TY  - JOUR
AU  - Vuković, Marijan
AU  - Čukman, Dunja
AU  - Milun, Milorad
AU  - Atanasoska, Ljiljana L.
AU  - Atanasoski, Radoslav T.
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4739
AB  - The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid on the electrode composition was established. A change in the Tafel slope from 33 to 90 mV per decade on going from pure ruthenium to pure iridium was found. The presence of 40% Ir in the coating yielded 300 times higher stability in comparison with the coating of pure ruthenium. In addition, a square-wave pulsing between -0.25 and 1.25 V vs. the saturated calomel electrode produced an oxide film with electrochromic properties which were directly related to the charge enhancement factor of the grown oxide.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
VL  - 330
IS  - 1-2
SP  - 663
EP  - 673
DO  - 10.1016/0022-0728(92)80335-2
ER  - 

@article{
author = "Vuković, Marijan and Čukman, Dunja and Milun, Milorad and Atanasoska, Ljiljana L. and Atanasoski, Radoslav T.",
year = "1992",
abstract = "The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid on the electrode composition was established. A change in the Tafel slope from 33 to 90 mV per decade on going from pure ruthenium to pure iridium was found. The presence of 40% Ir in the coating yielded 300 times higher stability in comparison with the coating of pure ruthenium. In addition, a square-wave pulsing between -0.25 and 1.25 V vs. the saturated calomel electrode produced an oxide film with electrochromic properties which were directly related to the charge enhancement factor of the grown oxide.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium",
volume = "330",
number = "1-2",
pages = "663-673",
doi = "10.1016/0022-0728(92)80335-2"
}

Vuković, M., Čukman, D., Milun, M., Atanasoska, L. L.,& Atanasoski, R. T.. (1992). Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium. in Journal of Electroanalytical Chemistry
Elsevier., 330(1-2), 663-673.
https://doi.org/10.1016/0022-0728(92)80335-2

Vuković M, Čukman D, Milun M, Atanasoska LL, Atanasoski RT. Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium. in Journal of Electroanalytical Chemistry. 1992;330(1-2):663-673.
doi:10.1016/0022-0728(92)80335-2 .

Vuković, Marijan, Čukman, Dunja, Milun, Milorad, Atanasoska, Ljiljana L., Atanasoski, Radoslav T., "Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium" in Journal of Electroanalytical Chemistry, 330, no. 1-2 (1992):663-673,
https://doi.org/10.1016/0022-0728(92)80335-2 . .

TY  - JOUR
AU  - Spasojević, Miroslav D.
AU  - Krstajić, Nedeljko V.
AU  - Despotov, P.
AU  - Atanasoski, Radoslav T.
AU  - Popov, Konstantin I.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4452
AB  - It is shown that good quality deposits of cobalt-molybdenum alloys may be produced using pulse plating and it is demonstrated that such coatings on titanium have a low overpotential for hydrogen evolution under typical brine electrolysis conditions.
PB  - Switzerland : Springer Nature
T2  - Journal of Applied Electrochemistry
T1  - The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics
VL  - 14
IS  - 2
SP  - 265
EP  - 266
DO  - 10.1007/BF00618745
ER  - 

@article{
author = "Spasojević, Miroslav D. and Krstajić, Nedeljko V. and Despotov, P. and Atanasoski, Radoslav T. and Popov, Konstantin I.",
year = "1984",
abstract = "It is shown that good quality deposits of cobalt-molybdenum alloys may be produced using pulse plating and it is demonstrated that such coatings on titanium have a low overpotential for hydrogen evolution under typical brine electrolysis conditions.",
publisher = "Switzerland : Springer Nature",
journal = "Journal of Applied Electrochemistry",
title = "The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics",
volume = "14",
number = "2",
pages = "265-266",
doi = "10.1007/BF00618745"
}

Spasojević, M. D., Krstajić, N. V., Despotov, P., Atanasoski, R. T.,& Popov, K. I.. (1984). The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics. in Journal of Applied Electrochemistry
Switzerland : Springer Nature., 14(2), 265-266.
https://doi.org/10.1007/BF00618745

Spasojević MD, Krstajić NV, Despotov P, Atanasoski RT, Popov KI. The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics. in Journal of Applied Electrochemistry. 1984;14(2):265-266.
doi:10.1007/BF00618745 .

Spasojević, Miroslav D., Krstajić, Nedeljko V., Despotov, P., Atanasoski, Radoslav T., Popov, Konstantin I., "The evolution of hydrogen on cobalt-molybdenum coating: polarization characteristics" in Journal of Applied Electrochemistry, 14, no. 2 (1984):265-266,
https://doi.org/10.1007/BF00618745 . .

TY  - JOUR
AU  - Krstajić, Nedeljko V.
AU  - Spasojević, Miroslav D.
AU  - Atanasoski, Radoslav T.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4451
AB  - There is practical interest in the use of titanium as a cathode material in brine electrolysis processes. The overvoltage of hydrogen evolution on titanium is, however, very high and, at the same time, hydrogen penetrates the bulk of the metal. Here, a new type of catalytically active coating has been applied on the surface of titanium in order to overcome these problems. The coating consists of a mixture of the thermal decomposition products of lanthanum chloride and sodium molybdate. The coating has been tested for 18 months of continuous operation. No change in the overvoltage gain (of 0.4 V at 3 kA m-2, as compared with pure titanium) nor change in the properties of the bulk metal have been noticed during this period.
PB  - Switzerland : Springer Nature
T2  - Journal of Applied Electrochemistry
T1  - Lanthanum-molybdenum coating for hydrogen evolution on titanium
VL  - 19
VL  - 14
IS  - 11
IS  - 1
DO  - 10.1007/BF00611270
ER  - 

@article{
author = "Krstajić, Nedeljko V. and Spasojević, Miroslav D. and Atanasoski, Radoslav T.",
year = "1984",
abstract = "There is practical interest in the use of titanium as a cathode material in brine electrolysis processes. The overvoltage of hydrogen evolution on titanium is, however, very high and, at the same time, hydrogen penetrates the bulk of the metal. Here, a new type of catalytically active coating has been applied on the surface of titanium in order to overcome these problems. The coating consists of a mixture of the thermal decomposition products of lanthanum chloride and sodium molybdate. The coating has been tested for 18 months of continuous operation. No change in the overvoltage gain (of 0.4 V at 3 kA m-2, as compared with pure titanium) nor change in the properties of the bulk metal have been noticed during this period.",
publisher = "Switzerland : Springer Nature",
journal = "Journal of Applied Electrochemistry",
title = "Lanthanum-molybdenum coating for hydrogen evolution on titanium",
volume = "19, 14",
number = "11, 1",
doi = "10.1007/BF00611270"
}

Krstajić, N. V., Spasojević, M. D.,& Atanasoski, R. T.. (1984). Lanthanum-molybdenum coating for hydrogen evolution on titanium. in Journal of Applied Electrochemistry
Switzerland : Springer Nature., 19(11).
https://doi.org/10.1007/BF00611270

Krstajić NV, Spasojević MD, Atanasoski RT. Lanthanum-molybdenum coating for hydrogen evolution on titanium. in Journal of Applied Electrochemistry. 1984;19(11).
doi:10.1007/BF00611270 .

Krstajić, Nedeljko V., Spasojević, Miroslav D., Atanasoski, Radoslav T., "Lanthanum-molybdenum coating for hydrogen evolution on titanium" in Journal of Applied Electrochemistry, 19, no. 11 (1984),
https://doi.org/10.1007/BF00611270 . .

TY  - JOUR
AU  - Despić, Aleksandar R.
AU  - Atanasoski, Radoslav T.
AU  - Đorović, Mihailo V.
PY  - 1976
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4590
AB  - Electrolytic cells consisting of mercury electrodes immersed into pure aqueous sulphuric acid solution (ideally polarizable electrodes) and in the one containing Ti3+/Ti4+ redox couple (presence of a faradaic process) were shown to resonate with an induction coil connected in series when a.c. of appropriate frequency is applied across the circuit. The parameters of this faradaic resonance, ωr (resonance frequency) and Ar (amplification factor at resonance) depend on the properties of the system such as the concentration of the redox couple and the electrode potential, as well as on the amplitude of the applied a.c. Higher harmonics have been detected even with the lowest applied amplitude (1 mV). A detailed theoretical consideration has been given to the expected resonance properties of an electrode based on purely activation controlled electrode process as well as of the one in which some diffusional effects become significant, for overpotential changes in the linear domain. This was done in an attempt to assess the value of faradaic resonance measurements for studying kinetic properties of electrochemical cells.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - The effect of faradaic processes on the resonance of electrochemical cells
VL  - 70
IS  - 1
SP  - 1
EP  - 16
DO  - 10.1016/S0022-0728(76)80257-4
ER  - 

@article{
author = "Despić, Aleksandar R. and Atanasoski, Radoslav T. and Đorović, Mihailo V.",
year = "1976",
abstract = "Electrolytic cells consisting of mercury electrodes immersed into pure aqueous sulphuric acid solution (ideally polarizable electrodes) and in the one containing Ti3+/Ti4+ redox couple (presence of a faradaic process) were shown to resonate with an induction coil connected in series when a.c. of appropriate frequency is applied across the circuit. The parameters of this faradaic resonance, ωr (resonance frequency) and Ar (amplification factor at resonance) depend on the properties of the system such as the concentration of the redox couple and the electrode potential, as well as on the amplitude of the applied a.c. Higher harmonics have been detected even with the lowest applied amplitude (1 mV). A detailed theoretical consideration has been given to the expected resonance properties of an electrode based on purely activation controlled electrode process as well as of the one in which some diffusional effects become significant, for overpotential changes in the linear domain. This was done in an attempt to assess the value of faradaic resonance measurements for studying kinetic properties of electrochemical cells.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "The effect of faradaic processes on the resonance of electrochemical cells",
volume = "70",
number = "1",
pages = "1-16",
doi = "10.1016/S0022-0728(76)80257-4"
}

Despić, A. R., Atanasoski, R. T.,& Đorović, M. V.. (1976). The effect of faradaic processes on the resonance of electrochemical cells. in Journal of Electroanalytical Chemistry
Elsevier., 70(1), 1-16.
https://doi.org/10.1016/S0022-0728(76)80257-4

Despić AR, Atanasoski RT, Đorović MV. The effect of faradaic processes on the resonance of electrochemical cells. in Journal of Electroanalytical Chemistry. 1976;70(1):1-16.
doi:10.1016/S0022-0728(76)80257-4 .

Despić, Aleksandar R., Atanasoski, Radoslav T., Đorović, Mihailo V., "The effect of faradaic processes on the resonance of electrochemical cells" in Journal of Electroanalytical Chemistry, 70, no. 1 (1976):1-16,
https://doi.org/10.1016/S0022-0728(76)80257-4 . .