TY  - JOUR
AU  - Stevanović, Jasmina
AU  - Skibina, LJ.
AU  - Stefanović, M.
AU  - Despić, Aleksandar
AU  - Jović, Vladimir D.
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6832
AB  - Anodic linear-sweep voltammetry (ALSV) was applied to electrodeposited alloy layers and to metallurgically obtained Cu−Zn alloys of different composition and structure. Metallurgically obtained samples covered the range of composition in which α, (α+β), β and (β+γ) intermediate phases were detected by X-ray. The ALSV of samples containing less than 30 wt % Zn exhibited a single peak at −0.08 to −0.1 V/SCE before massive dissolution, starting at about −0.05 V/SCE. The presence of the γ-phase gave another peak at a significantly more negative potential (−0.25 to −0.35 V/SCE). The ALSV of electrodeposited alloys were significantly more complex than the former, depending on the deposition potentials, with peaks attributable to pure Zn, to the ε-phase, to the η-phase as well as to the α-phase, present in most cases and dissolving at potentials similar to that of pure Cu. ALSV was shown to be a reliable and practical method for a fast determination of both the composition and the phase structure of electrodeposited brass.
PB  - Springer
T2  - Journal of Applied Electrochemistry
T1  - Phase-structure analysis of brass by anodic linear-sweep voltammetry
VL  - 22
IS  - 2
SP  - 172
EP  - 178
DO  - 10.1007/BF01023820
ER  - 

@article{
author = "Stevanović, Jasmina and Skibina, LJ. and Stefanović, M. and Despić, Aleksandar and Jović, Vladimir D.",
year = "1992",
abstract = "Anodic linear-sweep voltammetry (ALSV) was applied to electrodeposited alloy layers and to metallurgically obtained Cu−Zn alloys of different composition and structure. Metallurgically obtained samples covered the range of composition in which α, (α+β), β and (β+γ) intermediate phases were detected by X-ray. The ALSV of samples containing less than 30 wt % Zn exhibited a single peak at −0.08 to −0.1 V/SCE before massive dissolution, starting at about −0.05 V/SCE. The presence of the γ-phase gave another peak at a significantly more negative potential (−0.25 to −0.35 V/SCE). The ALSV of electrodeposited alloys were significantly more complex than the former, depending on the deposition potentials, with peaks attributable to pure Zn, to the ε-phase, to the η-phase as well as to the α-phase, present in most cases and dissolving at potentials similar to that of pure Cu. ALSV was shown to be a reliable and practical method for a fast determination of both the composition and the phase structure of electrodeposited brass.",
publisher = "Springer",
journal = "Journal of Applied Electrochemistry",
title = "Phase-structure analysis of brass by anodic linear-sweep voltammetry",
volume = "22",
number = "2",
pages = "172-178",
doi = "10.1007/BF01023820"
}

Stevanović, J., Skibina, LJ., Stefanović, M., Despić, A.,& Jović, V. D.. (1992). Phase-structure analysis of brass by anodic linear-sweep voltammetry. in Journal of Applied Electrochemistry
Springer., 22(2), 172-178.
https://doi.org/10.1007/BF01023820

Stevanović J, Skibina L, Stefanović M, Despić A, Jović VD. Phase-structure analysis of brass by anodic linear-sweep voltammetry. in Journal of Applied Electrochemistry. 1992;22(2):172-178.
doi:10.1007/BF01023820 .

Stevanović, Jasmina, Skibina, LJ., Stefanović, M., Despić, Aleksandar, Jović, Vladimir D., "Phase-structure analysis of brass by anodic linear-sweep voltammetry" in Journal of Applied Electrochemistry, 22, no. 2 (1992):172-178,
https://doi.org/10.1007/BF01023820 . .

TY  - JOUR
AU  - Skibina, Lj M.
AU  - Stevanović, Jasmina S.
AU  - Despić, Aleksandar R.
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4389
AB  - Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
VL  - 310
IS  - 1-2
SP  - 391
EP  - 401
DO  - 10.1016/0022-0728(91)85274-S
ER  - 

@article{
author = "Skibina, Lj M. and Stevanović, Jasmina S. and Despić, Aleksandar R.",
year = "1991",
abstract = "Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys",
volume = "310",
number = "1-2",
pages = "391-401",
doi = "10.1016/0022-0728(91)85274-S"
}

Skibina, L. M., Stevanović, J. S.,& Despić, A. R.. (1991). ALSV investigation of the phase composition of electrolytic Cu + Sn alloys. in Journal of Electroanalytical Chemistry
Elsevier., 310(1-2), 391-401.
https://doi.org/10.1016/0022-0728(91)85274-S

Skibina LM, Stevanović JS, Despić AR. ALSV investigation of the phase composition of electrolytic Cu + Sn alloys. in Journal of Electroanalytical Chemistry. 1991;310(1-2):391-401.
doi:10.1016/0022-0728(91)85274-S .

Skibina, Lj M., Stevanović, Jasmina S., Despić, Aleksandar R., "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys" in Journal of Electroanalytical Chemistry, 310, no. 1-2 (1991):391-401,
https://doi.org/10.1016/0022-0728(91)85274-S . .