Mg. Dodatno, TPR i hemisorpcija vodonika urađene su u cilju
procene opsega temperature redukcije prekursora i stepena disperzije nikla u redukovanim prekursorima. Utvrđeno je postojanje interakcija između Ni
2+ i perlitnog nosača, a
dokazana je za različite reducibilnosti i disperznosti kao funkcija Ni/SiO2 i Mg/Ni molskog odnosa. Nakon redukcije prekursora i impregnacije parafinskim uljem, dobijeni
katalizatori su testirani u reakciji hidrogenizacije suncokretovog ulja. Katalitička aktivnost je praćena padom indeksa refrakcije i potrošnjom vodonika. Utvrđeno je da na
katalitičku aktivnost dominantan uticaj ima dostupnost aktivnih Ni0 centara molekulima
triacilglicerola, a ne njihov stepen disperzije utvrđen vodonikom.
PB  - Belgrade : Association of the Chemical Engineers of Serbia AChE
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni
T1  - Mg-Ni supported on perlite as hydrogenation catalyst: Influence of Mg and Ni content
VL  - 25
IS  - 2
SP  - 193
EP  - 206
DO  - 10.2298/CICEQ181001032R
ER  - 
@article{
author = "Radonjić, Vojkan and Krstić, Jugoslav and Lončarević, Davor and Vukelić, Nikola and Jovanović, Dušan M.",
year = "2019",
abstract = "Use of broken honeycomb-like expanded perlite as support for magnesium modified nickel catalysts in process of partial hydrogenation of sunflower oil was studied. By the use of the precipitation-deposition method, two groups of precursors were synthesized: different Ni/SiO2 mole ratios with constant Mg/Ni mole ratio 0.1, and different Mg/Ni mole ratios with constant Ni/SiO2 mole ratio 0.25. Characterizations of precursors were done (scanning electron microscopy, diffuse reflectance UV–Vis, infrared spectroscopy, N2-physisorption, temperature programmed reduction (TPR) and He-pycnometry) to determine the material differences, considering the change in morphology, structure, texture and reducibility with overall Ni and Mg content. In addition, TPR and hydrogen chemisorption were performed in order to estimate the temperature reduction range of supported precursors and the dispersion degree of nickel in reduced precursors, respectively. The interaction between Ni2+ and perlite support was established. Different reducibility and dispersion were obtained as a function of Ni/SiO2 and Mg/Ni mole ratios. After the precursor’s reduction and paraffin oil impregnation, the obtained catalysts were tested in a sunflower oil hydrogenation reaction. Catalyst activity was monitored through the decrease of the refractive index and hydrogen consumption that gave the insight that the influence on catalyst activity represents the accessibility of triacylglycerols and not always the hydrogen determined dispersion degree, Proučavana je moguća upotreba ekspantiranog perlita, oblika lomljenog pčelinjeg saća,
kao nosača magnezijum modifikovanog niklenog katalizatora u procesu parcijalne hidrogenizacije suncokretovog ulja. Primenom precipitaciono-depozicione metode, sintetisane su dve grupe prekursora: različitog molskog odnosa Ni/SiO2 sa konstantnim Mg/Ni
molskim odnosom 0,1 i različitog Mg/Ni molskog odnosa sa konstantnim Ni/SiO2 molskim odnosom 0,25. Izvršena je karakterizacija prekursora (skenirajuća elektronska
mikroskopija, difuziona refleksiona ULj-Vid, infracrvena spektroskopija, N2-fizisorpcija,
temperaturski programirana redukcija - TPR i He-piknometrija) u cilju utvrđivanja razlika
u materijalu, uzimajući u obzir promene u morfologiji, strukturi, teksturi i reducibilnosti
ukupnog sadržaja Ni i Mg. Dodatno, TPR i hemisorpcija vodonika urađene su u cilju
procene opsega temperature redukcije prekursora i stepena disperzije nikla u redukovanim prekursorima. Utvrđeno je postojanje interakcija između Ni
2+ i perlitnog nosača, a
dokazana je za različite reducibilnosti i disperznosti kao funkcija Ni/SiO2 i Mg/Ni molskog odnosa. Nakon redukcije prekursora i impregnacije parafinskim uljem, dobijeni
katalizatori su testirani u reakciji hidrogenizacije suncokretovog ulja. Katalitička aktivnost je praćena padom indeksa refrakcije i potrošnjom vodonika. Utvrđeno je da na
katalitičku aktivnost dominantan uticaj ima dostupnost aktivnih Ni0 centara molekulima
triacilglicerola, a ne njihov stepen disperzije utvrđen vodonikom.",
publisher = "Belgrade : Association of the Chemical Engineers of Serbia AChE",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni, Mg-Ni supported on perlite as hydrogenation catalyst: Influence of Mg and Ni content",
volume = "25",
number = "2",
pages = "193-206",
doi = "10.2298/CICEQ181001032R"
}
Radonjić, V., Krstić, J., Lončarević, D., Vukelić, N.,& Jovanović, D. M.. (2019). Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni. in Chemical Industry & Chemical Engineering Quarterly
Belgrade : Association of the Chemical Engineers of Serbia AChE., 25(2), 193-206.
https://doi.org/10.2298/CICEQ181001032R
Radonjić V, Krstić J, Lončarević D, Vukelić N, Jovanović DM. Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni. in Chemical Industry & Chemical Engineering Quarterly. 2019;25(2):193-206.
doi:10.2298/CICEQ181001032R .
Radonjić, Vojkan, Krstić, Jugoslav, Lončarević, Davor, Vukelić, Nikola, Jovanović, Dušan M., "Mg-Ni na perlitnom nosaču kao hidrogenizacioni katalizator: uticaj sadržaja Mg i Ni" in Chemical Industry & Chemical Engineering Quarterly, 25, no. 2 (2019):193-206,
https://doi.org/10.2298/CICEQ181001032R . .
3
3

Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant

Gabrovska, Margarita; Nikolova, Dimitrinka; Krstić, Jugoslav; Lončarević, Davor; Tzvetkov, P.T.; Shopska, M.G.; Radonjić, Vojkan; Stanković, Miroslav; Jovanović, D.M.; Spasov, L.Т.; Simeonov, D.B.

(Bulgarian Academy of Sciences, 2018)

TY  - JOUR
AU  - Gabrovska, Margarita
AU  - Nikolova, Dimitrinka
AU  - Krstić, Jugoslav
AU  - Lončarević, Davor
AU  - Tzvetkov, P.T.
AU  - Shopska, M.G.
AU  - Radonjić, Vojkan
AU  - Stanković, Miroslav
AU  - Jovanović, D.M.
AU  - Spasov, L.Т.
AU  - Simeonov, D.B.
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2390
AB  - Mg-doped co-precipitated Ni/SIG precursors were studied as edible sunflower oil hydrogenation catalysts applying two types of commercial silica gels (SIG) as supports of different texture characteristics: a microporous type (SIG-A) and a mesoporous type (SIG-C). It was found that texture parameters of both the silica gels and magnesium addition allow obtaining of catalysts of various hydrogenation activities and fatty acid composition of the products. The results reveal the highest hydrogenation activity of MgNi/SIG-C catalyst because of higher amount and accessibility of metal nickel particles on the catalyst surface generated through reduction procedure. A dominant activity of MgNi/SIG-C catalyst is ascribed to appropriate mesoporosity, which controls diffusion. It was established that Mg-doped Ni/SIG-C possessed a capacity for use as an efficient edible vegetable oil hydrogenation catalyst due to high hydrogenation activity, high saturation level of linoleic acid (C18:2cis), moderate amounts of C18:1trans fatty acids, and C18:0 stearin acid formation in the partially hydrogenated sunflower oil.
PB  - Bulgarian Academy of Sciences
T2  - Bulgarian Chemical Communications
T1  - Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant
VL  - 50
SP  - 161
EP  - 168
UR  - https://hdl.handle.net/21.15107/rcub_cer_2390
ER  - 
@article{
author = "Gabrovska, Margarita and Nikolova, Dimitrinka and Krstić, Jugoslav and Lončarević, Davor and Tzvetkov, P.T. and Shopska, M.G. and Radonjić, Vojkan and Stanković, Miroslav and Jovanović, D.M. and Spasov, L.Т. and Simeonov, D.B.",
year = "2018",
abstract = "Mg-doped co-precipitated Ni/SIG precursors were studied as edible sunflower oil hydrogenation catalysts applying two types of commercial silica gels (SIG) as supports of different texture characteristics: a microporous type (SIG-A) and a mesoporous type (SIG-C). It was found that texture parameters of both the silica gels and magnesium addition allow obtaining of catalysts of various hydrogenation activities and fatty acid composition of the products. The results reveal the highest hydrogenation activity of MgNi/SIG-C catalyst because of higher amount and accessibility of metal nickel particles on the catalyst surface generated through reduction procedure. A dominant activity of MgNi/SIG-C catalyst is ascribed to appropriate mesoporosity, which controls diffusion. It was established that Mg-doped Ni/SIG-C possessed a capacity for use as an efficient edible vegetable oil hydrogenation catalyst due to high hydrogenation activity, high saturation level of linoleic acid (C18:2cis), moderate amounts of C18:1trans fatty acids, and C18:0 stearin acid formation in the partially hydrogenated sunflower oil.",
publisher = "Bulgarian Academy of Sciences",
journal = "Bulgarian Chemical Communications",
title = "Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant",
volume = "50",
pages = "161-168",
url = "https://hdl.handle.net/21.15107/rcub_cer_2390"
}
Gabrovska, M., Nikolova, D., Krstić, J., Lončarević, D., Tzvetkov, P.T., Shopska, M.G., Radonjić, V., Stanković, M., Jovanović, D.M., Spasov, L.Т.,& Simeonov, D.B.. (2018). Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant. in Bulgarian Chemical Communications
Bulgarian Academy of Sciences., 50, 161-168.
https://hdl.handle.net/21.15107/rcub_cer_2390
Gabrovska M, Nikolova D, Krstić J, Lončarević D, Tzvetkov P, Shopska M, Radonjić V, Stanković M, Jovanović D, Spasov L, Simeonov D. Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant. in Bulgarian Chemical Communications. 2018;50:161-168.
https://hdl.handle.net/21.15107/rcub_cer_2390 .
Gabrovska, Margarita, Nikolova, Dimitrinka, Krstić, Jugoslav, Lončarević, Davor, Tzvetkov, P.T., Shopska, M.G., Radonjić, Vojkan, Stanković, Miroslav, Jovanović, D.M., Spasov, L.Т., Simeonov, D.B., "Improved catalyst performance of Ni/SiO2 in vegetable oil hydrogenation: Impact of Mg dopant" in Bulgarian Chemical Communications, 50 (2018):161-168,
https://hdl.handle.net/21.15107/rcub_cer_2390 .

Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition

Stanković, Miroslav; Krstić, Jugoslav; Radonjić, Vojkan; Lončarević, Davor; Gabrovska, Margarita; Nikolova, Dimitrinka; Pavlović, Stefan

(Belgrade : Society of Physical Chemists of Serbia, 2016)

TY  - CONF
AU  - Stanković, Miroslav
AU  - Krstić, Jugoslav
AU  - Radonjić, Vojkan
AU  - Lončarević, Davor
AU  - Gabrovska, Margarita
AU  - Nikolova, Dimitrinka
AU  - Pavlović, Stefan
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3817
AB  - Diatomite supported Ni-Mg catalyst precursors (Ni-Mg/D) with a constant Ni/Mg ratio, prepared by the precipitation-deposition method using different nickel salts, sulfamate, nitrate, chloride, acetate or formate, were studied by hydrogen chemisorptions and temperature programmed reduction (H2- TPR).The results showed that the dispersion of nickel and the reducibility of the prepared catalyst precursors were different depending upon the counter ion of the nickel salt. Among the studied nickel salts, the best results for the dispersion of metallic Ni and reducibility of Ni-Mg/D catalyst precursors were achieved using nickel sulfamate salt.
PB  - Belgrade :  Society of Physical Chemists of Serbia
C3  - Physical Chemistry 2016 (Proceedings) - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade
T1  - Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition
VL  - 1
SP  - 223
EP  - 226
UR  - https://hdl.handle.net/21.15107/rcub_cer_3817
ER  - 
@conference{
author = "Stanković, Miroslav and Krstić, Jugoslav and Radonjić, Vojkan and Lončarević, Davor and Gabrovska, Margarita and Nikolova, Dimitrinka and Pavlović, Stefan",
year = "2016",
abstract = "Diatomite supported Ni-Mg catalyst precursors (Ni-Mg/D) with a constant Ni/Mg ratio, prepared by the precipitation-deposition method using different nickel salts, sulfamate, nitrate, chloride, acetate or formate, were studied by hydrogen chemisorptions and temperature programmed reduction (H2- TPR).The results showed that the dispersion of nickel and the reducibility of the prepared catalyst precursors were different depending upon the counter ion of the nickel salt. Among the studied nickel salts, the best results for the dispersion of metallic Ni and reducibility of Ni-Mg/D catalyst precursors were achieved using nickel sulfamate salt.",
publisher = "Belgrade :  Society of Physical Chemists of Serbia",
journal = "Physical Chemistry 2016 (Proceedings) - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade",
title = "Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition",
volume = "1",
pages = "223-226",
url = "https://hdl.handle.net/21.15107/rcub_cer_3817"
}
Stanković, M., Krstić, J., Radonjić, V., Lončarević, D., Gabrovska, M., Nikolova, D.,& Pavlović, S.. (2016). Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition. in Physical Chemistry 2016 (Proceedings) - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade
Belgrade :  Society of Physical Chemists of Serbia., 1, 223-226.
https://hdl.handle.net/21.15107/rcub_cer_3817
Stanković M, Krstić J, Radonjić V, Lončarević D, Gabrovska M, Nikolova D, Pavlović S. Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition. in Physical Chemistry 2016 (Proceedings) - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade. 2016;1:223-226.
https://hdl.handle.net/21.15107/rcub_cer_3817 .
Stanković, Miroslav, Krstić, Jugoslav, Radonjić, Vojkan, Lončarević, Davor, Gabrovska, Margarita, Nikolova, Dimitrinka, Pavlović, Stefan, "Effect of Nickel Salts on the Dispersion of Nickel and Reducibility of Supported Ni-Mg Catalyst Precursors Prepared by Precipitation-Deposition" in Physical Chemistry 2016 (Proceedings) - 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Belgrade, 1 (2016):223-226,
https://hdl.handle.net/21.15107/rcub_cer_3817 .

Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst

Lončarević, Davor; Dostanić, Jasmina; Radonjić, Vojkan; Živković, Ljiljana S.; Jovanović, Dušan M.

(Springer Netherlands, 2016)

TY  - JOUR
AU  - Lončarević, Davor
AU  - Dostanić, Jasmina
AU  - Radonjić, Vojkan
AU  - Živković, Ljiljana S.
AU  - Jovanović, Dušan M.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2016
AB  - The simultaneous photocatalytic degradation of two dyes: methylene blue (MB), a cationic dye, and arylazo pyridone dye (SD), an anionic dye was investigated using sol-gel prepared TiO2 particles. The paper shows the main difference in degradation kinetics between single dye solution and binary dye solutions. The effects of competitive adsorption and the concentration of the dyes on degradation rate were analyzed. The preferential adsorption capacity of TiO2 toward MB was attributed to electrostatic interactions between the cationic dye and negatively charged TiO2 surface, while repulsion between the negatively charged surface of the catalyst and SD dye results in its lower adsorption capacity. The TiO2 surface charge and accordingly adsorption affinity of investigated dyes were found to be the main factors affecting degradation rate of the dyes. In the single dye system, the catalyst showed considerably higher degradation activity toward MB than to SD. In binary dye systems, the presence of SD did not affect the degradation of MB. On the other hand, the degradation efficiency of SD was found to be highly influenced by initial MB concentration and absorption ability of MB. In addition, higher MB concentration induces the production of a higher amount of reaction products, which also determine the SD degradation rate. Three kinetic regimes for the photodegradation of SD in binary mixtures were observed, used as a starting point to elucidate most influencing parameters for SD reaction kinetics.
PB  - Springer Netherlands
T2  - Reaction Kinetics, Mechanisms and Catalysis
T1  - Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst
VL  - 118
IS  - 1
SP  - 153
EP  - 164
DO  - 10.1007/s11144-016-0990-0
ER  - 
@article{
author = "Lončarević, Davor and Dostanić, Jasmina and Radonjić, Vojkan and Živković, Ljiljana S. and Jovanović, Dušan M.",
year = "2016",
abstract = "The simultaneous photocatalytic degradation of two dyes: methylene blue (MB), a cationic dye, and arylazo pyridone dye (SD), an anionic dye was investigated using sol-gel prepared TiO2 particles. The paper shows the main difference in degradation kinetics between single dye solution and binary dye solutions. The effects of competitive adsorption and the concentration of the dyes on degradation rate were analyzed. The preferential adsorption capacity of TiO2 toward MB was attributed to electrostatic interactions between the cationic dye and negatively charged TiO2 surface, while repulsion between the negatively charged surface of the catalyst and SD dye results in its lower adsorption capacity. The TiO2 surface charge and accordingly adsorption affinity of investigated dyes were found to be the main factors affecting degradation rate of the dyes. In the single dye system, the catalyst showed considerably higher degradation activity toward MB than to SD. In binary dye systems, the presence of SD did not affect the degradation of MB. On the other hand, the degradation efficiency of SD was found to be highly influenced by initial MB concentration and absorption ability of MB. In addition, higher MB concentration induces the production of a higher amount of reaction products, which also determine the SD degradation rate. Three kinetic regimes for the photodegradation of SD in binary mixtures were observed, used as a starting point to elucidate most influencing parameters for SD reaction kinetics.",
publisher = "Springer Netherlands",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
title = "Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst",
volume = "118",
number = "1",
pages = "153-164",
doi = "10.1007/s11144-016-0990-0"
}
Lončarević, D., Dostanić, J., Radonjić, V., Živković, L. S.,& Jovanović, D. M.. (2016). Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst. in Reaction Kinetics, Mechanisms and Catalysis
Springer Netherlands., 118(1), 153-164.
https://doi.org/10.1007/s11144-016-0990-0
Lončarević D, Dostanić J, Radonjić V, Živković LS, Jovanović DM. Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst. in Reaction Kinetics, Mechanisms and Catalysis. 2016;118(1):153-164.
doi:10.1007/s11144-016-0990-0 .
Lončarević, Davor, Dostanić, Jasmina, Radonjić, Vojkan, Živković, Ljiljana S., Jovanović, Dušan M., "Simultaneous photodegradation of two textile dyes using TiO2 as a catalyst" in Reaction Kinetics, Mechanisms and Catalysis, 118, no. 1 (2016):153-164,
https://doi.org/10.1007/s11144-016-0990-0 . .
19
14
19

Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants

Lončarević, Davor; Dostanić, Jasmina; Radonjić, Vojkan; Radosavljevic-Mihajlovic, A; Jovanović, Dušan M.

(Elsevier, 2015)

TY  - JOUR
AU  - Lončarević, Davor
AU  - Dostanić, Jasmina
AU  - Radonjić, Vojkan
AU  - Radosavljevic-Mihajlovic, A
AU  - Jovanović, Dušan M.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1700
AB  - This study aims to gain insights in structure-activity relationship of TiO2 photocatalysts. For this purpose photocatalysts were synthesized via classical sol-gel method using titanium isopropoxide as a precursor and polyethylene glycols (PEGs) of different molecular mass (M-n = 200, 600, 2000, 10,000) as a template agents. Incorporating PEG into TiO2 network enhanced not only catalyst porous structure, but also increased the fraction of anatase phase. The use of low-molecular-weight PEGs resulted in catalysts with increased anatase content and enlarged specific surface area. The catalyst photoactivity was estimated through degradation of organic pollutants: Reactive Black 5, arylazo pyridone dye and phenol. The results revealed that the photoactivity was following the same order independently of target pollutant: TiO2/P600 > TiO2/P200 > TiO2/P2000 > TiO2/P10000 > TiO2. BET surface area and anatase fraction, rather than pore diameter or pore volume, were found to be predominant catalyst property determining the activity for particular reaction system. The existence of synergistic effect between anatase and rutile phases was confirmed for the most active catalysts TiO2/P200 and TiO2/P600. These catalysts showed similar activity in dye degradation, while TiO2/P200 displayed significantly lower activity in phenol degradation, which was attributed to its lower sorption capacity and lower UV light utilization. The difference in the reactivity between investigated pollutants was discussed in relationship with their size, structure and sorption ability.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants
VL  - 26
IS  - 4
SP  - 1162
EP  - 1170
DO  - 10.1016/j.apt.2015.05.012
ER  - 
@article{
author = "Lončarević, Davor and Dostanić, Jasmina and Radonjić, Vojkan and Radosavljevic-Mihajlovic, A and Jovanović, Dušan M.",
year = "2015",
abstract = "This study aims to gain insights in structure-activity relationship of TiO2 photocatalysts. For this purpose photocatalysts were synthesized via classical sol-gel method using titanium isopropoxide as a precursor and polyethylene glycols (PEGs) of different molecular mass (M-n = 200, 600, 2000, 10,000) as a template agents. Incorporating PEG into TiO2 network enhanced not only catalyst porous structure, but also increased the fraction of anatase phase. The use of low-molecular-weight PEGs resulted in catalysts with increased anatase content and enlarged specific surface area. The catalyst photoactivity was estimated through degradation of organic pollutants: Reactive Black 5, arylazo pyridone dye and phenol. The results revealed that the photoactivity was following the same order independently of target pollutant: TiO2/P600 > TiO2/P200 > TiO2/P2000 > TiO2/P10000 > TiO2. BET surface area and anatase fraction, rather than pore diameter or pore volume, were found to be predominant catalyst property determining the activity for particular reaction system. The existence of synergistic effect between anatase and rutile phases was confirmed for the most active catalysts TiO2/P200 and TiO2/P600. These catalysts showed similar activity in dye degradation, while TiO2/P200 displayed significantly lower activity in phenol degradation, which was attributed to its lower sorption capacity and lower UV light utilization. The difference in the reactivity between investigated pollutants was discussed in relationship with their size, structure and sorption ability.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants",
volume = "26",
number = "4",
pages = "1162-1170",
doi = "10.1016/j.apt.2015.05.012"
}
Lončarević, D., Dostanić, J., Radonjić, V., Radosavljevic-Mihajlovic, A.,& Jovanović, D. M.. (2015). Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants. in Advanced Powder Technology
Elsevier., 26(4), 1162-1170.
https://doi.org/10.1016/j.apt.2015.05.012
Lončarević D, Dostanić J, Radonjić V, Radosavljevic-Mihajlovic A, Jovanović DM. Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants. in Advanced Powder Technology. 2015;26(4):1162-1170.
doi:10.1016/j.apt.2015.05.012 .
Lončarević, Davor, Dostanić, Jasmina, Radonjić, Vojkan, Radosavljevic-Mihajlovic, A, Jovanović, Dušan M., "Structure-activity relationship of nanosized porous PEG-modified TiO2 powders in degradation of organic pollutants" in Advanced Powder Technology, 26, no. 4 (2015):1162-1170,
https://doi.org/10.1016/j.apt.2015.05.012 . .
7
6
9

Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation

Krstić, Jugoslav; Gabrovska, Margarita; Lončarević, Davor; Nikolova, Dimitrinka; Radonjić, Vojkan; Vukelić, Nikola; Jovanović, Dušan M.

(Inst Chemical Engineers, Rugby, 2015)

TY  - JOUR
AU  - Krstić, Jugoslav
AU  - Gabrovska, Margarita
AU  - Lončarević, Davor
AU  - Nikolova, Dimitrinka
AU  - Radonjić, Vojkan
AU  - Vukelić, Nikola
AU  - Jovanović, Dušan M.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1708
AB  - Sunflower oil hydrogenation process was studied on silica supported nickel catalysts. Three texturally different silica gel materials were used as supports for synthesis of Ni/SiO2 catalyst precursors. After precursors' reduction and paraffin oil impregnation, obtained catalysts were used in sunflower oil hydrogenation reaction. For catalytic test, a new type of catalyst feeder was constructed and presented. The hydrogenation activity of catalysts was monitored through the decrease of refractive index and hydrogen consumption. A correlation between iodine value, refractive index and hydrogen consumption was established. The reaction rate constants were obtained from fatty acid composition of partially hydrogenated oil and further studied for the investigation of possible reaction pathways. Kinetics and mechanisms were evaluated and tested with the aim to reduce the number of reactions participating in the reaction scheme. A set of ordinary differential equations, corresponding to the investigated model, was solved numerically by Gear's algorithm. It was shown that a number of significant reactions in a model depend on the activity of catalysts. More active catalyst results in more reaction pathways and more side chemical reactions.
PB  - Inst Chemical Engineers, Rugby
T2  - Chemical Engineering Research & Design
T1  - Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation
VL  - 100
SP  - 72
EP  - 80
DO  - 10.1016/j.cherd.2015.05.001
ER  - 
@article{
author = "Krstić, Jugoslav and Gabrovska, Margarita and Lončarević, Davor and Nikolova, Dimitrinka and Radonjić, Vojkan and Vukelić, Nikola and Jovanović, Dušan M.",
year = "2015",
abstract = "Sunflower oil hydrogenation process was studied on silica supported nickel catalysts. Three texturally different silica gel materials were used as supports for synthesis of Ni/SiO2 catalyst precursors. After precursors' reduction and paraffin oil impregnation, obtained catalysts were used in sunflower oil hydrogenation reaction. For catalytic test, a new type of catalyst feeder was constructed and presented. The hydrogenation activity of catalysts was monitored through the decrease of refractive index and hydrogen consumption. A correlation between iodine value, refractive index and hydrogen consumption was established. The reaction rate constants were obtained from fatty acid composition of partially hydrogenated oil and further studied for the investigation of possible reaction pathways. Kinetics and mechanisms were evaluated and tested with the aim to reduce the number of reactions participating in the reaction scheme. A set of ordinary differential equations, corresponding to the investigated model, was solved numerically by Gear's algorithm. It was shown that a number of significant reactions in a model depend on the activity of catalysts. More active catalyst results in more reaction pathways and more side chemical reactions.",
publisher = "Inst Chemical Engineers, Rugby",
journal = "Chemical Engineering Research & Design",
title = "Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation",
volume = "100",
pages = "72-80",
doi = "10.1016/j.cherd.2015.05.001"
}
Krstić, J., Gabrovska, M., Lončarević, D., Nikolova, D., Radonjić, V., Vukelić, N.,& Jovanović, D. M.. (2015). Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation. in Chemical Engineering Research & Design
Inst Chemical Engineers, Rugby., 100, 72-80.
https://doi.org/10.1016/j.cherd.2015.05.001
Krstić J, Gabrovska M, Lončarević D, Nikolova D, Radonjić V, Vukelić N, Jovanović DM. Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation. in Chemical Engineering Research & Design. 2015;100:72-80.
doi:10.1016/j.cherd.2015.05.001 .
Krstić, Jugoslav, Gabrovska, Margarita, Lončarević, Davor, Nikolova, Dimitrinka, Radonjić, Vojkan, Vukelić, Nikola, Jovanović, Dušan M., "Influence of Ni/SiO2 activity on the reaction pathway in sunflower oil hydrogenation" in Chemical Engineering Research & Design, 100 (2015):72-80,
https://doi.org/10.1016/j.cherd.2015.05.001 . .
6
6
8

Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation

Radonjić, Vojkan; Krstić, Jugoslav; Lončarević, Davor; Jovanović, Dušan M.; Vukelić, Nikola; Stanković, Miroslav; Nikolova, Dimitrinka; Gabrovska, Margarita

(Maik Nauka/Interperiodica/Springer, New York, 2015)

TY  - JOUR
AU  - Radonjić, Vojkan
AU  - Krstić, Jugoslav
AU  - Lončarević, Davor
AU  - Jovanović, Dušan M.
AU  - Vukelić, Nikola
AU  - Stanković, Miroslav
AU  - Nikolova, Dimitrinka
AU  - Gabrovska, Margarita
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1825
AB  - Investigation was conducted in order to elucidate the possibility of using perlite as support for preparation of nickel based precursor catalyst, potentially applicable in vegetable oil hydrogenation process. On three differently prepared expanded perlite, nickel catalyst precursors with identical Ni/SiO2 = 1.1 and Ni/Mg = 10/1 ratios were synthesized by precipitation-deposition method. Different techniques, SEM micrography, He-pycnometry, calcimetry, Hg-porosimetry, N-2-physisorption, H-2-chemisorption and temperature programmed reduction, were used for characterization of obtained samples. Determining the precursor texture, morphology and reducibility shows a successfully deposited nickel phase on perlite support with promising properties for vegetable oil hydrogenation. Chosen precursor was reduced and passivated in paraffin oil and the obtained catalyst showed significant catalytic activity in the test of sunflower oil hydrogenation.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation
VL  - 89
IS  - 13
SP  - 2359
EP  - 2366
DO  - 10.1134/S0036024415130294
ER  - 
@article{
author = "Radonjić, Vojkan and Krstić, Jugoslav and Lončarević, Davor and Jovanović, Dušan M. and Vukelić, Nikola and Stanković, Miroslav and Nikolova, Dimitrinka and Gabrovska, Margarita",
year = "2015",
abstract = "Investigation was conducted in order to elucidate the possibility of using perlite as support for preparation of nickel based precursor catalyst, potentially applicable in vegetable oil hydrogenation process. On three differently prepared expanded perlite, nickel catalyst precursors with identical Ni/SiO2 = 1.1 and Ni/Mg = 10/1 ratios were synthesized by precipitation-deposition method. Different techniques, SEM micrography, He-pycnometry, calcimetry, Hg-porosimetry, N-2-physisorption, H-2-chemisorption and temperature programmed reduction, were used for characterization of obtained samples. Determining the precursor texture, morphology and reducibility shows a successfully deposited nickel phase on perlite support with promising properties for vegetable oil hydrogenation. Chosen precursor was reduced and passivated in paraffin oil and the obtained catalyst showed significant catalytic activity in the test of sunflower oil hydrogenation.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation",
volume = "89",
number = "13",
pages = "2359-2366",
doi = "10.1134/S0036024415130294"
}
Radonjić, V., Krstić, J., Lončarević, D., Jovanović, D. M., Vukelić, N., Stanković, M., Nikolova, D.,& Gabrovska, M.. (2015). Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 89(13), 2359-2366.
https://doi.org/10.1134/S0036024415130294
Radonjić V, Krstić J, Lončarević D, Jovanović DM, Vukelić N, Stanković M, Nikolova D, Gabrovska M. Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation. in Russian Journal of Physical Chemistry A. 2015;89(13):2359-2366.
doi:10.1134/S0036024415130294 .
Radonjić, Vojkan, Krstić, Jugoslav, Lončarević, Davor, Jovanović, Dušan M., Vukelić, Nikola, Stanković, Miroslav, Nikolova, Dimitrinka, Gabrovska, Margarita, "Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation" in Russian Journal of Physical Chemistry A, 89, no. 13 (2015):2359-2366,
https://doi.org/10.1134/S0036024415130294 . .
4
5
5

Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics

Stanković, Miroslav; Radonjić, Vojkan; Krstić, Jugoslav; Marinković, Dalibor

(Society of Physical Chemists of Serbia, 2014)

TY  - CONF
AU  - Stanković, Miroslav
AU  - Radonjić, Vojkan
AU  - Krstić, Jugoslav
AU  - Marinković, Dalibor
PY  - 2014
UR  - http://www.socphyschemserb.org/en/events/pc2014/
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2916
AB  - Diatomite supported nickel catalyst precursors (Ni/D) were prepared by the precipitation-deposition (PD) method using different nickel salts such as nitrate, chloride, acetate and formate. The effect of counter ions (NO3-, Cl-, CH3COO-, and HCOO-) on the texture of prepared samples was studied. For determination of the textural characteristics mercury intrusion porosimetry (MIP) and N2 physisorption techniques were used. MIP and physisorption data (pore volume, pore size distribution, porosity as well as N2 adsorptiondesorption isotherms and BET surface area) showed that counter ions were found to have a profound effect on the microstructure and porosity characteristics of Ni/D precursors. An order of the counter ions effect on the textural characteristics of prepared precursors was determined.
PB  - Society of Physical Chemists of Serbia
C3  - Physical Chemistry 2014 - 12th International Conference on fundamental and applied aspects of Physical chemistry
T1  - Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics
VL  - 1
SP  - 284
EP  - 287
UR  - https://hdl.handle.net/21.15107/rcub_cer_2916
ER  - 
@conference{
author = "Stanković, Miroslav and Radonjić, Vojkan and Krstić, Jugoslav and Marinković, Dalibor",
year = "2014",
abstract = "Diatomite supported nickel catalyst precursors (Ni/D) were prepared by the precipitation-deposition (PD) method using different nickel salts such as nitrate, chloride, acetate and formate. The effect of counter ions (NO3-, Cl-, CH3COO-, and HCOO-) on the texture of prepared samples was studied. For determination of the textural characteristics mercury intrusion porosimetry (MIP) and N2 physisorption techniques were used. MIP and physisorption data (pore volume, pore size distribution, porosity as well as N2 adsorptiondesorption isotherms and BET surface area) showed that counter ions were found to have a profound effect on the microstructure and porosity characteristics of Ni/D precursors. An order of the counter ions effect on the textural characteristics of prepared precursors was determined.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical Chemistry 2014 - 12th International Conference on fundamental and applied aspects of Physical chemistry",
title = "Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics",
volume = "1",
pages = "284-287",
url = "https://hdl.handle.net/21.15107/rcub_cer_2916"
}
Stanković, M., Radonjić, V., Krstić, J.,& Marinković, D.. (2014). Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics. in Physical Chemistry 2014 - 12th International Conference on fundamental and applied aspects of Physical chemistry
Society of Physical Chemists of Serbia., 1, 284-287.
https://hdl.handle.net/21.15107/rcub_cer_2916
Stanković M, Radonjić V, Krstić J, Marinković D. Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics. in Physical Chemistry 2014 - 12th International Conference on fundamental and applied aspects of Physical chemistry. 2014;1:284-287.
https://hdl.handle.net/21.15107/rcub_cer_2916 .
Stanković, Miroslav, Radonjić, Vojkan, Krstić, Jugoslav, Marinković, Dalibor, "Preparation of Ni/diatomite hydrogenation catalyst precursors: Effect of counter ions on textural characteristics" in Physical Chemistry 2014 - 12th International Conference on fundamental and applied aspects of Physical chemistry, 1 (2014):284-287,
https://hdl.handle.net/21.15107/rcub_cer_2916 .