TY  - JOUR
AU  - Jambrec, Daliborka
AU  - Gvozdenović, Milica M.
AU  - Antov, Mirjana
AU  - Grgur, Branimir N.
AU  - Jokić, Bojan
AU  - Stevanović, Jasmina
AU  - Jugović, Branimir
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/975
AB  - Electrochemical deposition of polyaniline (PANI) on graphite electrode was performed galvanostaticaly at constant current density in the range of 1.0 - 5.0 mA cm(-2) from aqueous acidic electrolyte containing aniline monomer. Based on ratio of doping/dedoping charge capacities, it was estimated that current density of 2.0 mA cm(-2) was optimal. The structure of the electrochemically synthesized PANI was fibrous, uniform and three dimensional with highly developed surface. Immobilization of glucose oxidise (GOx) was achieved by cross linking via glutaraldehyde and the efficiency of the immobilization was determined spectrophotometrically. Chronoamperometric curves were recorded at different glucose concentrations and used to estimate the apparent Michaelis constant, which was shown to be 0.27 mM. The storage stability of the PANI enzyme electrode was also estimated.
PB  - Inst Materials Physics, Bucharest
T2  - Digest Journal of Nanomaterials and Biostructures
T1  - Electrochemically deposited nano fibrous polyanilne for amperometric determination of glucose
VL  - 7
IS  - 2
SP  - 785
EP  - 794
UR  - https://hdl.handle.net/21.15107/rcub_dais_469
ER  - 

@article{
author = "Jambrec, Daliborka and Gvozdenović, Milica M. and Antov, Mirjana and Grgur, Branimir N. and Jokić, Bojan and Stevanović, Jasmina and Jugović, Branimir",
year = "2012",
abstract = "Electrochemical deposition of polyaniline (PANI) on graphite electrode was performed galvanostaticaly at constant current density in the range of 1.0 - 5.0 mA cm(-2) from aqueous acidic electrolyte containing aniline monomer. Based on ratio of doping/dedoping charge capacities, it was estimated that current density of 2.0 mA cm(-2) was optimal. The structure of the electrochemically synthesized PANI was fibrous, uniform and three dimensional with highly developed surface. Immobilization of glucose oxidise (GOx) was achieved by cross linking via glutaraldehyde and the efficiency of the immobilization was determined spectrophotometrically. Chronoamperometric curves were recorded at different glucose concentrations and used to estimate the apparent Michaelis constant, which was shown to be 0.27 mM. The storage stability of the PANI enzyme electrode was also estimated.",
publisher = "Inst Materials Physics, Bucharest",
journal = "Digest Journal of Nanomaterials and Biostructures",
title = "Electrochemically deposited nano fibrous polyanilne for amperometric determination of glucose",
volume = "7",
number = "2",
pages = "785-794",
url = "https://hdl.handle.net/21.15107/rcub_dais_469"
}

Jambrec, D., Gvozdenović, M. M., Antov, M., Grgur, B. N., Jokić, B., Stevanović, J.,& Jugović, B.. (2012). Electrochemically deposited nano fibrous polyanilne for amperometric determination of glucose. in Digest Journal of Nanomaterials and Biostructures
Inst Materials Physics, Bucharest., 7(2), 785-794.
https://hdl.handle.net/21.15107/rcub_dais_469

Jambrec D, Gvozdenović MM, Antov M, Grgur BN, Jokić B, Stevanović J, Jugović B. Electrochemically deposited nano fibrous polyanilne for amperometric determination of glucose. in Digest Journal of Nanomaterials and Biostructures. 2012;7(2):785-794.
https://hdl.handle.net/21.15107/rcub_dais_469 .

Jambrec, Daliborka, Gvozdenović, Milica M., Antov, Mirjana, Grgur, Branimir N., Jokić, Bojan, Stevanović, Jasmina, Jugović, Branimir, "Electrochemically deposited nano fibrous polyanilne for amperometric determination of glucose" in Digest Journal of Nanomaterials and Biostructures, 7, no. 2 (2012):785-794,
https://hdl.handle.net/21.15107/rcub_dais_469 .

TY  - JOUR
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jambrec, Daliborka
AU  - Stevanović, Jasmina
AU  - Grgur, Branimir N.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1081
AB  - Polyaniline is probably the most investigated electroconducting polymer. This popularity is a result of its important features: existence of various oxidation states, electrical and optical activity, low cost monomer, red/ox reversibility, environmental stability, ease of both chemical and electrochemical synthesis etc. These unique features are partly inherited from its polymeric origin and partly aroused from its conductivity and could be considered for practical application in: electrochemical systems for energy storage and conversion, electronic devices, electromagnetic and microwave shielding materials, sensors, biosensors and corrosion protection as well. The motivation of application of polyaniline in corrosion protection of metals and alloys is replacement of environmentally hazardous materials, e.g. chromates in coating systems. Up to day, lot of studies on various metals both on iron, steels and non-ferrous metals and alloys were performed. The studies involve investigation on individual polyaniline coatings and polyaniline in coating systems. Owing to variation in experimental procedure (substrate, substrate preparation, coating type, corrosion environment, test method etc..) it is unlikely to propose unique mechanism for corrosion protection of metals in the presence of polyaniline. However, most of the literature is interpreted in terms of general mechanisms of corrosion protection, barrier and anodic protection.
AB  - Polianilin je najproučavaniji elektroprovodni polimer. Ova popularnost polianilina je posledica jedinstvenih svojstava, delom nasleđenih od polimerne prirode, a delom ostvarenih provodljivošću. Najvažnija svojstva polianilina: postojanje više oksidacionih stanja, elektronska provodljivost, optička aktivnost, postojanost u spoljašnjoj sredini, mogućnost hemijske i elektrohemisjke sinteze i niska cena monomera nalaze primenu u mnogim oblstima: elektrohemisjkim sistemima za skladištenje i proizvodnju električne energije, elektronici, za izradu sensorskhih i biosenzorskih elektroda, za izradu antistatičkih i materijala mikrotalasnih i magnetnih štitova i u zaštiti metala i legura od korozije. Primena polianilina u zaštiti od korozije je prvenstveno motivisana potrebom zamene toksičnih materijala iz sistema prevlaka. Postoji dosta literaturnih podataka iz ove oblasti. Ipak, imajući u vidu raznovrsnost metala i legura, korozionih sredina, postupaka pripreme materijala, nanošenja prevlaka i vrsta prevlaka, kao i eksperimentalnih procedura i observacija, praktično je nemoguće uspostaviti jedinstven mehanizam antikorozione zaštite metala u prisustvu polianilina. Najcitiraniji i najpopularniji mehanizmi koji se mogu naći u literaturi obuhvataju barijerni mehanizam i mehanizam anodne zaštite.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - Application of polyaniline in corrosion protection of metals
T1  - Primena polianilina u zaštiti metala od korozije
VL  - 53
IS  - 4
SP  - 353
EP  - 360
UR  - https://hdl.handle.net/21.15107/rcub_cer_1081
ER  - 

@article{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jambrec, Daliborka and Stevanović, Jasmina and Grgur, Branimir N.",
year = "2012",
abstract = "Polyaniline is probably the most investigated electroconducting polymer. This popularity is a result of its important features: existence of various oxidation states, electrical and optical activity, low cost monomer, red/ox reversibility, environmental stability, ease of both chemical and electrochemical synthesis etc. These unique features are partly inherited from its polymeric origin and partly aroused from its conductivity and could be considered for practical application in: electrochemical systems for energy storage and conversion, electronic devices, electromagnetic and microwave shielding materials, sensors, biosensors and corrosion protection as well. The motivation of application of polyaniline in corrosion protection of metals and alloys is replacement of environmentally hazardous materials, e.g. chromates in coating systems. Up to day, lot of studies on various metals both on iron, steels and non-ferrous metals and alloys were performed. The studies involve investigation on individual polyaniline coatings and polyaniline in coating systems. Owing to variation in experimental procedure (substrate, substrate preparation, coating type, corrosion environment, test method etc..) it is unlikely to propose unique mechanism for corrosion protection of metals in the presence of polyaniline. However, most of the literature is interpreted in terms of general mechanisms of corrosion protection, barrier and anodic protection., Polianilin je najproučavaniji elektroprovodni polimer. Ova popularnost polianilina je posledica jedinstvenih svojstava, delom nasleđenih od polimerne prirode, a delom ostvarenih provodljivošću. Najvažnija svojstva polianilina: postojanje više oksidacionih stanja, elektronska provodljivost, optička aktivnost, postojanost u spoljašnjoj sredini, mogućnost hemijske i elektrohemisjke sinteze i niska cena monomera nalaze primenu u mnogim oblstima: elektrohemisjkim sistemima za skladištenje i proizvodnju električne energije, elektronici, za izradu sensorskhih i biosenzorskih elektroda, za izradu antistatičkih i materijala mikrotalasnih i magnetnih štitova i u zaštiti metala i legura od korozije. Primena polianilina u zaštiti od korozije je prvenstveno motivisana potrebom zamene toksičnih materijala iz sistema prevlaka. Postoji dosta literaturnih podataka iz ove oblasti. Ipak, imajući u vidu raznovrsnost metala i legura, korozionih sredina, postupaka pripreme materijala, nanošenja prevlaka i vrsta prevlaka, kao i eksperimentalnih procedura i observacija, praktično je nemoguće uspostaviti jedinstven mehanizam antikorozione zaštite metala u prisustvu polianilina. Najcitiraniji i najpopularniji mehanizmi koji se mogu naći u literaturi obuhvataju barijerni mehanizam i mehanizam anodne zaštite.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "Application of polyaniline in corrosion protection of metals, Primena polianilina u zaštiti metala od korozije",
volume = "53",
number = "4",
pages = "353-360",
url = "https://hdl.handle.net/21.15107/rcub_cer_1081"
}

Gvozdenović, M. M., Jugović, B., Jambrec, D., Stevanović, J.,& Grgur, B. N.. (2012). Application of polyaniline in corrosion protection of metals. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 53(4), 353-360.
https://hdl.handle.net/21.15107/rcub_cer_1081

Gvozdenović MM, Jugović B, Jambrec D, Stevanović J, Grgur BN. Application of polyaniline in corrosion protection of metals. in Zaštita materijala. 2012;53(4):353-360.
https://hdl.handle.net/21.15107/rcub_cer_1081 .

Gvozdenović, Milica M., Jugović, Branimir, Jambrec, Daliborka, Stevanović, Jasmina, Grgur, Branimir N., "Application of polyaniline in corrosion protection of metals" in Zaštita materijala, 53, no. 4 (2012):353-360,
https://hdl.handle.net/21.15107/rcub_cer_1081 .

TY  - CONF
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jambrec, Daliborka
AU  - Grgur, Branimir N.
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/492
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2597
AB  - Polyaniline (PANI) was electrochemically synthesized on graphite electrode galvanostaticaly from aqueous solution of 0.25 mol dm-3 aniline and 0.5 mol dm-3 p-toluenesulfonic acid. Charge capacity available for the exchange and the total theoretical weight of polyaniline polymerized on graphite electrode was determined. Characterization polianiline electrode was performed by cyclic voltametry in 0.5 mol dm-3 HCl. Based on the PANI electrodes behavior during the cyclization, was tested the possibility of practical application of polyaniline doped p-toluenesulfonic acid as the anode material of secondary electrochemical power sources.
PB  - Tatranské Matliare : Slovak Society of Chemical Engineering
C3  - Proceedings of the 39th International Conference of Slovak Society of Chemical Engineering
T1  - The influence of current density on charge/discharge characteristics of polyaniline electrode
SP  - 1467
EP  - 1471
UR  - https://hdl.handle.net/21.15107/rcub_dais_492
ER  - 

@conference{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jambrec, Daliborka and Grgur, Branimir N. and Trišović, Tomislav and Stevanović, Jasmina",
year = "2012",
abstract = "Polyaniline (PANI) was electrochemically synthesized on graphite electrode galvanostaticaly from aqueous solution of 0.25 mol dm-3 aniline and 0.5 mol dm-3 p-toluenesulfonic acid. Charge capacity available for the exchange and the total theoretical weight of polyaniline polymerized on graphite electrode was determined. Characterization polianiline electrode was performed by cyclic voltametry in 0.5 mol dm-3 HCl. Based on the PANI electrodes behavior during the cyclization, was tested the possibility of practical application of polyaniline doped p-toluenesulfonic acid as the anode material of secondary electrochemical power sources.",
publisher = "Tatranské Matliare : Slovak Society of Chemical Engineering",
journal = "Proceedings of the 39th International Conference of Slovak Society of Chemical Engineering",
title = "The influence of current density on charge/discharge characteristics of polyaniline electrode",
pages = "1467-1471",
url = "https://hdl.handle.net/21.15107/rcub_dais_492"
}

Gvozdenović, M. M., Jugović, B., Jambrec, D., Grgur, B. N., Trišović, T.,& Stevanović, J.. (2012). The influence of current density on charge/discharge characteristics of polyaniline electrode. in Proceedings of the 39th International Conference of Slovak Society of Chemical Engineering
Tatranské Matliare : Slovak Society of Chemical Engineering., 1467-1471.
https://hdl.handle.net/21.15107/rcub_dais_492

Gvozdenović MM, Jugović B, Jambrec D, Grgur BN, Trišović T, Stevanović J. The influence of current density on charge/discharge characteristics of polyaniline electrode. in Proceedings of the 39th International Conference of Slovak Society of Chemical Engineering. 2012;:1467-1471.
https://hdl.handle.net/21.15107/rcub_dais_492 .

Gvozdenović, Milica M., Jugović, Branimir, Jambrec, Daliborka, Grgur, Branimir N., Trišović, Tomislav, Stevanović, Jasmina, "The influence of current density on charge/discharge characteristics of polyaniline electrode" in Proceedings of the 39th International Conference of Slovak Society of Chemical Engineering (2012):1467-1471,
https://hdl.handle.net/21.15107/rcub_dais_492 .

TY  - CONF
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jambrec, Daliborka
AU  - Grgur, Branimir N.
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/141
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3150
AB  - Poster presented at the 39th International Conference of Slovak Society of Chemical Engineering, Tatranske Matliare, Slovakia, May 21–25, 2012
T1  - The influence of current density on charge/discharge characteristics of polyaniline electrode
UR  - https://hdl.handle.net/21.15107/rcub_dais_492
ER  - 

@conference{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jambrec, Daliborka and Grgur, Branimir N. and Trišović, Tomislav and Stevanović, Jasmina",
year = "2012",
abstract = "Poster presented at the 39th International Conference of Slovak Society of Chemical Engineering, Tatranske Matliare, Slovakia, May 21–25, 2012",
title = "The influence of current density on charge/discharge characteristics of polyaniline electrode",
url = "https://hdl.handle.net/21.15107/rcub_dais_492"
}

Gvozdenović, M. M., Jugović, B., Jambrec, D., Grgur, B. N., Trišović, T.,& Stevanović, J.. (2012). The influence of current density on charge/discharge characteristics of polyaniline electrode. .
https://hdl.handle.net/21.15107/rcub_dais_492

Gvozdenović MM, Jugović B, Jambrec D, Grgur BN, Trišović T, Stevanović J. The influence of current density on charge/discharge characteristics of polyaniline electrode. 2012;.
https://hdl.handle.net/21.15107/rcub_dais_492 .

Gvozdenović, Milica M., Jugović, Branimir, Jambrec, Daliborka, Grgur, Branimir N., Trišović, Tomislav, Stevanović, Jasmina, "The influence of current density on charge/discharge characteristics of polyaniline electrode" (2012),
https://hdl.handle.net/21.15107/rcub_dais_492 .